RE: West Lake NPDES Analysis WorkOrder: 18040920semspub.epa.gov/work/07/30367908.pdf · State Dept Cert # NELAP Exp Date Lab Illinois IEPA 100226 NELAP 1/31/2019 Collinsville Kansas

http://www.teklabinc.com/

April 26, 2018

WorkOrder: 18040920West Lake NPDES AnalysisRE:

Dear Paul V. Rosasco, P.E.:

TEKLAB, INC received 4 samples on 4/15/2018 11:00:00 AM for the analysis presented in the following report.

Samples are analyzed on an as received basis unless otherwise requested and documented. The sample results contained in this report relate only to the requested analytes of interest as directed on the chain of custody. NELAP accredited fields of testing are indicated by the letters NELAP under the Certification column. Unless otherwise documented within this report, Teklab Inc. analyzes samples utilizing the most current methods in compliance with 40CFR. All tests are performed in the Collinsville, IL laboratory unless otherwise noted in the Case Narrative.

All quality control criteria applicable to the test methods employed for this project have been satisfactorily met and are in accordance with NELAP except where noted. The following report shall not be reproduced, except in full, without the written approval of Teklab, Inc.

If you have any questions regarding these tests results, please feel free to call.

Sincerely,

25923 Gateway DriveGolden, CO 80401

(303) 940-3426TEL:FAX:

Paul V. Rosasco, P.E.Engineering Management Support, Inc.

Emily PohlmanProject Manager(618)344-1004 ex [email protected]

Page 1 of 26

This reporting package includes the following:

Report Contents

Client Project: West Lake NPDES Analysis

Client: Engineering Management Support, Inc.

Report Date: 26-Apr-18

Work Order: 18040920


Cover Letter 1

Report Contents 2

Definitions 3

Case Narrative 4

Accreditations 5

Laboratory Results 6

Sample Summary 14

Dates Report 15

Quality Control Results 18

Receiving Check List 26

Chain of Custody Appended

Page 2 of 26

____TeklabHdrP

Definitions






Abbr Definition* Analytes on report marked with an asterisk are not NELAP accredited

CCV Continuing calibration verification is a check of a standard to determine the state of calibration of an instrument between recalibration.

DF Dilution factor is the dilution performed during analysis only and does not take into account any dilutions made during sample preparation. The reported result is final and includes all dilutions factors.

DNI Did not ignite

DUP Laboratory duplicate is an aliquot of a sample taken from the same container under laboratory conditions for independent processing and analysis independently of the original aliquot.

ICV Initial calibration verification is a check of a standard to determine the state of calibration of an instrument before sample analysis is initiated.

IDPH IL Dept. of Public Health

LCS Laboratory control sample, spiked with verified known amounts of analytes, is analyzed exactly like a sample to establish intra-laboratory or analyst specific precision and bias or to assess the performance of all or a portion of the measurement system. The acceptable recovery range is in the QC Package (provided upon request).

LCSD Laboratory control sample duplicate is a replicate laboratory control sample that is prepared and analyzed in order to determine the precision of the approved test method. The acceptable recovery range is listed in the QC Package (provided upon request).

MBLK Method blank is a sample of a matrix similar to the batch of associated sample (when available) that is free from the analytes of interest and is processed simultaneously with and under the same conditions as samples through all steps of the analytical procedures, and in which no target analytes or interferences should present at concentrations that impact the analytical results for sample analyses.

MDL Method detection limit means the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero.

MS Matrix spike is an aliquot of matrix fortified (spiked) with known quantities of specific analytes that is subjected to the entire analytical procedures in order to determine the effect of the matrix on an approved test method’s recovery system. The acceptable recovery range is listed in the QC Package (provided upon request).

MSD Matrix spike duplicate means a replicate matrix spike that is prepared and analyzed in order to determine the precision of the approved test method. The acceptable recovery range is listed in the QC Package (provided upon request).

MW Molecular weight

ND Not Detected at the Reporting Limit

NELAP NELAP Accredited

PQL Practical quantitation limit means the lowest level that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operation conditions. The acceptable recovery range is listed in the QC Package (provided upon request).

RL The reporting limit the lowest level that the data is displayed in the final report. The reporting limit may vary according to customer request or sample dilution. The reporting limit may not be less than the MDL.

RPD Relative percent difference is a calculated difference between two recoveries (ie. MS/MSD). The acceptable recovery limit is listed in the QC Package (provided upon request).

SPK The spike is a known mass of target analyte added to a blank sample or sub-sample; used to determine recovery deficiency or for other quality control purposes.

Surr Surrogates are compounds which are similar to the analytes of interest in chemical composition and behavior in the analytical process, but which are not normally found in environmental samples.

TIC Tentatively identified compound: Analytes tentatively identified in the sample by using a library search. Only results not in the calibration standard will be reported as tentatively identified compounds. Results for tentatively identified compounds that are not present in the calibration standard, but are assigned a specific chemical name based upon the library search, are calculated using total peak areas from reconstructed ion chromatograms and a response factor of one. The nearest Internal Standard is used for the calculation. The results of any TICs must be considered estimated, and are flagged with a "T". If the estimated result is above the calibration range it is flagged "ET"

TNTC Too numerous to count ( > 200 CFU )

Qualifiers# - Unknown hydrocarbon B - Analyte detected in associated Method Blank

E - Value above quantitation range H - Holding times exceeded

I - Associated internal standard was outside method criteria J - Analyte detected below quantitation limits

M - Manual Integration used to determine area response ND - Not Detected at the Reporting Limit

R - RPD outside accepted recovery limits S - Spike Recovery outside recovery limits

T - TIC(Tentatively identified compound) X - Value exceeds Maximum Contaminant Level

Page 3 of 26

Case Narrative






Cooler Receipt Temp: 2.22 °C

Hexavalent Chromium and Chromium analysis was performed by ESC Lab Sciences. See attached report for results and QC.

