R0 Shop Cleaning and Painting Procedure Tank

RUWAIS REFINERY

EXPANSION PROJECT

EPC-4 TANKAGE AND ASSOCIATED INTERCONNECTING PIPING

AGREEMENT No. 09-5578-E-4

PROJECT No. 5578 Doc. No. 5578-E4-1041-PD-MX-001 Rev. 0 Page 1/24

Daewoo Engineering & Construction - Kumho Asiana First Tower 57 Sinmunno 1-ga, Jongno-gu, Seoul 110-713, Korea

Shop Cleaning and

Painting Procedure(Tank)

AGREEMENT NO. : 09-5578-E-4 PROJECT NAME : Ruwais Refinery Expansion Project

EPC-4: Tankage & Associated Interconnecting Piping

COMPANY : Abu Dhabi Oil Refining Company (TAKREER) PMC : Mott MacDonald Ltd. CONTRACTOR : Daewoo Engineering & Construction Co., Ltd.

RUWAIS REFINERY

EXPANSION PROJECT





REVISION INDEX DETAILS

Rev Location of Change Brief Description of Change

RUWAIS REFINERY

EXPANSION PROJECT





TABLE OF CONTENTS

1.0 SCOPE .................................................................................................................................... 5

2.0 CODES AND STANDARDS………………………………………………..……………..5

3.0 SURFACE PREPARATION………………………………………………………………7

4.0 SHOP PAINTING.................................................................................................................. 8

5.0 MIXING, THINNING AND STORAGE ............................................................................. 9

6.0 SHOP TOUCH-UP REQUIREMENTS ............................................................................ 10

7.0 INSPECTION REQUIREMENTS……… ………………………………………………10

8.0 GENERAL REQUIREMENTS ..................................................................................... ….11

9.0 INSPECTION CHECK LIST………………………………………………………….…11 10.0 DOCUMENTATION / RECORDS ……………………………………………………...12

11.0 ATTACHMENT……………………………………………………………..……………13

ATTACHMENT 1. SHOP PRIMING INSTRUCTIONS

ATTACHMENT 2. LIMA WORKSHOP FACILITIES PHOTO

ATTACHMENT 3. PAINTING & TRANSPORTATION CONTROL FLOW CHART

ATTACHMENT 4. TRANSPORTATION ROUTE INFORMATION BY TANK ITEMS

ATTACHMENT 5. LAYDOWN AREA PAINTSHOP LOCATION

ATTACHMENT 6. LAYDOWN AREA AUTO BLASTING MACHINE LAYOUT ATTACHMENT 7. PAINTING SYSTEM TABLE AND VENDOR MSDS

RUWAIS REFINERY

EXPANSION PROJECT





1.0 SCOPE:

This procedure covers all necessary shop cleaning and painting activities to be performed at the

shop to support the execution of the Tankage Work. A separate Field Painting Procedure will be

developed later to all field painting activities. This procedure to comply with Company Procedure

DGS-MX-001 Painting.” This procedure shall comply with Project Technical Specifications and

their Amendments.

2.0 CODES AND STANDARDS It shall be the APPLICATOR’S responsibility to be, or to become, knowledgeable of the requirements of the

referenced codes and standards. The latest edition in force shall apply. 15 January 2008 is the effective date

for codes and standards i.e. the code or standard valid on that date shall be the one to be used.

NATIONAL ASSOCIATION OF CORROSION ENGINEERS (NACE)

RP0178 Fabrication Details, Surface Finish Requirements, and Proper Design

Considerations for Tanks and Vessels to be Lined for Immersion Service

(Except Appendix B of this standard RP0178)

RP0184 Repair of Lining Systems

RP0188 Discontinuity (Holiday) Testing of Protective Coatings

RP0287 Field Measurement of Surface Profile of Abrasive Blast Cleaned Steel Surfaces

Using a Replica Tape

RP0288 Inspection of Lining on Steel and Concrete

TM0174 Laboratory Methods for the Evaluation of Protective Coatings and Lining

Materials In Immersion Service

SSPC Steel Structures Painting Council(Volumes 1 & 2)

INTERNATIONAL ORGANIZATION FOR STANDARDIZATION (ISO)

ISO 2409 Paints and Varnishes – Cross-cut test for adhesion

ISO 2808 Paints and Varnishes – Determination of film thickness

RUWAIS REFINERY

EXPANSION PROJECT





ISO 4624 Paints and Varnishes – Pull-off test for adhesion

ISO 4628-2 Paints and Varnishes – Evaluation of degradation of paint coatings

- Designation of intensity, quantity and size of common types of defect

- Part 2: Designation of degree of blistering

ISO 4628-3 Paints and Varnishes – Evaluation of degradation of paint coatings –

Designation of intensity, quantity and size of common types of defect

- Part 3: Designation of degree of rusting



- Part 4: Designation of degree of cracking



- Part 5: Designation of degree of flaking



- Part 6: Rating of degree of chalking by tape method

SO 8501-1 Preparation of steel substrates before application of paints and related products

-Visual assessment of surface cleanliness

- Part 1: Rust grades and preparation grades of uncoated steel substrates and

steel substrates after overall removal of previous coatings

ISO 8502-1 Preparation of steel substrates before application of paints and related products

-Tests for the assessment of surface cleanliness

- Part 1: Field test for soluble iron corrosion products



- Part 2: Laboratory determination of chloride on cleaned surfaces

RUWAIS REFINERY

EXPANSION PROJECT







- Part 3: Assessment of dust on steel surfaces prepared for painting

(pressure-sensitive tape method)



- Part 4: Guidance on the estimation of the probability of condensation prior

to paint application

ISO 8503-2 Preparation of steel substrates before application of paints and related products-

rface roughness characteristics of blast cleaned steel substrates

- Part 2: Method for the grading of surface profile of abrasive

blast-cleaned steel-Comparator procedure


rface preparation methods

- Part 2: Abrasive blast-cleaning


rface preparation methods

- Part 3: Hand and power tool cleaning

3.0 SURFACE PREPARATION

Prior blasting cleaning, visible grease and oil shall be removed by solvent cleaning or solvent free

alkaline cleaner based on emulsifiers solution, ref. SSPC SP-1. After being dried, the washed surface

shall be tested for presence of residual oil and grease using water droplets.

QC-Department-05

Cross-Out

QC-Department-05

Replacement Text

surface

QC-Department-05

Cross-Out

QC-Department-05

Replacement Text

surface

QC-Department-05

Cross-Out

QC-Department-05

Replacement Text

surface

RUWAIS REFINERY

EXPANSION PROJECT





3.1 External carbon steel blast cleaning to Sa2 1/2 shall be followed and on the interior carbon steel

components Sa3 blast cleaning shall be followed. Sa3 standard shall also be achieved on the

underside surfaces of Tank bottoms. Blast media shall be Steel Shot S230(+/- 80%) & G-50(+/-

20%). The blasting abrasive working mix must be capable of producing a 50-75μ uniform anchor

profile or as specified by the coating manufacturer for the relevant paint material to be applied. The

anchor profile shall be verified, in accordance with ISO 8503 using course extra course replica tape

and a spring loaded micrometer.

