Programming Data for Hach

Programming data for Spectroquant® Test Kits for DR 5000 and DR 6000 photometer

from Hach, Hach-Lange

Date: January 15, 2013 1 of 49

General information for DR 5000 and DR 6000 when using Spectroquant® Test kits from Merck. Wavelength specification of the instrument: 190 to 1100 nm Photometric range: ± 3.0 A Standard cells which can be used: 16 mm (only US version), 13 mm (only European version), check your instrument before ordering the cell tests 10, 50 mm, 1-inch round and 1-inch rectangular cells (use the sample cell adapters coming with the instrument) Important: All Merck Spectroquant® cell tests have a diameter of 16 mm and can only be used in the DR 5000 and DR 6000 US-version. Our Spectroquant® round

tubes 16 mm are not applicable for the 13 mm diameter tubes from the DR 5000 and DR 6000 European version because of the 13 mm shaft. All our Spectroquant® reagent test kits using the 10, 20 and 50 mm cells can be measured with all DR 5000 instruments. The programming data can be found in the following list.

Information about Spectroquant® test kits: In our Internet homepage www.analytical-test-kits.com users can find all information about our test kits. All package inserts as well as the manuals from e.g. our Pharo spectrophotometers can be found there. This information helps to get a quick overview about the easy handling of our test kits. The package inserts include detailed descriptions about all handling steps, colour reaction, sample preparation if required, interference with other substances, analytical quality assurance data and more. Zeroing the instrument: Before measuring the sample users must enter the “Zero” value for each range. In the below enclosed programming tables it is mentioned for each parameter and measuring range, what “Zero” value is necessary. You can choose between the following options:

1) Own blank (= distilled water and reagents) 2) Cell with blank (white screw cap) 3) Distilled water 4) Clear sample without reagents

The advantages of Spectroquant® Tests kits are, that in some cases users can run as “Zero” distilled water or use the cell with blank (white screw cap) an therefore need not to waste always on determination. This makes live easier and reduce costs. The zero should be entered when the instruments request “Zero”. Message “Under range!” after zeroing the instrument: The instrument must be zeroed for each test or series of tests to establish a zero reference for the measurement. This is done by placing a zero solution (distilled water and reagents) in the cell holder and pressing ZERO. While entering a value of e.g. “25” for the low limit - and not “0” (like Hach) - the message “Under range!” appears in the display. This message doesn’t influence the results. Just go forward with the measurement. If you implement “0” for the low limit this message will not appear (identical as if you use an “original” Hach program). Please contact our local Merck companies or Merck agents for any questions or use the contact form in our internet homepage. No endorsement by Hach Company is implied or intended.

http://www.merckmillipore.com/photometry




Merck order no. 1.01758* 1.01758* 1.01762 1.00594.0001* 1.14825.0001 1.14825.0001 1.14825.0001

replaced by 1.01758

Program name Acid capacity01758

Acid capacity01758

Aluminium00594 Aluminium14825 Aluminium14825 Aluminium14825

Unit mmol/l mg/l mg/l mg/l mg/l mg/l

Wavelength 605 nm 605 nm 550 nm 550 nm 550 nm 550 nm

Resolution 0.01 1 0.01 0.01 0.001 0.001

Chemical Form 1 OH CaCO3 Al Al Al Al

Calibration “a” -10,074 -503,7 -0.253 -0.165 -0.0649 -0.033

Calibration “b” 30,24 1512 1.023 0.9585 0.37735 0.1917

Calibration “c” -23,081 -1154,1 -0.599 -0.3233 -0.12728 -0.06466

Calibration “d” 10,358 517,9 0.187 0.0719 0.02829 0.01437

Upper limit 8.00 400 0.50 1.20 0.472 0.240

Lower limit 0.40 20 0.02 0.10 0.039 0.020

Timer 1 (mm:ss) ----- ----- 05:00 02:00 02:00 02:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- -----

Additional Merck information

3) 3) 3) 3) 3) 3)

Cell size used 16 mm round 16 mm round 16 mm round 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14739.0001* 1.14558.0001* 1.14544.0001* 1.14559.0001* 1.14739.0001* 1.14558.0001* 1.14544.0001* 1.14559.0001*

Program name Ammonium14739 Ammonium14558 Ammonium14544 Ammonium14559 Ammonium14739 Ammonium14558 Ammonium14544 Ammonium14559

Unit mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l

Wavelength 690 nm 690 nm 690 nm 690 nm 690 nm 690 nm 690 nm 690 nm

Resolution 0.001 0.01 0.1 0.1 0.001 0.01 0.1 0.1

Chemical Form 1 NH4-N NH4-N NH4-N NH4-N NH4+ NH4

+ NH4+ NH4

+

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 0.877 4.26 7.84 36.4 1.13 5.49 10.1 46.8

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 2.000 8.00 16.0 80.0 2.576 10.30 20.6 103.0

Lower limit 0.010 0.20 0.5 4.0 0.013 0.26 0.6 5.2

Timer 1 (mm:ss) 15:00 15:00 15:00 15:00 15:00 15:00 15:00 15:00

Timer 2 (mm:ss) ----- ----- ----- ----- ------ ----- ----- -----


2) 2) 2) 2) 2) 2) 2) 2)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14752 1.14752 1.14752 1.00683.0001 1.00683.0001

Program name Ammonium14752 Ammonium14752 Ammonium14752 Ammonium00683 Ammonium00683

Unit mg/l mg/l mg/l mg/l mg/l

Wavelength 690 nm 690 nm 690 nm 690 nm 690 nm

Resolution 0.01 0.001 0.001 0.1 0.1

Chemical Form 1 NH4-N NH4-N NH4-N NH4-N NH4-N

Calibration “a” 0 0 0 0 0

Calibration “b” 1.23 0.483 0.245 27.8 55.6

Calibration “c” 0 0 0 0 0

Calibration “d” 0 0 0 0 0

Upper limit 3.00 1.18 0.500 75.0 150.0

Lower limit 0.05 0.02 0.010 2.0 5.0

Timer 1 (mm:ss) 05:00 05:00 05:00 15:00 15:00

Timer 2 (mm:ss) 05:00 05:00 05:00 ----- -----


1) 1) 1) 1) 1)

Cell size used 10 mm 1 inch 50 mm 10 mm 10 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14752 1.14752 1.14752 1.00683.0001 1.00683.0001 1.00675.0001*

Program name Ammonium14752 Ammonium14752 Ammonium14752 Ammonium00683 Ammonium00683 AOX00675

Unit mg/l mg/l mg/l mg/l mg/l mg/l


Resolution 0.01 0.001 0.001 0.1 0.1 0.01

Chemical Form 1 NH4+ NH4

+ NH4+ NH4

+ NH4+ AOX

Calibration “a” 0 0 0 0 0 0

Calibration “b” 1.58 0.622 0.316 35.8 71.5 4.00

Calibration “c” 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0

Upper limit 3.86 1.520 0.644 96.6 193.2 2.50

Lower limit 0.06 0.024 0.013 2.6 6.4 0.05

Timer 1 (mm:ss) 05:00 05:00 05:00 15:00 15:00 15:00

Timer 2 (mm:ss) 05:00 05:00 05:00 ----- ----- -----


1) 1) 1) 1) 1) 1)

