Reliance Industries Limited Page 1 Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai RELIANCE INDUSTRIES LIMITED Multi-Purpose Chemical Terminal Chennai, Tamil Nadu Pre-Feasibility Report For Proposed Expansion of Multi-Purpose Chemical Terminal (MCT) from 86928 KL to 108950 KL August 2017
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Reliance Industries Limited Page 1
Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
RELIANCE INDUSTRIES LIMITED
Multi-Purpose Chemical Terminal
Chennai, Tamil Nadu
Pre-Feasibility Report
For
Proposed Expansion of Multi-Purpose Chemical Terminal (MCT) from
86928 KL to 108950 KL
August 2017
Reliance Industries Limited Page 2
Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Contents
Section Description Page
Executive Summary 3
1. Introduction 4
2. Site Information 7
3. Project Description 9
4. Environment Control Measures 13
5. Project Implementation 15
6. Regional Brief 17
Annexure
I Topo sheet showing MCT Chennai 19
II Plot Plan 20
III Material Safety Data Sheet 21
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
EXECUTIVE SUMMARY
The Multipurpose Chemical Terminal (MCT), Chennai of Reliance Industries Limited (RIL)
was set up in year 2004 with the aim of receiving, storing and distribution of finished
Petroleum Products (i.e. Motor Sprit, High Speed Diesel & Ethanol) to the RIL Retail outlet
network for the state of Tamilnadu, Andhra Pradesh. The present capacity of this terminal is
86928 KL.
The terminal is located in the Notified Special & Hazardous Industrial use zone classified by
Chennai Metropolitan Development Authority (CMDA) at Vallur Village, about ~20 km aerial
distance from Chennai city. The terminal is easily accessible by road. The nearest airport of
Chennai Airport located at an aerial distance of ~40 km. The total area of the terminal facility
is ~33 acres and includes the tank farm, truck loading bays, office space and the associated
facilities.
It is now proposed to expand this multipurpose chemical terminal to 108950 KL. In the
proposed expansion, the terminal will increase storage of Class A products such as Motor
Spirit (MS), Naphtha & Ethanol and Class B products such as High Speed Diesel (HSD),
Superior Kerosene Oil (SKO), Aviation Turbine Fuel (ATF) by setting up new tanks and also
explore possibilities to increase the current storage level of existing tanks in-line with the
approvals from concerned statutory authorities. The dispatch of the petroleum products will
be through the existing 16 bays tank truck gantry.
The power supply to the terminal is from Tamilnadu Electricity Board (TNEB) at 11 KV.
During emergency, DG sets will also be used. The existing water requirement for the terminal
operation is ~ 18 KLD sourced from Chennai metropolitan water supply and sewerage
board/other local water supply by tankers. Additional water requirement of ~ 5 KLD for the
proposed project shall also be sourced from same.
The only source of air emissions from the terminal operations are DG sets which are operated
during emergencies and negligible. An Oily Water Separator (OWS) of a capacity of 300 KL
is provided to separate oil and adeqaute to handle the proposed project load also. The
hazardous & non-hazardous wastes generated in terminal shall be segregated and disposed
of through authorized agency as per Hazardous waste rules as per the existing practice. The
terminal has adequate safety & firefighting systems in line with the requirements of OISD
117/ Petroleum Rules 2002 to control any untoward incidents.
The existing manpower at the terminal is ~ 65 personal and may need additional ~ 12 people
during operation. The proposed project will lead to employment generation of ~ 50 people
during construction phase. Local manpower will be preferred. The Capex of the project is ~20
Cores & scheduled to be commissioned in stages starting within one year after the EC is
granted.
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
1. INTRODUCTION
Reliance Industries Limited (RIL) is one of the world leaders in the energy sector and has diversified in areas such as Exploration & Production (E&P) of Oil & Gas (O&G), Refining, manufacturing and marketing of petroleum and petrochemical products. The hydrocarbon retail & marketing arm of RIL has Multipurpose Chemical Terminal (MCT) at Chennai, which was set up in year 2004 for receiving, storing and distribution of finished Petroleum Products (i.e. Motor Sprit, High Speed Diesel & Ethanol) to the RIL & other oil companies retail outlet network in the state of Tamilnadu & Andhra Pradesh.
Presently MCT, Chennai receives the petroleum product from RIL, Jamnagar Refinery through Ennore port and is supplied by ~9 km pipeline from port to the terminal. The products stored in the existing tank farm and sold to the retail outlets, Industrial Customers and other Oil Marketing Companies by tank-trucks based on demand. A schematic diagram showing the project is given below:
The petroleum product storage capacity of the existing terminal is 86928 KL and with a 16 bay tank-truck loading gantry rack for filling the products in truck-tankers for dispatch to retail outlets. Associated facilities of the terminal include 2 DG sets of 325 KVA capacity for power back up and an electrical substation. The power required to operate the terminal is supplied by TNEB at 11 KV.
The terminal is also equipped with a laboratory for batch formation tests. A comprehensive firefighting facility has also been set up at the terminal to meet any untoward incidents. The firefighting capability comprises of fire engines with a hydrant network of 33 hydrants and 21 monitors along with cooling water Sprinklers and Foam Pourer System covering the entire tank farm area.
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
MCT, Chennai now proposes to expand its storage capacity from 86928 KL to 108950 KL within the existing MCT facility.
Project Justification
With an annual increase of ~ 6% in the consumption of petroleum products in the country and also due to the growing clientele of the company, the need for increasing the storage facilities has been felt by the company. This will help the company in expanding its business prospects and meet the future requirement of petroleum products in the state. No additional land is required as the expansion will be implemented within the existing terminal facility, Moreover, this will also provide edge by utilisation of the infrastructure already developed for existing in the facility to meet the proposed expansion. The rationale for the proposed expansion is as below;
Availability of requisite infrastructure facilities
Availability of land for the proposed expansion project within the premises of existing terminal
Lower capital cost compared to the grass root project.
Optimization of existing power and utilities assets
Due to the optimisation and use of available infrastructure and associated utilities for the proposed project activity, the environmental impacts are also reduced
MCT, Chennai has a well-established Integrated Management System, conforming to ISO 14001, 9001 & 18001 standards which will be strengthened and will cover this proposed project as well
Meeting the gap in demand and supply of petroleum products in Southern States in the country
Business Case
The MCT, Chennai is currently selling on an average 27691 KL per month of High Speed Diesel & 11460 KL per month of Motor Spirit with maximum daily sales of 1800 KL & 1200 KL respectively in single shift operation. With the augmentation in tankage, the designed throughput at the terminal would be 2455 KL/day for Class “B” & 1500 KL/day for Class “A” The expected increase in demand per day is:
Product ~ peak
sales/ day
~ Expected Peak sales / day after 3
years
Class B 1500 KL 2455 KL
Class A 1200 KL 1500 KL
The proposed project activity is Expansion of Multipurpose Chemical Terminal from 86928 KL to 108950 KL
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
As per the Environment Impact Assessment (EIA) Notification, 2006 the project falls under 'Category 6b - Isolated Storage & Handling of Hazardous Chemicals’ (As per threshold planning quantity indicated in column 3 of Schedule 2 & 3 of MSIHC Rules 1989 amended 2000), which requires Environment Clearance (EC) from SEIAA . This report is the prefeasibility report of the expansion project submitted to obtain terms of Reference (ToR) for carrying out the environment impact assessment studies and prepare an Environmental Impact Assessment (EIA) Report.
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
2. SITE INFORMATION
Site Location & Connectivity
The MCT, Chennai is located at Vallur Village, Ponneri Taluka, Tiruvallur Dist, Tamil Nadu ~20 km aerial distance from Chennai city. The MCT is located in the Notified Special & Hazardous Industrial use zone classified by Chennai Metropolitan Development Authority (CMDA). The area of the terminal facility is 33 acres and includes the tank farm, truck loading bays, office space and the associated facilities. The nearest airport is at Chennai located at an aerial distance of ~40 Km. The major road connectivity is from Manali- Minjur State Highway (SH-56) which is at an aerial distance of ~1.5 km. The Chennai- Sulurpetta- Nellore rail line is on the North East of the terminal and the nearest railway station is Athipattu Pudhunagar which is at an aerial distance of ~ 2 km. The site location map is shown below, the toposheet showing the MCT is given in Annexure-I.
Location Map of MCT Chennai
Latitude Longitude
13°13'59.28"N 80°17'13.65"E
13°14'6.95"N 80°17'14.99"E
13°14'11.66"N 80°17'14.30"E
13°14'13.28"N 80°17'15.54"E
13°14'12.79"N 80°17'18.30"E
13°14'13.21"N 80°17'18.72"E
13°14'12.92"N 80°17'21.84"E
13°14'11.28"N 80°17'21.62"E
13°14'11.39"N 80°17'20.28"E
13°14'9.19"N 80°17'19.60"E
13°14'8.69"N 80°17'22.63"E
13°14'6.29"N 80°17'22.08"E
13°14'5.53"N 80°17'24.88"E
13°13'58.83"N 80°17'24.12"E
13°13'57.78"N 80°17'26.09"E
13°13'54.57"N 80°17'25.66"E
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Land use and ownership
The proposed expansion will be carried out within the existing facility of the terminal. Hence, no alternate sites were considered for the project. The land use is industrial and no new land acquisition is required for the project. The land required for the expansion of the terminal facilities is already in possession of RIL. There are other terminal being operated around the terminal of the proposed project such as IOCL, HPCL etc. The survey numbers of the terminal are 1194, 1191, 1190, 1192, 1193, 1189/2, 1184, 1185, 1183, and 1177.
Land Area Details
The MCT is spread out in an area of 33 Acres. The proposed expansion will utilise existing
facilities and will not need additional area.
Area break-up
Description of Facility Area
(~Acres)
Existing Facilities
Storage Tanks, Roads, Open space, Loading Gantry 19.6 TT parking 1.54 Built-up area: Substation, DG Room, Admin Building, Security & Load Office, Workshop & Lab, Fire Water Pump House & Truck Driver Canteen 0.28
Proposed Project Storage Tanks 1.08 Green belt 10.5 Total Area 33
General Climate features
The project location has a humid subtropical climate, with cool, dry winters, a hot summer and a humid monsoon season. Summers start in late March and go on till mid-June, the average temperature being around 35 °C , with the peak of summer in May, when the highs regularly exceed 45 °C. The monsoon starts in late June and ends in late September.
Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
3. PROJECT DESCRIPTION
The facility at MCT, Chennai is designed in accordance with statutory requirements and International standards. MCT has its own HSSE management system which incorporates all the relevant statutory requirements and standards. The terminal receives refined petroleum products from Jamnagar refinery by Ocean tanker. The finished product is received into the storage tanks by 24” Jetty Pipeline. The terminal receives the product in their pure form. The clean products are loaded into dedicated tanks, and stored at atmospheric pressure. The storage tanks are contained in a single dyke area, segregated by firewalls in accordance with the provisions of the OISD-117 & Petroleum Rules 2002. The below table lists the details of existing storage capacities and the proposed expansion in storage capacities
Details of Storage Capacity Existing as well as Proposed Flammability
Class
Product Existing Capacity
(KL)
Proposed Expansion
Operational Capacity
(KL)
Total
Operational
Capacity
(KL) Safe
Storage
Capacity
(CCoE
Approved)
Operating
Storage
Capacity
Augmentation of
Capacity in
existing Tanks
Storage in
New
Tanks
Class A
Motor
Spirit*/Naphtha
34648
(6 tanks)
30301 4347 -- 34648
Ethanol* 40
(1 tank)
40 -- 80
(2 tanks)
120
Class B
High Speed
Diesel*
64512
(6 tanks)
56587 7925 -- 64512
Aviation
Turbine Fuel/
Superior
Kerosene Oil
-- -- -- 9670
(2 tanks)
9670
Total 86928 108950
-- Power
(DG set)
2 x 325
KvA
1 x 500
KvA
1150
KvA
Note: *Products stored at present
Product Receipt
The finished petroleum products are received at the Ennore jetty from the RIL Jamnagar Refinery. The products are transported to the MCT through a ~9 km pipeline. No modifications are envisaged in the pipeline during this proposed project. The pipeline has all the required statutory approvals in place and the same pipeline shall be used during the proposed project as well. The pipeline is provided with pigging facility, the pig launch facility is provided at jetty whereas the receiving facility is provided at the terminal with depressuring system.
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Dispatch facilities
Products are transferred to the Gantry by dedicated product pumps. There are 16 bays within the gantry, all the bays are designed for top loading through loading arms of 3 inch diameter. All the bays are also designed for bottom unloading through 3 inch unloading hoses. The products are delivered at minimum rate of 300 LPM & maximum rate of 1150 LPM per arm for the products. In the proposed expansion requires no additional dispatch facilities envisaged and the existing facility shall be used.
