SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name OPN-Zinc Spray - zinc gray - Other means of identification Article number 63110 Tariff No. 32081010 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.3 1.4 SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Category Hazard class and category Hazard statement 2.3 aerosols Cat. 1 (Aerosol 1) H222,H229 3.3 serious eye damage/eye irritation Cat. 2 (Eye Irrit. 2) H319 3.8D specific target organ toxicity - single exposure (narcotic effects, drowsiness) Cat. 3 (STOT SE 3) H336 4.1C hazardous to the aquatic environ- ment - chronic hazard Cat. 2 (Aquatic Chronic 2) H411 Remarks For full text of H-phrases: see SECTION 16. Supplemental hazard information EUH066 Repeated exposure may cause skin dryness or cracking. The most important adverse physicochemical, human health and environmental effects Spillage and fire water can cause pollution of watercourses. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) Signal word Danger Pictograms GHS02, GHS07, GHS09 Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU OPN-Zinc Spray - zinc gray - Version number: 2.0 Revision: 31.01.2018 Date of compilation: 19.08.2015 (en) Page 1 / 13 Relevant identified uses professional use industrial use Long term protection for metallic surfaces Sector of use Uses advised against consumer use (private households) Do not use for products that are intended for contact with food - exclude food contact. Details of the supplier of the safety data sheet Fax: +49 (0) 2735 / 7725-90 Web: www.opn-chemie.de OPN-CHEMIE OTTO PETRI GMBH In der Au 14 D-57290 Neunkirchen/Germany Tel.: +49 (0) 2735 / 7725-0 E-Mail: [email protected]Further information obtainable from: Safety data sheets Mrs. Barbara Angelika Gros-Petri Tel.: +49 (0) 2735 / 7725-20 E-Mail: [email protected]24 hours Emergency telephone number: Vergiftungs-Informations-Zentrale Freiburg +49 (0) 761 / 192 40 Hazard statements H222 H229 H319 H336 H411 Extremely flammable aerosol. Pressurized container: may burst if heated. Causes serious eye irritation. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects.
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OPN-Zinc Spray - zinc gray€¦ · according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU OPN-Zinc Spray - zinc gray - Version number: 2.0 Revision: 31.01.2018
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SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1 Product identifier
Trade name OPN-Zinc Spray - zinc gray -Other means of identificationArticle number 63110Tariff No. 32081010
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.3
1.4
SECTION 2: Hazards identification2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Section Hazard class Category Hazard class and category Hazardstatement
OPN-CHEMIE OTTO PETRI GMBH In der Au 14D-57290 Neunkirchen/Germany Tel.: +49 (0) 2735 / 7725-0E-Mail: [email protected] information obtainable from:Safety data sheets Mrs. Barbara Angelika Gros-PetriTel.: +49 (0) 2735 / 7725-20 E-Mail: [email protected]
Extremely flammable aerosol.Pressurized container: may burst if heated.Causes serious eye irritation.May cause drowsiness or dizziness.Toxic to aquatic life with long lasting effects.
Precautionary statements
P102 Keep out of reach of children.P210P211P251P260P271P273
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source.Do not pierce or burn, even after use.Do not breathe vapours/spray.Use only outdoors or in a well-ventilated area. Avoid release to the environment.Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338P305+P351+P338 IF IN EYES: rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.
P410+P412P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.P501 Dispose of contents/container to hazardous or special waste.Additional labelling requirementsEUH066 Repeated exposure may cause skin dryness or cracking.
Hazardous ingredients for labelling: acetone
2.3 Other hazardsThere is no additional information.
SECTION 3: Composition/information on ingredients3.1 Substances not relevant (mixture)3.2 Mixtures
Description of the mixture Mixture of substances listed below with nonhazardous additions
Name of substance Identifier wt% Classification acc. to1272/2008/EC
3.3For full text of abbreviations: see SECTION 16.
SECTION 4: First aid measures4.1 Description of first aid measures
General notesDo not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take offimmediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousnessplace person in the recovery position. Never give anything by mouth.Following inhalationIf breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Provide fresh air.Following skin contactWash with plenty of soap and water.Following eye contactRemove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, hold-ing the eyelids apart.Following ingestionNot applicable, as aerosol.
4.2 Most important symptoms and effects, both acute and delayedNarcotic effects.
4.3 Indication of any immediate medical attention and special treatment needednone
Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
5.2 Special hazards arising from the substance or mixtureIn case of insufficient ventilation and/or in use, may form flammable/explosive vapour-air mixture.
5.3 Advice for firefightersDo not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Remove undamagedcans from the danger area. If necessary, cool by spraying with water because of bursting.Wear fully protective suit. Wear self-containedbreathing apparatus.
SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnelRemove persons to safety.For emergency respondersWear breathing apparatus if exposed to vapours/dust/spray/gases.
6.2 Environmental precautionsKeep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. If substance has entered a wa-ter course or sewer, inform the responsible authority.
6.3 Methods and material for containment and cleaning upAdvices on how to contain a spillCovering of drains.Other information relating to spills and releasesPlace in appropriate containers for disposal. Ventilate affected area.
SECTION 7: Handling and storage7.1 Precautions for safe handling
Recommendations• Measures to prevent fire as well as aerosol and dust generationKeep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Use only in well-ventilatedareas. Prevent from heating up above 50 °C.Advice on general occupational hygieneWash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before enter-ing eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for foodor drink. Keep away from food, drink and animal feedingstuffs.
7.2 Conditions for safe storage, including any incompatibilitiesManaging of associated risksStorage class (LGK)2B.• Flammability hazardsDo not spray on an open flame or other ignition source. Protect from sunlight.Incompatible substances or mixturesSeparate storage required for storage class: 4.1 A, 4.1 B, 4.2, 4.3, 5.1 A, 5.1 B, 5.2, 6.2, 7.Consideration of other advice• Packaging compatibilitiesOnly packagings which are approved (e.g. acc. to ADR) may be used.
Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
7.3 Specific end use(s)No further relevant information available.
SECTION 8: Exposure controls/personal protection8.1 Control parameters
National limit valuesOccupational exposure limit values (Workplace Exposure Limits)
Country
Name of agent CAS No Identifier TWA[ppm]
TWA[mg/m³]
STEL[ppm]
STEL[mg/m³]
Source
DE Butane 106-97-8 AGW 1.000 2.400 4.000 9.600 TRGS 900
DE Acetone 67-64-1 AGW 500 1.200 1.000 2.400 TRGS 900
DE Propane 74-98-6 AGW 1.000 1.800 4.000 7.200 TRGS 900
DE Zinc 7440-66-6 MAK 2 4 DFG
DE Zinc 7440-66-6 MAK 0,1 0,4 DFG
DE Isobutane 75-28-5 AGW 1.000 2.400 4.000 9.600 TRGS 900
EU Acetone 67-64-1 IOELV 500 1.210 2009/161/EU
NotationSTEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period
unless otherwise specifiedTWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-
weighted average
Biological limit values
Coun-try
Name of agent Parameter Nota-tion
Identifier Value Source
DE Acetone Acetone BLV 80 mg/l TRGS 903
Relevant DNELs/DMELs/PNECs and other threshold levels• relevant DNELs of components of the mixture
8.2 Exposure controlsAppropriate engineering controlsGeneral ventilation.Individual protection measures (personal protective equipment)Eye/face protectionBy designated use no eye protection necessary. Do not spray in eyes.Skin protectionBy designated use no hand protection necessary.• type of materialIIR: isobutene-isoprene (butyl) rubber• material thickness> 0,7 mm.
• other protection measuresTake recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash hands thor-oughly after handling.Respiratory protectionBy designated use no protection necessary. Apply outdoors or well ventilated areas.Environmental exposure controlsUse appropriate container to avoid environmental contamination.
SECTION 9: Physical and chemical properties9.1 Information on basic physical and chemical properties
AppearancePhysical state aerosol (spray aerosol)Colour greyOdour product specificOther physical and chemical parametersInitial boiling point and boiling range Not applicable, as aerosol.*Flash point Not applicable, as aerosol.*Evaporation rate Not determinedFlammability (solid, gas) Flammable aerosol in accordance with GHS criteriaExplosive limits• lower explosion limit (LEL) 3 vol%• upper explosion limit (UEL) 15 vol%Vapour pressure 3,8 bar at 20 °C
6,8 bar at 50 °CDensity 0,86 g/cm³ at 20 °C
Water solubility insolublen-octanol/water (log KOW) this information is not availableAuto-ignition temperature 287 °CViscosity not relevant (aerosol)Explosive properties noneOxidising properties none
Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
9.2 Other informationSolvent content 75,3 %* The finished mixture in an aerosol container is formed after addition of propellant. Several details are not measurable in an hermeticclosed, pressurized container.
SECTION 10: Stability and reactivity10.1 Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". risk of ignition10.2 Chemical stability
See below "Conditions to avoid".10.3 Possibility of hazardous reactions
No known hazardous reactions.10.4 Conditions to avoid
Do not spray on an open flame or other ignition source. - Keep away from heat.Hints to prevent fire or explosionProtect from sunlight.Physical stresses which might result in a hazardous situation and have to be avoidedhigh temperatures
10.5 Incompatible materialsoxidisers
10.6 Hazardous decomposition productsReasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazard-ous combustion products: see section 5.