3.2 Abrasive blasted surfaces shall be either air blown with clean, dry air, or brushed cleaned before

priming. The substrate shall be inspected for the presence of visible dust or contamination, either of

which is unacceptable, and re-blown or re-cleaned as necessary.

3.3 Care shall be taken to prevent rusting and/or contamination of cleaned surfaces. Cleaned surfaces

shall be primed within 4 hours of blasting is done and before detrimental corrosion or

recontamination occurs. If rust forms, the surface shall be re-blast cleaned before priming. Abrasive

blasting shall not be performed when the ambient or the substrate temperatures are less than 3 deg. C.

above the dew point.

3.4 Surface preparation shall be carried out utilizing automatic surface preparation equipment. Areas that

can not be properly prepared by the automatic blast equipment shall be abrasive blasted manually

utilizing conventional blasting equipment.

3.5 For shop surface preparation requirements, work this procedure in conjunction with shop Plate Sheet.

4.0 SHOP PAINTING

4.1 For SHOP painting requirements, work this procedure in conjunction with shop Prime-Sheet and

Paints suppliers product data sheets..

4.2 Prior to coating weld margins are to be masked and or protected from coating. Weld margins are to

be ±50㎜ wide on either side of weld area. Weld through weldable inorganic zinc primers need not

to be masked / protected.

RUWAIS REFINERY

EXPANSION PROJECT





4.3 Priming will be carried out in generic formats:

1) Blast Sa2.5 and 25 microns zinc primer(outer shell and fixed roof externals).

2) Blast Sa3 and 25 microns zinc primer(inner shell, floating roof externals and fixed roof internals).

3) Blast Sa2.5 with 75 microns inorganic zinc(pontoon internals).

4) Blast Sa3 and 2 × 200 microns Glass Flake Epoxy(underside bottom plates).

4.4 Glass Flake Epoxy on Bottom Plate Underside

1) All surfaces should be clean and free from contamination. The surface should be assessed and

treated in accordance with ISO 8504.

2) Cleanliness: Power tool cleaning to min. St 2, mill scale free (ISO 8501-1:2007). Improved surface

treatment (blast cleaning to Sa 2½) will improve the performance. In case of hydro jetting the

flash rust degree shall not exceed moderate in SSPC and NACE standards for water prepared

surfaces.

3) Shopprimed steel

Clean, dry and undamaged approved shopprimer.

4) Coated surfaces

Clean, dry and undamaged compatible primer. Power tool cleaning to min. St 2 for rusted areas

5) Steel where blast cleaning may not be possible and on hydro jetted surfaces still being moist where

gloss and color retention is of minor importance.

5.0 MIXING, THINNING AND STORAGE

5.1 All containers of coating material shall remain unopened until required for use and shall be stored

under cover.

5.2 Coating material which has jelled or otherwise deteriorated during storage shall not be used.

5.3 All material shall be thoroughly mixed before use to a smooth and uniform consistency.

Mechanical agitation during application of inorganic zinc primers shall be sufficient to keep

pigment in solution.

RUWAIS REFINERY

EXPANSION PROJECT





5.4 Coating material shall be mixed in the original container and shall not be transferred until all settled

pigment is mixed in the vehicle. This does not imply that part of the vehicle may not be poured off

into another container to simplify the mixing.

5.5 Material, which does not have a limited pit life, or does not deteriorate on standing, shall be mixed

or re-mixed immediately before using but, if setting has occurred it shall be re-mixed before using.

Coating material shall not remain in spray pots or open buckets overnight, but shall be gathered

into a closed container or bucket and re-mixed before use.

5.6 Material Pot and shell life’s shall be adhered to all the times.

5.7 Mixing shall be performed in a well ventilated, clean and dust-free environment. All mixing shall

be performed by mechanical means. The mixing appliances shall be cleaned.

6.0 SHOP TOUCH-UP REQUIREMENTS

6.1 Abnormal or excessive runs and sags shall be abrasive paper cleaned until smooth and touched-up as

per each Plate-Sheet.

6.2 For touch-up or repair of localized damaged paint or to areas of incorrectly applied paint.

6.3 When applying the initial coat of paint to corners, edges or other irregular surfaces after spray

application and shall be done painting of stripe coats and touch-up paint.

6.4 Local damages during loading and unloading of tank steel plate shall be repaired as per company

Job specification (DGS-MX-001).

7.0 INSPECTION REQUIREMENTS

7.1 Surface preparation shall be checked visually using pictorial standards ISO 8501-1-1998.

7.2 Surface profile shall be Verified in accordance with ASTM D4417 method C or ISO 8503 using

course or extra course replica tape and a spring loaded micrometer.

7.3 A calibrated Elcometer or Microtest DFT Gauge shall be used to check the DFT for each coat of

paint applied, to insure the required DFT is achieved. If an area is found to be under the required

thickness, additional readings shall be taken, as needed to determine the area coated surface which

is under the specified thickness. The final DFT check shall be in accordance with SSPC PA-2.

QC-Department-05

Cross-Out

QC-Department-05

Replacement Text

pot

QC-Department-05

Cross-Out

QC-Department-05

Replacement Text

shelf

QC-Department-05

Cross-Out

QC-Department-05

Replacement Text

design general specification

RUWAIS REFINERY

EXPANSION PROJECT





7.4 A Daily Shop Blasting/Painting Inspection Report shall be completed each day that blasting and

painting operations occur.

7.5 Wet film thickness shall be spit checked in random areas as initial indication of the required film

thickness.

7.6 A sling psychrometer or whirling hygrometer in conjunction with Hydrometric Tables shall be used

to measure relative humidity and dew point. Paint application shall NOT proceed unless the relative

humidity and dew point are within acceptable limits set forth by the coating manufacturer.

8.0 GENERAL REQUIREMENTS

8.1 Painting of any surfaces shall not proceed when any of the following environmental conditions exist:

1) When the surface temperature is above the paint manufacturer’s requirements.

2) When the relative humidity in the work area is greater than 85% or otherwise specified by the

coating manufacturer.

3) The surface temperature is less than 3℃(5℉) above the dew point of the air in the work area.

4) Moisture or other detrimental surface contamination is evident on the surfaces to be blasted,

primed or over coated. Detrimental surface contamination does not include ingrain stains.

8.2 Paint shall be stored per the manufacturer’s recommendations.

8.3 Application of each coat of paint shall be per the manufacturer’s recommendations.

8.4 Thinning of the paints shall be per the manufacturer’s recommendations.

8.5 Drying times between coats shall be per the manufacturer’s recommendations.

8.6 Mixing of the paints shall be per the manufacturer’s recommendations.

9.0 INSPECTION CHECK LIST

9.1 Materials

1) Verify that shelf life of the coating has not been exceeded.