Cell size used 10 mm 1 inch 50 mm 10 mm 10 mm 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.01747.0001 1.01747.0001 1.00687.0001* 1.00826.0001* 1.14839.0001 1.00605.0001 1.00605.0001 1.00605.0001

Program name Arsenic01747 Arsenic01747 BOD00687 Boron00826 Boron14839 Bromine00605 Bromine00605 Bromine00605



Resolution 0.001 0.001 0.1 0.01 0.001 0.01 0.001 0.001

Chemical Form 1 As As O2 B B Br2 Br2 Br2

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 0.114 0.0447 13.5 1.38 0.328 7.519 2.960 1.504

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 1.000 0.039 12.0 2.00 0.800 10.00 3.937 2.000

Lower limit 0.005 0.002 0.5 0.05 0.050 0.10 0.039 0.020

Timer 1 (mm:ss) 120:00 120:00 ----- 60:00 12:00 01:00 01:00 01:00

Timer 2 (mm:ss) ----- ----- ----- ----- 02:00 ----- ----- -----


3) 3) 3) 1) 1) 3) 3) 3)

Cell size used 10 mm 1 inch 16 mm round 16 mm round 10 mm 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14834.0001* 1.01745.0001 1.01745.0001 1.01745.0001 1.00858.0001* 1.14815.0001 1.14815.0001

see appendix page 47

Program name Cadmium 14834

Cadmium01745 Cadmium01745 Cadmium01745 Calcium00858 Calcium14815 Calcium14815s

Unit mg/l mg/l mg/l mg/l mg/l mg/l mg/l

Wavelength 550 nm 525 nm 525 nm 525 nm 565 nm 550 nm 550 nm

Resolution 0.001 0.001 0.001 0.001 1 1 0.1

Chemical Form 1 Cd Cd Cd Cd Ca Ca Ca

Calibration “a” 0 0 0 0 -29.293 0 0

Calibration “b” 0.595 0.680 0.268 0.136 416.85 137 29.4

Calibration “c” 0 0 0 0 -252.27 0 0

Calibration “d” 0 0 0 0 99.158 0 0

Upper limit 1.000 0.010 0.005 0.002 250 160 15.0

Lower limit 0.025 0.500 0.197 0.100 10 10 1.0

Timer 1 (mm:ss) 02:00 02:00 02:00 02:00 03:00 08:00 08:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- -----


1) 1) 1) 1) 3) 1) 1)

Cell size used 16 mm round 10 mm 1 inch 50 mm 16 mm round 10 mm 10 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.00858.0001* 1.14815.0001 1.14815.0001 1.00858.0001* 1.14815.0001 1.14815.0001 1.19251.0001

see appendix page 47 see appendix page 47 180 *)

Program name Calcium00858 Calcium14815 Calcium14815s Calcium00858 Calcium14815 Calcium14815s Carbohyrazide see Oxygen Scavengers

Unit mg/l mg/l mg/l mg/l mg/l mg/l µg/l


Resolution 1 1 0.1 1 1 0.1 1

Chemical Form 1 CaCO3 CaCO3 CaCO3 CaO CaO CaO Carbohy

Calibration “a” -73.418 0 0 -41.011 0 0

Calibration “b” 1045 342 73.5 583.59 192 41.2

Calibration “c” -634.44 0 0 -353.18 0 0

Calibration “d” 249.09 0 0 138.82 0 0

Upper limit 625 400 37.5 350 224 21.0 600

Lower limit 25 25 2.5 14 14 1.4 0

Timer 1 (mm:ss) 03:00 08:00 08:00 03:00 08:00 08:00 10:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----


3) 1) 1) 3) 1) 1) 1)

Cell size used 16 mm round 10 mm 10 mm 16 mm round 10 mm 10 mm 1 inch

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary. Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box. As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14730.0001* 1.14897 1.14897 1.01807.0001 1.01804.0001* 1.00595.0001* 1.00597.0001* 1.00598

Program name Chloride14730 Chloride14897 Chloride14897 Chloride01807 Chloride01804 Chlorine00595 Chlorine00597 Chlorine00598



Resolution 1 1 0.1 0.01 0.1 0.01 0.01 0.01

Chemical Form 1 Cl- Cl- Cl- Cl- Cl- Cl2 Cl2 Cl2

Calibration “a” 0 0 0 0,01337 -1,537 0 0 0

Calibration “b” 114 107 28.2 4,873 13,35 2.469 2.469 3.333

Calibration “c” 0 0 0 -1,329 -2,082 0 0 0

Calibration “d” 0 0 0 1,018 3,146 0 0 0

Upper limit 125 250 25.0 5.00 15.0 6.00 6.00 6.00

Lower limit 5 10 2.5 0.10 0.5 0.03 0.03 0.05

Timer 1 (mm:ss) ----- 01:00 01:00 10:00 10:00 01:00 01:00 01:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


1) 1) 1) 1) 3) 3) 3) 3)

Cell size used 16 mm round 10 mm 10 mm 50 mm 16 mm round 16 mm round 16 mm round 10 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.00598 1.00598 1.00602 1.00602 1.00602 1.00599.0001 1.00599.0001 1.00599.0001

Program name Chlorine00598 Chlorine00598 Chlorine00602 Chlorine00602 Chlorine00602 Chlorine00599 Chlorine00599 Chlorine00599



Resolution 0.01 0.001 0.01 0.01 0.001 0.01 0.01 0.001

Chemical Form 1 Cl2 Cl2 Cl2 Cl2 Cl2 Cl2 Cl2 Cl2

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 1.312 0.667 3.333 1.312 0.667 3.333 1.312 0.667

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 3.00 1.000 6.00 2.36 1.000 6.00 2.36 1.000

Lower limit 0.02 0.010 0.05 0.02 0.010 0.05 0.02 0.010

Timer 1 (mm:ss) 01:00 01:00 01:00 01:00 01:00 01:00 01:00 01:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


3) 3) 3) 3) 3) 3) 3) 3)

Cell size used 1 inch 50 mm 10 mm 1 inch 50 mm 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.00086/1.00087

1.00088* 1.00086/1.00087

1.00088 1.00608.0001 1.00608.0001 1.00608.0001

Program name Chlorine00086/87/88

Chlorine00086/87/88

Chlorine dioxide00608



Unit mg/L mg/L mg/l mg/l mg/l


Resolution 0.01 0.001 0.01 0.01 0.001

Chemical Form 1 Cl2 Cl2 ClO2 ClO2 ClO2


Calibration “b” 2.47 0.67 6.33 2.49 1.27



Upper limit 6.00 1.000 10.00 3.94 2.000

Lower limit 0.03 0.010 0.10 0.04 0.020

Timer 1 (mm:ss) 01:00 01:00 02:00 02:00 02:00

Timer 2 (mm:ss) ----- ----- 01:00 01:00 01:00


3) 3) 3) 3) 3)

