PHASE 1 SOURCE EMISSION STACK TEST REPORT FOR ...

Environmental Consultants

S C S E N G I N E E R S

December 28, 2001File No. 05199008.05

2060 Reading Road

Suite 200

Cincinnati, Ohio 45202-1497

513 421-5353Fax 513 421-2847

[email protected]

Mr. Steve RenningerU.S. Environmental Protection AgencySuperfund Division (Mail Code B-2)26 W. Martin Luther King DriveCincinnati, Ohio 45286

Subject: Phase 1 Source Emission Stack Test ReportLandfill Gas Abatement SystemValleycrest Landfill, Dayton, Ohio

Dear Mr. Renninger:

On behalf of the Valleycrest Landfill Site Group, SCS Engineers (SCS) is submitting for yourreview the enclosed "Phase 1 - Emission Evaluation Test Program, Test Report" for theValleycrest Landfill Gas Abatement System (LGAS). This Test Report is being submitted toU.S. EPA for review following the implementation of the Phase 1 Stack Retest Workplan onNovember 20, 2001. Included with this submittal as part of the report are a description andsummary of the test and test results, copies of the field data sheets, emission rate calculations,the laboratory analysis report, and field equipment calibration data. Please note in the reportthat only seven (7) organic compounds on the TO-14 list and only one (1) tentatively identifiedcompound (TIC) were detected during Run #1 of the test. No compounds were detected duringRun #2.

If you have any questions or comments regarding this test report, please contact either GarySaylor or Jim Walsh of SCS at (513) 421-5353. We will then coordinate a response to youthrough Mr. Michael Samples at de maximis.

Sincerely,

Gary L. Saylor, P.E.Project ManagerSCS ENGINEERS

GLS/JJW:rae

Walsh, P.E.Project DirectorSCS ENGINEERS

cc: M. Samples, de maximis, inc.EPA Distribution List - *£.

Enclosure

Offices Nationwide

(l*ft+-1&U &»)$

EPA Region 5 Records Ctr.

231154

Air Nova, Inc.AIR QUALITY SERVICES

Project No. 2461

SCS Engineers © Valleycrest LandfillEnclosed Ground Flare

Landfill Gas Abatement SystemPhase I - Emission Evaluation Test Program

Test Report

1If*.1'•;'-•*.'

Project No. 2461

SCS Engineers @ Valleycrest LandfillEnclosed Ground Rare

Landfill Gas Abatement SystemPhase I - Emission Evaluation Test Program

Test Report

Prepared for

Mr. Gary SaylorSCS Engineers

2060 Reading RoadCincinnati, Ohio 45202

December 2001

Prepared by:

Mr. Lenny O. KaterynczukProject Manager

AirNova, Inc.

Table of Contents

Page

1.0 Introduction 1

2.0 Source Description 2

3.0 Summary of Test Results 4

4.0 Test Methodologies 64.1 Cyclonic Row Profile 64.2 Velocity and Volumetric Row Rate 74.3 Oxygen/Carbon Dioxide 74.4 Moisture 74.5 Specific Volatile Organic Compounds 84.6 Process Operation 9

5.0 Quality Assurance/Quality Control 105.1 S-Type Pfcot Tubes 105.2 Dry Gas Meters 105.3 Thermocouples 115.4 Labels 115.5 Chain-of-Custody Documentation 11

Appendix A - Field Data SheetsAppendix B - Emission CalculationsAppendix C - Laboratory DataAppendix 0 - Calibration DataAppendix E - Process Diagrams

SCS Engineers Project No. 2461December S001 Revision 0

1.0 Introduction

AirNova. Inc. conducted an emission evaluation test program on November 20, 2001 at the

Valleycrest Landfill located in Dayton, Ohio for the purpose of defining the actual speciated volatile organic

compounds of the enclosed landfill gas flare in operation at this site. The emission test program was

performed to establish the objectives, performance approach, and schedule for an emission compliance

retest program in accordance with the U.S. Environmental Protection Agency (EPA) approved Phase I

Workplan dated September 6.2001.

AirNova. Inc. was responsible for the performance of all on-site sampling and for the submittal of

this test report presenting the results and detailing all sampling and tn .diytical methods employed.

A description of the source which was evaluated, the sampling methodologies utilized and a

presentation of a complete summary of test results has been provided herein. Any questions pertaining

to this information may be addressed to:

Lenny D. KaterynczukProject ManagerAirNova, Inc.5845 Clayton AvenuePennsauken. New Jersey 08109Phone: [856)486-1500Fax: (856)486-9896E-mail: Ienny9aimova.com

AirNova. Inc.

SCS EngineersDecember 2001

Project No. 2461Revision 0

2.0 Source Description

The Valleycrest Landfill Site Group (VLSG) operates an enclosed landfill gas ground flare at the

Valleycrest Landfill located in Dayton. Ohio. The landfill gas flare is able to handle between 60 and 300

cubic feet per minute (cfm] of extracted landfill gas, as well as an expected methane target range as low

as 25 percent, and a combustion performance range between 0.9 and 9.0 MMBtu per hour.

Temperature thermocouples are installed at three separate, vertical elevations up the outside of the

ground flare. Each thermocouple is connected to the program logic controller (PLC) for combustion

temperature digital readout at the control panel of the system.

The PLC for the ground flare is programmed to ensure an average combustion temperature of

1500 degrees Fahrenheit through the combustion zone, and after achieving a minimum residence time

of 0.6 seconds. Automated adjustments can be made to the louver system to adjust the feed combustion

air in order to maintain combustion temperature.

Sampling at the outlet of the landfill gas flare was conducted in a vertical section of 54-inch

diameter exhaust stack. A total of four [4] test ports were installed through the exterior wall of the flare,

two [2] of which were situated at 90° apart above the flame zone and above the calculated 0.6 second

residence time level. These ports were located 4.2 duct diameters downstream and 0.5 duct diameters

upstream from the nearest flow disturbance, and were utilized for all sampling. A total of sixteen [16]

traverse points were utilized for all velocity traverses. These points were located as follows:

Table 2-1SCS Engineers 9 Valleycrest LandfillEnclosed Landfill Gas Ground Flare

Phase I - Emission Evaluation Test ProgramOutlet Traverse Point Locations

Traverse Point No.

1

2

3

% of Diameter

3.2

10.5

19.4

Location (inches]

1.8

5.7

10.5

AirNova, Inc.

SCS Engineers Project No. 246 1December 2001 Revision 0

4

5

6

7

8

32.3

67.7

80.6

89.5

96.8

17.4

36.6

43.5

48.3

52.3

Any pertinent engineering schematics of the entire flare system are included in Appendix E of this

report.

AirNova, Inc.

SCS Engineers Project No. 2461December 2001 Revision O

3.0 Summary of Test Results

The section which follows is a complete summary of test results for the evaluation test conducted

at Valleycrest Landfill on November 20.2001. Test results in tabular format have been utilized to present

the data in accordance with U.S. EPA NSPS requirements governing the operation of the enclosed landfill

gas ground flare. The results summary has been provided on the following page.

AirNova, Inc.



Table 3-1SCS Engineers @ Valleycrest LandfillEnclosed Landfill Gas Ground Flare

Phase I - Emission Evaluation Test ProgramTest Results Summary

IhâffifrAj- •'(* *\'J.':'J.-teZi(t.'t . •• ,tfi • j\.-

Date

Time Period

1- • • . ••.;. '-,.-. - ' - ; • • ' .

1 1/20/01

11:10 - 12:10

2•»> -

1 1/20/01

13:46 - 14:46

/Sta4 Gas.tqiara'cteristics .?.**-|nm<.'Jtt- -X, -.-•J'.'- ja^MjTSxv -*^,t .1. > . - - ,'

Oxygen (%dry)

Carbon Dioxide (%<Jry)

Moisture Content [%]

Stack Temperature (°F)

Gas Velocity [fps]

Volumetric Flow Rate (ACFM)

Volumetric Row Rate (DSCFM)

Specific Volatile OrganicCompounds

Chloromethane

Bromomethane

Chloroethane

Benzene

Toluene

Propylene

Acetone

11.69

7.91

8.2

1.350

8.5

8.093

2.147

11.49

8.18

7.0

1.317

7.4

7.032

1.923

Average

11.59

8.05

7.6

1.334

8.0

7.563

2.035

Concentration (ppbV) / Emission Rate (Ib/hr)

41/6.9*04

7.1/2.2*04

46/9.9*04

40/1.0*03

9.6/2.9*04

59/5.1*03

1 50/2.9*03

< 6.7/< 1 .0*04

<6.7/< 1.9*04

< 6.7/< 1 .3*04

<6.7/< 1.6*04

<6.7/< 1.8*04

<27/< 2.1*03

< 27/< 4.7e-04

< 24/< 4.0*04

<6.9/<2.1*04

< 26/< 5.6*04

< 23/< 5.8*04

< 8.2/< 2.4*04

< 28/< 3.6*03

< 89/< 1 .7*03

Standard Conditions: 68 deg. F. 29.92 in. Hg

AirNova. Inc.



1

4.0 Test Methodologies

The test program conducted at Valleycrest Landfill determined the actual speciation of volatile

organic compounds of the enclosed landfill gas ground flare. The specific parameters that were

determined during each of two [2] 1-hour test runs conducted for the flare utilized the following

methodologies:

Table 4-1SCS Engineers <9 Valleycrest LandfillEnclosed Landfill Gas Ground Rare

Emission Test Methodology Summary

-•J ,'-•-•• '. ' £ ' . - • • * " .• £ f

••• ;|EmissionJPsirameter\ v •••. - ',»#*• •••«** '4 .-/.. *:•..••..»•:, >.".!'- -Vi --1-- -i -

Volumetric Row Rate

Specific Volatile Organic Compounds

Moisture Content

Oxygen/Carbon Dioxide

Sjmpling and AnalyticaliMe^Hodology

EPA Reference Methods 1 & 2

EPA Compendium Method TO-1 4

EPA Reference Method 4

EPA Reference Method 3

A full description of the methodologies which were utilized to determine the above listed

parameters follows.

4.1 Cyclonic Flow Profile

The absence of significant cyclonic flow was demonstrated at the outlet sample location in

accordance with Section 11.4 of EPA Reference Method 1. An Stype pitot was connected to an inclined

manometer via leak-free connections. The pitot was placed so that the openings of the pitot tube were

perpendicular to the gas flow. An angle finder was placed on the pitot tube and was rotated until the

pressure reading [in. H20] on the manometer indicated null zero (0). This angle was then recorded. This

measurement was the absolute yaw angle for that traverse point position. This procedure was repeated

for each traverse point position along the sample location. Based on these measurements. AirNova. Inc.

calculated the average absolute yaw angle to verify that the location was acceptable in accordance with

EPA Reference Method 1. Section 2.4 requirements [absolute yaw angle < =20 degrees).

AirNova. Inc.

SCS Engineers Project No. 2461December 2001 i_ Revision 0

4.2 Velocity and Volumetric Flow Rate

The velocity profile was determined at the outlet test location in accordance with guidelines

outlined in EPA Reference Method 2, "Determination of Stack Gas Velocity and Volumetric Row Rate". The

gas velocity and volumetric flow rates were determined from velocity pressure and gas temperature data.

An S-type pitot tube and K-type thermocouple were used. The pitot tube was connected to an inclined

manometer and the thermocouple to a digital temperature indicator. The velocity pressure differentials

were measured on the manometer and the gas temperatures on the digital temperature indicator. These

readings were observed and recorded for each traverse point

4.3 Oxygen/Carbon Dioxide

The composition of the flue gas at the outlet test location was determined in accordance with

procedures outlined in EPA Reference Method 3, "Gas Analysis for Oxygen. Carbon Dioxide. Excess Air and

Dry Molecular Weight". An integrated sample of stack gas was collected utilizing a stainless steel probe

which was located twenty-four (24) inches from the inner port wall of the stack. The sample then entered

into teflon line and a condenser before being pulled into an evacuated sample bag through a sample pump

and rotameter. The samples were collected at a flow rate of 1 liter/min[±5%). The collected samples

at the outlet were analyzed by an Orsat analyzer in accordance with EPA Reference Method 3. Each Tedlar

bag was leak checked by connecting the bag to a water manometer and pressurizing the bag to 2-4 in.

H2O for approximately sixty [60] minutes. Any displacement in the water manometer indicates that a leak

was present

After a positive leak check, the bag was evacuated with a leak free pump connected on the

downstream side of a rotameter. When the gas was completely evacuated, no flow was evident if the bag

was leak free. Only leak free bags were utilized for sampling.

4.4 Moisture

Moisture content determinations performed at the outlet test location followed EPA Reference

Method 4, Section 2.0 as necessary. Stack gas sample was collected utilizing a stainless steel probe

AirNova. Inc. 7

SCS Engineers Project No. 2461December 2001 Revision 0

which was located twenty-four (24) inches from the inner port wall of the stack. Large capacity impingers

were utilized in the sampling train and a minimum sample volume of 40 DSCF was collected. One (1)

moisture content determination was conducted during each one [1 ] hour test run.

4.5 Specific Volatile Organic Compounds

Specific volatile organic compounds were determined in accordance with EPA Compendium

Method TO-14. This method is based on the collection of sample utilizing SUMMA silcosteel passivated

stainless steel canisters. Given the possibility of condensation forming in the canister during or after

sampling, the samples were limited in volume and collected in a partial vacuum. This insured that

condensation did not impact the integrity of the collected samples. In preparation for sampling using the

subatmospheric technique, the canister was evacuated to approximately 0.05 mm Hg. The sample line

between the sampling location and canister consisted of a stainless steel probe located twenty-four (24]

inches from the inner port wall and a minimal length of virgin Teflon tubing of 1/4-inch I.D. A leak check

is performed before and after each test run by pressurizing the sampling line up to the mass flow

controller with 15-psi of zero air. Each leak check is monitored for one (1 ] minute to ensure that there are

no pressure losses, thus indicating a leak in the sampling line. In addition to the initial and run end leak

checks, canister vacuum is recorded before and after each test run as well.

Sample collection is initiated by opening the sample valve allowing sample gas to flow into the

sample probe through the critical orifice flow restriction and into the canister. The critical orifice flow

restriction allows for control of the sample flow rate over the sample period. An appropriate orifice is

selected to allow for control of the sample flow rate over a continuous 1-hour period.

At the completion of sampling, the canister valve is closed and securely capped. It is then tagged

with the appropriate identification, and sent to the laboratory along with the chainof-custody

documentation. The canister vacuum was checked again by laboratory personnel after receipt of the

samples to compare the post sampling vacuum taken in the field to insure that leakage has not occurred

during shipping or storage. Analysis occurred for all volatile organic compounds on the TO-14 list, in

AirNova, Inc. 8


addition to the top ten {10) tentatively identified compounds (TIC's) that can be quantified. The analytical

strategy involves the use of a high resolution gas chromatograph (GC) coupled to a mass selective

detector (MSD) set in the scan mode. All ions are scanned by the MSD repeatedly during the GC run. The

system includes a computer and appropriate software for data acquisition, data reduction and reporting.

4.6 Process Operation

The automatic operating cycle for the landfill gas ground flare has varied in the past from eight [8)

to eighteen (18) hours per day. Currently, the flare normally operates in two (2) cycles of eight (8) hours

on and four (4) hours off each day. During this stack test, two (2) one (1 ] hour emission tests were

conducted during a single flare operating cycle. The first test was cor <uucted during the first hour of the

flare's operating cycle with sample collection commencing simultaneously with the startup of the flare.

The second test was conducted during the final hour of the flare operating cycle that concluded

simultaneous with the shutdown of the flare. The flare was operated in manual mode during the test and

operated continuously for 3 hours and 36 minutes before being manually shut down at the end of the

second test run.

AirNova, Inc.


5.0 Quality Assurance/Quality Control Procedures

All of the source sampling and analytical procedures were performed in accordance with the US

EPA's 'Good Laboratory Practice' guidelines. AirNova. Inc. followed the requirements of the individual test

methods to ensure the precision and accuracy of the source testing procedures. In addition. AirNova. Inc.

followed the procedures provided in the Quality Assurance Handbook for Air Pollution Measurement

Systems. Volume III, Stationary Sources'. Sampling equipment utilized in the test program was calibrated

prior to the test performance. The following procedures were utilized.

5.1 S-Type Pitot Tubes

The S-type pitot tubes were visually inspected to verify dimension requirements. Pitot tubes

meeting requirements were assigned a pitot tube coefficient of 0.84. Pitot tubes which did not meet the

requirements were not utilized.

5.2 Dry Gas Meters and Orifice

All dry gas meters used in the field were calibrated against a transfer standard dry gas meter that

is maintained in AirNova's calibration data. The transfer standard gas meter is calibrated annually and

certified against an MIST traceable Belktype Prover which operates by liquid displacement.

Field dry gas meters and orifice meters are calibrated at two month intervals at the following

orifice meter settings:

0.5 in. H201.0 in. H2O1.5 in. H202.0 in. H203.0 in. H204.0 in. H20

The initial and final volume readings and temperature readings were recorded for the dry gas

meter and the secondary standard test meter at each orifice meter setting. A dry gas meter correction

factor (DGMCF) was calculated for each setting and the average DGMCF was recorded.

All calibration documentation is stored in a designated filing cabinet for future reference. All repair

and maintenance documentation for each meter is stored in files that provide a history of each meter and

AirNova. Inc. 10


aid in our preventative maintenance program.

AirNova, Inc. also participates in the EPA Method 5 dry Gas Meter Audit Program.

5.3 Thermocouples

Thermocouples and thermometers utilized in the sampling program were calibrated according

to section 3.4.2 of the "Quality Assurance for Air Pollution Measurement Systems: Volume III" every two

months. The calibration method includes comparing each field thermometer and thermocouple at

different temperatures to an ASTM certified mercury-in-glass thermometer. The temperatures must

agree within the tolerances mentioned for the type of sampling equipment being calibrated. All the

calibi o Jon data is stored in a designated filing cabinet for future reference.

1. Stack Gas and Filter Housing Thermocouples and ThermometersThree temperatures are measured and extrapolated over the range of temperaturesencountered in field operations. The three temperatures used for calibration are:

1. Ice bath2. Boiling point of water3. Boiling point of cooking oil (or equivalent in solid salt bath]

2. Impringer Thermometers and ThermocouplesTwo temperatures are required to calibrate:

1. Ice bath2. Stabilized room temperature

3. Dry Gas ThermometersTwo temperatures are required to calibrate:

1. Stabilized hot water bath at approximately 104 -122°F (40 - 50°C]2. Stabilized room temperature

5.4 Labels

All samples collected as part of the sampling program (silica gel desiccant samples] were affixed

with labels which identify the following: 1 ] Project No., 2] Date. 3] Type of sample, 4] Run No., 5) Sample

location, and 6) Sample fraction.

5.5 Chain-of-Custody Documentation

Chairvof-custody documentation for all samples was implemented at the completion of sampling

and sample clean-up and was documented until the samples were received by the laboratory for analysis.

AirNova. Inc. 11

A

I

I.•w

' ' ' ' ' ' " ' ' ' ' ' ' ' * ' ' ' 'Appendix A

• . :'--:^^c:.. - • •Reid Data Sheets

' "

1 $pi§^ ^ : t :^ f (|i ^^v^ -> rr-

g ,<,,,,.».-..?,V:

3

il

Ul ii Liii-J L J t......J t^_J IL. .. J t.;~J i_iJ

rAirfNJova, Inc.

Vall

Project NoDate // -FacilityLocation '__Sample TypeRun NumberBarometric PressureSilica GelNumber(s)HZ0 Pickup(ml)Leak Check Pre-test QÔl a)

ISOKINETIC SAMPLING DATA SHEET

Probe NumberNoz2le Number

4Opera tor(s).Static Pressure

Meter Box Number--•---••--•-•-"jPitot NumberSample Box Number— —Assumed Moisture (%1 ~~ .— Âssumed Meter Temperature f*R -?-v ! ^:

t?rxij•.-.-'i.».'••' i'!(- •

inc.

Method 2 Gas^Velocity end Volume Data Sheet

Ptent 16 //*.Date II-Run No..Stack Diameter (io) ._Barometric Pressure ( HgJ.Static Pressure in Stack (Ps) ("Hg]OperatorsCp_j

. fv*-

TraversePoint

Number

X.

or

Schematic of Stack Cross Section

Positionfinches)

Velocity HeadC

.of

.n

• OO&

. o o

004

J2L

Scad;Temp.CB

WOO

/37"7Q7?

Cyckxiic How Determination.

AngteUwhich yields a null A P -

Sq.rtofAP

I

I

/3

1L.

1O/95 Average Angle ():

I- . ,

AirNova,lnc.

Proiect No..Dace llFacility l/^//fLocationSample TypeRun NumberBarometric PressureSilica Gel Number(s)HjO Pickup(ml)

ISOKINETIC SAMPLING DATA SHEET

Probe Number.

0/VNozzle Number

E9.+.Operator(s)Static Pressure

**r

- ----------- A HP- ----

.'/•='

Meter-Box NumberPitofrNumberSample Box Number -Assumed Moisture (%1Assumed MetarTeimperature (*F)_CO,

Leak Check Pre-test 0,061 2>lZ"Hp Post-test ,<>Olt\ ^Xfy•:rvrvn/r:K>wi%i/^fli ;>..- ... ;; M.-i-::,.,,.i>-^kfft*»E*t V«f-?i*' îLlii**-it* ;* ; ? i- •• J ' - " * ; •_< .•••!."$("

. toe.

Method 2 Gas VdcKatyj dVolumkOaca Sheet

DateRun No TWOSrackOiameterfinJBarometric Pressure f"Hal 2*/. 6Static Pressure in Stack IPs) f/Hg).Operators.Co 0> & V

r/

TraversePoint

Number-

Schematic of Stack Cross Section

PositionOnches)

Velocity HeadUPsJCHjO)

nl

StackTemp.rfl

1^70

Cydonic Row Determination.

Angledwhich yields a null A P

Sq.rtof4P

fl/nl

.flu I3L?

• 011211

.001 I X O

i£iLn

_OJ21

^2L• oo/

•00 /

r. 1O/95 Average Angle (]

Method 2 Gas VefocityjJOdValuaxe Data Sheet

P.-J

*!*

Plant.Oate_RunNo._Stack Diameter fmj.Barometric Pressure ('HgJStatic Pressure in Stack (Ps)£HgJ.Operators (A/WI/) Wl 7Cp ,f^/:

Schematic of ScackCross Section

^

1

I

^S

Oydonic How Determination.TraversePoint

Number AngteOwhich yields a nuO & P

i

1 *'•'•••!,iV.1 .••••/, •••:> '. • --.,.• ,'•>,•->s... -'''r ''/;:'-11'*t.>*tf'V'j>Qi;*v?%iJ/f-V-s;;*,7 -V: "•V.'&i'SiiVV,'-,- -^'rt?•*"''' ''•'" f---^.;i\,f,,<:.'.•;•• .•• •.";- .-..-.>:.: ;: •..; v^/^^^v^V^v-^^^^'^vvtWî.!'^^-.'*^ ' ';

££:>.•:/<•• • • ' - • • ' v--N-yl'--:>Apiahdk'fl>V-;^v'-''^'^:^

' • • •-•^.v^-^V^v--'^. • • •Emission Cabtifetions

•71

rjj 2461-01 AirNova, Inc.EPA Methods 1, 2, 3, 4. and TO-14

-3 (Flows, O2/CO2, H2O, and Specific VOC

iiiFacility

,, Location

.,4 Client

" Project No.

_ Test Location, Test Run

"" Test Date

Test Time

2

;*

*

,

-

1a

1*i

J

1

« ^_

,j

Vlc =

Vm =

Pstatic =Pb =

Ps =

Pstd =

dP =dH =

Tm =

Ts =

Tstd=Y =t =

Ds =

As =

Cp =Kp =

K1 =

K2 =

K3 =

R =

Valleycrest LandfillDayton, Ohio

SCS Engineers2461

Flare OutletOne

11/20/01

11:10-12:10

Emission Data81.3 cc

42.116 dcf

-0.032 in. H2O29.54 in. Hg

29.54 in. Hg

29.92 in. Hg

0.081 in. H2O A.51.700 in. H2O512.7 R

1809.5 R529.7 R

1.00

60 min.

4.500 ft.

15.904 sq.ft.0.84

85.49 {ft*[(lb/lbmol)*(inHg)]A

17.704 R/in.Hg

0.047301 cu.ft/ml

0.0026718 in.Hg'cf/ml'R

21.85 in.Hg'scf/lbmol'R

Vol. of H2O collectedDry gas meter reading

Static pressureBarometric pressure

Stack pressureEPA Sta-.J^rd pressure

Average sq.rt delta P

Average draft gauge readingAverage meter temperature

Average stack temperature

Standard temperatureMeter calibration factorDuration of sampling time

Diameter of stackCross sectional area of stack

Pitot tube coefficient

,5}/ls*R'inH2O]constant

constant Pitot tube constant

constant

Molar Gas Constant

Pagel

(02][CO2]

[N2J

Instrumental Data11.69 %-dry

7.91 %-dry

80.40 %-dry

Oxygen concentration

Carbon Dioxide concentrationNitrogen concentration

Client Valleycrest Landfill Test Location Flare Outlet Page 2Project No. 2461 Test Run One

Calculations

1) Volume of gas sampled at standard conditions, Vmstd.Vmstd =KV Y * Vm * (Pb + dH/13.6) / TmVmstd = 43.146 dscf

1.22 dscm

2) Volume of water vapor collected at standard conditions, Vwstd.Vwstd = K2 * VicVwstd = 3.846 scf

3) Decimal fraction of moisture by volume in stack gas, Bws.Bws = Vwstd / (VmstdWwstd)Bws = 0.082

4) Molecular weight of the stack gas on a wet basis, Ms.Ms = [ ((.44*%CO2) + (.32*%O2) + (.28*%N2)) ' (1-Bws) ] + (18*Bws)Ms= 28.77 Ib/lbmole

5) Average stack gas velocity, Vs.Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)A.5Vs= 8.48 fps

6) Average actual stack gas volumetric flowrate, Qa.Qa = 60 sec/min * Vs * AsQa= 8092.7 cfm

229.2 cmm

7) Average stack gas dry volumetric flowrate, Qstd.Qstd = Qa ' (Tstd/Ts) * (Ps/Pstd) * (1-Bws)Qstd= 2147.4 dscfm

60.8 dscmm

Client Valleycrest Landfill

Project No. 2461Test LocationTest Run

Flare OutletOne

8) Non-polar Volitlle Organic CompoundsE[NPVOC]

Compoundfreon 12freon114chloromethane

vinyl chloridebromomethane

chloroethanefreon 1 11,1-dichloroethene

freon 113methylene chloride,,1-dichloroe thane

cis -1,2-dichloroethenechloroform1,1,1-trichloroethanecarbon tetrachloride

benzene1 ,2-dichloroethanetrichloroethene1.2-dichloropropanecis-1 ,3-dichloropropene

toluenetrans-1 ,3-dichloropropene1,1.2-trichloroethanetetrachloroethene

ethylene dibromide;hlorobenzene

ethyl benzenem,p-xyleneo-xylenestyrene1 ,1 ,2,2-tetrachloroethane1 ,3,5-trimethylbenzene1 ,2,4-trimethylbenzene1 ,3-dichlorobenzene1 ,4-dichlorobenzenechlorotoluene1 ,2-dichlorobenzene1 ,2,4-trichlorobenzenehexachlorobutadienepropylene1 ,3-butadieneacetonecarbon disulfide

2-propanoltrans-1 ,2-dichloroethene

= [C[NPVOC](ppmV) *

Concentration(ppbv)

6.76.7

41.06.7

7.1

46.0

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

40.06.7

6.7

6.7

6.7

9.6

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

59.027.0

150.0

27.027.027.0

Qstd(dscfm) * MW(g/gmole) * 60(min/h)]

Concentration

(ppmv)0.0070.0070.0410.0070.0070.0460.0070.0070.0070.0070.0070.0070.0070.0070.0070.0400.0070.0070.0070.0070.0100.0070.0070.0070.0070.007

0.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.007

0.0590.0270.1500.0270.0270.027

Molecular Wt.(g/g-mole)

121171

50.562.594.964.513797

84.984.9

9996.9119133154

78.199

131113111

92.2111133166188113106106

106

104

168

120

120

147

147

127

147

181

261

261

54

58

76

60

96

/l(21.85*Tstd/Pstd)'10A6]

Emission Rate(Ib/hr)2.7E-004 *3.8E-004 *6.9E-0041.4E-004 *2.2E-0049.9E-0043.1E-004 *2.2E-004 *1.9E-004 *1.9E-004 *2.2E-004 *2.2E-004 *2.7E-004 *3.0E-004 *3.4E-004 *

1.0E-0032.2E-004 *2.9E-004 *2.5E-004 *2.5E-004 *2.9E-0042.5E-004 *

3.0E-004 *3.7E-004 *4.2E-004 *2.5E-004 *2.4E-004 *2.4E-004 '2.4E-004 *2.3E-004 *3.7E-004 *2.7E-004 *2.7E-004 *3.3E-004 *3.3E-004 *2.8E-004 '3.3E-004 *4.0E-004 '5.8E-004 *5.1E-0034.9E-004 *2.9E-0036.8E-004 *5.4E-004 *8.6E-004 '

Page 3

ClientProject No.

Valleycrest Landfill

2461

vinyl acetate2-butanone

hexanetetrahydrofuran

cyclohexane1,4-dioxanebromodichloromethane4-methyt-2-pentanone2-hexanonedibromochloromethanebromofonm4-ethyltolueneethanolmethyl tert-butyt ether

heptane

Test LocationTest Run

27.027.0

27.0

27.027.0

27.027.0

27.0

27.0

27.0

27.0

27.027.027.0

27.0

0.0270.0270.0270.0270.0270.0270.0270.0270.0270.027

0.0270.0270.0270.0270.027

Flare OutletOne

86

72

86

72

84

68

163

100

100

208

253

106

46

88

100

Page 4

7.7E-0046.5E-0047.7E-0046.5E-0047.6E-0047.9E-0041.5E-0039.0E-0049.0E-004

1.9E-0032.3E-0039.5E-0044.1E-0047.9E-0049.0E-004

* * * symbol indicates values given are the quantitative detection limit and should be viewed as nondetectable. r

2461-02

FacilityLocation

ClientProject No.Test Location

Test RunTest Date

Test Time

AirNova, Inc.EPA Methods 1, 2, 3,4. and TO-14

(Flows, O2/CO2, H2O, and Specific VOC

Valleycrest LandfillDayton, OhioSCS Engineers2461Flare Outlet

Two

11/20/0113:46-14:46

Pagel

Vlc =

Vm =Pstatic =

Pb =Ps =

Pstd =dP =

dH =

Tm =

Ts =Tstd=Y =

t =

Ds =As =

Cp =Kp =

K1 =K2 =

K3 =R =

69.4

42.49-0.02929.5229.5229.920.071

1.700

514.91776.8529.71.00

60

4.50015.9040.84

85.4917.704

0.0473010.0026718

21.85

Emission Dataccdcf

in. H20in. Hgin. Hg

in. Hg

in. H2O A.5

in. H2O

RRR

min.

ft.

sq.ft.

{ft*[(lb/lbmol)*(inHg)]A.R/in.Hg

cu. ft/mlin.Hg*cf/ml*R

in.Hg'scf/lbmol'R

Vol. of H2O collectedDry gas meter readingStatic pressureBarometric pressureStack pressureEPA Standard pressureAverage sq.rt delta P

Average draft gauge readingAverage meter temperatureAverage stack temperatureStandard temperatureMeter calibration factorDuration of sampling timeDiameter of stackCross sectional area of stackPilot tube coefficient

5}/[s*R*inH2O]constantconstant Pitot tube constantconstantMolar Gas Constant

Instrumental Data[O2] 11.49 %-dry

[CO2] 8.18 %-dry

[N2] 80.33 %-dry

Oxygen concentrationCarbon Dioxide concentrationNitrogen concentration

•v J

Client Valleycrest Landfill Test Location Flare Outlet Page 2

Project No. 2461 Test Run Two

Calculations

1) Volume of gas sampled at standard conditions, Vtnstd.Vmstd =K1 * Y * Vm * (Pb + dH/1 3.6) / Tm

Vmstd= 43.307 dscf1.23 dscm

2) Volume of water vapor collected at standard conditions, Vwstd.Vwstd = K2 * VicVwstd = 3.283 scf

3) Decimal fraction of moisture by volume In stack gas, Bws.Bws = Vwstd / (Vmstd+Vwstd)Bws = 0.070

4) Molecular weight of the stack gas on a wet basis, Ms.Ms = [ ((.44*%CO2) + (.32*%O2) + (.28*%N2)) * (1-Bws) ] «• (18*Bws)Ms = 26.94 Ib/lbmole

5) Average stack gas velocity, Vs.Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)A.5Vs= 7.37 fps

6) Average actual stack gas volumetric flowrate, Qa.Qa = 60 sec/min * Vs * As

Qa= 7032.4 cfm

199.2 cmm

7) Average stack gas dry volumetric flowrate, Qstd.Qstd = Qa * (Tstd/Ts) * (Ps/Pstd) * (1-Bws)Qstd= 1922.6 dscfm

54.4 dscmm

Client ValleycrestProject No. 2461

LandHII Test Location

Test Run

Flare Outlet

Two

8) Non-polar Volltile Organic CompoundsE[NPVOC]

Compoundfreon 12freon 114

chloromethanevinyl chloride

bromomethanechloroethanefreon 1 11.1-dichloroethenefreon 113methylene chloride

1.1-dichlorpethanecis -1,2-dichloroethenechloroform1,1,1-trichloroethane

carbon tetrachloridebenzene

1,2-dichloroethanetrichloroethene1 ,2-dichloropropanecis-1 ,3-dichloropropenetoluene

trans-1 ,3-dichloropropene1 , 1 ,2-trichloroethanetetrachloroethene

ethylene dibromidechlorobenzene-ethyl benzenem,p-xyleneo-xylenestyrene1 , 1 ,2.2-tetrachloroethane

1 ,3.5-trimethylbenzene1 ,2,4-trimethylbenzene

1 ,3-dichlorobenzene1 ,4-dichlorobenzenechlorotoluene

1 ,2-dichlorobenzene1 ,2,4-trichlorobenzenehexachlorobutadienepropylene1,3-butadieneacetonecarbon disulfide2-propanoltrans-1 ,2-dichloroethene

= (C[NPVOC](ppmV)

Concentration(ppbv)

6.76.76.76.76.76.76.76.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

27.027.027.0

27.027.0

27.0

* Qstd(dscfm) * MW(g/gmole) * 60(min/h)] / [(21 .85*Tstd/Pstd)*10A6]

Concentration(ppmv)

0.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.007

0.0070.0070.0070.0070.0070.0070.0070.007

0.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0070.0270.0270.0270.0270.0270.027

Molecular Wt.(g/g-mole)

12117150.562.594.964.513797

84.984.9

9996.9119133154

78.199

131113111

92.2111133166188113106106106104168120120147147127147181261261

5458766096

Emission Rate(Ib/hr)2.4E-004 *3.4E-004 *1.0E-004 '1.2E-004 *1.9E-004 *1.3E-004 *2.7E-004 *1.9E-004 *1.7E-004 *

1.7E-004 *2.0E-004 *1.9E-004 *2.4E-004 *

2.7E-004 *3.1E-004 *1.6E-004 *2.0E-004 *2.6E-004 '2.3E-004 *2.2E-004 *1.8E-004 *

2.2E-004 *2.7E-004 *3.3E-004 *3.8E-004 *2.3E-004 *2.1E-004 *2.1E-004 *2.1E-004 *2.1E-004 *3.4E-004 *2.4E-004 *2.4E-004 *2.9E-004 *2.9E-004 *2.5E-004 *2.9E-004 *3.6E-004 '5.2E-004 *

2.1E-003 *4.3E-004 *4.7E-004 *6.1E-004 '4.8E-004 •

7.7E-004 *

Page 3

ClientProject No.

Valleycrest Landfill

2461

vinyl acetate2-butanonehexanetetrahydrofuran

cyclohexane1.4-dioxanebromodichloromethane

4-methyl-2-pentanone2-hexanonedibromochloromethanebromofonn4-ethyltoluene

ethanolmethyl tert-butyl ether

heptane •

Test LocationTest Run

27.027.0

27.027.0

27.0

27.0

27.027.0

27.0

27.0

27.027.0

27.027.027.0

0.0270.0270.0270.0270.0270.0270.0270.0270.0270.0270.0270.0270.0270.0270.027

Flare Outlet

Two

867286728488

1631001002082531064688

.100

Page 4

6.9E-0045.8E-0046.9E-0045.8E-004

6.8E-0047.1E-004

1.3E-0038.0E-0048.0E-0041.7E-003

2.0E-0038.5E-0043.7E-0047.1E-0048.0E-004

" *" symbol indicates values given are the quantitative detection limit and should be viewed as nondetectable.

v- O

•*&$&<®&&&$$$l

I ;Sijj|$|tf ^^ ±' •,/^'.^?S?.;il3$'\$w:-r^,:.->

•<i$$i|&^^

3 •*-<S-A&:$: * ' : . - • ' • ' • ' . •Appendix C

Laboratory Data

,' ' : ^^^^^^^ -\Vi •' :'iv, -: ,'' |'l: ;•( .' ^V.'•'•,.*; •' • ' ;

•; •^V\-'J?;i''^•ir*'1'"\'i'-!•-;?!>'-'.'-'.'.';i-:'•'-•!<;::'. •' '

^^ j if ^^ ' •

••*"i

AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABORATORY

COMPREHENSIVE VALIDATION PACKAGETO-14

INVENTORY SHEET

Work Order #: 0111476

Page Nos.From To

1. Work Order Cover Page & Laboratory Narrative & Table 1 42. Sample Results and Raw Data (Organized By Sample) 5 32

a. ATL Sample Results Formb. Target Compound Raw Data

-Internal Standard Area and Retention Time Summary (If Applicable)-Surrogate Recovery Summary (If Applicable)-Chromatogram(s) and Ion Profiles (If Applicable)

3. QC Results and Raw Dataa. Method Blank (Results + Raw Data) 33 41b. Surrogate Recovery Summary Form (If Applicable) 42 42c. Internal Standard Summary Form (If Applicable) 43 43d. Duplicate Results Summary Sheet — -e. Matrix Spike/Matrix Spike Duplicate (Results + Raw Data) - -f. Initial Calibration Data (Summary Sheet + Raw Data) 44 14)g. MDL Study (If Applicable) - -h. Continuing Calibration Verification Data (Summary Sheet + Raw Data) 142 153i. Second Source LCS (Summary + Raw Data) 154 167j. Extraction Logs - -k. Instrument Run Logs/Software Verification 168 1711. GC/MS Tune (Results + Raw Data) 172 186

4. Shipping/Receiving Documents:a. Login Receipt Summary Sheet 187 189b. Chain-of-Custody Records 190 190c. Sample Log-In Sheet 191 191d. Misc. Shipping/Receiving Records (list individual records)

Sample Receipt Discrepancy Report 192 1925. Other Records (describe or list)

a. Canister Dilution Factors 193 194b. Laboratory Corrective Action Request - -c. CAS Number Reference 195 196d. Data Review Check Sheet 197 197

6. Canister Certification -

Completed by:

JcU&y. £ee Judy Lee/Document Control 12/12/01(Signature) (Print Name & Title) (Dale)


WORK ORDER #: 0111476

Work Order Summary

CLIENT: Mr. Joe JacksonAir Nova, Inc.5845 Clayton AvenuePennsauken, NJ 08109

BILL TO: Mr. Joe JacksonAir Nova, Inc.5845 Clayton AvenuePennsauken, NJ 08109

PHONE:

FAX:

DATE RECEIVED:

DATE COMPLETED:

856-486-1500

856-486-9896

11/27/01

12/10/01

P.0.# AN-2914

PROJECT # 2461 Valley Crest

CONTACT: Betty Chu

FRACTION* NAME01A RUN#1 Can #31429 Air Toxics 269202A RUN#2 Can #I268303A Lab Blank04A LCS

IESITO-14mCsTO-14/TICsTO-14/TICsTO-14/TICs

RECEIPTVAC7PRES.

27.0 "Hg27.0 "Hg

NANA

CERTIFIED BY: DATE: 12/10/01

Laboratory Director

I his report shall nor he reproduced, except in lull , without the wnrten approval ol Air I DXICS Ltd.

Certficaiion numbers: CA ELAP - 1149. NY ELAP - 11291. UT ELAP - E-217. AZ ELAP - AZ0567. LA - Al 30763Name of Accrediting Agency: NELAP/State of New York Department of Hea l th . Scope of Accreditation : Non Potable Water

Accreditat ion number :11291 , Effect ive date: 6/7/01, Expi ra t ion date: 4/1/02

I HO BLUE R A V I N E ROAD, SUITES FOLSOM. CA -45630( 9 1 6 ) 9 8 5 - 1 0 0 0 . (80()i985-5955 FAX (916) 985-1020

Pane I of I 1

LABORATORY NARRATIVETO-14

Air Nova, Inc.Workorder# Oil 1476

Two 6 Liter Summa Canister samples were received on November 27, 2001. The laboratoryperformed analysis via EPA Method TO-14 using GC/MS in the full scan mode. The method involvesconcentrating up to 0.5 liters of air. The concentrated aliquot is then flash vaporized and sweptthrough a water management system to remove water vapor. Following dehumidification, the samplepasses directly into the GC/MS for analysis. See the data sheets for the reporting limits for eachcompound.

During the five point calibration, two low-level standards are used. The low-level standard for TO-14compounds is spiked at 0.5 ppbv and represents the reporting limit for these compounds. Thelow-level standard for the non-TO-14 compounds is spiked at 2.0 ppbv and represents the reportinglimit for these compounds. The TO-14 compounds are present in both standards but are excluded fromreporting in the 2.0 ppbv standard since a lower level is already included in the curve.

Method modifications taken to run these samples include:Requirement

Internal standard retentiontimes.

Internal standard recoveries.

Initial calibration criteria.

Continuing calibrationverification criteria

Response factor forquantitalion.

TO-14

Not specified.

Not specified.

Not specified.

Not specified.

Average responsefactor (ICAL).

ATL Modifications

Within 0.50 minutes of most recent daily CCV internalstandards

Within 40% of the daily CCV internal standard area forblanks and samples.

RSD of 30% or less for standard compounds, 40% or lessfor non-standard and polar compounds

70 - 130% for at least 90% of standard compounds, 60 -140% for at least 80% of non-standard and polarcompounds

Average response factor (ICAL).

Receiving Notes

Samples RUN#1 Can #31429 Air Toxics 2692, and RUN#2 Can #12683 were received withsignificant vacuum remaining in the canister. The client was contacted and analysis proceeded. Theresidual canister vacuum resulted in elevated reporting limits.

Analytical Notes

There were no analytical discrepancies.

Definition of Data Qualifying Flags

Seven qualifiers may have been used on the data analysis sheets and indicates as follows:B - Compound present in laboratory blank greater than reporting limit(background subtraction not

performed).J - Estimated value.E - Exceeds instrument calibration range.S - Saturated peak.Q - Exceeds qua l i t y control l imits.

Page 2 of I I

U - Compound analyzed for but not detected above the reporting limit.N - The identification is based on presumptive evidence.