2) Verify that coating and thinning materials are as specified and from the same manufacturer.

3) Verify that blasting materials are as specified.

QC-Department-05

Cross-Out

QC-Department-05

Replacement Text

spot

RUWAIS REFINERY

EXPANSION PROJECT





9.2 Equipment

1) Verify adequacy of coating, cleaning and blasting equipment, hoses, spray guns etc.

2) Verify all inspection equipment are properly calibrated.

9.3 Surface Preparation

1) Verify that oil and grease are removed prior to surface preparation.

2) Verify cleanliness and dryness of abrasive.

3) Verify the adequacy of cleaning and blasting equipment.

4) Verify ambient, substrate, dew point temperatures are appropriate.

5) Verify the anchor profile is as specified using appropriate instruments.

10.0 DOCUMENTATION / RECORDS

10.1 The APPLICATOR shall notify the CONTRACTOR of any apparent conflict between Job

Specification, the application data, the codes and standards, and any other Specification noted herein.

Resolution and/or interpretation precedence shall be obtained from the CONTRACTOR in writing

before proceeding with surface preparation or application of coatings.

10.2 APPLICATOR shall submit the type and quantity of details and documentation for CONTRACTOR'S

authorization or information as listed in the individual material requisitions and purchase orders.

10.3 Any documents for application of the paint systems in accordance with this Specification shall be

followed as per Attachment 11-1 shop prime instruction.

RUWAIS REFINERY

EXPANSION PROJECT





11.0 ATTACHMENT

ATTACHMENT 1. SHOP PRIMING INSTRUCTIONS

RUWAIS REFINERY

EXPANSION PROJECT





ATTACHMENT 2. LIMA WORKSHOP FACILITIES PHOTO

AUTOMATIC SPRAY AND DRYER MACHINE #1

AUTOMATIC SPRAY AND DRYER MACHINE #2

RUWAIS REFINERY

EXPANSION PROJECT





AUTOMATIC BLASTING MACHINE #1

AUTOMATIC BLASTING MACHINE #2

RUWAIS REFINERY

EXPANSION PROJECT





DUST COLLECTOR

LO2 TANK

RUWAIS REFINERY

EXPANSION PROJECT





LPG TANK #2

ROLLER CONVEYOR FACILITIES

RUWAIS REFINERY

EXPANSION PROJECT





STOCK YARD 30 TON OVERHEAD CRANE

WATER STORAGE TANK (CAPA. 226 TON)

RUWAIS REFINERY

EXPANSION PROJECT





WORKSHOP OVERHEAD CRANE

WORKSHOP YARD

RUWAIS REFINERY

EXPANSION PROJECT





ATTACHMENT 3.

PAINTING & TRANSPORTATION CONTROL FLOW CHART for TANK MATERIAL

RUWAIS REFINERY

EXPANSION PROJECT





ATTACHMENT 4.

TRANSPORTATION ROUTE INFORMATION BY TANK ITEMS

Shell Plate (Area 1, 2, 5)DAMMAM(CBI) To RUWAISShell Plate (Area 1, 2, 5)DAMMAM(CBI) To RUWAISShell Plate (Area 1, 2, 5)DAMMAM(CBI) To RUWAIS

RUWAIS REFINERY

EXPANSION PROJECT





ATTACHMENT 5.

RRE EPC-4 LAYDOWN AREA PAINTSHOP LOCATION

RUWAIS REFINERY

EXPANSION PROJECT





ATTACHMENT 6.

RRE EPC-4 LAYDOWN AREA AUTO BLASTING MACHINE LAYOUT

RUWAIS REFINERY

EXPANSION PROJECT





ATTACHMENT 7. PAINTING SYSTEM TABLE AND VENDOR MSDS

Identification of the preparation and of the company

SAFETY DATA SHEETJotamastic 87 GF - Comp. A

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

1.

Emergency telephonenumber

Supplier/Manufacturer

:

:

Product use Coatings: Solvent-borne.:

Label No. : 525Jotun Paints (Europe) Ltd.Stather RoadFlixborough, ScunthorpeNorth LincolnshireDN15 8RREngland

Tel: +44 17 24 40 00 00 Fax: +44 17 24 40 01 [email protected]

Jotamastic 87 GF - Comp. AProduct name and/or code :

Contact National Poison Centre via Hospital or Registered Medical Practitioner

Hazards identification

The preparation may be a skin sensitiser. It may also be a skin irritant and repeated contact may increase this effect.

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

Additional warning phrases : Contains epoxy constituents. See information supplied by the manufacturer. Thisinformation is provided by the present Safety Data Sheet.

Flammable.Irritating to eyes and skin. May cause sensitisation by skincontact.Harmful to aquatic organisms, may cause long-term adverseeffects in the aquatic environment. Irritant

2.

Composition/information on ingredientsSubstances presenting a health or environmental hazard within the meaning of the Dangerous SubstancesDirective 67/548/EEC.

CASnumber

% byweight

ECnumber

ClassificationChemical name*

reaction product: bisphenol-A-(epichlorhydrin); epoxyresin (number average molecular weight ≤ 700)

- 25068-38-6 500-033-5 10 - 25 Xi; R36/38R43N; R51/53

xylene C 1330-20-7 215-535-7 2.5 - 10 R10Xn; R20/21Xi; R38

epoxy resin (MW 700-1200) - 25036-25-3 2.5 - 10 Xi; R36/38R43

2-methylpropan-1-ol 6 78-83-1 201-148-0 2.5 - 10 R10Xi; R41, R37/38R67

benzyl alcohol - 100-51-6 202-859-9 1 - 2.5 Xn; R20/22ethylbenzene - 100-41-4 202-849-4 1 - 2.5 F; R11

Xn; R20See section 16 for the full text of the R-phrasesdeclared above

Occupational exposure limits, if available, are listed in section 8.

3.

Notes

Date of issue : Page: 1/629.06.2010.

Jotamastic 87 GF - Comp. A

If swallowed, seek medical advice immediately and show the container or label.Keep person warm and at rest. Do not induce vomiting.

Skin contact

Check for and remove any contact lenses. Immediately flush eyes with running waterfor at least 15 minutes, keeping eyelids open.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognised skin cleanser. Do NOT use solvents or thinners.

4.First-aid measures

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing isirregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.

Ingestion

Inhalation

Eye contact

:

:

:

:

First-aid measures

General In all cases of doubt, or when symptoms persist, seek medical attention. Never giveanything by mouth to an unconscious person. If unconscious, place in recoveryposition and seek medical advice.

:

Fire-fighting measures5.Recommended: alcohol-resistant foam, CO2, powders, water spray.Extinguishing media :

Recommendations : Fire will produce dense black smoke. Exposure to decomposition products maycause a health hazard. Appropriate breathing apparatus may be required.Cool closed containers exposed to fire with water. Do not release runoff from fire todrains or watercourses.

