PRODUCT TECHNICAL DOSSIER SODIUM BENZOATE · PRODUCT TECHNICAL DOSSIER SODIUM BENZOATE Product Code: ... Benzoic Acid, Benzaldehyde Benzyl ... MATERIAL SAFETY DATA SHEET

Product Code: P1916 Version: 2 Page 1 of 17

PRODUCT TECHNICAL DOSSIER

SODIUM BENZOATE Product Code: P1916 Raw Material Full Name: Sodium Benzoate This material is Food Grade Assay: 99.0 – 100.5% CAS Number: 532-32-1 EC/EINECS Number: 208-534-8 Molecular Formula for the raw material: C6H5CO2Na pH: 6.5-8.0 Acidity & Alkalinity: Conforms Halogenated Compounds: Max 300ppm Chlorides: Max 60ppm Phenol Content: Max 2ppm


Zinc & Copper: Max 50ppm Loss on Drying: Max 2% Country of Origin: China Country of Origin of the Manufacture: Europe Base Source/Start Material: Toluene Oxidation, Benzoic Acid, Benzaldehyde Benzyl Alcohol Origin of Product – Synthetic, Plant, Mineral, Animal, Fish or Fermented: Synthetic Synthetic: What are the starting materials of the synthesis and their sources? Toluene Oxidation, Benzoic Acid, Benzaldehyde Benzyl Alcohol Material is: 100% Compound Ingredients: None Shelf Life from Date of Manufacture Minimum 2 Years (Batch Specific) Storage Conditions: Store in a cool and dry; product is slightly hygroscopic. Appearance: Crystalline/Granular Powder Colour: White to Off White


Flavour/Taste: Characteristic Odour: Characteristic Metals Heavy Metals: Max 10ppm Arsenic (As): Max 2ppm There are no nuts in this recipe and are no nuts on site, however we cannot guarantee that the raw materials entering the site are nut free.


INTOLERANCE DATA

If No please give details

Free from All Animal Products (Beef, Pork, Poultry or other) YES

Free from Bovine Products or Derivatives by using hormones to increase milk yield in cows YES

Free from Bone Meal YES

Free from Peanuts and Peanut Derivatives (including possible cross contamination) YES

Free from other Nut and Nut Derivatives YES

Free from Nut Derived Oil YES

Free from Sesame Seeds and Sesame Seed Derivatives YES

Free from Poppy Seeds and Poppy Seed Derivatives YES

Free from Sunflower Seeds and Sunflower Seeds Derivatives YES

Free from other Seeds and Seed Derivatives YES

Free from Milk and Milk Derivatives (including lactose) YES

Free from Egg and Egg Derivatives YES

Free from Cereals containing Gluten (wheat / rye / oats / barley/ spelt/ kamut or their hybridised strains) and Derivatives