Page 3 of I I

AIR TOXICS LTD.SAMPLE NAME: RUN#1 Can #31429 Air Toxics 2692

ID#: 0111476-01A

EPA METHOD TO-14 GC/MS FULL SCAN

Compound

Freon 12Freon 1 1 4Chloromethane

Vinyl ChlorideBromomethane

ChloroethaneFreon 1 11,1-DichloroetheneFreon 113Methylene Chloride1,1-Dichloroethanecis-1 ,2-DichloroetheneChloroform1,1,1 -TrichloroethaneCarbon Tetrachloride

Benzene1 ,2-DichloroethaneTrichloroethene1 ,2-Dichloropropanecis-1 ,3-Dichloropropene

toluenetrans-1 ,3-Dichloropropene1 , 1 ,2-TrichloroethaneTetrachloroetheneEthylene Dibromide

ChlorobenzeneEthyl Benzenem.p-Xyleneo-XyleneStyrene

1,1 ,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene

Chlorotoluene1,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobutadiene

Propylene

1,3-BuladieneAcetone

Rpt. Limit(ppbv)

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

27

27

27

Rpt. Limit(uG/m3)

34

48

14

17

26

18

38

27

52

24

28

27

33

37

43

22

28

36

31

31

26

31

37

46

52

31

30

30

30

29

47

33

33

41

41

3541

50

73

47

60

65

Amount(ppbv)

Not DetectedNot Detected

41Not Detected

7.1

46Not DetectedNot DetectedNot DetectedNot Detected

Not DetectedNot DetectedNot DetectedNot DetectedNot Detected


9.6Not DetectedNot DetectedNot DetectedNot Detected



Not DetectedNot DetectedNot DetectedNot Detected

59

Not Detected150

Amount(uG/m3)


85Not Detected

28







Not DetectedNot DetectedNot DetectedNot Detected

100

Not Detected360

Page 4 of 11


ID#: 0111476-01AEPA METHOD TO-14 GC/MS FULL SCAN

Rpt. LimitCompound

Carbon Disulfide

2-Propanoltrans- 1 ,2-DichtoroetheneVinyl Acetate2-Butanone (Methyl Ethyl Ketone)

HexaneTetrahydrofuran

Cyclohexane1 ,4-OioxaneBromodichloromethane4-Methyl-2-pentanone2-HexanoneOibromochloromethaneBromoform4-EthyltolueneEthanolMethyl tert-Butyl EtherHeptane

TENTATIVELY

Compound

1-Propene, 2-methyt-Unknown

Container Type: 6 Liter Summa Canister

Surrogates

1 ,2-Dichloroethane-d4Toluene-d84-Bromofluorobenzene

(ppbv)

27

27

27

27

27

27

27

27

27

27

27

27

27

27

27

27

27

27

Rpt. Limit(uG/m3)

85

67

110

96

80

96

80

94

98

180

110

110

230

280

130

5198

110

IDENTIFIED COMPOUNDS - Top

CAS Number

115-11-7NA

%Recovery

10199

91

Amount(ppbv)

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

10 Reported

Match Quality

72%

NA

Amount(uG/m3)

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DelectedNot DetectedNot DetectedNot Detected

Amount(ppbv)

130

71

MethodLimits

70-13070-13070-130

Page 5 of 11

AIR TOXICS LTD.SAMPLE NAME: RUN#2 Can #12683


Compound

Freon 12Freon 1 1 4Chloromethane

Vinyl ChlorideBromomethane

ChloroethaneFreon 1 11,1-DichloroetheneFreon 113Methylene Chloride

1,1-Dichloroethanecis-1 ,2-DichloroetheneChloroform1,1,1 -TrichloroethaneCarbon Tetrachloride

Benzene1,2-DichloroethaneTrichloroethene1 ,2-Dichloropropanecis-1 ,3-Dichloropropene

Toluenetrans- 1 ,3-Dichloropropene1 , 1 ,2-TrichloroethaneTetrachloroetheneEthylene Dibromide

ChlorobenzeneEthyl Benzenem,p-Xyleneo-XyleneStyrene1 , 1 ,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1,3-Dichlorobenzene1 ,4-Dichlorobenzene

Chlorotoluene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobutadienePropylene

1,3-ButadieneAcetone

Rpt. Limit(ppbv)

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.76.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

27

27

27

Rpt. Limit(uG/m3)

34

48

14

17

26

18

38

27

52

24

28

27

33

37

43

22

28

36

31

31

26

31

37

46

52

31

30

30

30

29

47

33

33

41

41

35

41

50

73

47

60

65

Amount(ppbv)






Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected



Amount(uG/m3)










Page 6 of 11


ID#:0111476-02AEPA METHOD TO-14 GC/MS FULL SCAN

Compound

Carbon Disulfide2-Propanoltrans- 1 ,2-DichloroetheneVinyl Acetate2-Butanone (Methyl Ethyl Ketone)HexaneTetrahydrofuranCyclohexane1 ,4-DioxaneBromodichloromethane

4-Methyl-2-pentanone2-HexanoneDibromochloromethaneBromoform4-EthyltolueneEthanolMethyl tert-Butyl EtherHeptane

TENTATIVELY

Compound

None Identified


Surrogates


Rpt. Limit(ppbv)

27

27272727

27

27272727

272727

27

27

27

2727

IDENTIFIED

Rpt. Limit(uG/m3)

85

671109680

96

809498180

110110230

280

130

51

98110

COMPOUNDS - Top

CAS Number

%Recovery

101

99

92

Amount(ppbv)


10 Reported

Match Quality

Amount(uG/m3)


Amount(ppbv)

MethodLimits

70-13070-13070-130

Page 7 oM 1

AIR TOXICS LTD.SAMPLE NAME: Lab Blank


Compound

Freon 12Freon 1 1 4ChloromelhaneVinyl ChlorideBromomethane

ChloroethaneFreon 1 11,1-DichloroetheneFreon 113Methylene Chloride1,1-Dichloroethanecis-1 ,2-DichloroetheneChloroform1,1,1 -TrichloroethaneCarbon TetrachlorideBenzene1 ,2-DichloroethaneTrichloroethene1 ,2-Dichloropropanecis-1 ,3-DichloropropeneToluenetrans- 1 ,3-Dichloropropene1 , 1 ,2-TrichloroethaneTetrachloroetheneEthylene DibromideChlorobenzeneEthyl Benzenem,p-Xyleneo-XyleneStyrene

1 , 1 ,2,2-Tetrachloroethane1 ,3.5-Trimethylbenzene1 ,2,4-Trimethylbenzene1,3-Dichlorobenzene1 ,4-Dichlorobenzene

Chlorotoluene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobutadienePropylene1,3-ButadieneAcetone

Rpt. Limit(ppbv)

0.500.500.500.500.50

0.500.500.500.500.50

0.500.500.500.500.50

0.500.500.500.500.50

0.500.500.500.500.50

0.500.500.500.500.50

0.500.500.500.500.50

6.500.500.500.502.0

2.0

2.0

Rpt. Limit(uG/m3)

2.53.61.01.32.01.32.8

2.0

3.9

1.8

2.0

2.0

2.5

2.8

3.2

1.6

2.0

2.7

2.3

2.3

1.9

2.3

2.8

3.4

3.9

2.3

2.2

2.2

2.2

2.2

3.5

2.5

2.5

3.0

3.0

2.6

3.0

3.8

5.4

3.5

4.5

4.8

Amount(ppbv)


Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected



Amount(uG/m3)



Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DelectedNot Detected



Page 8 of 11



Rpt. LimitCompound

Carbon Disulfida2-Propanoltrans- 1 ,2-DichloroetheneVinyl Acetate2-Butanone (Methyl Ethyl Ketone)HexaneTetrahydrofuranCyctohexane1 ,4-DioxaneBromodichloromethane

4-Methyl-2-pentanone2-HexanoneDibromochloromethaneBromoform4-EthyltolueneEthanolMethyl tert-Butyl EtherHeptane

TENTATIVELY

Compound

None Identified

Container Type: NA - Not Applicable

Surrogates


(ppbv)

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

Rpt. Limit(uG/m3)

6.3

5.0

8.0

7.2

6.0

7.2

6.0

7.0

7.3

14

8.38.3

17

21

10

3.8

7.3

8.3


CAS Number

%Recovery

100

100

87

Amount(ppbv)


Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

10 Reported

Match Quality

Amount(uG/m3)


Amount(ppbv)

MethodLimits

70-13070-13070-130

Page 9 of 11

AIR TOXICS LTD.SAMPLE NAME: LCS


Compound

Freon 12Freort 114ChloromethaneVinyl ChlorideBromomethaneChloroethaneFreon il1,1-DichloroetheneFreon 113Methylene Chloride

1,1-Dichloroethanecis-1 ,2-DichloroetheneChloroform1,1,1 -TrichloroethaneCarbon Tetrachloride

Benzene1 ,2-DichloroethaneTrichloroethene1 ,2-Dichloropropanecis-1 ,3-Dichloropropene

Toluenetrans-1 ,3-Dichloropropene1 , 1 ,2-TrichloroethaneTetrachloroetheneEthylene DibromideChlorobenzeneEthyl Benzenem,p-Xyleneo-XyleneStyrene1 ,1 ,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-Dichlorobenzene

Chlorotoluene1,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobutadienePropylene1,3-BuladieneAcetone

Rpt. Limit(ppbv)

0.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.502.0

2.0

2.0

Rpt. Limit(uG/m3)

2.5

3.6

1.0

1.3

2.0

1.3

2.8

2.0

3.9

1.8

2.0

2.0

2.5

2.8

3.2

1.6

2.0

2.7

2.3

2.3

1.9

2.3

2.83.4

3.9

2.3

2.2

2.2

2.2

2.2

3.5

2.5

2.5

3.0

3.0

2.6

3.0

3.8

5.4

3.5

4.5

4.8

%Recovery

105

106

90

102

110

111

105

99

98

98

110

94

101

106

98

97

98

96

113

102

104

94

9698

119

95

99

103

115

105

97

93

93

81

79

93

79

54 Q

60 Q

104

109

107

Page 10 of 11



Rpt. LimitCompound

Carbon Disulfide2-Propanoltrans- 1 ,2-DichloroetheneVinyl Acetate2-Butanone (Methyl Ethyl Ketone)HexaneTetrahydrofuranCyclohexane1 ,4-DioxaneBromodichloromethane4-Methyl-2-pentanone2-HexanoneDibromochloromethaneBromoform4-EthyltolueneEthanolMethyl tert-Butyl EtherHeptane

Q = Exceeds Quality Control limits.

TENTATIVELY

Compound

None Identified


Surrogates


(ppbv)

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.02.0

2.0

2.0

2.0

2.0

2.0

2.0

Rpt. Limit(uG/m3)

6.3

5.0

8.0

7.2

6.0

7.2

6.0

7.0

7.3

14

8.3

8.317

21

10

3.8

7.3

8.3

%Recovery

105

116

106

115

107

107

108

103

107

100

105

106

99

102

98

103

102

105

IDENTIFIED COMPOUNDS - Top 10 Reported

CAS Number Match Quality

%Recovery

97

105

102

Amount(ppbv)

MethodLimits

70-13070-13070-130

Page 11 of 11

i AIR TOXICS LTD. 0 0 0 1AN ENVIRONMENTAL ANALYTICAL LABORATORY

-3• jJ

WORK ORDER #: 0111476

Work Order Summary

CLIENT: Mr. Joe JacksonAir Nova, Inc.5845 Clayton AvenuePennsauken, NJ 08109


PHONE:

FAX:

DATE RECEIVED:

DATE COMPLETED:

856-486-1500

856-486-98%

11/27/01

12/10/01

P.O.* AN-2914

PROJECT # 2461 Valley Crest

CONTACT: Betty Chu

FRACTION »

01 A02A03A04A

RUN#1 Can #31429 Air Toxics 2692RUN#2 Can #12683Lab BlankLCS

TEST

TO-14/TICsTO-14/TICsTO-14/TICsTO-14/TICs

RECEIPTVAC7PRKS.

27.0 "Hg27.0 "Hg

NANA

53'

CERTIFIED BY: DATE: 12/10/01

Laboratory Director

I his report shall not be reproduced, except in hill, without the written approval ol Air I oxics Ltd.

Certfication numbers: CA ELAP - 1149. NY ELAP - 11291, UT ELAP - E-217, AZ ELAP - AZ0567. LA - AI 30763Name of Accrediting Agency: NELAP/State of New York Department of Health, Scope of Accreditation : Non Potable Waler

Accreditation number: 11291, Effective date: 6/7/01, Expiration date: 4/1/02

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Page 1 of 11

LABORATORY NARRATIVETO-14

Air Nova, Inc.Workorder# 0111476

0 0 0 2

Two 6 Liter Summa Canister samples were received on November 27, 2001. The laboratoryperformed analysis via EPA Method TO-14 using GC/MS in the full scan mode. The method involvesconcentrating up to 0.5 liters of air. The concentrated aliquot is then flash vaporized and sweptthrough a water management system to remove water vapor. Following dehumidification, the samplepasses directly into the GC/MS for analysis. See the data sheets for the reporting limits for eachcompound.

During the five point calibration, two low-level standards are used. The low-level standard for TO-14compounds is spiked at 0.5 ppbv and represents the reporting limit for these compounds. Thelow-level standard for the non-TO-14 compounds is spiked at 2.0 ppbv and represents the reportinglimit for these compounds. The TO-14 compounds are present in both standards but are excluded fromreporting in the 2.0 ppbv standard since a lower level is already included in the curve.

Method modifications taken to run these samples include:

Requirement

Internal standard retentiontimes.

Internal standard recoveries.

Initial calibration criteria.

Continuing calibrationverification criteria

Response factor forquantitation.

TO-14

Not specified.

Not specified.

Not specified.

Not specified.

Average responsefactor (ICAL).

ATL Modifications

Within 0.50 minutes of most recent daily CCV internalstandards

Within 40% of the daily CCV internal standard area forblanks and samples.

RSD of 30% or less for standard compounds, 40% or lessfor non-standard and polar compounds

70 - 1 30% for at least 90% of standard compounds, 60 -140% for at least 80% of non-standard and polarcompounds

Average response factor (ICAL).

Receiving Notes

Samples RUN#1 Can #31429 Air Toxics 2692, and RUN#2 Can #12683 were received withsignificant vacuum remaining in the canister. The client was contacted and analysis proceeded. Theresidual canister vacuum resulted in elevated reporting limits.

rrr

Analytical Notes

There were no analytical discrepancies.

Definition of Data Qualifying Flags

Seven qualifiers may have been used on the data analysis sheets and indicates as follows:B - Compound present in laboratory blank greater than reporting limit(background subtraction not

performed).J - Estimated value.E - Exceeds instrument calibration range.S - Saturated peak.Q - Exceeds quality control limits.

Page 2 of 11

J

0 0 0 3

U - Compound analyzed for but not detected above the reporting limit.N - The identification is based on presumptive evidence.

Page 3 of 11

0 0 0 4

Table 1

Sample Sample Extract

Client Lab Date Date Date Holding Date Holding Sample

Sample ID Sample ID Collected Received Extracted Time Analyzed Time Condition(Days) (Days)

ÛNn Can #31 429 Air!

RUN#2 Can #12683

Lab Blank

LCS

01 11 476-01 A

0111476-02A

0111476-03A

0111476-04A

11/20/2001

11/20/2001

MA

NA

11/27/2001

11/27/2001

NA

NA

NA

NA

NA

NA

10

10

NA

NA

11/30/2001

11/30/2001

11/29/2001

11/29/2001

NA

NA

NA

NA

Good

Good

Good

Good

0 0 0 5

Sample Results and Raw Data

0 0 0 6



Compound

Freon 12Freon114ChtoromethaneVinyl ChlorideBromomethaneChloroethaneFreon 111,1-DichloroetheneFreon 113Methytene Chloride1 , 1 -Oichloroethanecis-1 ,2-OichloroetheneChloroform1,1,1 -TrichtoroethaneCarbon TetrachlorideBenzene1 ,2-DichloroethaneTrichloroethene1 ,2-Dichk>ropropanecis-1 ,3-DichloropropeneToluenetrans- 1 ,3-Dichloropropene1 ,1 ,2-Trichk>roethaneTetrachloroetheneEthytene DforomideChlorobenzeneEthyl Benzenem,p-Xyleneo-XyteneStyrene1 ,1 ,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-DichlorobenzeneChlorotoluene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobutadienePropylene1 ,3-ButadieneAcetone

Rpt. Limit(ppbv)

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

27

27

27

Rpt. Limit(uG/m3)

34

48

14

17

26

18

38

27

52

24

28

27

33

37

43

22

28

36

31

31

26

31

37

46

52

31

30

30

30

29

47

33

33

41

41

35

41

50

73

47

60

65

Amount(ppbv)


41Not Detected

7.146

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected


9.6Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

59Not Delected

150

Amount(uG/m3)


85Not Detected

28120

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected


37Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

100Not Detected

360

Page 4 oM 1

0 0 0 7

AIR TOXICS LTD.SAMPLE NAME: RUNtfl Can #31429 Air Toxics 2692

IM: 0111476-01A


Compound

Carbon Disulfide2-Propanoltrans-1 ,2-OichloroetheneVinyl Acetate2-Butanone (Methyl EthylHexaneTetrahydroluranCyclohexane1,4-DioxaneBromodichloromethane

4-Methyl-2-pentanone2-HexanoneDibromochlorometrtaneBromoform

4-EthyttolueneEthanolMethyl tert-Butyl EtherHeptane

Rpt. Limit(ppbv)

27

27

27

27

Ketone) 2727

27

27

27

27

27

27

27

27

27

27

27

27

Rpt. Umlt(uG/m3)

85

67

110

96

80

96

80

94

98

180

110

110

230

280

130

51

98

110

TENTATIVELY IDENTIFIED COMPOUNDS - Top

Compound

1-Propene, 2-methyl-Unknown

CAS Number

115-11-7NA

Amount(ppbv)


10 Reported

Match Quality

72%

NA

Amount(uG/m3)


Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

Amount(ppbv)

13071


Surrogates

1 ,2-Dichloroethane-d4Toluene- d84-Bromofluorobenzene

%Recovery

10199

91

MethodLimits

70-13070-13070-130

Page 5 of 11

0008Data File: /chem/msdg.i/g-29nov.b/gll2924.dReport Date: 10-Dec-2001 13:37

Page 1

Data fileLab Snp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth DateCal DateAls bottleDil FactorIntegratorTarget Version: 3.50Processing Host: eeyore

Air Toxics Ltd.

AMBIENT AIR METHOD TO14 ./chem/msdg.i/g-29nov.b/gl!2924.d0111476-01A --~" Client Smp ID: RUN#lCan#31429AirTo*ic£30-NOV-2001 00:46xp — Inst ID: msdg.i200mL can#31429 —-27"Hg-5psi Air Nova

/chem/msdg.i/g-29nov.b/to!41102.m30-NOV-2001 05:44 xpan Quant Type: ISTD23-NOV-2001 14:27 Cal File: gl!2308.d113.40000 —HP RTE Compound Sublist: AT. sub

rtif

Sample Matrix: AIR

Concentration Formula: Amt * DF * CpndVariable

Cpnd Variable Local Compound Variable

RT

CONCENTRATIONS

ON-COL FINAL

BXP RT (RKL RT) MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO SIMILARITY

• S3 Brorochloron

15.059

15.059

15.059

• 69 1.

16.908

16.908

IS,

15.

IS.

.034 (1

.034 (0

.034 (0

ethane

.000)

.000)

.000)

130

128

49

320107 25.0000

54720

150336

4 - Di f Luorobensene

16.

16.

883 (1

.683 (0

.000)

.000)

114

88

1372602 25.0000

41392

• 90 Chlorobenzene-d5

22.510

22.510

$ 63 1.

16.218

16.218

22.

22.

,513 (1

,513 (1

.000)

.000)

2 -Dichloroethane -

16.

16.

193 (1

193 (0

.077)

.000)

117

82

d4

65

67

819609 25.0000

538811

CAS 1: 74-97-5

80.00-

29.56-

196.68-

CAS «: 540-36-

80.00-

0.00-

120

129

296

3

120

67

.00

.56

.68

.00

.48

100.

17.

46.

100.

3.

00

09

96

00

02

8931

9176

CAS I: 3114-55-4

80.00-

17.72-

120

117

.00

.72

100.

65.

00

74

CAS I: 17060-07-0

708836 25.2822

72056

S 79 Toluene -d8

19.723

19.723

19.

19.

.698 (1

.698 (0

.166)

.000)

98

70

1125176 24 .7781

29122

25.282 80.00-

0.00-

CAS *: 2037-26

24.778 80.00-

0.00-

120

99

-S

120

62

.00

.91

.00

. 12

100.

10.

100.

2.

00

17

00

59

10000

10000

I-k

fcata File: /chem/msdg.i/g-29nov.b/gl!2924.dReport Date: 10-Dec-2001 13:37

Page 2 0 0 0 9

RT

CONCENTRATIONS

ON-COL FINAL

EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TARGET RANOB RATIO SIMILARITY

5 79 Toluene -d8 (continued)

19. 723 19.698 (0.000) 100 171136 20.05- 120.05 15.21

~£$ 101 Bronofluorobenzene

J 24. 635

24.635

^24.635

\j

24.611

24.611

24.611

(1.

(0.

(0.

094)

000)

000)

95

174

176

512477 22.7473

106656

106208

2 Propylene

6.034

'': t *

.J eTo34

6.009

6.009

6.009

(0.

(0.

(0.

401)

000)

000)

41

42

39

96800 4.38668

7039

10003

^ 7 Chloronethane

a 7.0007.000

|J 13 Br

•3 8.683

8.683

•3

6.975

6.975

(0.

(0.

465)

465)

50

52

113929 3.03203

50816

DBone thane

8.659

8.659

(0.577)

(0.000)

94

96

8916 0.52755

571

• a ~-j 15 Chloroethane

9. 015

rt 9.0158.990

8.990

(0.

(0.

599)

000)

64

66

49858 3.47646

1700

28 Acetone

11 '

'-y,ii>«211.087

11.087

(0.

(0.

738)

000)

43

58

533092 11.1740

22528

64 Benzene

16.245

J16.245

16.221

16.221

(0.

(0.

961)

000)

78

77

256644 3.01245

9735

~( 80 Toluene

.J19.833

~*19.833

19.836

19.836

(1.

(0.

173)

000)

91

92

49178 0.71599

5300

CAS «:

22.747

CAS t:

58.782

CAS 1:

40.629

CAS 1:

7.069

CAS *:

46.584

CAS 1:

149.73

CAS *:

40.367

CAS «:

9.594

460-00-4

80.00-

0.30-

0.00-

120.00

100.30

98.30

100.

20.

20.

00

81

72

8419

115-07-1

80.00-

15.40-

30.90-

74-87-3

80.00-

0.00-

74-83-9

80.00-

44.79-

75-00-3

80.00-

0.00-

67-64-1

80.00-

0.00-

120.00

115.40

130.90

120.00

79.72

120.00

144.79

120.00

81.47

120.00

74.97

100.

7.

10.

100.

44.

100.

6.

100.

3.

100.

4.

00

27

33

00

60

00

40

00

41

00

23

7620

5732

4019

6524

71-43-2

80.00-

0.00-

108-88-

80.00-

11.65-

120.00

72.61

3

120.00

111.65

100.

3.

100.

10.

00

79

00

7B

5943

8155

Data File: /chen\/msdg.i/g-29nov.b/gll2924 .dReport Date: 10-Dec-2001 13:37

Page 30010

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth DateCal DateAla bottleOil FactorIntegrator-

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-29nov.b/gll2924.d0111476-01A30-NOV-2001 00:46xp200mL can#3142927"Hg-5psi Air Nova

Client Smp ID: RUN#lCantt31429AirTo

Inst ID: msdg.i

/chem/msdg.i/g-29nov.b/tol41102.m30-NOV-2001 05:44 xpan Quant Type: ISTD23-NOV-2001 14:27 Cal File: gl!2308.d113.40000HP RTE Compound Sublist: AT.sub

Target Version: 3.50Processing Host: eeyore

Sample Matrix: AIR



ISTD RT AREA AMOUNT

* 53 Bromochloromethane 15.059 2303201 25.000

CONCENTRATIONS

RT AREA OH-OOM PPBV) FINAL( PPBV) QUAL

QUANT

LIBRARY LIB ENTRY CPND •

1-Propene. 2-Mthyl-

7.276 911688 9.69587608

CAS I: 115-11-7

132.60 72 NBSS4K.1 79

Unknown

11.885 490681 5.32607383

CAS I:

71.369 53

Jlpata File: /chem/msdg. i/g-29nov.b/gl!2924 .dReport Date: 10-Dec-2001 13:37

3S Air Toxics Ltd.

Page 4 0© 11

INTERNAL STANDARD COMPOUNDSAREA AND RT SUMMARY

Instrument ID: msdg.i-Tjab File ID: gl!2924.dJjab Smp Id: 0111476-01AAnalysis Type: VOAr£uant Type: ISTD^Dperator: xpMethod File: /chem/msdg.i/g-29nov.b/tol41102.mMisc Info: 27"Hg-5psi Air Nova

Calibration Date: 29-NOV-2001Calibration Time: 06:35Client Smp ID: RUN#lCan#31429AirToLevel: LOWSample Type: AIR

Ji

IMPOUND

53 Bromochloromethan69 1,4-Difluorobenze90 Chlorobenzene-d5

STANDARD

"\ 3438621518725966768

AREA LIMITLOWER

206317911235580061

UPPER

48140721262151353475

SAMPLE

3201071372602819609

%DIFF

-6.91-9.62-15.22

COMPOUND


STANDARD

15.0316.8822.51

RT ILOWER

14.5316.3822.01

jIMITUPPER

15.5317.3823.01

SAMPLE

15.0616.9122.51

%DIFF

0.160.15-0.01

UPPER LIMIT = + 40% of internal standard area.AREA LOWER LIMIT = - 40% of internal standard area.

UPPER LIMIT = + 0.50 minutes of internal standard RT.LOWER LIMIT = - 0.50 minutes of internal standard RT.

Data File: /chem/msdg.i/g-29nov.b/gl!2924.dReport Date: 10-Dec-2001 13:37

Air Toxics Ltd.

Page 50012

RECOVERY REPORT

Client Name:Sample Matrix: GASLab Smp Id: 0111476-01ALevel: LOWData Type: MS DATASpikeList File:Sublist File: AT.subMethod File: /chem/msdg.i/g-29nov.b/to!41102.mMisc Info: 27"Hg-5psi Air Nova

Client SDG: g-29novFraction: VOAClient Smp ID: RUN#lCan#31429AirToOperator: xpSampleType: SAMPLEQuant Type: ISTD

SURROGATE COMPOUND

$ 63 1,2-Dichloroethane$ 79 Toluene -d8$ 101 Bromofluorobenzene

CONCADDEDPPBV

\_25.00025.00025.000

CONCRECOVEREDPPBV

25.28224.77822.747

%RECOVERED

101.1399.1190.99

LIMITS

70-13070-13070-130

IS

f.

Dat* : 30-NOV-2001 00:46

Client ID: RUNtlC«nt3142MirTo

Sanpl* Infot 200M. o*n»31429

Coluwi ph«»»: RTx-624Operator:

diwwtcr: 0.53

^^

t

6.4

6.2

6.0

B.8

B.6

B.4

B.2

B.O

4.8

4.6

4.4

4.2

4.0

3.8

3.6

3.4

3.2

2.8

2.6

2.4

2.2

2.0

1.8

1.6

1.4

1.2

1.0

0.8

0.6

0.4

0.2, ,

,/

10 11 12 13 J/4 IB 16

-WK«—17

1W5??-

18 19 20 21 '22—&? • <—mm—w-;t

23 31 32

Dat* Fil»J

Dat* J 30-NQV-2001 00:46

Client ID: RUNtlCanfl31429AirTo

Info: 200*L can*31429

0014

Column phas«t RTx-624

2 Propyl«n*

Instruitnt; *sdf.i

Operatort xp

Column dian»t«rt 0.53

Concentration: 68.762 PPBV

f-

s

2.01.81.61.41.21*0.80.6^0.4

o.oJ

"-44Scan 17 <6.034 n in) of fll2924.d

207

80 100 120m/i

140 160 180 200

1.11.00.90.80.70.60.80.40.30.20.10.0

Sow 17 <6.034 p»ln) of {112924.d <8ubtr»ot*d>

133\40 80 100 120

n/z140 160 180 200

10.0

9.0

8.0

7.0

6.0

5.0

: 4.0

3.0

2.0

1.0

0.0

412 Propyltn* <R»f«r«nc» Sp«otrtM>

40 60 80 100 120 140 160 180 200

100

80

60

40

20

0

-20

-40

-6O

-80

-100

Scan 17 (6.034 *in> of (112924.d (X DIFFERENCE)

x75

40 60 80 100 120 140 160 180 2005*15

Ion 41

£t-.

f

B.6 8.8 6.0Hin

6.2 6.4 6.6

Ion 42

Ion 39.

5.6 5.8 6.0Hin

6.2 6.4 6.6

0015

<X.Y>:l|f* UQrw na

HP MS

<~Y -

P MS

VHP MS

HP MS

~^^

8.592, 6486016gl!2924.d, Ion 50.00 1

_^____— .A6 6.5 7

gl!2924.d. Ion 52.00

III ^*1 ' 1 • ^~|^ 1 "*^"*i 1 ~~t 1 1

6 6.5 7gl!2924.d, Ion 44.00

-^^

6 6.5 7gl!2924.d, Ion 57.00

A A /6 6.5 7

gl!2924.d, Ion 78.00 J

•s, *" _^^N** -«. — . A ^S. -* ^ — /

«ctlv. Sp tn-: t~.r^| c|J* Xr CCkA*V_X: Y:

6.0-

' ' i

L 3.0-

< 2.0--

^ t * 1 MS gll2924.d, Scan 52: 7.000 win. (SUB)

50-

1 103x /H9 177

I J . ^ ' N.

JO 6O 90 120 150 180 210 240

6.0-1 :

I 3.0-i

< 2.0-j

» 1.0-i

HP MS gll2924.d, Scan 1: 5.592 win.

lOlv /131 191\ /207 2

30 60 90 120 150 ISO 210 240

0.0-;

> -i.o-i5 -2.0^

1 -4'°--5.0-i

v '.

HP MS gll2924,d. Scan 52: 7.000 pin. (SUB) (DIFF)- r -SO - 103-" ^19 .77 -

Data FiU: /chM%/Mdc.t/r-29txiv.b/cll2924.d

Dat» t 30-NOV-2001 00:46

Clitnt ID: RUHtlCant31429AirTo

Info: 2CX*L can*31429

0 0 1 6

Colupm phas*: RTx-624

7 CMorotwthan*

Instrwcnt:

Operator; xj»

Colunn diaiwtcr: 0.53


6.0

5.0

4.0XN

1 3'°x~ 2.0

1 6*.v

0.0

9.0

8.0

7.0

6.0

n 5.0

3 4.0X

2.01.00.0

10.0,9.08.0

7.0~ 6.0r><0 5.0^ A AJC ^«,V'

> 3.02.01.00.0

100,8060

4020

- 02z -40

-80-100

-A.40

^40

60-

L40

44-'

^

40

x^

J

if

\

Scan 62 <7.000 *ln> of (112924.d44

L /78 "•'v >*33 l77^ 2°^ ^M. _. J.^ ... .. . . . „ L >60 80 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0 2 2 0 2 4 0 2 6 0 2 8 0

n/z^^ Scan 52 <7.000 nin> of (112924.d (SubtraoUd)

1 /"

J "N^ y433 177\ 20*\ ^L * n t i n k i l h i . l i r

60 80 100 120 140 160 180 200 220 240 260 280H/Z

7 ChloroMthan* <R*f*r«nc* Spcotnn)

60 80 100 120 140 160 180 200 220 240 260 280

Scan 62 <7.000 Kin) of fH2924.d <X DIFFERENCE)

7ft

X . i J . • •Ate « • • . . . . i d . .

60 80 100 120 140 160 180 200 220 240 260 280

Ion 60.00

6.6 6.9 7.2 7.5Hin

Ion 52.003.4-; ft |3.2^ n ,:3.0-; 1 12.8-: | S2.6^2*4~- j I2.2^' I \2 A * * 1

-• * : I 1J> 1 \

^ 1.4-1 1> 1.2-: f V

1*°J- 1 \o.e-j 1 \0.6H J \0.4-; 1 t*\l'l\ AA M /

6.6 6.9 7.2 7.6Hin

rr

3iData File: /ohem/msdc.i/e-29nov.b/cll2924.d

S Date : 30-NOV-2001 00:46a1 Client ID: RUNtlCant31429AirTo

Sample Info: 200*4. oan*31429

\J Column phase: RTx-624

-. 13 Bromomethê

5 Scan 113 (8.683 min) of (112924. d^^^^

9.0

3 8.0

S

M

4£ 5*°%3 4.0

f"

,.,.,00

Instrument: nsdc.i

Operator: xp

Column diameter: 0.63


207^

^^>^^ t

1 || /** S3* 177\ik H I hi ill I i i 1 1 It

40 60 80 100 120 140 160 180 200 *220 240 260 280

Scan 4*3 (8.683 min) of (112924.d (Subtracted)

1.2

1.0

0.8n

3 °'6

^0.4

* 0.0

94^

/**

1,1 ,1JJ II i\

"Vi. *

>115

I I1 i 1

•3, 40 60 80 100 120 140 160 180 200*r m/z

U» ^

^cH .v/S •<*>>/*** r«y>i v_X

220 240 260 280

1 13 Iromomethane (Reference Spectrum)

^ >*0

-p 8.0

I I*o& *« 8.0

J3 4*°1 3.«,J 2.0

1 0.0

*N

^ 1 140 60 80 100 120 140 160 180 200 220 240 260 280

Z^ Scan 113 (8.683 *in> of (112924. d (X DIFFERENCE)

1 ™.

60

d! 40

f ,»j -20

T* -40

-80

T-100

*"\

jjjl J , J L 1 . 1

40 60 80 100 120 140 160 ISO 200n/z

X2oe

220 240 260 280

Ion 94.00

1.2 j .ft *

1.1 |

1.0

n1

, °'8

IS0.4 1

\«•*• , UA / «ft fl Ill T 1

8.1 8.4 8.7 9.0Hin

Ion 96.00k

1.5 A

1.4 Mi<3 rs1.2 / rI IIn 1*1 Jk 1 1<. (1 l J 1 1 Jl• j j • 1 l i A J I I n 4 / l^ 0.9 A Jill 11 Al l /V 1

*" 11 1 III JUll fl / M y" IAJ h 1 | Y*.6 In H |O.B y I

, . , , . . , . . , . .8.1 8.4 8.7 9.0

Hin

Data File: /chM/nsdc.i/'c-29nov.kv'cll2924.d

Date : 30-NOV-2001 00;4«

Client ID: RUHtlCan*31429AirTo

Info; 2004. car431429

Pace 100018

Instrument:

Column phase: RTx-624

IS Chloro*than*

: xp

ColiOT dlaneter: 0.53


5.58.04.84.0

~ 3.5£ 3.0O

~ 2.0> 1.8

1.0-0.8

8.58.04.84.0

fi 3'8e- 3-'"x 2«5

~ 2.0*" 1.8

1.00.80.0

10.09.08.0

7.0

^ al AJC â, V1

> 3.02.01.00.0

1008060

4020

- 0I -20

z -40

-60-80

-100

64-'

, I

ill 140 60

64--

I*J • •40 60

64-'

^.40 60

/*2 7

r*^l_tJM, •.

40 60

Scan 125 (9.018 *ln> of (112924.d207>^

1 *\ ^ /133

1 ..I I7* 1 , i L . i80 100 120 140 160 180 200 220 240 260 280

m/xScan 128 (9.018 nln) of (112924. d (Subtracted)

/T8 /103 14% 177, 20^ 26%

1 I I i 1 I I 1 - i I I80 100 120 140 160 180 200 220 240 260 280

H/T.IS Chloroethane (Reference SpectrtM)

80 100 120 140 160 180 200 220 240 260 280n/z

Scan 129 (9.015 "in) of (U2924.d (X DIFFERENCE)

N x103 x133 177\ 20N 26Ny i i . i i t i _ i i •

80 100 120 140 160 180 200 220 240 260 280m/z

Ion 64.00

8.4 8.7 9.0 9.3Hin

1.7, Ion «*•*• s1 6-i il *i:5-|1.4* I

il1.0- / 1* • I I

« 0 9-i 1 \* 0*8 I*1 °'81 \3 0.7^>- 0.6^ V

°-5i I0.4-i I0.3-j \A * ' • i l l«i / H

8.4 8.7 9.0 9.3Hin

It

fc

Data File: /chen/Msd(.l/(-29nov.b/cll2924.d

-- Date : 30-HOV-2001 00:46'5j.?? Client ID: RUNM.Can«3i429AirTo

Sanple Info: 200*L can«31429

•^ Coluwi phase: RTx-624

— 28 Aoetone

Pat* 11

Instrument:

Operator t xp

Colupn dianeter: 0.63


I '-1J, 8.0

1 ;•:J| B-«f> 3.0

,,

• 0.0

9.0

7 A.

6.0

5^ 5.0

"x 4.0

1 3.0

[ S-5 o.o

,HJ 8.0

7.0

~ 6.0

C B.Ort A ft\c 4*°U 3.0

1 2.0.

T o.oJ.

-r 100

60

li «*•

L •::J -»•-r* -40

1 -60

-80

-100r

Ju4C

jLi

44

L

44

/

40

Scan 201 (11.112 i»ln> of (112924.d

1 ^N

. -.1 L .60 80 100 120 140 160 180 200 220 240 260 2ov

n/z

Scan 201 (11.112 nin) of (112924.d (Subtracted)

96v U9ss 147v y!60 20^ ^82

60 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0 2 2 0 2 4 0 2 6 0 2 8 0H/Z

. 28 Aoetone (Reference Speotrun)• 43 ^^

I

1.160 80 100 120 140 160 180 200 220 240 260 280

Pt/Z

Scan 201 (11.112 »in> of cli2924.d (X DIFFERENCE)

.

60 80 100 120 140 160 18O ZOO 220 240 260 280

Ion 43.00

f 1

H fl;:?••«3 '•*"- . L ,c o — ' J ^^— — '

10.6 10.8 11.1 11.4Hin

Ion 68.00

2.4: r a2.2: n a2.0-: 1 1

"1O 4 9J I 1

1*°-*" 0.8-: I I

0.6-; J I

0.4-: I I°-2-; A] L_0.0- '

10.6 10.8 11.1 11.4Hln

0020 I

HP MS gll2924.d, Ion 78.00

A 14.5 15HP MS gl!2924.d, Ion 65.00

15.5

HP MS gj.!2924.d, Scan 387: 16.245 •in. (SUB)

x52*...ILL

~so

|L »N

30 60 90 120 ISO 180 210 240

Hf MS gl!2924.d, Scan 384: 16.163 win.

1.8-

1.5-1

1.2-|

0.9-|

0.6-;

0.3-:

0.0 ..L /7S

1 /133 191\i 1 . ll / X

/207/ 28

30 60

HP MS gll29^4.d, Scan 387: 16.245 min . (SUB) ( D I F F )90 120 150 180 210 24O

269N

Data File: /chtft/M*dc.i/c-29nov.tb'cll2924.d

Dat* t 30-NOV-2001 00:46

12 0 0 2 11'. Client ID: RUNtlCan*31429AirTo Instrument: itsdc.i

Sa»f>le Info: 200nL can«31429

kOrator: xp

* Colum phase: RTx-624 Coluwi diameter: 0.53

- 64 Benzene

I e.K '

1.1

1.0^ 0.9^ 0.8L 0.7.1| ••••a 0.6JXH

,» 0.0

w^r

J.J

y*'

J


Scan 387 (16.246 Hin) of (112924. d

?

X102

1. A33 17X »7\^ 281 83i IL . . _ k. . ;:

40 60 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0 2 2 0 2 4 0 2 6 0 2 8 0n/z

1 Scan 387 (16.248 nln) of (112924.d (Subtracted)

i.l]1.00.9

1 0.8•j °*Ik 0.7

|S 0.8*P 0.4.V 0.3

« 0.0

v*r

Ju

/*"

J7

^02

i IL . ..-J 40 60 80 100 120 140 160 180 200 220 240 260 280Jl5\jJ 8.0

f 7.0^ 6.0C 6.0fx 4.0^j" 2*0

r o.o

78^

•N

n/z64 Benzene (Reference Spectrun)

i.l.i-, 40 60 80 100 120 140 160 180 200 220 240 260 280

n/z** Scan 387 (16.246 nin) of cl!2924.d (X DIFFERENCE)r î

60

•V* 40r'

].*:r- -4oJ

1 -«o-80

-100

61v

V-4--J

^«

^-1(f

F 40 60 80 100 120 140 160 180 200 220 240 260 2801 m/z

Ion 78.00

3.9 Jf «5fl vfl

3.6

3.3

3.02.7

~ ™

{s> 1.8

1.2 J 1l0.9 1

\J \ ,

18.9 16.2 16.6 16.8Hin

Ion 77.00

8.0 11

7.0 J 1

6.0 I IN ) I I

* J 1

3 4 . 0 J l

3.0 I I

2.0 I

1.0 J \1 1

A A ^V W V \. >V ^VW.V-— ' . . , . . , . . , . . ,

16.9 16.2 16.6 16.8Hin

Data Filet

Date : 30-NOV-2001 00;4t

Client ID: RUNtlCanl3i429AirTo

Sanple Info: 200«L cani31429


BO Toluene

Pace 130022

Instrument:

Operator: xp

Colunn dlaneter: 0.53

Concentration: 9 .594 PPBV

9.O

8.0

7.0

~ 6.0? 5.0

3 4'°^ 3.0

2.01.0

0.0

^

/

Li ii k. ,,

Scan 517 (19.833 nin> of (112924. d

281

U ii i li I i Ik 140 60 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0 2 2 0 2 4 0 2 6 0 2 8 0

M/Z

Scan ya (19.833 »in> of (H2924.d (Subtracted)

9.0

6.0

7.0

6.0<* 5.063 4.0^ 3 0

2.0

1.0

0.0

•n.

y39

,1 .11 . „

±7?\ 2°N 2?1\L i i j . j .

40 60 80 100 120 140 160 180 200 220 240 260 280M/Z

10.0,9.08.0

7.0~ 6.0

2 8«°^ 4.0v

> 3.02.01.00.0

91-"

39

LuL.-,

80 Toluene (Reference Spectrum)

40 60 80 100 120 140 160 180 200 220 240 260 28Om/i

Scan 517 (19.833 ntn> of (112924. d (X DIFFERENCE)100 180

60

4020

- 0£ -20* -40

-60-80

-100

87\ 177\ X191 271\r-r--n- ^r

40 60 80 100 120 140 160 180 200 220 240 260 280n/z

Ion 91.00

fi" 89.0 I •1

8.0

7.0

6.0

£> 5.0 f

U . 1-5 4.0 I

3.0

2.0 1I

1.0 1 I

19.0 19.8 20.1 20.4Hin

Ion 92.005.6 Jfts4.8 ^

1 \ T44.44.03.6

fi 3'2

o 2.82 I l5 2.4

1.61.20.80.4 I \ft 0 ' »

•^ * • 1 • • I • • 1 • • •

19.5 19.8 20.1 20.4Hin

Data File: /ohe«/Pi»de.l/c-29nov.b/sll2924.d

Date t 30-NOV-2001 00t46

Client IDt RUNtlCant31429AirTo

Sanple Info; 200nL can*31429

Colum phaset RTx-624

Library Search Confound Hatch

02 3

Instrument:

Operator: xj>

Column dimeter: 0.53

CAS Hunber Library Entry Quality Fomula Height

1 1-Propene, 2-wethyl- 118-11-7 KBS64K.1 79 72 C4HB 062-Butene, <E>- 624-64-6 KBS54K.1 76 64 C4H8 562-Butene, (Z>- B90-18-1 NBS64K.1 78 64 C4H6 06

8.0

r>r*1 2*°

0.0

10.0

8.0

£ *•«

^ «.0'

1 2.0

0.0

10.0,

8.0

i:r o.o.

f io*°ii. ...i '•'-^ 4.0

J

0.0

..nil

Scan 62 (7.276 nin> of f!12924.d (Subtracted) (SCALED)

rill ^N /** ^117^ 28 y*^*

0 2 0 4 0 6 0 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 6 0 2 2 0m/x

41-"

"\ II. J. 1

Entry §79, 1-Propene, 2-«ethyl- (from NBSB4K.1) (SCALED)

06v\

l ll.l, 1

0 20 40 60 80 100 120 140 160 180 2 0 0 2 2 0m/z

41-

. ^ .ill. „

Entry t76, 2-Butene, (E>- (from HBS84K.1) (SCALED)

~\

1. ..11,1.

t

0 20 40 60 80 100 120 140 160 180 200 220n/z

41-

•N

...l il

Entry 178, 2-Butene, (Z>- (from NBS04K.1) (SCALED)

56N

,. ..II.I.

it

1.

0 20 40 60 80 100 120 140 160 180 200 220H/Z

Data Fil»t

Date I 30-NOV-2001 00:46

Client ID; RUNtlCant314e9AirTo

Sanple Info: 2CKM. car>i31429

ColiMn phase; RTx-624

Library Search Co ound Hatch

Unknown

Pate 0 0 2 4

: Hsd(.i

Operator: xp

Colupin dianeter; 0.53

CAS Nwbir Library Entry

0

Quality Fornula

0

r

10.0

1"

2.0

0.0

Scan 229 <11.885 nin> of (112924.4 (SU>tracUd> <SCALED>

121\ 17X 192v

40 50 70 80 90 100 110 120 130 140 150 160 170 180 190 200m/z

0 0 2 5


ID#: 01H476-02AEPA METHOD TO-14 GC/MS FULL SCAN

Compound

Freon 12Freon114ChloromethaneVinyl ChlorideBromomethaneChkxoethaneFreon 111 ,1 -DicNoroetheneFreon 113Methytene Chloride1,1-D(ch)oroethanecis-1 ,2-DichloroetheneChloroform1,1,1 -TrichloroethaneCarbon TetrachlorideBenzene1,2-DichloroethaneTrichloroethene1 ,2-Dichtoropropanecis-1 ,3-DichloropropeneToluenetrans- 1 ,3-Dichloropropene1 ,1 ,2-TrichloroethaneTetrachloroetheneEthylene DibromideChtorobenzeneEthyl Benzenem,p-Xyleneo-XyleneStyrene1 ,1 ,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-DichlorobenzeneChlorotoluene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobutadienePropylene1 ,3-ButadieneAcetone

Rpt. Limit(ppbv)

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

6.7

27

2727

Rpt. Limit(uG/m3)

3448141726

18

38

27

52

24

28

27

33

37

43

22

28

36

31

31

26

31

37

46

52

31

30

30

30

29

47

33

33

41

41

3541

50

73

47

60

65

Amount(ppbv)

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNol DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNoi DetectedNot Detected

Amount(uG/m3)

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

Page 6 of 11

0 0 2 6



Compound

Carbon Disulfide2-Propanoltrans- 1 ,2-DichtoroetheneVinyl Acetate2-Butanone (Methyl Ethyl Ketone)HexaneTetrahydrofuranCyctohexane1 ,4-DioxaneBromocficWoromethane4-Methy(-2-pentanone2-HexanoneOibromochloromethaneBromoform4-EthyitokjeneEthanolMethyl tert-Butyl EtherHeptane

TENTATIVELY

Compound

None Identified


Surrogates

1 ,2-Dichloroethane-d4Toluene-cl84-Bromofluorobenzene

Rpt. Limit(ppbv)

27

27272727

27

27272727272727

27

27

27

2727

Rpt. Umlt(uG/m3)

85

671109660

96

809498180110110230

280

130

51

98110

IDENTIFIED COMPOUNDS • Top

CAS Number

%Recovery

101

99

92

Amount(ppbv)


10 Reported

Match Quality

Amount(uG/m3)


Amount(ppbv)

MethodLimits

70-13070-13070-130

I

Page 7 ol 11

Data File: /chem/msdg.i/g-29nov.b/gl!2925.dHJReport Date: 10-Dec-2001 13:37

Page 10027

,. Data file^Lab Smp IdInj Date

§OperatorSmp InfoMisc Info

"• Comment^Method

Met-.h Date_C Date

bottleFactor

IntegratorjTarget Version: 3.50JProcessing Host: eeyore

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-29nov.b/gl!2925.d0111476-02A -^ Client Smp ID: RUN#2Can#1268330-NOV-2001 01:24xp Inst ID: msdg.i200mL can#12683 .27"Hg-5psi Air Nova

/chem/msdg.i/g-2 9nov.b/to!41102.m30-NOV-2001 05:44 xpan Quant Type: ISTD23-NOV-2001 14:27 Cal File: gl!2308.d113.40000 -—HP RTE Compound Sublist: AT.sub

Sample Matrix: AIR

U-IO-O)

roncentration Formula: Amt * DF * CpndVariable


CONCENTRATIONS

ON-COL FINAL

EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TAROBT RANGE RATIO SIMILARITY

1* 53 Brooochloromethane15.059

^ 15.059

'•* 15.059

?]* 69 1,

[| 16.908

16.908

15

15.

15.

.034 (1

.034 (0

.034 (0

.000)

.000)

.000)

130

128

49

319323 25.0000

52448

137408

4 - Di f luorobenzene16.

16.

.883 (1

.883 (0

.000)

.000)

114

88

1354360 25.0000

43280

—> 90 Chlorobenzene-dS

22.511

22.511

ii* 63 1.

16.218

'j 16.218

22

22.

.513 (1

.513 (1

.000)

.000)

2 - Dichloroe thane -16.

16

.193 (1

.193 (0

.077)

.000)

117

82

d4

65

67

808197 25.0000

543064

CAS #: 74-97-5

80

as196

.00- 120

.56- 129

.68- 296

.00

.56

.68

100

16

43.

.00

.42

.03

8975

CAS 1: 540-36-3

80

0

.00- 120

.00- 67

.00

.48

100.

3.

.00

.20

9157

CAS *: 3114-55-4

80

17

.00- 120

.72- 117

.00

.72

100.

67.

.00

.19

CAS •: 17060-07-0

708867 25.3454

74800

S 79 Toluene-d8

19.723

• 19.723

19

19

.698 (1

.698 (0

.166)

.000)

98

70

1104565 24.6519

28394

25.345 80

0

.00- 120

.00- 99

.00

.91

100

10

.00

.55

10000

CAS 1: 2037-26-5

24.652 80

0

.00- 120

.00- 62

.00

.12

100

2

.00

.57

10000

Data File: /chetn/msdg. i/g-29nov.b/gll2925.dReport Date: 10-Dec-2001 13:37

Page 20 0 2 8 6

CONCENTRATIONS

ON-COL FINAL.

RT EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO SIMILARITY

$ 79 Toluene-d8 (continued)

19.723 19.698 (0.000) 100 167040 20.05- 120.05 15.12

$ 101 Brcxnofluorobenzene

24.636 24.611 (1.094) 95

24.636 24.611 (0.000) 174

24.636 24.611 (0.000) 176

S086B3 22.8977

104488

101424

CAS t: 460-00-4

22.898 80.00- 120.00 100.00

0.30- 100.30 20.54

0.00- 98.30 19.94

8407

'Data File: /chem/msdg.i/g-29nov.b/gl!2925.dReport Date: 10-Dec-2001 13:37

Page 3 0029

_Data fileSmp IdDate

OperatorOSmp InfoIgMisc InfoComment

Meth DateCal Date

bottleFactor

ÎntegratorTarget Version: 3.50•Processing Host: eeyore

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-29nov.b/gl!2925.d0111476-02A Client Smp ID: RUN#2Can#1268330-NOV-2001 01:24xp Inst ID: msdg.i200mL can#1268327"Hg-5psi Air Nova

/chem/msdg.i/g-29nov.b/to!41102.m30-NOV-2001 05:44 xpan Quant Type: ISTD23-NOV-2001 14:27 Cal File: gl!2308.d113.40000HP RTE Compound Sublist: AT.sub

Sample Matrix: AIR

- NO TENTATIVELY IDENTIFIED COMPOUNDS -

a

Data File: /chem/msdg. i/g-29nov.b/gl!2925 .dReport Date: 10-Dec-2001 13:37

Page 4

Air Toxics Ltd.


