Top Banner
0 | Praxair Business Confidential | 10/20/2017 OTM Solid State Combined Reformer Progress Update GSTC 2017 Colorado Springs OTM
13

OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

Mar 17, 2020

Download

Documents

dariahiddleston
Welcome message from author
This document is posted to help you gain knowledge. Please leave a comment to let me know what you think about it! Share it to your friends and learn new things together.
Transcript
Page 1: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

0 | Praxair Business Confidential | 10/20/2017

OTM Solid State Combined Reformer

Progress Update

GSTC 2017

Colorado Springs

OTM

Page 2: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

1 | Praxair Business Confidential | 10/20/2017

Praxair’s OTM Combined Reformer

Why:

The most efficient process to produce syngas

for chemicals

What:

Oxygen-based syngas supply system without

the oxygen plant

SMR inputs ATR outputs

How:

Solid-state air separation combined with

reforming in a robust ceramic membrane within

a modular, scalable package

Page 3: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

2 | Praxair Business Confidential | 10/20/2017

Step Change Syngas Technology

Combined reforming in a single integrated efficient package

Primary steam

methane reformer

Air separation

unit

Secondary auto thermal

reformer

Multi-

process

combined

reforming

Solid state

combined

reforming

with OTM

Primary

Reformer

Tubes

Ceramic

ASU + ATR

Tubes

Feed Product

Page 4: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

3 | Praxair Business Confidential | 10/20/2017

Modular Syngas Technology

Combined reforming in a single integrated efficient package

OTM

Reformer

NG +

Steam

Syngas

Page 5: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

4 | Praxair Business Confidential | 10/20/2017

Furnace Design and Scale-Up

Simplified modular scale-up

1000BBL/d

50BBL/d

5BBL/d Modularly

Constructed

System

Multi

Module

“Train”

Panel Pack Train

Page 6: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

5 | Praxair Business Confidential | 10/20/2017

Robust System Operation

No ceramics failures through 44 week torture test

Site

power

failure

Month 1 2 3 4

Stand-by

Operating

OT

M

Process

Trips

Process Starts

Deep

thermal

cycles ■ Site NG Syngas

■ 50,000 scfd Syngas

■ +150 on/off syngas cycles

■ Multiple deep thermal cycles

Page 7: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

6 | Praxair Business Confidential | 10/20/2017

OTM Pilot System

New reactor and infrastructure for commercial scale panel operation

New reactor and infrastructure for commercial scale panel operation

Page 8: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

7 | Praxair Business Confidential | 10/20/2017

OTM

Plot

USGC 2019 Startup

Up to 8MMscfd syngas feed to MeOH plant

Evaluating OTM field demonstration project

OTM Syngas Pack

6 pack train

OTM Field Demonstration

Page 9: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

8 | Praxair Business Confidential | 10/20/2017

OTM Platform

Syngas platform

– Can be optimized for MeOH, H2, GTL, CO

– High NG conversion efficiency

Modular syngas offering for CO, Chemicals, GTL

– “Oxygen free” alternative to POx, ATR and Combined Reforming

– Opportunity to pursue small CO where O2 is not available and ASU is difficult to justify

– 10% – 15% more efficient than SMR for MeOH and GTL

– Advantages validated by third parties (technology licensors)

Paradigm shift for methanol and GTL economics

Page 10: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

9 | Praxair Business Confidential | 10/20/2017 9 | Praxair Business Confidential | 10/20/2017 9 | Praxair Business Confidential | 10/20/2017

Typical Process Flowsheet- NG to syngas

Page 11: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

10 | Praxair Business Confidential | 10/20/2017

OTM Platform: Large Methanol

Joint evaluations with major licensor and producer

Greenfield methanol plants: 1000 – 3000 metric tons/day

SMR + ATR + ASU (CR)

SMR

CO2 emissions Base +16% NG Consumption Base +13% Operating cost Base +7% Capital investment Base -9%

15 yr IRR, % 14.1% 14.9% Net income*, $MM/yr 82 84

OTM CR

-29% (142,000 t/yr) Base

-4% ($5 MM/yr) -18% ($175 MM)

18.4% 113

*3000 mT/d; MeOH @ $350/mT

Page 12: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

11 | Praxair Business Confidential | 10/20/2017

Technology Readiness

Achieved commercial ceramic performance targets

– Extraordinary progress on flux, strength, creep life, degradation

– Robust glass-ceramic seals

Proved unique combined reforming process

– Demonstrated at single and multi-panel levels

– Robust to system-start up, shut-down, trips, and transients

On-Track with Supply Chain and Cost Reduction

– Tube manufacturing capacity increased to 8 MM scfd syngas/yr

– Qualifying external parties for high volume substrate manufacturing

– Shops qualified to manufacture panel array modules

– Delivering on key capital cost reduction targets

Ready for industrial scale demonstration

Page 13: OTM Solid State Combined Reformer Progress Update Ines Stuckert.pdf · Modular syngas offering for CO, Chemicals, GTL –“Oxygen free” alternative to POx, ATR and Combined Reforming

12 | Praxair Business Confidential | 10/20/2017

Questions?

Thank you!