Cell size used 16 mm round 50 mm 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14552.0001* 1.14758.0001 1.14758.0001 1.14758.0001 1.14552.0001* 1.14758.0001 1.14758.0001 1.14758.0001

Program name Chromate14552 Chromate14758 Chromate14758 Chromate14758 Chromate14552 Chromate14758 Chromate14758 Chromate14758



Resolution 0.01 0.01 0.001 0.001 0.01 0.01 0.001 0.001

Chemical Form 1 Cr Cr Cr Cr CrO4 CrO4 CrO4 CrO4

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 0.971 1.30 0.511 0.260 2.17 2.90 1.14 0.579

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 2.00 3.00 1.181 0.600 4.46 6.69 2.635 1.338

Lower limit 0.05 0.05 0.020 0.010 0.11 0.11 0.044 0.022

Timer 1 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


2) 3) 3) 3) 2) 3) 3) 3)

Cell size used 16 mm round 10 mm 1 inch 50 mm 16 mm round 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.18750.0001* 1.18751.0001* 1.18752.0001* 1.18753.0001* 1.14560.0001* 1.01796.0001* 1.14540.0001*

Hach Program 431 *) 430 *) 435 *) 435 *)

Program name COD COD COD COD COD14560 COD01796 COD14540



Resolution 0.1 0.1 1

Chemical Form 1 COD COD COD COD COD COD COD

Calibration “a” 0 0 0

Calibration “b” -41.7 -40.7 -205,3

Calibration “c” 0 0 0

Calibration “d” 0 0 0

Upper limit 40.0 150 1500 15000 40.0 80.0 150

Lower limit 0.0 0 0 0 4.0 5.0 10

Timer 1 (mm:ss) ----- ----- ----- ----- ----- ----- -----

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- -----


1) 1) 1) 1) 1) 1) 1)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round

*) The above-mentioned Merck COD cell tests can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary. Handling is identical to the corresponding Hach COD tubes. Details can be found in the package insert, which is included in the box. As blank can be used: 1) own blank (= distilled water and reagents). The blank for COD is stabile for e.g. 3 month when storing dark. * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14895.0001* 1.14690.0001* 1.14541.0001* 1.14691.0001* 1.14555.0001* 1.01797.0001* 1.09772.0001*

Program name COD14895 COD14690 COD14541 COD14691 COD14555 COD01797 COD (Hg free)09772



Resolution 1 1 1 1 10 10 1

Chemical Form 1 COD COD COD COD COD COD COD

Calibration “a” 0 0 0 0 0 0 0

Calibration “b” -222 -397 1667 3226 4608 42553 -238

Calibration “c” 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0

Upper limit 300 500 1500 3500 10000 90000 150

Lower limit 15 50 25 300 500 5000 10

Timer 1 (mm:ss) ----- ----- ----- ----- ----- ----- -----

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- -----


1) 1) 1) 1) 1) 1) 1)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round As blank can be used: 1) own blank (= distilled water and reagents). The blank for COD is stabile for e.g. 3 month when storing dark. * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.09773.0001* 1.17058.0001* 1.17059.0001* 1.14553.0001* 1.14767.0001 1.14767.0001 1.14767.0001

Program name COD (Hg free)09773

COD seawater 17058

COD seawater 17059

Copper14553 Copper14767 Copper14767 Copper14767



Resolution 1 0.1 1 0.01 0.01 0.01 0.001

Chemical Form 1 COD COD COD Cu Cu Cu Cu


Calibration “b” 1923 -57.5 3650 3.60 4.44 1.75 0.889



Upper limit 1500 60.0 3000 8.00 6.00 2.36 1.200

Lower limit 100 5.0 50 0.05 0.10 0.04 0.020

Timer 1 (mm:ss) ----- ----- ----- 05:00 05:00 05:00 05:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ------ ------


1) 1) 1) 2) 3) 3) 3)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14561.0001* 1.09701.0001 1.09701.0001 1.09701.0001 1.14800.0001 1.14800.0001 1.14800.0001

Program name Cyanide14561 Cyanide09701 Cyanide09701 Cyanide09701 Cyanide14800 Cyanide14800 Cyanide14800



Resolution 0.001 0.001 0.001 0.001 0.001 0.001 0.001

Chemical Form 1 CN- CN- CN- CN- CN- CN- CN-


Calibration “b” 0.161 0.221 0.0871 0.0442 0.208 0.0819 0.0416



Upper limit 0.500 0.500 0.197 0.100 0.500 0.197 0.100

Lower limit 0.010 0.010 0.004 0.002 0.010 0.004 0.002

Timer 1 (mm:ss) 10:00 10:00 10:00 10:00 05:00 05:00 05:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- -----


3) 3) 3) 3) 3) 3) 3)

Cell size used 16 mm round 10 mm 1 inch 50 mm 10 mm 1 inch 50 mm

*) Instrument-specific calibration necessary! As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.19250.0001 1.19253.0001 1.19251.0001 1.14557.0001* 1.14557.0001 1.00809.0001* 1.00809.0001

*) *) 181 *) see appendix page 47


Program name Cyanuric Acid 19250

Cyanuric Acid 19253

DEHA see Oxygen Scavengers

Fluoride14557 Fluoride14557s Fluoride00809 Fluoride00809s

Unit mg/l mg/l µg/l mg/l mg/l mg/l mg/l


Resolution 1 1 1 0.01 0.001 0.01 0.001

Chemical Form 1 Cyanuric Acid Cyanuric Acid DEHA F- F- F- F-

Calibration “a” 0 0 0 0

Calibration “b” 1.33 0.323 1.43 0.312

Calibration “c” 0 0 0 0

Calibration “d” 0 0 0 0

Upper limit 160 160 450 1.50 0.500 1.80 0.500

Lower limit 2 2 0 0.10 0.025 0.10 0.025

Timer 1 (mm:ss) 03:00 03:00 10:00 05:00 05:00 15:00 15:00

Timer 2 (mm:ss) ---- ---- ---- ----- ----- ----- -----


4) 4) 1) 1) 1) 1) 1)

Cell size used 1 inch 1 inch 1 inch 16 mm round 50 mm 16 mm round 50 mm

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary. Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box.As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14598 1.14598 1.00822.0250 1.14500.0001* 1.14678.0001 1.14678.0001 1.14678.0001

190 *)

Program name Fluoride14598 Fluoride14598 Fluoride Formaldehyde 14500

Formaldehyde 14678

Formaldehyde 14678

Formaldehyde 14678



Resolution 0.01 0.1 0.1 0.01 0.01 0.01 0.001

Chemical Form 1 F- F- F- HCHO HCHO HCHO HCHO


Calibration “b” 2.02 21.5 3.23 4.22 1.66 0.844



Upper limit 2.00 20.0 2.00 8.00 8.00 3.15 1.500

Lower limit 0.10 1.0 0.02 0.10 0.10 0.04 0.020

Timer 1 (mm:ss) 05:00 05:00 01:00 05:00 10:00 10:00 10:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- -----


