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Putting Electrons to Work Doping and Semiconductor Devices
33

Putting Electrons to Work Doping and Semiconductor Devices.

Dec 22, 2015

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Page 1: Putting Electrons to Work Doping and Semiconductor Devices.

Putting Electrons to Work

Doping and Semiconductor Devices

Page 2: Putting Electrons to Work Doping and Semiconductor Devices.

What Have We Learned About Magnetic Storage?

• Two domains magnetized in same direction is a 0• Two domains magnetized in opposite directions is

a 1• Direction of magnetization changes at start of new

bit.• Magnetic data is written by running a current

through a loop of wire near the disk• As magnetic data passes by coil of wire, changing

field induces currents according to Faraday’s Law:

dt

dBA

dt

diR B

Page 3: Putting Electrons to Work Doping and Semiconductor Devices.

What Have We Learned About Magnetoresistance?

• Charges traveling through magnetic field experience magnetic force (provided velocity and field are not aligned):

FB = qv x B• In a current-carrying wire, this force results in more

frequent collisions and thus an increased resistance: Magnetoresistance

• Electrons traveling through magnetized material undergo spin-dependent scattering

• When magnetic field is present in magnetic superlattice, scattering of electrons is cut dramatically, greatly decreasing resistance: Giant magnetoresistanced

Page 4: Putting Electrons to Work Doping and Semiconductor Devices.

What Have We Learned About Atoms?

• ENERGY IS QUANTIZED

• Electrons can absorb energy and move to a higher level; they can emit light and move to a lower level

• In hydrogen the emitted light will have energy

E = (13.6 ev)(1/nf2 – 1/ ni

2)

• The wavelength is given by = hc/E = 1240(nm eV)/E

• Energy levels of nearby atoms are slightly shifted from each other, producing bands of allowed energies

• Electrons move from the locality of one atom to the next only if an energy state is available within the same band

Page 5: Putting Electrons to Work Doping and Semiconductor Devices.

What have we learned about Resistance?

• In many, ohmic, materials, current is proportional to voltage:

V = iR• Resistance is proportional to the length of an

object and inversely proportional to cross-sectional area:

R = L/A• The constant of proportionality here is called the

resistivity. It is a function of material and temperature.

Page 6: Putting Electrons to Work Doping and Semiconductor Devices.

dnevi

m

eEvd

m

ne

2

/1

Page 7: Putting Electrons to Work Doping and Semiconductor Devices.

A Good Analogy to Remember

Page 8: Putting Electrons to Work Doping and Semiconductor Devices.

What Have We Learned About Solids?

• In conductors, the valence band is only partially-full, so electrons can easily move

• In semiconductors and insulators, the valence band is completely full, so electrons must gain extra energy to move– semiconductors have smaller band gap, insulators have larger band

gap

• Conductors have a partially-filled valence band– The primary effect of higher temperature on resistance is to increase

R due to more collisions at higher temperatures

• Semiconductors have a completely-filled valence band– The primary effect of temperature on resistance is due to this

requirement: the higher the temperature, the more conduction electrons

Page 9: Putting Electrons to Work Doping and Semiconductor Devices.

Crystal (Perfect)

Page 10: Putting Electrons to Work Doping and Semiconductor Devices.

Crystal (Excited)

Page 11: Putting Electrons to Work Doping and Semiconductor Devices.

Crystal (Excited)

Page 12: Putting Electrons to Work Doping and Semiconductor Devices.

Band Gap

Valence Band

Conduction Band

Band Gap Energy Eg

(Minimum Energy needed tobreak the chemical bonds)

Energy

Position

Page 13: Putting Electrons to Work Doping and Semiconductor Devices.

Band Gap

Valence Band

Conduction Band

Energy

Position

photon in h Eg

Page 14: Putting Electrons to Work Doping and Semiconductor Devices.

Band Gap

Valence Band

Conduction Band

Energy

Position

photon out

Page 15: Putting Electrons to Work Doping and Semiconductor Devices.

Band Gap

Valence Band

Conduction Band

Energy

Position

photon out

Page 16: Putting Electrons to Work Doping and Semiconductor Devices.

Crystal (Doped n-type)

+5 +5Plus a little energy,

d.

Page 17: Putting Electrons to Work Doping and Semiconductor Devices.

Crystal (Doped p-type)

+3

Page 18: Putting Electrons to Work Doping and Semiconductor Devices.

N-type semiconductors

• N-type semiconductor is doped with a material having extra valance electrons

• Result is filled energy states in the band gap just below the conduction band

• These electrons can easily gain energy to jump to the conduction band and move through the material

Page 19: Putting Electrons to Work Doping and Semiconductor Devices.

Crystal (Doped p-type)

+3

Page 20: Putting Electrons to Work Doping and Semiconductor Devices.

P-type semiconductors

• P-type semiconductor is doped with a material having fewer valance electrons

• Result is “holes”, or empty energy states in the band gap just above the valance band

• Since no single electron travels through the material, we describe the charge carrier as a positive hole moving the other way

Page 21: Putting Electrons to Work Doping and Semiconductor Devices.

Doped Semiconductors

Energy

n-type p-type

donor level

acceptor level

•Put them together?

Page 22: Putting Electrons to Work Doping and Semiconductor Devices.

p-n junction

n-type

p-type

Energy

depleted region(electric field)

+ + + + + ++

+

--------

Page 23: Putting Electrons to Work Doping and Semiconductor Devices.

P-n junction• As more electrons from the n-side combine with holes from the

p-side, each additional combination adds to the potential difference across junction

• This can be envisioned as shifting the energy bands, making it harder for electrons to travel across the barrier

Page 24: Putting Electrons to Work Doping and Semiconductor Devices.

p-n junction

n-type

p-type

Energy

depleted region(electric field)

+ + + + + ++

+

--------

Vo

Page 25: Putting Electrons to Work Doping and Semiconductor Devices.

What happens if a bias is applied?

Page 26: Putting Electrons to Work Doping and Semiconductor Devices.

Biased junction

n-type

p-type

depleted region(electric field)

Negativebias

positivebias

Page 27: Putting Electrons to Work Doping and Semiconductor Devices.

Biased junction

n-type

p-type

depleted region(electric field)

Negativebias

photon out

Page 28: Putting Electrons to Work Doping and Semiconductor Devices.

P-n junction

• Originally both p and n sides are electrically neutral

• Electrons in n side see holes in p side and combine

Second electron needs add’l energy to get over charge barrier – can represent as rise in energy levels of p section

Page 29: Putting Electrons to Work Doping and Semiconductor Devices.

Forward Biasing

• Eventually, the potential difference is so large, electrons cannot travel across it without gaining energy

• Applying a forward bias decreases the potential difference so current can flow

Page 30: Putting Electrons to Work Doping and Semiconductor Devices.

Reverse Biasing

• Applying a reverse bias will increase the barrier rather than decreasing it, so no current flows

Page 31: Putting Electrons to Work Doping and Semiconductor Devices.

Light-emitting Diode

• When an electron loses energy to recombine with a hole, it can emit that lost energy in the form of light.

• This light always has roughly same E, so LEDs emit small range of wavelengths

This light-emitting property of p-n junctions can be utilized to create a laser

Be sure to come to class to hear Dr. Schowalter say . . .

Page 32: Putting Electrons to Work Doping and Semiconductor Devices.

Do Today’s Activity

• How is an incandescent light bulb different from an LED?

• What is the difference between the different colors of LED?

• Why might these differences occur?

Page 33: Putting Electrons to Work Doping and Semiconductor Devices.

Before the next class, . . .

• Finish Homework 16

• Do Activity 15 Evaluation by Midnight Monday

• Read Chapter 6 in Turton.