Instrument ID: msdg.iLab File ID: gl!2925.dLab Smp Id: 0111476-02AAnalysis Type: VOAQuant Type: ISTDOperator: xpMethod File: /chem/msdg.i/g-29nov.b/to!41102.mMisc Info: 27MHg-5psi Air Nova

Calibration Date: 29-NOV-2001Calibration Time: 06:35Client Smp ID: RUN#2Can#12683Level: LOWSample Type: AIR

COMPOUND


STANDARD

^ — 3438621518725966768

AREALOWER

206317911235580061

LIMITUPPER

48140721262151353475

SAMPLE

3193231354360808197

%DIFF

-7.14-10.82-16.40

COMPOUND


STANDARD

15.0316.8822.51

RT ILOWER

14.5316.3822.01

jIMITUPPER

15.5317.3823.01

SAMPLE

15.0616.9122.51

%DIFF

0.170.15-0.01

AREA UPPER LIMIT = + 40% of internal standard area.AREA LOWER LIMIT = - 40% of internal standard area.RT UPPER LIMIT = + 0.50 minutes of internal standard RT.RT LOWER LIMIT = - 0.50 minutes of internal standard RT.

mData File: /chem/msdg.i/g-29nov.b/gl!2925.dReport Date: 10-Dec-2001 13:37

Air Toxics Ltd.

RECOVERY REPORT

Page 5 0031

Client Name:__ Sample Matrix: GAS;Lab Smp Id: 0111476-02A^Level: LOWData Type: MS DATA

f SpikeList File:fjSublist File: AT.subMethod File: /chem/msdg.i/g-29nov.b/to!41102.m

-r?Misc Info: 27"Hg-5psi Air Nova

Client SDG: g-29novFraction: VOAClient Smp ID: RUN#2Can#12683Operator: xpSampleType: SAMPLEQuant Type: ISTD

-oURROGATE COMPOUND


CONGADDEDPPBV

\ 25.00025.00025.000

CONGRECOVEREDPPBV

25.34524.65222.898

%RECOVERED

101.3898.6191.59

LIMITS

70-13070-13070-130

IT**

i

D«t* File:D*te : 30-NOV-2001 01:24Client ID: RUN»2C«n«i2683Swple Info: 200*L oant!2683

Colunn phut: RTx-624

Instrument:

Operator: xpColuttn 0.53

4.3-il/c-29nov.b/cil2929.d

10 11 12 13 14 16 17 18 19Hln

20 21 22 23 24 26 26 27 28 29 30 31 32

0033

QC Results and Raw Data

0 0 3 4



Compound

Freon 12Freon 114ChloromethaneVinyl ChlorideBromomethaneChloroethaneFreon 1 11,1-DichloroetheneFreon 113Methylene Chloride1,1-Dichloroethanecis-1 ,2-DichloroetheneChloroform1,1,1 -TrichloroethaneCarbon TetrachlorideBenzene1 ,2-DichloroethaneTrichloroethene1 ,2-Dichloropropanecis-1 ,3-DichloropropeneToluenetrans- 1 ,3-Dichloropropene1 ,1 ,2-TrichloroethaneTetrachloroetheneEthylene DibromideChtorobenzeneEthyl Benzenem,p-Xyleneo-XyleneStyrene1 , 1 ,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-DichlorobenzeneChlorotoluene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobutadienePropylene1 ,3-ButadieneAcetone

Rpt. Limit(ppbv)

0.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.502.0

2.0

2.0

Rpt. Umit(uG/m3)

2.5

3.6

1.0

1.3

2.0

1.3

2.8

2.0

3.9

1.8

2.0

2.0

2.5

2.8

3.2

1.6

2.0

2-72.3

2.3

1.9

2.3

2.8

3.4

3.9

2.3

2.2

2.2

2.2

2.2

3.5

2.5

2.5

3.0

3.0

2.6

3.0

3.8

5.4

3.5

4.5

4.8

Amount(ppbv)

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

Amount(uG/m3)

Not DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DelectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot DetectedNot Detected

Page 8 of 11

0035

n


ID#: 0111476-03A


Compound

Carbon Disulfide2-Propanoltrans- 1 ,2-DichtoroetheneVinyl Acetate2-Butanone (Methyl Ethyl Ketone)HexaneTetrahydrofuranCyclohexane1,4-DioxaneBromodichloromethane4-Methyl-2-pentanone2-HexanoneDibromochloromethaneBromoform4-EthyttolueneEthanolMethyl tert-Birtyl EtherHeptane

TENTATIVELY

Compound

None Identified


Surrogates


Rpt. Limit(ppbv)

2.0

2.02.02.02.02.0

2.02.02.02.02.02.02.0

2.0

2.0

2.0

2.02.0

RpL Limit(uG/m3)

6.3

5.08.07.26.07.2

6.07.07.3148.38.317

21

10

3.8

7.38.3


CAS Number

%Recovery

100

100

87

Amount(ppbv)


10 Reported

Match Quality

Amount(uG/m3)


Amount(ppbv)

MethodLimits

70-13070-13070-130

Page 9 of 11

Data File: /chem/msdg.i/g-29nov.b/gll2907.dReport Date: 29-Nov-2001 11:18

Page 0036

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth DateCal DateAls bottleOil FactorIntegratorTarget Version: 3.50Processing Host: eeyore

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-29nov.b/gl!2907.dLab Blank Client Smp ID:29-NOV-2001 10:40jk Inst ID: msdg.200mL #9924Blank

Lab Blank

/chem/msdg.i/g-29nov.b/tol41102 .m29-NOV-20Q1 11:16 kbadal Quant Type: ISTD23-NOV-2001 14:27 Cal File: gl!2308.d11.00000HP RTE Compound Sublist: AT+3.sub

Sample Matrix: AIR



CONCENTRATIONS

OH-COL FIKAL.

RT EXF RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO SIMILARITY

• 53 Broaochlorofnethane

15.035

15.035

15.035

• 69 1,

16.884

16.884

15.034

15.034

15.034

(1.000)

(0.000)

(0.000)

130

128

49

317815 25.0000

55880

146240

4-Dlfluorobeniene

16.883

16.883

(1.000)

(0.000)

114

88

1476113 25.0000

46072

• 90 Chlorobenzene-dS

22.514

22.514

$ 63 1.

16.194

16.194

22.513

22.513

(1.000)

(1.000)

117

82

905530 25.0000

588196

2-Dichloroethane-d4

16.193

16.193

(1.077)

(0V000)

65

67

697358 25.0522

67440

S 79 Toluene -da

19.699

19.699

19.698

19.698

(1.167)

(0.000)

98

70

1222090 25.0251

31872

CAS 1: 74

80

29

196

-97-5

.00-

.56-

.68-

120

129

296

.00

.56

.68

100.

17.

46.

.00

.58

.01

8913

CAS tt: 540-36-3

80

0

.00-

.00-

CAS t: 3114-55

80

17

.00-

.72-

120

67

-4

120

117

.00

.48

.00

.72

100.

3.

100.

64

.00

.12

.00

.96

9149

CAS 1: 17060-07-0

25.052 80

0

.00-

.00-

CAS I-. 2037-26

25.025 80

0

.00-

.00-

120

99

-5

120

62

.00

.91

.00

.12

100.

9.

100.

2

.00

67

.00

61

10000

10000

JBJData File: /chem/msdg. i/g-29nov.b/gl!2907 .d Page 2A n 9 7Report Date: 29-Nov-2001 11:18 ^ J V O f

CONCENTRATIONS

ON-COL FINAL

RT EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TAROBT RANGE RATIO SIMILARITY

• $ 79 Toluene-d8 (continued)

: 19.699 19.698 (0.000) 100 183296 20.05- 120.05 15.00i

$ 101 Bromofluorobenzene CAS I: 460-00-4

I 24.611 24.611 (1.093) 95 544434 21.8728 21.873 80.00- 120.00 100.00 7669i' 24.611 24.611 (0.000) 174 73672 0.30- 100.30 13.53

24.611 24.611 (0.000) 176 70976 0.00- 98.30 13.04


Page $ 0 3 8 F

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth DateCal DateAla bottleOil FactorIntegrator

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-29nov.b/gll2907.dLab Blank Client Smp ID: Lab Blank29-NOV-2001 10:40jk Inst ID: msdg.i200mL #9924Blank

/chem/msdg.i/g-29nov.b/tol41102.m29-Nov-2001 11:16 kbadal Quant Type: ISTD23-NOV-20Q1 14:27 Cal File: gll2308.d

1.00000HP RTE


Compound Sublist: AT+3.subSample Matrix: AIR

- NO TENTATIVELY IDENTIFIED COMPOUNDS -

i

ttv

Data File: /chem/msdg.i/g-29nov.b/gl!2907.dReport Date: 29-Nov-2001 11:18

Air Toxics Ltd.


Page 4 Q Q 3

iInstrument ID: msdg.i

- Lab File ID: gl!2907.d;j Lab Smp Id: Lab Blank*" Analysis Type : VOAQuant Type: ISTD

^ Operator: j k3l Method File: /chem/msdg.i/g-29nov.b/to!41102Misc Info: Blank

Calibration Date: 29-NOV-2001Calibration Time: 06:35Client Smp ID: Lab BlankLevel: LOWSample Type: AIR

m

COMPOUND


STANDARD

^~—343&621518725966768

AREALOWER

206317911235580061

LIMITUPPER

48140721262151353475

SAMPLE

3178151476113905530

%DIFF

-7.57-2.81-6.33

COMPOUND


STANDARD

15.0316.8822.51

RT ]LOWER

14.5316.3822.01

_,IMITUPPER

15.5317.3823.01

SAMPLE

15.0316.8822.51

%DIFF

0.000.000.00

fsAREA UPPER LIMIT = + 40% of internal standard area.AREA LOWER LIMIT = - 40% of internal standard area.

_RT UPPER LIMIT = + 0.50 minutes of internal standard RT.~RT LOWER LIMIT = - 0.50 minutes of internal standard RT.

Data File: /chem/msdg.i/g-29nov.b/g!12907.dReport Date: 29-Nov-2001 11:18

Air Toxics Ltd.

RECOVERY REPORT

Page 5 t

Client Name:Sample Matrix: GASLab Smp Id: Lab BlankLevel: LOWData Type: MS DATASpikeList File:Sublist File: AT+3.subMethod File: /chem/msdg.i/g-29nov.b/to!41102.mMisc Info: Blank

Client SDG: g-29novFraction: VOAClient Smp ID: Lab BlankOperator: jkSampleType: SAMPLEQuant Type: ISTD

r

SURROGATE COMPOUND

$ 63 1,2-Dichloroethane$ 79 Toluene-d8$ 101 Bromofluorobenzene

CONGADDEDPPBV

~~ \ 25.00025.00025.000

CONGRECOVEREDPPBV

25.05225.02521.873

%RECOVERED

100.21100.1087.49

LIMITS

70-13070-13070-130

ife

Data File: /ohei»X>i*dc.l//c-29nov.b/cll2907.dDate : 29-NOV-2001 10:40Client ID: Lab BlankSample Info: 200mL 19924


Pa ft 6

Instrument: nsdg.i

Operator: JkColumn .diameter: 0.53

/ /,

8.4-8.2-!8.0-;7.8H7.6,:

7.4-:7.2-j7.0-j6.8-;6.6-;6.4^6.2-:6.0-ie.8-:6.6^8.4-:8.2-i8.0-:4.8-;4.6-:

I/1

10 I . 12 13 18 16 17 18 19Hln

20 ) 22 23 24 28 26 27 28 29 30 31 32

\m KSTI rm KSH wm

LEVEL-IV VALIDATABLE


SURROGATE RECOVERY FORM

0 0 4 2

Lab Name: AIR TOXICS LIMITED. SDG No.:

01

02

03

04

05

06

07

08

09

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

CLIENTSAMPLE NO.

RUN*1 Can f 31 429 Air Toxics2692RUN#2 Can #12683

Lab Blank

LCS

SURROGATE % RECOVERY

l,2-Dichk>roethane-d4

101

101

100

97

*

Toluene-dS

99

99

100

105

#4-BromofluorobenMne

91

92

87

102

* *

TOTALOUT

0

0 ^T

0

0

0

0

0

0

0

0

0

0

0

0

0

0 ^-l

0

0

0

0

0

0

0

0

0

Surrogate Recovery Limits

1,2-Dichloroethane-d4 70-130Toluene-d8 70 - 130

4-Bromofluorobenzene 70 - 130

# Column used to flag values outside QC limits with an asterisk

Page 1 of 1

LEVEL-IV VALIDATABLE

EPA METHOD TO-14 GC/MS Full Scan

INTERNAL STANDARD AREA AND RT SUMMARY

0 0 4 3

Lab Name: AIR TOXICS, LTD

Lab File ID: g112902.d

Instrument ID: msdg.i

SDGNo:

Date Analyzed: 11/29/2001

Time Analyzed: 06:35 AM

01

02

03

04

05

06

07

08

09

10

11

12

_,j

14

15

16

17

18

19

20

21

22

24-HOUR STD

UPPER LIMIT

LOWER LIMIT

CLIENT SAMPLE NO

RUN*1 Can *31429 Air Toxics 2

RUN#2 Can *1 2683

Lab Blank

LCS

1 ,4-Difluorobenzene

Area

1518725

2126215

911235

1372602

1354360

1476113

1512628

#

RT

16.88

17.38

16.38

16.91

16.91

16.88

16.88

t

Chk>robenzene-d5

Area

966768

1353475

580061

B1960T

808197

905530

964073

#

RT

22.51

23.01

22.01

22.51

22.51

22.51

22.51

ft

Bromochloromethane

Area

343862

481407

206317

320107

319323

317815

333625

*

RT

15.03

15.53

14.53

15.06

15.06

15.03

15.03

ft

'Area Upper Limit=+40% of internal standard area'

'Area Lower Limit=-40% of internal standard area1

RT Upper Limit=+O.50 minutes o( internal standard RT

RT Lower Umit=-0 50 minutes of internal standard RT

n Column used to flag values outside QC limits with an asterisk* Designates values outside of QC limits

Page 1 of 4

Report Date : 05-Nov-2001 07:15 Page 10044

Start Cal DateEnd Cal DateQuant MethodOriginTarget VersionIntegratorMethod fileCal DateCurve

Air Toxics Ltd.

INITIAL CALIBRATION DATA

02-NOV-2001 09:1904-NOV-2001 18:28ISTD ADisabled3.50HP RTE/chetn/msdg. i/g-04nov.b/to!41102 .mP5-NOV-2QQ1 07:15 jkhatri

Level 1Level 2Level 3Level 4

Level

i/g-04novi/g-04novi/g-02novi/g-04novi/g-02novi/g-04nov

b/gll0402.db/gl!0407.db/gll0207 . db/gll0408.db/g!10212.db/gl!0409.d

& 11 *<£«*.e-

1I Compound ';

1 i

1 3! 3

t 4

1 5

1 «1 8

» . >'

PropyleneOichlorodifliioitofcethane/FmFreon 12Freon 114Ivobutylen*Chloroaoth*neDimethyl EtherVinyl Chloride

4»*£i&«fe\:\ . - - - . .

rslPim-1 13

f 14

1 is1 «

1 20

1 IB

i 21! 19

! 22

1 24

1 23

1 25

1

B*6oipAiethane

Chloroethane

2 -Methyl - 1 -BuCene

Trichlorof luoromethAne/Frll

Freon 21

Pentine

1-Penter.e

Echanol

Ethyl Ether

Freonl23

Acrolein

Freon 113

0.50000

.Level 1

*****

I 2.000

| Level 2

1.89542

5.36525) *****

3.121851 *****

3.83017) *****

2.51288

**f«* .

*£*

• .«•+*** ..

*****

1.1.4000] *****

1.05910] *****

5.07032) *****

***** 0.83406

2.95817] ».*,«

25.000 |

Level 3 |

1.810J7f/

6. 33744 |

3.30506)

2.98049)

2.94559]

***** I

1.31034|

1.13712)

5.92064|

0.86858|

3.21396|

1. 1-Oichloroethene | 4 . 4 2 4 0 6 ] .«*». | 4 . 6 0 7 8 6 )

1 1 1

SO. 000 | 100.000 | 200.000 |

Level 4 | Level 5 | Level 6 |

S1.

5.

1-

2.

2.

-t.

715121^

99669)

14649)

80064 |

75158)

•.*"+*»»;. 1•>*«»*• \ , \

i.i.

5-

0.

3 .

4 .

38600)

15002]

79366]

06276!

35481)

1

1.63*77) l!-55628f^

5.60968)

2. 96899 |

2.59880)

2.58156)

***** j

1 39570)

1.13685)

5 19655 j

0.76932)

2 . 8 6 9 8 9 ]

4 . 11941]

1

5.28427]

2.84086)

2.46279)

2 .44226)

1. 40999 t

~**f l'

1.36763)

1.11723)

4.94TJO|

0.75458]

2 .76836 |

4 . 0 1 4 0 7 )

1

1

RRF ! %

-1,2339^

5.71867)

3.07665)

2 .93458)

2 .64677)

1RSD |

7.793|X

7 .750 )

5.775)

18.331|

7.657]

1.53311| 6.6071

***** | **>.*«• f<-

***** . J ***** .- [<*

1.31993)

1. 12006]

5 .33977)

0 . 8 0 4 0 4 ]

2 . 9 7 4 6 3 1

4. 30404 |

ii

8 .022)

3 . 2 1 7 )

7.458|

5 . 8 4 2 ]

5 .794 |

5 .540]

1

Report Date : 05-Nov-2001 07:15 Page§045

Start Cal DateEnd Cal DateQuant MethodOriginTarget VersionIntegratorMethod fileCal Date

Air Toxics Ltd.


02-NOV-2001 09:1904-NOV-2001 18:28ISTDDisabled3.50HP RTE/chem/msdg.i/g-04nov.b/tol4ll02.mQ5:Npv-2001 07:15 jkhatri

-1

11111

11111

1

111r

1

1

rii.tI

iI

iiiiiiiiiiiii

Coopound

26

27

14

154

28

31

34

32

3S

36

37

39

38

4043

n

45

• 46

47

48

50

52

53

54

55

Acetonel-Prop*nol

C*rbbn Di«ullide_ _-, ^- — —^4

Methyl ene ChlorideM7BCtr*A>- 1 . 2 -Dichlbroechene

Allvl AleofUiL

2" * D^fl^vH&lMMKAIUt -

Ethyl Acetate

3-Butanonecis- 1 , 2 - DichloroetheneTe t rahydro furanChloroform1,1, 1-TrichloroethaneCyclohexane

Carbon Tetrachloride

0.50000 2.000 |

Level 1 Level 2 |

***** 3.96763)***** 4.11408)

***** 6.09687)

3.57360] ***** |

*****

*****

*****

.•• *»»*» ,'

**„*

*****

*****

6.79609)

2.08158)

3.50127)

4.9««94|

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2.72153]

4.61795]

4.23211] ***** |

***** | 2.71658]

4.51600] ***** |

3.91335) ***** |

» > * * < • 2 . 8 3 2 1 0 )

3.47897] *.*»» |

i i

25.000 |

Level 3 |

3.91865)

3.95293)

5.53348

3.21615]

6. 13152 |

1.98728)

3.23452)

3, 18401|

+*»»». . (

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4.64611)

3.86306)

2.51059]

4.81145)

4 .44438)

2.619291

4.09799|

i

50.000 |

Level 4 |

3.75805]

3.79184)

5.24893)

3.02389)

5.82316)

1.85249)

2.99349)

100.000 |

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3

3

5

2.

5.

I

2.

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56831)

69506|

00016

89035]

53065]

77176]

92827]

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4 .02864J

4.45393]

3.65404)

2.38355]

4.536151

4.19797]

2 43£10 |

3.89897!

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46110)

27254]

28797)

94454]

31448]

656191

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3.41722)

3.60614)

4.89043

2.85707]

5.35602]

1.71440]

2.84708]

5.943691

***** |

4.08848]

4.19355]

3 .34239]

2.22393)

4.11763)

3.76601!

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1

1

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3.72597)

3.83201)

5.3S397

3.11221)

5.92549)

1.88150)

3.10093)

4 KttOCt

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4.43591J

3. 71054 |

2.42144]

4 . 4 5 3 8 4 )

4 . 0 5 3 2 5 ]

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1

1

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6 . 2 4 7 )

5.309)

9.031

9 . 4 4 8 J

9.573]

8.062]

8.592]

3.279]

t '4**V- (*

21.382]

4 .573]

9 .493]

8.199]

5.931)

6.618]

9 .774 |

7 . 2 2 2 ]

1


0046

Start Cal DateEnd Cal DateQuant MethodOriginTarget VersionIntegratorMethod fileCal Date

Air Toxics Ltd.


02-NOV-2001 09:1904-NOV-2001 18:28ISTDDisabled3.50HP RTE/chfem/msdg.i/g-04nov.b/tol41102.m

;-20.01 09:01 kbadal

CM

60

62

63

61

70

71

74

75

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7(

78

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83

85

86

89

88

90

92

94

95

pound

Benxeo*

1.2- bichloroetbane

Beptwie

ci*~l,3-»Dichloroprop«ne

4 -Methyl -2 -pent aoonejîiijjijli; . , •;•.••.• .: • .

k,y^ , -^--,;, ; . .

îlîB^'''Te t rachl oroe thane

2-Hexinone

Dlbromochloroae thane

1 , 2 -Dlbromoethane

ChlorobenxeneEthyl Benzene

m,p-Xylene

o-Xylene

Styrene

0.10000 |

Level 1 |

1.65352)

0.84648)

***** |

0.671491

0 49893)

0.8C550)

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1.420831

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1.90122)

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0.66373)

1.15745)

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0.71060)

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0.28261)

0 95093 (

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1.08715)

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1.39364)

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66883)

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1.46194)

0.73478)

0.63748)

0.58046)

0 46819)

0.27558)

Q 85866)

0.72935)

1.02371)

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0.80567)

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0.95438)

1

200.000 |

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1.41526)

0.70788)

0.63531)

0.56509)

0 45B42)

0.26993)

0 83519)

0.71499)

1.01275)

1.22064)

***** |

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0.7iJ4>t

0.76364)

1.45962)

0 .94485)

0 .76625)

1.29005)

0.594S3|

0.62112|

0.51780)

0.91665)

1

1

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1.55169)

0.78576)

0.64292)

0.62240):

0 49209)

0.28555)

0 90463)

0.78341|

1.03919)

1.25101)

***** |

I SS'tfSSt

0.87506)

1.50464)

1.10518J

0.94991)

1.46992)

0.66313|

0 . 6 2 6 3 4 )

0.57709)

0 .99697)

1

1

% USD |

7.304)

7.974)

6.979|

7.881)

5.955)

5.1261

6 090 1

8.121)

3.377)

8.636)

>.*>*, . |«

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'9.906)

5.961)

12.547)

17.935)

16.996)

13.729!

14.712]

1 0 . 6 2 B )

10.094|

1

Report Date : 05-Nov-2Q01 07:15 Page 4

0047

Start Cal DateEnd Cal DateQuant MethodOriginTarget VersionIntegratorMethod fileCal DateC irve fy£e -

Air Toxics Ltd.


02-NOV-2001 09:1904-NOV-2001 18:28ISTDDisabled3.50HP RTE/chem/msdg.i/g-04nov.b/tol41102.m05-*£>v-2001 07:15 jkhatri

' '

T' coupaupd'

\ 99 1.2,3-TtichlorOpropan*

| 97 CuBene

| 101 Propylbwiiene| 104. D4tc»ni»[• 100 1, 1,2, 2 -T« tract! oro« thane

| 105 alphi-Kethyiityirene| 102 4-etnylSdluen*| 101 l.J.S-Triwnliylbenrcna| 107 c«rt-Butylljen*»ne

| 108 •«c-Butylb*nj«ne| 109 p-Cywerte| 106 1.2.4-Trinetnylltttnzene

111 1,2,3-TriMthylbenzene

_ 112 Ondacane| 110 l,3-Dichlqrob4msene[ til. I i f'Vict&ovqbeateiie

| 119 Bromobenzene| 120 2,2-Olchloropropane

I 118 l,2-Dlbromo-3-Cnloropropane| 121 2-Chlorotoluene| 122 4-Chloroeoluene

) 125 Diisobutyl Ketone

| 126 Naphthalene

| 123 1.2, 4-Trichlorobenzene

| 124 Hexachlorobutadienei 127 Aniline

| 128 Isooctyl Alcohol

| 129 1, 3, 5-Trichlorobenzene

1

0.50000 | 2.000

Level 1 ) Level 2

***** | 0.90121

2.2813J) *****

***** | 1. 20<711.258*7) *****

***** | ********** | *****

1.0108«| *****

1.58195) *****1.41C7SL »**•+».

i'.jijpijll ' +»*Vj".

0 .91440| *****

0 .70689] *****

1

25.000 50.000 | 100.000 200.000Level 3 Level 4 | Level 5 Level 6

1.06390 1. 01447 | 0.86217 0.81573

l.B248«| 1.70278) 1.52990) 1.46590)

l.«0919| 1.71790) 1.47928) 1. 45559)1.39707) 1.28866) 1.26145) 1 .--24470)

1.00686) 1.03469) 0.96398 0.97723)

1.07267) 0.97453) 0.94160) 0. 90569 |

• 0;M064| 0.897101 0.85746) O.|2866|: f**>»- I *>»«*. '1 ***** 1 ; *»«»« |-• -•- .*.; . .. .••• "„••;. • - •'./'.-'HiîHSj;.' . XfV)i.t3\ i;xi:sjHr3i| iA4t345l

«.9iiiJV fr.iweij o.l795if o.iiise)

0.14199] 0 . 3 6 2 2 2 | 0 . 3 3 3 0 0 ] 0 . 3 4 6 9 4 )0 .44885] 0 . 4 6 8 S 7 ] 0 . 4 2 7 7 9 ) 0 . 4 3 1 4 7 ]

1 1 1 1

RXF % RSD

0.93150 11.200

1.76096) 18.373

1.49333) 12.9151.29057) 4.774

0.99872) 2.821

1.09529) 25 .478J

0.98816) 24.619|**.***. ( »•»•» .' I

iio3'i<if : ' ;r:-r^C*7jj

0 .45971] 55.339

0 . 4 9 6 7 2 ] 2 3 . 8 7 7

1


0048

Start Cal DateEnd Cal DateQuant MethodOriginTarget VersionIntegratorMethod file

Air Toxics Ltd.


02-NOV-2001 09:1904-NOV-2001 18:28ISTDDisabled3.50HP RTE/chent/msdg. i/g-04nov.b/to!41102 .m<ifj -ôvr 2 Q p l: 09101 klbadal

11

IS

I*1*1

CoopQund

130 I*ooctyl Acifylate

58. lr 2-0iclildl?o£tliAn6-d4

7? Tb&iifef)ft-tf8 "'. ' '

98 anw>fliK>vob«nsen«

| O.SOOOO | 2.000 |

t Level l | Level 2 |

| «++»» | »•»

| 2.18222) 2.

| 0. 82426 1 0.

| 0. 6*858 1 0.

1 . 1

22494)

82878)

<«904|

1

25.000 |

Level 3 |

2.19729)

0.1»u:»t

0.70977)

. 1

50.000 |

Level 4 |

2

0

0

.21857!

.77276)

. 67814 1

1

100.000 f

Level 5 I

2. 15818|

0.87530|

0-71652)

|

200.000 |

Level £ |

2.

0;

0

.15673)

.86995)

.70110[

1

_ 1

RRF i

2.18965]

0.82708)

0.68719)

I

1

% RSD |

1.334)

4 . 95S |

3.831)

1


Start Cal DateEnd Cal DateQuant MethodOriginTarget VersionIntegratorMethod file

Air Toxics Ltd.


02-NOV-2001 09:1904-NOV-2001 18:28ISTDDisabled3.50HP RTB

- i/g-04nov.b/to!41102 .m-2aoi 09: 01..

.Awrag* IRBP R« cults.

(C»lcul»C«<J IR30 » 10.SSM349

• }0

%RSt> T«»t.

Report Date: 05-Nov-2001 09:03

Calibration History

Method : /chem/msdg.i/g-04nov.b/to!41102.mStart Cal Date: 02-NOV-2001 09:19End Cal Date : 04-NOV-2001 18:28

Initial Calibration

0050

| Injection Date | Sublist+ +

Calibration File

Cal Level: 1 , Cal Amount: 0.50000

04-NOV-2001 10:.3102-NOV-2001 15-: 37

T014MPxylehe

/chem/msdg.i/g-04nov.b/gl!0402.d/chem/msdg.i/g-02riov.b/gl!0217.d

Cal Level : 2 , Cal Amount : 2 . 00000i = =« =5 = = =i = a

04-NOV-2Q01 17:12 fethylact02-tfOV-2001 09:19 (ATonly

/chem/msdg.i/g-04nov.b/gl!0407.d/chem/msdg.i/g-02nov.b/gl!0206.d

j Cal Level: 3 . Cal Amount : 25.00000+ =: = SC = = =!j=i= = =:^ = za = i=aia:=: = = e = 3: = z = = = = = = = = = = =1

J02-NOV-2001 09:57 JAT | /chem/tnsdg. i/g-02nov.b/gll0207 .d= =!-= c:s = i

Cal Level: 4 , Cal Amovmt: 50.00000

0402

-NOV-2001-NOV-2001

1710:50:39

ethyl-actAT

/chem/rasdg/chem/msdg

. i/g-04nov.

. i/g-02nov.b/gl!0408.b/gl!0209.

dd

... _ . p>

I

| Cal Level: 6 , Cal Amount: 200.00000

04-NOV-2001 18:2802-NOV-2001 12:10

ethylactAT

/chem/msdg.i/g-04nov.b/gl!0409.d/chem/msdg.i/g-02nov.b/gl!0213.d

*r

A

$

Scott Specialty Gases6141 EAST0N ROAD, BLDG 1 PO BOX 310 '

Shipped PLUMSTBADVILLE PA 18949-0310 0051From: Phone: 800-331-4953 Fax: 215-7S6T7226

C E R T I F I C A T E O P A N A L Y S I S

AIR TOXICS LTD

180 BLUE RAVINS ROADStfjtB BPOLSOM CA 95630

PROJECT #: 01-41391-002P0#: 13504ITEM #: 0102BT00090 ALDATE: 11/07/00

CYUNDKR #: AAL170620514 PSIA

0-XYLfflfE

NITROGEN

ANALYTICAL ACCURACY: +/-10%PRODUCT EXPIRATION: 11/07/2001

Scott Specialty Gases6141 BA$tON ROAD, BLDG 1 PO BOX 310

Shipped PLUMSTE&DVILLB PA 18949-0310Prom: Phone: 800-331-4953 pax: 215-766-7226

C B R T I P I C A T B O P A N A L Y S I S

AIR TOXICS LTD

190 BLUE RAVINE ROADSUITE BFOLSOM

PHQJBCT #:13504

CA 95530

: 0102E90Q080 ATDATE: 11/07/00

Flit.ft: AAL17062SUR8: 154 PSIA

I<^ ACCURACY: +/-10% *•;11/07/2001 fc

1,3-BUTADIHNB(TSACHLQROBTHANE

THRNB

» »

mBALANCE

5.28

cott Specialty Gases6141 EASTON ROAD, BLDG 1 PQ BOX 310 "

Shipped PLUMSTEADVILLE PA 18949-0310 0 0 5 3From: Phone: 800-331-4953 Fax: 215-766-.7226

C E R T I P I C A T E O F A N A L Y S I S

AIR TOXICS LTD

180 BLUE RAVINE ROADSUITE BFOLSOM CA 95630

PROJECT #: 01-58888-005P0#: 14481ITEM #: 0102BT00090 ALDATE: 9/10/01

CYLINDER *•.. ALM039560 .FILL BfcBSSURE: 0154-PSlA

(ALPHA)

j , ... . .1,3,5-TRIMETHYLBEMZENEVINYL CHLORIDEM-XYLENE0-XYLENEP-XYLENENITROGEN

ANALYtlCAT£i:VAqCURACY: +/ -10 %PRODUCT EXPJft&TION: 9/10/2002

?§.290 ; 4 35^285.;365. [364. "985. 3135-P5 .294,385;; 2 55'. 2 5'5.37'4 .755.29'5.295.445.425.424.805. iS5 .405.234 . 5 94 . 9 75 . 4,25 '.40

•5.345.35

PPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPPMPP/Mjp|»MPP&PPMPPMPPMPPMPPMPPMPPMBALANCE

bcott Specialty Gases6141 EASTON ROAD, BLDG 1

Shipped PLUMSTEADVILLE PAFrom: Phone: 800-331-4953

C E R T I F I C A T E

PO BOX 310 -18949-0310 DO 5 4

Fax: 215-766-7?2g " *

O F A N A L Y S I S

AIR TOXICS. LTD

180 BLUE RAVINE ROADSUITE BFOLSOM CA 95630

PROJECT #: Ol-58888-oolP0#: 14481 IITEM #: 0102E900080 ALDATE: 9/10/01

CYLINDER .#..- ALM039560FILL PRESSURE: 0154 PSIA

'?•'• " --• .'-.I.B:^':•-;•.. .>.• •*

4l:''-'jife itiirfg Etei!;1 ?' - ".'•» "'" ..":''

'€ -TRXNITRdGEN

EXPlKlitlON: 9/10/2002

-.: •'•• '-.*$( '':••&&*&&&\i~: "'• TT

I

ANALYST^TERRANOE/P . BOSWfiLL

Urtg^

Standard ID: 855-32Analyst:Preparation Date:Expiration Date: .

0 0 5 5

Bag Blend Standard Calculation:

i (Volume added uL) (density) (IOOP) (24.055) (Purity*)I PpmV (Formula Weight) (Final Volume L)

I 'Standards are corrected For purity when purity is S 96%, otherwise a purity of 100% is assumed.' . •

Final Volume:' 6 ;O. .L . . •

\ r:^î^^S^:::Hf^'-;'--•',';^:'-v •.•'•'.••.>'-'-.''^-.^t-":'' , ' ^ • ' ' • • -

lt.'il<.L*-L-r\ i fp SX

/ r>*.< ^ JOOonkJ

j Pigs 32 Sisnid Date Reviewrd Dare Rev. 0&'1

Bag Blend Standard Preparation Log @Air Toxics Ltd Logbook* 797

0 0 5 6^•Standard ID: 797-182^.Analyst: w\i- Preparation Date:

Expiration Date:

' •-! •*

£ *


= (Volume added uL) (density) (1000) (24.055) (Purity*)(Formula Weight) (Final Vohune L)

ibfc

Standards are corrected for purity when purity is S 96%, otherwise a purity of 100% is assumed.

» »*'Senzsty.xls'

u JL. I

Standard ID: 773-139-* Analyst:J Preparation Date:

41UU11 iÛg @Air Toxics Ltd. Logbook #: ??3

0 0 5 7Y//

Expiration Date: - f - * i

,„ Bag Blend Standard Calculation:

_ (Volume added uL) (density) (1000) (24.055) (Purity*)•* (Formula Weight) (Final Volume L)

-*J| *

; 'Standards are corrected for purity when purity is < 96%, otherwise a purity of 100% is assumed.-Tt -. " :

FmaJ Volume! fc. ° L (.•M , • • . : - t / v V- : ' . ' • ; ' . ' * - • "~. '• "

3

r/1

fc2*AM

Net 34.

>K-'t&.mmm%'$

-•'>.••

Hexine

AttkhAkfrichAWrich

SSL0.659 86.11

1.93.9

5.04.4

101

101100

5Q

' 5R

SQ5Q

KEWUVOl

Proccdurt: Measure 8L nitrogen Into a TedJar bag and spik* in amounts of anafytes Usted Inthe table. Add SOul purged H20. Contents of Tedar bag transferred to 6L can. Canpressurized to 15 psi. Final concentration: 50 pprnv.

Paa; 139 SignedA^J

Date Date R?v,, 10.0(

;Air Toxics Ltd. Logoook .__^ss

0 0 5 8Standard ID: 855-33Analyst: fc£Preparation Date:Expiration Date:


_ (Volume added uL) (density) (1000) (24.055) (Purity*)PPmV (Formula Weight) (Final Volume L)

'Standards are corrected for purity when purity is £ 96%, otherwise a purity of 100% is assumed.

Final Volume:" 6*0 L

Compound Supplier Purity CAS# Density F.W. ppmv

C-Page 33 Signed

lO-b-01Date Reviewed Date Rev

UHUJU Toxics Ltd

Standard ED: 797-154Analyst:

0 0 5 9

Preparation Date: 0/bi \o \Expiration Date: Y.


_ (Volume added uL) (density) (1000) (24.055) (Purity*)

(Formula Weight) (Final Volume L)

*Standards are corrected for purity when purity is <> 96%, otherwise a purity of 100% is assumed.

Final Volume: • b<0 L -

Procedure: Measure 8L nitrogen into a Tedlar bag and spike in amounts of analytes listedin the table. Add SOui purged H20. Contents of Tecflar bag transferred^) 6L can. Canpressurized to 15 psi. Final concentration: 50 ppmv.

Paec 154 Sisn-

nra Dats Da:; Rev. 06-0'.

Standard ID: 797-153Analyst:Preparation Date:Expiration Date: ZJZnlol

0 0 6 0


(Volume added uL) (density) (1000) (24.055) (Purity*)ppmv = •


"Standards are corrected for purity when purity is < 96%, otherwise a purity of 100% is assumed.

Final Volume: •£'. O L

Page 153 Sighed Dte Reviewed Date Rev. 06/01

Standard ID: 855-106Analyst: Eg

1 Preparation Date:Expiration Date:

l|~ l~ ° '1 1- «-f-O I

y i Bag Blend Standard Calculation:

- _ (Volume added uL) (density) (1000) (24.055) (Purity*)•£ « ppmv (Formula Weight) (Final Volume L)

'Standards are corrected for purity when purity is £ 96%* otherwise a purity of 100% is assumed.

Final Volume: (>0 L15

1

^T31 ;

*^

&

*•*itf

11

?i

Compound' ; * - . - •

-.-; \. : " '

"•

' .

<^: • • .

• «

Supplier

-**r .. .

Lot*

^^-^

Purity

•

:::.CAS«- Density

_---

F.W.

~ .

,-*

^^

ppmvPurityCheckDate

.

r

1

Procedure/Comrnents: To ,f- <? L

-^v^c •• X/^-":"-::'.

JLLPage 106 Signed Date Reviewed

•x

Date Rev. 06/01

rJi

13b

Bag Blend Standard Preparation Log @Air Toxics Ltd Logbook #:

Standard ED: 773-65Analyst:

0062H"Preparation Date:Expiration Date:

r- E>«II- (£-0 I


nomv™

(Volume added uL) (density) (1000) (24.055) (Purity*)' - '. ' — —


Standards are corrected for purity when purity is £ 96%, otherwise a purity of 100% is assumed

e; L-'l t * ; . ! f r f• "

/.>t

* -

*

P-L,

i

*w

flfriaa***.

Procedure/Comments:

Jmp2.xb

88.11

KJO.Y2

41JQ55AM7653

1 I

Page 65 Signed Date Reviewed date- Rev. 10/00

Data File: /chem/msdg.i/g-02nov.b/gl!0217 . dReport Date: 05-Nov-2001 09:00

Page 1

0063

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth

miIntegrator

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg. i/g-02nov.b/gl 102 17. dlevel 1 Client Smp ID: level 102-NOV-2001 15:37nk Inst ID: msdg.i0.25ml #855-103 [200ppbv]0.25ppbv m,p-xylene only

/che4m/m8dg.i/g-02nov.b/tol41102 .m09:00 kbadal Quant Type: ISTD

1.00000HP RTE

Target Version: 3.50Processincf Host: eeyore

- iw*- •

Compound Sublist: MPxylene.subSample Matrix: AIR

Concentration Formula: Amt * DF * CpndVariable tM


AMOUNTS

CM,-MfT OH- COL

RT BXP RT (REL RT) MASS RESKJNSI ( PP8V) ( PPBV) TARGET RANGE RATIO SIMIIARITY

• 31 BronochlotcimthwMIS

15

•i*

:-"tf16

.052

.052

'*"&-*•

.901

15.052

IS. 052

SKS16.901

(1

(0

„•£

1

.000)

.000)

''•f '*$??•*

IP(0.000)

130 3518(4 25.0000128 55161

• « » • . .1J«$£

©^"iiSteoboo-88 47864

• 87 Chlorobeni«ne-dS22

22

22

22

.503

.503

92 ra.

.641

.641

22.50322.503

p-Xylene2 2 . 6 4 12 2 . 6 4 1

(1(1

.000)

.000)117 939838 25.0000

82 630623

CAS «: 74-

50.

27.

*««•

; -«**t/:|jj

0.

97-

00-

07-

*?.-

60-V00-

5

ISO.

127.

?«*•

ISO.

67.

00

07

53

00

69

100.

IS.

38.

100.

3.

00 9086

68

0>

00 9222

04 >'

CAS »: 3114-55-4

SO.

16.

00-

95-

CA.S «: 108-38(1

il

.006)

.006)106 8997 0 .50000

91 26545

0.3821 50.179.

00-

25-

150.

116.

-3

150.

279 .

00

95

00

25'

100.

67.

100.

295.

00

10

00

04

'aH!

Data File: /chem/msdg.i/g-02nov.b/gl!0217.d Page 2, A #Report Date: OS-Nov-2001 09:00 U 0 0 4

QC Flag Legend

a - Target compound detected but, quantitated amountBelow Limit Of Quantitation(BLOQ).

H - Operator selected an alternate compound hit.


Air Toxics Ltd.


Page 1

OOG5

Instrument ID: msdg.iLab File ID: gll0217.dLab Smp Id: level 1Analysis Type: VOAQuant Type: ISTDOperator: nkMethod File: /chem/msdg.i/g-02nov.b/to!41102.mMisc Info: 0.25ppbv m,p-xylene only

Calibration Date: 02-NOV-2001Calibration Time: 10:39Client Smp ID: level 1Level: LOWSample Type: AIR

v'ddjfiwW> ' ": .'' ' " " •51 Bfompcfalotomethan65 i ,4 -&i f iuorofeenze87 CMiar^^nzaine-dS

STANDARD

3467151S37085879614

•••^••.••.^".•••.«Ma-LOWER

208029922251527768

-LIMITUPPER

48540121519191231460

*• - * - • . ' '

SAMPLE

3518641575362

939838

%DIFF

1.492 .496.85

SB

• . - •,.C(S«PDUtfp

it at ak ss S» fci taii 'a: t= « lar at j> != s» ifc si a *' ±c

51 Bro«io<!bl drome than65 l,4-bi{luo*o|>ena!&87 Chlorobertzerie-dS

STANDARD^^*o'»:='^ = *jr=-

15.0516.9022.53

RT LIMITIjpWER

fx^masstsffsi:

14.5516.4022.03

UPPER= = :*3:*= = =iS3»^

15.5517.4023.03

SAMPLEs.s a: e^ tea ar 9* ib

15.0516.9022.50

%DIFF= != = = ==«

0.020.02

-0.11

UPPER LIMIT = + 40% of internal standard area.AREA LplfRR LIMIT = - 40% of internal standard area..|$|jfe& standard RT;|$li$! standard j«r

' " ••' ' • — * • : ! - ^ ' '* ' - " * r : " ''••'' "•• • " • ' ' ' • ' • - -

T*

CO

• i .C; !

D*U FiU:D«t» t 02-NOV-2001 15J37

Client ID: I«v»l 1S«Mpl» Info: 0.2BM1 t80B-103C20Opr*v3

Column phas«: RTx-424

Instrunvnt; n«d(.i

nk

Colunt t O.B3

Page 1

8 9 10 11 12


Page 1

0067

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMe£h IDate

,

"factor.integrator

Air Toxics Ltd.