Extinguishing media not tobe used

: Do not use water jet.

Personal precautions Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.Refer to protective measures listed in sections 7 and 8. Contain and collect spillagewith non-combustible, absorbent material e.g. sand, earth, vermiculite ordiatomaceous earth and place in container for disposal according to local regulations(see section 13).

6. Accidental release measures:

:Spill Preferably clean with a detergent. Avoid using solvents.Note: see section 8 for personal protective equipment and section 13 for waste disposal.

Handling

Handling and storage7.Vapours are heavier than air and may spread along floors. Vapours may formexplosive mixtures with air. Prevent the creation of flammable or explosiveconcentrations of vapours in air and avoid vapour concentrations higher than theoccupational exposure limits.In addition, the product should only be used in areas from which all naked lights andother sources of ignition have been excluded. Electrical equipment should beprotected to the appropriate standard.To dissipate static electricity during transfer, earth drum and connect to receivingcontainer with bonding strap. Operators should wear antistatic footwear and clothingand floors should be of the conducting type.Keep container tightly closed. Keep away from heat, sparks and flame. No sparkingtools should be used.Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray ormist arising from the application of this preparation. Avoid inhalation of dust fromsanding.Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed.Put on appropriate personal protective equipment (see section 8).Never use pressure to empty. Container is not a pressure vessel.Always keep in containers made from the same material as the original one.Comply with the health and safety at work laws.

When operators, whether spraying or not, have to work inside the spray booth,ventilation is unlikely to be sufficient to control particulates and solvent vapour in allcases. In such circumstances they should wear a compressed air-fed respiratorduring the spraying process and until such time as the particulates and solventvapour concentration has fallen below the exposure limits.

:


Jotamastic 87 GF - Comp. AStorage Store in accordance with local regulations. Observe label precautions. Store in a dry,

cool and well-ventilated area. Keep away from heat and direct sunlight.Keep away from sources of ignition. Keep away from: oxidising agents, strongalkalis, strong acids.No smoking. Prevent unauthorised access. Containers that have been opened mustbe carefully resealed and kept upright to prevent leakage. Do not empty into drains.

:

Engineering measures Provide adequate ventilation. Where reasonably practicable, this should be achievedby the use of local exhaust ventilation and good general extraction. If these are notsufficient to maintain concentrations of particulates and solvent vapours below theOEL, suitable respiratory protection must be worn.

8. Exposure controls/personal protection

Skin and body

Personal protective equipmentIf workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use respiratory mask with charcoal and dust filterwhen spraying this product.(as filter combination A2-P2). In confined spaces, usecompressed-air or fresh-air respiratory equipment. When use of roller or brush,consider use of charcoalfilter.Personnel should wear antistatic clothing made of natural fibres or of high-temperature-resistant synthetic fibres.

Use safety eyewear designed to protect against splash of liquids.Eyes

Respiratory system

:

:

:

:

:

Occupational exposure limitsxylene EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed

through skin. STEL: 441 mg/m³ 15 minute(s). STEL: 100 ppm 15 minute(s). TWA: 220 mg/m³ 8 hour(s). TWA: 50 ppm 8 hour(s).

2-methylpropan-1-ol EH40/2005 WELs (United Kingdom (UK), 8/2007). STEL: 231 mg/m³ 15 minute(s). STEL: 75 ppm 15 minute(s). TWA: 154 mg/m³ 8 hour(s). TWA: 50 ppm 8 hour(s).

ethylbenzene EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbedthrough skin. STEL: 552 mg/m³ 15 minute(s). STEL: 125 ppm 15 minute(s). TWA: 100 ppm 8 hour(s). TWA: 441 mg/m³ 8 hour(s).

Wear suitable gloves.

Recommended, gloves(breakthrough time) > 8 hours: Viton, Responder, fluorrubber, nitrile rubber, 4H, TeflonMay be used, gloves(breakthrough time) 4 - 8 hours: neoprene, butyl rubberNot recommended, gloves(breakthrough time) < 1 hour: polyvinyl alcohol (PVA),PVC

Hands

For right choice of glove materials, with focus on chemical resistance and time ofpenetration, seek advice by the supplier of chemical resistant gloves.

Ingredient name

The user must check that the final choice of type of glove selected for handling thisproduct is the most appropriate and takes into account the particular conditions ofuse, as included in the user's risk assessment.

Physical and chemical properties9.Physical state

Solubility

Liquid.

Insoluble in the following materials: cold water and hot water.

Characteristic.OdourVarious colours.Colour

Flash point Closed cup: 35°C (95°F)

:::

:

:Density : 1.5 g/cm3

Explosion limits : 1.1 - 13%


Jotamastic 87 GF - Comp. A

Stability and reactivityStable under recommended storage and handling conditions (see section 7).

Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strongacids.

10.

Toxicological information11.There is no data available on the preparation itself. The preparation has been assessed following the conventionalmethod of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. Seesections 2 and 15 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result inadverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin.Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, lossof consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin,resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may causeirritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritation andchemical pneumonia.

Based on the properties of the epoxy constituent(s) and considering toxicological data on similar preparations, thispreparation may be a skin sensitiser and an irritant. It contains low molecular weight epoxy constituents which areirritating to eyes, mucous membrane and skin. Repeated skin contact may lead to irritation and to sensitisation, possiblywith cross-sensitisation to other epoxies. Skin contact with the preparation and exposure to spray mist and vapourshould be avoided.

Contains: reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight ≤ 700), epoxyresin (MW 700-1200). May produce an allergic reaction.

Ecological information12.There is no data available on the preparation itself.Do not allow to enter drains or watercourses.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 3 and 15 for details.

LogKow BCF PotentialBioaccumulative potential

Ecological information

Product/ingredient name

Product/ingredient name Aquatic half-life Photolysis Biodegradabilityreaction product: bisphenol-A-(epichlorhydrin); epoxy resin (numberaverage molecular weight ≤ 700)

- - Not readily

xylene - - Readilybenzyl alcohol - - Readily

Aquatic ecotoxicity

reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (numberaverage molecular weight ≤ 700)

- Acute EC50 1,4 mg/l Daphnia 48 hours

- Acute LC50 3,1 mg/l Fish - fatheadminnow

96 hours

xylene Mortality Acute LC50 12000 to16114 ug/L Fresh water

Fish - Bluegill- Lepomismacrochirus -1,1 g

96 hours

ethylbenzene Population Acute EC50 7,2 mg/L Algae 48 hoursIntoxication Acute EC50 2,93 mg/L Daphnia 48 hoursMortality Acute LC50 4,2 mg/L Fish 96 hours

Product/ingredient name Test SpeciesResult Exposure

Biodegradability


Jotamastic 87 GF - Comp. Areaction product: bisphenol-A-(epichlorhydrin); epoxy resin (numberaverage molecular weight ≤ 700)

>3 - high

xylene 3,12 - highbenzyl alcohol 1,1 <100 low

Disposal considerations13.Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.