1) 1) 1) 3) 3) 3) 3)

Cell size used 10 mm 10 mm 1 inch 16 mm round 10 mm 1 inch 50 mm





Merck order no. 1.14821.0001 1.09711.0001 1.09711.0001 1.09711.0001 1.14731.0001* 1.14731.0001


Program name Gold14821 Hydrazine09711 Hydrazine09711 Hydrazine09711 Hydrogen peroxide14731

Hydrogen peroxide14731s



Resolution 0.1 0.01 0.001 0.001 0.1 0.01

Chemical Form 1 Au N2H4 N2H4 N2H4 H2O2 H2O2


Calibration “b” 6.25 0.870 0.342 0.174 38.5 10.5



Upper limit 12.0 2.00 0.787 0.400 20.0 5.00

Lower limit 0.5 0.02 0.008 0.005 2.0 0.25

Timer 1 (mm:ss) ----- 05:00 05:00 05:00 02: 00 02: 00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- -----


1) 3) 3) 3) 2) 3)

Cell size used 10 mm 10 mm 1 inch 50 mm 16 mm round 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.18789.0001 1.18789.0001 1.19251.0001 1.00606.0001 1.00606.0001 1.00606.0001

182 *)

Program name Hydrogen peroxide18789

Hydrogen peroxide18789

Hydroquinone see Oxygen Scavengers

Iodine00606 Iodine00606 Iodine00606

Unit mg/l mg/l µg/l mg/l mg/l mg/l


Resolution 0.01 0.01 1 0.01 0.01 0.001

Chemical Form 1 H2O2 H2O2 Hydro I2 I2 I2


Calibration “b” 2.65 1.04 11.9 4.69 2.38



Upper limit 6.00 2.36 1000 10.00 3.94 2.000

Lower limit 0.03 0.01 0 0.20 0.08 0.050

Timer 1 (mm:ss) 10: 00 10: 00 2:00 01:00 01:00 01:00

Timer 2 (mm:ss) ----- ----- ---- ---- ----- -----


1) 1) 1) 3) 3) 3)

Cell size used 10 mm 1 inch 1 inch 10 mm 1 inch 50 mm





Merck order no. 1.14549.0001* 1.14896.0001* 1.14761 1.14761 1.14761 1.100796.0001 1.100796.0001 1.100796.0001

Program name Iron14549 Iron14896 Iron14761 Iron14761 Iron14761 Iron00796 Iron00796 Iron00796



Resolution 0.01 0.1 0.01 0.001 0.001 0.01 0.01 0.001

Chemical Form 1 Fe Fe Fe Fe Fe Fe Fe Fe

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 1.64 28.3 2.08 0.820 0.417 5.56 2.19 1.11

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 4.00 50.0 5.00 1.97 1.000 5.00 1.97 1.000

Lower limit 0.05 1.0 0.05 0.02 0.005 0.10 0.04 0.010

Timer 1 (mm:ss) 03:00 05:00 03:00 03:00 03:00 10:00 10:00 10:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


2) 2) 3) 3) 3) 3) 3) 3)

Cell size used 16 mm round 16 mm round 10 mm 1 inch 50 mm 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.19251.0001 1.14833.0001* 1.09717.0001 1.09717.0001 1.09717.0001 1.00815.0001*

183 *)

Program name Isoascorbic acid see Oxygen Scavengers

Lead14833 Lead09717 Lead09717 Lead09717 Magnesium 00815

Unit µg/l mg/l mg/l mg/l mg/l mg/l


Resolution 1 0.01 0.01 0.001 0.001 0.1

Chemical Form 1 ISA Pb Pb Pb Pb Mg

Calibration “a” 0 0 0 0 -20.79

Calibration “b” 4.39 6.25 2.46 1.25 337.41

Calibration “c” 0 0 0 0 -513.33

Calibration “d” 0 0 0 0 458.21

Upper limit 1500 5.00 5.00 1.970 1.000 75.0

Lower limit 0 0.10 0.10 0.039 0.010 5.0

Timer 1 (mm:ss) 10:00 ----- ----- ----- ----- 03:00

Timer 2 (mm:ss) ---- ----- ----- ----- ----- -----


1) 2) 1) 1) 1) 3)

Cell size used 1 inch 16 mm round 10 mm 1 inch 50 mm 16 mm round

*) The above-mentioned Merck test can be used with Hach factory-programmed instrument calibrations. No calibration table is necessary. Handling is identical to the corresponding Hach test. Details can be found in the package insert, which is included in the box. As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to DR 5000 US version. DR 5000 European versions (with 13 mm cell holder) do not allow tests with 16 mm round cells!




Merck order no. 1.00816.0001* 1.01846.0001 1.01846.0001 1.01846.0001

Program name Manganese 00816

Manganese 01846

Manganese 01846

Manganese 01846

Unit mg/l mg/l mg/l mg/l

Wavelength 445 nm 565 nm 565 nm 565 nm

Resolution 0.01 0.01 0.001 0.001

Chemical Form 1 Mn Mn Mn Mn


Calibration “b” 4.13 1.67 0.657 0.334



Upper limit 5.00 2.00 0.790 0.400

Lower limit 0.10 0.05 0.020 0.005

Timer 1 (mm:ss) 02:00 10:00 10:00 10:00

Timer 2 (mm:ss) 05:00 ----- ----- -----


2) 1) 1) 1)

Cell size used 16 mm round 10 mm 1 inch 50 mm





Merck order no. 1.01739.0001 1.01739.0001 1.01739.0001 1.14770 1.14770 1.14770 1.19251.0001

184 *)

Program name Manganese 01739

Manganese 01739

Manganese 01739

Manganese 14770

Manganese 14770

Manganese 14770

Methylethylketoxime see Oxygen Scavengers

Unit mg/l mg/l mg/l mg/l mg/l mg/l µg/l


Resolution 0.01 0.001 0.001 0.01 0.01 0.001 1

Chemical Form 1 Mn Mn Mn Mn Mn Mn MEKO


Calibration “b” 1.72 0.679 0.345 5.62 2.21 1.12



Upper limit 2.00 0.790 0.400 10.00 3.94 2.000 1000

Lower limit 0.05 0.020 0.005 0.50 0.20 0.010 0

Timer 1 (mm:ss) 10:00 10:00 10:00 02:00 02:00 02:00 10:00

Timer 2 (mm:ss) ----- ----- ----- 02:00 02:00 02:00 ----


1) 1) 1) 3) 3) 3) 1)

Cell size used 10 mm 1 inch 50 mm 10 mm 1 inch 50 mm 1 inch





Merck order no. 1.00860.0001* 1.19252.0001 1.01632.0001 1.01632.0001 1.01632.0001 1.01632.0001 1.01632.0001 1.01632.0001

Hach Program 320 *)