AMBIENT AIR METHOD TO 14/chem/msdg. i/g-04nov.b/gl!0402 .dleal Level 104-NOV-2001 10:31jk Inst ID: msdg.iO.SmL #855-1030 . Sppbv

/cheni/msdg. i/g-04nov,b/tol41102 .m04-Nov-20pl 11:03 jkhatri Quant Type: ISTD

10; 31 Ga.l'

i.HP RTB

'Target Version: 3.50Processing Host: eeyore

Level:' 1

Compound Sublist: TO14.subSample Matrix: AIR

Concentration Formula: Amt * DP .* CpndVariable


AMOUNTS

CAL-AMT OH-COL

RT EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TMKJET RAJWB RATIO SIMILARITY

51 Broaochloroaethino

.052 15.052 (1.000) 130

15.052 15.052 (0.000) 128

1«.*01' If-Wt'

16.901 1C.901 (0.000)

•tl'4

88

371446 25.0000

60296

"S««.

l«7»54t 25.0006

51576

CAS «: 74-J7-5

30.00- ISO.00 100.00

27.57- 127.57 16.23

i»«.«a- a>«.63 42.il

100.06

3.07

5».OO- 150.00

0.00- 67.80

9037

9190


22.503 22.503 (1.000) 117

22.503 22.503 (1.000) 82

996332 25.0000

667275

CAS I: 3114-55-4

30.00- 150.00 100.00

17.05- 117.05 66.97

$ 58 1.2-Dichloroethane-d4

16.211 16.211 (1.077) 65

16.211 16.211 (0.000) 67

810576 25.0000

8S336

CAS •: 17060-07-0

24.915 50.00- 150.00 100.00

0.00- 99.91 10.53

9913

S 77 Toluene-d8

19.716 19.716 (1.167) 98

19.716 19.716 (0.000) 70

1384371 25.0000

37200

CAS «: 2037-26-5

24.915 50.00- 150.00 100.00

0.00- 62.12 2.69

9980

Data File: /chem/msdg.i/g-04nov.b/gl10402.dReport Date: 04-Nov-2001 11:03

Page 2

O O G 8

RT

AMOUNTS

CAL-AMT ON-COL

EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO SIMILARITY


19.716 19.716 (0.000) 100 214784 20.05- 120.OS IS.51

$ 98 Bronofluorobenzcne CAS 8: 460-00-4

24.628 24.628 (1.094) 95 646199 25.0000 23.S9S $0.00- 150.00 100.00 8280

24.628 24.628 (0.000) 174 132480 9.52- 109.52 20.50

24.628 24.628 (0.000) 176 130379 7.66- 107.66 20.18

V^ttir/-' *!!*?^ 5tt,0d--i5ft;«o 100,00 9«n*)6.193 6.193 (0.000) 87 1421 0.00- 83.09 3.57

4 Freon 114 CAS •: 76-14-2

6.717 6.717 (0.446) 135 23192 0.50000 0.5073 50.00- ISO.00 100.00 8917

6.717 6.717 (0.000) 137 967 0.00- 81.92 4.17

7 Chloromechane CAS *. 74-87-3

7.048 7.048 (0.468) SO 284S4 O.SOOOO 0:6S26 50.OS- 150.00 100.00

7.Q21 7.021 (0.466) 52 5078 0.00- 79.72 17.85

8 Vinyl Chloride CAS It 75-01-4

7.462 7.461 (0.496) 62 18668 O.SOOOO 0.4747 50.00- 150.00 100.QO 4024(a)

7.462 7.462 (0.000) 64 663 0.00- 81.IS 3.55

13 BrowOMthajcie CAS »i 74-83-9

8.704 8.7*4 (O.S78) 94 8469 O.SOOOO 0.4318 BO.00- ISO.00 100.00 6081(a)

8.704 8.704 (0.000) 96° 1043 44.63- 144.63 12.33

14 Chloroethane

9.063 9.063 (0.602)

9.(

CAS »: 75-00-3

7868 0.50000 0.4728 50.00- ISO.00 100.00

a$S 0-00- 81.47 3,24

r .643 9.643 (0.000) 103

37667 0.50000

3382

5- 150.00 lOOrOO

13.59- 113.59 8.98

23 Freon 113

10.829 10.829 (0.719) 151 21976 0.50000

10.829 10.829 (0.000) 153 1158

10.829 10.829 (0.000) 101 3143

CAS »: 76-13-1

0.4972 50.00- 150.00 100.00

9.83- 109.83 S.27

91.24- 191.24 14.30

25 1,1-DichloroeChene

10.940 10.940 (0.727) 61 32866 0.50000

10.940 10.940 (0.003) 96 1785

10.940 10.940 (0.0001 98 1647

CAS »: 75-35-4

0.5139 50.00- 150.00 100 00

0.00- 95 7} 5.43

0.00- 81.17 s.oi

if,,

3623 (a)

8367 (a)

7978


Page 3O O G 9

RT

AMOUNTS

CAL-AKT ON-COL

EXP RT (R£L RT) MASS RESPONSE ( PPBV) { PPBV) TARGET RANGE RATIO SIMILARITY

32 Hethylene Chloride CAS »: 7S-09-2

12.071 12.071 (0.802) 49 26548 0.50000 0.5741 50.00- 150.00 100.00 8871

12.071 12.071 (0.000) 84 3200 12.55- 112.55 12.05

12.071 12.071 (0.000) 51 1247 0.00- 79.01 4.70

42 1.1-Dichloroettune CAS *: 15-34-3

13.424 13.424 (0.892) 63 30834 O.SOOOO O.SQOO 50.00- 150.00 100.00 6345

13.424 13.424 (0.000) 65 1729 0.00- 11.73 . 5.61

' ""•r' -r*"": -•-— -A--TJV-"*:— ..-.---'".,'.'•'•.-••• • ..' c*»'-|. is«"-i£> :;; .' • " , •

14.541 14.Sit (0.965) 61 31440 O.SOOOO 0.5703 50.00- 150.00 100.00 1213

14.528 14.528 (0.000) 96 3697 12.02- 112.02 11.76

14.528 14.528 (0.000) 98 1737 0.00- 17.48 5.52

51 ChlOTpfdir* CAS «i 67-66-3

15.107 15-107 (1.004) 83 33549 O.SOOOO 0.5070 50.00- 150.00 100.00 8495

15.107 15.107 (0.000) 85 3936 14.40- 114.40 11.73

51 l.l.l,-mchlojO»thane CAS «: 71-55-6

15.494 IS.494 (1.029) >7 290720.50000 0.4S27 50.00-150.00 100.00 7482(a)

15.4*4 IS.494 (0.000) 99 2536 13.03- 113.02 8.72

55 Carbon Tetraehlorid* CAS I: 56-23-5

15.769 IS-769 (1.048) 119 25845 O.SOOOO 0.4670 SO.00- 150.00 100.00 8753(a)

15,769 15.769 (0.000) 117 4510 S6.3t- 156.28 17.45

60 Benren* CAS t: 71-43-2

.6.239 16.239 (0.961) 78 55S43 O.SOOOO O.S328 50.00- 150.00 100.00 3073

16.219 16.239 (0.000) 77 1993 0.00- 72.61 3.59

-.« .1,

«2

CAS, »; 107-06-2

so iiM"i#&*:-tia

100.00

68 Trichloroethene

17.398 17.398 (1.029) 95 22556 O.SOOOO

17.398 17.398 (0.000) 130 3461

17.398 17.398 (0.000) 97 2739

CAS I: 79-01-6 f

0.5394 50.00- 150.00 100.00'

34.65- 134.65 15.34

14.11- 114.11 12.14

8853

70 1,2-Dichloropropane

17.950 17.950 (1.062) 63 16759 O.SOOOO

17.950 17.950 (0.000) 62 2295

17.950 17.950 (0.000) 41 2603

CAS I: 78-87-5

0.5069 50.00- 150.00 100.00

22.76- 122.76 13.69

22.17- 122.17 15.53

8103

75 cia-1,3-Dichloropropene

19.247 19.2*7 (1.119) 75 2907} 0.50000

CAS »: 10061-01-5

0.5524 50.00- 150.00 100.00 8013


Page 40 0 7 0

RT

MOUNTS

CAL-AHT ON-COL


75 cli-1.3-Dichloropropene (continued)

19.247 19.247 (0.000) 77 2300 0.00- 82.23 7.91

19.247 19.247 (0.000) 39 4701 17.46- 117.46 16.17

78 Toluene CAS t: 101-88-3

19.854 19.854 (1.175) 91 477270.50000 0.5679 50.00-150.00 100.00 7967

19.854 19.854 (0.000) 92 5576 11.09- 111.09 11.68

_ , ........ _ „ »1 f _ . ..... . rf .._ . » ..... ..... .....

79 tr»n*-l,3-Dichloroprop*n* . CAS »t. lM*f-OJ-V ,

«i*»i6-/»«X,a>«v fo;f«»y.:';-"7S:;-.'.; Jih«q>5bo8<> Ve.'sjitr >ttlo*s;i$aj5^r too.ojj , . »ns

20.196 20.J9S CO.OOO) IT : 2645 6.db- ftl.85~ 9.06

20.296 20.296 (0.000) 1* 4676 13.36- 113.36 16.02

80. 1,1.2-Trlchloiroetbane CAS •: 79-00-520.682 20.6o* 10..919) 97 21430 O.SOOOO 0.5938 50.00- 150.00 100.00 8890

20.681 20.683 (0.000) 99 3389 12.04- 112.04 15.81

20.682 20.682 (0.000) 83 5268 42.33- 1*2.33 24.58

82 TetractUoroechene CAS *: 127-18-420.t«« 20.848 (0.926) 166 192260.50000 0.5513 50.00-150.00 100.00 9112

20.848 20.848 (0.0001 12.9 3824 25.84-135.8* 19.89

20,848 20.848 (O.OOftT 131 3494 22.03-122.02 18.17

_ _ _ „ _ . , _ . _ * . _ . . „ _ . _ _ ; . . _ _ . .._.- „ - - - ....... ......... .... A-

86 1,2-Dibroaovtbara CAS *< 106-93-4

21.7S8 21.758 (0.967) 107 21672 O.SOOOO 0.6253 50.00- ISO.00 10O.OO 5293

21.758 21.758 (0.000) 109 4885 42.58- 142.58 20.64

88 CUorobenzane

22.559 22.559 (1.002) 112

22.SS9 22.559 (0.000) 114

77

22.641 22.641 (1.006)

3.7885 O.SOOOO

3427

6516

91 54684

CAS I: 108-90-7

0.6467 50.00- 150.00 100.00

0.00- 82.34 9.05

19.1,1- 119.11 17.20. - • • • ' . . •;•. ' .• Hi'v:-..'-'.' ".••. .••. '• '••••,-. . . ' . i

291.37- J91.37 336.45

7476

94 o-Xylene

23.607 23.607 (1 .049) 106 132260.50000

23.607 23.607 (0 .000) 91 8720

CAS t: 95-47-6

0.5751 50.00- 150.00 100.00

183.36- 283.36 65.93

8897

95 SCyrene

23.635 21.635 (1.050) 104 230640.50000

23.635 23.635 (0.000! 78 3748

CAS «: 100-42-5

0.5805 50.00- 150.00 100.00

4 . 8 0 - 1C*.80 16.25

8843

100 1.1.2.2-Tetrachloroethane

2 4 . 8 4 9 2 * .8 * 9 (1 .104! 83 45459 O . S O O O O

CAS It: 79-34-S

0.6478 50.00- 150.00 100.00 8827


Page

0071

AMOWTS

CAL-AMT ON-COL


100 1.1.2.2-Tetracblorocthane (continued)

24.849 24.849 (0.000) 85 8782 12.1C- 112.16 19.32

103 1.3.S-Trlmethylbeniene CAS t: 108-67-8

25.236 25.236 (1.121) 105 25087 0.50000 0.4878 SO.00- 150.00 100.00

25.236 25.236 (1.121) 120 12231 0.00- 97.04 48.75

106 1.2,4-TTioethylbonte'ne CAS li S5-63-6

• $Q;pQ* ."150'.0Q -lOOi, 00

110 1.1-Diehlorobentene CAS •: 541-73-126.SIB 2C.S88 (1.182) 146 31531 0.50000 0.7332 50.00- 150.00 100.00

26.588 26.S88 (1.182) 148 19688 13.40- 113.40 62.46

26.588 26.588 (1.182) 111 14354 0.00- 95.92 45.54

111 1,4-Dichlotobeniene CAS I: 106-46-726.754 26.754 (1.189) 146 28111 O.SOOOO 0.7169 50.00- 150.00 100.00

26.754 24.754 (1.189) 148 17803 13.}2- 111.22 61.06

26.754 26.754 (1.189) 111 10561 0.00- 92.92 37.41

114 B«tityl Chloride CAS H: 100-4«-7

26.974 26.974 (1.199) 91 S1049 0.50000 0.7328 50.00- 150.00 100.00 -6852

26.974 26.974 (0.000) 126 241S 0.00- 68.20 4.77

115 l,2-Dichlarob«ni«ne CAS It 95-50-1

27.499 37.499 (1.222) 14C 304S4 O.SOOOO 0.7408 50.00- 150.00 100.00 8793

7.499 27.499 (0.000) 148 4514 11.74- 113.74 14.82

"27.499 27.499 (0.000) 111 3320 0.00- 95.83 10.90

133 Ir2,4-Xrichl0tt»j«*lte0« . .... Ckf.lt ,I*B-.I?-1.

124 Hexachlorobutadiene CAS t: 87-61-3 f

30.976 30.976 (1.377) 225 14086 O.SOOOO 0.7116 50.00- 150.00 100.00 8623

30.976 30.976 (0.000) 223 1643 12.98- 112.98 11.66

QC Flag Legend



Air Toxics Ltd.


Page 0072

Instrument ID: msdg.iLab File ID: gl!0402.dLab Smp Id: leal Level 1Analysis Type: VOAQuant Type: ISTDOperator: jkMethod File: /chem/msdg.i/g-04nov.b/tol41102.mMisc Info: O.Sppbv

Calibration Date: 04-NOV-2001Calibration Time: 10:31

Level: LOWSample Type: AIR

v-dofi§?di$tr ' " ' • " . • ; ' "51 BromochlofotHethaui65 1,4 -Di£ luorobenze87 Chlor<ahenzene-d5

' W&oti&371446

1679541996332

f:;I^si15R

222S681007725

597799

-"' ul£$R

52002422513571394865

V'-* ••o''J>'- •'.: •';•'• • ' '-.'••'-".'

SAMPLE!371446

1679541996332

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0.000.000 .00

COMPOUNDsi s±± sissi jS»s.=Sie-iii «» atss s»a»ari»a ifa-

51 Bromochloromethan65 1, 4-pifluorobenze87 chlordbensene-ds

ST&^Kp= ssail= Sis* $e* ±i*:

15.0516.9022.50

Rf LIMITLOWB£

• = ai==afs±a».s6if3B:

14.5516.4022 .00

UJ&I&R. =a a «:*» stars: a

19.5517.4023.00

SAMPLE5:»isa!=— =*-—

15.0516.9022.50

%DIFF-»-=i'.t!r=rzsi=

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AREA UPPER LIMITLOWER LIMIT

+ 40% of internal standard area.- 40% of. internal standard area.0 • SQ jttin^feff ,^ in^^riMil.,$rtia|i(i|i

^ ^'"''•' •'-';-'""''i ' ''''-• :'"'' :'~ "- ' '.-'' • ' V';; •' • '. "'V.' -'.;•'-.

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: 04-NOV-2001 10:31cn«nt ID:S«npl* Info: 0.8*0. MSB-103

Coluvm RTx-624

In«trumntt

Op*r«tor: JkColunn dl«M»Urt 0.53

R9R rm ®§3& ITC8 tassg w $%m n^; Rssfl Jr-as


Page

Data fileLab Smp IdInj DateOperatorStnp InfoMisc InfoCommentMethodMeth Date

Oil FatatorIntegrator

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg. i/g-02nov.b/gl!0206.dLevel 2 Client Smp ID: Level 202-NOV-2001 09:19kb Inst ID : msdg . i#855-103 200ppbv2ml 2 . Oppbv

/ chem/msdg. i/g-02nov.b/t o!4 11 02 .mp2-rJSJ6v-2p01 19:35 nkhan Quarit .Type:

1

i; do oooHP Rf E

Target 'Versioni 3*50Processing Host: eeyore

Compound Sublist: ATonly.subSample Matrix: AIR

Concentration Formula: Amt * DF * CppdVariable

Cpnd Variable Local Compound Variable feb H- E

RT

AMOUNTS

CAL-AHT OM-COL

EXP RT (REL RT) MASS RESPONSE [ PPBV) ( PPBV) TARGfiT RANGE RATIO SIMILARITY

• 51 Bromochlorofflethane15.04915.049

: '*:•• '•

16

16

--•;'-?.6&î *'.898

.898

15.04915.049

;SS'i'f'~,f^ft \rtCit

it.tn16.898

(1

(0

+£.

(i(0

.000) 130

.000) 128

:£*-ti&£gajj '~ •-.-.--OoV); ' 1H.000) 88

357288 25.000061528

,.v-. ;.... ...V-,^;...•• ' •--'.-. '"-.•.'.:. V..,-; ' '• .• ;

^16l04«» 3$. 000052312


22

$

16

16

$

19

19

.500

.500

58 1.

.208

.208

22.50022.500

(i .000) 117

(1.000) 82

975897 25.0000648286

2 - Dichloroethane -d4

16.208

16.208

(1

(0

.077) 65

.000) 67

794945 25.000082256

77 Toluene-d8

.713

.71319.713

19.713

(1

'0

.167) 98

.000) 70

1334720 25.0000

36208

CAS »: 74

50

30

^..y..^*^• VcMJ:Hfcf?jtjj[

" :/ •' ^4

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-97-5

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IEjfv-jft-;oV".00-

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^4:">^- :fV-Sr.!' ;. •'.:.•• ,..^4- • .";--;•

V«0 .'."".''. ' »"i«Q'-'.28 /

CAS *: 3114-55-4SO

16

.00-

.43-

ISO

116

.00

.43

100

66

.00

.43

CAS It: 17060-07-025.000 50

0

.00-

.00-

CAS t: 2037-26

25.000 SO

0

.00-

.00-

ISO

99

-S

150

61

.00

.60

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100

49

100

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.92


Page 9 9 7 5

RT EXP RT (REL RT)

AMOUNTS

CAL-AMT ON-COL

MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO SIMILARITY

$ 77 Toluene-da19.713 19.713

(continued)(0 .000) 100 213184

$ 98 Bromof luorobeniene

24.625

24.625

24.625

24.625

24.625

24.625

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RT EXP RT (REL RT)

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38 Hexane (continued)

12.869 12.869 (0.000)

12.869 12.869 (0.000)

41 Vinyl Acetate

13.338 13.338 (0.886)

13.338 13.338 (0.000)

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50 tecfahydroCurmn

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54 Cyclohewme

15.518 15.518 (1.031)

15.518 15.511 (0.000)

15.518 15.518 (0.000)

63 Heptane

16.374 16.374 (0.969)

16.374 16.374 (0.000)

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20.982 20.982 (0.933)

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- AMOUNTS

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83 2-Hexanone (continued)

20.982 20.982 (0.000) 100 1821 0.00- 57.05 7.05

85 Dibromochloromethane

21.452 21.452 (0.953) 129

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Calibration Date: 02-NOV-2001Calibration Time: 09:19Client Smp ID: Level 2Level: LOWSample Type: AIR

COMPOUND

5 1 Bromochloromethan65 1," -Difluorobenze87 Chlorobenzene-dS

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19.714 19.714 (0.000) 100 193024 20.50- 120.50 70.80

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24.626 24.626 (1.093) 95 64602925.0000 25.738 50.00- 150.00 100.00 8011

24.626 24.626 (0.000) 174 122624 9.79- 109.79 58.67

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6.163 6.163 (0.410) 85 2211570 25.0000 25.000 50.00- 150.00 100.00 9037

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6.660 6.660 (0.443) 115 1163795 25.0000 25.000 50.00- 150.00 100.00 8938

6.660 6.660 (0.000) 137 53712 0.00- 82.83 32.83

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„ 7.405 7.40S (0.493) 62 1017215 25.0000 35.000 50.00- 150.00 100.00 4813

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8.675 8.675 (0.000) 96 53618 45.65- 145.65 95.65

14 Chloroethane CAS »: 75-00-3

8.951 8.951 (0.595) 64 400408 25.0000 25.000 50.00- 150.00 100.00 4019

8.951 8.951 (0.000) 66 17816 0.00- 81.15 31.15

16 Trichlorofluoro«ethane/Frll CAS f: 75-69-4

9.613 9.613 (0.639) 101 2084804 25.0000 25.000 50.00- 150.00 100.00 9058

9.613 9.613 (0.000) 103 182260 14.02- 114.02 64.C2

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10.082 10.082 (0.670) 45 30S849 25.0000 25.507 50.00- 150.00 100.00 3570

Data File: /chem/msdg,i/g-02nov.b/gl10207.dReport Date: 02-Nov-2001 19:35

Page 3

0 0 8 2

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RT

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54 Cyclohexane

15.519 15.519 (1.031) 84 922317 25.0000

CAS It 110-82-7

24.024 50.00- 150-00 100.00

SIMILARITY

42 1, 1-Dichloroechane

13.422 13.422 (0.892)

13.422 13.422 (0.000)

41 Vinyl Acetate

13.339 13.339 (0.886)

13.339 13.339 (0.000)

13.339 13.139 (0.000)

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14.528 14.426 (0.9IS)

14.526 14.526 (0.000)

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47 2-B'utanone

14.470 14.470 (0.961)

14.470 14.470 (0.000)

14.470 14.470 (0,000)

50 Tetrahydrofuran

15.032 15,022 (0.998)

15.022 15.022 (0.000)

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52 Chloroform15.07* IS. 078 U.002)

5.078 15.078 (0.000)

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11.39- 111.39

0.00- 90.00

CAS t: 78-93-3

25.076 50.00- 150.00

0.00- 69.16

0.00- 57.24

CAS »: 109-99-S

24.015 50.00- 150.00

6.00- 86.95

0.00- 87.46

CAS I; 67-66-3

25.000 50.00- 150.00

13.89- 113.89

100.00

31.35

100.00

9.35

6.95

100.00

61.39

40.00

100.00

18.77

7.23

100.00

35.81

35.72

100.00

63.89

6409

6006

8240

7882

7505

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9176

8293

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15

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15,492

15.492

(1.029) 97

(0.000) 99

1564977 25.0000

158016

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IS

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15.767

15.767

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1443006 25.0000

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60 Benzene&

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16

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16.237

16.237

(0.961) 78

(0.000) 77

2619026 25.0000

95264

25.000 50.00-

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CAS 1: 56-23-5

25.000 50.00-

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CAS 1: 71-43-2

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8818

9036

62 1,2-Dlchloroethane

16.347 16.347 (0.967) 62 1320259 25.0000

CAS I: 107-06-2

25.000 50.00- 150.00 100.00 5873


Page 6 0 8 4

RT

AMOUNTS

CAL-AMT ON-COL


62 1,2-Dichloroethane (continued)16.347 16.341 (0.000) 64 86024 0.00- 82 .23 32.13

63 Heptane CAS »; 142-82-S16.37S 16.375 (0.969) 43 1012845 25.0000 23.816 50.00- 150.00 100.00 7166

16.375 16.375 (0 .000) 57 63504 0.29- 100.29 48.40

16.375 16.375 (0.000) 71 61872 0 . 0 0 - 97.27 47.16

, _ . » . . - . . _ - . - . .... . ..... .

68 Trichlo«o*l;ben* ... , CAS ». 79-01-6

17.423 VK4J3- U-OID W i04"»OTT 25. W>00 25v<*OO 50.OQ- ISO.Ofc WO.OO 8120

17.433 17.423 ( O . O a O ) 130 177920 36.34- 136.34 86.34

17.423 17.433 (0 .000) 97 131384 13.85- 113.85 63.85

70 1,2-Dichloropropane CAS «: 78-87-517.948 17.948 (1.062) 61 832955 25.0000 25.000 50.00- 150.00 100.00 B449

17.948 17.948 (0.000) 62 133696 24 .22 - 124.22 74.22

17.948 17.948 (0.000) 41 119956 21.98- 121.98 71.98

71 1,4-Dfoxane CAS 1= 123-91-1

18.058 18.058 (1.069) 88 480798 25.0000 26.027 50.00- 150.00 100.00 2761

18.058 18.058 <0.ftOO) S» 77312 27.07- 127.01 77.88

18.058 i8.Oil (0.000) 57 21120 0.00- 76.81 28.S3

74 Bro«odlchioro<**th*ne CAS *t 75-27-418.417 18.417 (1.090) 83 1SOO496 2S.OOW 25.086 50.00- 150.00 100.00 9214

18.417 18.417 (0.000) 85 209656 14.35- 114.35 «.«

75 ci»-l,3-DlchlOroprop«o«

19.245 19.345 (1.135) 75

19.245 1J.245 (0.000) 77

1294839 25. 0000

104280

CAS »i 10061-01-5

25.000 50.00- 150.00 100.00

0.00- 81.18 31.18

1C.74-116.74 *fi,74.

19.438 19.438 (O.OOOJ

19.438 19.438 (0.000)

8270

7157

78 Toluene

19.852 19.852 (1.175) 91

19.852 19.852 (0.000) 92

1954844 25.0000

264384

CAS »: 108-88-3

25.000 50.00- 150.00 100.00

10.73- 110.73 60.73

8817

79 trana-l,3-Dichloropropene

20.294 20.294 (0.901) 75 1214822 25.0000

20.294 20 .294 (0 .000) 77 102568

20.294 20.294 (0 .000) 39 211198

CAS I: 10061-02-6

25.000 50.00- 150.00 100.00

0.00- 81.08 31.08

14.01- 114.01 64.01

9270


Page 6

0 0 8 5

RT

AMOUNTS

CAL-AHT ON-COL


80 1,1.3-Trichloroethane CAS »: 79-00-5

20.680 20.680 (0.918) 97 909095 25.0000 25.000 50.00- 150.00 100.00 8931

20.680 20.680 (0.000) 99 148388 12.52- 112.52 62.52

20.680 20.680 (0.000) 81 217984 41.91- 141.91 91.91

82 Tetrachloroethene CAS »: 127-11-4

20.873 20.873 (0.926) 166 866386 25.0000 25.000 50.00- 150.00 100.00 9309

20.873 20.873 (0.000) .129 140224 21.Si- 121.58" 71.58

ao.ais .»p.-»7> (o.aod) m . ii*5« je.7p-PB.IO :«*-70."

83 2'HMCflJWUe CAS *: 591-78-6

20.9B4 20.9»4 (0.931) 43 1477038 25.0000 26.908 50.00- ISO.00 100.00 8337

20.984 20.984 (0.000) 51 177280 0.00- 98.17 48.87

20.984 20.9*4 (0.000) 100 25952 0.00- 57.10 7.15

85 Dibromochloromsthane CAS *.• 134-48-1

21.453 21.453 (0.952) 129 1152229 25.0000 26.118 50.00- 150.00 100.00 8533

21.45) 21.453 (0.000) 308 13170 0.00- 54.49 4.50

86 1.2-DibTOOKMthane CAS I: 106-93-4

2I.7S6 21.756 (0.966) 107 924)75 25.0000 25.000 50.04* 150.00 100.00 5533' . • • • - • • • • ' ' • ' •

3i;756 21:756 (O.OiW- 109 23*976 4*. 13- 144.13 94.13

86 Chlorob«n*«n« CAS »: 100-90-722.5B4 22.584 (1.002) 112 1336435 2S.0000 25.000 90.00- 150.00 100.00 9173

33.584 23 M4 (0.000) 114 111160 0.00- 82.73 32.73

J.5fl4 22.384 (0.000) 77 294630 16.15- 116.15 6C.15

90 Ethyl Bcnzen*

22.639 23.639 (1.005) 106

CAS I: 100-41-4

617341 25.0000 25.000 50.00- 150.00 100.00

22.860 33.860 (1.015)

94 o-Xylene

23.605 33.605 (1.048) 106

33.605 33.605 (0.000) 91

563G33 35.0000

374979

CAS •: 95-47-6

35.000 50.00- 150.00 100.00

178.07- 278.07 228.07

95 Styrene

23.633 23.633 (1.049) 104

23.633 23.633 (0.000) 78

939269 25.0000

138894

CAS tt: 100-42-5

25.000 50.00- 150.00 100.00

8.42- 108.42 58.42

96 Bromoforra

24.102 24.102 (1.070) 173 968352 25.0000

CAS *: 75-35-2

37.070 50.00- 150.00 100.00

9196

8633

8675


Page 70 0 8 6

RT

AMOUNTS

CAL-AMT ON-COL

EXP RT (REL, RT) MASS RESPONSE ( PPBV! ( PPBV) TARGET RANGE RATIO SIMILARITY

96 Bromoform (continued)

24.102 24 .102 (0 .000) 171 136624 0.13- ICO.13 52.52

100 1,1.2,2-Tetrachloroethane CAS »: 79-34-5

24.847 24 .847 (1.103) 83 1660990 2S.0000 25.000 50.00- 150.00 100.00 9149

2 4 . 8 4 7 2 4 . 8 4 7 ( 0 . 0 0 0 ) 85 309952 12.40- 112.40 62.40

102 «-Ethyltoluene . CAS I: 622-96-8

25-151 25.151 (1-116) 105 14*4>7* 2 5 . O Q O O 28.594 50 .00 -130 .00 100.00 9331

25.151 25.151 (0.000) ''.JJO M9U5 0.00- 79.93 36.34

103 1.3.5-Trimethylbenzene CAS »: 108-67-8

25.234 25.•'•'1 (1.120) 105 1271605 25.0000 25.000 50.00- 150.00 100.00

25.234 25.234 (1.120) 120 584578 0.00- 95.97 4S.97

106 1.2.4-Trimethylb«nzene CAS »: 95-63-6

25.951 25.951 (1.152) 105 916439 25.0000 25.000 50.00- 150.00 100.00 8803

25.951 25.951 (0.000) 120 105664 0.00- 93.66 43 .66

110 1.3-DichIorobenzene CAS It 541-73-1

26.586 26.586 (1.180) 14< 97633725.0000 25.000 50.60- 150.00 100.00

26.58< 26.586 (1.180) 148 617387 13.24- 113.2* €3.24

26.586 26.586 (1.180) 111 448624 0.00- 95.95 45.95

111 l,4-Dichlorob*ni«na CAS I: 106-46-7

26.752 26.753 (1.187) 146 8S6166 25.0000 35.000 50.00- ISO.00 100.00

36.752 36.752 (1.187) 1«B 545104 13.74- 113.74 63.74

26.752 26.752 (1.187) 111 385161 0.00- 94.99 44.99

114 Benzyl Chlorid* CAS •: 100-44-7

28. QQO 50.00. - 150. 00 100.09JT. (JPO.;;* MO tl-l$f> . , . »1 _ 1WWJ.3,^ _L^~' * <^^ ~uZ. A.V..>'_ - V.:*a't.- . . '"— 'j-.**"' ". — • • W j£— VC.'-

Z7.497 J7.497 (1.220)

27.497 27.497 (0.000)

27.497 27.497 (0.000>

146

148

111

904773 25.0000

166711

119145

25.000 . 50.00- 150.00

13.32- 113.32

0.00- 95.25

100.00

63.32

45.25

93 (a

8974

123 1,2,4-Trichlorobenzene

30.808 30.808 (1.367) 180

30.808 30.808 (0.000) 182

311277 25.0000

74264

CAS I: 120-82-1

25.000 50.00- 150.00 100.00

45.94- 145.94 95.94

8636

124 Hexachlorobutadiene

31.002 31.002 (1.376) 225

31.002 31.002 (0.000) 223

408546 25.0000

56279

CAS K: 87-68-3

25.000 50.00- 150.00 100.00

14.18- 114.18 64.18

9566


Air Toxics Ltd.


Page '0087

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/chem/msdg.i/g-02nov.b/to!41102.m02-10V-2001 19:35 nkhan Quant Type: ISTD02-$OV-20Q1 10:39 Cat

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AMOUNTS

CAL-AHT ON-COL

RT KIP RT (REt KT) MASS ftSSFOHSE ( PPBV) ( PPBV) TARGR RANOB RATIO SIMILARITY

' 51 BroaochloroMtthaoe

15.049 15.049 (1.000) 130

15.049 15.04* (0.000) 128

346715 25.0000

57)28

CAS I: 74-97-5

80.00- 120.00 100.00

28.27- 128.27 78.27

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16.198 16.898 (0.000) 88 46496 0.00- 67.53 17.53 .'

• 87 Chlorobenzene-dS

•;| 22.528 22.528 (1.000) 117 879614 25.0000

iS 22.528 22.528 (1.000) 82 590866

CAS »: 3114-55-4

80.00- 120.00 100.00

16.90- 116.90 67.17

$ 58 1.2-Dichloroethane-d4 CAS •: 17060-07-0

16.208 16.208 (1.077) 65 769210 25.0000 25.056 80.00- 120.00 100.00 9906

16.208 16.208 (0.000) 67 83808 0.00- 99.73 51.11

$ 77 Toluene-d8

19.713 19.713 (1.167)

19.713 19.713 (0.000)

CAS #: 2037-26-5

98 1187795 25.0000 24.220 80.00- 120.00 100.00

70 31040 0.00- 62.12 12.34

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$ 77 Toluene-da (continued)19.713 19.713 (0 000) 100 172672

$ 98 Broiaof luorobeniene24.62524.625

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10.081 10.081 (0.670! 550347 50.0000

CAS #: 64-17-5

47.690 80.00- 120.00 100.00 3570


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21 Ethanol (continued)

10.081 10.081 (0 .000)

10.081 10.081 (0 .000)

23 Freon 113

10.826 10.826 (0 .719)

10:826 10.826 (0.000)

10.826 10.126 (0 .000)

25 1,1-BiChlorocthene10.936 16.936 (0.727)

10.936 10.936 (0.000)

10.936 10.936 (0.000)

26 Acetone11.074 11.074 (0 .736)

11.074 11.074 (0.000)

28 Carbon Di«uUide

11.418 11.488 (0:763)

27 2-PTop*nol

11.240 11.240 (0.747)

11.340 11.240 (0.000)

11.240 11.240 (O.OQO)

32 MaUiylcn* Chloride

12.040 12.040 (0.800)

12.040 12.040 (0.000)

12.040 12.040 (0.000)

t:^îjj&&? '

12.399 12.399 (0.000)

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12.510 12.510 (0.831)

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12.510 12.510 (0.000)

38 Kexane

12.868 12.868 (0 .855)

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50.0000 47.962 80.00- 120.00

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42 1.1-Dichloroethane

13.420 13.420 (0.892)

13.420 13.420 (0.000)

41 Vinyl Acetace13.337 13.337 (0.886)

13.337 13.337 10.000)

13.337 13.3.37 (0.000) •

• ••V*--cl»il,-'T.t>itshioro»«i*14.524 14.524 (0.965)

14.524 14.524 (0.000)

14.524 14.524 (0.000)

47 _2-But»nooo

11.497 14.497 (0.963)

14-497 14.497 (0.000)

14.497 14.497 (0.000)

50 TetriJ^xofurwIS. oai iS.Wt <ft:S9«>15.021 IS'. 081 (0,OO«>

15.021 15.091 (0. BOO)

52 CMorOfot*

15.104 15.104 (1.004)

15.104 IS. 104 (0.000)

54 CyclotwjuM15.511 15.511 (1.031)

i:, ; ^»^#K.-

15.490 15.4*6 (1-029)

15.490 15.490 (0.000)

55 Carbon Tecrachloride15.766 15.766 (1.048)

15.766 15.766 (0.000)

60 Benzene16.235 16.235 (0.9S1)

16.235 16.235 (0.000)

63

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48 .630 80.00- 120.00

0.00- 81.55

CAS *: 108-05-4

49.981 80.00- 120.00

0.00- 58.78

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CAS »• 156-5J-2

48.610 80.00-120.00

11.01- 111.01

0.00- 88.60

CAS »: 78-93-3

4 B . 7 0 2 80.00- 120.00

0.00- 70.24

0.00- 57.25

CAS »'• 109-99-9

46.977 80.00- 120.00

0.00- 84.66

0.00- 87.27

CAS *: 67-66-3

48.527 80.00- 120.00

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53.28- 153.28

CAS »: 71-43-2

48 .220 80.00- 120.00

0.00- 72.48

100.00

31.55

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62 1.2-Oichloroethane

16.346 16.346 (0.967) 62 2450524 50.0000

CAS »: 107-06-2

48.616 80.00- 120.00 100.00 5962


Page ^ Q g 3

RT EXP RT (REL RT)

AMOUNTS

CAL-ANT ON-COL


62 1,2-Dichloroethane (continued)

16.346 16.346 (0 .000) 64 150336 0.00- 81.85 31 46

63 Heptane CAS *: 142-82-5

16.373 16.373 (0.969) 43 1797919 50.0000 45.178 80.00- 120.00 100.00 7158

16.373 16.373 (0 .000) 57 109326 0.00- 99.77 48 .73

16.373 16.373 (0.000) 71 104664 0.00- 97.06 46.65

68 TXichlorcMttfte** .'' CAS »> 79-01-6

ll;«3» 17-.4-il (Ic9jl).: 95 - 1134751 59.0000 48.350 80.09- 120.00 100.00 8868

17.433 17.422 (o'.bdO) 130- 331C48 3«.4B- 136.48 86.48

17.422 17.422 (0.000) 97 249283 15.00- 115.00 65.00

70 1.2-Dichloroprop»ne CAS »• 78-87-5

17.946 17.944 (1.062) 63 1547372 50.0000 48.637 80.00- 120.00 100.00 8464

17.946 17.946 (0.000) 62 215168 23.07- 123.07 73.07

17.946 17.946 (0.000) 41 208910 20.95- 120.95 70.95

71 l,4-Wc*»n« CAS »: 123-91-1

18.084 18.084 (L.070) 88 900123 50.0000 49.783 80.00- 130.00 100.00 2761

18.Q84 18.084 (0.000) 58 143744 ?*•??• "5/72 75.72

18.084 18.084 (OiOOe)/ 5? ' 90380 0.00- 76.70 26.49_. . _ » » ^..~_..... _ . , , ~ .-..--.. . -_*- . — .._..---. — ... ..... ...rf

74 BromodiChlprpSKthan* CAS »: 7Sr37-4

18.416 18.416 (1.090) 83 2830682 50.0000 48.818 80.00- 120.00 100.00- 9180

18.416 18.416 <0.090) 85 415040 13.«7- 113.67 63.67

75 ci«-l,3-Dichloropropene

19.343 19.343 (1.139) 75

19.343 19.343 (0.000) 77

2400603 50.0000

191514

CAS »: 10061-01-5

48.587 80,00- 120.00 100.00

0.00- 81.73 31.73

19.437 19.437 (0.000)

19.437 19.437 (0.000)

78 Toluene

19.851 19.851 (1.175) 91

19.851 19.851 (0.000) 92

3446418 50.0000

460416

CAS »: 108-88-3

47.332 80.00- 120.00 100.00

11.57- 111.57 61.57

79 crans-l,3-Dlchloropropene

20.292 20.292 (0.901) 75 2249884 50.0000

20.292 20.292 (0 .000) 77 179748

20.292 20.292 (0.000) 39 375088

CAS »: 10061-02-6

48.933 80.00- 120.00 100.00

0.00- 81.59 31.59

15.91- 115.91 65.91

8248

0.00- 86.44

0.00- 63.83

8972

9150


Page <Q Q Q 4

RT

AMOUNTS

CAL-AMT ON-COL

EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO

90 Ethyl Benzene

32.631 23.08 (1.005) IOC 1070192 50.0000

CAS *: 100-41-4

47.213 80.00- 120.00 100.00

SIMILARITY

80 1,

20.679

20.679

20.679

1. 2 -Tr ichloroethane

20.679

20.679

20.679

(0.918)

(0.000)

(0.000)

97

99

83

1664889 50.0000

260288

382080

82 Tetrachloroethene

20.872

20.872

20 8T3

83 2-1

21.010

21.010

21.010

20-872

20.872

20.872

Hex»non«

21.010

21.010

21.010

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(0.000)

(0.000)

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(0.933)

(0.000)

(0.000)

166

129

131

43

58

100

1548683 50.0000

266112

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2748198 50.0000

339280

55072

85 Dibromochlorcme thane

21.451

21.451

86 1,:

21.755

21.155

21.4S1

21.451

.21.755

21.7S5

(0-952)

(0.000)

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(0.966)

(a. 000)

129

208

107

10»

2151014 50.0000

24342

1713670 50.0000

4SS512

88 Chlorobeniena22.583

22.583

27.583

22.583

23.583

22.583

(1.002)

(0.000)

(0.000)

112

114

77

2377837 50.0000

205248

438485

CAS *: 79-

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51.190 80.

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CAS »: 124

51.190 80.

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22.859 23.859 (1.015) 4851182 163.44- 263.44 213.00

94 o-Xylene23.604 23.604 (1.048) 106

231604 23.604 (0 .000) 91

954121 50.0000

606531

CAS »: 95-47-6

46.734 80.00- 120.00 100.00

181.26- 281.36 231.26

9244

95 Styrene

23.659 23.659 (1.050) 104

23.659 23.659 (0.000) 78

1626347 50.0000

216532

CAS I: 100-42-5

47.252 80.00- 130.00 100.00

0.00- 97.60 47.60

9303

96 BromoCorm

24.128 24.128 (1.071) 173 1784692 50.0000

CAS »: 75-25-2

51.071 80.00- 120.00 100.00 9390


Page1)095

RT

AMOUNTS

CAL-AMT ON-COL



24.128 24.128 (0.000) 171 239808 2.30- 102.30 5 2 . 3 0

100 1,1,2.2-Tetrachloroethane CAS *: 79-34-5

24 .84£ 24 .646 (1.103) 83 299SS79 50.0000 48.269 80.00- 120.00 100.00 9093

24 .846 24 .846 (0 .000) 85 519168 12.49- 112.49 6 2 . 4 9

102 4-Ethyltoluene • CAS *: 622-96-8

25.14:9 23, H9( ia i6) 105 30JV7* 50.0000 56.861 80.00-120.00 100.00 9323

2S.14* B&i44''t(KMO)- 120 125069 *,00- 78.09 28 09

- -- .--<-- - - - - - -

10J 1.3,S-Tri«ethylb«n*ene CAS »: 108-67-1

25.232 25.232(1.120) 105 226704750.0000 47.982 80.00-120.00 100.00

25.232 25.232 (1.120) 120 1137551 0.00- 98.07 50.18

10* 1.2.4-Triraethylbenxene CAS »: 95-63-6

25.950 25.950 (1.152) 105 1820248 50.0000 50.681 80.00- 120.00 100.00 8807

25.950 25.940 (0.000) 120 228626 0.00- 93.40 43 .40

110 1,3-Dicblorotoaniena CAS »: 541-73-1

26,585 2SV51S (1.110). 146 1714424 50.0000 47.603 (0.00- 120.00 100.00

26.585 26.515 (1.110) 148 1093*69 13.S2- 111.52 63.80

26.585 26.58S Uil8«) 111 794023 0.00- 96.11 46.31

$ 111 1.4-IHchl«XO»>BM«ne ' CM »: 105-46-7

*"* 26.750 36.750 (1.187) 146 1578548 50.0000 48.831 80.00- 130.00 100.00

26.750 26:750 (1.187) 148 989045 13.20- 113.20 62.66

!: "~" 26.750 26.750 (1.187) 111 684732 0.00- 94.18 43.38

CAS •: 100-44-7

100.00 9355

27.495 27.«»5 (1.2201 146 160792650.0000 47.902 80.00- 120.00 100.00.' 8891

27.495 27.495 (0.000) 148 311940 14.13- 114.13 64.13

27.495 27.495 (0.000) 111 226279 0.00- 96.52 46.52

123 1.2,4-Trichlorobenienc

30.807 30.807 (1.368) 180

30.807 30.807 (0.000) 182

637223 50.0000

144896

CAS »: 120-82-1

51.436 80.00- 120.00 100.00

43.24- 143.24 93.24

8593


31.000 31.000 (1.376) 225

31.000 31.000 (0.000) 223

824319 50.0000

114000

CAS •: 87-68-3

51.074 80.00- 120.00 100.00

12.30- 112.30 62.30

9528


Air Toxics Ltd.


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16.209

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$ 77 Toluene-da (continued)19.714 19.714 (0 .000) 100 223120 19.61- 119.64 68.93

$ 98 Broroofluorobeniene CAS »: 460-00-4

24 .626 2 4 . 6 2 6 (1.094) 95 75S944 25.0000 25.835 SO.00- 150.00 100.00 8065

24.626 24.626 (0 .000) 174 144384 9.36- 108.36 58.72

24.536 24 .626 (0.000) 17_6 140800 6.31- 106.32 57.26

1 Propyltoe . CAS I: 115-07-1

8,035 4K03B (0.400) 41 236554* 100.000 92.896 • S»>00- ISO.00 100.00 7S86

6.025 6.025 (0.000) 42 19436* 14.94- 114.94 64.64

6.025 6.025 (0.000) 39 243186 31.23- 131.23 80.55

2 Dichloroditluoromethane/FrlJ CAS I: 75-71-8

6.191 6.191 (0.411) 85 8092565 100.000 93-787 50.00- 150.00 100.00 9037

6.191 6.191 (0.000) 87 282432 0.00- 81.83 31.83

4 Freon 114 CAS I: 76-14-2

6.688 6.688 (0.444) 135 4233086 100.000 94.548 50.00- 150.00 100.00 9059

6.688 6.688 (0.000) 137 197632 0.00- 82.10 32.22

7 Chlotcpnithjiin* CAS f: 74-87-3

6.991 6.991 (0.465) 50 3749044 100.000 93.036 50.00- 150.00 100.00

6.991 6.991 (0.465) 52 1220874 0.00- 82.77 32.56

8 Vinyl Chlorld* CAS t. 75-01-4

7.433 7.473 (0.494) 62 3724183 100.000 93.549 90.00- ISO.00 100.00 4529

7.433 7.433 (0.000) 64 123206 0.00- 80.27 30.35

9 1.3-BuCadltna CAS t. 106-99-0

8.675

8.675

l.«75 (O.S76)

8,675 (0.000)

94

96

2913453 100.000

232761

102.32 50.00- 150.00

44.82- 144.82

100.00 f

94.71

6554

6621

14 Chloroethane

9.006 9.006 (0.598) 64

9.006 9.006 (0.000) 66

1640027 100.000

58328

CAS I: 75-00-3

99.608 50.00- 150.00 100.00

0.00- 81.23 31.57

4082

16 Trichlorofluororoethane/Frll

9.613 9.613 (0.639) 101 7496589 100.000

9.613 9.613 (0.000) 103 660864

CAS I: 75-69-4

93.458 50.00- 150.00 100.00

14.01- 114.01 63.67

9013

21 EChanol

10.110 10.110 (0.672) 45 1109824 100.000

CAS #: 64-17-5

94.232 50.00- 150.00 100.00 3570


Page 3

0100

RT

AMOUNTS

CAL-AMT ON-COL


21 Bchanol (continued!

10.110 10.110 (0-000!