08 01 11* waste paint and varnish containing organic solvents or other dangeroussubstances. If this product is mixed with other wastes, this code may no longer apply.If mixed with other wastes, the appropriate code should be assigned. For furtherinformation, contact your local waste authority.

European waste catalogue(EWC)

:

14.

International transport regulationsPaint.Proper shipping name

Packing group IIILabel

:

::

Transport information

1263UN Number :Class 3:

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure thatpersons transporting the product know what to do in the event of an accident or spillage.

Additional informationADR / RID : Tunnel restriction code: (D/E)

Hazard identification number: 30Special provisions: 640EADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable toreceptacles < 450 litre capacity).Emergency schedules (EmS): F-E, S-EMarine pollutant: No.

:IMDG

IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5(applicable to receptacles < 30 litre capacity).

Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

Regulatory information

Irritant

15.

Safety phrases S23- Do not breathe vapour / spray.S24- Avoid contact with skin.S37- Wear suitable gloves.S51- Use only in well-ventilated areas.

R10- Flammable.R36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

Hazard symbol or symbols

Risk phrases

EU regulations

:

:

:

:

: The product is classified and labelled for supply in accordance with the Directive1999/45/EC as follows:

reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number averagemolecular weight ≤ 700)epoxy resin (MW 700-1200)

Contains:


Jotamastic 87 GF - Comp. AAdditional warningphrases

: Contains epoxy constituents. See information supplied by the manufacturer. Thisinformation is provided by the present Safety Data Sheet.

Industrial use : The information contained in this safety data sheet does not constitute the user’sown assessment of workplace risks, as required by other health and safetylegislation. The provisions of the national health and safety at work regulations applyto the use of this product at work.

Other information16.

Date of issue 29.06.2010.Version

The information in this SDS is based on the present state of our knowledge and on current laws. The productis not to be used for purposes other than those specified under section 1 without first obtaining writtenhandling instructions. It is always the responsibility of the user to take all necessary steps to fulfil thedemands set out in the local rules and legislation. The information in this SDS is meant to be a description ofthe safety requirements for our product. It is not to be considered a guarantee of the product's properties.

Notice to reader

3:

CEPE Classification : 1R11- Highly flammable.R10- Flammable.R20- Harmful by inhalation.R20/21- Harmful by inhalation and in contact with skin.R20/22- Harmful by inhalation and if swallowed.R41- Risk of serious damage to eyes.R38- Irritating to skin.R36/38- Irritating to eyes and skin.R37/38- Irritating to respiratory system and skin.R43- May cause sensitisation by skin contact.R67- Vapours may cause drowsiness and dizziness.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

:Full text of R-phrasesreferred to in sections 2 and3 - United Kingdom (UK)

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006.

:

Indicates information that has changed from previously issued version.


Jotamastic 87 GF Page 1 of 4

Technical Data

Jotamastic 87 GF

Product descriptionJotamastic 87 GF is a two-pack surface tolerant, glass flake reinforced, abrasion resistant, high solids epoxy mastic coating which may be applied in high film thickness. Available with different hardeners for varying substrate temperatures, Standard (Std) and Wintergrade (WG). This product is a part of a complete system which is certified not to spread flames.

Recommended useSteel where blast cleaning may not be possible and on hydrojetted surfaces still being moist where gloss and colour retention is of minor importance. Can be used alone or in combination with various systems of primers and topcoats. Gives excellent corrosion protection both in salt and fresh water. If exposed to sunlight chalking may occur. Glass Flakes improve abrasion resistance and general wear and tear characteristics.

Film thickness and spreading rateStd Comp. B Minimum Maximum Typical

Film thickness, dry (µm) 200 350 250

Film thickness, wet (µm) 250 440 315

Theoretical spreading rate (m²/l) 4 2,3 3,2

WG Comp. B Minimum Maximum Typical



Theoretical spreading rate (m²/l) 3,5 2,3 2,8

CommentsHong Kong rules: Category of paints - Other vessel coatings; VOC 250 gms/ltr HK EPD method (Ready to use); Exempt compound - N/A; Specific gravity: 1.41 (A+B); Both VOC and Specific gravity values provided are typical values, subject to changes when different colour involved.


Physical propertiesColour Grey, Red, White

Solids (vol %)* 80 ± 2 Std Comp.B70 ± 2 WG Comp.B

Flash point Std Comp. B:35ºC ± 2 (Setaflash)WG Comp. B:31ºC ± 2 (Setaflash)

VOC 2,09 lbs/gal (250 gms/ltr) USA-EPA Method 24170 gms/ltr UK-PG6/23(97). Appendix 3

Gloss Semigloss

Gloss retention Fair

Water resistance Excellent

Abrasion resistance Excellent

Solvent resistance Good

Chemical resistance Very good

Flexibility Good

*Measured according to ISO 3233:1998 (E)

Surface preparation

All surfaces should be clean and free from contamination. The surface should be assessed and treated in accordance with ISO 8504.

Bare steelCleanliness: Power tool cleaning to min. St 2, mill scale free (ISO 8501-1:2007). Improved surface treatment (blast cleaning to Sa 2½) will improve the performance. In case of hydrojetting the flash rust degree shall not exceed moderate in SSPC and NACE standards for water prepared surfaces.

Shopprimed steelClean, dry and undamaged approved shopprimer.

Coated surfacesClean, dry and undamaged compatible primer. Contact your local Jotun office for more information. For maintenance UHPWJ to WJ2 (NACE No.5/SSPC-SP 12) or Power tool cleaning to min. St 2 for rusted areas

Other surfacesThe coating may be used on other substrates. Please contact your local Jotun office for more information.

Condition during applicationThe temperature of the substrate should be minimum +10°C (Std) (-5°C in WG) and at least 3°C above the dew point of the air, temperature and relative humidity measured in the vicinity of the substrate. Good ventilation is required in confined areas to ensure proper drying.

Hydrojetting of steel surface makes a wet surface. The surrounding air must have a relative humidity not exceeding 85 %. Before painting the surface shall not be glossy with moisture, but can have a patchy appearance.

Application methodsSpray Use airless spray

Brush Recommended for stripe coating and small areas, care must be taken to achieve the specified dry film thickness.

Roller May be used for small areas but not recommended for first primer coat, however when using roller application care must be taken to apply sufficient material in order to achieve the specified dry film thickness.


Application data Mixing ratio (volume) Std Comp. B:

6:1WG Comp. B:4:1

Mixing 6 parts Comp. A (base) to be mixed thoroughly with 1 part Jotamastic 87, Std Comp. B (curing agent). 4 parts Comp. A (base) to be mixed thoroughly with 1 part Jotamastic 87, WG Comp. B. (curing agent).

Induction time 10 minutes.

