Physical properties of alkanes mostly `even Steven’ Boiling point vs #C in Boiling point vs #C in unbranched chain alkanes (C unbranched chain alkanes (C n H H 2 n+2 2 n+2 ) Melting point vs #C in Melting point vs #C in unbranched chain alkanes (C unbranched chain alkanes (C n H H 2 2 n+2 n+2 )
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Physical properties of alkanes mostly `even Steven’ Boiling point vs #C in unbranched chain alkanes (C n H 2 n+2 ) Melting point vs #C in unbranched chain.
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Physical properties of alkanesmostly `even Steven’
Boiling point vs #C in unbranched Boiling point vs #C in unbranched chain alkanes (Cchain alkanes (CnnH H 2 n+22 n+2))
Melting point vs #C in unbranched Melting point vs #C in unbranched chain alkanes (Cchain alkanes (CnnH H 2 n+22 n+2))
Alkane physical properties (continued)
Straight chain boils higher than equivalent branched chain Straight chain boils higher than equivalent branched chain with same #C (`packing’ matters)with same #C (`packing’ matters)
Example:n pentane 36 Example:n pentane 36 ooC > isopentane 28 C > isopentane 28 oo C > neopentane C > neopentane oo10 C10 C
36 o C
28 o C
10 oC
More More spherical spherical means less means less stickysticky
Lower bp, less stickyLower bp, less sticky
bp (bp (ooC)C)
3636
2828
1010
INTUITION:MORE SPHERICALLY SHAPED ISOMERS ARE LESS STICKY.
VISUAL INTUITION ON BP TREND
Alkane physical properties (continued
Density variations reflect local molecular effects until Density variations reflect local molecular effects until chains get past 3 Carbons .chains get past 3 Carbons .
A brief look at rotational isomers (pp 80-85)A brief look at rotational isomers (pp 80-85)
An isomeric set = isomers share the same formula: e.g. CAn isomeric set = isomers share the same formula: e.g. C55HH12 12
Structural isomersStructural isomers
Structurally distinctStructurally distinct
Physically/chemically differentPhysically/chemically different
Different namesDifferent names
bp bp ((ooC)C)
3636
2828
1010
Rotational isomersRotational isomers
Structurally similarStructurally similar
Physically/chemically similar Physically/chemically similar (but not =)(but not =)
Same nameSame name
bpbp
decreasingdecreasing
Sum of all its Sum of all its rotational rotational isomersisomers
(helps explain (helps explain bp range)bp range)
EXTENSION OF INTUITIVE MODEL OF BOILING POINT (BP) VS STRUCTURE FOR ROTATIONAL ISOMERIC FORMS