10.110 10.110 (0 .000)

23 Freon 113

10.827 10.827 (0.719)

10.827 10.827 (0.000)

10.827 10.837 (0.000)

10.938 10..93B (0.727)

10.938 10.938 (0.000)

10.938 10.938 (0.000)

26 Acetone

11.103 11.103 (0 .738)

11.103 11.103 (0.000)

28 Carbon DliUltide

U.S17 11.517 (0.765)

27 2- Propane 111.241 11.241 (0.747;

11.241 11.241 (0.000)

11.24} 11.241 (Q.OOO)

32 Mcthyluw Chlorid*

12.042 12.042 (0.800)

12.042 12.042 (0.000)

12.042 12.042 (0.000}

12.401 12.401 (0.000)

43

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36 tr«n»-l,2-Dichloro«th«n«

12.511 12.511 (0.831)

12.511 12.511 (0.000)

12.511 12.511 (0 .000)

38 Hexane

12.842 12.842 (0.853)

12.842 12.842 (0 .000)

12.842 12.842 (0 .000)

96

61

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2955954 100.000

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94.130 50.00- 150.00

12.53- 112.53

93.15- 193.15 '

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0.00- 99.29

0.00- 81.71

CAS *: 67-64-1

93.825 50.00- 150.00

0.00- 74.86

CAS »i 75-15-0

91.413 50.00- 150.00

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95.026 50.00- ISO. 00

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0.00- 52.98

CAS I: 75-09-2

94.969 50.00- 150.00

11.65- 111.65

0.00- 80.03

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CAS •: 156-60-5

92.122 50.00- 150.00

127.31- 227.31

12.93- 112.93

CAS »: 110-54-3

92.538 50.00- 150.00

17.86- 117.86

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Page 4

0101

RT

AMOUNTS

CAL-AMT ON -COL


42 1. 1-Dichloroethani

13.422 13.422 (0 .892)

13.422 13.422 (0 .000)

41 Vinyl Acetate

13.339 13.339 (0 .886)

13.339 13.339 (0.000)

13.339 13.339 (0-000)

v«-ci*,^Ti*ehi^14.526 14.SK (0.9«S)

14.536 14.526 (0.000)

14.526 14.536 (0.000)

47 2-Butanon*14.498 14.491 (0.963)

14.491 14.498 (0.000)

14.498 14.498 (0.000)

50 TetTvhydrotvittn

15.033 15.023 (0.9S»)

15.032 15.031 (0.000)

15.023 15.033 (0.000)

52 Chloroform

15.105 15.109 (1.004)

.5.105 15.105 (0.000)

S4 Cyclob*xan«

15.519 15.511 (1.031)

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598892

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6157054 100.000

227456

83496

3378384 100.000

2*9*30'

234116

61*1156 100.000

710400

3331111 100.000

. ,«.«i7*« ,.-• ' •

CAS »: 75-34-3

94.113 50.00- 150.00

0.00- 11.57

CAS »: 101-05-4

100.74 50.00* 150.00

0.00- 51.15

0.00- 56.55

CAS t:~ i£Sv$*.Jjr •

94.511 50,00-150.00

11.05- 111.05

0.00- 11.19

CAS 1: 71-91-3

94.911 50.00- 150.00

0.00- 69.69

0.00- 57.37

CAS «- . - 109- 99- »

91.978 50.00- ISO. 00

O.«fr-X|6.09

0.00- 17.06

CM »> 47-4)*- 3

94.341 50,00- 150.00

13.39- 111. 39

CAS »: 110-13-7

90.746 50.00- 150.00

.;. ... .;.,,.J3..|g>.lJ£..«l

100.00

31.80

100.00

9.05

6.63

100.00

60.77

31.07

100.00

30.32

7.33

100.00

35:64

36.43

100 ..00

63.24

100.00

. 135.02

6409

5936

8240

7913

7502-

*

9150

1275

1 15.493 15.493 (1.039) 97 5690435 100.000 94-015 50.00- 150.00 100.00 f

•':'. .- •"'-' .' :. •:.-">',•-- - '.~, .'•• ~~: "

7442

15.493 15.492 (0.000) 99 567108 14.39- 114.29 63.41

55 Carbon Tetrachloride

15.767 15.767 (1.048) 119

15.767 15.767 (0.000) 117

5274456 100.000

884890

CAS •: 56-23-5

94.125 50.00- 150.00 100.00 ,

54.39- 154.39 104.39

8778

60 Benzene

16.237 16.237 (0.961) 78

16.237 16.237 (0.000) 77

9509404 100.000

359488

CAS «: 71-43-2

93.520 50.00- 150.00 100.00

0.00- 72.52 22.61

9270

62 1,2-Dichloroethane

16.347 16.347 (0.967) 62 4779498 100.000

CAS »: 107-06-2

92.836 50.00- 150.00 100.00 5841


AMOUNTS

CAL-AMT ON-COL

KT EXP RT (REL RT) MASS RES.POKSE ( PPBV) ( PPBV) TARGET RANGE RATIO

0 1 0 2

SIMILARITY

62 1.2-Dichloroethane (continued)

IS.347 16.347 (0.000) 64 305280 0.00- 81.76 31.58

63 Heptane CAS #: 142-82-5

16.375 16.375 (0.969) 43 4146576 100.000 98.862 50.00- 150.00 100.00 7409

16.375 16.375 (0.000) 57 296853 0-00- 99.59 49.03

16.375 16.375 (0.000) 71 284672 0.00- 97.05 47.02

68 Trichloroethene ; CAS ».- 7J-01-6 . .17i:433 17,423 (1:031) « 37WI 100.000 9t.»5* 50.00- 150.OO 100.00 8809

17.423 17.423 (0.000) 130 645440 36.37- 136.37 (6.30

17.423 17.423 (0.000) 97 483072 14.48- 114.48 «4.S9

70 1.2-Dlchloroprop*ne CAS #i 7»-87-5

17.948 17.948 (1.061) 63 3045397 100.000 93.445 50.00- 150.00 100.00 8494

17.948 17.948 (0.000) 62 456704 23.89- 123.89 74.37

17.948 17.948 (0.000) 41 429750 20.97- 120.97 69.98

71 l,4-Dioa»n« CAS •; 123-91-1

18.058 It.058 (1.069) 88 1792552 100.000 95.207 50.00- 150.00 100.00 2827

la.OSi 18.051 (0.000) 51 293504 27.28- 127.38 79.25

18,05» 18.0$a (0.000) 57 104440 0.00- 77.01 21.20

74 BrMtodicWprooiethane CAS I: 75-27-4

18.417 18.417 (1.090) 83 5S85308 100.000 93.132 50.00- 150.00 100.00 9203

18.417 18.417 (0.000) 85 7864J2 13.88- 113.81 63.1J

75 cli-l,3-01chloroprop«n«

19.243 1J.24S (1.139) 75

19.245 19.245 (0.000) 77

4744144 100.000

385088

CAS *: 10061-01-5

93.644 50.00- 150.00 100.00

0.00- 81.40 31.37

19.410 (0.000)

19.410 (0.000)

i

8316

6933

78 Toluene19.852 19.853 (1.175) 91

19.852 19.852 (0 .000) 92

8098271 100.000

1098752

CAS ft: 108-88-3

103.36 50.00- 150.00 100.00

11.06- 111.06 60.87

89938f

79 tran»-l,3-Dichloropropene CAS »•• 10061-02-6

20.294 20.294 (0 .902) 75 4442590 100.000 86.140 50.00- 150.00 100.00 9154

20.294 20.294 (0 .000) 77 385689 0.00- 81.44 31.64

20.294 20.294 ( 0 . 0 0 0 ) 39 775396 14.51- 114.51 63.61


Page 60103

RT EXP RT (REL RT)

AMOUNTS

CAL-AMT ON-COL


80 i. 1, 2-Trichloroethane

20.680 20.680 (0.919)

20.680 20.680 (0.000)

20.680 20.680 (0.000)


20.846 20.846 (0.926)

20.846 20.846 (0.000)

20.846 2Q. 846 (0,000)

— 83 2-Hexanone

20.914 20.984 (0.933)

20.984 20.984 (0.000)

20.984 20.984 (0.000)

83 Dlbroooctiloromethane

21.453 21.453 (0.953)

21.453 21.453 (0.000)

86 1.2-Dibronocchane

21.756 21.756 (0.9471

31.75* 21.756. (O.OOOT

It Chlorobenien*

22.557 22.557 (1.002)

13.5S7 33.337 (0.000)

_.2.5S7 33.557 (0.000)

97

99

83

166

129

111

43

58

100

129

208

107

109

113

114

77

3257311 100.000

534272

789120

3437811 100.000

631936

6.03} 12

6270999 100.000

815744

118600

4212507 100.000

46118

3399976 100.000

173034

5641171 100.000

4J7696

1039111

CAS «: 79-00-5

85.225 50.00- 150.00

11.86- 111.86

41.04- 141.04

CAS I: 127-18-4

92.333 50.00- 150.00

24.60- 124.60

21.69- 131.69

CAS It 591-71-6

98.027 SO. 00- 150.00

0.00- 99.68

0.00- 57.50

CAS 1: 124-41-1

87.159 50.00- 150.00

0.00' 54.42

CAS »: 106-93-4

86,465 SO. 00- ISO. 00

44.30- 144.30

CAS I: 101-90-7

96.551 50.00- 150.00

0.00- 12.01

11.11- 111.88

100.00

61.83

91.31

100.00

• 80.06

76.28

100.00

49.55

7.20

100.00

4.45

100.00

94.83

100.00

31.64

74.41

8921

8996

8369

8521

5531

8975

J2 90 Ethyl B«n»en» CAS It 100-41-4

22.639 23.619 (1.006) 106 2611700 100.000 97.417 50.00- ISO.00 100.00

;-• . 83,63». aj.M^ (V,OQ6) 91, I93TM1 . 393.0,1-391,03 341;8123"^-" ' • - ' . ' " . * '•",• .- . ' . - . i '^". >;'.- : "'•:'• i~" : ' '"•' V ••^•.•.'•^•'•'r '• • '• • ' • • • . . - . ' "-'. ' >- ,"J a"'-I ?'•'•"• •'. • • • • • • ' . ."•.-'»:•.'*. i"."T"^r'-rî^*.rS>.,-Tr *r.--*~vi41.?5;T'*Jf^' *':**"" "''\"-!^*"r* •""•* Wj»*y!Â**.k"'"*.'>'" t "*'.'.'" .••i **•*.••.•','!• *^-

22.833 22.833 (1.01S) 91 11749963 U3.W- 263.39 213.28

94 o-Xylene CAS I: 95-47-6

23.605 23.605 (1.049) 106 2293332 100.000 95.679 50.00- 150.00 100.00 9207

23.605 23.605 (0 .000) 91 1555B9S 17J.62- 379.62 229.52

95 Styrene CAS I: 100-43-5

23.633 23.633 (1.050) 104 4027569 100.000 98.365 50.00- 150.00 100.00 8756

23.633 23.633 (0 .000) 78 599591 4.01- 104.01 56.01

96 Bromoform CAS »: 75-25-2

24.102 24.102 (1.071) 173 3638436 100.000 89.768 50.00- 150.00 100.00 8715


RT EXP RT (PEL RT)

AMOUNTS

CAL-AMT ON-COL

MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO

Page ()4

SIMILARITY

1

96 Bromoforu (continued)

24.102 24.102 ( 0 . 0 0 0 ) 171 527616 1.19- 101.19 52.20

100 l.l,2,2-Tetrachloro«thane CAS *-. 79-34-5

24 .S47 24 .847 (1.104) 83 6456317 100.000 90.749 50.00- 150.00 100.00 9171

2 4 . 8 4 7 2 4 . 8 4 7 ( 0 . 0 0 0 ) 85 1225728 12.71- 112.71 63 .23

102 4-Ethyltoluene . " CAS i: 422-96-8

35.151 25US1, (1.111) igS .6242£73 1.00.000 94.437 50.00- 150.00 100.00 9-135

25.J51 2S:-isi {a.epd) 136 4«>i7s o.'n- ie.99 as.oi

103 1,3,5-Trinettiylbcniene CAS I: 108-67-8

25.234 25.234 (1.121) IDS 5331851 100.000 95.978 50.00- 150.00 100.00

25.234 25.234 (1.121) 120 2399524 0.00- 97.05 45.00

106 1.2,4-Trinechylbcnzene CAS • : 9S-63-6

25.924 25.924 (1.152) IDS 4068074 100.000 96.221 50.00- 150.00 100.00 8863

25.924 25.924 (0.000) 120 440198 0.00- 92.84 41.46

110 l,3-Dlchlor<abeniene CAS »-. 541-13-1

26.586 26.586 (1.182) 146 3973639 100.000 94.513 50.00- 150,00 100.00

2SVS96 26.S8& (1.182) 148 2545756 1J.70- 11J-.70 64.07

26.586 2C.586 (1.182) 111 1130979 0.00- 96.11 46.08

111 1.4-Dictaorab0nten> CAS *i 106-46-7

J6.7S2 36.752 (1.1191 146 3(18561 100.000 95.436 50.90- 150.00 100.00

26.752 26.753 (1.189) 14» 2276338 13.10- 113.10 C2.91

26.752 26.752 (1.189) 111 1597446 0.00- 94.17 44.15

114 B4u»yl Chloride

27.497 27.497 (1.223) 146

37.497 27.497 (0.000) 148

27.497 27.497 (0.000) 111

3711588 100.000

681911

488640

94.654 50.00- 150.00

13.78- 113.78

0.00- 95.85

100.00

63.89

4S.78

123 l,2.4-Trlchloroben*ene

30.808 30.808 (1.369) 180

30.808 30.808 (0.000) 113

1405288 100.000

338432

CAS *: 120-82-1

96.316 50.00- 150.00 100.00

44.58- 144.58 94.56

124 Hexachlorobucadiene

31.002 31.002 (1.378) 225

31.002 31.002 (0.000) 223

1805311 100.000

237045

CAS *: 87-68-3

95.403 50.00- 150.00 100.00

12.33- 112.33 60.50

9002

fc

8733

9583

i


Air Toxics Ltd.


Page 1 D 1 0 5

Instrument ID: msdg.iLab File ID: gl!0212.dLab Snip Id: Level 5Analysis Type: VOAQuant Type: ISTDOperator: kbMethod File: /chem/msdg.i/g-02nov.b/to!41102.mMisc Info: 100ml lOOppbv


.'.... ."-.."'.. •' ' '• •

COMPOUND


STANDARD

3467151537085879614

LOfft&

208029922251527768

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48540121519191231460

SAMPLE

36065216261611055021

%DIFF

4.025.8019.94

9?

COMPOUNDs ten* *'«e£ is 4t s acd* var S criatt s aai'

51 BrcHribchloromethan651, 4 - Dl f luorobehze87 Chlorobenzenfe-dS

STANDARD=r=3^ = t»=Site"atte

15.0516.9022.53

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-otio»i«=»i»;:»=»ii

14.5516.4022.03

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IS. 65.16.5022.50

;%PIFF»ili*A«==t

0,010.01

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AREA UPP R LIMITAREA LOWgR LIMIT' + 40% of internal standard, area.

- 40% of internal standard area.

,- :.-3

DattD«t» : 02-NOV-2001 11:31

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;M 2* 27 28 29 30 31 32


RT

AMOUNTS

CAi-AMT ON-COL

EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TAJIGET RANGE RATIO SIMILARITY

••— 96 Bromoform (continued)

^< 24.102 24.102 (0.000) 171 527616 1.19- 101.19 52.20

100 1.1,2,2-Tetrachloroeehane CAS »-. 79-34-5

&t 24.847 24.847 (1.104) 83 6456317 100.000 90.749 50.00- 150.00 100.00 9171

«> 24.847 24.847 (0.000) 85 1225728 12.71- 112.71 £3.23

2j!J 102 4-Ethyltolu«ne • CAS t: £22-96-8

SJ} 25.151 25.151. U. 1181 105 6212672 100.000 98.437 SO.00- 150.00 100,00 9329

25.ISi 25,151 (0 000) 120 449175 9.00- 78.99 2».0>

53 - -.•/••} 103 1,3.5-Trimethylbenzene CAS I: 108-67-S

"*" 25.234 25.234 (1.121) 105 5331851 100.000 95.978 50.00- 150.00 100.00

25.234 25.234 (1.121) 120 2399524 0.00- 97.05 45.00

™ 106 1.2.4-Trimethylbeniene CAS I: 95-63-6

25.924 25.924 (1.152) 105 4068074 100.000 96.221 50.00- 150.00 100.00 8863

C3 25.924 25.924 (0.000) 120 4*0198 0.00- 92.84 41.46

110 1,3-DlchlorObcnxene CAS t: 541-73-1•a 26.586 24.5»«- (1.182> . 146 3973639100.000 94.513 50.00- 150.00 100.00

^ 26.586 24.5(6- 41.K?) 14« 2M57J6 11.70- 113.70 64.07

^" 26.586 26.58C (1.182) 111 1810979 0.00- 96.11 46.08

§ 111 l,4'Dlchlorob«ax«n« CAS I: 106-46-7

26.752 26.752 (1.1(9) 146 3*185*1 100.000 95.436 50.00- 150.00 100.00

_ 26.752 26.752 (1.189) 148 1276328 11.10- 113.10 62.91

26.752 26.7S2 (1.189) 111 1597446 0.00- 94.17 44.15

27.497 27.497 (1.222)

27.497 27.497 (0.000)

27.497 27.497 (0.000)

146

148

111

3711588 100.000

£81918

488640

50.00- 150.00 ' 100. 00.*

13.78- 111.78 £3.89

0.00- 95.85 45.71

9002

123 1.2,4-Trlchlorobenzene

30.808 30.808 (1.369) 180

30.808 30.808 (0.000) 182

1405288 100.000

338432

CAS •: 120-82-1

96.316 50.00- 150.00 100.00

44.58- 144.58 94.56

8723

124 Hexschlorobutadiene

31.002 31.002 (1.378) 225

31.002 31.002 (0.000) 223

1805311 100.000

237045

CAS •: 87-68-3

95.403 50.00- 150.00 100.00

12.33- 112.33 £0.50

9583

Data File: /chem/msdg. i/g-02nov.b/gl!0212 .dReport Date: 02-Nov-2001 19:35

Page busAir Toxics Ltd.


Instrument ID: msdg.iLab File ID: gl!0212.dLab Smp Id: Level 5Analysis Type: VOAQuant Type: ISTDOperator: kbMethod File: /chem/msdg.i/g-02nov.b/to!41102.mMisc Info: 100ml lOOppbv


. ' - ' "" '"•:*.'• • ' . ' " €

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3467151537085879614

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208029922251527768

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48540121519191231460

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.COMPOUND•«S=»j»,3.**'a«ti«i.ii:!a«li-=aaD»i3:e

51 Srbraochloromethan65 l ,..* ~0i f luorofceiaie87 Chlorobenzene-d&

STANDARD.a:=l:in = is±l;=tn*

15.0516.9022.53

Rf LIMITLOWfiR

W= •» »= s :»:«».» .ip

14 .is16.4022.03

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15.5517.4023.03

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15.0516.9022.50

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0.010.01

-0.12

AREA UPPER LIMIT = + 40% of internal standard area.AREA LOWER LIMIT = - 40% of internal standard area.

-p'';--'-" -: '' :: - ''-'-:"' ; : > - "''•'••' ::': ' ' ? ' ' ''

RT.

Data File:Date : 02-NOV-20O1 11:31

Client ID: L*v»l 9Sa«f1* Info: •80B-103 ZOOppbv


Page ()

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth pate

OilIntegratorTarget Version: 3.50Processing Host: eeyore

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-02nov.b/gl!0213.dLevel 6 Client Smp ID: Level 602-NOV-2001 12:10kb Inst ID: msdg.i#855-103 200ppbv200ml 200ppbv

/chem/msdg.i/g-02nov.b/tol41102.m02-NOV-20Q1 19:35 nkhan Quant Type: ISTD

12:10 - qal P.ia r'gJtlMl vd .,'..-.Calibratibri Setft le, Level: 6

1.00000HP RTE Compound Sublist: AT.sub

Sample Matrix: AIR



RT

AMOUNTS

CAi-AMT OM-COL

EXJ> RT (KBL XT) MASS B£SPOMSB ( PPBV) ( PPBV) TARGET HANGS RATIO SIMILARITY

• 51 Bromothloronxthane

15.053 13.052 <1.000)

19.052 15.052 (0.000)

CAS I: 74-97-5

SO.00- 150.00

27.43- 127.4}

5583

i«.Wi% i«.w»t (i-ood)'1C. 901 16.901 (0.000)

* 87 Chlorob«nxene-d5

22.504 22.504 (1.000)

22.504 22.504 (1.000)

' 114 .

88

117

82

5 58 1.2-Dichloroethane-d«

16.211 16.211 (1.077) 65

16.211 16.211 (0.000) 67

iS2Q»TJ 25.0000

52760

1072970 25.0000

720403

783236 25.0000

81952

50.00- ISO. 00

0;00- 67.93

CAS 1: 3114-55-4

50.00- 150.00

17.06- 117.06

CAS »: 17060-07-0

24.607 50.00- 150.00

0.00- 99.70

lOO.OO •

17.66

100.00

67.14

100.00

49.27

9136

9988

$ 77 Toluene-d8

19.716 19.716 (1.167)

19.716 19.716 (0.000)

CAS »: 2037-26-5

98 1410089 25.0000 26.278 50.00- 150.00 100.00

70 38888 0.00- 62.13 12.07

9896


Page 20111

AMOUNTS

CAL-AMT ON-COL

RT EXP RT (REL RT) MASS RESPONSE ( PFBV) ! PPBV) TARGET RANGE RATIO SIMILARITY

S 77 Toluene-da (continued)

19.716 19.716 (0.000) 100 232489 20.14- 120.14 72.15

$ 98 Bromofluorobenzene CAS I: 460-00-4

24.629 24.629 (1.094) 95 752258 25.0000 25.222 50.00- 150.00 100.00 8060

24.629 24.629 (0.000) 174 146304 8.64- 108.64 59.74

24.629 24.629 (0.000) 176 141542 6.62- 106.62 57.80- - - _ _ _ - _ _ _ . . . . _ . _ __, ... _ _ _ _ _ . . _ . . - _ _ . . _ _ . , _ _ _ . - - _ _ _ - _ . _ - . - _ _ _ - - - - - » - _ _ _ _ . _ _ _ _ _ _ _ _ _

1 Propylerte -. . . , CAS t: 115-07-1

.«.».? */031 (A,400) 41- 4S21410 300.000 180,61 50.'00- 150.00 100.00 7686

6.027 6.027 (0.000) 43 360704 15.40- 115.40 67.24

6.027 6.027 (0.000) 39 427038 30.90- 130.90 79.60

2 Dichlorodifluoromethane/Frl2 CAS »: 75-71-8

6.193 (.193 (0.411) 85 1S352237 200.000 182.00 50.00- 150.00 100.00 9037

6.193 6.193 (0.000) 87 519360 0.00- 81.76 31.54

IS 4 Freon 114 CAS tt: 76-14-2

S3 6.717 6.717 (0.446) 135 8253465 200.000 185.35 50.00- 150.00 100.00 9065

«.717 6.717 (0.000) 137 369984 0.00- 82.07 31.96

i,.,• 7 Chlorooethana CAS ft: 74-87-3

6.993 6.993 (0.465) 50 7155086 200.000 181.71 50.00- 150.00 100.00 -

_ 6.993 $.993 (0.465) 52 3322865 0.00- 82.69 33.46

** 8 Vinyl Chloride CAS «i 75-01-4-_, 7.435 7.435 (0.194) 62 7095421200.000 182.24 50.00- 150.00 100.00 4507

6? 7.435 7.435 (0.000) 64 233346 0.00- 80.22 30.07

9 1.3-Butadiene CAS *: 106-99-0

—; ..„.. VH5? ' ?;.*i>i'.ffti*?U . s.4 ..«!>?«'.>:.i»PP-"00 »»1.'4 ..-.javlpft .Wp,00... 100.00. «S5.4 „ ,. .

1 .' '• • •«-' '• -"••7- -«'*'i •*-:•.'.-.• • . :-'•-''. ' ' • • ;'*•'.\;- V - >j *>_.'• ,*;•'• -•-••••' \ ? '_•' ~ - •'•"*• • '•T- •'••''.- V -.'-.-•"' * ' • "g|* • :- —'— K'4'.-i V *'• l>'-7.-»'» -"*"» *'~t " •* »'fcl-» *»•>. V* i»*r|ij-;.* *4l* ""I,1^ T ''** <*J*"*'.*' J'1~ »T*-'"->'—' * *'->** "A-» •'.•-•. . *">;

i'C 8.704 8.704 (0.578) 94 39733)0200.000 200.40 50.00-150.00 100.00. ' 6S23 (A)

5* 8.704 8.704 (0.000) 96 445921 44.47- 144.47 93.41

H3 14 Chloroethane CAS t: 75-00-3

nj 9.008 9.008 (O.S9B) 64 3245864 200.000 196.82 50.00- 150.00 100.00 4019

9.008 9.008 (0.000) 66 104688 0.00- 81.28 31.43

*•-» _ _ . » - - _ , - - _ _ - _ _ - _ _ _ _ _ _ _ _ _ _ _ _ _ , _ . _ _ - _ » _ _ _ _ _ _ _ _ _ _ _ _ , _ _ - - _ . .- — _ _ - _ - - _ — _ - - _ • - _ - - - - - - - _ - ,

, 16 Trichlorofluoromethane/Frll CAS «: 75-69-4

^ 9.643 9.643 (0.641) 101 14374409 200.000 183.01 50.00- 150.00 100.00 9021

9.643 9.643 (0.000) 103 1305310 14.00- 114.00 63.96

21 Ethanol CAS I. 64-17-5

10.112 10.112 (0.672) 45 2192260 200.000 187.70 50.00- 150.00 100.00 3570


Page

RT

AMOUNTS

CAL-AHT OH-COL



10.112 10.112 (0.000)

10.112 10.112 (0.000)

23 Freon 113

10.830 10.830 (0.719)

10.830 10.830 (0.000)

10,830 10.830 (0.000)•* '

, i;l o*brtl*B*'10.940 10.940 10.727)

10.940 10.940 (0.000)

10.940 10 940 (0.000)

26 Acatone11.106 11.106 (0.. 73*)

11.106 11.106 (0.000)

28 Carbon Di«ul fide

11.520 11.520 (0.765)

27 2-Proptnol.

11.244 11.244 (0.747)

11.244 11.244 (0.000)

11.244 11.244 (0.000)

32 Hethylen* Chloride12.071 12.071 (O.<02)

12.Q71 12.071 (0.000)

12.071 12.071 (0.000)

. i -i . . i* . . ii i ,si; _•_ . . ',- - ,^ jNfiwfc ; --V '; : ~

ir.ioY /XiV'<o3 "fdV'boifi12.403 12.. 403 (0.000)

43

46

151

153

'101

61

96

98

43

58

76

45

43

59

49

M

51

,,--.

Vv

^41

68854

115112

8042831 200.000

580544

1341952

' *'. •. '. ~

11661959 200.000

923410

585587

9927941 200.000

500992

14208037 200.000

10476804 200.000

0

51464

8300572 200.000

880«0

414912

- - . » »-v- »,- . — - - - r •

.•'-. EsfeV. '

iVj&i488971

36 tran»-l,2-Dichloroethene

12.541 12.541 (0.833)

12.541 12.541 (0.000)

12.541 12.541 (0.000)

38 Hexane

12.872 12.872 (0.855;

12.872 12.872 (0.000)

12.872 12.872 10.000)

96

61

98

57

43

86

4980803 200.000

1527643

576128

8271541 200.000

604939

121464

0.00- 73.56

0 00- 87.72

CAS »: 76-13-1

185.87 50.00- 150.00

13.06- 113.06

94.73- 194.73

«$'•: 75-3S-4

187. 83 50.00- 150.00

0.00- 98.94

0.00- 81.37

CAS 1: 67-64-1

183.43 50.00- 150.00

0.00- 74.97

CAS *: 75-15-0

182.68 50.00- 150.00

CAS I: C7-63-0

188.21 50.00- 150.00

0.00- 50.00

0.00- 52.94

CAS l> 75-09-2

190.67 50.00- 150.00

12.02- 112.02

0.00- 79.96

.--,i, » » -..--. .--? -T-

;:;^li-::";;.:" ''bVoo- "74.01

0.00- 75.37

CAS 1: 156-60-5

182.24 50.00- 150.00

125.59- 225.59

13.07- 113.0?

CAS *: 110-54-3

183.63 50.00- 150.00

17.69- 117.69

0.00- 63.99

22.68

37.91

100.00

64.67

149.48

100.00

47.87

30.35

100.00

25.38

100.00

100.00

0.00

2.80

100.00

C3.12

29.74

--*,---,-.-- ,

.. .... - -. -.- ."•• . .. ; : ', .

23 94 ; - '1

25.28 '

100.00

168.73

63.63

100.00

67.03

13.46

8620

8702

6493

8053

6144

9471

--•- -

«70

8245

7287

Data File: /chem/msdg.i/g-02nov.b/gl!0213.d^ Report Date: 02-Nov-2001 19:35

Page D113

RT EXP RT (REL RT)

AMOUNTS

CAL-AMT ON-COL


54 Cycloh*x»M

15.S21 15.521 (1.031)

CAS I: 110-82-7

84 C472213 200.000 179.23 50.00- 150.00 100.00

H-; iiio* . •.-/.'.• ••..•:.-MiH-i-iwii'*-

SIMILARITY

42 1, 1-Dichloroethane

13.424 13.424 (0 .892)

13.424 13.424 (0 .000 )

41 Vinyl Ace cats

13.341 13.341 (0.886)

13.341 13.341 (0 .000)

13.341 13.341 (0.000)

_.- 4* ei»-Vv*êii«hio*o«tJi14.555 U/5S5 (0.567)

14.555 14.SS5 (0.000)

14.555 14.5S5 (0.000)

47 2-ButanoiM

14.500 14.500- (0.963)

14.500 14.500 (0.000)

14.500 14. SOO (0.000)

SO Tetr«hydrofu*an15.024 15.024 (0.»98>

15.024 15.024 (0.000)

15.024 15.024 (0.000)

52 ChlorofarB3.107 15.107 (1.004)

15.107 15.107 (0.000)

63

65

43

42

86

\OfSSk' '

<196

98

43

72

57

42

71

72

83

85

11216446 200.000

650304

146S32B5 200.000

220391

158528

'•• ' '%' • •

9710542 200.000

1190378

765056

12183400 200.000

473600

171008

6461,12ft 200.000

445952

4S620I

11962833 200.000

1443S40

CAS »: 75-34-3

186.06 50.00- 150.00

0.00- 81.57

CAS »: 108-05-4

196.77 50.00- 150.00

0.00- 58.86

0.00- 56.52

• 'da.. tvisiVw-i186.72 5D.OO- 150.00

11.83- 111.83

0.00- 89.48

CAS #: 78-93-3

189.07 50.00- 150.00

0.00- 69.80

0.00- 57.28

CAS *: 109-99-9

183.69 50.00- 150.00

0.00- 85.94

0.00- 86.91

CAS 1: 67-66-3

18S.55 50.00- 150.00

13.33- 113.33

100.00

31.59

100.00

8.90

6.40

100.00

64.17

41.24

100.00

2 0 . 2 4

7.31

100.00

35.50

36.31

100.00

63.44

6409

5924

8240

7907

749>

'

9162

SJ 1,1,

15.494 15.494 (1.029)

15.494 15.494 (0.000)

97 10941274 200.000 184.24 50.00- 150.00 100.00 '

99 1060352 14.22- 114.22 64.02

8291

7441

55 Carbon Tctrachloride

15.770 15.770 (1.048) 119

15.770 15.770 (0.000) 117

10142256 200.000

1637592

CAS I: 56-23-5

184.41 50.00- 150.00 100.00

54.52- 154.52 104.91

8674

60 Benzene

16.239 16.239 (0.961)

16.239 16.239 (0.000)

78 18351718 200.000

77 703680

CAS *: 71-43-2

185.46 SO.OC- 150.00 100.00

0.00- 72.58 2 2 . 7 7

9320

62 1.2-Dichloroethane

16.349 16.349 (0 .967 ; 62 9179035 200.000

CAS »: 107-06-2

183.72 50.00- 150.00 100.00 5896


Page

RT EXP RT (REL RT)

AMOUNTS

CAL-AMT OJJ-COL

MASS RESPONSE I PPBV) ( PPBV) TARGET RANGE RATIO SIMILARITY

62 1,2-Dichloroethane (continued)16.349 16.349 (0.000) 64 5S95SS 0.00- 81.63 31.24

63 Heptane CAS »: 142-82-5

16.377 16.377 (0.969) 13 8238027200.000 197.63 50.00- 150.00 100.00 7508

16.377 16.377 (0.000) 57 604660 0.00- 99.60 49.67

16.377 16.377 (0.000) .71 578368 0.00- 97.14 47.51

«a Triehlorofywtrt . •. C*S *•, 79-oi-e!•>.€»«- IT.4Jft O.Olt) 9Jt3i7553 200.000 1*5.24 S8.00- 150.00 100.00 8843

17.436 17.426 (0.000) 130 1267712 35.95- 135.95 84.68

17.426 17.126 (0.000) 97 961600 14.42- 114.42 64 .23

70 1,2-Dichloropropane CAS »: 78-87-5

17.9SO 17.950 (1.062) 63 5944404 200.000 186.97 50.00- 150.00 100.00 8539

17.930 17.950 (0.000) 62 841512 23.64- 123.64 72.88

17.950 17.950 (0.000) 41 807981 20.58- 120.51 69.40

71 1.4-Dloxane CXS *: 123-91-118.088 IS.088 (1.0701. 88 3500177 200.000 189.06 50.00- 150.60 100.00 2827

18.088 18.088 (0.000) 58 542912 26.57- 126.S7 73.75

18.088 18.088 (0.000) 57 193408 0.00- 76.9J 26.27

74 BroaodiclUoroMttiMe CAS I.- 75-27-418.419 18.41S (1.090) 8J 10829890 200.000 184.65 50.00- 150.00 100.00 9173

18.419 It.419 (0.000) 85 1556480 13.74- 113.74 63.20

75 ci»-l,3-Dichlotopropene

19.247 19.247 (1.139) 75

19.247 19.247 (0.000) 77

9271273 200.000

757056

CAS *: 10061-01-5

187.44 50.00- 150.00 100.00

0.00- 81.48 31.73

8307

19.413 19.413 (0.000)

19.413 19.413 (0.000)

43

SB

85

1*132313 itW.'pOO

1021824

346808

194.91 SO'.OC iSO.OO

0.00- 86.51

0.00- 63.28

36.67

12.45

78 Toluene19.854 19.854 (1.17S) 91

19.854 19.854 (0.000) 92

15828047 200.000

2167296

CAS *: 108-88-3

202.00 50.00- 150.00 100.00

11.20- 111.20 61.64

9056(A)

79 trans-1.3-Dlchloropropene

20.296 20.296 (0.902) 75 8618522 200.000

20.296 20.296 (0.000) 77 734589

20.296 20.296 (0.000) 39 1495688

CAS t: 10061-02-6

171.99 50.00- 150.00 100.00

0.00- 81.46 31.54

14.44- 114.44 64.22

9160


Page 15

RT

AMOUNTS

CAL-WfT ON-COL


•£: 80 1.1.2-Trlchloroethane=" 20.682 20.682 (0.919)

20 .682 20 .682 (0 .000 )

33 20.682 20.682 (0 .000)

82 Tetrachloroethene•m 20.848 20.848 (0.926)

£] 20.848 20.848 (0.000)

30, m lO'irti io.wo>'

- 83 2-Hexinone

•3 20.986 20.986 (0.933)

20.98C 20.986 (0.000)

• 20.986 20.986 (0.000)PH

97

99

83

166

'l29

m ;

43

58

100

6313261 200.000

1034944

1523200

6554892 200.000

1209856

liS4744

12528994 200.000

K583C8

241152

aa • -85 Dibronochlorooethane

™ 21.455 21.455 (0.953)

m 21.455 21.455 (0.000)

86 1.2-DibronoathaoeMgj

j|j 21.738 21.758 (0.967)

-J 21.758 21.758 (0.000)

j3| 88 ChlorabanMM<H 22.569 22.559 (1.002)

»3.9S9 22,539 (0.000)

— "~ 22. 559 22.559 (0.000)

H 90 Ethyl Benzene22.««2 22. (42 (1.006)

S. : ':., l- i? .IJ^?«).. ;;

^^gS^^T ;.|fe"•a "'r :-22-.8« 'ii.««2 U.0l«),• T] .

jll 22.835 22.835 (1.015)

^ 94 o-Xylene

id 23.608 23.608 (1.049)

"** 23.608 23.608 (0.000)

95 Styrene

SfiJ 23.635 23.635 (1.050)

23.635 23.635 (0 .000)• ".

129

208

107

109

112

114

77

106

. »> ...

106

91

106

91

104

78

8110355 200.000

90587

•6577344 200.000

1684992

11073513 200.000

863808

2026218

5103318 200.000

..-.t.W*.M*. • :

10C&ti07 400.000

22505357

4444645 200.000

2988513

7868277 200.000

1180127

CAS *: 79-00-5

170.42 50.00- 150.00

12.01- 112.01

41.25- 141.25

CAS »: 127-18-4

179.13 50.00- 150.00

26.00- 126.00

.22*M^..1»-.SJ

CAS «: 591-78-6

194.02 50.00- 150.00

0.00- 99.76

0.00- 57.46

CAS *: 124-48-1

170.98 50.00- ISO. 00

0.00- 54.43

CAS «: 106-93-4

172.11 50.00- ISO. 00

44.19- It*. 19

CAS 1: 101-90-7

189.42 50.00- 150.00

0.00- 81.89

20.15- 120.15

CAS •: 100-41-4

190.25 50.00- 150.00

, • • ;;L^)a.v»iji_.; jja, ,««,_•;

374.58 50.00- iSO.OO

162.61- 262.81

CAS t: 95-47-6

186.45 50.00- ISO.OO

178.62- 278.62

CAS •'. 100-42-5

191.60 50.00- 150.00

4.47- 104.47

100.00 8926

6 2 . 4 3

91.88

100.00 8996

80.18

76.37

100.00 8363

50.06

7.28

100.00 8489

4.47

100.00 5533

94.17

100.00 8999

31.54

73.98

100.00

J-ii.31

100.00 '; (A)

211.06 '

100.00 9151

225.63

100.00 8765

55.85

96 Bronoforn

24.104 24.104 (1.071) 173 7002065 200.000

CAS «: 75-25-2

175.14 50.00- 150.00 100.00 8723


116

RT

AMOUNTS

CAL-AMT ON-COL

EXP RT (R£L RT) MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO SIMILARITY

96 Br onto form (continued)

24.104 24.104 (0.000) 171 999040 1.31- 101.31 51.80

100 1.1.2,2-Tecrachloroethane CAS I: 79-34-5

2 4 . 8 4 9 2 4 . 8 4 9 (1.104) 63 12582927200.000 179.77 50.00- ISO.00 100.00 9207

24.849 24 .849 (0 .000) 85 2378240 12.77- 112.77 62 .94

102 4-Ethyltoluane ' CAS •: 622-96-8

" ' 2 0 0 . 0 0 0 19-4.a* so:-oo- iso.ea ioo.«» 934*. ••'••' - ';Vi'oo--' Te.ii ?e.S4

103 1,3,5-Trimethylbenrene CAS I: 108-67-8

25.236 25.23C (1.IJ1) 105 10S84J38 200.000 191.72 50.00- 150.00 100.00

25.236 25.236 (1.121) 120 4837031 0.00- 96.61 45.27

106 l,2,4-TYi«JlChyiben«ene CAS »: 95-63-6

25.926 25.926 (1.152) 105 8388333 200.000 196.29 50.00- 150.00 100.00 8857

25.926 25.926 (O.OflO) 120 921230 0.00- 92.53 41.61

110 l,J-DichI<>rc**n*ene CAS f: 541-73-1

16.588 26,5«1 (l.-l»3) 14< .777434(200,000 19S.04 5O.OO-150.00 100.00

26.588 26.5»e (1.1S2) 148 4933105 13.64- 113.64 63.45

26.588 26.5*8 (1.182) 111 3552775 0.00- 96.01 45.70

111 1,4-DlchlQtqbcinan* CAS I. 106-46-7

26.754 26.7S4 (1.U9) 14« 7113017 200.000 188.11 50.00- 150.00 100.00

16.754 M.754 (1.1*9) 148 4532516 13.26- 113.26 63.72

26.754 24.754 (1.189) 111 3177346 0.00- 94.29 44.67

114 B*H»yl QUorid* CAS >: 100-44-7

Wl;27.499 27.499 (1.222) 14*

27.499 27.499 (0.000) 148

27.499 27.499 (0.000) 111

7223738 200.000

1342176

943744

CA» ifi 95-50-1

185.51 50.00- 150.90 100.00'

13.98- 113.98 64.61

0.00- 95.74 45.43

8999

123 1,2,4-Trichlorobenien*

30.811 30.811 (1.369) 180

30.811 30.811 (0.000) 182

2978090 200.000

704960

CAS *: 120-82-1

200.52 50.00- 150.00 100.00

44.43- 144.43 93.98

8696(A)

124 Hexachlorobucadiene

31.004 31.004 (1.378) 225

31.004 31.004 (0.000) 223

3703617 200.000

499624

CAS *: 87-68-3

194.28 50.00- 150.00 100.00

12 .44- 112.44 62.79

9612

fei


QC Flag Legend

A - Target compound detected but, quantitated amountexceeded maximum amount.

Page 8 " 1 1 •

'J&

1

a

J3J


Air Toxics Ltd.


Pa9el0118

Instrument ID: msdg.iLab File ID: gl!0213.dLab Smp Id: Level 6Analysis Type: VOAQuant Type: ISTDOperator: kbMethod File: /chem/msdg.i/g-02nov.b/tol41102.mMisc Info: 200ml. 20Oppbv

Calibration Date-. 02-NOV-2001Calibration Time: 10:39Client Smp ID: Level 6Level: LOWSample Type: AIR

COMPOUND

51 Brortiochloromethan651,4-Difl uorobenze8? Chlorobenzeiie-d5

STANDARD

3467151537085879614

iARBALOWER

208029922251527768

LIMITUPPER

48540121519191231460

SAMPLE

36315916208771072970

%DIFF

4.745.45

21.98

COMPOUND

51 Brorrtoehloromethan65 1,4 -p,i f luorofcen ze87

15.0516.9022.53

RT

14.5516.4022.03

UPPER

15.5517.4023.03

SAMPLE

15.0516.9022.50

%DIFF

0.020.02-0.11

AREA UPPER LIMITLIMIT

+ 40% of internal standard area.- 40% of internal standard area.

• - - .

i?n*D i ch 1 orod i f 1 uoronethane/F

-Fr*on 114-ChloroM* thane

-Vinyl Chloride*

-Brononethane-Chloroe thane

-Trichlorofluorotwthane/Fr

Bisulfide

-Htthylen* Chloride,2-BloMoreethene

-«i*-l,2-DicMcroeth»ne

-Br«>oohlor O>H| thane*-Cyclohexane*

-Trtiohior«iethen»

L^pîîn'i VlTi n "•• n ,-ri V-'JiTjrrt'-Y"./.' ' -i,l,»?-T»tr»chIoroeth*»>

-1,2,4-TrlwethMlberaene

-Benzyl Chloride'

• -1,2-Diohlorobenzene

0119£ 'fSSIs > * « »

fT5 1

Data File: /chem/msdg.i/g-04nov.b/gl!0407 . dReport Date: 05-Nov-2001 07:15

10 1 2 0m!„•

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethod

Dil FatorIntegrator

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg. i/g-04nov.b/gl 104 07. dLevel 2 Client Smp ID: Level 204-NOV-2001 17:12xp Inst ID: msdg.i2ml #855-1062 0 Oppbv- 2ppbv

/chem/msdg. i/g-04nov.b/tol41102,m0?:15 jkhatri Quant Type,;

• • • • - • • •i . 6 0 ooHP RTB

Target Version; 3.50Processing Host: eeyore

LeVel: 2

Compound Sublist: ethylact.subSample Matrix: AIR



AJOOBT3

CAL-AHT ON-COt

RT SXP RT (*Et tT) MASS RESPONSE ( Pfr»V) ( PWV) TAtKST RANCH RATIO SIMiLMUTY

• 5115.034 15.024 (1.000)

15.024. If/PS* (0,0*0)' " ' " '

130 363352 25.0000

CAS »: 7«-97-5

50.00- ISO.00

27. H- 127. IS

100.00

16,40

,««..7>-

"*-*'- j"*W- *'--»*C,.» .*«> T *,*-» -'

16.874 16.874 (0.000) 4 9584

*».'««- 150.00

0.00- 67.75

100.00

3.01

9178

• 87 Chlorobensenc-dS

22.504 22.504 (1.000) 117

22.504 22.504 (1.000) 82

989869 25.0000

(S9622

CAS »: 3114-55-4

50.00- 150.00 100.00

16.93- 116.93 66.64

46 Ethyl Acetate

14.417 14.417 (0.960) 43 79110 2.00000

14.41? 14.417 (0.000) 61 1859

14.417 14.417 (0.000) 45 1991

CAS I: 141-78-6

1.506 50.00- 150.00 100.00

0.00- 63.41 2.35

0.00- 64.44 2.52

6234(a)


QC Flag Legend



Air Toxics Ltd.


Page

Instrument ID: msdg.iLab File ID: gl!0407.dLab Smp Id: Level 2Analysis Type: VOAQuant Type: ISTDOperator: xpMethod File: /chem/msdg.i/g-04nov.b/to!41102.mMisc Info: 200ppbv-2ppbv


KM

{$B5-

£

£

!T

fo

COMPOUND

51 Braraochloromethan65 1 , 4 - Bi t luorobenze87 Chlorob;erizene-d5

STANDARD

3446951582780931176

AREALOWER

206817949668558706

LIMITUPPER

48257322158921303646

SAMPLE

3633521648731989869

%DIFF

5.414.176.30

COMPOUND

51 Bromochloromethan65 1 , 4- :f luptêrtie87 chlorobeftspene-dS

STANDARD,

15.0516.9022 . 50

RT ILOWER

14.5516.4022.00

..IMITUtPEfR

15.5517.4023.60

SAMPLE

15.0216.8722.50

%DIFF

-0.16-0.14

0.02 Uj

AREA UPPER LIMIT

V.. •':

+ 40% of internal standard area-.40% Q£ internal, standard area

"" '

CO/oh««/>i»dc.l/f-O4nov.b/'sll0407.d

: 04-HOV-2(X>1 17112

Clivnt ID: L»v»l 2

Info: 2nl »8B5-106

Column ph«s*: RTx-624

10 11 12 •&-, 14 18 « '17 .«-...» Ji* 21 22'Hlrt '

, 28 26 27 28 29 30 31 32


Page QLJ 2 4

Data fileLab Snip IdInj DateOperatorSmp InfoMisc InfoCommentMethodMath Date' "

Dil Pa6torIntegrator

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg. i/g-04nov.b/gll0408 .dLevel 4 Client Smp ID: Level 404-NOV-2001 17:50xp Inst ID: msdg.i50ml #855-106200ppbv-50ppbv

/chQm/msdg.i/g-04nov.b/tol41102.m'- 20.01 07:15 jkhatri Quant Type:

17:50

i.oooobHP RTB


Compound Sublist: ethylact.subSample Matrix: AIR



AMOUNTS

CAL-AKT ON-COL

RT RXP RT (RBL RT) MASS RESPONSE ( PPBV) ( PPttV) TARGET RAMCB RATIO SIMIUUtlTY

' •• 51 a>ro«ochlorofi*ctMin«

15.048 15.048 (1.000)

15.Q48 15.648 (9.000)

^.;~- ' -f?f^*??> '$jj$$4$£!IIQ!-:ty's- - tî^-'ti wi'iigi^sSsfeife

16.898 16.898 (0.000)

* 87 Chlorobeniene-dS

22,500 32.500 (1.000)

22.500 22.500 (1.000)

46 Ethyl Acetate

14.414 14.414 (0.958)

14.414 14.414 ( 0 . 0 0 0 )

14.414 14.414 (0 .000)

130

12»

344695 25.0000

57(48

: jiifcM~.'-l%H- - Va— * * i *."- i - - - 1 .*-.î;-SV^/.^'-'-' ;- ,

•""'iii ; ism<« 25.000088

117

82

43

61

45

51016

931176 25.0000

619822

2777301 50.0000

65088

69848

CAS #: 74-97-5

10.00-

27.34-

''c^-:*v's:i*.}'fc§<j. 00-

0.00-

CAS »: 3114-55

80.00-

16.93-

CAS »: 141-78-

55.754 80.00-

0 .00-

0.00-

120.00

1)7.34

110.00

68.10

-4

120.00

116.93

6

120.00

63.41

64 .44

100.00

16.72

"ioo.oo" f'3.22

100.00

66.56

100.00

2 .34

2.51

9119

9220

6146

Data File: /chem/msdg.i/g-04nov.b/gl!0408.d-* Report Date: 05-Nov-2001 07:15 10125

Air Toxics Ltd.


Instrument ID: msdg.iLab File ID: gl!0408.dLab Smp Id: Level 4Analysis Type: VOAQuant Type: ISTDOperator: xpMethod File: /chem/msdg.i/g-04nov.b/to!41102.mMisc Info: 200ppbv-50ppbv


COMPOUND

51 Brorooehioromethan65 l;4-Difiuoroioenze87 Chlorobenzene-d5

STANDARD

3446951582780931176

206817949668558706

UPPER

48257322158921303646

SAMPLE

3446951582780931176

%DIFF

0.000.000.00

COMPOUND*Si*aim -;'iat4ti*:3=:-=r=:»=i:=:a:=

51 Bromochloromethan65 1, 4,-0if luorobenze87 Chlorobenzene-d5

STANDARDse':*s*rsC8s<**

15.0516.9022 . 50

RT LIMITLOWER

=as: = = = i3S = =

14.5516.4022.00

UPPER= = t=airiS5 ==a

15.5517.4023.00

SAMPLE= = = = n=33* = =3

15.0516.9022.50

%PIFF£. = = e = 3 =

0.000.000.00

AREA UPPER LIMITAREA, LQWBR LIMIT""""

+ 40% of internal standard area- 40% of internal standard area

; T-""'•; -r-/7!.- • -vp'-'-T r "~ ' "•.'••'• "-.' ' '•V'v>f>'V<'"<

1 ::-':vv^-" 't:

. n

CO

0«t» : 04-NOV-2001 17J50Client ID: L»v»l 4Smplc Info: 60ml 08S5-1C*

Column phase: RTx-624 Column diMwt«ri 0.53

1.1-

1.0-

0.9-

0.8-

0.7-

0.6-

> 0.5-

0.4-

0.3-

0.2-

0.1-

jJW «-t^4_u

s

<*.•*'a

AJU.

?

8 9 10 11 12 13 14 18 16 17 18 19 26 21 22 29 26 27 28 29 30 31 32


Page 2 7

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethod

Oil FactorIntegrator

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-04nov.b/gl!0409.dLevel 6 Client Smp ID: Level 604-NOV-2001 18:28xp Inst ID: msdg.i200ml #855-1062 0 Oppbv-2 0 Oppbv

/ch.em/msdg.i/g-04nov.b/tol41102.m05-Noy-2o5l 07:15 jkhatri Quant Type:

• • • ••" a" ' - ' "•"• . ISra-f l f - ' ' - ' " - • ' • •Cal-'-FUAv-:^-..^—-- .Galibritibii sai^le> tavel: 6

ISTD

1.00000HP RTE

Target Version: 3.50Processing Host : eeyore

Compounu Sublist: ethylact.subSample Matrix: AIR

••3 Concentration Formula: Amt * DF * CpndVariable


AMOUNTS

CAL-AMT ON-COL

RT EXP RT (REL RT) MASS RESPONSE ( PVBV) ( PPBV) TARGET RANGE RATIO SIMILARITY

• 51 BrcmbchlorcMnethana

15.051

15.051

•2&$&-•*'*:-'&

£^**i'is.joo16.900

15.

15.

•'•••'•*&zsm$?$!• / i • \ i*i

1C.

16.

Oil

951

GSc

w900

(1.000)

(0.000)

apfyiifess^P^yfySp?