Pot life (23°C) Std Comp. B:10C: 4 hours, 23C: 2 hours, 40C: 1 hour WG Comp. B:1 hour

Thinner/Cleaner Jotun Thinner No. 17

Guiding data airless spray

Pressure at nozzle 15 MPa (150 kp/cm², 2100 psi).

Nozzle tip 0.63 - 1.09 mm (0.025-0.043")

Spray angle 40 - 80°

Filter Filters to be removed prior to spraying.

Note * The temperature of the mixture of base and curing agent is recommended to be at least 15°C, otherwise extra solvent may be required to obtain correct viscosity. * Too much solvent results in lower sag resistance and slower cure. * If extra solvent is necessary, this should be added after mixing of the two components.

Drying timeDrying times are generally related to air circulation, temperature, film thickness and number of coats, and will be affected correspondingly. The figures given in the table are typical with:* Good ventilation (Outdoor exposure or free circulation of air)* Typical film thickness* One coat on top of inert substrate

Std Comp. B

Substrate temperature 10°C 23°C 40°C

Surface dry 8 h 4 h 2 h

Through dry 24 h 10 h 4 h

Cured 14 d 7 d 2 d

Dry to recoat, minimum 24 h 10 h 4 h

Dry to recoat, maximum 1 - - -

WG Comp. B

Substrate temperature -5°C 0°C 5°C 10°C 23°C

Surface dry 24 h 18 h 12 h 6 h 2,5 h

Through dry 48 h 26 h 18 h 12 h 5 h

Cured 21 d 14 d 7 d 3 d 2 d

Dry to recoat, minimum 48 h 26 h 18 h 12 h 5 h

Dry to recoat, maximum 1

1. Provided the surface is free from chalking and other contamination prior to application, there is normally no overcoating time limit. Best intercoat adhesion occurs, however, when the subsequent coat is applied before preceding coat has cured. If the coating has been exposed to direct sunlight for some time, special attention must be paid to surface cleaning and mattening/removal of the surface layer in order to obtain good adhesion.


The given data must be considered as guidelines only. The actual drying time/times before recoating may be shorter or longer, depending on film thickness, ventilation, humidity, underlying paint system, requirement for early handling and mechanical strength etc. A complete system can be described on a system sheet, where all parameters and special conditions could be included.

Typical paint system

Jotamastic 87 GF 2 x 250 µm (Dry Film Thickness)Hardtop AS/XP 1 x 50 µm (Dry Film Thickness)

Other systems may be specified, depending on area of use

StorageThe product must be stored in accordance with national regulations. Storage conditions are to keep the containers in a dry, cool, well ventilated space and away from source of heat and ignition. Containers must be kept tightly closed.

HandlingHandle with care. Stir well before use.

Packing size16 litres Comp. A (base) in a 20 litre container and 2.7 litres Jotamastic 87, Std Comp. B (curing agent) in a 3 litre container. 16 litres Comp. A (base) in a 20 litre container and 4 litres Jotamastic 87, WG Comp. B (curing agent) in a 5 litre container.

Health and safetyPlease observe the precautionary notices displayed on the container. Use under well ventilated conditions. Do not breathe or inhale mist. Avoid skin contact. Spillage on the skin should immediately be removed with suitable cleanser, soap and water. Eyes should be well flushed with water and medical attention sought immediately.

For detailed information on the health and safety hazards and precautions for use of this product, we refer to the Material Safety Data Sheet.

DISCLAIMERThe information in this data sheet is given to the best of our knowledge based on laboratory testing and practical experience. However, as the product is often used under conditions beyond our control, we cannot guarantee anything but the quality of the product itself. We reserve the right to change the given data without notice.

Jotun is a World Wide company with factories, sales offices and stocks in more than 50 countries. For your nearest local Jotun address please contact the nearest regional office or visit our website at www.jotun.com

ISSUED 3 APRIL 2010 BY JOTUNTHIS DATA SHEET SUPERSEDES THOSE PREVIOUSLY ISSUED

Resist 86 Page 1 of 4

Technical Data

Resist 86

Product descriptionResist 86 is a two-pack, quick curing zinc rich ethyl silicate coating that complies with the compositional requirements for SSPC Paint 20 level 1 and ISO 12944. Can also be made to order with ASTM D520 Type II zinc dust.

Recommended useA general purpose, heavy duty, anti-corrosive primer: 1. As the first coat in a multiple layer system. 2. As a single coating for long term protection of steel exposed to moderately to severely corrosive environment.

Resistant to cyclic dry temperatures up to 400°C.

Film thickness and spreading rateMinimum Maximum Typical



Theoretical spreading rate (m²/l) 13,4 7,4 8,9

CommentsThere is a risk of mud-cracking if the film thickness exceeds 120µm.

Physical propertiesColour Greenish grey, Grey

Solids (vol %)* 67 ± 2

Flash point 14ºC ± 2 (Setaflash)

VOC 465 gms/ltr UK-PG6/23(97). Appendix 3

Gloss Flat

Water resistance Very good

Abrasion resistance Excellent

Solvent resistance Excellent

Chemical resistance Excellent within pH-range 6-10

Flexibility Limited

*Measured according to OCCA Monograph No. 4

Surface preparation

All surfaces should be clean, dry and free from contamination. The surface should be assessed and treated in accordance with ISO 8504.

Bare steelCleanliness: Blast cleaning to Sa 2½ (ISO 8501-1:2007). Roughness: using abrasives suitable to achieve grade Fine to Medium G (30-85 µm, Ry5) (ISO 8503-2)


Other surfacesThe coating may be used on other substrates. Please contact your local Jotun office for more information.

Condition during applicationThe temperature of the substrate should be min. 5°C and at least 3°C above the dew point of the air, temperature and relative humidity measured in the vicinity of the substrate. Zinc silicate paints in general requires moisture for curing. At low humidity the curing will be improved by gently sprinkling fresh water over the paint film, and/or by artificial humidification of the surrounding atmosphere. The paint must be completely cured before topcoating, otherwise the adhesion of the subsequent coat will be unsatisfactory. Use Methyl ethyl ketone (MEK) test according to ASTM D 4752-87 to verify the curing time before topcoating. Unweathered zinc silicate films are porous and the porosity may vary according to the weather condition during application and the application technique. When overcoating, the air in the pores will escape through the new coat of paint and may cause blisters or pinholes ("popping") in the coat just after application. To avoid this a mist coat/full coat technique is recommended: First apply a thin coat to fill the pores in the zinc silicate film and a few minutes later apply to full specified film thickness. In difficult cases it may be necessary to thin the next coat, or use Penguard Tie Coat 100 as first overcoat.

Application methodsSpray Use airless spray or conventional spray

Brush Recommended for stripe coating and small areas, care must be taken to achieve the specified dry film thickness. In order to avoid settling of heavy zinc, continuous mechanical stirring during application is recommended.