YES

Free from Soya and Soya Derivatives YES

Free from Maize and Maize Derivatives YES

Free from Corn and Corn Derivatives YES

Free from Lupin and Lupin Derivatives YES

Free from Yeast and Yeast Derivatives YES

Free from Cotton Seeds (Flour) and Cotton Seed Derivatives YES

Free from Rice and Rice Derivatives YES

Free from Mustard and Mustard Derivatives YES

Free from Celery or Celery Derivatives YES

Free from Celeriac or Celeriac Derivatives YES

Free from Fruit and Fruit Derivatives YES

Free from Vegetable and Vegetable Derivatives YES

Free from Carrot and Carrot Derivatives YES

Free from Legumes / Pulses YES

Free from Fish and Fish Derivatives YES

Free from Crustaceans / Molluscs and their Derivatives YES

Free from Additives YES

Free from Added Salt YES

Free from Added Sugar YES

Free from Antioxidants YES

Free from Artificial Glutamates YES

Free from Aspartame YES

Free from Azo and Coal Tar Dyes YES

Free from Benzoates (E210 / E219) NO <500ppm

Free from BHA / BHT (E320 / E321) YES

Free from Caffeine YES

Free from Cinnamon YES

Free from Cocoa YES

Free from Colours (Artificial / Nature Identical / Natural / Smoked) YES

Free from Dextrose YES

Free from Dioxins YES

Free from Ethanol YES


INTOLERANCE DATA

If No please give details

Free from Ethylene Oxide YES

Free from Flavourings (Artificial / Nature Identical / Natural / Smoked) YES

Free from Garlic YES

Free from Gelatine YES

Free from Glutamates (E620 to E625) YES

Free from Histamine YES

Free from Hickory YES

Free from Honey YES

Free from Lactose YES

Free from Latex YES

Free from MSG (Added and Naturally Occurring E621) YES

Free from Nucleotides (E627, E630, E631, E635) YES

Free from Polyols YES

Free from Preservatives YES

Free from Starch Products (Including Maltodextrin) YES

Free from Sorbic Acid (E200, E203) YES

Free from Sulphur Dioxide and Sulphites at levels above 10mg/kg or 10mg/litre expressed as SO2 YES

Free from Sulphites (E220, E228) YES

Free from Sweeteners YES

Free from Vannillin YES

Suitable for Diabetics YES

Suitable for Coeliacs YES

Suitable for Ovo-Lacto Vegetarians YES

Suitable for Vegans YES

Kosher Certified NO Not Certified

Halal Certified NO Not Certified


PRODUCT PROCESS FLOW DIAGRAM PRODUCT NAME: SODIUM BENZOATE PRODUCT CODE: P1916

Toluene

Oxidation

Benzoic Acid

Benzaidehyde

Benzyl Alcohol

Purox B Liquid (Pure

Grade Benzoic Acid)

Purox B Flakes (Pure

Grade Benzoic Acid)

Purox S Grains (Pure

Grade Sodium

Benzoate)

Benzaldehyde

Benzyl Alcohol

Customer

Purification

NaOH

Purification


CONFIRMATION OF BSE/TSE STATUS This is to certify that this product complies with all relevant current UK and EU Legislative requirements in regard to Transmissible Spongiform Encephalopathies (TSE) and Bovine Spongiform Encephalopathy (BSE) for human food, and so is free of TSE/BSE. This is also to certify that, during the course of their manufacture, the above-mentioned product did not come into contact with any materials, which could be derived from TSE/BSE risk materials. CONFIRMATION OF GM STATUS This is to certify that this product is not manufactured from GM raw materials and is therefore not subject to labelling under regulations 1829/2003/EC and 1830/2003/EC. CONFIRMATION OF NON IRRADIATION STATUS This is to certify that this product, whole or in part, has not been subjected to Ionising Radiation as per European Directives 1999/2/EC and 1000/3/EC. CONFIRMATION OF NANDROLONE STATUS This is to certify that this product, whole or in part, has not come into contact with Nandrolone or any of its precursors in any way. CONFIRMATION OF IOC PRODUCT STATUS This is to certify that this product, whole or in part, has not come into contact with any product/s, which is banned by the IOC (International Olympics Committee). CONFIRMATION OF ANIMAL TESTING STATUS

This is to certify that all the products sold by Cambridge Commodities have not been tested on animals in any part of its manufacture in accordance with regulation 86/609/EEC. CONFIRMATION OF PESTICIDES STATUS

This is to certify that the above-mentioned product complies with the regulation (EC) No.396/2005 of 23rd February 2005 and commission Regulation (EU) No. 559/2011 of 7th June 2011 amending annexes II and III of the above Regulation.


MATERIAL SAFETY DATA SHEET Section 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Name: SODIUM BENZOATE Product Code: P1916 Supplier: Cambridge Commodities Limited 78 Lancaster Way, Ely, Cambridgeshire, CB6 3NW. Tel: 01353 667258. Email: [email protected] 1.1 Product Identifier Components CAS Number EC/EINECS Number REACH Registration No. Sodium Benzoate 532-32-1 208-534-8 01-2119460683-35-0000 Synonyms Sodium Benzoic Acid, Benzoic Acid Sodium Salt 1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against 1.21 Relevant Identified Uses Main Use Category : Industrial use, Professional Use Use of the Substance/Preparation : ES1: Manufacturing of the substance and industrial use as auxiliary for

polymerization in a closed continuous process, with occasional exposure, including sampling. ES2: Industrial use as an auxiliary in polymerization processes in a closed continuous process, no likelihood of exposure including storing and forwarding. ES3: Charging/ discharging at non-dedicated facilities in an industrial setting ES4: Charging/ discharging at dedicated facilities in an industrial setting. ES5: Transfer of substance into small containers in an industrial setting. ES6: Industrial use in closed batch process – formulation and auxiliary in polymerization processes. ES7: Mixing and blending in batch processes for formulation or preparations and articles (multistage and/or significant contact).