"uifiboi(0.000)

130

128

^^-v^rZ'^ *•*• *-'*•$$£:• k.'..-..'1

; '^ ' l l4

88

349216 25.0000

58584

y^^.^.--:,;:.,aZxftyifqfe.. --T -j.Mi.-iii«*i;-4J'> XvK^ V.i?.-T.-;;'";;>..»-:^?>: - . ' • • -:-.-•.-;••-•149473'b 25.0000

44256

• 87 Chlorob«nz*ne-d5

22.530

22.503

22.

22.

530

503

(1.000)

(1.000)

117

82

871238 25.0000

582291

CA3 »: 74-97-5

50.

27.

•_..&&

"r'.'.X^-'r*'

00- 150.1C- 137.

»4>.-a«.-'*4.;.v!/ix

00

16

»P.

100.16.

44;

^^•Sw i-'iiMi-::1- • • • . • . - • • ; • • :sir. ""0.

00- ISO.

00- 67.00

75

100.2.

00

78

77

* "

00 f

96

8924

•'•'•'•'. ..-:

\

9164

CAS »: 3114-55-4

50.

16.

00- 150.

93- 116.

00

93

100.

66.

00

83

46 Ethyl Acetate

14.444 14.444 (0.960)

14.444 14.444 (0.000)

14.444 14.444 (0.000)

43 11422112 200.000

61 2S86B8

45 2B0640

CAS I: 141-78-6

226.33 50.00- 150.00 100.00

0.00- 63.41 2.26

0.00- 64.44 2.46

61B3(A)

Data File: /chem/msdg . i/g-04nov. b/gl!0409 . d Page 20128Report Date: 05-Nov-2001 07:15

QC Flag Legend

A - Target compound detected but, quantitated amountexceeded maximum amount.


Air Toxics Ltd.


Page 10129

Instrument ID: msdg.iLab File ID: gl!0409.dLab Srap Id: Level 6Analysis Type: VOAQuant Type: ISTDOperator: xpMethod File: /chem/msdg.i/g-04nov.b/to!41102.mMisc Info: 200ppb.v-200ppbv


...',; V. ?-.'•£ ~ ~

COMPOUNDsazas»9 = = ssz3sa::a = ±: = a

51 Bromochloromethan65 1,4-Difiuorobenze87 ChlQFQ enfcene-etS

• ' ' . - • .

STANDARD= = nc = ;i=i = =s= =

3446951582780931176

: ; AREA LIMITLOWER

=3===fe====

206817949668558706

UPPER= = =:=3=*=t3 = =3 =

48257322158921303646

SAMPLE= = ===3:31 = =:= = =:

3492161494730871238

%DIFF=======

1.31-5.56-6.44

COMPOUND=S==e=! tst±»-rk = =, a=a«=a=« a =c = = =:=»==

51 BrorttQchlororoethan6587

15.0516.9022.50

RT LIMITLOWER

14.5516.4022.00

UPPER

15.5517. 4Q23.00

SAMPLE

15.0516.9022.53

%DIFF

0.020.020.13

AREA UPPER LIMIT = + 40% of internal standard area.- 40% of internal standard area.

9•<Qf

1

oCO

-- J

I Data Ftl»: Xoh»iv'in»«t.i/i-O4nov.b/tll0409.el

D«t* : 04-HOV-2001 18:28

Cli*nt ID: L*v*l 6

Info: 200nl V86S-106

Pat*

Column ph«»«: RTx-*24

In»trun«ntt

Operator: xpCeluwi <ti«M>t«r: 0.63

14 SS :ii 17 18

Data File: /chem/msdg.i/g-04nov.b/gl!0405.dReport Date: OB-Nov-2001 05:45

Air Toxics Ltd.

RECOVERY REPORT

Page 1

Client Name:Sample Matrix: GASLab Smp Id: LCSLevel: LOWData Type: MS DATASpikeList File: AFCEE3.0.spkSublist File: AT.subMethod File: /chem/msdg.i/g-04nov.b/to!41102.mMisc Info: 200ppbv-25ppbv

Client SDG: g-04novFraction: VOAClient Smp ID: LCSOperator: xpSampleType: LCSQuant Type: ISTD

0131

. • • m •

SPIKE COMPOUND

1 Propylene2 Dichlprodifluorome4 Freon 1147 Chi orome thane8 Vinyl Chloride9 1, 3-Butadiene

13 Bromome thane14 Chloroethaine1.6 Trlchl<5rof luoromet21 Ethanol23 Freon 11325 1,1-Dichloroethene26 Acetone28 Carbon Bisulfide27 2-Propanol32 Methylene Chloride35 MTBES J ana- 1, 2 -pdcfelgro

' *i:tf'"'' 'W«WUMi" ~'J~' '** '*'?i::''-.'?'*'t \' '

• : •'.: " ^ i S ^ g Hf ^ -'""•.." •'•-4 / iOTj l ^ ^ V ''"'•• ' '''•48 irifl-i, 2^Dichiejroet47 2-Butanone50 Tetrahydrofuran52 Chloroform54 Cyclohexane53 1, 1,1-Trichloroeth55 Carbon Tetrachlori60 Benzene62 1, 2-Dichloroethane63 Heptane68 Trichloroethene70 1,2-Dichloropropan

CONGADDEDPPBV

25.00025.00025,00025.00025.00025.00025.00025.00025.00025.00025.00025.00025.00025.00025.00025.00025.00025.0003K<$Q•.-••• a fto--25. 6'Od25.00025.00025.00025.00025.00025.00025.00025.00025.00025.00025.00025.000

COtfCRECOVEREDPPBV

24.60429.35028.63725.69629.08928.49631.57826.82929.04924.477 -26.38526.03926.36725.68926.62024.53425.7622.6. 16a& eias; 3762$. 4 1724'. 44024.95624.98627.22425.90428.83427.58425.01525.38625.48024.97728.611

%RECOVERED

98.42117.40114.55102.79116.36113.98126.31107.32116.1997.91105.54104.16105.47102.75106.4898.14103.05104.66166.47113; 50105. 6797.7699.8299.94108.9010"3.61115.34110.33100.06101.54101.9299.91114.45

LIMITS

60-14070-13070-13070-13070-13060-14070-13070-13070-13060-14070-13070-13060-14060-14060-14070-13060-14060-140£0-1.4070>13060-14670-13060-14060-14075-12560-14075-12575-12575-12575-12560-14075-12570-130


Page 2

0132

SPIKE COMPOUND

71 1,4-Dioxane74 Bromodichlorometha75 cis-l,3-Dichloropr76 4-Methyl-2-pentano78 Toluene79 trans-l,3-Dichloro80 1,1,2-Trichloroeth82 Tetrachlproethene8

CONGADDEDPPBV

25.00025.00025.00025.00025.00025.00025.00025.00025.000

25,00025.00050.00025.00025.00025.00025.000

25.00025.0002s;oqo25.00025.00025.00025.00025.000

CONCRECOVERED

PPBV

24.43624 .33424.69224.39427.57322.54824.59926.01023,33124,i:il30.5J5Q24.61625.96352.43628.98224.45024.90224.62621.95424.72823.78021.35120.79022.17920.59614.83317.121

RECOVERED

97.7497.3498.7797.58110.2990.1998.39104.0493.3296.44122.0198.46103.85104.87115.9397.8099.6198.5087.8298.9195.1285.4083.1688.7182.3959.33*68.49*

LIMITS

60-14060-14070-13060-14070-13070-13070-13070-13060-14060-^14075-12570-13070-13075-12575-12575-12560-14070-13060-14070-13070-13070-13070-13070-13070-13070-13070-130

<S

$ 77 bi?iieti«*-d:8$ 98 Bromofluorbbenzene

GiMJC

mmm^-:-: :&ff£:->

25.00025.000

CONC

26^.46424 .963

RECOVERED

98.48105.86

99.85

LIMITS

70-13070-13070-130


Page 1

0133

Data fileLab Stnp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth Date

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-04nov.b/gl10405.dLCS Client Smp ID: LCS04-NOV-2001 14:02xp Inst ID: msdg.i25ml #855-782 0 Oppbv-2 5ppbv

/chem/msdg.i/g-04nov.b/to!41102.m04-NOV-200I 13:46 jkhatri Quant Type: ISTD

Gal FiX6: gll0402.dtCS • •

Integrator HP RTETarget Veraion: 3.50Processing Host: eeyore

Compound Subli st: AT.subSample Matrix: AIR

Concentration Formula: Amt * DF * CpndVariaJble

Cj>nd Variable Local Compound Variable

CONCENTRATIONS

GH-COL FINAL

RT BXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPflV) TARQEt RANOB RATIO SIMILARITY

* SI BrooiochloroiMthane15.024 15.050 (1.000) 130

15.024 15.050 (0.000) 128

i»,pj4 . i?.<NJ.o, ,co««o.o) 4?

CAS |: 74-97-5

354574 25.0000 80.00- 120.00

59224 18.18- 121. IB

1S7»M 1*3.16- 283.16

100.00

16.70

47.33

8482

'•;•' i«.'»oi 16.899 (0.000) »8 4»«08 """0.00- 6T.SO 2.92

• 87 Chlorabensen«-d5

22.503 22.501 (1.000) 117

22.503 22.501 (1.000) 82

1077372 25.0000

714433

CAS »: 3114-55-4

80.00- 120.00 100.00

17.05- 117.05 66.31

$ 58 l,2-Oichloroethane-d4

16.211 16.209 (1.079) 65

16.211 16.209'(0.000) 67

764587 24.6198

73952

CAS *: 17060-07-0

24.620 80.00- 120.00 100.00

0.00- 99.91 9.67

$ 77 Toluene-de

19.716 19.714 (1.167) 98

19.716 19.714 (0.000) 70

1456134 26.4641

35448

CAS #: 2037-26-5

26.464 80.00- 120.00 100.00

0.00- 62.12 2.43

I

9J41

fe10000

10000


Page 2

0134

RT

CONCENTRAT IONS

ON-COL FINAL


S 77 Toluene-da (continued)

19.716 19.714 (0 .000) 100

$ 98 Bromofluorobenzene

24 .628 24.626 (1.094)

2 4 . 6 2 8 24.626 (0.000)

24 .628 24.626 (0 .000)

l Propylene .

6.027 6.835 (0.000)

6.027 6.025 (0.000)

95

174

176

42

39

205632

739261 24.

156160

148224

••

'601401 24.

54100

627(8

2 Dichlorodif Iuoromechane/Frl2

6.192 6.191 (0.412) 85 2380555 29.

(.192 6.191 (0.000) 87 83776

4 Preon 114

6. (39 6.687 (0.445)

6.689 6.687 (0.000)

7 CtalorooBthAbt

C.993 6.963 (0.465)

6.993 6.9(3 (0.4(5)

8 Vinyl Chloride

7.434 7.433 (0.495)

7.434 7.433 (0,000)

9 l,3-But*dien«

' ^ !» ,3f &^$$S^>' .-:i&*i'i $*$$'i&?%i?.-?*••^•$m&^-~ '::

8.676 8. (74 (0.578)

8.676 8.674 (0.000)

14 Chlorocthane

8.980 8.978 (0.598)

8.980 8.978 (0.000)

135

137

50

52

62

64

• %*,•

'':ftV-

' • '..•»'•.':.

94

96

64

66

1249607 28.

56(56

1069517 25.

357780

1091991 29.

362)5

.6X94.13 .28,

Uî£,;v;

•>»-1*"-t>Vf*'**'-':i'•„ .' ••:v*-"-""': * ' '

591161 31.

6995*

426208 26.

21064

16 Trichlorofluoromethane/Frll

9.615 9.613 (0 .640) 101 2199968 29.

9.615 9.613 (0 .000) 103 201792

20.05- 120.05

CAS »: 460-00-4

9629 24.963 80.00- 120.00

11.45- 111.45

10.01- 110.01

CAS l< 115-07.1

(04 4 24.604 $6. 0,0,- '.. tiO . 00

15.40- 115.40

30.90- 130.90

CAS I: 75-71-8

3506 2 9 . 3 5 0 80.00- 120.00

0.00- 81.75

CAS ft: 74-14-2

(371 28.637 80.00- 120.00

0.00- 83.29

CAS ti 74-r»-l

(966 25.696 80.00- 120.00

0.00- 79.72

CAS I: 75-01-4

0894 29.089 80.00- 120.00

0.00- 81.15

CAS I: 106-99-0

4951 28.496 .10.00- 120.00

'£ : / , , . . ; '4| i£&.:?'&";fj *^$&$^$*"-r.:••'•'••'..••••' ewf-fi >«i-(b^--' '••'-'5781 31.578 10.00- 120.00

45.47- 145.47

CAS »: 7S-00-3

8294 26.829 80.00- 120.00

0.00- 81.47

CAS »: 75-69-4

0487 29 .049 80.00- 120.00

14.11- 114.11

14.12

100.00 8500

21.12

20.05

100.00 7636

9.00

10.44

100.00 9032

3.52

100.00 9039

4.53

100.00 '

33.45

100.00 4512

3.32

109,00 6554

•i::;-t5r«.;.> -"^V:.-;

•*~V.--.-*.y -»>>:- - »«.^->- * •V i .

100.00. >' 6628

11.83

100.00 4081

4 .94

100.00 9005

9.17

21 Ethanol

10.084 10.082 (0.671) 45 279124 24 .4767

CAS I: (4-17-5

2 4 . 4 7 7 80.00- 120.00 100.00 3570


Page 3 0135

RT EXP ST (REL RT)

CONCENTRATIONS

ON-COL FINAL,


21 Kthanol (continued)

10.084 10.082 (0.000) 43 12430 0.00- 73.56 4.45

10.084 10.082 (0.000) 46 18472 0.00- 87.72 6.62

23 Freon 113 CAS »-. 76-13-1

10.801 10.827 (0.719) 151 1113165 26.3852 26.385 80.00- 120.00 100.00 8598

10.801 10.827 (0.000) 1_S3 80448 13.57- 113.57 7.23

10.801 10.827 (0.000) -"lOl 181378 93.62- 193.62" 16.29

.--- •-.-.-,;,».. »-- . i ',*-' '""' ---.i--..-.- -

JS- i.J-DtcJiloBieibewB ' , C*S »> 75-3S-*10.939 1ft.937 (0.728) 61 1589574 26.0390 26.039 80.00- 120.00 100.00 8840

10.939 10.937 (0.000) 96 133022 0.00- 99.16 8.37

10.939 10.937 (0.000) 98 879«8 0.00- 81.58 5.53

26 ACetone CAS t: 67-64-1

11.077 11.103 (0.737) 43 1393392 76.3674 26.367 80.00- 120.00 100.00 6493

11.077 11.103 (0.000) 58 67232 0.00- 74.97 4.83

28 Carbon Diaulfide CAB «: 75-15-0

11.491 11.489 (0.765) 76 1950678 25.6887 25.689 80.00- 120.00 100.00 8032

27 2-Pi'opMbl CAS »: 67-63-0

11.343 11.241 (0.748) 45 1446800 26.6204 26.620 80.00- 120.00 100.00 «154

11.243 11.241 (0.000) 43 0 0.00- 50.00 0.00

11.243 11.241 (0.000) 59 796S 0.00- 52.94 0.55

32 MethyleiM Chloride CAS »: 75-09-212.043 12.041 (0.802) 49 1082965 24.5346 24.534 80.00- 120.00 100.00 9460

12.943 12.041 (0.000) 84 155968 12.97- 112.97 14.40

12.043 12.041 (0.600) 51 70784 0.00- 79.01 6.54

V'- -' C-i ^ .i. 'v!** . ' '4 - -,- .•''""''''"'' ""' " ' '''" " ' ••••-•• - ^

.01

12.374 12.400 (0.000) 41 66252 0.00- 75.37 3.06

36 trans-l,2-Dichloroethene CAS • : 156-60-5

12.512 12.511 (0.833) 96 698246 26.1660 26.166 80.00- 120.00 100.00 8246

12.512 12.511 (0.000) 61 217088 123.87- 223.87 31.09

12.512 12.511 (0.000) 98 81824 13.07- 113.07 11.72

I

38 Hexane

12.844 12.842 (0.855) 57

12.844 12.842 JO.000) 43

12.844 12.842 (0.000) 86

1170661 26.6178

83191

17232

CAS V: 110-54-3

26.618 80.00- 120.00 100.00

17.69- 117.69 7.11

0.00- 63.99 1.47

7287


Page 4

0136

RT

CONCENTRATIONS

ON-COL FINAL

EXP ST (REL RT) MASS RESPONSE { PPBV) ( PPBV) TARGET RANGE RATIO

54 cyclohexana

15.493 15.491 (1.031) 84 913110 25.9036

SIMILARITY

42 1,

13.423

13.423

1 -Dichloroethane

13.

13.

41 Vinyl

13.340

13.340

13.340

'.jilt*!

14.527

14.527

14.527

13.

13.

13.

S"iv

14.

14.

14.

421 (0

421 (0

.893)

.000)

63

65

1670200 28.3759

91064

Acetate

339 (0

339 (0

.339 (0

525 (0

525 (0

525 (0

.888)

.000)

.000)

.967)

.000)

.000)

43

.42

86

Jj*»e , .

61

96

98

1920740 26.4170

30235

22584

*•*•'.'-

1286182 24.4398

172352

106184

47 2-Butanona

14.472

14.472

14.472

14.

14.

14.

470 (0

470 (0

470 <0

.961)

.000)

.000)

43

72

57

1570104 24.9562

62648

22992

50 Tetrahydrofuxan

15.024

15.424

15.024

IS.

15.

15.

022. (1

022 (0

.000)

.000)-

022 (0.000)

42

71

72

858101 24.9861

60114

59296

52 ChloroformIS. 079

15.079

is.15.

077 (1

077 (0

.004)

.000)

83

• 5

1719739 27.2246

212864

CAS »: 75-34-3

28.376 80.

0.

00-

00-

120.00

81.93

100.

5.

.00

45

6409

CAS 1: 108-05-4

26.417 80.

0.

0.

00-

00-

00-

120.00

58.86

56.5?

100.

1.

1.

00

57

18

6002

;CA»-»f lSe>5»-2 • ' . . - . ' •

24.440 80.

11.

0.

CAS •: 78-

24.956 80.

0.

0.

CAS t- 109

24.986 80.

0.

0.

CAS »: 67-

27.224 10.

13.

00-

B4-

00-

93-3

00-

00-

00-

-99-

00-

00-

00-

66-3

00-

10-

120.00

111.84

89.63

120.00

70.15

57,28

9

120.00

86.24

86.91

120.00

111.10

100.

13.

8.

100.

3.

1.

100.

7.

6.

100.

12.

00

40

26

00

99

46

00

04

91

00

38

8240

7917

7493

*"

9199

CAS It 110-82-7

25.904 80.flO- 120.00 100.00

71 1?,80

'.- >tbH' *.;

8267

15.493 15.491 (1.031) 97

15.493 15.491 (0.000) 99

1657990 28.8341

166656

28.834 80.00- 120.00

13.60- 113.60

100.00-

10.05

7435

55 Carbon Tetrachlorlde

15.769 15.767 (1.050) 119

15.769 15.767 (0.000) 117

1457131 27.5835

239952

CAS t: 56-23-5

27.584 80.00- 120.00 100.00

54.50- 154.SO 16.47

8631

60 Benzene

16.211 16.236 (0.959) 78

16.211 16.236 (0.000) 77

2582247 25.0147

97600

CAS *•. 71-43-2

25.015 80.00- 120.00 100.00

0.00- 72.61 3.78

8768

62 1,2-Oichloroechane

16.349 16.347 (0.967) 62 1327008 25.3856

CAS *: 107-06-2

25.386 80.00- 120.00 100.00 5690

Data File: /chem/msdg.i/g-04nov.b/gl10405.dReport Date: 05-Nov-2001 05:45

CONCENTRATIONS

ON-COL FINAL

RT EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV) TARGET RANGE RATIO

Page 6 1 3 7

li

SIMILARITY

75 ci»-l,3-Dlcnloropropen«11.346 19.245 (1.139) 75

19.24* 19.245 (0.000) 77

1286898 24.6922

95713

CAS *: 10061-01-5

24.692 80.00- 120.00 100.00

0.00- 82.08 7,44

62 1,2-Dichloroechane (continued)

16.349 16.347 (0.000) 64 88312 0.00- 81.40 6.65

63 Heptane CAS * 142-82-S

16.376 16.374 (0.969) 43 1089835 25.4806 25.480 SO.00- 120.00 100.00 7225

16.376 16.374 (0.000) 57 75288 0.00- 99.60 6.91

16.376 16.374 (0.000) 31 71024 0.00- 97.14 6.52

68 T*i<hior<>»tb«ne • CAS »: 79-01-6

lr.-J»'ii 17:39"$' flV*»9V 9S 103««4 14.9771 24.977 80.W-120.00 100..6Q »»S2

17.397 17.195 (O.OOO) 1)0 184064 31.96- 111.96 17.80

17.397 17.3»5 (0.000) 97 139072 14.17- 114.17 13.45

70 1,3-Dichloropropane CAS »: 78-87-5

17.949 17.947 (1.062) 63 936651 28.6115 28.611 80.00- 120.00 100.00 8528

17.949 17.947 (0.000) 62 147904 23.26- 123.26 15.79

17.949 17.947 (0.000) 41 133430 19.26- 119.26 14.25

71 1.4-Dioxahe CAS I: 123-91-1

18.060 18.038 (1,069) 88 46419924.4358 24.436 80.00- 120.00 100.00 2761

11.060 18.058 (0.000) 58 80032 28.£5-128.65 17.34

18.060 18.058 (0.049) S7 29272 0.00- 76.92 6.31••

?« BrowbdichlorOaethadB CA3 I: 75-27-4

18.391 18.417 (1.018) S3 1464484 24.3343 24.334 80.00- 120.00 100.00 9313

18.391 18.417 (0.000) 85 217464 13.64- 113.64 14.86

$

8528

'j''..;'' Siv;.•S'.'V •-

19.412 19.410 (0.000)

19.412 19,410 (0.000)

78 Toluene

19.826 19.852 (1.173) 91

19.826 19.852 ( O . O O C ) 92

2294754 27.5727

303808

CAS »: 108-88-3

27.573 80.00- 120.00 100.00

11.05- 111.05 13.24

8877

79 trans-l,3-Dichloropropene

20.295 20.293 (0.902) 75 1192253 22.5485

20.295 20 .293 (0 .000 ) 77 103219

20.295 20 .293 (0 .000) 39 1990BO

CAS K: 10061-02-6

2 2 . 5 4 8 80.00- 120.00 100.00

0.00- 81.30 8.66

13.85- 110.85 16.70

9033

Data File: /chem/tnsdg. i/g-04nov.b/gll0405 .dReport Date: 05-Nov-2001 05:45

i

RT EXP RT (REL RT)

CONCENTRATIONS

ON-COL FINAL

MASS RESPONSE { PPBV) ( PPBV! TARGET RANGE RATIO

..J

86 1.

21.730 31.75« (0.966) 107 124863230.5015

21.730 21.756 ro.000) 109 316736

CAS I: 106-93-4

30.502 80.00- 120.06 100.00

44.84- 144.84 25.37

90 Xthyl B*n»ane

22.641 22.«39 (1.006) 106

CAS »: 100-41-4

741966 25.9634 25.963 80.00-120.00 100.00

<>1 22-;fc34''^fliiiV^tl'Vis} ' • ' ' ToT ' isStm'ii.iaBt'"' S2.4"i6"'*WFi*»V 120.00 " lOO.'OO •

Page 60 1 3 8

SIMILARITY

80 1. 1,2-Trichloroethane

20.682 20.680 (0.919)

20.682 20.680 (0.000)

20.682 20.680 (0.000)

82 Tecrachloroethene

20.847 20.845 (0.926)

20.847 20.845 (0.000)

20.847 20. 8«S (0.000)

83 2-H«ianone

20.985 20.983 (0.933)

20.985 20.983 (0.000)

20.98S 20.983 (0.000)

85 Dibromochloromethane

21.427 21.453 (0.952)

21.427 21.152 (0.000)

97

99

83

1*6

129

131

43

58

100

129

208

959996 24.5986

154432

215296

980834 26.0095

187392

183208

1512813 23.3307

213360

33768

1148349 24.1109

11236

CAS »: 79-00-5

24.599 80.00- 120.00

11.62- 111.62

37.94- 137.94

CAS 1: 127-18-4

26.010 80.00- 120.00

27.53- 127.53

23,00- 133.00

CAS 1: 591-78-6

23.331 80.00- 120.00

0.65- 100.65

0.00- S7.46

CAS 8: 124-48-1

24.111 80.00- 120.00

0.00- 54.75

100.00

16.09

22 .43

100.00

19. 11

18.38

100.00

14.24

2.23

100.00

0.98

8920

9220

8429

8215

5531

88 Chloroben»cne

22.SSB

22.558

22.558

22.556

22.536

22.556

(1

(0

(0

.002)

.008)

.000)

112

114

77

1559138 24.6161

145984

311065

CAS 81 108-90-7

24.816 80.

0.

21.

00-

op-88-

120.00

81.49

121.88

100.

9.

19.

00

36

95

9177

22.834 22.832 (1.015)

i'd< ; 1534m "si.91 3300365

52.436" 81J..OO- 126.00 " 100.00

166.S3- 286.53 215.01

94 o-Xylene

23.607 23.605 (1.049) 106

23.607 23.605 (0.000) 91

CAS »: 95-47-6

720766 28.9816 28.982 80.00- 120.00 100.00

459373 175.37- 275.37 63.73

8867

95 Styrene

23.635 23.633 (1.050) 104

23.635 23.633 (O.OQC) 78

1050490 24.4504

166124

CAS *: 100-42-5

24.450 80.00- 120.00 100.00

5.06- 105.06 15.81

9137

96 Bromotorm

24.104 24.102 (1.071) 173 999656 24.9025

CAS ft: 75-25-2

24.902 80.00- 120.00 100.00 9186


Page 70139

RT

CONCENTRATIONS

ON-COL FINAL

EXP RT (REL RT) MASS RESPONSE ( PPBV) ( PPBV! TARGET RANGE RATIO SIMILARITY


24.104 24.102 (0.000) 171 162112 1.52- 101.52 16.22

100 1.1,2,2-Tetrachloroethane CAS ft: 79-34-5

24.849 2 4 . 8 4 7 (1.104) 83 1868808 24.6258 24 .626 80.00- 120.03 100.00 9185

24.849 2 4 . 8 4 7 (0.000) 85 365696 12.83- 112.83 19.57

102 4.Ethyl toluene • CAS It 622-96-8

25.US 25.123 (1-1X7} 105 14V2849 21.953* 21.954 80.00- 120.00 100.00 9209

25,125- •'35.123 te;0«r)- • liO; . U6512 0.00- 76.13 8.25

103 1.3,5-trinaehylbeniene CAS «: 108-67-825.235 25.233 (1.121) 105 1375273 24.7176 24.728 80.00- 120.00 100.00

25.235 25.233 (1.121) 120 625125 0.00- 97.04 45.45

106 1,2.4-TriiMenylbeiuene CAS «-. 95-63-6IS.925 25.923 (1.152) 105 1023471 23.7796 23.780 80.00- 120.00 100.00 8810

25.925 25.923 (0.000) 120 136778 0.00- 90.91 13.36

110 l,)-Dlchlbrobensene CAS »: 541-73-126.388 26.586 (1.182) 146 1007804 21.3512 21.351 80.00- 120.00 100.00

36.58* 36.586 (1-182) 14* 637433 13.40- 113.40 63.25

26.588 26.586 (1.182) 111 460815 0.00- 95.92 45.72

111 1,4-DiclUorobenketM CAS »•. 106-46-7- 26.7S3 36.751 (1.18») 146 885323 30.7897 20.790 80.00- 130.00 100.00

26.753 36.751 (1.189) 148 557930 13.23- 113.22 63.02

26.753 26.751 (1.189) 111 390516 0.00- 92.92 44.11

11« Bezuyl Chloride CAS *: 100-44-7:.f£'aifcS7f .• 37.QOP .Ui'jJM...' ..91... 1«707M J2.17»7 J2.179 JIO,flCh WOf.OO 100.00 9111

ir. 471 37.496 (1.221) 1*6 91S544 20.S96* 20.596 80.00- 120.00 100.007

27.471 27.496 (0.000) 148 153728 14.29- 114.29 16.79

27.471 27.496 (0.000) 111 122656 0.00- 94.67 11.40

8536

123 i;2.4-Trictvlorobenxcne

30.810 30.808 (1.369) 180

30.810 30.808 (0.000) 182

293858 14.8329

69384

CAS «: 120-82-1

14.833 80.00- 120.00 100.00

45.31- 145.31 23.61

8963(R)


30.976 31.001 (1.377) 225

30.976 31.001 (0.000) 223

366496 17.1213

48439

CAS I: 87-68-3

17.121 80.00- 120.00 100.CO

12.69- 112.69 13.22

9 3 3 9 I R )


QC Flag Legend

R - Spike/Surrogate failed recovery limits.

Page <0 1 4 0

m

:. fii-aJ . 1

D«t» : OH-NOV-2001 14:02

CU»nt IDt LCSInfo; 23nl t888-78

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Data File: /chem/msdg. i/g-29nov.b/g!12902 .d Page 1 * **Report Date: 29-Nov-2001 08:07

"-"' i-;J Air Toxics Ltd.

• CONTINUING CALIBRATION COMPOUNDS'£

Instrument ID: msdg.i Injection Date: 29-NOV-2001 06:35— Lab File ID: gl!2902.d Init. Cal. Date(s): 02-NOV-2001 23-NOV-2001

Analysis Type: AIR Init. Cal. Times: 09:19 14:27^ Lab Sample ID: Method Spike Quant Type: ISTD

Method: /chem/msdg.i/g-28novb.b/to!41102.m

1 1 1| COMPOUND • IRRF / AMOUNT)

• 63

r» 791* 101

2

3

6

7

9

11

13

15

17

21

24

25

28

33

_- 3°35

36

37

43

• .-,47

' . «*•

Si

SO

52

54

58

57

61

64

66

67

70

1 , 2 - Dichioroethane - d4Toluene-dg

Bronofluorobenzene

PropyleneDichlorodlfluoronethane/Frl

Freon 114Chi orone thane

Vinyl Chloride1,3 -Butadiene

BroooBe thaneChi oroe thaneTrichloroCluorooethane/Frll

Ethanol

Freon 1131, 1-Dichloroethene

AcetoneCarbon Diaulfide2-PropanolMetnylene ChlorideMTBB

tran»-l,2-Dichloroethene

HexaiMiIjX-DlChlorbe thaneViiiyl Acatat* . .oJVrl,?-Dichloroe'tBene2-ButanoneTetrahydrofuranChloroform

Cyclohexane1,1,1- TrichloroethaneCarbon Tetrachlorlde

Bensene1, 2-Dichloroethane

HeptaneTrichloroethene

'.

2

0

0

1

S

3

2

2

1

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4

3

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.82708)

.68719)

.72339)

.71867)

.07665)

.93458)

.64677)

.53311)

.31993)

.12006)

.33977)

.80404)

.97463)

.30404)

.72597)

.35397)

.83201)

.11221)

.92549)

.88150)

.10093)

.15004)

.12646)

.71054)

.43591)

.42144)

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.44182)0

.27670)0

.13261)0

.00709)0

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.82061)0

.07802)0

.63997)0

.26812)0

.78114)0

.94666)0

.75325)0

.86322)0

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.30813)

.60351)

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.31928)

.90676)

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.33309)

.16643)

.98234)

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1

Data File: /chem/msdg.i/g-29nov.b/gl!2902.d Page 2Report Date: 29-Nov-2001 08:07

Air Toxics Ltd.

CONTINUING CALIBRATION COMPOUNDS

Instrument ID: msdg.i Injection Date: 29-NOV-2001 06:35Lab File ID: gl!2902.d Init. Cal. Date(s): 02-NOV-2001 23-NOV-2001Analysis Type: AIR Init. Cal. Times: 09:19 14:27Lab Sample ID: Method Spike Quant Type: ISTDMethod: /chem/msdg.i/g-28novb.b/to!41102.m

0143r

COMPOUND . IRRP / AMOUNT)

72

73

75

77

78

80

82

84

85

86

87

88

91

93

95

96

97

98

102

104

107

111

114

.115:J-17

iis126

127

1,3-Dichloropropane •

1,4-DIoxaneBromodichloroaethane

ci»- 1 . 3 -Dichloropropene

4 -Methyl - 2 - pentanone

Toluenetrans- 1 , 3 -Dichloropropene1,1,2- Trlchloroethane

Tetrachloroethene

2-HexanoneDibroBochloromethane1 , 2 -Dibroooe thaneChlorobenzene

Ethyl BenzeneB.p-Xylene

o-XyleneStyren*Bronoforv1.1,2, 2 -Tctrachloroetnane4 -Ethyl toluene

1 , 3 . s-TriMtnylbensen*1,2, 4-TrlBetaylbeniene

1,3-DlchlotobenjenattVBl.chlOrob*n««n« .

Beniyl csiiojrid*;1 , 3 -Dichloxobenxen*1,2,4- Tr ichlorobenieneHexachlorobutadiene

0.

0.

0.

0.

1.1.1.0.

0.

1.1.0.

1.0.

0.

0.

0.

0.

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22695)

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94991)

46992)

66313)

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57709)

99697)

93150)

76096)

49333)

29057)

99872 |

09929)

988161

74805)

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45971)

49673)

1

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0

0

0

0

1

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.88128)0.

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.00000)

.00000)

.00000)

.00000)

.00000)

. 31830J 30.00000)

.195821

.58271)

.39867)

.16887)

.70198)

1

30

30

30

30

30

.00000)

.00000)

.00000)

. 00000 |

.00000)

1

Averaged)

Averaged)Averaged)

Averaged)

Averaged)

Averaged)Averaged)

Averaged |Averaged)Averaged)

Averaged)Averaged)Averaged)Averaged)Averaged )Averaged)Averaged)Averaged |Averaged)Averaged)

Averaged)Averaged)

Averaged)

Averaged)

Averaged)Averaged)Averaged) <- £3Averaged)

1


Page 1(| 1 4 4

Air Toxics Ltd.

RECOVERY REPORT

Client Name:Sample Matrix: GASLab Smp Id: Method SpikeLevel: LOWData Type: MS DATASpikeList File:Sublist File: AT.subMethod File: /chem/msdg.i/g-29nov.b/to!41102.mMi sc Info: 20 Oml- 5 Oppbv

Client SDG: g-29novFraction: VOAClient Smp ID: Method SpikeOperator: kbSampleType: SAMPLEQuant Type: ISTD

SURROGATE COMPOUND


GONGADDEDPPBV

25.00025.00025.000

CONCRECOVEREDPPBV

24.14126.54625.221

%RECOVERED

\ 96.56^X106.18\100.88

LIMITS

70-13070-13070-130


Page 1 0145I"

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth DateCal DateAls bottleDil FactorIntegrator

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-29nov.b/gl!2902.dMethod Spike Client Smp ID: Method Spike29-NOV-2001 06:35kb Inst ID: msdg.i#855-134 SOppbv200ml SOppbv

/chem/msdg.i/g-28novb.b/to!41102.m29-Npv-2001 07:06 kbadal Quant Type: ISTD

14:27 Cal File: gl!2308.dContinuing Calibration Sample

23-NOV-200111.00000ii? RTE

rt


Compound Sublist: AT.subSample Matrix: AIR



RT BXP RT (RBL RT)

AMOUNTS

CAL-AMT ON-COL


• 53 Brodochloronethane

15.034

15.034

15.034

• 89 1,

16.883

16.883

15.034

15.034

15.034

t-DltluO

16.883

16.883

(1.

(0.

(6.

rot

(l.(0.

000)

000)

000)

ienxeni

000)

000)

130

128

...-«r

*•• .•" •.'114

88

343862 25.0000

58600

1816W . . : •; ;

1518725 25.0000

46424

* 90 Chlorobenxene-d5

22.513

22.513

S 63 1.

16.193

16.193

22.513

22.513

(1.

(1.

000)

000)

117

82

966768 25.0000

643310

2 -Dichloroetbane-d4

16.193

16.193

$ 79 Toluene-d8

19.698

19.698

19.698

19.698

(1.(0.

'

(1.(0.

077)

000)

65

67

727068 25.0000

71104

CAS I: 74-97-5

80.00-

29.56-

196.68-

• CAS I: 540-36-

80.00-

0.00-

120.

129.

296.

3

120.

67.

00

56

68

00

48

100

17

52

100

3

.00

.04

.84-r

.00

.06

8003

9226

CAS 1: 3114-55-4

80.00-

17.72-

120.

117.

00

72

100

66

.00

.54

CAS '»: 17060-07-0

24.141 80.00-

0.00-

120.

99.

00

91

100

9

.00

.78

10000

CAS 1: 2037-26-5

167)

000)

98

70

1333795 25.0000

37416

26.546 80.00-

0.00-

120.

62.

00

12

100

2

.00

.81

10000


Page 2 0 1 4 6

AMOUNTS

CAL-AMT ON-COL


|jj $ 79 Toluene -d8 (continued)

19.698_ 19.698 (0.000) 100 198304

5S $ 101 Bromofluorobenxene

24.611

24.611

i3 24.611

24.611

24.611

24.611

(1.093)

(0.000)

(0.000)

95

174

176

670218 25.0000

94784

91015

2 Propylene *

vg '' 6.009

^ 6.009

6.009

6 . 0,09

6.009

6.009

(0.400)

(0.000)

(0.000)

41

42

39

1232139 50.0000

103312

124573

I 3 Dlchlorodifluoronethane/Frl2

* 6.175

6.175

m6.175

6.175

(0.411)

(0.000)

85

87

3715780 50.0000

133568

paE3 6 Freon 114

6.672

ip 6.672

6.672

6.672

(0.444)

(0.000)

135

137

2012449 50.0000

89288

7 Chloroaethane

~a 6.975

ll 6'97S

6.975

6.975

(0.464)

(0.464)

50

52

1661462 50.0000

548982

N_- 9 Vinyl Chloride

§ 7.417

7.417

11 1,

^ 7.527

". • TV**

7.417

7.417

(0.493)

(0.000)

62

64

1632731 50.0000

54963

3 -Butadiene

7:52?

7.&

(D.501)

(0.000)

54

39

9*1574 50.0000

152091

§ 13 Brodome thane

8.659

8.659•-"*)

8.659

8.659

(0.576)

(0.000)

94

96

878019 50.0000

100722

§j 15 Chi oroe thane

8.990

— 8.990

8.990

8.990

(0.598)

(0.000)

64

66

778921 50.0000

27936

17 Trichlorofluoromethane/Frll

9.625

.'.') 9.625

9.625

9.625

(0.640)

(O'.OOO)

101

103

3443496 50.0000

299656

CAS «:

25.221

CAS ft:

51.979

CAS ft:

47.240

CAS ft:

47.556

CAS ft:

41.162

CAS ft:

44.849

CAS ft:

47.023

CAS ft:

48.362

CAS «t

50.560

CAS ft:

46.885

20.05- 120.05 14.87

460-00-4

80.00-

0.30-

0.00-

120.

100.

98.

00

30

30

100.

14.

13.

00

14

58

7678

115-07-1

80.00-

15.40-

30.90-

120.

115.

130.

00

40

90

100.

8.

10.

00

38

11

7686

75-71-8

80.00-

0.00-

76-14-2

80.00-

0.00-

74-87-3

80.00-

0.00-

75-01-4

80.00-

0.00-

120.

82.

120.

81.

120.

79.

120.

81.

00

32

00

96

00

72

00

15

100.

3.

100.

4.

100.

33.

100.

3.

00

59

00

44

00

04

00

37

9032

9101

4507

106-99-0

IO-.00-

56.90-

74-83-9

80.00-

44.79-

75-00-J

80.00-

0.00-

75-69-4

80.00-

13.16-

120.

156.

120.

144.

120.

81.

120.

113.

00

90

00

79

00

47

00

16

100.

IS.

100.

11.

100.

3.

100.

B.

00

J4

00

47

00

59

00

70

6554

6628

4019

9459

21 Bthanol

10.066 10.066 (0.670) 45 542129 50.0000

CAS I: 64-17-5

49.021 80.00- 120.00 100.00 3570


Page 3 0 1 4 7

RT

AMOUNTS

CAL-AMT OK-COL



10.066

10.066

10.066

10.066

(0.000)

(0.000)

43

46

17736

29240

24 Freon 113

10.811

10.811

10.811

25 1.

10.922

10.922

10.922

10.811

10.811

10.811

(0.719)

(0.000)

(0.000)

151

1S3

101

1939799 50.0000

132352

308928* __

1 -Diehloroethene

10.922

10.922

10.922

(0.726)

(0.000)

(0.000)

61

96

98

2804555 50.0000

222136

143168

28 Acetone

11.087

11.087

11.087

11.087

(0.737)

(0.000)

43

58

2503296 50.0000

128208

33 Carbon Dlsulfide

11.501 11.501 (0.765) 76 3623014 50.0000

30 2-Propanol

11.225

11.225

11.225

11.225

11.225

11.225

35 Metbylene

12.053

12.053

12.053

36 HT.

12.38,5 '•'.'

12.385

12.385

12.053

13 . OS3

12.053

i».'.;....' '••iliiis".12.385

12.385

(0.747)

(0.000)

(0.000)

Chloride

(0.802)

(0.000)

(0.000)

(0.824)

(0.000)

(0.000)

45

43

59

49

84

51

73

57

41

2600379 50.0000

0

12035

2026492 50.0000

246400

116341

395(648 SO. 0000

117504

124747

37 tran»-l,2-Dichloroathene

12.523

12.523

12.523

12.523

12.523

12.523

(0.833)

(0.000)

(0.000)

96

61

98

1281381 50.0000

383014

144960

43 Hexane

12.854

12.854

12.854

12.854

12.854

12.854

(0.855)

(OtOOO)

(0.000)

57

43

86

2140060 50.0000

147684

30464

CAS I:

47.411

CAS 1:

47.374

CAS *:

48.846

CAS *:

49.198

CAS I:

49.336

CAS »:

47.340

CAS 1.

48.547

CAS »:

49.514

CAS t:

50.175

0.00-

0.00-

76-13-1

80.00-

11.86-

94.39-

75-35-4

80.00-

0.00-

0.00-

67-64-1

80.00-

0.00-

75-15-0

80.00-

67-63-0

80.00-

0.00-

0.00-

75-09-2

80.00-

12.63-

0.00-

73

87

120

111

194

120

98

81

120

74

120

120

50

52

120

112

79

.56

.72

.00

.86

.39

.00

.82

.46

.00

.97

.00

.00

.00

.94

.00

.63

.01

3.

5.

100.

6.

15.

100.

7.

5.

100.

5.

100.

100.

0.

0.

100.

12.

5.

27

39

00

82

93

00

92

10

00

12

00

00

00

46

00

16

74

8611

8709

6493

8048

6158

9283

1634-04-4

80.00-

0.00-

0.00-

120.00

74

75

.28

.37

100.

2.

3.

00

97

15

6408

156-60-5

80.00-

117.92-

13.07-

110-54-

80.00-

17.69-

0.00-

120

217

113

3

120

117

63

.00

.92

.07

.00

.69

.99

100.

29.

11.

100.

6.

1.

00

89

31

00

90

42

8246

7287

BH

Data File: /chem/msdg.i/g-29nov.b/gl!2902.d-3 Report Date: 29-Nov-2001 08:07

Page 4 Q 1 4 8

RT

AMOUNTS

CAL-AMT ON-COL


£i

n*'i

ÎPd

47 l. l-Dichloroethane

13.406 13.406 (0.892)

13.406 13.406 (0.000)

46 Vinyl Acetate

13.323 13.323 (0.886)

13.323 13.323 (0.000)

13.323 13.323 (0.000)

63

65

43

42

86

2762300 50.0000

152704

3811474 50.0000

54336

41208

^? " 51 ci»-l,2rDichloroethene

V;

ii

1|fjj

J3

^

11

1

.--,

^ '

14.537 14.537 (0.967)

14.537 14.537 (0.000)

14.537 14.537 (0.000)

50 2-Butanone14.482 14.482 (0.963)

14.482 14.482 (0.000)

14.482 14.482 (0.000)

52 Tetrahydrofuran

15.006 15.006 (0.998)

15.006 15.006 (0.000)

15.006 15.006 (0.000)

•54 Chloroform

•x_,.089 15.089 (1.004)

15.089 15.089 (0.000)

58 CycloheicaiM

15.503 15.503 (1.031)

15.503 15.503 (O.6bpi

.is . so* is ; 503V v.(»» So*) ; >

61

96

98

43

72

57

42

71

72

83

85

84

:.s<-$•

2348669 50.0000

296782

188992

3060840 50.0000

116024

41304

1645857 50.0000

108496

111312

2879772 50.0000

355776

1664392 50.0000

329536

195176

;.;} 57 1,1,1-Trichloroethane£i

,e

M

•-.

fti

15.476 15.476 (1.029)

15.476 15.476 (0.000)

61 Carbon Tatrachlorlde

15.779 15.779 (1.050)

15.779 15.779 (0.000)

64 Benzene

16.221 16.221 (0.961)

16.221 16.221 (0?000)

97

99

119

117

78

77

2591230 50.0000

245760

2376256 50.0000

366838

4557719 50.0000

164383

CAS ft: 75-34-3

48.392 80.00- 120.00

0.00- 81.47

CAS ft: 108-05-4

54.054 80.00- 120.00

0.00- 58.86

0.00- 56.52

CAS »: 156-S9-2

46.019 80.00- 120.00

13.92- 113.92

0.00- 90.70

CAS ft: 78-93-3

50.166 80.00- 120.00

0.00- 69.99

0.00- 57.28

CAS ft: 109-99-9

49.417 80.00- 120.00

0.00- 85.42

0.00- 86.91

CAS ft: 67-66-3

47.009 80.00- 120.00

14.44- 114.44

CAS ft: 110-82-7

48.677 80.00- 120.00

18 .73- 18».7S

. v-. 32.18- 13 J. 18

CAS ft: 71-55-6

46.479 80.00- 120.00

13.73- 113.72

CAS ft: 56-23-5

46.384 80.00- 120.00

52.55- 152.55

CAS ft: 71-43-2

48.351 80.00- 120.00

0.00- 72.61

100.00

5.53

100.00

1.43

1.08

100.00

12.64

8.05

100.00

3.79

1.35

100.00

6.59

6.76

100.00

12.35

100.00

15.80

11,73

100.00

9.48

100.00

15.44

100.00

3.61

6614

5937

8238

7906

7503

9182

8297

- . -

.' .: ' . '

7464

8584

9141


16.359 16.359 (0.969) 62 2209688 50.0000

CAS I: 107-06-2

46.292 80.00- 120.00 100.00 5880


Page 5 Q 1 4 g

RT EXP RT (REL RT)

AMOUNTS

CAL-AMT ON-COL


66 1.2-Dichloroethane (continued)

16.359 16.359 (0.000) 64 143296 0.00- 81.40 6.46

67 Heptane CAS ft: 142-82-5

16.359 16.359 (0.969) 43 1984751 50.0000 50.817 80.00- 120.00 100.00 7191

16.359 16.359 (0.000) 57 131392 0.00- 99.60 6.62

16.359 16.359 (0.000) Tl 129528 0.00- 97.14 6.53

70 Trichloroethene ' CAS I: 79-01-6

17.407 17.4,07 (1.031) 95 1769788 50.0000 46.808 80.00- 120.00 100.00 8858

17.407 17.407 (0.000) 130 305344 32.86- 132.86 17.25

17.407 17.407 (0.000) 97 233408 13.34- 113.34 13.19

72 1.2-Dichloropropane CAS ft: 78-87-5

17.959 17.959 (1.064) 63 1447002 50.0000 48.40S 80.00- 120.00 100.00 8572

17.959 17.959 (0.000) 62 211520 23.30- 123.30 14.62

17.959 17.959 (0.000) 41 191112 16.23- 116.23 13.21

73 1,4-Dioxane CAS ft: 123-91-1

18.070 18.070 (1.070) 88 848488 50.0000 48.913 80.00- 120.00 100.00 2761

18.070 18.070 (0.000) 58 ' 143424 25.30- 125.30 16.90

18.070 18.070 (0.000) 57 50604 0.00- 76.92 5.96

75 Brooiodlchlofoaethaiie CAS ft: 75-27-4

18.401 18.401 (1.090) 83 2676849 50.0000 48.710 80.00- 120.00 100.00 9155

18.401 18.401 (0.000) 85 394112 12.31- 112.31 14.72

77 ci»-l,3-Dicbloropropene CAS ft: 10061-01-5

19.229 19.229 (1.139) 75 2286761 50.0000 48.050 80.00- 130.00 100.00 8231

19.229 19.229 (0.000) 77 171303 0.00- 81.40 7.49

19.219 19.229 (0.000) 39 373322 18.41-118 41 16.32

78 4-Methyi-2-pent»none CAS fi 108,-10-1

19.422 19.422 (1.150) 43 312729$ 50.0000 49.538 80.00- 120.00 100.00 7040

19.422 19.422 (0.000) 58 363873 0.00- 86.51 8.44

19.422 19.422 (0.000) 85 96989 0.00- 63.26 3.10

80 Toluene CAS ft: 10B-8B-3

19.836 19.836 (1.175) 91 3714386 50.0000 48.875 80.00- 120.00 100.00 8980

19.836 19.836 (0.000) 92 517920 11.65- 111.65 13.94

f-

fc.-

t

82 tran«-l,3-Dlchloropropene

20.305 20.305 (0.902) 75 2135216 50.0000

20.305 20.305 <0?000) 77 166417

20.305 20.305 (0.000) 39 305300

CAS ft: 10061-02-6

45.002 80.00- 120.00 100.00

0.00- 81.09 7.79

7.04- 107.04 14.30

9000

Data File: /chem/msdg.i/g-29nov.b/gl!2902.d-, Report Date: 29-NOV-2001 08:07

Page 6 0150

RT EXP RT (REL RT)

AMOUNTS

CAL-AMT ON-COL


98 Bromofom

24.114 24.114 (1.071) 173 1713663 50.0000

CAS t: 7S-25-2

47.573 80.00- 120.00

SIMILARITY

^ 84 1, 1, 2-Trichloroethane

_,

a'-1a

•

1

20.664 20.664 (0.918)

20.664 20.664 (0.000)

20.664 20.664 (0.000)


20.857 20.857 (0.926)

20.857 20.857 (0.000)

857 20.857 (0.000)

86 2-Hexanone

20.995 20.995 (0.933)

20.995 20.995 (0.000)

20.995 20.995 (0.000)

97

99

83

166

129

131

43

58

100

1530801 50.0000

222464

333056

1572049 50.0000

285440

278*32

2785781 50.0000

362880

59096

87 Dlbromocblorooethane

*!$

^' •"•'

^•1J

•"

^"3

-:

....