Locations

___________________________________Collinsville

5445 Horseshoe Lake Road

Collinsville, IL 62234-7425

(618) 344-1004

(618) 344-1005

[email protected]

___________________________________Springfield

3920 Pintail Dr

Springfield, IL 62711-9415

(217) 698-1004

(217) 698-1005

[email protected]

___________________________________Kansas City

8421 Nieman Road

Lenexa, KS 66214

(913) 541-1998

(913) 541-1998

[email protected]

___________________________________Collinsville Air


Collinsville, IL 62234-7425

(618) 344-1004

(618) 344-1005

[email protected]

___________________________________Chicago

1319 Butterfield Rd.

Downers Grove, IL 60515

(630) 324-6855

[email protected]

Page 4 of 26

____TeklabHdrP

Accreditations






NELAPState Cert # Exp Date LabDept

Illinois 100226 1/31/2019 CollinsvilleNELAPIEPA

Kansas E-10374 4/30/2018 CollinsvilleNELAPKDHE

Louisiana 166493 6/30/2018 CollinsvilleNELAPLDEQ

Louisiana 166578 6/30/2018 CollinsvilleNELAPLDEQ

Texas T104704515-12-1 7/31/2018 CollinsvilleNELAPTCEQ

Arkansas 88-0966 3/14/2019 CollinsvilleADEQ

Illinois 17584 5/31/2019 CollinsvilleIDPH

Indiana C-IL-06 1/31/2019 CollinsvilleISDH

Kentucky 98006 12/31/2018 CollinsvilleKDEP

Kentucky 0073 1/31/2019 CollinsvilleUST

Louisiana LA170027 12/31/2018 CollinsvilleLDPH

Missouri 930 1/31/2019 CollinsvilleMDNR

Missouri 00930 5/31/2019 CollinsvilleMDNR

Oklahoma 9978 8/31/2018 CollinsvilleODEQ

Tennessee 04905 1/31/2019 CollinsvilleTDEC

Page 5 of 26http://www.teklabinc.com/

TeklabHdrP

Laboratory Results






Analyses Result Units Date AnalyzedRL DFCertification Qual

Collection Date: 04/14/2018 8:25

Lab ID: 18040920-001 Client Sample ID: OU-1-003A

Matrix: WASTE WATER

Batch

EPA 1664AHexane Extractable Material 04/18/2018 10:205 mg/L 1< 5NELAP R246020

EPA 600 375.2 REV 2.0 1993 (TOTAL)Sulfate S 04/16/2018 14:24100 mg/L 10228NELAP R245877

Matrix spike did not recover within control limits. Results verified by dilution.

STANDARD METHODS 2540 D 1997Total Suspended Solids 04/16/2018 13:016 mg/L 1< 6NELAP R245885

Sample and Duplicate RPD meet the SOP QC criteria for low level results. Data is reportable.

STANDARD METHODS 2540 F 1997Solids, Settleable H 04/16/2018 10:140.1 ml/L 1< 0.1NELAP R245868

STANDARD METHODS 4500-CL E (TOTAL) 1997Chloride 04/16/2018 14:115 mg/L 131NELAP R245962

STANDARD METHODS 4500-NH3 H MODIFIED (TOTAL) 1997Nitrogen, Ammonia (as N) JS 04/17/2018 17:410.10 mg/L 10.05NELAP R245932

Matrix spike did not recover within control limits due to matrix interference.

STANDARD METHODS 5210 B 2001Biochemical Oxygen Demand H 04/16/2018 15:225 mg/L 1< 5NELAP 140895

STANDARD METHODS 5220 D (TOTAL) 1997Chemical Oxygen Demand J 04/17/2018 18:4450 mg/L 131NELAP R245940

EPA 600 245.1 R3.0 (TOTAL)Mercury 04/17/2018 8:430.00020 mg/L 1< 0.00020NELAP 140887

EPA 600 4.1.4, 200.7R4.4, METALS BY ICP (TOTAL)Aluminum 04/17/2018 21:540.0250 mg/L 10.142NELAP 140892

Barium 04/17/2018 21:540.0025 mg/L 10.0472NELAP 140892

Beryllium 04/17/2018 21:540.0005 mg/L 1< 0.0005NELAP 140892

Cobalt 04/17/2018 21:540.0050 mg/L 1< 0.0050NELAP 140892

Copper J 04/17/2018 21:540.0050 mg/L 10.0027NELAP 140892

Iron 04/18/2018 20:200.0400 mg/L 10.149NELAP 140892

Nickel J 04/17/2018 21:540.0050 mg/L 10.0043NELAP 140892

Silver 04/17/2018 21:540.0070 mg/L 1< 0.0070NELAP 140892

Zinc 04/17/2018 21:540.0100 mg/L 10.0613NELAP 140892

EPA 600 4.1.4, 200.8 R5.4, METALS BY ICPMS (TOTAL)Antimony J 04/18/2018 12:050.0010 mg/L 50.0008NELAP 140893

Arsenic 04/18/2018 12:050.0010 mg/L 50.0023NELAP 140893

Cadmium 04/18/2018 12:050.0010 mg/L 5< 0.0010NELAP 140893

Lead 04/18/2018 12:050.0010 mg/L 5< 0.0010NELAP 140893

Selenium 04/18/2018 12:050.0010 mg/L 50.0074NELAP 140893

Thallium 04/18/2018 12:050.0020 mg/L 5< 0.0020NELAP 140893

EPA 600 625 (MODIFIED), SEMI-VOLATILE ORGANIC COMPOUNDS BY GC/MSalpha-Terpineol 04/18/2018 14:350.008 mg/L 1ND* 140886

Benzoic acid 04/18/2018 14:350.039 mg/L 1ND* 140886

p-Cresol 04/18/2018 14:350.008 mg/L 1ND* 140886

Phenol 04/18/2018 14:350.004 mg/L 1NDNELAP 140886

Surr: 2,4,6-Tribromophenol 04/18/2018 14:3528.4-122 %REC 162.9* 140886

Surr: 2-Fluorobiphenyl 04/18/2018 14:3536.3-102 %REC 169.1* 140886

Surr: 2-Fluorophenol 04/18/2018 14:3512.3-72.5 %REC 134.0* 140886

Surr: Nitrobenzene-d5 04/18/2018 14:3532.3-100 %REC 176.2* 140886

Page 6 of 26

TeklabHdrP

Laboratory Results








Lab ID: 18040920-001 Client Sample ID: OU-1-003A

Matrix: WASTE WATER

Batch

EPA 600 625 (MODIFIED), SEMI-VOLATILE ORGANIC COMPOUNDS BY GC/MS Surr: Phenol-d5 04/18/2018 14:3510-62.5 %REC 125.0* 140886

Surr: p-Terphenyl-d14 04/18/2018 14:3510-112 %REC 135.2* 140886

Due to the absence of m,p-Cresol in the sample, p-Cresol is reported as non-detect.CCV recovered outside upper method limits for Benzoic acid. Sample results are below the reporting limit. Data is reportable per the TNI Standard.

