phenyl)-amine and their photocatalytic properties Alkyl … · S1 Electronic supplementary information (ESI) Alkyl groups-directed assembly of coordination polymers based on...
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Electronic supplementary information (ESI)
Alkyl groups-directed assembly of coordination polymers based on bis-(4-imidazol-1-yl-
phenyl)-amine and their photocatalytic properties
Hong-Jian Cheng*, Ya-Li Shen, Yi-Feng Lu, Ji Ma, Hong-Wei Ji, Wen-Yu Yin, Xiao-Yan Tang, Yun-Sheng Ma and Rong-Xin
Yuan*
School of Chemistry and Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu
Insititute of Technology, Changshu, Jiangsu, 215500, P. R. China
a Symmetry codes: (A) x + 1, y + 1, z; (B) x + 1, y – 1, z; (C) x + 1/2, – y, z + 1/2 for 1. (A) – x + 3, – y + 1, – z + 2; (B) – x + 2, – y, – z + 2 for 2. (A) x – 1, y + 1, z; (B) – x + 1, y + 1/2, – z + 3/2. for 3. (A) x, y + 1, z; (B) – x + 1, – y + 1, – z +1; (C) x – 1, y , z for 4.
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Table S2. Hydrogen-bonding interactions in 1-4._____________________________________________________________________Interaction D−H [Å] H···A [Å] D···A [Å] Angle (D−H···A) [°]_____________________________________________________________________Complex 1N3−H3A···O5a 0.86 2.52 3.36(2) 164N8−H8A···O3b 0.86 2.43 3.27(2) 165.0Symmetry codes: a, x − 1, y, z; b, x, y + 1, z.Complex 2O9−H9B···O4a 1.07 1.76 2.811(4) 165.03O9−H9C···O5b 0.82 1.97 2.781(4) 170.3O10−H10A···O1c 0.82 1.96 2.759(4) 164.8O10−H10B···O13d 1.04 2.13 3.151(4) 165.3O11−H11B···O13e 0.90 2.13 3.017(4) 167.3O11−H11C···O6e 0.82 1.97 2.759(5) 162.6O12−H12B···O2f 0.82 1.92 2.738(4) 179.6O12−H12C···O7g 0.93 1.88 2.807(4) 171.1O13−H13A···O8 0.85 1.85 2.663(4) 159.6O13−H13B···O3h 0.85 1.95 2.740(4) 153.2N3−H3A···O13i 0.86 2.110 2.943(5) 165.2Symmetry codes: a, − x + 2, − y + 2, − z + 2; b, x − 1, y + 1, z ; c, − x + 2, − y + 1 , − z + 2; d, − x + 2, − y, − z + 2; e, − x + 3, − y, − z + 2; f, x + 1, y − 1, z; g, − x + 3, − y − 1, − z + 2; h, x, y − 1, z; i, − x + 5/2, − y + 1/2, − z + 3/2.Complex 3O5−H5B···O3 a 0.85(6) 2.18 3.027(4) 179.1O5−H5C···O6 0.85 1.96 2.772(5) 160.1O6−H6B···O2b 0.85 1.95 2.784(4) 168.0O6−H6C···O3c 0.86 2.06 2.913(4) 175.8N3−H3A···O5e 0.86 1.90 2.713(9) 157.9Symmetry codes: a, − x + 1, − y + 1, − z + 1; b, − x + 1, − y + 2, − z + 1 ; c, x, − y + 3/2, z − 1.Complex 4O5−H5C···O1 0.85 2.14 2.922(6) 153.7O5−H5D···O4a 0.85 1.96 2.804(6) 173.5N3−H3A···O3bb 0.86 2.18 2.934(5) 145.9Symmetry codes: a, x − 1, y, z; b, − x + 1, y − 1/2, − z + 1/2.