*

iij

21.437 21.437 (0.952)

21.437 21.437 (0.000)

88 1,2-Dibroooethane21.740 21.740 (0.966)

21.740 21.740 (0.000)

91 Cnlorobenzene

" 568 22.568 (1.002)

_56I 22.568 (0.000)

22.568 22.568 (0.000)

93 Kthyl Benzene

22.623 22.623 (1.005)

35.623 2*. 623 (1.005)

22.844 22.844 (1.015)

22.844 22.844 (1.015)

96 o-Zylene

23.589 23.589 (1.048)

23.589 23.589 (0.000)

97 Styrene

23.645 23.645 (1.050)

23.645 23.645 (0.000)

L

129

208

107

109

112

114

77

106

••»••

'". - -.:

106

91

106

91

104

78

2040052 50.0000

21786

1596865 50.0000

428932

2575722 50.0000

234304

484404

1164249 50.0000

4003836 .'.

2400418 100.000

5067494

•

995062 50.0000

578458

1804276 50.0000

260419

CAS *: 79-00-5

43.712 80.00- 120.00

12.05- 112.05

42.90- 142.90

CAS «: 127-18-4

46.456 80.00- 120.00

23.54- 123.54

21.63- 121.63

CAS *: 591-78-6

47.878 80.00- 130.00

2.57- 102.57

0.00- 57.46

CAS »: 124-48-1

47.734 80.00- 120.00

0.00- 53.87

CAS »: 106-93-4

43.471 80.00- 120.00

42.86- 142.86

CAS •: 108-90-7

45.313 80.00- 120.00

0.00- (2.13

16.43- 116.43

CAS t: 100-41-4

45.401 80.00- 120.00

291.37- 3»l'.a7

CAS f: io*>rt-a; •.'>•'•..'91.380 80.00- 120.00

166.53- 266.53

CAS t: 95-47-6

44.588 80.00- 120.00

181.28- 281.28

CAS f: 100-42-5

46.799 80.00- 120.00

0.00- 98.14

100.00

14.53

21.76

100.00

18.16

17.69

100.00

13.03

2.12

100.00

1.07

100.00

26.86

100.00

9.10

18.81

100.00

344.07 '

100.00

211.11

100.00

58.13

100.00

14.43

8908

9263

8438

8391

5523

9188

9276

9267

100.00 9342

Data File: /chem/msdg.i/g-29nov.b/gll2902 .dReport Date: 29-Nov-2001 08:07

Page 7 Q 1 5 1

RT EXP RT (REL RT)

AMOUNTS

CAL-AMT ON-COL


98 Brotnoforro (continued)

24.114 24.114 (0.000) 171 2S2544 0.88- 100.88 14.74

102 1,1,2.2-Tecrachloroethane CAS f: 79-34-5

24.8S9 24.859 (1.104) 83 2978017 50.0000 43.732 80.00- 120.00 100.00 9285

24.859 24.859 (0.000) 85 503438 13.20- 113.20 16.91

104 4-Ethyltoluene • CAS »: 622-96-8

25.135 25.135 (1.116) IDS 2666309 50.0000 46.171 80.00- 120.00 100.00 9336

25.135 25.135 (0.000) 120 219955 0.00- 77.73 8.25

107 1,3,5-Trimethylbenxene CAS I: 108-67-8

25.245 25.245 (1.121) 105 1967873 50.0000 39.430 80.00- 120.00 100.00

25.245 25.245 (1.121) 120 898122 0.00- 97.04 45.64

111 1,2,4-Triroethylbenrene CAS I: 95-63-6

25.935 25.935 (1.152) 105 1563856 50.0000 40.492 80.00- 120.00 100.00 8859

25.935 25.935 (0.000) 120 218258 0.00- 93.92 13.96

114 1,3-Dichlorobenzene CAS I: 541-73-126.570 26.570 (1.180) 146 1687485 50.0000 39.841 80.00- 120.00 100.00

26.570 26.570 (1.180) 148 1067614 13.40- 113.40 63.27

26.570 26.570 (1-180) 111 767491 0.00- 95.92 45.48

115 1,4-Dichlorobenxcne CAS I: 106-46-7

26.716 26.136 (1.188) 146 14865*2 50.0000 38.902 (0.00- 120.00 100.00

26.736 26.736 (1.188) 148 950061 13.22- 113.22 63.91

26.736 26.736 (1.188) 111 652800 0.00- 92.92 43.91

117 Beiwyl Chloride CAS »: 100-44-7

26.9»4 2«.9M (1-199) 1, '285323$ 50.OQQO 42.30> »0.00- 120.00 100.00 . 932$

26.984 2S.984 (O.BOa) 12« 152.nl>' . . , 0.00- 68.30 5.36

lit l,2-DiChlorobenien« CAS t: 95-50-1

27.481 27.481 (1.221) 146 1547687 50.0000 38.801 80.00- 120.00 100.00 8791

27.481 27.481 (0.000) 148 293157 13.15- 113.15 18.94

27.481 27.481 (0.000) 111 223985 0.00- 98.25 14.47

126 1.2,4-Trichlorobeniene CAS I: 120-82-1

30.793 30.793 (1.368) 180 558486 50.0000 31.416 80.00- 120.00 100.00 8524

30.793 30.793 (0.000) 182 123336 ^ 45.86- 145.86 22.08

P

I


30.986 30.986 (1.-376) 225

30.986 30.986 (0.000) 223

675154 50.0000

92975

CAS f: 87-68-3

35.149 80.00- 120.00 100.00

10.76- 110.76 13.77

9510


Air Toxics Ltd.


Page 1 0 1 5 2

Instrument ID: msdg.iLab File ID: gl!2902.dLab Smp Id: Method SpikeAnalysis Type: VOAQuant Type: ISTDOperator: kbMethod File: /chem/msdg.i/g-28novb.b/to!41102.mMisc Info: 200ml-BOppbv

Calibration Date: 28-NOV-2001Calibration Time: 15:59Client Smp ID: Method SpikeLevel: LOWSample Type: AIR

COMPOUND

53 Bromochloromethan69 1,4-Dif luorobenze90 Chlorobenzene-d5

STANDARD

3427211504762966752

AREALOWER

205633902857580051

LIMITUPPER

47980921066671353453

SAMPLE

3438621518725966768

%DIFF

0.330.930.00

COMPOUND

53 Bromochloromethan69 1,4-Dif luorobenze90 Chlorobenzene-d5

r-

STANDARD

15.0616.9122.51

RT ILOWER

14.5616.4122.01

jIMITUPPER

15.5617.4123.01

SAMPLE

15.0316.8822.51

%DIFF

-0.18-0.160.00

AREA UPPER LIMITAREA LOWER LIMITRT UPPER LIM T =»RT LOWER LIMiT -

+ 40% of internal standard area.- 40% of internal standard area.0.50 minutes of internal standard RT;.0.50 minutes of internal standard RT.

CO

Data Fil»: /Ch»n/'ii»sdt.i/'t-29nov.b/'jll2902.dD»t» : 29-NOV-2001 06:35Client ID; H»thod Si»ik*S»mpl« Info: #855-134

Column ph«»«: RTx-624

In»tru»«ntt

Of«r*tort kbColumn diwwtcrt 0.83

10 It 12 13 14 IS 16 17 18 19 20 21 22 23 24 2S 26 27 28 29 30 31 32

0 1 5 4



Compound

Freon 12Freon 1 1 4ChloromethaneVinyl ChlorideBromomethaneChloroethaneFreon 111,1-DichloroetheneFreon 113Methylene Chloride1,1-Dichloroethanecis-1 ,2-DichloroetheneChloroform1,1,1 -TrichloroethaneCarbon TetrachlorideBenzene1 ,2-DichloroethaneTrichloroethene1 ,2-Dichloropropanecis-1 ,3-DichloropropeneToluenetrans- 1 ,3-Dichloropropene1 , 1 ,2-Trichlor oethaneTetrachloroetheneEthylene DibromideChlorobenzeneEthyl Benzenem,p-Xyleneo-XyleneStyrene1 ,1 ,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-DichlorobenzeneChlorotoluene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobuladienePropylene1 ,3-ButadieneAcetone

Rpt. Limit(ppbv)

0.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.502.0

2.0

2.0

Rpt. Limit(uG/m3)

2.5

3.6

1.0

1.3

2.0

1.3

2.8

2.0

3.9

1.8

2.0

2.0

2.5

2.8

3.2

1.6

2.0

2.7

2.3

2.3

1.9

2.32.8

3.4

3.9

2.3

2.2

2.2

2.2

2.2

3.5

2.5

2.5

3.0

3.0

2.6

3.0

3.8

5.4

3.5

4.5

4.8

%Recovery

105

106

90

102

110

111

105

99

98

98

110

94

101

106

98

97

98

96

113

102

104

94

96

98

119

95

99

103

115

105

97

93

93

81

79

93

79

54Q

60 Q104

109107

Page 10 of 11

01


ID#: 0111476-04A


Compound

Carbon DisulfkJe2-Propandtrans- 1 ,2-DichloroetheneVinyl Acetate2-Butanone (Methyl Ethyl Ketone)HexaneTetrahydrofuranCyclohexane1 ,4-DioxaneBromodichloromethane4-Methyl-2-pentanone2-HexanoneDibromochloromethaneBromoform4-EthyltolueneEthanolMethyl tert-Butyl EtherHeptane

Q = Exceeds Quality Control limits.

TENTATIVELY

Compound

None Identified

Container Type: NA • Not Applicable

Surrogates

1 ,2-Dichloroethane-d4Toluene-dS4-Bromofluorobenzene

Rpt. Limit(ppbv)

2.02.02.02.02.0

2.0

2.0

2.0

2.02.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

2.0

Rpt. Limit(uG/m3)

6.3

5.0

8.0

7.2

6.0

7.2

6.0

7.0

7.314

8.3

8.3

17

21

10

3.8

7.3

8.3

%Recovery

105

116

106

115 ^107

107

108

103

107

100

105

106

99

102

98

103

102

105

-—

IDENTIFIED COMPOUNDS - Top 10 Reported

CAS Number Match Quality

%Recovery

97105102

Amount(ppbv)

MethodLimits

70-13070-13070-130

Page 11 of 11


Air Toxics Ltd.

RECOVERY REPORT

Page 1 0 1 5 6

Client Name:" Sample Matrix: GAS£j Lab Smp Id: LCS

Level: LOW^ Data Type: MS DATAm SpikeList File: AT.spk*" Sublist File: AT.sub

Method File: /chem/msdg.i/g-28novb.b/to!41102.m53 Misc Info: 100ml-SOppbv

Client SDG: g-29novFraction: VOAClient Smp ID: LCSOperator: kbSampleType: LCS""Quant Type: ISTD

SPIKE COMPOUND

2 Propylene3 Dichlorodifluorome6 Freon 1147 Chi orome thane9 Vinyl Chloride

11 1, 3-Butadiene13 Bromome thane15 Chloroethane17 Trichlorof luoromet21 Ethanol24 Freon 11325 1, 1-Dichloroethene

__. 28 Acetone33 Carbon Disulfide30 2-Propanol35 Methylene Chloride36 MTBE37 t rains r 1 / 2-;Diphlpro

: 43'- He>caifxe ;; Y.-V'-' •.••••- ;;47 l/i-bichibroefchaiie46 Vinyl Acetate51 cis-l,2-Dichloroet50 2-Butanone52 Tetrahydrofuran54 Chloroform58 Cyclohexane57 1,1,1-Trichloroeth61 Carbon Tetrachlori64 Benzene66 1, 2-Dichloroethane67 Heptane70 Trichloroethene72 1,2 -Dichloropropan

CONGADDEDPPBV

50.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050. POO50:00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.000

CONCRECOVEREDPPBV

51.95852.61353.11044.96451.10454.52155.14355.63852.49051.35548.81649.74353.38852.38158.15449.03951.03452.83053.30455.18957.36646.99453.51253.91250.51351.57153.22949.15748.66448.81852.64748.06256.699

RECOVERED

103.92105.23106.2289.93102.21109.04110.29111.28104.98102.7197.6399.49106.78104.76116.3198.08102.07105.66106.61110.38114.7393.99107.02107.82101.03103.14106.4698.3197.3397.64105.2996.12113.40

LIMITS

60-14070-13070-13070-13070-13060-14070-13070-13070-13060-14070-13070-13060-14060-14060-14070-13060-14060-14060-14070-13060-14070-13060-14060-14070-13060-14070-13070-13070-13070-13060-14070-13070-130


Page 2 0157

SPIKE COMPOUND

73 1,4-Dioxane75 Bromodichlorometha77 cis-1, 3-Dichloropr78 4 -Methyl -2 -pent ano80 Toluene82 trans- 1 , 3-Dichloro84 1,1,2-Trichloroeth85 Tetrachloroethene86 2-Hexanone87 Dibrpmochlorometha88 1, 2-Dibromoethane91 Chlorobenzene93 Ethyl Benzene95 m,p-Xylene96 o-Xylene97 Styrene98 Bromoform102 1,1,2,2-Tetrachlor104 4 -Ethyl toluene107 1,3,5-Trimethylben111 1,2,4-Trimethylben114 1,3-Dichlorbbenzen115 1,4-Dichlorobenzen117 Benzyl Chloride118 1,2-Dichlorobenzen126 1,2,4-Trichloroben127 Hexachlorobutadien

CONCADDEDPPBV

50.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.000100.0050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.00050.000

CONCRECOVEREDPPBV

53.30749.97051.06152.59251.93047.11948.06448.90852.79449.70459.62447.58249.414103.0957.41052.39051.16748.74248.96346.61146.46540.39239.70746.57439.39326.94630.157

%RECOVERED

106.6199.94102.12105.18103.8694.2496.1397.82105.5999.41119.2595.1798.83103.09114.82104.78102.3397.4897.9393.2292.9380.7879.4193.1578.7953.89*60.31*

LIMITS

60-14060-14070-13060-14070-13070-13070-13070-13060-14060-14070-13070-13070-13070-13070-13070-13060-14070-13060-14070-13070-13070-13070-13070-13070-13070-13070-130

SURROGATE COMPOUND


CONCADDEDPPBV

25.00025.00025.000

CONCRECOVEREDPPBV

24.32426.18525.498

%RECOVERED

97.30104.74101.99

LIMITS

70-13070-13070-130


Page 10158

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethodMeth Date1 Date

kis bott.leDil FactorIntegratorTarget Version: 3.50Processing Host: eeyore

Air Toxics Ltd.

AMBIENT AIR METHOD TO14/chem/msdg.i/g-29nov.b/gl!2903.dLCS Client Smp ID: LCS29-NOV-2001 07:22kb Inst ID: msdg.i#855-119 lOOppbv100ml SOppbv

/chem/msdg.i/g-28novb.b/to!41102.m29-Npv-2001 07:06 kbadal Quant Type: ISTD23-NOV-2001 14:27 Cal File: gl!2308.d1 QC Sample: LCS1.00000HP RTE Compound Sublist: AT.sub

Sample Matrix: AIR

Concentration Formula: Amt * DP * CpndVariable


CONCENTRATIONS

ON-COL FINAL

IT EZP RT (RKL KT) MASS RESPONSE ( PPBV) ( PPBV) TAROR RANGB RATIO SIMILARITY

23

-;•>:$•****

„:q

• 53 Bromochlorooe thane15

15

15

*

16

16

.033

.033

.033

69 1.

.882

.882

15.034

15.034

15.034

(1.000)

(0.000)

(a. ooo)

130

128

49

333625 25.0000

58592

179264

4-Dif loorobenxene '16.883

16.883

(1.000)

(0.000)

114

88

1512628 25.0000

46832


if

•--— ;

22

22

$

16

16

$

19

19

.512

.512

63 1.

.192

.192

22.513

22.513

(1.000)

(1.000)

117

82

964073 25.0000

644834

2-Dichloroethane-d416.193

16.193

(1.077)

(0.000)f

65

67

710782 24.3244

70880

79 Toluene -d8.697

.697

19.698

19.698

(1.167)

(0.000)

98

70

1310351 26.1847

34866

CAS •: 74-97-5

80.00- 120

29.56- 129

196. 61* 296/.•:?•:

CAS *: 540-36-3

80.00- 120

0.00- 67

CAS •: 3114-55-4

80.00- 120

17.72- 117

CAS I: 17060-07-0

24.324 80.00- 120

0.00- 99

CAS 1: 2037-26-5

26.185 80.00- 120

0.00- 62

.00

.56

.68

.00

.48

.00

.72

.00

.91

.00

.12

100

17,

53,

100,

3,

100.

66

100

9

100

2

.00

.56

.73•

.00

.10

.00

.89

.00

.97

.00

.66

7672

9223

10000

10000


Page 2 0150

RT

CONCENTRATIONS

ON-COL FINAL



19.697 19.698 (0.000) 100 195782 20.05- 120.05 14.94

$ 101 Bromofluorobenzene CAS «: 460-00-4

24.609 24.611 (1.093) 95 675705 25.4982 25.498 80.00- 120.00 100.00 7601

24.609 24.611 (0.000) 174 87704 0.30- 100.30 12.98

24.609 24.611 (0.000) 176 86912 0.00- 98.30 12.86

2 Propylene • CAS I: llS-07-i6.008' 6.009 (0.400) 41 1194955 51.9576 51.958 80.00- 120.00 100.00 7686

6.008 6.009 (0.000) 42 99064 15.40- 115.40 8.29

6.008 6.009 (0.000) 39 118583 30.90- 130.90 9.92

3 Dichlorodifluoronethane/Frl2 CAS I: 75-71-8

6.174 6.175 (0.411) 85 4015209 52.6132 52.613 80.00- 120.00 100.00 9036

6.174 6.175 (0.000) 87 136640 0.00- 82.32 3.40

6 Freon 114 CAS ». 76-14-2

6.670 6.672 (0.444) 135 2180568 53.1096 53.110 80.00- 120.00 100.00 9106

6.670 6.672 (0.000) 137 97712 0.00- 81.96 4.48

7 ChloroBethane CAS I: 74-87-36.946 6.975 (0.462) 50 1760892 44.9644 44.964 80.00- 120.00 100.00

6.946 6.975 (0.462) 52 584810 0.00- 79.72 33.21

9 Vinyl Chloride CAS I: 75-01-4

7.415 7.417 (0.493) 62 1805044 51.1037 51.104 80.00- 120.00 100.00 4791

7.415 7.417 (0.000) 64 60512 0.00- 81.15 3.35

11 1.3-Butadiene CAS I: 106-99-0

7.498 7.527 (0.49») 54 111546354.5209 54.521 80.00-120.00 . 100.00 6554

7V49S 7.527 (0.000) 39 170388 56.90- 156.9ft 15.33

- - - *» -'---I- -'•.-- ---*.•-----,. i. — -- _.-. -. . ..._.. --,---ta.i."--_ ._

13 Bronoaetbahe CAS »: 74-83-98.657 8.659 (0.576) 94 971323 55.1433 55.143 80.00- 120.00 100.00 6640

8.657 6.659 (0.000) 96 114171 44.79- 144.79 11.75

15 Chloroethane CAS I: 75-00-38.961 8.990 (0.596) 64 831643 55.6385 55.638 80.00- 120.00 100.00 4019

8.961 8.990 (0.000) 66 35760 0.00- 81.47 4.30

17 Trichlorofluoronethane/Frll CAS I: 75-69-49.596 9.625 (0.638) 101 3740438 52.4906 52.490 80.00- 120.00 100.00 9029

9.596 9.625 (O-OOO) 103 326221 13.16- 113.16 8.72

21 Ethanol

10.065 10.066 (0.670) 45 551034 51.3550

CAS I: 64-17-5

51.355 80.00- 120.00 100.00 3570


Page 3 0160

RT

CONCENTRATIONS

ON-COL FINAL


SJi 21 Ethanol (continued)

10.065 10.066 (0.000)

£3 10.065 10.066 (0.000)

24 Freon 113

10. BIO 10.811 (0.719)

•fd 10. BIO 10.811 (0.000)

"3 10.810 10.811 (0.000)

?5| ^ 25 1,1-DicWoroethene." ti£ 10.920 10.922 (0.726)

10.920 10.922 (0.000)

•H 10.920 10.922 (0.000)

28 Acetone11.086 11.087 (0.737)

3| 11.086 11.087 (0.000)

33 Carbon Disulfide§35 11.500 11.501 (0.765)

30 2-PropanoXX* 11.224 11.225 (0.747)

H 11.224 11.225 (0.000)

".224 11.225 (0.000)

jja " —5c{ 35 Methylene Chloride£« 12.024 12.053 (0.800)

12.024 12.053 (0.000)

"" 12.024 12.053 (0.000)

"^ V3*vife: -•••;•/;; ' :53J 12;J83;~12;3»S ibj824)

^J 12.383 12.385 (0.000)

™ 12.383 12.385 (0.000)

43

46

151

153

101

61

96

98

43

58

76

45

43

59

49

84

51

73

57

41

20256

33056

1937824 48.8161

138944

318080

2857116 49.7431

236062

153040

2654614 53.3879

138368

3742562 52.3810

2973882 58.1539

0

15732

2036725 49.0393

239168

119408

40355S1 51.0340

123872

129090

'.'/.' 37 tran»-l,2-Dichloroethene

?§ 12.521 12.523 (0.833)

12.521 12.523 (0.000)

'••• 12.521 12.523 (0.000)

43 Hexane_^, 12.825 12.854 (0.853)

.>"•; 12.825 12.854 (0:000)

-^ 12.825 12.854 (0.000)

96

61

98

57

43

86

1326501 52.8304

368832

138496

2205835 53.3044

151912

30544

0.00- 73.56

0.00- 87.72

CAS »: 76-13-1

48.816 80.00- 120.00

11.86- 111.86

94.39- 194.39

CAS t: 75-35-4

49.743 80.00- 120.00

0.00- 98.82

0.00- 81.46

CAS 1: 67-64-1

53.388 80.00- 120.00

0.00- 74.97

CAS 1: 75-15-0

52.381 80.00- 120.00

CAS 1: 67-63-0

58.154 80.00- 120.00

0.00- 50.00

0.00- 52.94

CAS 1: 75-09-2

49.039 80.00- 120.00

12.63- 112.63

0.00- 79.01

CAB •: 1614-04-*

51.034 80.00- 120.00

0.00- 74.28

0.00- 75.37

CAS t: 156-60-5

52.830 80.00- 120.00

117.92- 217.92

13.07- 113.07\

CAS 1: 110-54-3

53.304 80.00- 120.00

17.69- 117.69

0.00- 63.99

3.68

6.00

100.00

7.17

16.41

100.00

8.26

5.36

100.00

5.21

100.00

100.00

0.00

0.53

100.00

11.74

5.86

100.00

3.07

3.20

100.00

27.80

10.44

100.00

6.89

1.38

8604

8698

6493

8051

6193

9442

6406

8233

7287


Page 4 0161

RT

CONCENTRATIONS

ON-COL FINAL


47 1.

13.404

13.404

1 - Dichloroethane

13.406

13.406

(0.892)

(0.000)

63

65

3056481 5S.1888

172608

46 Vinyl Acetate

13.321

13.321

13.321

13.323

13.323

13.323

(0.886)

(0.000)

(0.000)

43

42

86

3924546 57.3658

60025

44000•

51 ci»-l,2rDichloroethene14.536

14.536

14.536

50 2-

14.491

14.481

14.481

14.537

14.537

14.537

(0.967)

(P nnO)

(0.000)

61

96

98

2326994 46.9937

284293

185728

Butanone

14.482

14.482

14.482

(0.963)

(0.000)

(0.000)

43

72

57

3167741 53.5117

123552

43368

52 Tetrahydrofuran

15.005

15.005

15.005

15.006

15.006

15.006

(0.998)

(0.000)

(0.000)

42

71

72

1742102 53.9115

117720

118952

54 Chloroform

15.088

15.088

15.089

15.089

(1.004)

(0.000)

83

85

3002319 50.5131

363136

58 Cyclohexane15.502

1S.502

15.502

57 1.

15.474

15.474

15.503

15.503

15.503

(1.031)

(0.000)

(0.000)

84

5<

41 .

1710873 51.5713

336640

203171

1. 1-Trichloroetbane

15.476

15.476

(1.029)

(0.000)

97

99

2879191 53.2290

275840

61 Carbon Tetracblorlde

15.750

15.750

15.779

15.779

(1.048)

(0.000)

119

117

2443342 49.1568

391629

64 Benzene

16.219

16.219

16.221

16.221

(0.961)

(O'.OOO)

78

77

4568890 48.6645

166784

CAS »:

55.189

CAS *:

57.366

CAS *:

46.994

CAS *:

53.512

CAS •:

53.912

CAS t.

50.513

CAS ti

51.571

CAS »:

53.229

CAS «:

49.157

\.

CAS 1:

48.664

75-34-3

80.00-

0.00-

120.

81.

00

47

100.

5.

00

65

£409

108-05-4

80.00-

0.00-

0.00-

120.

58.

56.

00

86

52

100.

1.

1.

00

S3

12

5945

156-59-2

80.00-

13.92-

0.00-

120.

113.

90.

00

92

70

100.

12.

7.

00

22

98

8550

78-93-3

80.00-

0.00-

0.00-

120.

69.

57.

00

99

28

100.

3.

1.

00

90

37

7910

109-99-9

80.00-

0.00-

0.00-

67-66-3

80.00-

14.44-

110-82-

80.00-

88.75-

32.18-

71-55-6

80.00-

13.72-

56-23-5

80.00-

52.55-

71-43-2

80.00-

0.00-

120.

85.

86.

120.

114.

7

120.

US.

132.

120.

113.

120.

152.

120.

00

42

91

00

44

00

75

18

00

72

00

55

00

72.61

100.

6.

6.

100.

12.

100.

19.

11.

100.

9.

100.

16.

100.

3.

00

76

83

00

10

00

68

88

00

SB

00

03

00

65

7SOO

9525

8294

7457

8667

9178


16.357 16.359 (0.969) 62 2320939 48.8180

CAS *: 107-06-2

48.818 80.00- 120.00 100.00 S839


Page 5 0 1 6 2

RT EXP RT (REL RT)

CONCENTRATIONS

ON-COL FINAL


66 1,2-Dichloroethane (continued)

16.357 16.359 (0.000)

67 Heptane

16.357 16.359 (0.969)

16.357 16.359 (0.000)

16.357 16.359 (0.000)

70 Trichloroethene

17.406 17.407 (1.031)

17.406 17.407 (0.000)

17.406 17.407 (0.000)

72 1,2-Dlchloropropuie

17.958 17.959 (1.064)

17.958 17.959 (0.000)

17.958 17.959 (0.000)

73 1,4-Dloxane

18.068 18.070 (1.070)

18.068 18.070 (0.000)

18.068 18.070 (0.000)

75 BroModlchloroBetbane

.400 18.401 (1.090)

_>.400 18.401 (0.000)

64

43

57

71

95

130

97

63

62

41

88

58

57

83

85

146112

2047963 52.6472

137344

134656

•

1809935 48.0623

318720

244224

1688149 56.6994

251328

224508

920991 53.3068

153664

56064

2735073 49.9699

404S44

77 ci»-l,3-Dichloropropene

19.227 19.229 (1.139)

19.227 19.229 (0.000)

19V32T 19.22$ (0.000)

7> 40tet*yi:.a-penta*>ne

19.421 19.422 (1.150)

19.421 19.422 (0.000)

19.421 19.422 (0.000)

80 Toluene

19.835 19.836 (1.175)

19.835 19.836 (0.000)

75

77

39

43

58

as

91

92

2420286 51.0607

181824

39352*

3306794 52.5921

279744

105238

3930736 51.9303

539904

82 tran«-l, 3-Dichloropropene

20.304 20.305 (0.902) 75 2229403 47.1186

0.00- 81.40

CAS 1: 142-82-5

52.647 80.00- 120.00

0.00- 99.60

0.00- 97.14

CAS |: 79-01-6

48.062 80.00- 120.00

32.86- 132.86

13.34- 113.34

CAS 1: 78-87-5

56.699 80.00- 120.00

23.30- 123.30

16.23- 116.23

CAS «: 123-91-1

53.307 80.00- 120.00

25.30- 125.30

0.00- 76.92

CAS It 75-27-4

49.970 80.00- 120.00

12.31- 112.31

CAS It 10061-01-5

51.061 80.00- 120.00

0.00- 81.40

18.41-118.41

CAS |: 108-10-1

52.592 80.00- 120.00

0.00- 86.51

0.00- 63.28

CAS I: 108-88-3

51.930 80.00- 120.00

11.65- 111.65

CAS I: 10061-02-6

47.119 80.00- 120.00

6.30

100.00

6.71

6.58

100.00

17.61

13.49

100.00

14.89

13.30

100.00

16.68

6.09

100.00

14.79

100.00

7.51

16.26

100.00

8.46

3.18

100.00

13.74

100.00

7173

8848

8592

2761

9056

8217

7047

8975

9105

20.304 20.305 (0'. 000) 77 178197

20.304 20.305 (0.000) 39 325756

0.00- 81.09 7.99

7.04- 107.04 14.61


0 1 6 3 1Page 6

I

RT EXP RT (RBL RT)

CONCENTRATIONS

ON-COL FINAL


98 Bromofom

24.112 24.114 (1.071) 173 1837994 51.1673

CAS I: 75-25-2

51.167 80.00- 120.00

SIMILARITY

84 1.1,2-Trichloroethane

20.690

20.690

20.690

20.664

20.664

20.664

(0.

(0.

(0.

919)

000)

000)

97

99

83

1678507 48.0641

242176

343616


20.856

20.856

20.856

20.857

20.857

20.857

(0.

(0.

(0.

926)

000)

000)

166

129

131

1650399 48.9082

300352

286\44

86 2-Hexanone

20.994

20.994

20.994

20.995

20.995

20.995

(0.

(0.

(0.

933)

000)

000)

43

58

100

3063300 52.7944

412992

65800

87 DibrooochloroBethane

21.435

21.435

88 1,

31.719

21.739

21.437

21.437

(0.

(0.

952)

000)

129

208

2118331 49.7037

23332

2 -DibroMoethane

21.740

21.740

(0.

(0.

966}

000)

107

109

2184128 59.6245

585792

91 Chloroben»ene22.567

22.567

22.567

22.568

22.568

22.568

(1.(0.

(0.

002)

000)

000)

112

114

77

2697197 47.5826

247168

512054

93 Ethyl Benzene

22.622

32.622

•95 m,

22.843

22.843

22.623

22.623

p-zyien*22.844

22.844

(1.u.

(1.(1.

005)

003)

015)

015)

106

91

ioe91

1263621 49.4141

4304923

2700584 103.094

5737144

96 o-Xylene

23.616

23.616

23.589

23.589

(1.(0.

049)

000)

106

91

1277627 57.4101

680420

97 Styrene

23.643

23.643

23.645

23.645

(1.(0.

'r

050)

000)

104

78

2014163 52.3895

297892

CAS It:

48.064

CAS II :

48.908

CAS «:

52.794

CAS »:

49.704

CAS •:

59.624

CAS *:

47.582

CAS •:

49.414

CAS *i

103.09

CAS •:

57.410

CAS *:

52.390

79-00-5

80.00- 120

12.05- 112

42.90- 142

127-18-4

80.00- 120

23.54- 123

21.63- 121

591-78-6

80.00- 120

2.57- 102

0.00- 57

124-48-1

80.00- 120

0.00- S3

106-93-4

80.00- 120

42.86- 142

108-90-7

80.00- 120

0.00- 82

16.43- 116

100-41-4

80.00- 120

291.37- 391

108-38-3

80.00- 120

166.53- 266

95-47-6

80.00- 120

181.28- 281

100-42-5

80.00- 120

0.00- 98

.00

.05

.90

.00

.54

.63

.00

.57

.46

.00

.87

.00

.86

.00

.13

.43

.00

• 3'

.00

.S3

.00

.28

.00

.14

100

14

20

100

18

17

100

13

2

100

1

100

26

100

9

18

100

340

100

212

100

53

100

14

.00

.43

.47

.00

.20

.34

.00

.48

.15

.00

.10

.00

.82

.00

.16

.98

.00

.68

.00

.44

.00

.26

.00

.79

8947

9273

8430

8367

5530

9215

8133

9282

£"i'T*!

fc

100.00 9309

Data File: /chem/msdg.i/g-29nov.b/g!12903.dReport Date: 29-Nov-2001 07:55

Page 7 0 1 6 4

RT

CONCENTRATIONS

ON-COL FINAL


*"• 98 Bromoform (continued)

24.112 24.114 (0.000) 171 278528 0.88- 100.88 15.15r-P

£3 102 1.1.2,2-Tetrachloroethane CAS I: 79-34-5

24.858 24.859 (1.104) 83 3309934 48.7417 48.742 80.00- 120.00 100.00 9279

r~H 24.858 24.859 (0.000) 85 579840 13.20- 113.20 17.52i -^04 4-Ethyltoluene CAS t-. 622-96-8

^ -133 25.135 (1.116) 105 2819*674 48.9634 48.9«3 80.00-120.00 100.00 9318

3} 25.133 25.1)5 (0.000) 120 240448 0.00- 77.73 8.53

.ij .. . : ^, __._.

107 1.3.5-Trinethylbenieii* CAS •: 108-67-1

8 25.344 25.245 (1.121) 105 2319724 46.6106 46.611 BO.00- 120.00 100.00

25.244 25.245 (1.121) 120 1074960 0.00- 97.04 46.34

jn 111 1.2,4-Trinethylbenzene CAS t: 95-63-6

«| 25.934 25.935 (1.152) 105 1789534 46.4649 46.465 80.00- 120.00 100.00 8852

25.934 25.935 (0.000) 130 253469 0.00- 93.92 14.16

;HS 114 1.3-Dlchloroben«ene CAS I: 541-73-1

—• 26.569 26.570 (1.180) 146 1706054 40.3919 40.392 80.00- 120.00 100.00

26.569 26.570 (1.180) 148 1089223 13.40- 113.40 £3.84

T 26.569 26.570 (1.180) 111 775925 0.00- 95.92 45.48

5 1.4-Dichlorobenxena CAS ft: 106-46-7

.-£ W.734 26.736 (1.188) 146 1513094 39.7071 39.707 80.00- 120.00 100.00

'--,' 26.734 26.736 (1.188) 148 973940 13.22- 113.22 64.37•2

26.734 26.736 (1.188) 111 667649 0.00- 92.92 44.12

^ 117 Bensyl Chloride CAS *: 100-44-7

!3 26..98J 2«.9»4 U-199) 91 313958046.574$ 45.574 80.00- 120,00 100.00 9317

2«.9«V 26.984 (S.OOOt ,i26 172841 «.00- 6t.20 5.51

~% .-..:lv:...- ,.:...i::,-...;..-..:.-.: .......'. ....." :kj 118 1.2-Dichlorobensene CAS *: 95-50-1

27.479 27.481 (1.221) 146 1566933 39.3930 39.393 80.00- 130.00 100.00 8745

,_, 27.479 27.481 (0.000) 148 291640 13.15- 113.15 18.61

' 27.479 27.481 (0.000) 111 321952 0.00- 98.25 14.16S3

126 1,2,4-Trichlorobenxene CAS »: 120-82-1

30.791 30.793 (1.368) 180 477690 26.9458 26.946 80.00- 130.00 100.00 8543(R)

^ 30.791 30.793 (0.000) 182 101456 v 45.16- 145.86 21.24


30.984 30.986 (1:376) 225

30.984 30.986 (0.000) 223

CAS «: 87-68-3

577644 30.1566 30.157 80.00- 120.00 100.00

80304 10.76- 110.76 13.90

9520(R)

Data File: /chem/msdg. i/g-29nov.b/gl!2903 .d Page 8 ft 1 ftReport Date: 29-Nov-2001 07:55 V-I U

QC Flag Legend

R - Spike/Surrogate failed recovery limits.


Page 10166

Air Toxics Ltd.


Instrument ID: msdg.iLab File ID: gl!2903.dLab Smp Id: LCSAnalysis Type: VOAQuant Type: ISTDOperator: kbMethod File: /chem/msdg.i/g-28novb.b/to!41102.mMisc Info: 100ml-BOppbv

Calibration Date: 29-NOV-2001Calibration Time: 06:35Client Smp ID: LCSLevel: LOWSample Type: AIR

COMPOUND


STANDARD

3438621518725966768

AREALOWER

206317911235580061

LIMITUPPER

48140721262151353475

SAMPLE

3336251512628964073

%DIFF

-2.98-0.40-0.28

COMPOUND


STANDARD

15.0316.8822.51

RT ILOWER

14.5316.3822.01

jIMITUPPER

15.5317.3823.01

SAMPLE

15.0316.8822.51

%DIFF

-0.01-0.01-0.01

AREA UPPER LIMIT = + 40% of internal standard area.AREA LOWER LIMIT - - 40% of internal standard area.RT tjPIjJJJi LIMIT =» + 0.50 minutes of internal standard RT.RT IiOWER LIMIT =» - 0.50 minutes of internal standard RT.

^ D«t«

^ D»t» : 29-NOV-2001 07:22

Client ID: LCS

Info: »885-119

RTx-624ColumnOperator: •*Column diaiwtert 0.63

30 31 32

oo

Instrument Run Log

COMl TMhf tmt Mmm fiMinllii ((TO)

Lot Book •:.

Instrument Run LogGC/MS Toalnj ind Man Cmlibratloo (BFB)

@Air Toxia Ltd. Log Book *__±L1

BFB File ID:.

BFB Injection Ditc ll

BFB Injectifln rime: '

95

96

173

174

175

176

177

30 - 60% of Itac b*ce pe«k

Bci peit, 100% relaive tbuadince

5.0-9.0% of oust 95

Lea* ftan 2% of mm 174

Gremr HIM 50% of HUM 95

5.0-9.0ft «(iMV 1?4

101% of mm 174

5.0- kl*

(OQ.OO

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2 •• vita ik ptrenthon k ft I

Vaa«m:

BO*i,4-DFB

Calculation Cbetfa File ID: G » Ot O H Compouad: (( PL

r Arei of Cooroounj |j $fflpte . Qiac InL Stindud fpybv^ x DUvtio* Ftdoc

AnaoflaLStaodvdiaStnpli ICALRRF

(a. Y.RCTCTttdttq.lt:

H.

| 278

MJL$

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Signed CMc Revi»ed:

Instrument Run LogGC/MS Toning and Mass Calibrate* (BFB)

@Air Toxics Ltd Log Book #:_

BFB File ID:

SO 15 - 40% of the base peak

75

95

96

173

174

30 - 60% of the base peak

Base peak, 100% relative abundance

5.0- 9.0% of mass 95

Less than 2% of man 174

Greater than 50% of man 95

175 5.0- 9.0% of mass 174

176 Greater than 95% but less than 101% of mass 174

177 5.0-9.0% of mass 176

6-1*

(7-U

BFB Injection Date:_

BFB Injection Time:_

Tekmar Purge Flow:

Vacuum:

1 - value in paitotbesU is % mas* 174 2 - value in pueathcsis is % mas* 176

THIS TUNE CHECK APPLIES TO THE FOLLOWING SAMPLES, BLANKS AND STANDARDS

*AT-ll"7 '-s- Area count*

BCM

1,4-CTO

10

11

12

13

14

13

•k»latk>n Check: FileTD: Compoon* initials:

Area of lot. SUodard m SanplcIxDihtkuFKMr

PI*rvtltu?k

ICALRRF

X ( )•Reported Rcnk:

Signed

In ""ITT EaC ito IrirJirfi

T—l

r»*-*

Innrament Run Log •AkTHIeiLid.

75».JOim*ita«.

175 5.0 • 9.0% •<•»• I7«

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ins.0

IOO.OO

(Cl.OO )1

^THB TONE aaac ATTUBS TO THE TOLLOWHO IAMTLB, KANU AMD ITAMMIID*

snôt-

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L f '."".'".'./^?F :ââssp^fSf••:'^?Ks0ferTm nb Dk' * rfc-A1"- '* V&f.

Data File: /chem/msdg.i/g-02nov.b/gbl!0201.d75 Report Date: 02-Nov-2001 05:53

Page #172

Air Toxics Ltd.

Data file /chem/msdg.i/g-02nov.b/gbl!0201.dLab Smp Id

02-NOV-2001 05:47kbBFB Tune Check50ng 2ul #843-017

Inj DateOperatorSmp InfoMisc InfoCommentMethod

ileOil FactorIntegrator

Client Smp ID: BFB

Inst ID: msdg.i

/cheTn/msdg. i/g- 02nov. b/bf b.m05:53

1.00000HP RtB


Quant Type: BSTDGaX'Fiier .QC Sample: BFB

Confound Sublist: a11.subSample Matrix: WATER

Concentration Formula: Amt * DP * Uf * Vf * Vi * CpndVariable

Name Value Description

DPUfVfVi

vtvooooo1 . 000001.06000i . 00600

Dilution Factorng unit correction factorVolumetric correction factorinjection Volutiie

"-Cpnd Variable—•» ' • •' Local Compound Variable

_ ^ , .,.

' ''' '

B

8

B

B

8

B

B

8

8

1 btb

276 1

276 1

276

276

276

276

276

276

276 <

1.247

1.247

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.247

.247

.247

.247

.247

1.247

0

0

0

0

0

0

0

0

0

029

029

029

029

029

029

029

029

029

95

50

75

96

173

174

175

176

177

B4391S

220144

4510B4

56357

1262

510848

38930

494461

32475

CAS I: 460-00-4

100.00- 100.00

15.00- 40.00

30.00- 60.00

S.OO- 9.00

0.00- 2.00

50.00- 100.00

5.00- 9.00

95.00- 101.00

5.00- 9.00

Data File; /ch««/m$dt.i/j-02nov.b/tbl!0201.d

Dat» : 02-NOV-2001 09:47

Client ID: STB

Sample Info: BFB Tune Check

Volume Injected CuL>: 1.0

Column phase;

Pace 2 0173Instrument: msdg.i

Operator: kb

Column diameter; 2.0O

/chem,

4.2

4.0

3.8

3.6

3.4

3.2

•3.0 ". • . . ' • . • •

t 2.4

32,22.0

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£

fi

Data File; /ch««/<»sdt.i/£-02nov.b/{bllC>201.d

Date : 02-NOV-2001 06:47

Client ID: BFB


Volume Injected <uL): 1.0

Column phase:

1 bfb

p'<-3 0 17 4Instrument: nsdg.i

Operator: kb

Column diameter: 2.0O

8.4

8.1

7.8

7.5

7.2

6.9

6.6

6.3

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,

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\ 79 30.00 - 60.00X Of mass 98 83.46

1 96 8.00 - 9.00X of MM 96 6.68

1 173 Less than 2.00X of mass 174 0.18 < 0.26)

1 174 60.00 - 100. OCX of mass 98 60.63

1 179 6.00 - 9.00X of MSS 174 4.61 C 7.62)

1 176 98.00 - 101. OCX of MSS 174 68.59 ( 96.79) 1

1 177 5.00 - 9.00X of MSS 176 3.88 < 6.87) 1

Data File: /chem/msdf.i/e-02nov.b/cbll0201.d

Date : 02-NOV-2001 05:47

Client ID: BFB


Volume Injected (uL>: 1.0

Column phase:

Instrument: msdg.i

Operator: kb


Data File: jb!10201.d

Spectrum: ftv(. Scans 165-167 < 8.28), Background Scan 152

Location of Maximum: 95.00

Number of points: 203

m/z

1 36.00*

1 37.001 38.00

1 39.00

1 40.00

1 43.00

1 44.00

1 49.001 46.00

1 47.00

1 48.00

1 49.001 50.00

1 91.40

1 52.00

1 89.001 86.00

1 87.00

1 88.00

> 89.00

1 W.OO

Y

10045

5277646992

18272

1049

420

6171

9612

386

12810

6887

4448622009*

647282848

2408

1408924792

819309

•774

m/z

1

1

iii

iiiii

iitii

ii

95.00

96.00

97,00104.00

105.00

106.

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112.

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118.

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1 163.001 164.00

1 168.00

1 169.00

1 170.00

1 171.00

1 172.00

1 173.001 174.00

1 178.00

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271.00

272.00273.00

274.00

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277.00

280.00

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Data File; /ch*n/nsd(.i/(-02nov.b/(bll0201.d

Date : 02-NOV-2001 OSM?Client ID; BFB


Voluwe Injected (uL>: 1.0

Column phase:

I nstrvwent: nsd(. i

Operator: kb

Column dianeter: 2.0O

0176

Data File: fbll02Ol.d

Spectru»: Avg. Scans 165-167 ( 8.28), Background Scan 152

Location of Haxinun: 95.00

Hunber of points: 2O3

£3

11111

11111

11111

1

II

76..

77.'"TtJ*».80.

81.

82.83.85.86.

87.88.91.92.93.