Loading Facilities
The loading of the Truck-Tankers (TT) operation is fully automated through the Terminal Automation System (TAS). The gantry area is classified as a Zone 1 hazard area and all electrical equipment used in the area are of intrinsically safe type. All TT are also inspected to ensure the electrical wirings and electrical equipment (e.g. lightings) is safe and properly secured. The top loading bays are also fitted with additional safety feature for working at height
Swing platform which provide access from the platform to the TT;
Safety harness to protect drivers from falling from TT to the ground;
Easily accessed staircases situated at each platform. The height of the platform is 3.4 meters and made of anti-slip gratings.
The terminal plot plan showing the facilities is provided in Annexure-II. The table below provides an overview of the terminal facilities.
Terminal Facility Overview
Description Item Description
General Distribution of product is via TT using gantry facility Gantry operations from 0900 to 2200 hours
Products handled Receipt: MS (Grade - MS BSIV), HSD (Grade -HSD BSIV) & Delivery: MS,HSD
Pipeline within Terminal
Ocean Tanker receipt line:, 24” for HSD & MS Delivery line from tanks: 14” for HSD, 10”&12” for MS
Loading arm type Aluminium alloy 3” loading arm with spring loaded Dead-man Valve for all products & Over spill Sensors
Firefighting facilities
Fire water tanks (designed for 4 hours of the 150% of maximum fire water demand based on different emergency scenarios) Pressurised fire water network designed to provide a minimum residual pressure of 10.5 kg/cm2 at the most hydraulically remote point when the maximum fire water as per demand is being discharged midway of the fire water network. The network consists of
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
single/double hydrants, water cum foam monitors & water monitors. Hydrant valves are designed for operating at a pressure of 10.5 kg/cm2. Pressure is maintained by 2 jockey pump and 6 diesel fired water pumps Jockey pumps & Firewater pumps automatically start at set pressures as per the design philosophy. Jockeys stop automatically at set pressure while the firewater pumps are stopped manually. Fixed foam pourers for all tanks, manually activated Water sprinklers for all product storage tanks Water cum foam monitors at gantry and Tank Farm
Utilities
The details of the existing utilities such as power, instrumentation, water etc are given below;
Power
Power supply (main and standby) at MCT is through Tamilnadu Electricity Board (TNEB) at 11 KV. This is stepped down to 415V and utilized in the terminal. 11 KV overhead transmission line from Napalayam Substation of TNEB has been installed to provide required electrical power supply for the operations and illumination at the terminal. Bi-pole structure is provided to support outdoor equipment. To measure electrical energy consumed, electronic meter has been installed in TNEB switchyard. 11 KV/433 Volt / 1600 KVA Transformer is provided to step down electrical power and its output is connected to Power and Motor Control Center (PMCC) from where power distributed to equipment through Motor control Centers (MCC’s). The PMCC and MCC’s are housed in electric substation along with relay panel and other control panels. 2 x 325 KVA, 415 Volt DG sets are installed to cater to the power requirement in case of TNEB power supply failure for uninterrupted operations at terminal. 2 x 20 KVA UPS modules have been installed to provide uninterrupted power supply to Terminal automation System and Computers for safe shut down of terminal equipment. During the proposed expansion additional DG set with capacity 1 x 500 KVA will be included.
Instrumentation & Automation Instrumentation and Automation will be provided through the following:
Terminal Automation System (TAS – Road loading pumps /gantries. Also included is Ocean tanker receipt system)
Tank Farm Management System (TIS- Product receipt and storage)
Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Water
The water required for the terminal such as operation, domestic, fire water etc. The existing water usage at the terminal is ~ 18 KLD supplied by Chennai metropolitan water supply and sewerage board, through pipeline. During the proposed project an additional water quantity of ~ 5 KLD is envisaged which will be supplied by Chennai metropolitan water supply and sewerage board which has already allotted ~ 20 KLD of water and also the water will be sourced locally, supplied through tankers on need basis. Fire water make-up is purchased locally and supplied through tankers on need basis. Firewater quantity is based on OISD 117. The below table provides the details on the water storage and requirement.
Water Requirement
Activity Existing (KLD) After Proposed
Expansion (KLD)
Source
Domestic 10 12 Metro Water /
Purchased from local
water suppliers through
tankers for fire water
make-up
Operation 3 4
Green belt 5 7
Fire fighting Used only during
emergency
12836 KL (Stored Capacity)
Used only during
emergency
19254 KL (Stored
Capacity)
Purchased from local
water suppliers through
tankers for fire water
make-up
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
4. ENVIRONMENT CONTROL MEASURES
The proposed expansion involves receipt, storage and distribution of petroleum products only. No manufacturing is involved and hence, no significant emissions are envisaged from the proposed expansion except from DG sets, which are used only during emergencies. Emissions from the DG sets shall be vented out through stack as per statutory norms and will be monitored. Fugitive emission from the proposed project is envisaged during construction and from storage tanks. Construction in the proposed project is a shortterm activity and fugitive emission from this activity is negligible and controlled. Adequate control measures such as seals, roof design are in place in the storage tanks to control fugitive emissions. Periodic monitoring is being carried out to detect & control such fugitive emissions and the same shall be strergthened during the proposed project. There will be no effluent generated from this project. However, an Oily Water Separator (OWS) is provided for separation of oily water mixture. The exisitng OWS system of capacity 300 KL for the separation of water oil mixture drained from storage tanks, gantry drains and other operating areas. In case of any spillage of oil during gantry operation or from tankage area shall be sent to OWS. The TPI in the OWS helps in further separation of oil from water up to 10ppm oil in water. The water from OWS/TPI will be reused for dust suppression during truck movement. Separate storm water drains are provided at the terminal. This drains carry storm water from tank dykes/other areas outside the terminal premises in a controlled manner. Plans are in place to utilise this water for green belt development.
The terminal is completely paved in operational areas. In case of leak/spill, the product to be retrieved with the help of adsorbents to reduce loss and prevent environmental damage. The product retrieved shall be subjected to laboratory test for reuse into storage tanks or disposed of as per HWM rules. While loading road tankers, the leak/spill is contained and recovered to minimize the loss and prevent soil contamination. A drum/trays are used to collect any leakage/spillage around pumps areas and the bailed out oil from the drum/trays are taken back to respective tanks. In case of strainer cleaning of pumps & filter, arrangement are made to ensure complete draining of oil in trays/drums. Sampling drums are used for collection during sampling and are periodically emptied out in unloading line and taken to respective tank. Spillages of grease/oil are minimized during overhauling/maintenance of equipment. Arrangements are made for collection of excess oil/grease used. Adequate quantity of adsorption material (cotton waste, rags etc.) is kept handy while carrying out the maintenance. All containers/boxes of grease/oil stored in containers in workshop are covered at all times and protected from fall during storage, to avoid spillage.
Sewage from the administrative building is routed to the septic tanks and the sludge generated from septic tanks will be dried and used a manure in the green belt. Other solid waste generated in terminal from operational activities are classified as hazardous & non-hazardous material & it is safely disposed of through authorized agency as per statutory norms. The below table provides the details of the Solid waste that generated during the existing project as well during the proposed expansion. These wastes are generated only during maintenance activities.
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Details of Waste generated
Type of Waste Existing Quantity
(Tons/Year)
~Expected Quantity
(Tons/Year)
Used Oil 1.5 2.5
Fuel Filters 0.5 1
Oily Sludge 1.4 2.8
Contaminated drums 6 9
The terminal has a green belt of ~10.5 Acers which shall be strengthened during the proposed
expansion.
Safety at Terminal
The following safety measure are provided to ensure that the safety standards are in line with
the applicable regulations & current best industry practices.
Remote operated valves are provided in each pipe connecting to the tank inlet & outlet.
Tank level gauging instrumentation, alarm and safety interlock system are provided
using independent guided wave radar type & level transmitters type gauging
instruments
Fixed water spray system are provided for storage tanks as per OISD 117 guidelines.
Semi-fixed foam system with suitable heat detection and alarm system to ensure
timely application of foam to prevent escalation of rim seal & tank pool fires.
Emergency push buttons stations to stop all operations and isolating the product
storage tanks are provided at safe locations in the Terminal to prevent any fuel
released in case of a leak.
Fire protection facilities are provided fully meeting the requirements of Oil Industry Safety
Directorate Standard (OISD-117). These include the following:
Fire water storage tanks to meet 2 simultaneous largest fire contingencies in the
terminal: 6418 KL x 2 tanks
Main fire water pumps and jockey pump:- 3 jockey pumps & 6 fire water pumps
Fire water network with hydrants (33 Nos), monitors (21 Nos) and medium-velocity
sprinkler systems (all storage tanks);
Fixed foam system (all storage tanks), foam storage: 16000 litres
Mobile firefighting equipment : 83 Nos of 9 kg extinguishers, 10 Nos. of 25 kg
extinguishers, 5 Nos. of 75 kg extinguishers, 14 Nos of CO2 type extinguishers
Portable fire extinguishers: 5 Nos of 200 litres foam trolley;
Fire detection & alarm system including manual call points (37 points); and
Hydrocarbon carbon detectors are provided in the MS tanks dyke and pump bay with
Audio Visual Alarm at field and Control room in case of hydrocarbon leak.
An Emergency Management System has been provided in operation management and in emergency, on operating ESD switch, all operation in the terminal will stop the pumps and close the motor operated valves at the tank outlets.
The MSDS of the products being stored is provided in Annexure-III
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
5. PROJECT IMPLEMENTATION
Execution Strategy
Execution of the project includes engineering, procurement, construction, installation and start-up the facilities and it will follow the disciplined and orderly project management approach. Established Project management processes and procedures of RIL shall be adopted to complete the project safely within approved Budget, Schedule and Quality. Basic engineering shall be executed by the Terminal team, Detailed Engineering for this project shall be executed by Detail Engineering Consultant i.e. Mumbai Engineering Group (MEG) Detail engineering activities includes development of overall engineering deliverables for all disciplines. Procurement shall be done with the help of Procurement and Contracts department. Engineering deliverables for procurement such as SOQ for construction contracts, MRs for all tagged equipment and PR for all bulk items shall be developed by MEG. Commissioning and Start-up of the plant shall be joint responsibility of MEG and MCT Site operations. After successful start-up and handover of facilities, Maintenance and Operation of the facility will be performed by the MCT Operations with routine inspections and surveillance throughout the design basis life cycle.
Project Schedule
The proposed project is scheduled to be commissioned in stages starting within one year after EC is granted. Following are the major activities which will be scheduled based on logical interdependencies in order to complete this project as per schedule:- Engineering:
An experienced and well-equipped project management team shall be deployed to execute, monitor and control the project throughout the engineering, procurement phases till start-up. Major activities in project management includes the following:-
Interface with various internal and external stakeholders supporting the project
Ensuring compliance with all regulatory requirements
Coordinating the development of “Basic Engineering design package”
Leading the detailed engineering phase and directing detail engineering consultant (MEC) for development of engineering deliverables to enable procurement and construction activities
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Timely communication (review meetings, written communication, reports etc) with all stakeholders
Enabling procurement activities by providing necessary inputs i.e. MR for long lead items, SOQs for contracts, bids/ tender evaluation, contract award etc.
Materials Management & Quality Assurance
Co-ordination for overall activities at site
Project Control activities such as planning, scheduling, monitoring/ controlling, cost control, variance analysis etc
Reporting of project progress
Co-ordination for commissioning and start-up activities to ensure successful “performance guarantee test run” of the project
Handover of plant to Asset owner and Close-out of the project
Manpower
The existing manpower at the terminal is ~ 65 personal. The proposed project will lead to
employment generation of ~ 50 people during construction phase. Local manpower will be
preferred. During the operation phase of the proposed expansion additional ~ 12 people will
be employed on a continuous basis.
Project Schedule & Cost
The proposed project is scheduled to be commissioned in stages starting within one year after
EC is granted. The estimated cost of the project ~ 20 Cores.
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
6. REGIONAL BRIEF
The followings sections provide a brief on the regional setting.
Type of industries, habitations, facilities, transportation etc.
The study area is fast industrialising taking advantage of the nearby Ennore Port (Kamarajar Port Limited) which is located about ~7 kms to the East of the RIL MCT Facility. The port is being developed as an Energy Port and at present is the 12th largest major port in India. Taking advantage of the port, the study area is developing as a logistic and storage hub with several other facilities storing petroleum based products. Existing industrial facilities falling in the vicinity of MCT are NTECL TPP, Ashok Leyland, North Chennai Thermal Power Station, HPCL Ennore Terminal, IOC Petronas LPG Terminal, EID Parry Fertilizer Factory, Zuari Cements, India Cements, etc. Several other heavy/manufacturing industries are also located to the immediate south of the 10 kms study area and they form a part of the Manali industrial region. There are habitations within the 10 km radius area such as Ennore town, Minjur, Manali new town, Ponneri, Cholavaram, Vichoor, and other small villages.
Demographic Structure
As per the 2011 census, the 10 km study area around the facility comprises of a population of 47,40,388 individuals. The percentage of males and females are 50.27% and 49.72% respectively with the sex ratio being 989. The prevailing literacy level is 79%. About 1.83% population belong to Scheduled Tribes (ST) and 47.83% Scheduled Castes (SC) indicating that about 49.67% of the population in the study area belongs to socially weaker sections.