EPA 600 624 (MODIFIED), VOLATILE ORGANIC COMPOUNDS BY GC/MSBenzene 04/16/2018 16:040.5 µg/L 1NDNELAP 140908

Surr: 1,2-Dichloroethane-d4 04/16/2018 16:0479.6-118 %REC 1100.1* 140908

Surr: 4-Bromofluorobenzene 04/16/2018 16:0483.9-115 %REC 1100.8* 140908

Surr: Dibromofluoromethane 04/16/2018 16:0484.9-113 %REC 1103.2* 140908

Surr: Toluene-d8 04/16/2018 16:0486.7-112 %REC 196.9* 140908

SEE ATTACHED FOR SUBCONTRACTING ANALYSISSubcontracted Analysis 04/20/2018 1:190 1See Attached* R246226

Subcontracted Analysis 04/20/2018 18:210 1See Attached* R246226

Page 7 of 26

TeklabHdrP

Laboratory Results








Lab ID: 18040920-002 Client Sample ID: OU-1-002

Matrix: WASTE WATER

Batch


EPA 600 375.2 REV 2.0 1993 (TOTAL)Sulfate 04/16/2018 14:41100 mg/L 10388NELAP R245877

STANDARD METHODS 2540 D 1997Total Suspended Solids 04/16/2018 13:146 mg/L 18NELAP R245885

STANDARD METHODS 2540 F 1997Solids, Settleable H 04/16/2018 10:140.1 ml/L 1< 0.1NELAP R245868


STANDARD METHODS 4500-NH3 H MODIFIED (TOTAL) 1997Nitrogen, Ammonia (as N) 04/17/2018 18:110.10 mg/L 1< 0.10NELAP R245932

STANDARD METHODS 5210 B 2001Biochemical Oxygen Demand H 04/16/2018 15:285 mg/L 1< 5NELAP 140895




Barium 04/17/2018 22:120.0025 mg/L 10.0822NELAP 140892


Cobalt 04/17/2018 22:120.0050 mg/L 1< 0.0050NELAP 140892


Iron 04/18/2018 20:380.0400 mg/L 10.0676NELAP 140892

Nickel 04/17/2018 22:120.0050 mg/L 10.0175NELAP 140892

Silver 04/17/2018 22:120.0070 mg/L 1< 0.0070NELAP 140892

Zinc 04/17/2018 22:120.0100 mg/L 10.0384NELAP 140892


Arsenic J 04/18/2018 12:130.0010 mg/L 50.0009NELAP 140893


Lead J 04/18/2018 12:130.0010 mg/L 50.0003NELAP 140893





p-Cresol 04/18/2018 15:030.008 mg/L 1ND* 140886






Surr: Phenol-d5 04/18/2018 15:0310-62.5 %REC 122.2* 140886


Page 8 of 26

TeklabHdrP

Laboratory Results









Matrix: WASTE WATER

Batch

EPA 600 625 (MODIFIED), SEMI-VOLATILE ORGANIC COMPOUNDS BY GC/MSDue to the absence of m,p-Cresol in the sample, p-Cresol is reported as non-detect.CCV recovered outside upper method limits for Benzoic acid. Sample results are below the reporting limit. Data is reportable per the TNI Standard.








Page 9 of 26

TeklabHdrP

Laboratory Results









Matrix: WASTE WATER

Batch



STANDARD METHODS 2540 D 1997Total Suspended Solids 04/16/2018 13:146 mg/L 112NELAP R245885

STANDARD METHODS 2540 F 1997Solids, Settleable H 04/16/2018 10:140.1 ml/L 10.1NELAP R245868


STANDARD METHODS 4500-NH3 H MODIFIED (TOTAL) 1997Nitrogen, Ammonia (as N) J 04/17/2018 18:140.10 mg/L 10.08NELAP R245932

STANDARD METHODS 5210 B 2001Biochemical Oxygen Demand H 04/16/2018 15:315 mg/L 121NELAP 140895

STANDARD METHODS 5220 D (TOTAL) 1997Chemical Oxygen Demand 04/17/2018 18:4550 mg/L 163NELAP R245940



Barium 04/17/2018 22:180.0025 mg/L 10.0921NELAP 140892


Cobalt 04/17/2018 22:180.0050 mg/L 1< 0.0050NELAP 140892

Copper 04/17/2018 22:180.0050 mg/L 10.0071NELAP 140892

Iron 04/18/2018 20:430.0400 mg/L 10.418NELAP 140892

Nickel 04/17/2018 22:180.0050 mg/L 10.0087NELAP 140892

Silver 04/17/2018 22:180.0070 mg/L 1< 0.0070NELAP 140892

Zinc 04/17/2018 22:180.0100 mg/L 10.0471NELAP 140892



Cadmium J 04/18/2018 12:220.0010 mg/L 50.0002NELAP 140893

Lead 04/18/2018 12:220.0010 mg/L 50.0023NELAP 140893





p-Cresol 04/18/2018 15:310.008 mg/L 1ND* 140886






Surr: Phenol-d5 04/18/2018 15:3110-62.5 %REC 120.2* 140886


Page 10 of 26

TeklabHdrP

Laboratory Results









Matrix: WASTE WATER

Batch









Page 11 of 26

TeklabHdrP

Laboratory Results









Matrix: WASTE WATER

Batch



STANDARD METHODS 2540 D 1997Total Suspended Solids 04/17/2018 11:1116 mg/L 2.7230NELAP R245937

STANDARD METHODS 2540 F 1997Solids, Settleable 04/16/2018 10:140.1 ml/L 13.0NELAP R245868


STANDARD METHODS 4500-NH3 H MODIFIED (TOTAL) 1997Nitrogen, Ammonia (as N) J 04/17/2018 18:160.10 mg/L 10.07NELAP R245932

STANDARD METHODS 5210 B 2001Biochemical Oxygen Demand H 04/16/2018 15:345 mg/L 17NELAP 140895




Barium 04/17/2018 22:240.0025 mg/L 10.196NELAP 140892


Cobalt 04/17/2018 22:240.0050 mg/L 1< 0.0050NELAP 140892


Iron 04/18/2018 20:490.0400 mg/L 11.29NELAP 140892

Nickel J 04/17/2018 22:240.0050 mg/L 10.0045NELAP 140892

Silver 04/17/2018 22:240.0070 mg/L 1< 0.0070NELAP 140892

Zinc 04/17/2018 22:240.0100 mg/L 10.0306NELAP 140892




Lead 04/18/2018 12:300.0010 mg/L 50.0013NELAP 140893

Selenium J 04/18/2018 12:300.0010 mg/L 50.0003NELAP 140893




p-Cresol 04/18/2018 15:590.008 mg/L 1ND* 140886






Surr: Phenol-d5 04/18/2018 15:5910-62.5 %REC 122.1* 140886


Page 12 of 26

TeklabHdrP

Laboratory Results









Matrix: WASTE WATER

Batch









Page 13 of 26

Lab Sample ID Client Sample ID Collection DateFractions

TeklabHdrP

Matrix

Sample Summary






18040920-001 OU-1-003A 04/14/2018 8:2511Waste Water

18040920-002 OU-1-002 04/14/2018 9:0011Waste Water

18040920-003 OU-1-001 04/14/2018 10:0511Waste Water

18040920-004 OU-1-008 04/14/2018 11:1511Waste Water

Page 14 of 26

Analysis Date/TimeTest Name Prep Date/Time

____TeklabHdrP

Sample ID Client Sample ID Collection Date Received Date

Dates Report






18040920-001A OU-1-003A 04/14/2018 8:25 04/15/2018 11:00

EPA 600 625 (Modified), Semi-Volatile Organic Compounds by GC/MS 04/18/2018 14:3504/17/2018 9:07