94.

i/i

«d00

00: '0000

0000

0000

00

0000000000

00

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379844473

•$fc?Jitesi'8079

151042820

96110607

35448318402471

22400

34320

931*8

ft

I 144,1 148,I :-fM'4

'»J'i4fe1 149.

1 180.1 152.1 153.1 154,1 165,

1 iB6.1 167,

I 181'.r t*o.riu.

I 162.

u"z

00

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0000

00

0000

00

00000000

00

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272 1

W '".•iji-.'f.1443 »

4oe i

1110 1511 16* 1

572 11404 i

387- 1*367 |

9359 122* f869 1

164 1— .— !i ,j.

H/Z

226.00227.00•J2t*00'isM.'-.oo234.00

238.00236.00240.00241.00245.00

248.00280.00

864***'iieioo283.60

254.00

Y

- 51 199 1** i

23^ {707 1

7 1122 1

8* 1111 1

50 1

222 1533 1450 t209 1

1871 1

(92 1+.

m/z

321.00

324tOOjtj^.^032 .00 '328.00

329.00332.00338.00337.00338.00

340.00343.00344;oo34 :00349.00

Y

1485

2170097

2891

HI7164

511093

4069467

1

1(

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1

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11

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Data File: /chem/msdg.i/g-04nov.b/gbll0401.dReport Date: 04-Nov-2001 09:55

Page fl j 7 7

«

Air Toxics Ltd.

Data file : /chem/msdg. i/g-04nov.b/gb!10401 .dLab Smp Id: Client Smp ID: BFBInj Date : 04-NOV-2001 09:49

kb Inst ID: msdg.iBFB Tune Check50ng 2ul #843-017

OperatorSmp InfoMisc InfoCommentMethod /che*ymsdg.i/g-04nov.b/bfb.m

** • -tr ;-'-"'•• •.•i -.VY*''-"--*-1**'' «• <• '•'•'ri^-^1.00000HP RTfi

ersion: 3.50Host: eeyore

Compound Sublist: all. subSample Matrix: WATER

Concentration Formula: Amt * DF * Uf * vf * Vi . * CpndVariable

Name Value

OfVfVi

Cpnd Variable

i . oooo1.00&OO

Description

ngt ujilt correct ion factorVolumetric correction factorinjection Volume

Local Compound Variable

i/i>. ; : :- *&iH+mm '••~:~r(v."'• -'-''j"v•'- '' T'32*iLMi*£iJ££

1 Bfb

8.261

8.261

8.261

8.261

B.261

8.261

8.261

8.261

8.261

.247

.247

.247

.247

.247

.247

.247

.247

.247

0

0

0

0

0

0

0

0

0

w*

014

014

014

014

014

014

014

014

014

''"'". '•

95

50

75

96

173

174

175

176

177

•"••*'•' .71*- '•'

960651

244745

513115

64960

0

590766

44369

561270

37124

CAS •: 460-00-4

100.00-.100.00 100.00

15.00- 40.00 25.48

30.00- 60.00 53.41

S.OO- 9.00 6.76

0.00- 2.00 0.00

50.00- 100.00 61.50

5.00- 9.00 7.51

95.00- 101.00 95.

5.00- 9.00 6.61

1

.4

Data File: /che«/«sdt.i/t-04nov.b/jbll0401.d Pate 2

Oat* : 04-NOV-2001 09:49 0178

Client ID: BFB Instrument: Mdt.i

Sa*f»le Info: BFB Tune Check

Volune Injected <uL>: 1.0 Operator; kb

Column phase: Colum dianetrr; 2.00

riI

4.4

4.,

II

3.8

^ 4 a

3 M2.0

4.8

1.6

1.4

1.2

1.0

0.8

r i

I

I ,, < .,.,,,L* T A t £ •» * • A A ft.9 ft i O.& ' ft^ft %1A *> Wl * at 0^* 4A. A 4A.». *JV.4

.- Hin

Data File: /che«/msdf.i/j-04nov.b/'tbll0401.d

Date : 04-NOV-2001 09:49

Client ID: BFi

Sample Info: Vt Tune Check

Volume Injected (uD: 1.0

Column phase:1 bf b

Pace 3

0179Instrument:

Operator; kb


So*n« 163-165 ( 8.26), B*ck(round Scan 182

^ ** ^ ^ P

PifZ

96

173

174

175

176

177

«.<* - >»*OSr of' WM» *U*» than 2.0WC of **** 17490.00 - lOO.OWT of MM» 999.00 - 9.00* of MSS 174

95.00 - 101.00X of mass 1745.00 - 9.00X of MSS 176

6.76O.OO < 0.00)

61.504.« < 7.51)

58.43 < 95.01)3.86 ( 6.61)

Data File: /cheiVmsdj. l/'f-O4nov.b/'sbll0401.d

Date : 04-NOV-2001 09:49

Client ID: BFB

Sanple Info: BFB Tun* Check

Volume Injected <uL>: 1.0

Colunn

Pace 4

Instrument: «isd(.i

Operator: kb

Column diameter; 2.00

0180

Data File: jbll0401.d

Spectrun: ftvj. Scans 163-165 ( 8.26), Background Scan 152

Location of Maxim*: 95.00


40»00

41.00

42.00

43.00

44.00

1892 I 96.00

477 I 97.00

429 I 99.00

299 I 99kOO

5122 I 100.00

64960 I 189,00

4837 I 189.00

412 I 161.00

119 I 162.00

116 I 164.00

284 I

561 I

790 I

139 I

197 I

264.00

267.00

269.00

269.00

270.00

81 I

46 I

1834 I

59 I

483 I

—f196 I

282 I

166 I

2119 I

23 I

34 I 1«M»

93* (1*6,00

510 I 272.00

68 I 273.00

182 I 2?*.00

20* I j!77.*0

274 I 296.00

173 I112 I283 I

159 I6 I

701 I 282,00890720 I 284.00

861216 I 291.0037120 I 298.00

829 I144 I

S* I78 I

131 I

269 1

11111+•"

11111

61.0062.00

63.00

64.00

68.00

66.00

67.00

68.00

69.00

70.00

47104

48808

36804

3132340

427

2908

106440

106080

7212

120.00

122.00

123,00

124.00

128.00

126.00

127.00

128.00

129.00

130.00

12690122849731

74

170

2058

1042

2069

188.00186.00

187.00

190.00

192.00

198.00

197.00

198.00

201.00

204.00

812122405

1316

391

122120

05

24

•" — "71 306.001 307.00

1 313.00

1 314.00

1 318.00

1 317.00

1 322.00

1 324.00

1 326.00

1 329.00

• • ' ' — »

221 1167 1

114 1 ,'144 1

313 1

88 1

433 1

292 1

75 1

232 1

Data Filt: /che«/n*dg.i/'(-04nov.b/tbll0401.d

Date : 04-NOV-2001 09:49

Client 19: BFB

Sanfle Info: BP1 Tun* Check

Voluwe Injected <uL>: 1.0

Column phase:

: M&d(.i

Operator: kb

Coluwi diameter: 3.00

0181

Data Filet (bll04Ol.dSf«ctrui| Avf, Scans 163-165 < 8.26), BacVfround Scan 152

Location of Haxinun: 90.00Hunter of points: 200

•/Z n/x m/z

I 71,00.

I 72,06

183 I 131.00

««* .'.«!&•*>.

278 I 209.00882 I 212.00

964 I 331.00

183 t.332.00

I 77.*»

I 79v*ft

4131* I 140.004)10 f 141.00

«a*H,**N»

I 144.00i .. .. ,, .| .... >.

. M*3* ' *<*+#

341 I M9.00*9C« | 220.00

900 I ZH.OQ•138 I 222.00i<9 I 230.00

CB I212 I

322 I332 I

69 I

339.00

340.00

341.00

342.00

348.00

326 I274 I

161 I

62 I189 I

304 I

40 I

I 82i<K>

r

627 I 2*liOO

94 I 233.00

146 I399 I

2» \300 I

347.00

3BO.OO

154 I88 I

I 86,00 3JH4f.». 190.00 402 1 243.OO 99 I»-

Data File: /chem/msdg.i/g-29nov.b/gbl!2901.dReport Date: 29-Nov-2001 06:14

10182

Air Toxics Ltd.

Data fileLab Smp IdInj DateOperatorSmp InfoMisc InfoCommentMethod;th Date

tal DateAls bottleOil FactorIntegrator

/chem/msdg.i/g-29nov.b/gbl!2901.dClient Smp ID: BFB

29-NOV-2001 06:06kbBFB Tune Check50ng 2ul #843-017

Inst ID: msdg.i

/chem/msdg.i/g-29nov.b/bfb.m29-NOV-2001 06:14

1.00000HP RTE


Quant Type;Cal File:QC Sample:

ESTD

BFB

Compound Sublist: all.subSample Matrix: WATER

Concentration Formula: Amt * DF * Uf * Vf * Vi * CpndVariable

Name Value Description

DFUfVfVi

1.000001.000001.000001.00000

Dilution Factorng unit correction factorVolumetric correction factorInjection Volume


RT BXP RT DLT RT

CONCENTRATIONS .

. OH-COt FIKAt

MASS , RSSPOM5B ( ug/L) ( Og/L) TMtOBT RAHGK RATIO

31 bfb

t*r*'••I;1

1

.„,

- *

,'•/i '>

aa8

8

8

8

8

8

8

.2S9

.259

.259

.259

.259

.259

.259

.259

.259

8.247

8.247

8.247

8.247

8.247

8.247

8.247

8.247

8.247

0

0

0

0

0

0

0

0

0

.012

.012

.012

.012

.012

.012

.012

.012

.012

95

50

75

96

173

174

175

176

177

924135

239462

483071

57658

0

556944

42644

541680

37255

CAS *: 460-00-4

100

IS

30

5

-. °SO

5

95

S

.00-

.00-

.00-

.00-

.00-

.00-

.00-

.00-

.00-

100.

40.

60.

9.

2.

100.

9.

101.

9.

00

00

00

00

00

00

00

00

00

100.00

25.91

52.27

6.24

0.00

60.27

7.66

97.26

6.98

Data File: />chept/»sdc.i/c-29rx>v.b/'8bll2901.d

Date J 29-NOV-2001 06:06

Client ID: BFB


Volune Injected <uL>: 1.0

Colum phase:

P«C* 2

Instrunent: nsdj.l

Operator: kb

Colunn dlaneter: 2.00

0183

4.8

4.6

4.4

4.2

4.0

3.8

3.6

3.4

3.2

3.0

2.8

2.6\X

>• 2.4

2.2

2.0

1.8

1.6

1.4

1.2

1.0

0.8

0.6

£

7.2 7.4 7.6 7.8 8.0 8.2 8.4 8.6 8.8Hln

».0 9iZ 9.4 9.6 9.8 10.0 10,2 10.4

Data File: /chem//msd5.i/8-29nov.b/jbli29Ol.d

Date : 29-NOV-2001 06:06

Client ID: BFB

Sample Info: BFB Tun* Check

Volume Injected <uL>: 1.0

Column phase:1 bfta

Pace 30184Instrument: msdg.i

Operator: kb


9.08.78.48.17.87.57.26.96.6

- 6.36.05.75.45.1

3 4.8

S 4'53 4.2»- 3.9

3.63.33.02.72.42.11.81.51.20.9

t^ 0.60.3o.oJ

6Ov

1*1,40

75v

|

II

11

60

^^^ ftvf. Scans 163-165 < 8.26), Background Scan ISO

X174

1 III /"7 X143LiJJL _ JL jj _

It*. II JQ t>\v*> 1 • AT - 1

y!93 240v 269vy270 -306 >327546

80 100 120 140 160 180 200 220 240 260 280 300 320 340m/z

X RELATIVEft/e IOH AKJHDAWCE CRITERIA . MUttANCE

95 Base Peak, 100X relative abundance 100.0050 15.00 - 40.00X of mass 96 25.9175 30.00 - 60.00X of mass 96 52.2796 6.00 - 9.00X of mass 95 6.24

173 Less than 2.00X of Mass 174 0.00 < 0.00)174 50.00 - 100.00* of mass 95 60.27175 5.00 - 9.00X of mass 174 4.61 ( 7.66)176 95.00 - 101.00X of mass 174 " 58.61 C 97.26)177 5.00 - 9.00X of mass 176 4.03 ( 6.88)

«

Data File: /che*/«sdt.i/s-29nov.b/ibll2901.d

Date : 29-NOV-2001 06:06

Client ID: BFB


Volume Injected (uL>: 1.0

Column phase:

0185Instrument:

Operator: kb


Data Filet (tall2901.d

Spectrum: ftvf. Scans 163-165 C 8.26), Background Scan 150

Location of Maximum; 96.00

NiMber of points: 204

m/z m/z m/z m/z1

1 33.00

1 36.00

1 37.00

1 38.00

1 39.00

1 40.00

1 41.00

1 44.00

1 45.00

1 46.00

1 47.00

1 48.00

1 49.00

1 50.00

1 51.00

1 52.00

1 53.00

1 56.00

1 56.00

1 57.00

1 68.00

;... » $9.00'.;;; . \ •"*»;*».'.•/.

I 6i;001 (2.00

1 63.00

1 64.00

1 65.00

1 67.00

1 68.00

1 69.00

1 70.00

•. 1 71.00

1 72.00

1 73.00

83 1

11016 1

55608 1

48840 1

19464 1

835 1

960 1

4828 1

10101 1

78 1

13092 1

6903 1

46352 1

239424 1

69720 1

3106 1

189 1

2347 1

14397 1

26808 1

923 1

t37«H

*#M;

44864 1

43416 1

33520 1

2500 1

458 1

751 1

102072 1

99520 1

7405 1

399 1

3694 1

40880 1

94.00

95.00

96.00

97.00

98.00

101.00

103.00

104.00

105.00

106.00

107.00

108.00

110.00

111.00

113.00

114.00

115.00

116.00

117.00

118.00

119.00

'i2oio*..121:06; :

122.06

123.00

124.00 .

125.00

126.00

127.00

128.00

129.00

130.00

131.00

132.00

134.00

104320 1

924096 1

57666 1

3023 1

207 1

398 1

1156 1

1388 1

1127 1

2560 1

403 1

64 1

550 1

477 1

615 1

249 1

870 1

1783 1

4763 1

2268 1

4252 1

•i&i430.1

301 1

427 1

606 1

547 1

447 1

1465 1

2487 1V *

1264 1

2668 1

78 1

837 1

636 1

159.00

160.00

162.00

163.00

165.00

166.00

168.00

169.00

170.00

171.00

172.00

174.00

176.00

.176.00

177.00

178.00

179.00

180.00

182.00

183.00

187.OO

189.06193.00197.00198.00

199.00

206.00

208.00

210.00

212.00

216.00

219.00

220.00

221.00

225.00

1045 1

135 1

156 1

194 1

889 1

526 1

96 1

127 1

264 1

827 1

210 1

666928 1

42640 1

841632 1

37248 1

353 1

298 1

40 1

234 1

84 1

131 1

279 1

1613 1

157 1

55 1

62 1

587 1

336 1

612 1

81 1

2 1

296 1

54 1

259 1

273 1

264.00

267.00

268.00

269.00

270.00

271.00

272.00

273.00

280.00

281.00

282.00

284.00

286.00

287.00

290.00

292.00

295.00

298.00

301.00

306.00

307.00

3101.00

311.00

313.00

314.00

316.00

318.00

321.00

322.00

324.00

326.00

327.00

330.00

331.00

332.00

152 1

4 1

460 1

2914 1

1334 1

266 1

335 1

189 1

137 1

805 1

87 1

68 1

309 1

115 1

74 1

68 1382 1161 197 1279 1

92 152122 11 1

242 1

72 1103 161 12 1

338 1

266 1940 163 117 1

102 1

Data File: /chei»/iwd{.i/j-29nov.b/jbll2901.d

Date : 29-NOV-2001 06:06

Client ID; BFB

Sample Info; BFB Tun* Check

Volune Injected <uL>: 1.0

Colum phase:

Pat* 5

Instrument: nsdf.i

Operator: kb

Column dianeter; 2.00

0186

Data File:

Speotrun; ftvf. Scans 163-168 < 8.26), Background Scan 160

Location of Haxinunt 95.00


n/z H/Z

11111

11111

11111

11

74

75767778

7980

818283

8586878891

9293

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

153216 1

483008 1

42056 1

5643 1

3420 1

16216 15296 1

17256 1

3792 1

544 1

48 1971 1

36312 1

36128 1

1925 1

23392 1

37360 1

136.137.139.14X>.

141.

142.143.144.146.147.

148.

180.154.158.156.

157.

158.

0000000000

00000000

00

0000000000

0000

236 1

176 1

156 1

613 1

5720 1

794 1

6004 1

148 1

714 1

155 1

1062 1

180 1

409 1

1877 1

301 1

1344 1

266 1

226.00

230,00

238,00

237.00

238.00

239.00

240.00

241.00

242.00

243.00

244.00

281.00

258.00

299.00

260.00

261.00

263.00

103 1

193 1

115 1

334 1

77 1

349 1

388 1

338 1

66 1

55 1

60 1

272 1

87 1

194 1

502 1

695 1

179 1

333334

336336339

341

342343344345

346347348

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

64 1

3 1

87 1

161 1

124 1

539 1

189 1

77 1

937 1

181 1

115 1

174 1

112 1

11

1

'

0187

Shipping/ Receiving Documents

0188

EMAIL RECEIPT SUMMARY

CLIENT: Air Nova, Inc.

WORK ORDER NUMBER: 0111476

EMAIL ID: [email protected]

DATE SENT: 11/28/01 3:30:36 PM

USER INITIALS: KCB

Signed:.

*

AIR TOXICS LTD. 0189

AN ENVIRONMENTAL ANALYTICAL LABARATORY

180 Blue Ravine Road, Suite B |Folsom, CA 95630

Phone (916) 985-1000 FAX (916) 985-1020 S

Hours 8:00 A.M. to 6:00 P.M. Pacific .'

COMPANY: Air Nova. Inc. F

ATTENTION: Mr. Joe Jackson I

FAX#: 856-486-9896 _

FROM: Sample Receiving ;

Workorder #: 0111476

# of pages (Including Cover): 4 I

11/28/01

Thank you for selecting Air Toxics Ltd. We have received your samples and have found discrepancies. fIn order to expedite analysis and reporting, please review the attached information for accuracy. *Corrections can be faxed to Betty Chu at 916-985-1020.ATL will proceed with the analysis as specified on the Chain of Custody and Sample Login page.

The following discrepancies have been observed: »

Samples RUN#1 Can #31429 Air Toxics 2692. and RUN#2 Can #12683 were both received at 27" Hg. L

This high vacuum will result in a higher dilution factor. ATL will proceed with the analysis unless otherwise " f

notified. ris

Your prompt response is appreciated.

» ™ ™^^T^n nr ™~ Sample Transportation Notice 180 BLUE RAVINE ROAD, SUITE BAIR TOXICS LTD Relinquishing signature on this document indicates that sample is being shipped In compliance FOLSOM, CA 95630-4719

v^^*.AV^v_7 M^t M. M*r» ipp|iclb|e |0ca, State Federi|( national, and international laws, regulations and (916)985-1000 FAX: (916) 985-1020AN ENVIRONMENTAL ANALYTICAL LABORATORY ordinances of any kind. Air Toxics Limited assumes no liability with respect to the collection.

handling or shipping of these samples. Relinquishing signature also Indicates agreement to holdCH AIN-OF-CUSTODY RECORD harmless, defend, and indemnify Air Toxics Limited against any dalm, demand, or action of anyvsiij-iiii vxi wîwb/i III-VS^/IILS ^ co||ect|oo handnng or shipping of samples. D.O.T. Hotline (600) 467-4922

Page _/_ of _/_

Contact Person _

Company /rf/2-

Address

Phone

Collected By: Signature

Project Info:

Project #

Project

Turn Around Time:

RushSpecify

LabI.D;

Field Sampl Date & Time Analyses RequestedCanister Pressure / VacuumInitial Final Receipt

OiA

^

LabUseOnly

Shipper Name WortcOrder f, jr ff^Q

r *IL<\ -x u y *<(> kr- 45£«^ -- Yes No ^_Npfle^ 0111476v ^ A * •! \f •• -

Form 1293 r*v. 09

?m i?v:.;-l v Tl


0191

Fraction

01A02A03A04A

SAMPLE RECEIPT SUMMARY

WORKORDER 0111476

Client

Mr. Joe JacksonAir Nova, Inc.5845 Clayton AvenuePennsauken, NJ 08109

Sales Rep: RMW

Sample #

RUN#1 Can #31429 Air Toxics 2692RUN#2 Can #12683Lab BlankLCS

Phone

856-486-1500

Fax

856-486-9896

Date Promised: 12/10/01

Dale Completed: 12/10/01

Date Received: 11/27/01

P0#: AN-2914

Project* 2461 Valley Crest

Total $: $695.00

Logged By: LT

Analysis

TO-14/TICsTO-14/TICsTO-14/TICsTO-14/TICs

Misc. Charges 6 Liter Summa Canister (2) @ $50.00 each.Flow Controller-12 hr (1) @ $25.00 each.

Collected

11/20/0111/20/01

NANA

ReceiptVacTPres.

27.0 "Hg27.0 "Hg

NANA

AmountS

$285.00$285.00

$0.00$0.00

$100.00$25.00

Note: Samples received after 3 P.M. PST are considered to be received on the following work day.Atlas Project Name/Profile*: Valley Crest LF/3505


Analysis Code: TO-14

Reporting Method: TO-14/TICs

180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630(916) 985-1000 . (800) 985-5955 . FAX (916) 985-1020

Pagel

Client Services must receive Form within 24 hrs of initiation if Section HI is filled outJ_=__y

Initiated By: '' Date: Given To:Sections I - III must be filled out by person initiating this Sample Discrepancy Report.

Client Service: Date: Given To:Section IV must be filled out by Client Serv. Personnel only and returned to Workorder Folder within 24hrs.

I. Work order(s) affected: Q'U

Sample(s) affected: A \\

II. Discrepancies To be noted in Los-in FAX/E-mail and in Lab Narrative:

Q Chain of Custody Record (COC) improperly relinquished.Q COC was not filled out in ink.

~* Number of samples on the COC does not match the number of samples that were received.Sampling date / time is not documented.

Q Sample tags do not match the COC.QSamples received at wrong temperature.^Canister sample received at >15"Hg.Q Sample container (Tube/VOA vial) was received broken, however, sample was intact.Q No brass cap.Q Custody seal on the outside of the container was broken.Q Flow controller used - canister samples received at <2.5"Hg.Q Other

Describe the Discrepancy; ifo'V'^ £€C''*V^ 7 /r*#?

'-utials: ML Date:

III. Discrepancies To be documented in Client Contacts and in Lab Narrative:

Q Chain of Custody Record (COC) was not received with samplers).Q Analysis method(s) is not specified on the COC.Q Sample(s) received out of holding time.Q Sample container (Tube/VOA vial) was received broken.Q Container for VOA analysis received with headspace.Q Tedlar Bag received leaking, or found to be leaking at the time of analysis.Q Tedlar Bag received flat, or found to be flat at the time of analysis.Q Canister received with a leaky valve, or found to be leaking at the time of analysis.Q Tedlar bag / canister received emitting a strong odor (sample cannot be analyzed).Q Initial laboratory VacTPress. does not match final field pressure.Q VOST tube saturated, bag dilution is necessary.Q Sample loss due to instrument malfunction.Q Other

; Describe the Discrepancy:.

Initials: Date:

Revision Date: 09/12/01 Air Toxics Ltd. (Continued)

Other Records

DILUTION FACTORS

Dilution Factor = Final PressureInitial Vacuum

0 19414.7 psi + Final Pressure (psi)

14.7 psi - [(Initial Pressure ("Hg)) (14.7 psi / 30 HHg)

Dilution Factor = Final PressureInitial Pressure

Initial 5 psi 10 psi 15 psiVacuum Final Press. Final Press. Final Press.

("Hg) Oil. Factor Oil. Factor Dil Factor0.0 1.34 1.68 2.02

16.0 2.87 3.60

17.0 3.09 3.88 4.66

18.0 3.35 4.20 5.05

19.0 3.65 4.58 5.51

20.0 4.02 5.04 6.06

14.7 psi + Final Pressure (psi)14.7 psi + Initial Pressure (psi)

Initial 5 psi 10 psi 15 psiVacuum Final Press. Final Press. Final Press.

("Hg) Dil. Factor Dil Factor Dil. Factor

29.0 40.20

Initial 5 psi 10 psi 15 psiPressure Final Press. Final Press. Final Press.

(psi) Dil. Factor Oil. Factor Dil. Factor

1.21 1.52 1.82

2.0 1.18,

1.48 1.78

2.4 1.15 1.44 1.74

2.8 1.13 1.41 1.70

3.2 1.10 1.38 1.66

3.6 1.08 1.35 1.62

4.0 1.05 1.32 1.591 Rev. 5/99

12/10/2001 2:18:58PM

Compound ListingTO-14/TIC's

CAS Number

75-71-876-14-274-87-375-01-474-83-975-00-375-69-475-35-476-13-175-09-275-34-3156-59-267-66-371-55-656-23-571-43-2107-06-279-01-678-87-510061-01-5108-88-310061-02-679-00-5127-18-4106-93-4108-90-7100-41-4108-38-395-47-6100-42-579-34-5108-67-895-63-6541-73-1106-46-7100-44-795-50-1120-82-187-68-3115-07-1106-99-067-64-175-15-067-63-0156-60-5108-05-478-93-3

Compound

Freon 12Freon 114ChloromethaneVinyl ChlorideBromomethaneChloroethaneFreon 1 11,1-DichloroetheneFreon 113Methylene Chloride1,1-Dichloroethanecis-1 ,2-DichloroetheneChloroform1 , 1 , 1 -TrichloroethaneCarbon TetrachlorideBenzene1 ,2-DichloroethaneTrichloroethene1 ,2-Dichloropropanecis-1 ,3-DichloropropeneToluenetrans-1 ,3-Dichloropropene1 ,1 ,2-TrichloroethaneTetrachloroetheneEthylene DibromideChlorobenzeneEthyl Benzenem.p-Xyleneo-XyteneStyrene1 ,1 ,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dichlorobenzene1 ,4-DichlorobenzeneChtorotoluene1 ,2-Dichlorobenzene1 ,2,4-TrichlorobenzeneHexachlorobutadienePropylene1 ,3-ButadieneAcetoneCarbon Disulfide2-Propanoltrans-1 ,2-DichloroetheneVinyl Acetate2-Butanone (Methyl Ethyl Ketone)

Detection

ppbv

0.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.502.02.02.02.02.02.02.02.0

0195

Limit

-

t

f.

£fe

•r

'—'.

P£**.Tu

.£5

-' ;'

<•

•-

p.

„ ,

^

Compound ListingTO-14/TIC's

12/10/2001 2:18:58PM

0196

CAS Number

110-54-3109-99-9110-82-7123-91-175-27-4108-10-1591-78-6124-48-175-25-2r~?-96-8-17-5

1634-04-4142-82-52037-26-5460-00-417060-07-0

Compound

HexaneTetrahydrofuranCyclohexane1 ,4-DioxaneBromodichloromethane4-Methyl-2-pentanone2-HexanoneDibromochloromethaneBromoform4-EthyltolueneEthanolMethyl tert-Butyl EtherHeptaneToluene-d84-Bromofluorobenzene1 ,2-Dichloroethane-d4

Detection Limit

ppbv

2.02.02.02.02.02.02.02.02.02.02.02.02.0

Q- ora

Q-' QQA*

Of Q

Q" Gar Q"or Q

a

d dar d-or d

T Qa aQ GQ QG GG GG GG GQ GG GG GG GG GG GG GG QG GG GG G

GGGQG

@Air Toxics Lid.

REVIEW CHECKLIST Work Order #: 01

0197Lab Narrative is correct (proper method, description)Corrective Action issued - #Unusual Circumstances documented in Notes Section belowAnalysis versus Project Profile/SOP requirements checkedCCV, LCS, End Check, Duplicates met required QC criteriaAppropriate Data Qualifier Flags are usedHold Time is met for all Samples12 Hour Clock Verification (if required by the project)C.O.C. checked for Field Blanks and Dups; Checked Samples for TrendsCorrect Amount of Sample AnalyzedSamples pressurized w/ appropriate gas(Nj)br He)Final Pressure consistent with Caniste^ size{6pvs.lL) ...Dilution Factor Correctly Calculated (based on Sarftple vol. loaded/Final Pressure)*-'SS, I.S., COz, DNPH or System Peaks are identifiedin ehromatogram(s)Peak Area Integra^h CorrectRetention-Times ftaê been verifiedSpectra Verified^ - Documentation of Difficult Calls includedAppropriate jC^L(s) includedBFB/D^TPP^Tune, GCV, LCS, SS, and Simple Result Calculation checkedManually calculated/manually entered results checkedThe Final Report has the correct Reporting Limits, Units, and Header Info.Special Units for. all samples in thelSnaT report are correctly calculatedCVP paclcage/CJient Specific Deliverable is correct

_. .

Notes: (to include* noting samples with QA/QC problems. Blanks with positive hits, narratives, etc.)'£*'.- '-i'.;-. '•• : " .:

A,(Analytical Review/Date)

IA> /t/30/0

A2

(Analytical Review/Date) (Technical Review/Datc) (QA Review/Date)

Note: Please check all the appropriate boxes. Indicate "NA" for any statement that does not apply.

Revision Date: 09/14/01

inc.5845 Oayton Avenue. Pennsauken. New Jersey O81O9

(856) 486-15OO • FAX 486-9896 • wwwaimova.com

PROJECT NO. LOCATION

SAMPUNG TIME (24-hr CLOCK).

SAMPLING LOCATION

-J-ex-t

SAMPLE TYPÂG. INTEGRATED, CONTINUOUSp

ANALYTICAL METHOD €/# /flfc#>/ 3 -

AMBIENT TEMPERATURE

Run otj£

Gas

C02

O2 (NET IS ACTUALO/READING MINUSACTUAL CO, READING

CO (NET IS ACTUALCO READING MINUSACTUAL O, READING

N, (NET IS 100 MINUSACTUAL CO READING

1

ActualReading

1.1

/u

Net

7?in

2

ActualReading

?.o

til

Net

r.o//7

3

ActualReading

7 ?

/?r

Net

7-7

//.£

AverageNetVolume

7în

Run 7~LJO

Gas

C02

O, (NET IS ACTUALO, READING MINUSACTUAL CO, READING


N, (NET IS 100 MINUSACTUAL CO READING

1

ActualReading

f,^

24~o

Net

f.2~

n.f

2

ActualReading

£?fl-7

Net

f.3

M

3

ActualReading

f.tlU

Net

?.l

nr

AverageNet

Volume

^

U?

Run

Gas

C02

O2 (NET IS ACTUALO, READING MINUSACTUAL CO, READING


N2 (NET IS 100 MINUSACTUAL CO READING

1

ActualReading

Net

2

ActualReading

Net

3

ActualReading

Net

AverageNet

Volume

-i &7&J&.

. . • • • .• • • •

AirlMova, Inc.

PROJECT NUMBEF

PLANT

5845-A Clayton Avenue, Pennsauken. New Jersey 08109(609) 486-1500 • FAX 486-9896

CHAIN OP CUSTODY DOCUMENTATION FORM

SAMPLE PATK //

COC DOCUM t NT ATIQN *

P A C E / . . or

&<•*£SAMPLE LOCATION

RECOVERY DATE .

SAMPLE RECOVERED BY.

TESTSET

COLLECTIONMETHOD

emin

''

1

/~\

RUN*

/A

£

SAMPLE MATRIXJ (INDICATE # OF SAMPLES) w

I JS gSJ JS „ | f ff |5 55 j?fl 5 % f 8 S ? g?N a f c . o n 5 < * = i i r « o

7^/ozV//II

?

CONTAINBM

: .1 1 1 : t.i I i I nX 9 t. *• MO

1/

PNBSBIIVATION

>i *y kl

W W XW * t

• 0

SAFCTY

SEAL.

INTACT

(Y/N)

PRIORITY

RESULTS

(X)

FOR

YES

IKWIHQUISHKD

iWlM ncciivco »r:

0*Tl:

TIME: cr 'io BV.

AIR TOXICS LTD.-. AN ENVIRONMENTAL ANALYTICAL LABARATORY

i ;

Air Toxics Ltd. Introduces the Electronic Sample Receipt Confirmation

Thank you for choosing Air Toxics Ltd. To better serve our customers, we are providing the sample login |confirmation by e-mail. This document is provided in Portable Document Format which can be viewed withAcrobat Reader by Adobe. »This sample receipt confirmation includes the following: f

• Cover Page noting any sample receiving discrepancies; >—'

• Sample Receipt Summary; ,- • &

• Chain of custody (copy);

• Compound Listing; and ' t

• Unretumed Equipment. *

O

( \ 180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020Hours 8:OOAJyito 6:00 P.M. Pacific

E-mail to:samplereceiving@alrtoxlc*.com

AIR TOXICS LTD.AN ENVIRONMENTAL ANALYTICAL LABARATORY

Air Toxics Ltd. Sample Receipt Confirmation Cover Page

Thank YOU for selecting Air Toxics Ltd. We have received vour samples and have found no discrepancies.

In order to expedite analysis and reporting, please review the attached information for accuracy.Fax/E-mail corrections to Bettv Chu at 916-985-1020/samDlerecelvina<a)airtoxlcs.com

ATL will proceed with the analysis as specified on the Chain of Custody and Sample Receipt Summary page.

The following have been observed:

Samples RUN#1 Can #31429 Air Toxics 2692, and RUN#2 Can #12683 were both received at 27" Hg. Thishigh vacuum will result in a higher dilution factor. ATL will proceed with the analysis unless otherwise notified.

, , 180 BLUE RAVINE ROAD, SUITE B FOLSOM, CA - 95630

(916) 985-1000 .FAX (916) 985-1020Hours 8:00 A.M to 6:00 P.M. Pacific

E-mail to:[email protected]


SAMPLE RECEIPT SUMMARY

WORKORDER 0111476

Client

Fraction

01A02A

Mr. Joe JacksonAir Nova, Inc.5845 Clayton AvenuePennsauken, NJ 08109

Sales Rep: RMW

Sample *

RUNtfl Can #31429 Air Toxics 2692RUN#2 Can #12683

Phone

856-486-1500

Fax

856-486-98%

Date Promised: 12/10/01

Date Completed:

Date Received: 11/27/01

PO*: AN-2914

Project*: 2461 Valley Crest

TotalS: $ 695.00

Logged By: LT

Analyst*

TO-14/nCsTO-14/TICs

Collected

11/20/01

11/20/01

ReceiptVac^Prea.

27.0 "Hg

27.0 "Hg

r

Misc. Charges 6 Liter Summa Canister (2) @ $50.00 each.Flow Controller-12 hr (1) @ $25.00 each.

$285.00

$285.00

$100.00$25.00

o

Note: Samples received after 3 P.M. PST are considered to be received on the following work day.Adas Project Name/Profile* Valley Crest LF/3505


Analysis Code: TO-14

uReporting Method: TO-14/TICs

180 BLUE RAVINE ROAD. SUITE B FOLSOM. CA - 95630(916) 985-1000. (800) 985-5955. FAX (916) 985-1020

Pagcl

•80 BLUE RAVINE ROAD. SU.TE B-OLSOM, CA 96630-£916)985-1000 FAX:

Turn Around Ttrrw

Ganteter Pressure / Vacuum

I Q1I1476

12/4/2001 9:27:34AM

Compound ListingTO-14friCfs

CAS Number

75-71-876-14-274-87-3754)1-474-83-9754)0-375-69-475-35-4

76-13-1754)9-2 .75-34-3156-59-267-66-371-55356-23-571-43-2107-06-2794)1-678-87-510061-01-5108-88-310061-02-6794)0-5127-1 &4106-93-4108-90-7100-41-4108-38-395-47-6100-42-5

79-34-5108-67-895-63-6541-73-1106-46-7100-44-795-50-1120-82-187-68-31154)7-1106-994)674W-175-154)674*34)1564JO-5

| 1084)5-4

Compound

Freon12Freon114

ChkxomethaneVinyl ChlorideBromomethaneChtoroe thaneFreon111.1-DichloroetheneFreon 113Methytene Chloride1,1-Otchkxoethanecis-1 ,2-DichloroetheneChloroform1,1,1-TrichloroethaneCarbon TetrachtorideBenzene1.2-DichloroethaneTrichloroethene1 ,2-Dichloropropanecis-1 ,3-DichloropropeneToluenetrans- 1 ,3-Oichloropropene1.1,2-TrichloroethaneTetrachtoroetheneEthytene DibromjdeChlorobenzene rEthyl Benzenem,p-Xyteneo-XyleneStyrene1.1,2,2-Tetrachloroethane1 ,3,5-Trimethylbenzene1 ,2,4-Trimethylbenzene1 ,3-Dlchlorobenzene1 ,4-DichlorobenzeneChlorotoluene1.2-Oichlorobenzene1 ,2,4-TrichlorobenzeneHexachtorobutadtenePropytene1,3-ButadieneAcetoneCarbon Disulfide2-Propanoltrans- 1 ,2-DichloroetheneVinyl Acetate

Detection Limit

ppbv

0.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.500.502.02.02.02.02.02.02.0

12/4/2001 9:27:34AM

Compound Listing

TO-14/nC's

CAS Number Compound Detection Limit

ppbv

78-93-3110-54-3109-99-9110-82-7123-91-175-27-4108-10-1591-78-6124-48-175-25-2 .622-96-8

64-17-5

1634-04-4142-82-5

2037-26-5460-00-417060-07-0

2-Butanone (Methyl Ethyl Ketone)HexaneTetrahydrofuran

Cydohexane1.4-Dioxane

Bromodichloromethane

4-Methyt-2-pentanone2-Hexanone

DibromochloromethaneBrofnoform4-Ethyltoluene

EthanolMethyl tert-Butyl EtherHeptaneToluene-d84-Bromofluorobenzene1,2-Dichk>roethane-d4

2.02.02.02.02.02.02.02.02.02.02.02.02.02.0

.

I

CaHbration Data

AirNova, Inc.Dry gas meter & orificeCalibration data and calculations

Meter Box #:Checked with Pump #:

Date:Calibrator:

88

11/09/01JRJ

delta H =Pb =Time =

Std Test

IVw =v_ FVw =

TVw =tw =

delta H =Pb =Time =

Std Test

IVw =FVw =

^ TVw =tw =

delta H =Pb =Time =

Std Test

IVw =FVw =TVw =tw =

0.5 in. H2O30.29 in. Hg15.0 min.

Meter Data

265.617271.685

6.06860

1.0 in. H2030.29 in. Hg

13.0 min.

Meter Data

221.017228.576

7.55960

1.5 in. H2O30.29 in. Hg10.0 min.

Meter Data

230.612237.513

6.90160

Drv Test Meter Data

IVd =FVd =TVdltd =Ftd=Avg. td =

101.469107.175

5.7066766

66.5

Drv Test Meter Data

IVd =FVd =TVdltd =Rd=Avg. td =

57.59264.8257.233

616362

Drv Test Meter Data


66.79273.5256.733

636564

1.642 1.075

1.603

AYi

1.047

AVi

1.701

Yi

1.029

Pg. 1 of 2

Date: 11/09/01

AirNova, Inc.

Calibration Data MB#: 8

delta H =Pb =Time =

Std Test

IVw =FVw =TVw =tw =

delta H =Pb =Time =

Std Test

IVw =FVw =TVw =tw =

delta H =Pb =Time =

Std Test

IVw =FVw =TVw =tw =

2.0 in. H2O30.29 in. Hg10.9 min.

Meter Data

238.637247.178

8.54159

3.0 in. H2O30.29 in. Hg

7.0 min.

Meter Data

248.943255.654

6.71160

4.0 in. H2O30.29 in. Hg

6.0 min.

Meter Data

258.015264.644

6.62959

Avg.AH@

» i i A

Dry Test


Dry Test


Drv Test


\ s

1

Meter Data

74.62583.0638.438

6566

65.5

Meter Data

84.81491.5266.712

676767

Meter Data

93.887100.555

6.6686768

67.5

1.70

9 / / /Signature: Mb /UfA£V\

AH@8

1.747 1.020

1.753 1.006

1.751 1.001

Avg.Y= 1.03

Date: ll'1'Ol- 2 of 2

AirNova, Inc.Calibration data and calculationsMeter Box Temperature Sensors

Meter Box #:Date:

CalibratorAmbient Temp. (F):

Barometric Pressure (*Hg):Reference Thermometer.

Dry Gas Meter Thermocouple - INLET

Reference Point Ref. ThermometerTemp. fR

Ambient Temp. 59Hot Water (104-122F) N/A

Dry Gas Meter Thermocouple - OUTLET

Reference Point Ref. ThermometerTqmp. (F)

Ambient Temp. 59Hot Water (1 04-1 22F) N/A

811/09/01JRJ5930.29ASTM-2F

ThermocoupleTemp. (F)

57N/A

ThermocoupleTemp. (R

57N/A

PJfL

20

DifL

20

note: tolerance for inlet and outlet = +/- 5.4 F

Thermocouple connector/LED readout:

1 Stack2 Probe3 Filter4 Dryer5Aux

Ref. ThermometerTemp. (F)

5959595959


5959595959

Qif

00000

note: tolerance = +/- 2 F

Signature: Date:

i 3

AirNova, Inc.Dry gas meter & orificeCalibration data and calculations

Meter Box #:Checked with Pump #:

Date:Calibrator.

88

09/27/01TEL

delta H =Pb =Time =

0.5 in. H2O30.00 in. Hg

13 min.

Std Test Meter Data Drv Test Meter Data

IVw =FVw-TVw =tw =

delta H =Pb =Time =

9.83815.1455.30768.5

1.0 in. H2O30.00 in. Hg

11 min.


848.073853.238

5.16569.570.5

70

1.671 1.029

Std Test Meter Data Drv Test Meter Data

IVw =FVw =TVw =tw =

delta H =Pb =Time =

3.2639.6706.40768.5

1.5 in. H2O30.00 in. Hg

8 min.


841.537847.928

6.39170

71.570.75

1.639 1.004

Std Test Meter Data

IVw =FVw =TVw =tw =

15.39121.0185.627

69

Drv Test Meter Data


853.478859.155

5.67770.571.5

71

1.688 0.991

Pg. 1 0(2

A4

Date: 09/27/01

AirNova, Inc.Calibration Data MB#: 8

delta H =Pb =Time =

Std Test

IVw =FVw =TVw =tw =

delta H =Pb =Time =

Std Test

IVw =FVw =TVw =tw =

^ delta H =Pb =Time =

Std Test

IVw =FVw =TVw =tw =

Signatui

2.0 in. H2O30.00 in. Hg

8 min.

Meter Data

21.40027.7906.390

69\ K

3.0 in. H2O30.00 in. Hg

6 min.

Meter Data

28.48834.3375.84969.5

4.0 in. H2O30.00 in. Hg

5 min.

Meter Data

34.63940.288

5.64969.5

Avg.AH@

^~~ —re>^^ ^^€ t > /s^~

Dry Test


Dry Test


Drv Test

IVd =FVd =Wdltd =Ftd=Avg. td =

>/^4&C--

Meter Data

859.548865.991

6.4437172

71.5

Meter Data

866.687872.602

5.9157273

72.5

Meter Data

872.917878.652

5.7357273

72.5

1.71

^

AH@i

1.744 0.992

1.756 0.987

1.743 0.981

Avg.Y= 1.00

Date: rPg. 2 of 2

AirNova, Inc.Calibration data and calculationsMeter Box Temperature Sensors

Meter Box #:Date:

CalibratorAmbient Temp. (F):

Barometric Pressure (*Hg):Reference Thermometer

Dry Gas Meter Thermocouple - INLET

Reference Point Ref. ThermometerTemp. (F)


Dry Gas Meter Thermocouple - OUTLET

Reference Point Ref. ThermometerTemp. (R


809/27/01TEL6830.00ASTM-2F

ThermocoupleTemo. (R

67N/A

ThermocoupleTemp. (R

67N/A

BjfL

10

DHL

10

note: tolerance for inlet and outlet = +/- 5.4 F

Thermocouple connector/LED readout:

1 Stack2 Probe3 Filter4 Dryer5Aux

Ref. ThermometerTemp. (R

6868686868


6868686868

OH

00000

note: tolerance = +/- 2 F

Signature; Date:

AirNova, Inc.Pitot ThermocoupleCalibration data

I

iReference

PointSource

Ice Water

Boiling Water

Hot Oil Bath

Date:

Thermocouple I.D.:

Probe Length:

Calibrator

Ambient Temp.(F):

Barometric Pressure (" Hg):

Reference Thermometer

Ref. ThermometerTemp.(F)

32

212

446

ThermocoupleTemp.(F)

34

214

445

12/06/01

P-6-B

6 Foot

TEL

69

30.14

ASTM-2F

TemperatureDOT. (%)

0.4%

0.3%

0.1%

Average Temp. Change:

Temperature Difference must be < 1.5%

0.3%

Signature Date:

'.*'.'.: AinfMowa, inc.• • ••'

Type S Pitot TubeDimensional Specification Verification Form

Pitot No. PCalibrator TEX

Date t>./u>|

Verify the following criteria and check all that apply

•

1) Face opening plane perpendicular to the transverse axis ? O*—

2) Face-opening plane parallel to the logitudinal axis ? g>lC^

3) Are Legs A & B of equal length and are centetlines coincident ? **—

If all the above criteria are met, a pitot coeffecient of 0.84 may be assigned tothe respective pitot tube. If one of the following criteria above is not met, thepitot tube must be calibrated in a wind tunnel.

Recommended Dimensions

4) Diameter of pitot tubing ? (Dt) = 3> in. ( 0.1 875 < Dt < 0.375)

5) Dimensions of Pa = .*/?£ in. Pa/Dt = A 27 (1 .05 < Dt < 1 .50)

6) Dimensions of Pb = A°ft in. Pb/Dt = />2>3 (1 .05 < Dt < 1 .50)

Irvi( AMI

FMCort«*c —

fc«*tfflM«

• I *«fi. f •; • ~~ / I'* J •-•.<•<•-..

V ' •

O Ti«T~^T" ~

- R

AirNova, Inc.Pitot ThermocoupleCalibration data

Date:

Thermocouple I.D.:

Probe Length:

Calibrator

Ambient Temp.(F):

Barometric Pressure (" Hg).

Reference Thermometer

10/11/01

P-6-B

6 Foot

TEL

69

30.45

ASTM-2F

ReferencePoint

Source Ref. ThermometerTemp.(F)

ThermocoupleTemp.(F)

TemperatureDiff. (%)

Ice Water

Boiling Water

Hot Oil Bath

32

212

419

33

217

421

0.2%

0.7%

0.2%

Average Temp. Change:

Temperature Difference must be <1.5%

0.4%

Dotei: /•a/yv /& /•

^••••II. /Virl\lo\/a, Iric.

Type S Pitot TubeDimensional Specification Verification Form

Pitot No. _Calibrator

Date /o - //-O t

Verify the following criteria and check all that apply

0

1) Face opening plane perpendicular to the transverse axis ?

2) Face-opening plane parallel to the logitudinal axis ? ^

3) Are Legs A & B of equal length and are centeriines coincident ? <*

If all the above criteria are met, a pitot coefficient of 0.84 may be assigned tothe respective pitot tube. If one of the following criteria above is not met, thepitot tube must be calibrated in a wind tunnel.

Recommended Dimensions

4) Diameter of pitot tubing 1 (Dt) = .y)*l in. (0.1875 < Dt < 0.375)

5) Dimensions of Pa = -5*** in. Pa/Dt= W (1.05 < Dt < 1.50)

6) Dimensions of Pb = ««/09 in. Pb/Dt = J-31 (1.05 < Dt < 1.50)

TUMtttltStt«M ««I

FACC

^ lL • __ y\'_ _. .FT i

; 0

Appendix E

Process Diagrams'

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