Ecological Setting
There are no declared National Parks or Sanctuaries located within 10 km radius of the MCT.
There are water bodies located within 10 km such as Kosatalayar river, Buckingum canal,
Puzhal lake, Cholavaram lake, retteri lake etc.
Assessment of Infrastructure Demand (Physical and Social)
The infrastructure resource base of the area with reference to education, medical facilities, water supply, post and telegraph, transportation and communication facilities and power supply etc. are briefly described below: Education: The villages and sub-urban towns located within the 10 km study area have access to 49 govt. primary schools, 22 middle schools, 7 secondary schools and 2 senior secondary schools. Other than that, there are several private educational facilities imparting education from primary to higher education lying within the Chennai Municipal Corporation area. Communities within the study area are mostly dependent on Chennai for fulfilling the needs of higher education.
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Drinking Water: As per Census 2011 data, tap water supplies from treated sources are available in the entire study area and people depend on this source both for drinking and daily household uses. Other than that several tube wells are also present within the study area. However, being close to the coastal area, the water in saline.
Communication and Transportation:
State Highway 56 which is aligned from north to south within the study area is the main arterial road / highway servicing the area. The highway also acts as the key road linkage to the Ennore Port through the Athipattu Main Road. All weather roads are present in all neighbouring villages and regular bus / auto services are available in almost all the villages. The Southern Railway main line which runs through the Coromandel Coast also traverses though the study area and connects to Chennai city. Two nearby railway stations are Nadiyampakkam and Attipattu which have EMU local train services, in addition to long distance express train plying through them. A Post office/sub-post offices are present 7 villages within the study area. Post offices are also present in nearest urban areas. Telephone and cell phone connectivity is available in the entire area.
Power Supply: Power supply is available in all of the villages and sub-urban areas within the study area.
Medical/Primary Health Care: 8 Primary health sub-centres are present and 7 primary health centres is present in study area villages. Several hospitals are present in neighbouring Chennai city which are regularly accessed by people of the area.
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Annexure-I
Toposheet showing MCT Chennai
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Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Annexure-II
Plot Plan
Proposed Tanks
Reliance Industries Limited Page 21
Project Pre-Feasibility Report - Multipurpose Chemical Terminal, Chennai
Annexure-III
Material Safety Data Sheets
(Material)Safety Data Sheet Issue Date: Jan. 01, 2016 AVIATION TURBINE FUEL/JET A-1 Supercedes: Aug. 01, 2013
Flash point < 23 degrees C and initial boiling point < 35 degrees C. Extremely flammable liquid and vapour
Flash point < 23 degrees C and initial boiling point > 35 degrees C. Highly flammable liquid and vapour
Flash point > 23 degrees C< 60 degrees C. Flammable liquid and vapour
Flash point > 60 degrees C < 93 degrees C. Combustible liquid
Not Applicable
Note: Gases concentration are expressed in parts per million per volume (ppmV). NOTE 1: Category 5 is for mixtures which are of relatively low acute toxicity but which under certain circumstances may pose a hazard to vulnerable populations. These mixtures are anticipated to have an oral or dermal LD50 value in the range of 2000-5000 mg/kg bodyweight or equivalent dose for other routes of exposure. In light of animal welfare considerations, testing in animals in Category 5 ranges is discouraged and should only be considered when there is a strong likelihood that results of such testing would have a direct relevance for protecting human health.
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NOTE 2: These values are designed to be used in the calculation of the ATE for classification of a mixture based on its ingredients and do not represent test results. The values are conservatively set at the lower end of the range of Categories 1 and 2, and at a point approximately 1/10th from the lower end of the range for Categories 3 – 5. GHS Category table for reference: Continued
Study/hazard statement
Category 1 Category 2 Category 3
Eye Irritation
Effects on the cornea, iris or conjunctiva that are not expected to reverse or that have not fully reversed within 21 days. Causes severe eye damage.
2A: Effects on the cornea, iris or conjunctiva that fully reverse within 21 days. Causes severe eye irritation. 2B : Effects on the cornea, iris or conjunctiva that fully reverse within 7 days. Causes eye irritation.
Not applicable
Skin Irritation
Destruction of skin tissue, with sub categorization based on exposure of up to 3 minutes (A), 1 hour (B), or 4 hours (C). Causes severe skin burns and eye damage.
Mean value of >2.3 > 4.0 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed); inflammation that persists to end of the (normally 14-day) observation period. Causes skin irritation.
Mean value of >1.5 < 2.3 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed). Causes mild skin irritation.
Environment: Acute Toxicity Category
96 hr LC50 (fish) <1 mg/L 48 hr EC50 (crustacea) < 1 mg/L, 72/96 hr ErC50 (aquatic plants) < 1 mg/L Very toxic to aquatic life
Extremely flammable aerosol Flammable aerosol Not Applicable
Flammable solids
Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time < 5 minutes Flammable solid
Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire for at least 4 minutes and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time > 5 < 10 minutes Flammable solid
Not Applicable
Flammable gases
Gases, which at 20 degrees C and a standard pressure of 101.3 kPA: (a) are ignitable when in a mixture of 13% or less by volume in air; or (b) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Extremely flammable gas
Gases, other than those of category 1, which, at 20 degrees C and a standard pressure of 101.3 kPA, have a flammable range while mixed in air. Flammable gas
Not Applicable
GHS Label: GHS08: Carcinogen
Signal word: Danger
Details of Statements:
Hazard Statements
H304: May be fatal if swallowed and enters airways. H226: Flammable liquid and vapour.
Precautionary Statement Prevention
P102: Keep out of reach of children. P103: Read label before use. P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P280: Wear protective gloves/protective clothing/eye protection/face protection*.
Precautionary Statement Response
P101: If medical advice is needed, have product container or label at hand. P301 IF SWALLOWED: P310: IF SWELLOWED: Immediately call a POISON CENTER or doctor/physician.
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P331: Do not induce vomiting. P303 +P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 + P378: In case of fire: Use foam or water fog for extinction
Precautionary Statement
Storage
P405: Store locked up. P403 + P235: Store in a well-ventilated place. Keep cool.
Precautionary Statement Disposal
Follow local regulation
Data reference: Official Journal of the European Union regarding EU GHS Hazard ratings:
NFPA HAZARD CODES RATINGS SYSTEM
HEALTH: 2 0 = No Hazard
FLAMMABILITY: 2 1 = Slight Hazard
INSTABILITY: 0 2 = Moderate Hazard
3 = Serious Hazard
4 = Severe Hazard
Data Reference: http://ecb.jrc.ec.europa.eu/esis/index.
2.2 Information pertaining to particular dangers for human: Ingestion The swallowing of small amounts is unlikely to have adverse effects; larger amounts may cause irritation with diarrhoea and vomiting. Skin Unlikely to cause irritation on single contact. Prolonged or repeated contact may cause dermatitis which could eventually lead to irreversible skin disorders. Injection of fuel under pressure through the skin may have serious effects which at first may not seem serious but, within hours, may become very painful. Eyes May cause irritation with short-term redness and stinging. Inhalation Fumes or vapour may cause irritation to eyes and mucous membranes, and drowsiness leading to loss of consciousness.
2.3 Information pertaining to particular dangers for the environment: NA
2.4 Other adverse effects: There are small concentrations of cetane no. improvers, flow improvers, anti-foam and detergent additives and marker/dye that are not considered to represent a health risk. Injection of fuel under the skin may have serious medical effects. Route of entry: Occupational exposure can occur through inhalation, dermal contact and ingestion.
DATA REFERENCE: http://toxnet.nlm.nih.gov/cgibin/sis/search.
Health hazards:
Source NTP listed? IARC cancer review group? OSHA Regulated?
Carcinogenicity No No No
DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and Health
Administration (OSHA) carcinogen, National Toxicological program (NTP), International
Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgi-bin/sis/search.
Section 3 – COMPOSITION & INFORMATION ON INGREDIENTS
(Material)Safety Data Sheet Issue Date: Jan. 01, 2016 AVIATION TURBINE FUEL/JET A-1 Supercedes: Aug. 01, 2013
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Ingredients CAS No. EINECS No. Percentage
Kerosine (Petroleum) 8008-20-6 232-366-4 0-100%
Kerosine (Petroleum),
Hydrodesulphurised
64742-81-0 265-184-9 0-100%
Kerosine (Petroleum)
Sweetened
91770-15-9 294-799-5 0-100%
NA: Data not available
Data reference: http://ecb.jrc.ec.europa.eu/esis/, http://toxnet.nlm.nih.gov/cgi-
bin/sis/search/
Section 4 – FIRST AID MEASURES
4.1 General advice IMMEDIATE MEDICAL ATTENTION IS REQUIRED AFTER INHALATION OR AFTER SWALLOWING. In case of health troubles or doubts, seek medical advice immediately and show this (Material) Safety Data Sheet. Ensure activity of vitally important functions until the arrival of the doctor (artificial respiration, inhalation of oxygen, heart massage). If patient is unconscious, or in case of danger of blackout, transport patient in a stabilised position. In case of first degree burns (painful redness), and second degree burns (painful blisters), cool the affected area with cold running water for a long time. In case of third degree burns (redness, cracking pale skin, usually without pain), do not cool affected skin, dress the area with sterile dry gauze only. 4.2 Inhalation If inhalation of vapour causes irritation or drowsiness remove to fresh air. Get medical advice if the symptoms continue.
4.3 Skin contact Wash skin as soon as possible with water. Change contaminated clothing and launder before reuse. Get medical advice if irritation persists. Any injection of fuel under the skin should be considered an EMERGENCY - get Medical Advice URGENTLY. 4.4 Eye contact Wash out thoroughly with large amounts of water. If redness and/or irritation continues get medical advice. 4.5 Swallowing Wash mouth out with water and give water to drink. If a large amount has been swallowed get medical advice. DO NOT INDUCE VOMITING BECAUSE OF THE DANGER OF ASPIRATION.
Section 5 – FIRE FIGHTING MEASURES
5.1 Suitable extinguishing media Extinguish with Dry Powder, Foam or Water Fog. For small fires use CO2 5.2 Extinguishing media to be avoided Do not use water jets
5.3 Caution about specific danger in case of fire and fire-fighting
procedures Fires in closed or confined spaces should be tackled by trained personnel who should wear breathing apparatus. 5.4 Special protective equipment for fire-fighters
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Wear full protective fire-resistant clothing and self-contained breathing apparatus.
Section 6 –ACCIDENTAL RELEASE MEASURES
6.1 Person-related safety precautions Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard. May cause damage to surfaces making them SLIPPERY. 6.2 Precautions for protection of the environment Prevent from further leaks of substance. Do not allow substance to enter soil, water and sewage systems. In case of substance discharge to water courses or containers, inform water consumers immediately. 6.3 Recommended methods for cleaning and disposal Contain spillage - do not wash spillage down drain. Absorb using absorbent clay, or other suitable absorbent.
Section 7 –HANDLING AND STORAGE
7.1 Information for safe handling Its derivatives are designed to be used in closed systems. Avoid skin contact when refueling vehicles or working on fuel system components. Where exposure is likely PROTECTIVE CLOTHING should be worn including impervious GLOVES and EYE PROTECTION. Ensure good ventilation. 7.2 Information for storage Drums should be stored on their sides on racks preferably under cover, out of direct sunlight, in well ventilated conditions. Other types of containers should be stored under cover out of direct sunlight, in well ventilated conditions. Care should be taken to avoid over-stacking. 7.3 Information for specific use: NA.
Section 8 –EXPOSURE CONTROL & PERSONAL PROTECTION
8.1 Occupational Exposure Limits: Material Source Type ppm mg/m3 Notation
Kerosine (Petroleum)
ACGIH TWA NA 200 Skin;A3 ACGIH STEL NA NA ACGIH SKIN_DES TWA NA NA NIOSH IDLH OSHA TWA OSHA STEL
NA: Data not available
8.2 Occupational exposure controls
Collective protection measures: General and local ventilation, effective exhaust. Individual protection measures: Personal protective equipment (PPE) for the protection of eyes, hands and skin corresponding with the performed labour has to be kept at disposition for the employees. In cases, where the workplace exposure control limits cannot be observed with the help of technical equipment or where it is not possible to ensure that the respiratory system exposure does not
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represent a health hazard for the personnel, adequate respiratory protection have to be kept at disposition. In the case of continuous use of this equipment during constant work, safety breaks have to be scheduled, if the PPE-character requires this. All PPE have to be kept in disposable state and the damaged or contaminated equipment has to be replaced immediately. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):
HANDS EYES BODY RESPIRATORY
Respiratory protection: Unlikely to be required in normal use but ensure good ventilation. Eye protection: Eye protection is recommended at all times Hand protection: Wear gloves of impervious material.
Body protection: Hand and skin protection recommended at all times. Hygiene Measures: Wash hands, forearms and face thoroughly after handling. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
8.3 Environmental exposure controls: Proceed in accordance with valid air and water legislative regulations. Engineering measures: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Section 9 –PHYSICAL AND CHEMICAL PROPERTIES
Appearance Almost colourless or Pale yellow, liquid Odour Characteristic not disagreeable odour Solubility in water Insoluble Relative Density (H2O=1) 0 .8 Boiling Point °C 175 – 325°C Melting Point °C -48°C Relative Vapour Density (Air=1) >5 Flash point °C 35°C – 65°C (depending upon composition). Auto ignition °C 210°C Vapour pressure (mmHg) @ 20 °C 0.480 Molecular weight NA Explosive limits in air % by volume LEL 0.5% UEL 5.0% pH NA Viscosity mm2/Sec@40 °C NA Pour point NA Evaporation rate (water=1) NA Octanol/water partition coefficient log Kow
NA
(Material)Safety Data Sheet Issue Date: Jan. 01, 2016 AVIATION TURBINE FUEL/JET A-1 Supercedes: Aug. 01, 2013
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% volatile NA NA: NOT AVAILABLE DATA REFERENCE: http://toxnet.nlm.nih.gov/cgi-bin/sis/search:
Section 10 –CHEMICAL STABILITY AND REACTIVITY INFORMATION
10.1 Conditions to avoid: Heat.
10.2 Material to avoid: May react with strong oxidising materials. 10.3 Hazardous decomposition products With incomplete combustion smoke and hazardous fumes and gases, including carbon monoxide may be formed.
Section 11 –TOXICOLOGICAL INFORMATION
11.1 Acute effects Acute toxicity data:
Parameter Route Species Values Exposure period LD50 Oral Rat 28000 mg/kg Not applicable LC50 Inhalation Rat >5.28 mg/l 4h LD50 Dermal Rabbit >2000 mg/kg 24h Data Reference: http://toxnet.nlm.nih.gov/cgibin/sis/search.; http://java.epa.gov/chemview# 11.2 Repeated dose toxicity Chronic effects prolonged exposure may cause lung and skin irritation. 11.3 Sensitisation May cause skin allergy. 11.4 CMR effects (carcinogenicity, mutagenicity, toxicity for reproduction) CAS No. 8008-20-6: showed carcinogenicity (tumor promotion) in mice. Substance does not have mutagenic effects. Substance dose not have adverse effect on reproduction. 11.5 Toxicokinetics, metabolism, distribution: NA.
Section 12 –ECOLOGICAL INFORMATION
12.1 Ecotoxicity data: NA
NA: Data not available
12.2 Mobility
Moderate to Low mobility in soil
12.3 Persistence and degradability
Kerosene (8008-20-6)
Persistence: P1 (Low) - P2 (Moderate)
Degradability: This product is inherently biodegradable. 12.4 Bio accumulative potential
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B1 (Low) to B3 (High) 12.5 Results of PBT assessment Persistence and Degradation: The rate of photo oxidation is expected to be slow to rapid for most components of the category. 12.6 Other adverse effects May bio accumulate; films formed on water may affect oxygen transfer and damage organisms. Likely to biodegrade slowly. Environmental Fate: If released to soil, it is expected to biodegrade under both aerobic and anaerobic conditions.
Section 13– DISPOSAL CONSIDERATION
Local Legislation: Disposal should be in accordance with applicable regional, national, and local laws and regulations. This product should not be dumped, spilled, rinsed or washed into sewers or public waterways.
13.1 Recommended disposal methods for the substance / mixture
Product reuse or disposal in accordance with valid waste legislative regulations.
13.2 Recommended disposal methods for contaminated packaging
Product is transported in tank-vehicles. 13.3 Waste management measures that control exposure of humans and environment
Proceed in accordance with valid health, air and water legislative regulations. 13.4 Waste regulation Dispose by incineration or by methods approved by Local Authority. Do not discharge into the public drainage system, or marine and inland waterways.
(M)SDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989. The Factories Act 1948 International Regulations: European SDS Directive ANSI MSDS Standard ISO 11014-1 1994 WHMIS Requirements United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives
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Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council
*RISK PHRASES: R10: Flammable, R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, R65 - Harmful: May cause lung damage if swallowed, R67: Vapours may cause drowsiness and dizziness.
*SAFETY PHRASES: S2: Keep out of the reach of children, S24: Avoid contact with skin, S43: In case of fire, use: Extinguish with carbon dioxide, dry chemical, foam or water spray. Do not use water jet or water spray, S61: Avoid release to the environment. Refer to special instructions/Safety Data Sheets, S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label *These standard risk and safety phrases for use when interpreting (Material) Safety data Sheets are derived from the European Union Regulation, CHIP Regulations - Chemicals (Hazard Information and Packaging for Supply). They are required to be used in (Materials) Safety Data Sheets to identify potential hazards and offer safe handling advice.
Section 16 – OTHER INFORMATION
Training instructions Personnel handling the product has to be acquainted demonstrably with its hazardous properties, with health and environmental protection principles related to the product and first aid principles. Tremcard details/Reference: Refer Section 14 Local bodies involved (Applicable only with in India): Local District Authority and Local Crisis Group Sources of data used to compile the (Material) Safety Data Sheet Data compilation reference: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search, http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630, . http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein, http://www.cdc.gov/niosh/npg/npgd0049.html, Data reference: Official Journal of the European Union regarding EU GHS (M)SDS Revision Status:
Date of Revision Revised Sections Supercedes Sep. 01, 2009 Format revised Feb. 01, 2008 Sep. 01, 2011 Section 4 (4.3) Sep. 01, 2009 Aug. 01, 2013 Section 2 NFPA Hazard statement Sep. 01, 2011 Jan.01,2016 Section 2,11,12,15 Aug. 01, 2013
This (M)SDS is issued by the Centre for HSE Excellence, Reliance Industries Limited.
(Material)Safety Data Sheet Issue Date: Jan. 01, 2016 AVIATION TURBINE FUEL/JET A-1 Supercedes: Aug. 01, 2013
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Contact Details: For any enquiry/comment regarding this (Material) Safety Data Sheet, kindly contact the Centre for HSE Excellence at [email protected] Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.
End of (M)SDS
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Section-1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
1.1. Identification of the substance/preparation: Commercial name: High Speed Diesel Chemical name: 1. Fuels, diesel 2. Distillates (petroleum), hydrodesulfurized middle
1.2 Use of the substance /preparation: Automotive gas oil, Industrial Fuel, Fuel for road diesel-powered engine. 1.3 MANUFACTURER & SUPPLIER: Reliance Industries Limited
Emergency Coordination Centre contact details: Jamnagar Mfg. Division
Village Meghpar / Padana, Taluka Lalpur, Dist. Jamnagar, Gujarat
SSM Office
+ 91 288 6612400
Mobile 9998007989
+ 91 288 6611190/1/6
SSM: Site Shift Manager
Section 2 – HAZARD IDENTIFICATION
2.1 Classification of the substance/preparation: Hazard class and category code.
GHS Category: Health Environmental Physical Carcinogenic category: 1B
Aquatic Toxicity – Category- NA
Flammable – Category NA
NA: Not available GHS Category table for reference: Study/hazard statement
Dose equivalent to oral or dermal LC50 of 2000-5000 mg/kg Maybe harmful if inhaled
Flammable liquids
Flash point < 23 degrees C and initial boiling point < 35 degrees C. Extremely flammable liquid and vapour
Flash point < 23 degrees C and initial boiling point > 35 degrees C. Highly flammable liquid and vapour
Flash point > 23 degrees C< 60 degrees C. Flammable liquid and vapour
Flash point > 60 degrees C < 93 degrees C. Combustible liquid
Not Applicable
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GHS Category table for reference: Continued Study/hazard statement
Category 1 Category 2 Category 3
Eye Irritation
Effects on the cornea, iris or conjunctiva that are not expected to reverse or that have not fully reversed within 21 days. Causes severe eye damage.
2A: Effects on the cornea, iris or conjunctiva that fully reverse within 21 days. Causes severe eye irritation. 2B : Effects on the cornea, iris or conjunctiva that fully reverse within 7 days. Causes eye irritation.
Not applicable
Skin Irritation
Destruction of skin tissue, with sub categorization based on exposure of up to 3 minutes (A), 1 hour (B), or 4 hours (C). Causes severe skin burns and eye damage.
Mean value of >2.3 > 4.0 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed); inflammation that persists to end of the (normally 14-day) observation period. Causes skin irritation.
Mean value of >1.5 < 2.3 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed). Causes mild skin irritation.
Environment: Acute Toxicity Category
96 hr LC50 (fish) <1 mg/L 48 hr EC50 (crustacea) < 1 mg/L, 72/96 hr ErC50 (aquatic plants) < 1 mg/L Very toxic to aquatic life
Extremely flammable aerosol Flammable aerosol Not Applicable
Flammable solids
Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time < 5 minutes Flammable solid
Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire for at least 4 minutes and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time > 5 < 10 minutes Flammable solid
Not Applicable
Flammable gases
Gases, which at 20 degrees C and a standard pressure of 101.3 kPA: (a) are ignitable when in a mixture of 13% or less by volume in air; or (b) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Extremely flammable gas
Gases, other than those of category 1, which, at 20 degrees C and a standard pressure of 101.3 kPA, have a flammable range while mixed in air. Flammable gas
Details of statements: Hazard Statements H350: May cause cancer
H304: May be fatal if swallowed and enters airways. H225: Highly flammable liquid and vapour. H340: May cause genetic defects H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement Prevention
P103 Read label before use. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking P260: Do not breathe /fume/gas/mist/vapours/spray. P 243: Take precautionary measures against static discharge. P281 Use personal protective equipment as required
Precautionary Statement Response
P308 IF exposed or concerned P313 Get medical advice/attention. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting.
Precautionary P405 Store locked up
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Statement Storage Precautionary
Statement Disposal Follow local regulation
2.2 Information pertaining to particular dangers for human: Ingestion Given the nature of gas oil and the fact that it is normally handled hot, its ingestion must be regarded as highly improbable. However, in the unlikely event of it happening, spontaneous vomiting would be expected to occur. There could also be irritation of the gastro-intestinal tract. Skin Because of the high handling temperatures, particularly with the heavy grades, a major hazard is the possibility of skin burns. However, this possibility, together with the unpleasant smell and colour of the fuel, provides a deterrent against direct skin contact. Nevertheless, where exposure arises and precautions and personal hygiene are poor, there is the possibility firstly of skin and eye irritation of a relatively mild nature, and secondly of dermatitis on more prolonged contact either directly on the skin or via fuel-soaked clothing. Prolonged or repeated skin contact, particularly under conditions of poor personal hygiene, may lead to effects ranging from dry skin with irritation to oil acne and oil folliculitis. Some individuals may be particularly susceptible to skin cracking and dermatitis. With exposure under such conditions, in rare cases serious disorders such as skin cancer could eventually occur. Eyes Eye contact from splashes or high mist levels is likely to cause irritation. Inhalation Mist and vapours will be evolved from gas oils at the elevated temperatures encountered in storage and use and these are likely to cause eye and respiratory irritation. However, such exposure is minimal under normal use conditions and significant exposure is most likely during maintenance operations, adequate personal protective equipment must be worn.
2.3 Information pertaining to particular dangers for the environment: NA.
2.4 Other adverse effects: Hydrogen sulphide may be evolved from gas oils under certain conditions such as elevated temperatures. It is highly toxic, causing effects which include eye irritation, nervousness, nausea, headache, insomnia and, in severe cases, unconsciousness and death. Hydrogen sulphide can also paralyse the olfactory system, making it inadvisable to rely on detecting its odour as a warning of its presence. Route of entry: Occupational exposure can occur through inhalation, dermal contact and ingestion.
Data reference: http://ecb.jrc.ec.europa.eu/esis/ Health hazards:
Carcinogenicity NTP listed? IARC cancer review group? OSHA Regulated?
Data yes yes yes
DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and
Health Administration (OSHA) carcinogen, National Toxicological program (NTP),
International Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgi-
Gas oils (petroleum), hydrodesulfurized; Gasoil /Yes
64742-79-6 265-182-8 0-100 %
Fuels, diesel, No 2; Gasoil /Yes 68476-34-6 270-676-1 0-100 %
Data reference: http://ecb.jrc.ec.europa.eu/esis/
Section 4 – FIRST AID MEASURES
4.1 General advice IMMEDIATE MEDICAL ATTENTION IS REQUIRED AFTER INHALATION OR AFTER SWALLOWING. In case of health troubles or doubts, seek medical advice immediately and show this (Material) Safety Data Sheet. Ensure activity of vitally important functions until the arrival of the doctor (artificial respiration, inhalation of oxygen, heart massage). If patient is unconscious, or in case of danger of blackout, transport patient in a stabilised position. In case of first degree burns (painful redness), and second degree burns (painful blisters), cool the affected area with cold running water for a long time. In case of third degree burns (redness, cracking pale skin, usually without pain), do not cool affected skin, dress the area with sterile dry gauze only. 4.2 Inhalation Remove to fresh air. If breathing but unconscious, place in the recovery position. If breathing has stopped, apply artificial respiration. If heartbeat absent give external cardiac compression. Monitor breathing and pulse. OBTAIN MEDICAL ATTENTION IMMEDIATELY.