18040920-001B OU-1-003A 04/14/2018 8:25 04/15/2018 11:00

Standard Methods 2540 F 1997 04/16/2018 10:14

18040920-001C OU-1-003A 04/14/2018 8:25 04/15/2018 11:00

EPA 600 375.2 Rev 2.0 1993 (Total) 04/16/2018 14:24

Standard Methods 2540 D 1997 04/16/2018 13:01

Standard Methods 4500-Cl E (Total) 1997 04/16/2018 14:11

Standard Methods 5210 B 2001 04/16/2018 15:2204/16/2018 12:17

18040920-001D OU-1-003A 04/14/2018 8:25 04/15/2018 11:00

See Attached for Subcontracting Analysis 04/20/2018 18:21

18040920-001E OU-1-003A 04/14/2018 8:25 04/15/2018 11:00

EPA 600 245.1 R3.0 (Total) 04/17/2018 8:4304/16/2018 10:28

EPA 600 4.1.4, 200.7R4.4, Metals by ICP (Total) 04/17/2018 21:5404/16/2018 11:23


EPA 600 4.1.4, 200.8 R5.4, Metals by ICPMS (Total) 04/18/2018 12:0504/16/2018 11:32

18040920-001F OU-1-003A 04/14/2018 8:25 04/15/2018 11:00

EPA 1664A 04/18/2018 10:20

18040920-001G OU-1-003A 04/14/2018 8:25 04/15/2018 11:00

Standard Methods 4500-NH3 H Modified (Total) 1997 04/17/2018 17:41

Standard Methods 5220 D (Total) 1997 04/17/2018 18:44

18040920-001H OU-1-003A 04/14/2018 8:25 04/15/2018 11:00


18040920-001K OU-1-003A 04/14/2018 8:25 04/15/2018 11:00

EPA 600 624 (Modified), Volatile Organic Compounds by GC/MS 04/16/2018 16:04

18040920-002A OU-1-002 04/14/2018 9:00 04/15/2018 11:00


18040920-002B OU-1-002 04/14/2018 9:00 04/15/2018 11:00


18040920-002C OU-1-002 04/14/2018 9:00 04/15/2018 11:00

EPA 600 375.2 Rev 2.0 1993 (Total) 04/16/2018 14:41




18040920-002D OU-1-002 04/14/2018 9:00 04/15/2018 11:00


Page 15 of 26


____TeklabHdrP


Dates Report






18040920-002E OU-1-002 04/14/2018 9:00 04/15/2018 11:00

EPA 600 245.1 R3.0 (Total) 04/17/2018 8:4504/16/2018 10:28




18040920-002F OU-1-002 04/14/2018 9:00 04/15/2018 11:00

EPA 1664A 04/18/2018 10:20

18040920-002G OU-1-002 04/14/2018 9:00 04/15/2018 11:00



18040920-002H OU-1-002 04/14/2018 9:00 04/15/2018 11:00


18040920-002K OU-1-002 04/14/2018 9:00 04/15/2018 11:00


18040920-003A OU-1-001 04/14/2018 10:05 04/15/2018 11:00


18040920-003B OU-1-001 04/14/2018 10:05 04/15/2018 11:00


18040920-003C OU-1-001 04/14/2018 10:05 04/15/2018 11:00

EPA 600 375.2 Rev 2.0 1993 (Total) 04/16/2018 14:51




18040920-003D OU-1-001 04/14/2018 10:05 04/15/2018 11:00


18040920-003E OU-1-001 04/14/2018 10:05 04/15/2018 11:00

EPA 600 245.1 R3.0 (Total) 04/17/2018 9:3704/16/2018 10:28




18040920-003F OU-1-001 04/14/2018 10:05 04/15/2018 11:00

EPA 1664A 04/18/2018 10:20

18040920-003G OU-1-001 04/14/2018 10:05 04/15/2018 11:00



18040920-003H OU-1-001 04/14/2018 10:05 04/15/2018 11:00

Page 16 of 26


____TeklabHdrP


Dates Report







18040920-003K OU-1-001 04/14/2018 10:05 04/15/2018 11:00


18040920-004A OU-1-008 04/14/2018 11:15 04/15/2018 11:00


18040920-004B OU-1-008 04/14/2018 11:15 04/15/2018 11:00


18040920-004C OU-1-008 04/14/2018 11:15 04/15/2018 11:00

EPA 600 375.2 Rev 2.0 1993 (Total) 04/16/2018 15:16




18040920-004D OU-1-008 04/14/2018 11:15 04/15/2018 11:00


18040920-004E OU-1-008 04/14/2018 11:15 04/15/2018 11:00

EPA 600 245.1 R3.0 (Total) 04/17/2018 9:3904/16/2018 10:28




18040920-004F OU-1-008 04/14/2018 11:15 04/15/2018 11:00

EPA 1664A 04/18/2018 10:20

18040920-004G OU-1-008 04/14/2018 11:15 04/15/2018 11:00



18040920-004H OU-1-008 04/14/2018 11:15 04/15/2018 11:00


18040920-004K OU-1-008 04/14/2018 11:15 04/15/2018 11:00


Page 17 of 26

Quality Control Results






EPA 1664A

SampID: MBLK

SampType: MBLK mg/LUnitsR246020Batch

Analyses ResultDate

AnalyzedRL SpikeQual SPK Ref Val %REC Low Limit High Limit

Hexane Extractable Material 04/18/20185 3.500< 5 00 -100 100

SampID: LCS

SampType: LCS mg/LUnitsR246020Batch

Analyses ResultDate


Hexane Extractable Material 04/18/20185 40.0033 82.50 78 114

SampID: LCSD

SampType: LCSD mg/LUnitsR246020Batch RPD Limit 18

Analyses ResultDate

AnalyzedRL SpikeQual SPK Ref Val %REC RPD Ref Val %RPD

Hexane Extractable Material 04/18/20185 40.0034 84.8 2.690 33.00

EPA 600 375.2 REV 2.0 1993 (TOTAL)

SampID: ICB/MBLK


Analyses ResultDate


Sulfate 04/16/201810 5.000< 10 00 -100 100

SampID: ICV/LCS


Analyses ResultDate


Sulfate 04/16/201810 20.0018 92.00 90 110

SampID: 18040920-001CMS

SampType: MS mg/LUnitsR245877Batch

Analyses ResultDate


Sulfate 04/16/2018100 100.0331 103.4227.7 90 110

SampID: 18040920-001CMSD

SampType: MSD mg/LUnitsR245877Batch RPD Limit 10

Analyses ResultDate


Sulfate S 04/16/2018100 100.0316 87.9 4.81227.7 331.2

STANDARD METHODS 2540 D 1997

SampID: MBLK


Analyses ResultDate


Total Suspended Solids 04/16/20180.5 < 0.5

Total Suspended Solids 04/16/20186 4.000< 6 00 -100 100



Page 18 of 26







STANDARD METHODS 2540 D 1997

SampID: LCS


Analyses ResultDate


Total Suspended Solids 04/16/20186 100.0102 102.00 85 115

SampID: LCSQC

SampType: LCSQC mg/LUnitsR245885Batch

Analyses ResultDate





SampID: 18040920-001CDUP

SampType: DUP mg/LUnitsR245885Batch RPD Limit 5

Analyses ResultDate


Total Suspended Solids J 04/16/20186 4 0.000

SampID: MBLK


Analyses ResultDate





Total Suspended Solids 04/17/20180.5 < 0.5

SampID: LCS


Analyses ResultDate



SampID: LCSQC

SampType: LCSQC mg/LUnitsR245937Batch

Analyses ResultDate





STANDARD METHODS 4500-CL E (TOTAL) 1997

SampID: ICB/MBLK


Analyses ResultDate


Chloride 04/16/20185 0.3300< 5 00 -100 100

Page 19 of 26







STANDARD METHODS 4500-CL E (TOTAL) 1997

SampID: ICV/LCS


Analyses ResultDate


Chloride 04/16/20185 20.0020 99.60 90 110

SampID: 18040920-001CMS


Analyses ResultDate


Chloride E 04/16/20185 20.0051 98.530.82 85 115

SampID: 18040920-001CMSD


Analyses ResultDate


Chloride 04/16/20185 20.0050 95.4 1.2230.82 50.51

STANDARD METHODS 4500-NH3 H MODIFIED (TOTAL) 1997

SampID: ICB/MBLK


Analyses ResultDate


Nitrogen, Ammonia (as N) 04/17/20180.10 0.04600< 0.10 00 -100 100

SampID: ICV/LCS


Analyses ResultDate


Nitrogen, Ammonia (as N) 04/17/20180.10 1.0001.02 101.50 90 110

SampID: 18040920-001GMS


Analyses ResultDate


Nitrogen, Ammonia (as N) S 04/17/20180.10 2.0001.71 83.00.04900 85 115

SampID: 18040920-001GMSD


Analyses ResultDate


Nitrogen, Ammonia (as N) S 04/17/20180.10 2.0001.72 83.6 0.640.04900 1.710

STANDARD METHODS 5210 B 2001

SampID: LCS-BOD-1-041618

SampType: LCS mg/LUnits140895Batch

Analyses ResultDate


Biochemical Oxygen Demand 04/16/20185 198.0212 107.10 84.6 115.4

Page 20 of 26







STANDARD METHODS 5210 B 2001

SampID: 18040920-001CDUP

SampType: DUP mg/LUnits140895Batch RPD Limit 40

Analyses ResultDate


Biochemical Oxygen Demand H 04/16/20185 < 5 0.000

STANDARD METHODS 5220 D (TOTAL) 1997

SampID: MBLK


Analyses ResultDate


Chemical Oxygen Demand 04/17/201850 13.00< 50 00 -100 100

SampID: LCS


Analyses ResultDate


Chemical Oxygen Demand 04/17/201850 200.0201 100.30 90 110

SampID: 18040920-002GMS


Analyses ResultDate


Chemical Oxygen Demand 04/17/2018100 10001010 99.316.98 85 115

SampID: 18040920-002GMSD


Analyses ResultDate


Chemical Oxygen Demand 04/17/2018100 10001000 98.4 0.9316.98 1010

EPA 600 245.1 R3.0 (TOTAL)

SampID: MBLK-140887

SampType: MBLK mg/LUnits140887Batch

Analyses ResultDate


Mercury 04/17/20180.00020 0.00008000< 0.00020 00 -100 100

SampID: LCS-140887


Analyses ResultDate


Mercury 04/17/20180.00020 0.0050000.00511 102.30 85 115

SampID: 18040920-002EMS

SampType: MS mg/LUnits140887Batch

Analyses ResultDate


Mercury 04/17/20180.00020 0.0050000.00514 102.80 75 125

Page 21 of 26







EPA 600 245.1 R3.0 (TOTAL)

SampID: 18040920-002EMSD

SampType: MSD mg/LUnits140887Batch RPD Limit 15

Analyses ResultDate


Mercury 04/17/20180.00020 0.0050000.00512 102.4 0.460 0.005142

EPA 600 4.1.4, 200.7R4.4, METALS BY ICP (TOTAL)

SampID: MBLK-140892


Analyses ResultDate


Aluminum 04/17/20180.0250 0.009100< 0.0250 00 -100 100

Barium 04/17/20180.0025 0.0007000< 0.0025 00 -100 100

Beryllium 04/17/20180.0005 0.0002000< 0.0005 00 -100 100

Cobalt 04/17/20180.0050 0.002000< 0.0050 00 -100 100

Copper 04/17/20180.0050 0.001300< 0.0050 00 -100 100

Iron 04/18/20180.0400 0.02000< 0.0400 00 -100 100

Nickel 04/17/20180.0050 0.001600< 0.0050 00 -100 100

Silver 04/17/20180.0070 0.002700< 0.0070 00 -100 100

Zinc 04/17/20180.0100 0.005000< 0.0100 00 -100 100

SampID: LCS-140892


Analyses ResultDate


Aluminum 04/17/20180.0250 2.0002.15 107.50 85 115

Barium 04/17/20180.0025 2.0002.06 102.80 85 115

Beryllium 04/17/20180.0005 0.050000.0527 105.40 85 115

Cobalt 04/17/20180.0050 0.50000.499 99.80 85 115

Copper 04/17/20180.0050 0.25000.259 103.80 85 115

Iron 04/18/20180.0400 2.0002.08 104.00 85 115

Nickel 04/17/20180.0050 0.50000.514 102.80 85 115

Silver 04/17/20180.0070 0.050000.0510 102.00 85 115

Zinc 04/17/20180.0100 0.50000.507 101.30 85 115

SampID: 18040920-001EMS


Analyses ResultDate


Aluminum 04/17/20180.0250 2.0002.30 107.70.1415 75 125

Barium 04/17/20180.0025 2.0002.05 100.30.04720 75 125

Beryllium 04/17/20180.0005 0.050000.0512 102.40 75 125

Cobalt 04/17/20180.0050 0.50000.481 96.30 75 125

Copper 04/17/20180.0050 0.25000.258 102.10.002700 75 125

Iron 04/18/20180.0400 2.0002.16 100.70.1491 75 125

Nickel 04/17/20180.0050 0.50000.500 99.10.004300 75 125

Silver 04/17/20180.0070 0.050000.0493 98.60 75 125

Zinc 04/17/20180.0100 0.50000.546 96.80.06130 75 125

Page 22 of 26







EPA 600 4.1.4, 200.7R4.4, METALS BY ICP (TOTAL)



Analyses ResultDate


Aluminum 04/17/20180.0250 2.0002.33 109.3 1.430.1415 2.295

Barium 04/17/20180.0025 2.0002.05 100.0 0.340.04720 2.054

Beryllium 04/17/20180.0005 0.050000.0509 101.8 0.590 0.05120

Cobalt 04/17/20180.0050 0.50000.490 98.0 1.790 0.4813

Copper 04/17/20180.0050 0.25000.262 103.7 1.540.002700 0.2579

Iron 04/18/20180.0400 2.0002.11 98.0 2.480.1491 2.163

Iron 04/17/20180.0400 2.0002.25 105.3 2.150.1465 2.205

Nickel 04/17/20180.0050 0.50000.510 101.1 1.920.004300 0.4999

Silver 04/17/20180.0070 0.050000.0505 101.0 2.400 0.04930

Zinc 04/17/20180.0100 0.50000.558 99.3 2.250.06130 0.5455

EPA 600 4.1.4, 200.8 R5.4, METALS BY ICPMS (TOTAL)

SampID: MBLK-140893


Analyses ResultDate


Antimony 04/18/20180.0010 0.0004500< 0.0010 00 -100 100

Arsenic 04/18/20180.0010 0.0003800< 0.0010 00 -100 100

Cadmium 04/18/20180.0010 0.0001300< 0.0010 00 -100 100

Lead 04/18/20180.0010 0.0001800< 0.0010 00 -100 100

Selenium 04/18/20180.0010 0.0002800< 0.0010 00 -100 100

Thallium 04/18/20180.0020 0.0008500< 0.0020 00 -100 100

SampID: LCS-140893


Analyses ResultDate


Antimony 04/18/20180.0010 0.50000.507 101.50 85 115

Arsenic 04/18/20180.0010 0.50000.521 104.20 85 115

Cadmium 04/18/20180.0010 0.050000.0483 96.70 85 115

Lead 04/18/20180.0010 0.50000.506 101.10 85 115

Selenium 04/18/20180.0010 0.50000.511 102.20 85 115

Thallium 04/18/20180.0020 0.25000.245 97.90 85 115

SampID: 18040920-001EMS


Analyses ResultDate


Antimony 04/18/20180.0010 0.50000.506 101.10.0007938 70 130

Arsenic 04/18/20180.0010 0.50000.515 102.60.002285 70 130

Cadmium 04/18/20180.0010 0.050000.0469 93.80 70 130

Lead 04/18/20180.0010 0.50000.498 99.70 70 130

Selenium 04/18/20180.0010 0.50000.509 100.30.007427 70 130

Thallium 04/18/20180.0020 0.25000.239 95.50 70 130

Page 23 of 26







EPA 600 4.1.4, 200.8 R5.4, METALS BY ICPMS (TOTAL)