SECTION 11: Toxicological information11.1 Information on toxicological effects
Test data are not available for the complete mixture.Classification procedureThe method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Classification according to GHS (1272/2008/EC, CLP)Acute toxicityShall not be classified as acutely toxic.Skin corrosion/irritationShall not be classified as corrosive/irritant to skin.Serious eye damage/eye irritationCauses serious eye irritation.Respiratory or skin sensitisationShall not be classified as a respiratory or skin sensitiser.Summary of evaluation of the CMR propertiesShall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.Specific target organ toxicity (STOT)• Specific target organ toxicity - single exposureMay cause drowsiness or dizziness.• Specific target organ toxicity - repeated exposureShall not be classified as a specific target organ toxicant (repeated exposure).Aspiration hazardShall not be classified as presenting an aspiration hazard.
Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
Other informationRepeated exposure may cause skin dryness or cracking.
SECTION 12: Ecological information12.1 Toxicity
Toxic to aquatic life.Wassergefährdungsklasse, WGK (water hazard class) (WGK; Germany): 2 (obviously hazardous to water)Aquatic toxicity (acute)Aquatic toxicity (acute) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposuretime
12.2 Persistence and degradabilityDegradability of components of the mixture
Name of substance CAS No Process Degradationrate
Time
Acetone 67-64-1 Carbon dioxide generation 90,9 % 28 d
Hydrocarbons, C9, aromatics 64742-95-6128601-23-0
Oxygen depletion 30,9 % 2 d
12.3 Bioaccumulative potentialData are not available.Bioaccumulative potential of components of the mixture
Name of substance CAS No BCF Log KOW BOD5/COD
Butane 106-97-8 1,09 (pH value: 7, 20 °C)
Acetone 67-64-1 -0,24
Propane 74-98-6 1,09 (pH value: 7, 20 °C)
Isobutane 75-28-5 1,09 (pH value: 7, 20 °C)
12.4 Mobility in soilData are not available.
12.5 Results of PBT and vPvB assessmentData are not available.
12.6 Other adverse effectsData are not available.Endocrine disrupting potentialThe mixture contains substance(s) with an endocrine disrupting potential.
LegendCAT2 Category 2 - at least some in vitro evidence of biological activity related to endocrine disruptionCAT3 Category 3 - no evidence of endocrine disruption or no data available
Sewage disposal-relevant informationDo not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.Waste treatment of containers/packagingsIt is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Completely emptied packages can be re-cycled. Handle contaminated packages in the same way as the substance itself.
13.2 Relevant provisions relating to wasteList of wastes15 01 04 Metallic packaging15 01 10 Packaging containing residues of or contaminated by dangerous substances16 05 04 Containing hazardous gases in pressure containers (including halons)
Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
13.3 RemarksPlease consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separatelyby the local or national waste management facilities.
SECTION 14: Transport information14.1 UN number 195014.2 UN proper shipping name AEROSOLS14.3 Transport hazard class(es)
Class 2 (gases) (aerosol)Subsidiary risk(s) 2.1 (flammability)
14.4 Packing group not assigned to a packing group14.5 Environmental hazards14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.14.8 Information for each of the UN Model Regulations
• Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)UN number 1950Proper shipping name AEROSOLSClass 2Classification code 5FDanger label(s) 2.1 + "fish and tree"
Special provisions (SP) 190, 327, 344, 625Excepted quantities (EQ) E0Limited quantities (LQ) 1 LTransport category (TC) 2Tunnel restriction code (TRC) D• International Maritime Dangerous Goods Code (IMDG)UN number 1950Proper shipping name AEROSOLSClass 2.1Danger label(s) 2.1 + "fish and tree"
• International Civil Aviation Organization (ICAO-IATA/DGR)UN number 1950Proper shipping name Aerosols, flammableClass 2.1Danger label(s) 2.1
Special provisions (SP) A145, A167Excepted quantities (EQ) E0Limited quantities (LQ) 30 kg
SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)• List of substances subject to authorisation (REACH, Annex XIV)None of the ingredients are listed.• Directive 75/324/EEC relating to aerosol dispensersClassification of the gas/aerosol Extremely flammableLabelling Pressurized container: may burst if heated
Keep out of the reach of childrenKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. NosmokingDo not pierce or burn, even after useProtect from sunlight. Do not expose to temperatures exceeding 50 °C
• Limitation of emissions of volatile organic compounds due to the use of organic solvents in certain paints and varnishesand vehicle refinishing products (2004/42/EC, Deco-Paint Directive)VOC content 75,3 %
Vehicle refinishing products Special finishes All types 840
• Directive on industrial emissions (VOCs, 2010/75/EU)VOC content 75,3 %• Regulation 166/2006/EC concerning the establishment of a European Pollutant Release and Transfer Register (PRTR)