4.3 Skin contact If high pressure injection injuries occur, obtain medical attention immediately. In the case of burns, wash skin thoroughly with water. Contaminated clothing must be removed as soon as possible. It must be laundered before reuse. If persistent irritation occurs, obtain medical attention. 4.4 Eye contact Flush eye with water. If persistent irritation occurs or if there is any suspicion of damage from hot product, obtain medical attention immediately. 4.5 Swallowing
Do not induce vomiting. Protect the airway if vomiting begins. Give nothing by mouth. If breathing but unconscious, place in the recovery position. If breathing has stopped, apply artificial respiration. DO NOT DELAY, OBTAIN MEDICAL ATTENTION IMMEDIATELY.
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Extinguish with Dry Powder, Foam or Water Fog. For small fires use CO2 5.2 Extinguishing media to be avoided Do not use water jets
5.3 Caution about specific danger in case of fire and fire-fighting
procedures Fires in closed or confined spaces should be tackled by trained personnel who should wear breathing apparatus. 5.4 Special protective equipment for fire-fighters Wear full protective fire-resistant clothing and self-contained breathing apparatus.
Section 6 –ACCIDENTAL RELEASE MEASURES
6.1 Person-related safety precautions Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard. May cause damage to surfaces making them SLIPPERY. 6.2 Precautions for protection of the environment Prevent from further leaks of substance. Do not allow substance to enter soil, water and sewage systems. In case of substance discharge to water courses or water containers, inform water consumers immediately, stop service and exploitation of water. 6.3 Recommended methods for cleaning and disposal When it is required to dispose of gas oil, for example, following a spillage or tank cleaning operations, this should be done through a recognised waste contractor. In marine applications, all waste gas oil should be collected and disposed of on land in accordance with local regulations.
Section 7 –HANDLING AND STORAGE
7.1 Information for safe handling In the event of a spillage, absorb or contain liquid with sand, earth or other spill control material. Prevent from entering drains, ditches or waterways. If this cannot be done, inform local authorities. 7.2 Information for storage Storage tanks in land based applications should be surrounded by oil tight bund walls to prevent escape of gas oil into the environment in the event of a major spillage or tank failure. Precautions should be taken to avoid skin burns from unprotected pipelines and equipment components. 7.3 Information for specific use: NA.
Section 8 –EXPOSURE CONTROL & PERSONAL PROTECTION
8.1 Occupational Exposure Limits: Material Source Type ppm mg/m3 Notation
High Speed Diesel
*Shell UK Limited, Landon
TWA NA 500
* Shell UK Limited, Landon
STEL NA 1000
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NA: Data not available, Shell UK Limited, Landon
Data reference: http://ecb.jrc.ec.europa.eu/esis/
8.2 Occupational exposure controls
Collective protection measures: General and local ventilation, effective exhaust. Individual protection measures: Personal protective equipment (PPE) for the protection of eyes, hands and skin corresponding with the performed labour has to be kept at disposition for the employees. In cases, where the workplace exposure control limits cannot be observed with the help of technical equipment or where it is not possible to ensure that the respiratory system exposure does not represent a health hazard for the personnel, adequate respiratory protection have to be kept at disposition. In the case of continuous use of this equipment during constant work, safety breaks have to be scheduled, if the PPE-character requires this. All PPE have to be kept in disposable state and the damaged or contaminated equipment has to be replaced immediately. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE): HANDS EYES BODY RESPIRATORY
Respiratory protection: Unlikely to be required in normal use but ensure good ventilation. Eye protection: Eye protection is recommended at all times Hand protection: Wear gloves of impervious material.
Body protection: Hand and skin protection recommended at all times. Where exposure is likely protective clothing must be worn, including nitrile gloves. Hygiene Measures: Wash hands, forearms and face thoroughly after handling. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
8.3 Environmental exposure controls Proceed in accordance with valid air and water legislative regulations. Engineering measures: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
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Section 9 –PHYSICAL AND CHEMICAL PROPERTIES Appearance Colourless, Liquid Odour Characteristic Solubility in water Negligible Relative Density (H2O=1) @ 15°C 0.82 - 0.87 Boiling Point °C 160–400°C Melting Point °C -12°C in winter & -3 °C in summer Relative Vapour Density (Air=1) NA Flash point °C > 66°C, Closed cup Auto ignition °C 220°C Vapour pressure (hPa) @ 40 °C 4 Molecular weight NA Explosive limits in air % by volume LEL 1.4 % UEL 7.6% PH NA Viscosity cSt @40 °C 1.5 – 5.7 Pour point NA Evaporation rate (ether=1) NA Octanol/water partition coefficient 3.9– 6 % volatile NA NA: NOT AVAILABLE
Data reference: http://ecb.jrc.ec.europa.eu/esis/
Section 10 –CHEMICAL STABILITY AND REACTIVITY INFORMATION
10.1 Conditions to avoid: Heat
10.2 Material to avoid: May react with strong oxidising materials.
10.3 Hazardous decomposition products With incomplete combustion smoke and hazardous fumes and gases, including carbon monoxide may be formed.
Section 11 –TOXICOLOGICAL INFORMATION
11.1 Acute effects When gas oils contain cracked components they are classified as carcinogens. With the use of good occupational and hygiene practices any risk will be minimal. Acute toxicity data:
Parameter Route Species Values Exposure period LD50 Oral Rat 7.5 g/kg Not applicable
Data Reference: Health Compendium of Chemical Hazards for Diesel
11.2 Repeated dose toxicity Chronic effects prolonged exposure may cause lung and skin cancer. 11.3 Sensitisation: May cause skin allergy. 11.4 CMR effects (carcinogenicity, mutagenicity, toxicity for reproduction): Substance is carcinogenic 11.5 Toxicokinetics, metabolism, distribution: NA.
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Section 12 –ECOLOGICAL INFORMATION
12.1 Ecotoxicity data:
Parameter Route Species Values Exposure period
Condition of bioassay
LC50 Inhalation
Jordenella floridae(fresh water fish)
54 mg/l 96 hours Not specified
Data Reference: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein
12.2 Mobility: Expected to have high mobility in soil.
12.3 Persistence and degradability: Substance is biodegradable.
12.4 Bio accumulative potential: Studies of the accidental and intentional release of fuel oils to the aquatic environment indicate that aquatic organisms are able to bio accumulate some hydrocarbon fractions, particularly PAHs (Farrington et al. 1982b); however, depuration does occur if the source of the contamination is removed (Cox et al. 1975; Williams et al. 1989). 12.5 Results of PBT assessment Persistence and Degradation: Photo-degrade in air. 12.6 Other adverse effects Expected to harm aquatic organisms, may cause long-term effects in the aquatic environment. May bioaccumulate; films formed on water may affect oxygen transfer and damage organisms. Likely to biodegrade slowly. Environmental Fate: Expected to have high mobility in soil.
Section 13– DISPOSAL CONSIDERATION Local Legislation: Disposal should be in accordance with applicable regional, national, and local laws and regulations. This product should not be dumped, spilled, rinsed or washed into sewers or public waterways.
13.1 Recommended disposal methods for the substance / preparation Product reuse or disposal in accordance with valid waste legislative regulations. 13.2 Recommended disposal methods for contaminated packaging Product is transported in tank-vehicles. 13.3 Waste management measures that control exposure of humans and environment Proceed in accordance with valid health, air and water legislative regulations. 13.4 Waste regulation Dispose by incineration or by methods approved by Local Authority. Do not discharge into the public drainage system, or marine and inland waterways.
Section 14– TRANSPORT INFORMATION International Transport Regulation:
Gas oil, Flammable liquid UN Number: 1202 Packing Group: III Packing Instructions: P001, IBC03, LP01 Portable Tanks: T2/TP1
(Material) Safety Data Sheet Issue Date: Mar. 01, 2016 GAS OIL
14.2 Special transport precautionary measures ADR/RID Hazard Class: 3
Section 15– REGULATORY INFORMATION (M)SDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989. The Factories Act 1948 International Regulations: European SDS Directive ANSI MSDS Standard ISO 11014-1 1994 WHMIS Requirements United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council *RISK PHRASES: R10: Flammable, R45: May cause cancer, R46: May cause heritable genetic damage, R65: Harmful: may cause lung damage if swallowed, R51/53: Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment *SAFETY PHRASES: S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible), S53: Avoid exposure - obtain special instructions before use, S61: Avoid release to the environment. refer to special instructions/ safety data sheets, S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. *These standard risk and safety phrases for use when interpreting (Material) Safety data Sheets are derived from the European Union Regulation, CHIP Regulations – Chemicals (Hazard Information and Packaging for Supply). They are required to be used in (Materials) Safety Data Sheets to identify potential hazards and offer safe handling advice.
Section 16 – OTHER INFORMATION
Training instructions
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Personnel handling the product has to be acquainted demonstrably with its hazardous properties, with health and environmental protection principles related to the product and first aid principles. Tremcard details/Reference: Refer Section 14 Local bodies involved (Applicable only with in India): Local District Authority and Local Crisis Group Sources of data used to compile the (Material) Safety Data Sheet Data compilation reference: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search, http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630, . http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein, http://www.cdc.gov/niosh/npg/npgd0049.html, Official Journal of the European Union regarding EU GHS (M)SDS Revision Status:
Date of Revision Revised Sections Supercedes Sep. 01, 2009 Format revised Feb. 01, 2008 Sep. 01, 2011 Section 4 (4.3) Sep. 01, 2009 Aug. 01, 2013 Section 1.3 Sep. 01, 2011 Mar.01,2016 Section 11,12,14 Aug. 01, 2013
This (M)SDS is issued by the Centre for HSE Excellence, Reliance Industries Limited Contact Details: For any enquiry/comment regarding this (Material )Safety Data Sheet, kindly contact the Centre for HSE Excellence at [email protected] Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.
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Section-1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE
AND OF THE COMPANY/UNDERTAKING
1.1 Identification of the substance/mixture:
Commercial name: Gasoline Chemical name: 1. Motor spirit 2. Petrol
Synonyms:
1. Motor spirit 2. Petrol
1.2 Use of the substance /mixture: Automotive gasoline (unleaded), Fuel, Fuel for road petrol-powered engine. As fuel in internal combustion engines of the spark-ignited & reciprocating.
Flash point < 23 degrees C and initial boiling point < 35 degrees C. Extremely flammable liquid and vapour
Flash point < 23 degrees C and initial boiling point > 35 degrees C. Highly flammable liquid and vapour
Flash point > 23 degrees C< 60 degrees C. Flammable liquid and vapour
Flash point > 60 degrees C < 93 degrees C. Combustible liquid
Not Applicable
Note: Gases concentration are expressed in parts per million per volume (ppmV). NOTE 1: Category 5 is for mixtures which are of relatively low acute toxicity but which under certain circumstances may pose a hazard to vulnerable populations. These mixtures are anticipated to have an oral or dermal LD50 value in the range of 2000-5000 mg/kg bodyweight or equivalent dose for other routes of exposure. In light of animal welfare considerations,
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testing in animals in Category 5 ranges is discouraged and should only be considered when there is a strong likelihood that results of such testing would have a direct relevance for protecting human health. NOTE 2: These values are designed to be used in the calculation of the ATE for classification of a mixture based on its ingredients and do not represent test results. The values are conservatively set at the lower end of the range of Categories 1 and 2, and at a point approximately 1/10th from the lower end of the range for Categories 3 – 5.
GHS Category table for reference: Continued Study/hazard statement
Category 1 Category 2 Category 3
Eye Irritation
Effects on the cornea, iris or conjunctiva that are not expected to reverse or that have not fully reversed within 21 days. Causes severe eye damage.
2A: Effects on the cornea, iris or conjunctiva that fully reverse within 21 days. Causes severe eye irritation. 2B : Effects on the cornea, iris or conjunctiva that fully reverse within 7 days. Causes eye irritation.
Not applicable
Skin Irritation
Destruction of skin tissue, with sub categorization based on exposure of up to 3 minutes (A), 1 hour (B), or 4 hours (C). Causes severe skin burns and eye damage.
Mean value of >2.3 > 4.0 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed); inflammation that persists to end of the (normally 14-day) observation period. Causes skin irritation.
Mean value of >1.5 < 2.3 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed). Causes mild skin irritation.
Environment: Acute Toxicity Category
96 hr LC50 (fish) <1 mg/L 48 hr EC50 (crustacea) < 1 mg/L, 72/96 hr ErC50 (aquatic plants) < 1 mg/L Very toxic to aquatic life
Extremely flammable aerosol Flammable aerosol Not Applicable
Flammable solids
Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time < 5 minutes Flammable solid
Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire for at least 4 minutes and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time > 5 < 10 minutes Flammable solid
Not Applicable
Flammable gases
Gases, which at 20 degrees C and a standard pressure of 101.3 kPA: (a) are ignitable when in a mixture of 13% or less by volume in air; or (b) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Extremely flammable gas
Gases, other than those of category 1, which, at 20 degrees C and a standard pressure of 101.3 kPA, have a flammable range while mixed in air. Flammable gas
Statements H350: May cause cancer H304: May be fatal if swallowed and enters airways.