Analyses ResultDate


Antimony 04/18/20180.0010 0.50000.501 100.1 0.960.0007938 0.5062

Arsenic 04/18/20180.0010 0.50000.521 103.7 1.050.002285 0.5151

Cadmium 04/18/20180.0010 0.050000.0468 93.6 0.140 0.04689

Lead 04/18/20180.0010 0.50000.494 98.9 0.800 0.4983

Selenium 04/18/20180.0010 0.50000.514 101.3 0.970.007427 0.5089

Thallium 04/18/20180.0020 0.25000.236 94.5 1.130 0.2388

EPA 600 625 (MODIFIED), SEMI-VOLATILE ORGANIC COMPOUNDS BY GC/MS

SampID: MBLK-140886


Analyses ResultDate


alpha-Terpineol 04/18/20180.010 ND

Benzoic acid 04/17/20180.050 ND

Phenol 04/17/20180.005 ND

Surr: 2,4,6-Tribromophenol 04/17/20180.050000.039 78.5 59.1 112

Surr: 2-Fluorobiphenyl 04/17/20180.025000.019 77.3 49.6 96.2

Surr: 2-Fluorophenol 04/17/20180.050000.028 56.7 35.2 74.5

Surr: Nitrobenzene-d5 04/17/20180.025000.021 82.4 43.6 98.7

Surr: Phenol-d5 04/17/20180.050000.019 38.6 23.7 53.6

Surr: p-Terphenyl-d14 04/17/20180.025000.021 85.0 55.7 120

SampID: LCS-140886


Analyses ResultDate


Phenol 04/17/20180.005 0.050000.021 41.40 19.5 66.9

Surr: 2,4,6-Tribromophenol 04/17/20180.050000.043 86.9 59.1 112

Surr: 2-Fluorobiphenyl 04/17/20180.025000.018 71.5 49.6 96.2

Surr: 2-Fluorophenol 04/17/20180.050000.027 53.7 35.2 74.5

Surr: Nitrobenzene-d5 04/17/20180.025000.019 76.4 43.6 98.7

Surr: Phenol-d5 04/17/20180.050000.019 37.6 23.7 53.6

Surr: p-Terphenyl-d14 04/17/20180.025000.022 89.6 55.7 120

SampID: LCSD-140886

SampType: LCSD mg/LUnits140886Batch RPD Limit 40

Analyses ResultDate


Phenol 04/17/20180.005 0.050000.024 47.9 14.610 0.02069

Surr: 2,4,6-Tribromophenol 04/17/20180.050000.043 85.4

Surr: 2-Fluorobiphenyl 04/17/20180.025000.020 79.0

Surr: 2-Fluorophenol 04/17/20180.050000.030 61.0

Surr: Nitrobenzene-d5 04/17/20180.025000.021 83.8

Surr: Phenol-d5 04/17/20180.050000.022 43.0

Surr: p-Terphenyl-d14 04/17/20180.025000.023 90.0

Page 24 of 26







EPA 600 624 (MODIFIED), VOLATILE ORGANIC COMPOUNDS BY GC/MS

SampID: MBLK-T180416A-1

SampType: MBLK µg/LUnits140908Batch

Analyses ResultDate


Benzene 04/16/20180.5 ND

Surr: 1,2-Dichloroethane-d4 04/16/201850.0050.4 100.8 79.6 118

Surr: 4-Bromofluorobenzene 04/16/201850.0051.1 102.2 83.9 115

Surr: Dibromofluoromethane 04/16/201850.0051.4 102.8 84.9 113

Surr: Toluene-d8 04/16/201850.0047.8 95.7 86.7 112

SampID: LCSD-T180416A-1

SampType: LCSD µg/LUnits140908Batch RPD Limit 40

Analyses ResultDate


Benzene 04/16/20180.5 50.0056.6 113.3 0.140 56.73

Surr: 1,2-Dichloroethane-d4 04/16/201850.0048.9 97.9

Surr: 4-Bromofluorobenzene 04/16/201850.0048.8 97.6

Surr: Dibromofluoromethane 04/16/201850.0052.0 103.9

Surr: Toluene-d8 04/16/201850.0047.0 93.9

SampID: LCS-T180416A-1

SampType: LCS µg/LUnits140908Batch

Analyses ResultDate


Benzene 04/16/20180.5 50.0056.7 113.50 77.8 120

Surr: 1,2-Dichloroethane-d4 04/16/201850.0048.0 96.1 79.6 118

Surr: 4-Bromofluorobenzene 04/16/201850.0048.2 96.5 83.9 115

Surr: Dibromofluoromethane 04/16/201850.0051.7 103.4 84.9 113

Surr: Toluene-d8 04/16/201850.0047.0 94.0 86.7 112

Page 25 of 26

Receiving Check List






Received By: TWMCarrier: Jon Wilkinson

Completed by: Reviewed by:

On:

16-Apr-18

On:

16-Apr-18

Shipping container/cooler in good condition? Yes No Not Present

Chain of custody present? Yes No

Chain of custody signed when relinquished and received? Yes No

Chain of custody agrees with sample labels? Yes No

Samples in proper container/bottle? Yes No

Sample containers intact? Yes No

Sufficient sample volume for indicated test? Yes No

All samples received within holding time? Yes No

Container/Temp Blank temperature in compliance? Yes No

Temp °C

When thermal preservation is required, samples are compliant with a temperature between 0.1°C - 6.0°C, or when samples are received on ice the same day as collected.

The samples were checked for chlorine upon arrival at the laboratory. Chlorine was not present; analysis will be performed from the Hydrochloric Acid-preserved vials. - adilallo - 4/16/2018 9:36:50 AM

Samples were received with insufficient amount of time to meet hold time requirements for BOD and Settleable Solids analyses. Per Jon Wilkinson, proceed with analyses. - adilallo/epohlman - 4/16/2018 9:18:49 AM

Water – at least one vial per sample has zero headspace? Yes No No VOA vials

Water - pH acceptable upon receipt? Yes No NA

Type of thermal preservation? None Ice Blue Ice Dry Ice

Chain of custody 1 Extra pages included 14

Reported field parameters measured: Field Lab NA

Water - TOX containers have zero headspace? No TOX containersYes No

NPDES/CWA TCN interferences checked/treated in the field? Yes No NA

Amber M. Dilallo Elizabeth A. Hurley

Page 26 of 26

ANALYTICAL REPORTApri l 24, 2018

TEKLAB, Inc.

Sample Delivery Group: L986501

Samples Received: 04/17/2018

Project Number:

Description:

Report To: Emily Pohlman


Collinsville, IL 62234

Entire Report Reviewed By:

Apri l 24, 2018

[Preliminary Report]

Darren ReederTechnica l Serv ice Representa t ive

Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.

12065 Lebanon Rd Mount Jul iet , TN 37122 615-758-5858 800-767-5859 www.esclabsciences.com

Apri l 24, 2018

Darren ReederTechnica l Serv ice Representa t ive

http://www.esclabsciences.com

https://www.esclabsciences.com/login

mailto:[email protected]; [email protected]?subject=ESC Lab Sciences SDG: L986501&body=Email regarding SDG: L986501

mailto:[email protected]?subject=ESC Lab Sciences SDG: L986501&body=Email regarding SDG: L986501

http://www.esclabsciences.com


ONE LAB. NATIONWIDE.TABLE OF CONTENTS

Cp: Cover Page 1

Tc: Table of Contents 2

Ss: Sample Summary 3

Cn: Case Narrative 4

Sr: Sample Results 5

18040920-01 L986501-01 5

18040920-02 L986501-02 6

18040920-03 L986501-03 7

18040920-04 L986501-04 8

Qc: Quality Control Summary 9

Wet Chemistry by Method 218.6M 9

Metals (ICP) by Method 200.7 10

Gl: Glossary of Terms 11

Al: Accreditations & Locations 12

Sc: Sample Chain of Custody 13

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

TEKLAB, Inc. L986501 04/24/18 13:00 2 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 2 of 14

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

18040920-01 L986501-01 WW 18040920 04/14/18 08:25 04/17/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Calculated Results WG1099741 1 04/19/18 08:34 04/20/18 18:21 MCG

Wet Chemistry by Method 218.6M WG1100785 1 04/20/18 18:21 04/20/18 18:21 MCG

Metals (ICP) by Method 200.7 WG1099741 1 04/19/18 08:34 04/20/18 01:19 TRB


18040920-02 L986501-02 WW 18040920 04/14/18 09:00 04/17/18 08:45


date/time date/time





18040920-03 L986501-03 WW 18040920 04/14/18 10:05 04/17/18 08:45


date/time date/time





18040920-04 L986501-04 WW 18040920 04/14/18 11:15 04/17/18 08:45


date/time date/time




1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 3 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 3 of 14

ONE LAB. NATIONWIDE.CASE NARRATIVE

All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated withinthe report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental sampleshave been corrected for the dilution factor used in the analysis. All radiochemical sample results for solids are reported on a dry weight basis with the exception of tritium, carbon-14 and radon, unless wet weight was requested by the client. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data.