ES8: Use in batch and other process (synthesis) where opportunity for exposure arises. ES9: Professional use of laboratory chemicals. Most Common technical function of the substance: Additive.

1.2.2 Use Advised Against No additional information available. Section 2: Hazard Identification 2.1 Classification of the Substance or Mixture Classification According to Regulation (EC) No.1272/2008 [CLP] Eye irrit. 2 H319 Full text of H-phrases: see section 16. Classification According to Directive 67/548/EEC or 1999/45/EC Xi: R36 Full text of R-phrases: see section16. Adverse Physicochemical, Human Health and Environmental Effects Causes serious eye irritation. 2.2 Label Elements Labelling According to Regulation (EC) No.1272/2008 [CLP] Hazard Pictograms (CLP): GHS07 CLP Signal Word :Warning Hazard Statements (CLP) :H319- Causes serious eye irritation Precautionary Statements (CLP) :P264- Wash hands thoroughly after handling

P280- Wear protective gloves/protective clothing/eye protection/face protection. P305 + P351 + P338 – IF EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 – If eye irritation persists: get medical advice/attention.


Section 3 Composition and ingredients

Name Product Identifier % Classification According to Directive 67/548/EEC

Sodium Benzoate (CAS no.) 532-32-1 (EC No.) 208-534-8 (REACH No.) 01-2119460683-35-0000

100 Xi; R36

Name Product Identifier % Classification According to Regulation (EC) No. 1272/2008 [CLP]

Sodium Benzoate (CAS no.) 532-32-1 (EC No.) 208-534-8

(REACH No.) 01-2119460683-35-0000

100 Eye irrit. 2, H319

Full text of R-, H- and EUH-phrases: see section 16 3.2 Mixtures N/A Section 4 First Aid Measures 4.1 Description of First Aid Measures First- Aid Measure General : Move the affected person away from the contaminated area and

into the fresh air. First-Aid Measure After Inhalation : Remove to fresh air and keep at rest in position comfortable for

breathing if irritation persists, consult a doctor. First- Aid Measures After Skin contact : Rinse with plenty of water. Remove all contaminated clothing and

footwear. If case of redness or irritation, call a doctor. First- Aid Measures After Eye Contact : Rinse immediately and thoroughly, pulling the eyelids well away

from the eye (15 minutes minimum). If irritation persists, consult an eye specialist.

First- Aid Measures After Ingestion : Rinse mouth out with water. Never give anything by mouth to an unconscious person. Get medical advice and attention if feel unwell.

4.2 Most Important Symptoms and Effects, Both Acute and Delayed Symptoms/ Injuries After Inhalation : Dust from this product may cause irritation to the respiratory tract.

Cough. Symptoms/ Injuries After Eye Contact : Eye irritation. Redness. 4.3 Indication of any immediate Medical Attention and Special Treatments Needed Treat symptomatically.


Section 5 : Fire Fighting Media 5.1 Extinguishing Media Suitable Extinguishing Media Dry Powder Carbon Dioxide (CO2) For Significant Fire: Water Spray Foam Dry Powder 5.2 Special Hazards Arising From the Substance and Mixture Fire Hazard :Dust may form explosive mixture in air. During Combustion: Toxic fumes may be released (Carbon Oxide (CO and CO2), (Sodium

Oxide). 5.3 Advice for Fire Fighters Fire Fighting Instructions : Contain extinguishing fluids by bunding. Protection During Fire Fighting : Do not attempt to take action without suitable protective equipment.

Complete protective clothing. Section 6 : Accidental Release Measures 6.1 Person Precautions, Protective Equipment and Emergency Procedures 6.1.1 For Non-Emergency Personnel Emergency Procedures : Avoid raising powdered material due to explosive hazard. Keep away

from ignition sources (including static discharges). Explosion-free electrical equipment and lighting with earth.