H225: Highly flammable liquid and vapour. H340: May cause genetic defects H372: Causes damage to organs H319: Causes serious eye irritation. H315: Causes skin irritation.
Precautionary Statement Prevention
P 102: Keep out of reach of children. P 103: Read label before use. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and
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understood. P210: Keep away from heat/sparks/open flames/hot surfaces* No smoking. P 233: Keep container tightly closed. P 240: Ground/bond container and receiving equipment. P 241: Use explosion-proof electrical/ventilating/lighting/ equipment. P 242: Use only non-sparking tools. P 243: Take precautionary measures against static discharge. P 260: Do not breathe dust/fume/gas/mist/vapours/spray*. P 264: Wash thoroughly after handling. P 270: Do not eat, drink or smoke when using this product. P 280: Wear protective gloves/protective clothing/eye protection/face protection*. P281: Use personal protective equipment as required.
Precautionary Statement Response
P 101: If medical advice is needed, have product container or label at hand. P 301: IF SWALLOWED: P 302: IF ON SKIN: P 303: IF ON SKIN (or hair): P 305: IF IN EYES: P308: IF ON CLOTHING: P 310: Immediately call a POISON CENTER or doctor/physician. P313: Get medical advice/attention. P 314: Get medical advice/attention if you feel unwell. P 321: Specific treatment (see on this label).* P 331: Do NOT induce vomiting. P 332: If skin irritation occurs: P 337: If eye irritation persists: P 338: Remove contact lenses, if present and easy to do. Continue rinsing. P 351: Rinse cautiously with water for several minutes. P 352: Wash with plenty of soap and water. P 353: Rinse skin with water/shower. P 361: Remove/Take off immediately all contaminated clothing. P 362: Take off contaminated clothing and wash before re-use. P 370: In case of fire: P 378: Use for extinction. H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement
Storage
P235 Keep cool. P403: Store in a well-ventilated place. P405: Store locked up.
Precautionary Statement Disposal
Follow local regulation
Hazard ratings:
NFPA HAZARD CODES RATINGS SYSTEM
HEALTH: 2 0 = No Hazard
FLAMMABILITY: 3 1 = Slight Hazard
INSTABILITY: 0 2 = Moderate Hazard
3 = Serious Hazard
4 = Severe Hazard
Data Reference: http://ecb.jrc.ec.europa.eu/esis/index
2.2 Information pertaining to particular dangers for human: Ingestion The swallowing of small amounts is unlikely to have adverse effects; larger amounts may cause irritation with diarrhoea and vomiting. Skin
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Unlikely to cause irritation on single contact. Prolonged or repeated contact may cause dermatitis which could eventually lead to irreversible skin disorders. Injection of fuel under pressure through the skin may have serious effects which at first may not seem serious but, within hours, may become very painful. Eyes May cause irritation with short-term redness and stinging. Inhalation Fumes or vapour may cause irritation to eyes and mucous membranes, and drowsiness leading to loss of consciousness. 2.3 Information pertaining to particular dangers for the environment: Classified as dangerous for the environment. 2.4 Other adverse effects: Exposure to gases generated due to the burning of this product in an area without adequate ventilation may result in unconsciousness and suffocation. Injection of fuel under the skin may have serious medical effects. Route of entry: Occupational exposure can occur through inhalation, dermal contact and ingestion.
DATA REFERENCE: http://toxnet.nlm.nih.gov/cgibin/sis/search.
Health hazards: Due to Benzene content
Source NTP listed? IARC cancer
review group?
OSHA Regulated?
Carcinogenicity Chemical is
known to be
carcinogenic
Carcinogenic to
humans
Chemical appears at 29
CFR part 1910 subpartZ.
DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and Health Administration (OSHA) carcinogen, National Toxicological program (NTP), International Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgi-bin/sis/search.
Section 3 – COMPOSITION & INFORMATION ON INGREDIENTS
Ingredients / Hazardous CAS No. EC No. Percentage
Gasoline 86290-81-5 289-220-8 98.5% min.
Benzene 71-43-2 200-753-7 1.5% max.
A complex blend of petrolem derived normal and branched chain alkanes,
cycloalkanes, alkenes and aromatic hydrocarbons may contain antioxidant and
multifunction additives. Oxygeneted gasoline will have required ammount of
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4.1 General advice IMMEDIATE MEDICAL ATTENTION IS REQUIRED AFTER INHALATION OR AFTER SWALLOWING. In case of health troubles or doubts, seek medical advice immediately and show this (Material) Safety Data Sheet. Ensure activity of vitally important functions until the arrival of the doctor (artificial respiration, inhalation of oxygen, heart massage). If patient is unconscious, or in case of danger of blackout, transport patient in a stabilized position. In case of first degree burns (painful redness), and second degree burns (painful blisters), cool the affected area with cold running water for a long time. In case of third degree burns (redness, cracking pale skin, usually without pain), do not cool affected skin, dress the area with sterile dry gauze only. 4.2 Inhalation If inhalation of vapour causes irritation or drowsiness remove to fresh air. Get Medical advice if the symptoms continue.
4.3 Skin contact
Wash skin as soon as possible with water. Change contaminated clothing and launder before reuse. Get medical advice if irritation persists. Any injection of fuel under the skin should be considered an EMERGENCY - get Medical Advice URGENTLY. 4.4 Eye contact Wash out thoroughly with large amounts of water. If redness and/or irritation continues get medical advice. 4.5 Swallowing Wash mouth out with water and give water to drink. If a large amount has been swallowed get medical advice. DO NOT INDUCE VOMITING BECAUSE OF THE DANGER OF ASPIRATION.
Section 5 – FIRE FIGHTING MEASURES
5.1 Suitable extinguishing media
Extinguish with Dry Powder, Foam or Water Fog. For small fires use CO2
5.2 Extinguishing media to be avoided: Do not use water jets
5.3 Caution about specific danger in case of fire and fire-fighting
procedures: Fires in closed or confined spaces should be tackled by trained
personnel who should wear breathing apparatus. 5.4 Special protective equipment for fire-fighters: Wear full protective fire-resistant clothing and self-contained breathing apparatus.
Section 6 –ACCIDENTAL RELEASE MEASURES
6.1 Person-related safety precautions Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard. May cause damage to surfaces making them SLIPPERY. 6.2 Precautions for protection of the environment Prevent from further leaks of substance. Do not allow substance to enter soil, water and sewage systems. In case of substance discharge to water courses or water containers, inform water consumers immediately, stop service and exploitation of water. 6.3 Recommended methods for cleaning and disposal
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Contain spillage - do not wash spillage down drain. Absorb using absorbent clay, diatomaceous clay or other suitable absorbent.
Section 7 –HANDLING AND STORAGE
7.1 Information for safe handling Product is designed to be used in closed systems. Electrostatic generation takes place while during product transfer and flow. Take precautionary measures against static discharges. Avoid skin contact when working on fuel system components. Where exposure is likely PROTECTIVE CLOTHING should be worn including impervious GLOVES and EYE PROTECTION. Ensure good ventilation. 7.2 Information for storage Drums should be stored on their sides on racks preferably under cover, out of direct sunlight, in well ventilated conditions. Other types of containers should be stored under cover out of direct sunlight, in well ventilated conditions. Care should be taken to avoid over-stacking. 7.3 Information for specific use: NA.
Section 8 –EXPOSURE CONTROL & PERSONAL PROTECTION
8.1 Occupational Exposure Limits: NA NA: Data not available Provide adequate ventilation when using the material and follow the principles of good occupational hygiene to control personal exposure. Recommended determination method in the work place atmosphere: gas chromatography, detector tube.
8.2 Occupational exposure controls
Collective protection measures: General and local ventilation, effective exhaust. Individual protection measures: Personal protective equipment (PPE) for the protection of eyes, hands and skin corresponding with the performed labour has to be kept at disposition for the employees. In the case of continuous use of this equipment during constant work, safety breaks have to be scheduled, if the PPE-character requires this. All PPE have to be kept in disposable state and the damaged or contaminated equipment has to be replaced immediately. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):
HANDS EYES BODY RESPIRATORY
Respiratory protection: Unlikely to be required in normal use but ensure good ventilation. Eye protection: Eye protection is recommended at all times
Hand protection: Wear gloves of impervious material.
Body protection: Hand and skin protection recommended at all times. Hygiene Measures: Wash hands, forearms and face thoroughly after handling. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
8.3 Environmental exposure controls
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Proceed in accordance with valid air and water legislative regulations. Engineering measures: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Section 9 –PHYSICAL AND CHEMICAL PROPERTIES
Appearance Liquid, colourless Odour Typical gasoline odour Solubility in water Negligible Relative Density (H2O=1) @ 15°C 0.68 - 0.79 Boiling Point °C 20 - 200°C Melting Point °C -90.5°C to -95.4°C Relative Vapour Density (Air=1) 3.5 Flash point °C -30°C min. Closed cup Auto ignition °C 280 °C Vapour pressure (kPa) @ 37.8 °C <107 Molecular weight NA Explosive limits in air % by volume LEL 1.4 % UEL 7.6% PH NA Viscosity cst @40 °C <1 Pour point NA Evaporation rate (ether=1) NA Octanol/water partition coefficient 2.1 - 6 % volatile NA NA: NOT AVAILABLE DATA REFERENCE http://toxnet.nlm.nih.gov/cgi-bin/sis/search
Section 10 –CHEMICAL STABILITY AND REACTIVITY INFORMATION
10.1 Conditions to avoid: Heat 10.2 Material to avoid: May react with strong oxidizing materials. 10.3 Hazardous decomposition products: With incomplete combustion smoke and hazardous fumes and gases, including carbon monoxide may be formed.
Section 11 –TOXICOLOGICAL INFORMATION
11.1 Acute effects Over exposure (orally, dermally or by inhalation) to product is harmful. With the use of good occupational and hygiene practices any risk will be minimal. Acute toxicity data: For Gasoline
Parameter Route Species Values Exposure period LD50 Oral Rat 18.75 mL/kg Not applicable
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LD50 Dermal Rabbit >5 mL/kg Not applicable For Benzene Parameter Route Species Values Exposure period
LD50 Oral Rat 3306 mg/Kg Not applicable LD50 Dermal Rabbit >8260 mg/kg Not applicable
LC50 Inhalation Rat 10000 ppm 7 hours
Data Reference: http://toxnet.nlm.nih.gov/cgibin/sis/search. 11.2 Repeated dose toxicity Chronic effects prolonged exposure may cause lung and skin cancer. 11.3 Sensitisation May cause skin allergy. 11.4 CMR effects (carcinogenicity, mutagenicity, toxicity for reproduction) Substance is carcinogenic, mutagenic, and reproductive toxin. 11.5 Toxicokinetics, metabolism, distribution Not applicable.
Section 12 –ECOLOGICAL INFORMATION
12.1 Eco toxicity data: For Gasoline
Parameter Route Species Values Exposure period
Condition of bioassay
LC50 Inhalation
Oncorhynchus my kiss
(Rainbow trout)
16 mg/L 96 hours static
EC50 Inhalation Daphnia
magna (water flea)
12 mg/L 48 Hours static
For Benzene Parameter Route Species Values Exposure
period Condition of bioassay
LC50 Inhalation
Palaemonetes pugio (grass
shrimp)
27 ppm 96 hours Not specified
LC50 Inhalation Carassius auratus
(goldfish)
46 mg/l 24 hours Not specified
LC50 Inhalation Crangon franciscorum
(shrimp);
20 ppm 96 hours Not specified
Data Reference: http://toxnet.nlm.nih.gov/cgi-bin/sis/search
12.2 Mobility: Expected to have high mobility in soil.
12.3 Persistence and degradability:
Hydrolysis: Substance is not expected to be an important environmental fate process since gasoline does not contain any constituents with hydrolyzable functional groups
Substance is biodegradable.
12.4 Bio accumulative potential: The bio concentration potential of the major components
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12.5 Results of PBT assessment Persistence and Degradation: Not considered to be a
PBT or v PvB.
12.6 Other adverse effects: NA Environmental Fate: Expected to have high mobility in soil.
Section 13– DISPOSAL CONSIDERATION
Local Legislation: Disposal should be in accordance with applicable regional, national, and local laws and regulations. This product should not be dumped, spilled, rinsed or washed into sewers or public waterways.
13.1 Recommended disposal methods for the substance / mixture
Product reuse or disposal in accordance with valid waste legislative regulations.
13.2 Recommended disposal methods for contaminated packaging
Product is transported in tank-vehicles. 13.3 Waste management measures that control exposure of humans and environment
Proceed in accordance with valid health, air and water legislative regulations. 13.4 Waste regulation
Dispose by incineration or by methods approved by Local Authority. Do not discharge into the public drainage system, or marine and inland waterways.