[Preliminary Report]

Darren ReederTechn ica l Se rv i ce Represen ta t i ve

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 4 of 14

Darren ReederTechn ica l Se rv i ce Represen ta t i ve


TEKLAB, Inc. L986501 04/24/18 13:39 4 of 14



ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 9 8 6 5 0 1

18040920-01C o l l e c t e d d a t e / t i m e : 0 4 / 1 4 / 1 8 0 8 : 2 5

Calculated Results

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chromium,Trivalent U 0.150 0.500 1 04/20/2018 18:21 WG1099741

Wet Chemistry by Method 218.6M



Hexavalent Chromium 1.40 0.150 0.500 1 04/20/2018 18:21 WG1100785

Metals (ICP) by Method 200.7



Chromium U 1.80 10.0 1 04/20/2018 01:19 WG1099741

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 5 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 5 of 14



Calculated Results







Hexavalent Chromium U 0.150 0.500 1 04/20/2018 18:29 WG1100785




Chromium U 1.80 10.0 1 04/20/2018 01:22 WG1099741

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 6 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 6 of 14



Calculated Results







Hexavalent Chromium U 0.150 0.500 1 04/20/2018 18:38 WG1100785




Chromium U 1.80 10.0 1 04/20/2018 01:24 WG1099741

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 7 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 7 of 14



Calculated Results







Hexavalent Chromium 0.229 J 0.150 0.500 1 04/20/2018 18:46 WG1100785




Chromium U 1.80 10.0 1 04/20/2018 01:27 WG1099741

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 8 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 8 of 14

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1100785W e t C h e m i s t r y b y M e t h o d 2 1 8 . 6 M L 9 8 6 5 0 1 - 0 1 , 0 2 , 0 3 , 0 4

Method Blank (MB)

(MB) R3303612-1 04/20/18 15:37

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Hexavalent Chromium U 0.150 0.500

L985405-01 Original Sample (OS) • Duplicate (DUP)

(OS) L985405-01 04/20/18 16:19 • (DUP) R3303612-4 04/20/18 16:30

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Hexavalent Chromium 1.12 1.21 1 8.11 20

L987021-02 Original Sample (OS) • Duplicate (DUP)

(OS) L987021-02 04/20/18 20:11 • (DUP) R3303612-7 04/20/18 20:20

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Hexavalent Chromium 1.64 1.71 1 3.92 20

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3303612-2 04/20/18 15:45 • (LCSD) R3303612-3 04/20/18 15:53

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Hexavalent Chromium 2.00 2.08 2.06 104 103 90.0-110 1.10 20

L986491-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L986491-01 04/20/18 17:38 • (MS) R3303612-5 04/20/18 17:48 • (MSD) R3303612-6 04/20/18 17:57

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Hexavalent Chromium 50.0 0.261 50.7 50.9 101 101 1 90.0-110 0.430 20

L987027-01 Original Sample (OS) • Matrix Spike (MS)

(OS) L987027-01 04/20/18 20:28 • (MS) R3303612-8 04/20/18 20:36

Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier

Analyte ug/l ug/l ug/l % %

Hexavalent Chromium 50.0 ND 50.6 101 1 90.0-110

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 9 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 9 of 14

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1099741M e t a l s ( I C P ) b y M e t h o d 2 0 0 . 7 L 9 8 6 5 0 1 - 0 1 , 0 2 , 0 3 , 0 4

Method Blank (MB)

(MB) R3303327-1 04/20/18 00:17

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Chromium U 1.80 10.0

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3303327-2 04/20/18 00:20 • (LCSD) R3303327-3 04/20/18 00:22

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Chromium 1000 1010 1010 101 101 85.0-115 0.191 20


(OS) L986436-06 04/20/18 00:25 • (MS) R3303327-5 04/20/18 00:30 • (MSD) R3303327-6 04/20/18 00:32



Chromium 1000 ND 1010 1000 101 100 1 70.0-130 0.818 20


(OS) L986510-02 04/20/18 00:35 • (MS) R3303327-7 04/20/18 00:37 • (MSD) R3303327-8 04/20/18 00:40



Chromium 1000 ND 1020 1010 102 101 1 70.0-130 0.300 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 10 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 10 of 14

ONE LAB. NATIONWIDE.GLOSSARY OF TERMS

Guide to Reading and Understanding Your Laboratory Report

The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative.

Abbreviations and Definitions

MDL Method Detection Limit.

RDL Reported Detection Limit.

Rec. Recovery.

RPD Relative Percent Difference.

SDG Sample Delivery Group.

U Not detected at the Reporting Limit (or MDL where applicable).

Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported.

DilutionIf the sample matrix contains an interfering material, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.

LimitsThese are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges.

Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG.

QualifierThis column provides a letter and/or number designation that corresponds to additional information concerning the resultreported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.

Result

The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte.

Case Narrative (Cn)A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.

Quality Control Summary (Qc)

This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material.

Sample Chain of Custody (Sc)

This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis.

Sample Results (Sr)This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section foreach sample will provide the name and method number for the analysis reported.

Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates andtimes of preparation and/or analysis.

Qualifier Description

J The identification of the analyte is acceptable; the reported value is an estimate.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 11 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 11 of 14

ONE LAB. NATIONWIDE.

ESC Lab Sciences is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences.

State AccreditationsAlabama 40660 Nebraska NE-OS-15-05

Alaska 17-026 Nevada TN-03-2002-34

Arizona AZ0612 New Hampshire 2975

Arkansas 88-0469 New Jersey–NELAP TN002

California 2932 New Mexico ¹ n/a

Colorado TN00003 New York 11742

Connecticut PH-0197 North Carolina Env375

Florida E87487 North Carolina ¹ DW21704

Georgia NELAP North Carolina ³ 41

Georgia ¹ 923 North Dakota R-140

Idaho TN00003 Ohio–VAP CL0069

Illinois 200008 Oklahoma 9915

Indiana C-TN-01 Oregon TN200002

Iowa 364 Pennsylvania 68-02979

Kansas E-10277 Rhode Island LAO00356

Kentucky ¹ ⁶ 90010 South Carolina 84004

Kentucky ² 16 South Dakota n/a

Louisiana AI30792 Tennessee ¹ ⁴ 2006

Louisiana ¹ LA180010 Texas T 104704245-17-14

Maine TN0002 Texas ⁵ LAB0152

Maryland 324 Utah TN00003

Massachusetts M-TN003 Vermont VT2006

Michigan 9958 Virginia 460132

Minnesota 047-999-395 Washington C847

Mississippi TN00003 West Virginia 233

Missouri 340 Wisconsin 9980939910

Montana CERT0086 Wyoming A2LA

Third Party Federal AccreditationsA2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789

A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234

EPA–Crypto TN00003

ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable

Our LocationsESC Lab Sciences has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. ESC Lab Sciences performs all testing at our central laboratory.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc


TEKLAB, Inc. L986501 04/24/18 13:00 12 of 14


TEKLAB, Inc. L986501 04/24/18 13:39 12 of 14

http://www.esclabsciences.com/technical/accreditations

http://www.esclabsciences.com/aboutus/locations.aspx

RE: West Lake NPDES Analysis WorkOrder: 18040920semspub.epa.gov/work/07/30367908.pdf · State Dept Cert # NELAP Exp Date Lab Illinois IEPA 100226 NELAP 1/31/2019 Collinsville Kansas

Documents