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Presentation of Nanotechnology Roadmap (2012-2016) Erwin P. Enriquez, PhD Chemistry / Materials Science & Engineering Program Ateneo de Manila University Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017
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Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

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Page 1: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Presentation of Nanotechnology Roadmap (2012-2016)

Erwin P. Enriquez, PhD

Chemistry / Materials Science & Engineering Program

Ateneo de Manila University

Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022)

Crowne Plaza Manila Galleria, 28 September 2017

Page 2: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Outline

•Definition

•Why Nanotechnology

•Nanoscience in a nutshell

•Philippines’ Roadmap (2012-2016)

• Local Capabilities

2Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Page 3: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Definition

Deals with the design, fabrication or synthesis, and manipulation of matter with dimensions within 100 nm including processes that occur within these length scales.

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for meter dimensions

TECHNOLOGYNANO

1 nm ≡ 10-9 m = 0.000000001 m

1 atom 0.1 nm diameterGraphene

thickness ~ 0.3-1 nm

Buckyballd ~ 0.71 nm

C Nanotubed ~ 0.22 - 1 nm

Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Page 4: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Nanotechnology is the major driving force for the technology revolution of the 21st Century*

4

*Wennersten et al. Handbook of Performability Engineering (2008)

Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Page 5: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Nanotechnology is the major driving force for the technology revolution of the 21st Century*

5

*Wennersten et al. Handbook of Performability Engineering (2008)

Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

By formulating their product with bits of carnauba (palm-tree wax) that are only nanometers wide, automotive cosmetics maker Eagle One says it's able to make a coating that always goes on clear.

Discover Magazine Top Nanotechnology in Consumer Products (2010)

Page 6: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Nanotechnology is the major driving force for the technology revolution of the 21st Century*

6

*Wennersten et al. Handbook of Performability Engineering (2008)

Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Clay nanoparticles allow Miller Brewing to bottle its beer in plastic containers. The tiny reinforcements keep oxygen out and hold carbon dioxide in, which prevents the brewed beverage from spoiling.

Discover Magazine Top Nanotechnology in Consumer Products (2010)

Page 7: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Nanotechnology is the major driving force for the technology revolution of the 21st Century*

7

*Wennersten et al. Handbook of Performability Engineering (2008)

Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Gold nanoparticles can make the pink "get ready to be a parent" mark on home pregnancy tests much easier to read. When a woman gets pregnant, her body immediately starts making the hormone human chorionic gonadotropin (hCG).

Discover Magazine Top Nanotechnology in Consumer Products (2010)

Page 8: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Nanotechnology is the major driving force for the technology revolution of the 21st Century*

9

*Wennersten et al. Handbook of Performability Engineering (2008)

Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

BOYSEN® KNOxOUT™ contains CristalACTiV™ photocatalytic technology, which is ultrafine titanium dioxide, (TiO2) that absorbs energy from light and transforms ordinary water vapor into hydroxyl and peroxyl free-radicals at the surface of the TiO2.

Product of the Philippines

Air-cleaning and Self-sanitizingAnti-bacterial Protection TechnologyOdor-less and low VOCWater-based, lead-free and mercury-freeOutstanding color retentionAcrylic water-basedFlat finish

Page 9: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Nanoscience: unique properties in the nano-regime

10Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

• Large surface-to-volume ratio: surface atoms are under 'tension'

0 20 40 60 80 1000

0.2

0.4

0.6

0.8

10.923

0.03

R n( )

1001 n

Nanomaterial • Quantum effects: size-tunableproperties

Klabunde (2001). Copyright: Wiley-VCH Verlag GmbH & Co. KGaA.

Gold Nanoparticles 2 nm 20 nm

Surface Area-to-Volume Ratio vs Number of Atoms

Page 10: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

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PCASTRD (2008) Dr. Reynaldo V. Ebora PCIEERD Dr. Amelia P. Guevara

Dr. Rowena Cristina L. GuevaraDr. Carlos Primo C. David

Page 11: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

2012-2015 Philippine Nanotechnology Roadmap

12Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Key Topics• Food and Agriculture• Polymers and Composites• Energy• Biomedicine• ICT & Semiconductors• Environment• Nanotechnology Risk• Education

Page 12: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

13Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Page 13: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

14Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Highlights• Nano-

photocatalysts• Nanosilica heat

exchanger• Nanocomposite• Nanoclay-based

materials

Page 14: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

15Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Highlights• Nanotech Center at

UPLB• Nanobiosensors• Nanosensors• Nano-standards for

neutraceticals• Nanosilica• Nanocellulose• Nano-precipitated

CaCO3

• Nano-encapsulated• Molecularly imprinted

polymers• Nanoliposomes

Page 15: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

16Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Highlights• Nanolab at the

MSD-ITDI• HR-TEM facility• DOST ADMATEL• Fuel Cell

applications• Printed Electronics• Fullerene, Carbon

Nanotubes, Graphene

• Solar Cell applications

• Supercapacitors• Optoelectronics

applications

Page 16: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Capabilities• Research Expertise

• Nanomaterial synthesis and formulations: CNT, graphene, metallic, semiconductor (TiO2, Q-dots), nanoclays• Nanocomposites: polymer-nanoclay, organic-inorganic hybrid materials, bio-sourced nanomaterials• Nanosensors and biosensors: design and fabrication, testing• Advanced characterization techniques

• Human Resources• Faculty and fulltime researchers • Graduate student scholarships and special grants (e.g., ADMATEL support)

• Instrumentation• Composition (Auger, TOF-SIMS, FE-SEM/TEM-EDS, Powder XRD)• Microscopy-Sizing (TEM, FE-SEM, SEM, AFM, Nano-sizers, DLS-Zetasizers)• Fabrication (E-beam, MBE, CVD, Self-Assembly, Synthesis, Printing/Additive Manufacturing)

• Products/technologies• Patent applications, IP reviews• Commercialization evaluations and strategies• Technology transfer support• Industry linkages (e.g., TODAY)

17Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017

Page 17: Presentation of Nanotechnology Roadmap (2012-2016)pcieerd.dost.gov.ph/images/downloads/presentation... · 2017-10-04 · Nanotechnology is the major driving force for the technology

Thank you for your attention.

18Round Table Discussion: Updating of Advanced Materials & Nanotechnology Roadmap (2017-2022) Crowne Plaza Manila Galleria, 28 September 2017