Program name Molybdenum 00860

Molybdenum Monochloramine01632

Monochloramine01632

Monochloramine01632

Monochloramine 01632





Resolution 0.01 0.01 0.01 0.001 0.01 0.01 0.001

Chemical Form 1 Mo Mo Cl2 Cl2 Cl2 NH2Cl NH2Cl NH2Cl


Calibration “b” 1.10 5.00 1.97 1.00 3.67 1.44 0.733



Upper limit 1.00 40.0 10.00 3.94 2.000 7.25 2.85 1.450

Lower limit 0.02 0.2 0.25 0.10 0.050 0.18 0.09 0.036

Timer 1 (mm:ss) 02:00 05:00 05:00 05:00 05:00 05:00 05:00 05:00

Timer 2 (mm:ss) ----- ---- 10:00 10:00 10:00 10:00 10:00 10:00


1) 4) 1) 1) 1) 1) 1) 1)

Cell size used 16 mm round 1 inch 10 mm 1 inch 50 mm 10 mm 1 inch 50 mm





Merck order no. 1.01632.0001 1.01632.0001 1.01632.0001 1.14554.0001* 1.14785.0001 1.14785.0001 1.14785.0001

Program name Monochloramine 01632



Nickel14554 Nickel14785 Nickel14785 Nickel14785



Resolution 0.01 0.01 0.001 0.01 0.01 0.01 0.001

Chemical Form 1 NH2Cl-N NH2Cl-N NH2Cl-N Ni Ni Ni Ni


Calibration “b” 0.988 0.389 0.198 3.82 4.76 1.87 0.952



Upper limit 1.96 0.77 0.392 6.00 5.00 1.97 1.000

Lower limit 0.05 0.02 0.010 0.10 0.10 0.04 0.020

Timer 1 (mm:ss) 05:00 05:00 05:00 01:00 01:00 01:00 01:00

Timer 2 (mm:ss) 10:00 10:00 10:00 02:00 02:00 02:00 02:00


1) 1) 1) 2) 3) 3) 3)

Cell size used 10 mm 1 inch 50 mm 16 mm round 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14542.0001* 1.14563.0001* 1.14764.0001* 1.00614.0001* 1.14542.0001* 1.14563.0001* 1.14764.0001*

Program name Nitrate14542 Nitrate14563 Nitrate14764 Nitrate00614 Nitrate14542 Nitrate14563 Nitrate14764



Resolution 0.1 0.1 0.1 1 0.1 0.1 0.1

Chemical Form 1 NO3-N NO3-N NO3-N NO3-N NO3- NO3

- NO3-


Calibration “b” 7.14 14.7 27.9 128 31.6 65.3 124



Upper limit 18.0 25.0 50.0 225 79.7 110.7 221.3

Lower limit 0.5 0.5 1.0 23 2.2 2.2 4.4

Timer 1 (mm:ss) 10:00 10:00 10:00 05:00 10:00 10:00 10:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- -----


2) 2) 2) 2) 2) 2) 2)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.00614.0001* 1.14773.0001 1.14773.0001 1.14773.0001 1.14773.0001

Program name Nitrate00614 Nitrate14773 Nitrate14773 Nitrate14773 Nitrate14773

Unit mg/l mg/l mg/l mg/l mg/l


Resolution 1 0.1 0.1 0.1 0.1

Chemical Form 1 NO3- NO3-N NO3-N NO3

- NO3-


Calibration “b” 568 9.62 3.79 42.6 16.8



Upper limit 996 20.0 7.9 88.5 34.8

Lower limit 102 0.5 0.2 2.2 0.9

Timer 1 (mm:ss) 05:00 10:00 10:00 10:00 10:00

Timer 2 (mm:ss) ----- ----- ----- ----- -----


2) 1) 1) 1) 1)

Cell size used 16 mm round 10 mm 1 inch 10 mm 1 inch As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.09713 1.09713 1.09713 1.09713 1.09713 1.09713

Program name Nitrate09713 Nitrate09713 Nitrate09713 Nitrate09713 Nitrate09713 Nitrate09713



Resolution 0.1 0.1 0.01 0.1 0.1 0.1

Chemical Form 1 NO3-N NO3-N NO3-N NO3- NO3

- NO3-


Calibration “b” 19.6 7.72 3.92 86.8 34.2 17.4



Upper limit 25.0 9.8 5.00 110.7 43.6 22.1

Lower limit 1.0 0.4 0.10 4.4 1.7 0.4

Timer 1 (mm:ss) 10:00 10:00 10:00 10:00 10:00 10:00

Timer 2 (mm:ss)


1) 1) 1) 1) 1) 1)

Cell size used 10 mm 1 inch 50 mm 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14556.0001* 1.14942.0001 1.01842.0001 1.01842.0001 1.14556.0001* 1.14942.0001 1.00609.0001*

Program name Nitrate seawater14556

Nitrate seawater14942 Nitrate01842 Nitrate01842 Nitrate

seawater14556 Nitrate

seawater14942 Nitrite00609



Resolution 0.01 0.01 0.1 0.1 0.01 0.1 0.1

Chemical Form 1 NO3-N NO3-N NO3-N NO3- NO3

- NO3- NO2

-

Calibration “a” -0.047 0.421 -0,5041 -2.2315 -0.0442 -1.865 0

Calibration “b” 1.718 8.251 32,2843 142.913 7.182 36.524 82.64

Calibration “c” -0.438 -0.5679 -21,08326 -93.329 -1.6478 -2.515 0

Calibration “d” 0.0821 0.335 7,1650 31.717 0.3041 149 0

Upper limit 3.00 17.00 30.0 132.9 13.28 75.3 90.0

Lower limit 0.10 0.20 0.3 1.3 0.44 0.9 1.0

Timer 1 (mm:ss) 30:00 15:00 10:00 10:00 30:00 15:00 20:00

Timer 2 (mm:ss) ----- 60:00 ----- ----- ----- 60:00 -----


3) 3) 1) 1) 3) 3) 1)

Cell size used 16 mm round 10 mm 50 mm 50 mm 16 mm round 10 mm 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14547.0001* 1.14776 1.14776 1.14776 1.14547.0001* 1.14776 1.14776

Program name Nitrite14547 Nitrite14776 Nitrite14776 Nitrite14776 Nitrite14547 Nitrite14776 Nitrite14776



Resolution 0.001 0.001 0.001 0.001 0.001 0.001 0.001

Chemical Form 1 NO2-N NO2-N NO2-N NO2-N NO2- NO2

- NO2-


Calibration “b” 0.274 0.376 0.148 0.0752 0.900 1.22 0.479



Upper limit 0.700 1.000 0.394 0.200 2.300 3.285 1.293

Lower limit 0.010 0.020 0.008 0.002 0.033 0.066 0.026

Timer 1 (mm:ss) 10:00 10:00 10:00 10:00 10:00 10:00 10:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- -----


2) 3) 3) 3) 2) 3) 3)