6.1.2 For Emergency Responders Protective Equipment : Do not attempt to take action without suitable protective equipment.

For further information refer to section 8 “Exposure Controls/Personal Protection.

6.2 Environmental Precautions Contain the spilled material by bunding. Do not discharge into drains or rivers. 6.3 Methods and Material for Containment and Cleaning up For containment : Sweep or vacuum up the product. Put into a labelled container and

provide safe disposal. Flame proof, lighting, electrical equipment and ventilation.

Method of Cleaning Up : Wash non-recoverable remainder with large amounts of water. 6.4 Reference to Other Sections For further information refer to section 13. Section 7 Handling and Storage


7.1 Precautions for Safe Handling Precautions for Safe Handling : Ensure good ventilation of the work station. Extraction to remove dust at its source. Do not breathe dust. Use personal protective equipment as required. Avoid raising powdered material due to explosive hazard. Flame proof, lighting, electrical equipment and ventilation. Keep away from ignition sources (including static discharge). Hygiene Measures : Do not drink, eat or smoke in the work place. Always wash your hands after handling this product. 7.2 Conditions for Safe Storage, Including any Incompatibilities Storage Conditions : Keep container tightly closed and dry. Keep in a cool, well-ventilated place away from heat. Take precautionary measures against static discharge. Keep away from incompatible materials. Avoid any contamination of the product by other substances. Incompatible Products : None Packaging Materials :Polyethylene Polypropylene. 7.3 Specific End Use(s) N/A Section 8 Exposure Control/Personal Protection 8.1 Control Parameters

Sodium Benzoate (532-32-1)

DNEL?DMEL (Workers)

Long-term- Systemic Effects, Dermal 34,7 mg/kg Bodyweight/Day

Long-term- Local Effects, Dermal 4,5 mg/cm2

Long-term- Systemic Effects, Inhalation 10,4 mg/m3

Long-term- Local Effects, Inhalation 6,3 mg/m3

DNEL/DMEL (General Population)

Long-term- Systemic Effects, Oral 25 mg/kg Bodyweight/ Day

Long-term- Systemic Effects, Inhalation 2,1mg/m3

Long-term- Systemic Effects, Dermal 20,8 mg/kg Bodyweight/Day

Long-term – Local Effects, Dermal 2,7 mg/cm2

Long-term- Local Effects, Inhalation 1,3 mg/m3


8.2 Exposure Controls Appropriate Engineering Controls : Ensure good ventilation of the work station. Flame proof, lighting, electrical equipment and ventilation. Hand Protection Butyl-rubber protective gloves. Nitrile-rubber protective gloves. Neoprene protective gloves. Protective gloves mad of PVC. VITON gloves. Break through time (min): > 480 Eye Protection : Safety spectacles with side shields. Skin and Body Protection : Protective clothing. Respiratory Protection : Dust production: dust mask with filter type P2. Environmental Exposure Controls : Take all necessary precautions to avoid accidental release of the

product outside, due to the rupture of container or transfer systems.

Section 9 Physical and Chemical Properties Physical state : Solid Appearance : Solid. Pellet. Hygroscopic. Colour : White to Off White Odour : Odourless Odour Threshold : Not estimated. pH : 9 pH Solubility : 10% Melting Point : 436 oC (1013 hPa) (OECD 102) Boiling Point : 465 oC Flash Point : N/A oC Relat. Evapor. Rate Comp. to Butyl acetate : No Data Available Flammability (Solid, Gas) : Non-flammable. (Expert statement) Explosive Limits : No Data Available Vapour Pressure : Negligible .Pa Relative Vapour Density at 20 oC : No Data Available Relative Density : 1,5 (20oC) (OECD 109) Solubility : Water. 556 g/l (20oC)(Handbook) Log Pow : -2, 27 (Calculated Value) Self-Ignition Temperature : No Data Available Decomposition Temperature : No Data Available