Application data Mixing ratio (volume) 8:2,6

Mixing Comp. A is a liquid and Comp. B is dry zinc dust. Consists of 8 litres Comp. A and 18.5 kg/2,6L Jotun Zinc 100, Comp B or 18.5 kg/2,6L Jotun Zinc 100 ASTM D520 Type II, Comp B. Pour the zinc dust slowly into the liquid during mechanical mixing. The Comp. A must be well shaken before use. Stir until lump free and pass through a 60 mesh sieve.

Pot life (23°C) 8-12 hours. (Reduced at higher temp.)

Thinner/Cleaner Jotun Thinner No. 4/25 Adjusting spray pattern and drying may sometimes become necessary*. Use max 5% Jotun Thinner No. 4 (fast evaporation) when temperature is low and Jotun Thinner No. 25 (slow evaporation) when temperature is high. Thinner should be added after mixing of components

Guiding data airless spray

Pressure at nozzle 10 MPa (100 kg/cm², 1400 psi)

Nozzle tip 0.46-0.58 mm (0.018-0.023")

Spray angle 30-80º

Filter Check to ensure that filters are clean.

Note *Thinner should be added after mixing components.

Drying timeDrying times are generally related to air circulation, temperature, film thickness and number of coats, and will be affected correspondingly. The figures given in the table are typical with:* Good ventilation (Outdoor exposure or free circulation of air)* Typical film thickness* One coat on top of inert substrate* Relative humidity of 70%


Substrate temperature 5°C 10°C 23°C 40°C

Surface dry 60 min 30 min 15 min 13 min

Through dry 90 min 45 min 30 min 25 min

Cured 1 18 h 13 h 4 h 1,5 h

Dry to recoat, minimum 2 18 h 13 h 4 h 1,5 h

Dry to recoat, maximum 3

1. Curing time to be verified by MEK test (ASTM D 4752-87).2. Recommended data given for recoating with coatings normally specified on top of zinc ethyl silicate coatings.3. The surface should be free of zinc salts and other contamination prior to application.

The given data must be considered as guidelines only. The actual drying time/times before recoating may be shorter or longer, depending on film thickness, ventilation, humidity, underlying paint system, requirement for early handling and mechanical strength etc. A complete system can be described on a system sheet, where all parameters and special conditions could be included.

Typical paint system

Resist 86 1 x 75 µm (Dry Film Thickness)Normally overcoated with an epoxy system.

Other systems may be specified, depending on area of use

StorageThe product must be stored in accordance with national regulations. Storage conditions are to keep the containers in a dry, cool, well ventilated space and away from source of heat and ignition. Containers must be kept tightly closed. The component A must be stored below 25°C. The product component B is zinc dust and has no strict limitation's for storage. SHELF LIFE: 6 months at 23°C for Comp. A. , 4 years for comp. B, subject to re-inspection thereafter. Higher temperatures during storage may reduce the shelf life and may lead to gelling in the tin.

HandlingHandle with care. Stir well before use. Continuous stirring during application will prevent the heavy zinc pigment from settling.

Packing size10,6 litres unit: 8 litres Resist 86 Comp A in a 10 litre container and 18,5 kg/2,6 litres Jotun Zinc 100, Comp B (previously named Resist 78/86, Comp B) in a 20 litre container or 10,6 litres unit: 8 litres Resist 86 Comp A in a 10 litre container and 18,5 kg/2,6 litres Jotun Zinc 100 ASTM D520 Type II, Comp B (previously named Resist 86 ASTM D520 Type II, Comp B) in a 20 litre container.

Health and safetyPlease observe the precautionary notices displayed on the container. Use under well ventilated conditions. Do not breathe or inhale mist. Avoid skin contact. Spillage on the skin should immediately be removed with suitable cleanser, soap and water. Eyes should be well flushed with water and medical attention sought immediately.

For detailed information on the health and safety hazards and precautions for use of this product, we refer to the Material Safety Data Sheet.

DISCLAIMERThe information in this data sheet is given to the best of our knowledge based on laboratory testing and practical experience. However, as the product is often used under conditions beyond our control, we cannot guarantee anything but the quality of the product itself. We reserve the right to change the given data without notice.

Jotun is a World Wide company with factories, sales offices and stocks in more than 50 countries. For your nearest local Jotun address please contact the nearest regional office or visit our website at www.jotun.com


ISSUED 18 SEPTEMBER 2009 BY JOTUNTHIS DATA SHEET SUPERSEDES THOSE PREVIOUSLY ISSUED

Identification of the preparation and of the company

SAFETY DATA SHEETResist 86 - Comp. A

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

1.

Emergency telephonenumber

Supplier/Manufacturer

:

:

Product use Coatings: Solvent-borne.:

Label No. : 684

Jotun Paints (Europe) Ltd.Stather RoadFlixborough, ScunthorpeNorth LincolnshireDN15 8RREngland

Tel: +44 17 24 40 00 00 Fax: +44 17 24 40 01 [email protected]

Resist 86 - Comp. AProduct name and/or code :

Contact National Poison Centre via Hospital or Registered Medical Practitioner

Hazards identificationThe product is classified as dangerous according to Directive 1999/45/EC and its amendments.

Highly flammable.

Highly flammable

2.

Composition/information on ingredientsSubstances presenting a health or environmental hazard within the meaning of the Dangerous SubstancesDirective 67/548/EEC.

CASnumber

% byweight

ECnumber

ClassificationChemical name*

ethanol - 64-17-5 200-578-6 25 - 50 F; R111-methoxy-2-propanol - 107-98-2 203-539-1 10 - 25 R10

R672-butoxyethanol - 111-76-2 203-905-0 2.5 - 10 Xn; R20/21/22

Xi; R36/38tetraethyl silicate - 78-10-4 201-083-8 2.5 - 10 R10

Xn; R20Xi; R36/37

See section 16 for the full text of the R-phrasesdeclared above

Occupational exposure limits, if available, are listed in section 8.

3.

Notes

Skin contact Remove contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognised skin cleanser. Do NOT use solvents or thinners.

4.First-aid measures

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing isirregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.

Inhalation :

:

First-aid measures

General In all cases of doubt, or when symptoms persist, seek medical attention. Never giveanything by mouth to an unconscious person. If unconscious, place in recoveryposition and seek medical advice.

:


Resist 86 - Comp. A

If swallowed, seek medical advice immediately and show the container or label.Keep person warm and at rest. Do not induce vomiting.

Check for and remove any contact lenses. Immediately flush eyes with running waterfor at least 15 minutes, keeping eyelids open.

Ingestion

Eye contact

:

:

Fire-fighting measures5.Recommended: alcohol-resistant foam, CO2, powders, water spray.Extinguishing media :

Recommendations : Fire will produce dense black smoke. Exposure to decomposition products maycause a health hazard. Appropriate breathing apparatus may be required.Cool closed containers exposed to fire with water. Do not release runoff from fire todrains or watercourses.

Extinguishing media not tobe used

: Do not use water jet.