Section 14– TRANSPORT INFORMATION
International Transport Regulation:
14.2 Special transport precautionary measures Shipping name: Gasoline, Flammable liquid UN Number 1203 Packing Group: II Packaging Instruction: P001/IBC002 Portable Tank: T4/TP1 IMO Hazard Class: 3 IATA Hazard Class 3 Emergency Action Code: 3YE
14.2 Special transport precautionary measures ADR/RID Hazard Class: 3
Section 15– REGULATORY INFORMATION
(M)SDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989. The Factories Act 1948 International Regulations: European SDS Directive ANSI MSDS Standard ISO 11014-1 1994 WHMIS Requirements
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United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council *RISK PHRASES: R10: Flammable Toxic, R45: may cause cancer, R46: May cause heritable genetic damage, R51/53: Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment, R61: May cause harm to the unborn child, R65: Harmful: may cause lung damage if swallowed.
*SAFETY PHRASES: S45: In case of accident or if you feel unwell, seek medical advice immediately, S53: Avoid exposure - obtain special instructions before use, S61: Avoid release to the environment, refer to special instructions/ safety data sheets, S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
*These standard risk and safety phrases for use when interpreting (Material) Safety data Sheets are derived from the European Union Regulation, CHIP Regulations - Chemicals (Hazard Information and Packaging for Supply). They are required to be used in (Materials) Safety Data Sheets to identify potential hazards and offer safe handling advice.
Section 16 – OTHER INFORMATION
Training instructions Personnel handling the product has to be acquainted demonstrably with its hazardous properties, with health and environmental protection principles related to the product and first aid principles. Trem card details/Reference: Refer Section 14 Local bodies involved (Applicable only with in India): Local District Authority and Local Crisis Group Sources of data used to compile the (Material) Safety Data Sheet Data compilation reference: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search, http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630 . http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein, http://www.cdc.gov/niosh/npg/npgd0049.html (M)SDS Revision Status:
Date of Revision Revised Sections Supercedes Sep. 01, 2009 Format revised Feb. 01, 2008 Sep. 01, 2011 Section 4 (4.3) Sep. 01, 2009 Aug. 01, 2013 Section 2 NFPA Hazard statement Sep. 01, 2011
(Material) Safety Data Sheet Issue Date: Feb. 01, 2016 GASOLINE Supercedes: Aug. 01, 2013
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Feb.01,2016 Section 11,12,14 Aug. 01, 2013 This (M)SDS is issued by the Centre for HSE Excellence, Reliance Industries Limited Contact Details: For any enquiry/comment regarding this (Material) Safety Data Sheet, kindly contact the Centre for HSE Excellence at [email protected] Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.
NA: Not available Data reference: http://ecb.jrc.ec.europa.eu/esis/, Data reference: Official Journal of the European Union regarding EU GHS GHS Category table for reference:
Flash point < 23 degrees C and initial boiling point < 35 degrees C. Extremely flammable liquid and vapour
Flash point < 23 degrees C and initial boiling point > 35 degrees C. Highly flammable liquid and vapour
Flash point > 23 degrees C< 60 degrees C. Flammable liquid and vapour
Flash point > 60 degrees C < 93 degrees C. Combustible liquid
Not Applicable
Note: Gases concentration are expressed in parts per million per volume (ppmV). NOTE 1: Category 5 is for mixtures which are of relatively low acute toxicity but which under certain circumstances may pose a hazard to vulnerable populations. These mixtures are anticipated to have an oral or dermal LD50 value in the range of 2000-5000 mg/kg bodyweight or equivalent dose for other routes of exposure. In light of animal welfare considerations, testing in animals in Category 5 ranges is discouraged and should only be considered when there is a strong likelihood that results of such testing would have a direct relevance for protecting human health. NOTE 2: These values are designed to be used in the calculation of the ATE for classification of a mixture based on its ingredients and do not represent test results. The values are conservatively set at the lower end of the range of Categories 1
(Material) Safety Data Sheet Issue Date: Jan. 01, 2017 NAPHTHA Supercedes: Aug. 01, 2013
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and 2, and at a point approximately 1/10th from the lower end of the range for Categories 3 – 5.
GHS Category table for reference: Continued Study/hazard statement
Category 1 Category 2 Category 3
Eye Irritation
Effects on the cornea, iris or conjunctiva that are not expected to reverse or that have not fully reversed within 21 days. Causes severe eye damage.
2A: Effects on the cornea, iris or conjunctiva that fully reverse within 21 days. Causes severe eye irritation. 2B : Effects on the cornea, iris or conjunctiva that fully reverse within 7 days. Causes eye irritation.
Not applicable
Skin Irritation
Destruction of skin tissue, with sub categorization based on exposure of up to 3 minutes (A), 1 hour (B), or 4 hours (C). Causes severe skin burns and eye damage.
Mean value of >2.3 > 4.0 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed); inflammation that persists to end of the (normally 14-day) observation period. Causes skin irritation.
Mean value of >1.5 < 2.3 for erythema / eschar or edema in at least 2 of 3 tested animals from gradings at 24, 48, and 72 hours (or on 3 consecutive days after onset if reactions are delayed). Causes mild skin irritation.
Environment: Acute Toxicity Category
96 hr LC50 (fish) <1 mg/L 48 hr EC50 (crustacea) < 1 mg/L, 72/96 hr ErC50 (aquatic plants) < 1 mg/L Very toxic to aquatic life
Extremely flammable aerosol Flammable aerosol Not Applicable
Flammable solids
Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time < 5 minutes Flammable solid
Using the burning rate test, substances or mixtures other than metal powders: (a) wetted zone does not stop fire for at least 4 minutes and (b) burning time < 45 seconds or burning rate > 2.2 mm/second Using the burning rate test, metal powders that have burning time > 5 < 10 minutes Flammable solid
Not Applicable
Flammable gases
Gases, which at 20 degrees C and a standard pressure of 101.3 kPA: (a) are ignitable when in a mixture of 13% or less by volume in air; or (b) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Extremely flammable gas
Gases, other than those of category 1, which, at 20 degrees C and a standard pressure of 101.3 kPA, have a flammable range while mixed in air. Flammable gas
Not Applicable
GHS Label: GHS02: Flammables; GHS08: Carcinogen.
Signal Word: Danger. Details of statements:
Hazard Statements
H224: Extremely flammable liquid and vapour. H350: May cause cancer H304: May be fatal if swallowed and enters airways.
Precautionary Statement Prevention
P102: Keep out of reach of children. P 103: Read label before use. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge.
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P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required.
Precautionary Statement Response
P101: If medical advice is needed, have product container or label at hand. P308: IF ON CLOTHING: P313: Get medical advice/attention. P301 IF SWALLOWED: P310 Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting. P303 +P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 + P378: In case of fire: Use Dry chemical Powder, Foam or Water Fog for extinction.
Precautionary Statement
Storage
P405: Store locked up. P403 + P235: Store in a well-ventilated place. Keep cool.
Precautionary Statement Disposal
Follow local regulation
Data reference: Official Journal of the European Union regarding EU GHS
2.2 Information pertaining to particular dangers for human: Ingestion The swallowing of small amounts is unlikely to have adverse effects; larger amounts may cause irritation with diarrhea and vomiting. Skin Unlikely to cause irritation on single contact. Prolonged or repeated contact may cause dermatitis which could eventually lead to irreversible skin disorders. Eyes May cause irritation with short-term redness and stinging. Inhalation Fumes or vapour may cause irritation to eyes and mucous membranes, and drowsiness leading to loss of consciousness.
2.3 Information pertaining to particular dangers for the environment: NA.
2.4 Other adverse effects: NA. Route of entry: Occupational exposure can occur through inhalation, dermal contact and ingestion.
Data reference: http://ecb.jrc.ec.europa.eu/esis/
2.1 Health hazards:
Source NTP listed? IARC cancer review
group?
OSHA
Regulated?
Carcinogenicity Yes Yes Yes
DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and Health
Administration (OSHA) carcinogen, National Toxicological program (NTP), International
Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgi-bin/sis/search.
4.1 General advice IMMEDIATE MEDICAL ATTENTION IS REQUIRED AFTER INHALATION, EXPOSURE OR AFTER SWALLOWING. In case of health troubles or doubts, seek medical advice immediately and show this (Material) Safety Data Sheet. Ensure activity of vitally important functions until the arrival of the doctor (artificial respiration, inhalation of oxygen, heart massage). If patient is unconscious, or in case of danger of blackout, transport patient in a stabilized position. In case of first degree burns (painful redness), and second degree burns (painful blisters), cool the affected area with cold running water for a long time. In case of third degree burns (redness, cracking pale skin, usually without pain), do not cool affected skin, dress the area with sterile dry gauze only. 4.2 Inhalation If inhalation of vapour causes irritation or drowsiness remove to fresh air. Get Medical advice if the symptoms continue.
4.3 Skin contact Wash skin as soon as possible with water. Change contaminated clothing and launder before reuse. Get medical advice if irritation persists. Any injection of fuel under the skin should be considered an EMERGENCY - get Medical Advice URGENTLY. 4.4 Eye contact Wash out thoroughly with large amounts of water. If redness and/or irritation continues get medical advice. 4.5 Swallowing Wash mouth with water and give water to drink. If a large amount has been swallowed get medical advice. DO NOT INDUCE VOMITING BECAUSE OF THE DANGER OF ASPIRATION.
Section 5 – FIRE FIGHTING MEASURES
5.1 Suitable extinguishing media Extinguish with Dry chemical Powder, Foam or Water Fog. For small fires use CO2 5.2 Extinguishing media to be avoided Do not use water jets
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5.3 Caution about specific danger in case of fire and fire-fighting
procedures Fires in closed or confined spaces should be tackled by trained personnel who should wear breathing apparatus. 5.4 Special protective equipment for fire-fighters Wear full protective fire-resistant clothing and self-contained breathing apparatus.
Section 6 –ACCIDENTAL RELEASE MEASURES
6.1 Person-related safety precautions Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard. May cause damage to surfaces making them SLIPPERY. 6.2 Precautions for protection of the environment Prevent from further leaks of substance. Do not allow substance to enter soil, water and sewage systems. In case of substance discharge to water courses or water containers, inform water consumers immediately, stop service and exploitation of water. 6.3 Recommended methods for cleaning and disposal Contain spillage - do not wash spillage down drain. Absorb using absorbent clay or other suitable absorbent.
Section 7 –HANDLING AND STORAGE
7.1 Information for safe handling Avoid skin contact when working on fuel system components. Where exposure is likely PROTECTIVE CLOTHING should be worn including impervious GLOVES and EYE PROTECTION. Ensure good ventilation. 7.2 Information for storage Drums should be stored on their sides on racks preferably under cover, out of direct sunlight, in well ventilated conditions. Other types of containers should be stored under cover out of direct sunlight, in well ventilated conditions. Care should be taken to avoid over-stacking. 7.3 Information for specific use: Nil.
Section 8 –EXPOSURE CONTROL & PERSONAL PROTECTION
8.1 Occupational Exposure Limits: Material Source Type ppm mg/m3 Notation
Naphtha US TWA NA 1370
US STEL NA NA NA: Data not available, US: REPSOL PETROLEO
Data reference: http://ecb.jrc.ec.europa.eu/esis/
8.2 Occupational exposure controls
Collective protection measures: General and local ventilation, effective exhaust. Individual protection measures: Personal protective equipment (PPE) for the protection of eyes, hands and skin corresponding with the performed labour has to be kept at disposition for the employees. In cases, where the workplace
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exposure control limits cannot be observed with the help of technical equipment or where it is not possible to ensure that the respiratory system exposure does not represent a health hazard for the personnel, adequate respiratory protection have to be kept at disposition. In the case of continuous use of this equipment during constant work, safety breaks have to be scheduled, if the PPE-character requires this. All PPE have to be kept in disposable state and the damaged or contaminated equipment has to be replaced immediately. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):
HANDS EYES BODY RESPIRATORY
Respiratory protection: Unlikely to be required in normal use but ensure good ventilation. Eye protection: Eye protection is recommended at all times Hand protection: Wear gloves of impervious material.
Body protection: Hand and skin protection recommended at all times. Where exposure is likely protective clothing must be worn, including nitrile gloves approved. Hygiene Measures: Wash hands, forearms and face thoroughly after handling. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
8.3 Environmental exposure controls Proceed in accordance with valid air and water legislative regulations. Engineering measures: Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Section 9 –PHYSICAL AND CHEMICAL PROPERTIES
Appearance Liquid, colourless or brown Odour Characteristic Solubility in water Negligible Relative Density (H2O=1) @ 15°C 0.74 - 0.87 Boiling Point °C 27 - 233°C Melting Point °C <-50 Deg C Relative Vapour Density (Air=1) NA Flash point °C 20 Auto ignition °C 232 Vapour pressure (hpa) @ 37.8 °C 6.9-760 Molecular weight NA Explosive limits in air % by volume LEL 1%,UEL 6% PH NA Viscosity cSt @40 °C NA Pour point NA Evaporation rate (ether=1) NA Octanol/water partition coefficient 2.1-6
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% volatile NA NA: NOT AVAILABLE
Data reference: http://ecb.jrc.ec.europa.eu/esis/
Section 10 –CHEMICAL STABILITY AND REACTIVITY INFORMATION
10.1 Conditions to avoid: Heat
10.2 Material to avoid: May react with strong oxidizing materials. 10.3 Hazardous decomposition products With incomplete combustion smoke and hazardous fumes and gases, including carbon monoxide may be formed.