Viscosity, Kinematic : No Data Available Viscosity, dynamic : No Data Available Explosive Properties : N/A (Expert statement) Oxidizing Properties : N/A (Expert statement) 9.2 Other Information Minimum Ignition Energy : 10000 mJ Pellet. Other Properties : Surface Tension: 72.9 mN/m (20oC) (1 g/l) (OECD 115, EC A.5) Section 10 Stability and Reaction 10.1 Reactivity To our knowledge, the product does not present any risk. 10.2 Chemical Stability Stable at ambient temperature and under normal conditions of use. 10.3 Possibility of Hazardous Reactions None to our knowledge. 10.4 Conditions to Avoid No flames, No sparks. Eliminate all sources of ignition. Moisture. 10.5 Incompatible Materials Acids Oxidizing Materials Iron Salt. 10.6 Hazard Decomposition Products On Thermal Decompositions (Pyrolysis): Carbon Oxides (CO, CO2), Sodium oxide. Section 11 Toxicological Information 11.1 Information on Toxicological Effects Acute Toxicity : Not Classified


LD50 Oral Rat >2000 mg/kg

LD50 Dermal Rat >2000 mg/kg (read- across)

LC50 Inhalation Rat >12.2 mg/l (read- across)

Skin Corrosion/Irritation : Not classified (OECD 404) Serious Eye Damage/Irritation : Cause serious eye irritation (OECD 405)


Respiratory or Skin Sensitization : Not classified (Based on available data, the classification criteria are no met)

Germ Cell Mutagenicity : Not classified (Based on available data, the classification criteria are no met)

Carcinogenicity : Not classified (Based on available data, the classification criteria are no met)

Reproductive Toxicity : Not classified (Based on available data, the classification criteria are no met)

Specific Target Organ Toxicity (Single Exposure) : Not classified (Based on available data, the classification criteria are

no met) Specific Target Organ Toxicity (Repeated Exposure) : Not classified (Based on available data, the classification criteria are

no met) Aspiration Hazard Not classified (Technical impossibility to obtain the data) Section 12 Ecological Information 12.1 Toxicity


LC50 Fish >100 mg/l/96h (OECD 203)

EC50 Daphnia >100 mg/l/48h (Daphnia Magna) (OECD 211)

EC50 Other Aquatic Organisms >100 mg/l/24h (Achromobacter sp.)(Inhibition of Microbial Activity)

NOEC (Chronic) 51 mg/l/21 D (Daphnia Maga) (OECD 211)

ErC50 >100 mg/l/72h (OECD 201)

12.12 Persistence and Degradability


Persistence and Degradability Readily Biodegradable (OECD 301B)

12.3 Bioaccumulative Potential


Log Pow -2,27 (Calculated Value)

12.4 Mobility in Soil


Mobility in Soil No Data Available


12.5 Results of PBT and vPvB Assessment


Results of PBT Assessment The product does not meet the PBT and vPvB classification criteria.

12.6 Other Adverse Effects No additional information available. Section 13 Disposal Considerations 13.1 Waste Treatment Methods Waste Treatment Method : Dispose of in accordance with relevant local regulations. Section 14 Transport Information No dangerous good in sense of transport regulations. Section 15 Regulatory Information 15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture 15.1.1 EU- Regulations No additional information available. 15.1.2 National Regulations No additional information available. 15.2 Chemical Safety Assessment A chemical safety assessment has been carried out. Section 16 Other Information Data Sources : CSR (Chemical Safety Report) Full Text of R-, H- and EUH- Phrases:

Eye Irrit. 2 Serious Eye Damage/Irritation Category 2

H319 Cause Serious Eye Irritation

R36 Irritating to Eyes.

This advice is given by Cambridge Commodities Ltd who accept no legal liability for it. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not therefore be construed as guaranteeing specific properties.


Individuals working with chemicals should consider all chemicals to be potentially hazardous even if their individual hazards may be uncharacterised or unknown. We confirm that the information above is sourced from the original manufacturers/suppliers Specification To be used as per local legislation

Change History

Version Change Customer Notification required Yes / No

1 First Issue N/A

2 Shelf Life amended (Batch Specific) added No

QA Approval Date: 25.02.2015

Signature: Checked By: Kelsey Martin

PRODUCT TECHNICAL DOSSIER SODIUM BENZOATE · PRODUCT TECHNICAL DOSSIER SODIUM BENZOATE Product Code: ... Benzoic Acid, Benzaldehyde Benzyl ... MATERIAL SAFETY DATA SHEET

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