Cell size used 16 mm round 10 mm 1 inch 50 mm 16 mm round 10 mm 1 inch As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14776 1.00613.0001* 1.14537.0001* 1.14763.0001* 1.19251.0001 1.19251.0001 1.19251.0001

Hach Program 180 *) 181 *) 182 *)

Program name Nitrite14776 Nitrogen00613 Nitrogen14537 Nitrogen14763 Oxygen Scavengers Carbohyrazide

Oxygen Scavengers DEHA

Oxygen Scavengers Hydroquinone

Unit mg/l mg/l mg/l mg/l µg/l µg/l µg/l


Resolution 0.001 0.1 0.1 1 1 1 1

Chemical Form 1 NO2- N N N Carbohy DEHA Hydro


Calibration “b” 0.243 18.4 7.81 185



Upper limit 0.657 15.0 15.0 150 600 450 1000

Lower limit 0.007 0.5 0.5 10 0 0 0

Timer 1 (mm:ss) 10:00 10:00 10:00 10:00 10:00 10:00 2:00

Timer 2 (mm:ss) ----- ----- ----- ----- ---- ---- ----


3) 2) 1) 2) 1) 1) 1)

Cell size used 50 mm 16 mm round 16 mm round 16 mm round 1 inch 1 inch 1 inch





Merck order no. 1.19251.0001 1.19251.0001 1.14694.0001* 1.00607 1.00607 1.00607 1.01744.0001*

Hach Program 183 *) 184 *)

Program name Oxygen Scavengers Isoascorbic acid

Oxygen Scavengers Methylethylketoxime

Oxygen14694 Ozone00607 Ozone00607 Ozone00607 pH01744

Unit µg/l µg/l mg/l mg/l mg/l mg/l pH


Resolution 1 1 0.1 0.01 0.001 0.001 0.1

Chemical Form 1 ISA MEKO O2 O3 O3 O3

Calibration “a” 0 0 0 0 6.144

Calibration “b” 13.5 2.25 0.887 0.450 3.218

Calibration “c” 0 0 0 0 -2.318

Calibration “d” 0 0 0 0 0.714

Upper limit 1500 1000 12.0 4.00 1.575 0.800 6.4

Lower limit 0 0 0.5 0.05 0.020 0.010 8.8

Timer 1 (mm:ss) 10:00 10:00 ----- 01:00 01:00 01:00 -----

Timer 2 (mm:ss) ---- ---- ----- ----- ----- ----- -----


1) 1) 3) 3) 3) 3) 3)

Cell size used 1 inch 1 inch 16 mm round 10 mm 1 inch 50 mm 16 mm round





Merck order no. 1.14551.0001* 1.00856.0001 1.00856.0001 1.00856.0001 1.00856.0001 1.00474.0001* 1.14543.0001*

Program name Phenol14551 Phenol00856 Phenol00856 Phenol00856 Phenol00856 Phosphate00474 Phosphate14543



Resolution 0.01 0.001 0.01 0.01 0.001 0.01 0.01

Chemical Form 1 Phenol Phenol Phenol Phenol Phenol PO4-P PO4-P


Calibration “b” 3.39 0.0895 8.33 3.28 1.67 1.61 1.61



Upper limit 2.50 0.100 5.00 1.97 1.000 5.00 5.00

Lower limit 0.10 0.002 0.10 0.07 0.025 0.05 0.05

Timer 1 (mm:ss) 01:00 30:00 10:00 10:00 10:00 05:00 05:00

Timer 2 (mm:ss) ----- 10:00 ----- ----- ----- ----- -----


2) 1) 1) 1) 1) 2) 2)

Cell size used 16 mm round 1 inch 10 mm 1 inch 50 mm 16 mm round 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.00475.0001* 1.14729.0001* 1.00616.0001* 1.00673.0001* 1.00474.0001* 1.14543.0001* 1.00475.0001* 1.14729.0001*

Program name Phosphate00475 Phosphate14729 Phosphate00616 Phosphate00673 Phosphate00474 Phosphate14543 Phosphate00475 Phosphate14729



Resolution 0.1 0.1 0.1 0.1 0.01 0.01 0.1 0.1

Chemical Form 1 PO4-P PO4-P PO4-P PO4-P PO43-

PO43-

PO43-

PO43-

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 8.06 8.06 39.2 39.2 4.95 4.95 24.7 24.7

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 25.0 25.0 100.0 100.0 15.33 15.33 76.7 76.7

Lower limit 0.5 0.5 3.0 3.0 0.15 0.15 1.5 1.5

Timer 1 (mm:ss) 05:00 05:00 05:00 05:00 05:00 05:00 05:00 05:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


2) 2) 2) 2) 2) 2) 2) 2)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to DR 5000 US version. DR 5000 European versions (with 13 mm cell holder) do not allow tests with 16 mm round cells!




Merck order no. 1.00616.0001* 1.00673.0001* 1.00474.0001* 1.14543.0001* 1.00475.0001* 1.14729.0001* 1.00616.0001* 1.00673.0001*




Resolution 1 1 0.01 0.01 0.1 0.1 1 1

Chemical Form 1 PO43-

PO43-

P2O5 P2O5 P2O5 P2O5 P2O5 P2O5

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 120 120 3.70 3.70 18.5 18.5 89.9 89.9

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 307 307 11.46 11.46 57.3 57.3 229 229

Lower limit 9 9 0.11 0.11 1.1 1.1 7 7

Timer 1 (mm:ss) 05:00 05:00 05:00 05:00 05:00 05:00 05:00 05:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


2) 2) 2) 2) 2) 2) 2) 2)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14848 1.14848 1.14848 1.00798.0001 1.00798.0001 1.14848

Program name Phosphate14848 Phosphate14848 Phosphate14848 Phosphate00798 Phosphate00798 Phosphate14848



Resolution 0.01 0.01 0.001 0.1 0.1 0.1

Chemical Form 1 PO4-P PO4-P PO4-P PO4-P PO4-P PO43-


Calibration “b” 2.08 0.820 0.417 35.1 13.8 6.38



Upper limit 5.00 1.97 1.000 100.0 39.4 15.3

Lower limit 0.05 0.02 0.010 1.0 0.4 0.2

Timer 1 (mm:ss) 05:00 05:00 05:00 05:00 05:00 05:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- -----


1) 1) 1) 1) 1) 1)

Cell size used 10 mm 1 inch 50 mm 10 mm 1 inch 10 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14848 1.14848 1.00798.0001 1.00798.0001 1.14848 1.14848 1.14848 1.14546.0001*




Resolution 0.01 0.01 1 0.1 0.01 0.01 0.001 0.1

Chemical Form 1 PO43- PO4

3- PO43- PO4

3- P2O5 P2O5 P2O5 PO4-P

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 2.51 1.28 108 42.4 4.76 1.88 0.954 13.4

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 6.04 3.0 307 120.9 11.46 4.51 2.291 25.0

Lower limit 0.06 0.03 3 1.2 0.11 0.05 0.023 0.5

Timer 1 (mm:ss) 05:00 05:00 05:00 05:00 05:00 05:00 05:00 -----

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


1) 1) 1) 1) 1) 1) 1) 2)