Personal precautions Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.Refer to protective measures listed in sections 7 and 8. Contain and collect spillagewith non-combustible, absorbent material e.g. sand, earth, vermiculite ordiatomaceous earth and place in container for disposal according to local regulations(see section 13).

6. Accidental release measures:

:Spill Preferably clean with a detergent. Avoid using solvents.

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

Handling

Handling and storage

Storage

7.Vapours are heavier than air and may spread along floors. Vapours may formexplosive mixtures with air. Prevent the creation of flammable or explosiveconcentrations of vapours in air and avoid vapour concentrations higher than theoccupational exposure limits.In addition, the product should only be used in areas from which all naked lights andother sources of ignition have been excluded. Electrical equipment should beprotected to the appropriate standard.To dissipate static electricity during transfer, earth drum and connect to receivingcontainer with bonding strap. Operators should wear antistatic footwear and clothingand floors should be of the conducting type.Keep container tightly closed. Keep away from heat, sparks and flame. No sparkingtools should be used.Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray ormist arising from the application of this preparation. Avoid inhalation of dust fromsanding.Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed.Put on appropriate personal protective equipment (see section 8).Never use pressure to empty. Container is not a pressure vessel.Always keep in containers made from the same material as the original one.Comply with the health and safety at work laws.

When operators, whether spraying or not, have to work inside the spray booth,ventilation is unlikely to be sufficient to control particulates and solvent vapour in allcases. In such circumstances they should wear a compressed air-fed respiratorduring the spraying process and until such time as the particulates and solventvapour concentration has fallen below the exposure limits.

Store in accordance with local regulations. Observe label precautions. Store in a dry,cool and well-ventilated area. Keep away from heat and direct sunlight.Keep away from sources of ignition. Keep away from: oxidising agents, strongalkalis, strong acids.No smoking. Prevent unauthorised access. Containers that have been opened mustbe carefully resealed and kept upright to prevent leakage. Do not empty into drains.

:

:


Resist 86 - Comp. A

Engineering measures Provide adequate ventilation. Where reasonably practicable, this should be achievedby the use of local exhaust ventilation and good general extraction. If these are notsufficient to maintain concentrations of particulates and solvent vapours below theOEL, suitable respiratory protection must be worn.

8. Exposure controls/personal protection

Skin and body

Personal protective equipmentIf workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use respiratory mask with charcoal and dust filterwhen spraying this product.(as filter combination A2-P2). In confined spaces, usecompressed-air or fresh-air respiratory equipment. When use of roller or brush,consider use of charcoalfilter.

Personnel should wear antistatic clothing made of natural fibres or of high-temperature-resistant synthetic fibres.

Use safety eyewear designed to protect against splash of liquids.Eyes

Respiratory system

:

:

:

:

:

Occupational exposure limitsethanol EH40/2005 WELs (United Kingdom (UK), 8/2007).

TWA: 1920 mg/m³ 8 hour(s). TWA: 1000 ppm 8 hour(s).

1-methoxy-2-propanol EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbedthrough skin. STEL: 560 mg/m³ 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 375 mg/m³ 8 hour(s). TWA: 100 ppm 8 hour(s).

2-butoxyethanol EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbedthrough skin. STEL: 50 ppm 15 minute(s). TWA: 25 ppm 8 hour(s).

Wear suitable gloves.

May be used, gloves(breakthrough time) 4 - 8 hours: Teflon, PE, nitrile rubber,neopreneNot recommended, gloves(breakthrough time) < 1 hour: polyvinyl alcohol (PVA),PVCRecommended, gloves(breakthrough time) > 8 hours: butyl rubber, Viton, Saranex,4H

Hands

For right choice of glove materials, with focus on chemical resistance and time ofpenetration, seek advice by the supplier of chemical resistant gloves.

Ingredient name

The user must check that the final choice of type of glove selected for handling thisproduct is the most appropriate and takes into account the particular conditions ofuse, as included in the user's risk assessment.

Physical and chemical properties9.Physical state

Solubility

Liquid.

Insoluble in the following materials: cold water and hot water.

Characteristic.OdourVarious colours.Colour

Flash point Closed cup: 14°C (57,2°F)

:::

:

:Density : 1.09 g/cm3

Explosion limits : 1.1 - 19%

Stability and reactivityStable under recommended storage and handling conditions (see section 7).

Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strongacids.

10.


Resist 86 - Comp. A

Toxicological information11.There is no data available on the preparation itself. The preparation has been assessed following the conventionalmethod of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. Seesections 2 and 15 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result inadverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin.Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, lossof consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin,resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may causeirritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritation andchemical pneumonia.

Ecological information12.There is no data available on the preparation itself.Do not allow to enter drains or watercourses.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive1999/45/EC and is not classified as dangerous for the environment.

Disposal considerations13.Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.

08 01 11* waste paint and varnish containing organic solvents or other dangeroussubstances. If this product is mixed with other wastes, this code may no longer apply.If mixed with other wastes, the appropriate code should be assigned. For furtherinformation, contact your local waste authority.

European waste catalogue(EWC)

:

14.

International transport regulationsPaintProper shipping name

Packing group II

Label

:

::

Transport information

1263UN Number :Class 3:

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure thatpersons transporting the product know what to do in the event of an accident or spillage.

Additional informationADR / RID : Tunnel restriction code: (D/E)

Hazard identification number: 33Special provisions: 640D

Emergency schedules (EmS): F-E, S-EMarine pollutant: No.

:IMDG

Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

Regulatory information

Highly flammable

15.

Hazard symbol or symbols

EU regulations

:

: The product is classified and labelled for supply in accordance with the Directive1999/45/EC as follows:


Resist 86 - Comp. A

Safety phrases S23- Do not breathe vapour / spray.

R11- Highly flammable.Risk phrases::

Industrial use : The information contained in this safety data sheet does not constitute the user’sown assessment of workplace risks, as required by other health and safetylegislation. The provisions of the national health and safety at work regulations applyto the use of this product at work.

Other information16.

Date of issue 29.06.2010.Version

The information in this SDS is based on the present state of our knowledge and on current laws. The productis not to be used for purposes other than those specified under section 1 without first obtaining writtenhandling instructions. It is always the responsibility of the user to take all necessary steps to fulfil thedemands set out in the local rules and legislation. The information in this SDS is meant to be a description ofthe safety requirements for our product. It is not to be considered a guarantee of the product's properties.

Notice to reader

1.02:

CEPE Classification : 1

R11- Highly flammable.R10- Flammable.R20- Harmful by inhalation.R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.R36/37- Irritating to eyes and respiratory system.R36/38- Irritating to eyes and skin.R67- Vapours may cause drowsiness and dizziness.

:Full text of R-phrasesreferred to in sections 2 and3 - United Kingdom (UK)

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006.

:

Indicates information that has changed from previously issued version.


R0 Shop Cleaning and Painting Procedure Tank

Documents