Section 11 –TOXICOLOGICAL INFORMATION
11.1 Acute effects Acute toxicity data:
Parameter Route Species Values Exposure period LD50 Oral Rat > 5000 mg/kg Not applicable
Data Reference: : http://ecb.jrc.ec.europa.eu/esis/ 11.2 Repeated dose toxicity Chronic effects prolonged exposure may cause lung and skin cancer. 11.3 Sensitisation: May cause skin allergy. 11.4 CMR effects (carcinogenicity, mutagenicity, toxicity for reproduction) Substance is carcinogen 11.5 Toxicokinetics, metabolism, distribution: NA.
Section 12 –ECOLOGICAL INFORMATION
12.1 Eco toxicity data:
Parameter Route Species Values Exposure period
Condition of bioassay
LC50 Inhalation
Crangon crangon
4.3 mg/L 96 hours Not specified
Data reference: http://ecb.jrc.ec.europa.eu/esis/
12.2 Mobility: High mobility in soil
12.3 Persistence and degradability: Substance is biodegradable. 12.4 Bio accumulative potential: NA. 12.5 Results of PBT assessment Persistence and Degradation: Photo-degrade in air. 12.6 Other adverse effects Expected to harm aquatic organisms, films formed on water may affect oxygen transfer and damage organisms. Likely to biodegrade slowly. Environmental Fate: Expected to have high mobility in soil. Is expected to biodegrade in soils.
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Local Legislation: Disposal should be in accordance with applicable regional, national, and local laws and regulations. This product should not be dumped, spilled, rinsed or washed into sewers or public waterways.
13.1 Recommended disposal methods for the substance / mixture Product reuse or disposal in accordance with valid waste legislative regulations. 13.2 Recommended disposal methods for contaminated packaging Product is transported in tank-vehicles. 13.3 Waste management measures that control exposure of humans and environment Proceed in accordance with valid health, air and water legislative regulations. 13.4 Waste regulation Dispose by incineration or by methods approved by Local Authority. Do not discharge into the public drainage system, or marine and inland waterways.
Section 14– TRANSPORT INFORMATION
14.1 International Transport Regulation: Shipping name: PETROLEUM DISTILLATES, N.O.S. UN Number: 1268 Packaging Group: I Packaging Instruction: P001 Portable Containers: T11 (Special Instruction: TP1, TP8) IATA class: 3 IMDG: 3 Emergency Action Code: 3YE
14.2 Special transport precautionary measures ADR Classification Code: F1
Section 15– REGULATORY INFORMATION
(M)SDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989. The Factories Act 1948 International Regulations: European SDS Directive ANSI MSDS Standard ISO 11014-1 1994 WHMIS Requirements United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council
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*RISK PHRASES: R12 Extremely flammable R45 may cause cancer, R65 Harmful: may cause lung damage if swallowed.
*SAFETY PHRASES: S2: Keep out of reach of children, S9: Keep container in a well-ventilated place, S16: Keep away from sources of ignition - No Smoking! , S33: Take precautionary measures against static discharges, S45 In case of accident or if you feel unwell, seek medical advice immediately, S53 Avoid exposure – obtain special instruction before use. May cause cancer, flammable, Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
*These standard risk and safety phrases for use when interpreting (Material) Safety data Sheets are derived from the European Union Regulation, CHIP Regulations - Chemicals (Hazard Information and Packaging for Supply). They are required to be used in (Material) Safety Data Sheets to identify potential hazards and offer safe handling advice.
Section 16 – OTHER INFORMATION
Training instructions Personnel handling the product has to be acquainted demonstrably with its hazardous properties, with health and environmental protection principles related to the product and first aid principles. Tremcard details/Reference: Refer Section 14 Local bodies involved (Applicable only with in India): Local District Authority and Local Crisis Group Sources of data used to compile the (Material) Safety Data Sheet Data compilation reference: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search, http://webnet3.oecd.org/eChemPortal/Results2.aspx?SubstanceId=169630, . http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein, http://www.cdc.gov/niosh/npg/npgd0049.html (M)SDS Revision Status:
Date of Revision Revised Sections Supercedes Sep. 01, 2009 Format revised Feb. 01, 2008 Sep. 01, 2011 Section 4 (4.3) Sep. 01, 2009 Aug. 01, 2013 Section 1.3 Sep. 01, 2011 Jan.01,2017 Section 2.1,9,14,15 Aug. 01, 2013
This (M)SDS is issued by the Centre for HSE Excellence, Reliance Industries Limited Contact Details: For any enquiry/comment regarding this (Material) Safety Data Sheet, kindly contact the Centre for HSE Excellence at [email protected]
(Material) Safety Data Sheet Issue Date: Jan. 01, 2017 NAPHTHA Supercedes: Aug. 01, 2013
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Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.
End of (M)SDS
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Material Safety Data SheetKerosene MSDS
Section 1: Chemical Product and Company Identification
Product Name: Kerosene
Catalog Codes: SLK1048
CAS#: 8008-20-6 or 64742-81-0
RTECS: OA5500000
TSCA: TSCA 8(b) inventory: Kerosene
CI#: Not available.
Synonym: Astral Oil; Coal Oil, Fuel Oil No. 5, Deobase,Astral Oil, Jet A Fuel; Jet Fuel JP-1; JP-5 Navy Fuel;Kerosine, petroleum; Range Oil; K1 Kerosene; Kerosene,hydrodesulfurized; Kerosine
Chemical Name: Kerosene
Chemical Formula: Not available.
Contact Information:
Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396
US Sales: 1-800-901-7247International Sales: 1-281-441-4400
For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Kerosene 8008-20-6 or 100
64742-81-0
Toxicological Data on Ingredients: Kerosene: ORAL (LD50): Acute: 15000 mg/kg [Rat]. 20000 mg/kg [Guinea pig]. 2835mg/kg [Rabbit].
Section 3: Hazards Identification
Potential Acute Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case ofskin contact (permeator). Severe over-exposure can result in death.
Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available.The substance is toxic to the nervous system. The substance may be toxic to blood, kidneys, liver, central nervous system(CNS). Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a highlytoxic material may produce general deterioration of health by an accumulation in one or many human organs.
Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention.
Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.
Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.
Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek immediate medical attention.
Ingestion:If swallowed, do NOT induce vomiting. If swallowed, do not induce vomiting unless directed to do so by medical personnel.Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Getmedical attention immediately.
Fire Hazards in Presence of Various Substances: Flammable in presence of open flames and sparks, of heat.
Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.
Fire Fighting Media and Instructions:Flammable liquid, insoluble in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Coolcontaining vessels with water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill:
p. 3
Toxic flammable liquid, insoluble or very slightly soluble in water. Poisonous liquid. Keep away from heat. Keep away fromsources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get waterinside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements orconfined areas; dike if needed. Call for assistance on disposal.
Section 7: Handling and Storage
Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents.
Storage:Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed andsealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Section 8: Exposure Controls/Personal Protection
Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.
Exposure Limits: Not available.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid. (Oily liquid.)
Odor: Not available.
Taste: Not available.
Molecular Weight: Not available.
Color: Yellow. Clear (Light.)
pH (1% soln/water): Not applicable.
Boiling Point: 149°C (300.2°F) - 325 C
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 0.775 - .840(Water = 1)
Vapor Pressure: 0.1 kPa (@ 20°C)
Vapor Density: 4.5 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
p. 4
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility:Insoluble in cold water, hot water. Miscible with other petroleum solvents
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources (sparks, flames), incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity: Not considered to be corrosive for metals and glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Eye contact.
Toxicity to Animals: Acute oral toxicity (LD50): 2835 mg/kg [Rabbit].
Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. Causes damage to the following organs: the nervous system.May cause damage to the following organs: blood, kidneys, liver, central nervous system (CNS).
Other Toxic Effects on Humans:Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant). Slightly hazardous in case of skin contact(permeator).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic)
Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes moderate to severe skin irritation. It can cause defatting dermatitis. Eyes:May cause eye irritation. Inhalation: May cause respiratory tract and mucous membrane irritation and a burning sensationin the chest. Because of its relatively low volatility, overexposure by inhalation is uncommon, but it can occur in poorlyventilated areas or by inhalation of mists or aerosols. Symptoms of inhalation overexposure include central nevous system(CNS) depression (transient euphora, headache, irritability, excitement, ringing in the ears, weakness, incoordination,confusion, disorientation, drowsiness, tremor, somnolence, hallucinations, seizures, coma, death). May affect the heart(cardiac arrythmias), liver, kidneys, and respiration( asphyxia, apnea, acute pulmonary edema, dyspnea, fibrosis, or cyanosis)Ingestion: Causes gastrointestinal tract irritation with burning sensation in mouth, esophagus, and stomach, a b d o m i n a l pa i n , n a u s e a , v o m i t i n g , h y p e r m o t i l i t y , d i a r r h e a , h e a d a c h e , m a l a i s e . M a y a f f e c t respiration/trachea/bronchi through accidental pulmonary aspiration which can cause hypoxia, chemical pneumonitis, and noncardiogenicpulmonary edema, pulmonary hemmorrhage, coughing, breathing difficulty, acute or chronic pulmonary edema, emphysema,respiratory stimulation. It may also affect the heart (dysrrhythmias, myocardial depression, tachycardia), liver, endocrinesystem (pancreas - hypoglycemia), behavior/central nervous system (symptoms similar to that of inhalation). Chronic PotentialHealth Effects: Inhalation: Repeated or prolonged inhalation may cause respiratory tract irritation and affect behavior/centralnervous system with symptoms similar to that of acute inhalation. It may also affect the blood (changes in white blood cellcount, changes in serum compositon, pigmented or nucleated red blood cells, leukopenia, normocytic anemia) , cardiovascular
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system, respiratory system (trachea, bronchi), and may cause kidney damage. Ingestion: Repeated or prolonged ingestionmay affect the liver, endocrine system (adrenal gland, pancreas, spleen), and metabolism (weight loss), and blood. Skin:Repeated or prolonged skin contact may cause defatting dermatitis, erythema, and eczema-like skin lesions, drying andcracking of the skin, and possible burns.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: Not available.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: CLASS 3: Flammable liquid.
Identification: : Kerosene UNNA: 1223 PG: III
Special Provisions for Transport: Not available.
Section 15: Other Regulatory Information
Federal and State Regulations:Connecticut hazardous material survey.: Kerosene Rhode Island RTK hazardous substances: Kerosene Pennsylvania RTK:Kerosene Massachusetts RTK: Kerosene Massachusetts spill list: Kerosene New Jersey: Kerosene TSCA 8(b) inventory:Kerosene
Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-2B: Material causingother toxic effects (TOXIC).
DSCL (EEC):R10- Flammable. R65- Harmful: may cause lung damage if swallowed. S23- Do not breathe gas/fumes/vapour/spray S24-Avoid contact with skin. S62- If swallowed, do not induce vomiting: seek medical advice immediately and show this containeror label.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 2
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Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 0
Flammability: 2
Reactivity: 0
Specific hazard:
Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/09/2005 05:54 PM
Last Updated: 05/21/2013 12:00 PM
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MATERIAL SAFETY DATA SHEET
PRODUCT: ETHANOL, Date of Issue: December 2010
1. IDENTIFICATION OF CHEMICAL PRODUCT AND SUPPLIER
PRODUCT IDENTIFICATION:
Product Names: Supplier’s Product Code:
Ethanol, denatured
Other Names: Nil
Recommended Use: General chemical
Formula:
Chemical family Alcohol
Supplier: Formula Chemicals (N.S.W.) Pty Ltd
Address: 86 Hermitage Rd West Ryde NSW 2114
Telephone Number: (02) 9807 4266
Emergency Telephone: (02) 9807 4266 or Poisons Information Centre 131126
ACN: 001 129 406
2. HAZARDS IDENTIFICATION
NON-HAZARDOUS SUBSTANCE. DANGEROUS GOODS Not classified as hazardous according to the criteria of NOHSC.
Hazard Category: F+ Highly flammable.
Risk phrases: R11 Highly flammable.
Safety phrases: S7 Keep container tightly closed. S16 Keep away from sources of ignition.
Contact Point: Quality Assurance Manager Tel (02) 9807 4266
DISCLAIMER: All information given in this data sheet and by the company's technical staff is compiled from the best information currently available to the company. The
company accepts no responsibility whatsoever for its accuracy or for any results which may be obtained by customers. Any customer who relies upon any advice or
information given in this data sheet by the company or by its technical staff does so entirely at its own risk, and the company will not be liable for any loss or damage thereby
suffered notwithstanding any want of care on the part of the company or its staff in compiling or giving the advice or information.