Cell size used 1 inch 50 mm 10 mm 1 inch 10 mm 1 inch 50 mm 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14842.0001 1.14842.0001 1.14546.0001* 1.14842.0001 1.14842.0001 1.14546.0001* 1.14842.0001 1.14842.0001




Resolution 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1

Chemical Form 1 PO4-P PO4-P PO43-

PO43- PO4

3- P2O5 P2O5 P2O5

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 18.0 7.09 41.2 55.2 21.7 30.8 41.3 16.2

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 30.0 11.8 76.7 92.0 36.2 57.3 68.7 27.0

Lower limit 1.0 0.4 1.5 3.1 1.2 1.1 2.3 0.9

Timer 1 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


1) 1) 2) 1) 1) 2) 1) 1)

Cell size used 10 mm 1 inch 16 mm round 10 mm 1 inch 16 mm round 10 mm 1 inch As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14562.0001* 1.00615.0001* 1.14683.0001* 1.14683.0001* 1.14683.0001* 1.14683.0001* 1.14683.0001* 1.14683.0001*

*) *)

Program name Potassium14562 Potassium00615 Residual Hardness14683

Residual Hardness14683







Resolution 0.1 1 0.01 0.01 0.01 0.001 0.001 0.001

Chemical Form 1 K K Ca CaCO3 CaO °d °e °f

Calibration “a” -0.46153 -1.1538 -0.64615 -0.06461 -0.08077 -0.11538

Calibration “b” 4.62293 11.557 6.4721 0.64721 0.80901 1.15573

Calibration “c” -1.14084 -2.8521 -1.59717 -0.15972 -0.19965 -0.28521

Calibration “d” 0.32358 0.8089 0.45301 0.0453 0.05663 0.08089

Upper limit 50.0 300 5.00 12.50 7.00 0.700 0.875 1.250

Lower limit 5.0 30 0.50 1.25 0.70 0.070 0.088 0.125

Timer 1 (mm:ss) 05:00 05:00 10:00 10:00 10:00 10:00 10:00 10:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- -----


3) 3) 3) 3) 3) 3) 3) 3)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round





Merck order no. 1.14794.0001 1.14794.0001 1.14794.0001 1.00857.0001 1.00857.0001 1.00857.0001 1.00857.0001 1.01813.0001

Program name Silicate14794 Silicate14794 Silicate14794 Silicate00857 Silicate00857 Silicate00857 Silicate00857 Silicate01813



Resolution 0.01 0.01 0.001 0.1 0.1 1 0.1 0.0001

Chemical Form 1 Si Si Si Si Si Si Si Si

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 3.74 1.47 0.286 28.0 11.0 282 111 0.785

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 5.00 1.97 0.750 50.0 19.7 500 196.9 0.2337

Lower limit 0.10 0.04 0.005 0.5 0.2 5 2.0 0.0002

Timer 1 (mm:ss) 03:00 03:00 03:00 02:00 02:00 02:00 02:00 05:00

Timer 2 (mm:ss) 10:00 10:00 10:00 02:00 02:00 02:00 02:00 05:00


3) 3) 3) 3) 3) 3) 3) 1)

Cell size used 10 mm 1 inch 50 mm 10 mm 1 inch 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14794.0001 1.14794.0001 1.14794.0001 1.00857.0001 1.00857.0001 1.00857.0001 1.00857.0001 1.01813.0001

Program name Silicate14794 Silicate14794 Silicate14794 Silicate00857 Silicate00857 Silicate00857 Silicate00857 Silicate01813

Unit mg/l mg/l mg/l Mg/l mg/l mg/l mg/l mg/l


Resolution 0.01 0.01 0.001 0.1 0.1 1 1 0.0001

Chemical Form 1 SiO2 SiO2 SiO2 SiO2 SiO2 SiO2 SiO2 SiO2

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 8.00 3.15 0.611 59.8 23.5 603 237 1.68

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 10.70 4.21 1.600 107.0 42.1 1070 421 0.5000

Lower limit 0.21 0.08 0.010 1.1 0.4 11 4 0.0005

Timer 1 (mm:ss) 03:00 03:00 03:00 02:00 02:00 02:00 02:00 05:00

Timer 2 (mm:ss) 10:00 10:00 10:00 02:00 02:00 02:00 02:00 05:00


3) 3) 3) 3) 3) 3) 3) 1)

Cell size used 10 mm 1 inch 50 mm 10 mm 1 inch 10 mm 1 inch 50 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14831.0001 1.14831.0001 1.00885.0001* 1.14548.0001* 1.00617.0001* 1.14564.0001* 1.14791.0001

*) *) *)

Program name Silver14831 Silver14831 Sodium00885 Sulfate14548 Sulfate00617 Sulfate14564 Sulfate14791



Resolution 0.01 0.01 1 1

Chemical Form 1 Ag Ag Na SO42- SO4

2- SO4

2- SO4

2-


Calibration “b” 2.22 0.874 263 256



Upper limit 3.00 1.18 300 250 500 1000 300

Lower limit 0.50 0.20 10 5 50 100 25

Timer 1 (mm:ss) 05:00 05:00 01:00 02:00 02:00 02:00 05:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- 07:00


1) 1) 1) 4) 4) 4) 1)

Cell size used 10 mm 1 inch 16 mm round 16 mm round 16 mm round 16 mm round 10 mm





Merck order no. 1.01812.0001 1.01812.0001 1.01812.0001 1.14779.0001 1.14779.0001 1.14394.0001* 1.14394.0001*

*) *) *)

Program name Sulfate01812 Sulfate01812 Sulfate01812 Sulfide14779 Sulfide14779 Sulfite14394 Sulfite14394



Resolution 0.1 0.1 0.01 0.01 0.001 0.1 0.1

Chemical Form 1 SO42- SO4

2- SO4

2- S2- S2- SO3

2- SO2

Calibration “a” 0.0052 0 0 0

Calibration “b” 1.1079 0.244 8.77 7.02

Calibration “c” -0.0055 0 0 0

Calibration “d” 0.1062 0 0 0

Upper limit 50.0 19.7 10.00 1.50 0.500 20.0 16.0

Lower limit 2.5 1.0 0.50 0.10 0.020 1.0 0.8

Timer 1 (mm:ss) 02:00 02:00 02:00 01:00 01:00 02:00 02:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- -----


4) 4) 4) 3) 3) 2) 2)

Cell size used 10 mm 1 inch 50 mm 10 mm 50 mm 16 mm round 16 mm round





Merck order no. 1.14394.0001 1.14394.0001 1.01746.0001 1.01746.0001 1.14697.0001* 1.01764.0001* 1.01787.0001* 1.14622.0001*

see appendix page 48 see appendix page 48

Program name Sulfite14394s Sulfite14394s Sulfite01746 Sulfite01746 Surfact.anion. 14697