Name of substance CAS No Re-marks
Threshold forreleases toair (kg/year)
Threshold forreleases to
water(kg/year)
Threshold forreleases to
land (kg/year)
Zinc 7440-66-6 (8) 200 100 100
Legend(8) All metals shall be reported as the total mass of the element in all chemical forms present in the release
National regulations (Germany)• Verordnung über Anlagen zum Umgang mit wassergefährdenden Stoffen (Ordinance on facilities for handling substanceshazardous to water) (AwSV)Wassergefährdungsklasse, WGK (waterhazard class)
2 (obviously hazardous to water)
Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
Notation3) A total mass flow of 0.50 kg/h or a total mass concentration of 50 mg/m³, each of which to be indicated as total carbon, shall
not be exceeded (except organic particulate matter)
• Storage of hazardous substances in non-stationary containers (TRGS 510) (Germany)Storage class (LGK): 2 B (aerosol dispensers and lighters)
15.2 Chemical Safety AssessmentChemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other informationAbbreviations and acronyms2009/161/EU. Comission Directive establishing a third list of indicative occupational exposure limit values in implementation of
Council Directive 98/24/EC and amending Commission Directive 2000/39/EC.ADN. Accord européen relatif au transport international des marchandises dangereuses par voies de navigation intérieures
(European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways).ADR. Accord européen relatif au transport international des marchandises dangereuses par route (European Agreement
concerning the International Carriage of Dangerous Goods by Road).AGW. Workplace exposure limit.Aquatic Acute. Hazardous to the aquatic environment - acute hazard.Aquatic Chronic. Hazardous to the aquatic environment - chronic hazard.Asp. Tox. Aspiration hazard.BCF. Bioconcentration factor.BOD. Biochemical Oxygen Demand.CAS. Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances).CLP. Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.CMR. Carcinogenic, Mutagenic or toxic for Reproduction.COD. Chemical oxygen demand.DFG. Deutsche Forschungsgemeinschaft MAK-und BAT-Werte-Liste, Senatskommission zur Prüfung
gesundheitsschädlicher Arbeitsstoffe, Wiley-VCH, Weinheim.DGR. Dangerous Goods Regulations (see IATA/DGR).DMEL. Derived Minimal Effect Level.DNEL. Derived No-Effect Level.EC No. The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identifier of
substances commercially available within the EU (European Union).EINECS. European Inventory of Existing Commercial Chemical Substances.ELINCS. European List of Notified Chemical Substances.EmS. Emergency Schedule.Eye Dam. Seriously damaging to the eye.Eye Irrit. Irritant to the eye.Flam. Gas. Flammable gas.Flam. Liq. Flammable liquid.GHS. "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations.IATA. International Air Transport Association.IATA/DGR. Dangerous Goods Regulations (DGR) for the air transport (IATA).ICAO. International Civil Aviation Organization.IMDG. International Maritime Dangerous Goods Code.IOELV. Indicative occupational exposure limit value.LGK. Lagerklasse (storage class according to TRGS 510, Germany).Log KOW. n-Octanol/water.MARPOL. International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant").NLP. No-Longer Polymer.PBT. Persistent, Bioaccumulative and Toxic.PNEC. Predicted No-Effect Concentration.Ppm. Parts per million.Press. Gas. Gas under pressure.REACH. Registration, Evaluation, Authorisation and Restriction of Chemicals.RID. Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations concerning
the International carriage of Dangerous goods by Rail).STEL. Short-term exposure limit.STOT SE. Specific target organ toxicity - single exposure.TRGS. Technische Regeln für GefahrStoffe (technical rules for hazardous substances, Germany).TRGS 900. Arbeitsplatzgrenzwerte (TRGS 900).TRGS 903. Biologische Grenzwerte (TRGS 903).TWA. Time-weighted average.VOC. Volatile Organic Compounds.VPvB. Very Persistent and very Bioaccumulative.
Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
Key literature references and sources for data- Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU- Regulation (EC) No. 1272/2008 (CLP, EU GHS)
Classification procedurePhysical and chemical properties: The classification is based on tested mixture.Health hazards: The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
List of relevant phrases (code and full text as stated in chapter 2 and 3)H220. Extremely flammable gas.H222. Extremely flammable aerosol.H225. Highly flammable liquid and vapour.H226. Flammable liquid and vapour.H229. Pressurized container: may burst if heated.H280. Contains gas under pressure; may explode if heated.H304. May be fatal if swallowed and enters airways.H319. Causes serious eye irritation.H335. May cause respiratory irritation.H336. May cause drowsiness or dizziness.H400. Very toxic to aquatic life.H410. Very toxic to aquatic life with long lasting effects.H411. Toxic to aquatic life with long lasting effects.
DisclaimerThis information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.
Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU