Proposed Nutrient Criteria for Drinking Water Lakes and Reservoirs in NY State Cliff Callinan, P.E. & Ron Entringer, P.E.; NYSDEC John Hassett, Ph.D., SUNY ESF Jim Hyde, NYSDOH 2013 NYC Watershed/Tifft Science & Technical Symposium CWA NYWEA SDWA NYSAWWA
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Proposed Nutrient Criteria for Drinking Water Lakes and Reservoirs in NY State
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Proposed Nutrient Criteria for Drinking Water Lakes and Reservoirs in NY State
Allochthonous v. Autochthonous• Source Water Protection Perspective Allochthonous largely beyond our control Autochthonous amenable to control via nutrient
management (i.e., NNC)• Water Treatment Perspective Allochthonous easier to remove Autochthonous hard to remove
1219 September, 2013 Callinan - 2013 Watershed/TifftFrom: Sadiq et al. (2004)
“A major challenge for water suppliers is how to balance the risks from microbial pathogens and disinfection byproducts. It is important to provide protection from microbial pathogens while simultaneously minimizing health risks to the population from disinfection byproducts.”From: http://water.epa.gov/lawsregs/rulesregs/sdwa/mdbp/index.cfm
• Very good relationship observed between total phosphorus (causal variable) and chlorophyll a (response variable) - r2 ~ 0.85 Generally consistent with (NY) statewide
findings as well as other investigators Supports the hypothesis that phosphorus
controls algae growth within these systems during the growing season
Where to Draw the Line & Verification ?• THMFP is a “worst case” scenario
• How to compare THMFP results to real world TTHMs• Employ off-the-shelf, peer-reviewed model THM = f (DOC, time, dose, pH, temperature) Run 1: Verify using SMs: Observed v. Model Run 2: Use “typical” albeit conservative PWS
conditions & TTHM MCL, Solve DOCcrit.
Use DOCcrit. to solve for THMFPcrit. Use THMFPcrit. to solve for [Chl-a] threshold
• Verification: (1) Ground-truth w/ Real World Cases & (2) Corroboration from Independent Studies
Initial Cyanotoxin Findings• Caveats: (1) No U.S. CB toxin criteria – defer to WHO
D.W. G.V. for MC-LR of 1 ug/l; (2) Additional NY Studies ongoing, but not yet fully analyzed
• Preliminary findings suggest nutrient thresholds for the control of cyanobacteria and associated toxins is somewhat higher than thresholds for DBPs. Findings also consistent w/ others (e.g., Downing, et al. 2001)
• Thus, it would appear that the thresholds derived for DBPs would also be protective for cyanobacteria and associated toxins.
Initial Arsenic Findings• Results indicate arsenic levels can become
elevated in hypolimnetic waters of some eutrophic lakes and reservoirs in New York during growing season
• In general, it appears that arsenic is originating from natural sources, however, its enrichment in hypolimnion is likely due to DO depletion (in part due to cultural eutrophication), and reductive release.