Surfact.cat. 01764

Surfact.nonion. 01787

Tin14622



Resolution 0.01 0.01 0.1 0.1 0.01 0.01 0.01 0.01

Chemical Form 1 SO32-

SO2 SO32-

SO2 Surfact. CTAB Triton X-100 Sn

Calibration “a” 0 0 0 0 0 0 0 0.03

Calibration “b” 1.69 1.35 29.4 23.5 1.80 1.92 6.06 1.5544

Calibration “c” 0 0 0 0 0 0 0 -0.5016

Calibration “d” 0 0 0 0 0 0 0 0.147

Upper limit 3.00 2.40 60.0 48.0 2.00 1.50 7.50 2.50

Lower limit 0.05 0.04 1.0 0.8 0.05 0.05 0.10 0.10

Timer 1 (mm:ss) 02:00 02:00 02:00 02:00 10:00 05:00 02:00 15:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


1) 1) 1) 1) 2) 2) 2) 3)

Cell size used 50 mm 50 mm 10 mm 10 mm 16 mm round 16 mm round 16 mm round 16 mm round As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.14878.0001* 1.14879.0001* 1.00961.0001* 1.00961.0001* 1.00961.0001* 1.00961.0001* 1.00961.0001* 1.00961.0001*

Program name TOC14878 TOC14879 Total hardness 00961

Total hardness 00961







Resolution 0.1 1 1 1 1 0.1 0.1 0.1

Chemical Form 1 TOC TOC Ca CaCO3 CaO °d °e °f

Calibration “a” 0 0 -22.354 -55.594 -31.296 -3.1296 -3.8748 -5.5594

Calibration “b” -64.5 -645 339.98 849.94 475.97 47.597 59.261 84.994

Calibration “c” 0 0 -195.26 -489.08 -273.36 -27.336 -33.641 -48.908

Calibration “d” 0 0 69.671 175.17 97.54 9.754 11.864 17.517

Upper limit 80.0 800 215 538 301 30.1 37.6 53.8

Lower limit 5.0 50 5 13 7 0.7 0.9 1.3

Timer 1 (mm:ss) ----- ----- 03:00 03:00 03:00 03:00 03:00 03:00

Timer 2 (mm:ss) ----- ----- ----- ----- ----- ----- ----- -----


1) 1) 3) 3) 3) 3) 3) 3)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!




Merck order no. 1.01763.0001* 1.01749.0001* 1.01749.0001* 1.01809.0001* 1.01809.0001* 1.00861.0001* 1.14566.0001* 1.14832.0001

Program name Volatile Org.Acids01763

Volatile Org.Acids01749




Zinc00861 Zinc14566 Zinc14832



Resolution 1 1 1 1 1 0.001 0.01 0.01

Chemical Form 1 HOAc HOAc Butyric acid HOAc Butyric acid Zn Zn Zn

Calibration “a” 0 0 0 0 0 0 0 0

Calibration “b” 1430 1841 2486 1841 2486 1.36 4.88 1.08

Calibration “c” 0 0 0 0 0 0 0 0

Calibration “d” 0 0 0 0 0 0 0 0

Upper limit 3000 3000 4401 3000 4401 1.000 5.00 2.50

Lower limit 50 50 73 50 73 0.025 0.20 0.05

Timer 1 (mm:ss) 03:00 01:00 01:00 01:00 01:00 15:00 15:00 03:00

Timer 2 (mm:ss) 10:00 ----- ----- ----- ----- ----- ----- 02:00


1) 1) 1) 1) 1) 1) 2) 3)

Cell size used 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 16 mm round 10 mm As blank can be used: 1) own blank (= distilled water and reagents) 2) cell with blank (white screw cap) 3) distilled water 4) clear sample without reagents * Only applicable to US versions (16 mm round cells) of DR 5000 and DR 6000. The EU version (13 mm cells) doesn’t allow tests!’’




Appendix: Measuring range with appendix Each test kit contains a package insert with detailed information regarding the standard procedure of the measurement. In some cases, however, special points have to be considered which are not mentioned in the package inserts. In this appendix you will find specific applications and modified methods for analyses for sensitive measurements indicated with “see appendix page 47”. Calcium: with Spectroquant® Calcium Test, Cat. No. 1.14815.0001 Measuring range: 1.0 – 15.0 mg/L Ca 2.5 – 37.5 mg/L CaCO3 1.4 – 21.0 mg/L CaO Procedure: Add 10 ml of reagent Ca-1A and 8 drops each of reagent Ca-2A and Ca-3A to 1 ml of the sample solution and mix. Leave to stand for 8 min for colour development. After filling into 10 mm cells measure in the photometer at 550 nm. Prepare the blank required for the measurement according to the above-mentioned procedure using 1 ml of distilled water instead of the sample solution. Fluoride: with Spectroquant® Fluoride Cell Test, Cat. No. 1.14557.0001 Measuring range: 0.025 – 0.500 mg/l F- Procedure: Pipette 10 ml of sample solution into the reaction cell, mix and add 1 blue microspoon of reagent F-1K. Close the cell tightly and dissolve the solid by shaking. Leave to stand for 5 min for colour development. After filling into 50 mm cells measure in the photometer at 620 nm. Prepare the blank required for the measurement according to the above-mentioned procedure using 10 ml of distilled water instead of the sample solution. Fluoride: with Spectroquant® Fluoride Cell Test, Cat. No. 1.00809.0001 Measuring range: 0.025 – 0.500 mg/l F- Procedure: Pipette 10 ml of sample solution into the reaction cell, mix and add 1 blue microspoon of reagent F-1K. Close the cell tightly and dissolve the solid by shaking. Leave to stand for 15 min for colour development. After filling into 50 mm cells measure in the photometer at 620 nm. Prepare the blank required for the measurement according to the above-mentioned procedure using 10 ml of distilled water instead of the sample solution Hydrogen peroxide: with Spectroquant® Hydrogen peroxide Cell Test, Cat. No. 1.14731.0001 Measuring range: 0.25 – 5.00 mg/l H2O2 Procedure: The test method of the package insert can be used without any alteration. After filling into 50 mm cells measure in the photometer at 410 nm




Sulfite: with Spectroquant® Sulfite Cell Test, Cat. No. 1.14394.0001 Measuring range: 0.005 – 3.00 mg/l SO3

2- Procedure: Place 1 microspoon of reagent SO3-1K in the cell, close tightly and shake until the complete dissolution of the solid. Then pipette 7 ml of the sample solution into the cell and mix. After the reaction time of 2 min fill into 50 cells and measure in the photometer at 410 nm. Prepare the blank required for the measurement according to the above-mentioned procedure using 7 ml of distilled water instead of the sample solution. Please contact our local Merck companies or Merck agents for any questions. Alternatively contact: [email protected]. No endorsement by Hach Company is implied or intended.

mailto:[email protected]

Programming Data for Hach

Documents

white screw cap

spectroquant test kits

local merck companies

programmed instrument calibrations

chlorine dioxide00608 mg

hydrogen peroxide18789 mg

nitrate seawater14556 mg

nitrate seawater14942 mg