S1 Supporting Information for On the bromination of the dihydroazulene/vinylheptafulvene photo-/thermoswitch Virginia Mazzanti 1,2 , Martina Cacciarini 1,3 , Søren Lindbæk Broman 1 , Christian R. Parker 1 , Magnus Schau-Magnussen 1 , Andrew D. Bond 4 and Mogens Brøndsted Nielsen 1* Address: 1 Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark, 2 Sino-Danish Center for Education and Research (SDC), Niels Jensens Vej 2, DK-8000 Aarhus C, Denmark 3 Department of Chemistry, University of Florence, via della Lastruccia 3-13, I-50019, Sesto F.no, Italy and 4 Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, DK-5230 Odense M, Denmark Email: Mogens Brøndsted Nielsen - [email protected]*Corresponding author 1D and 2D NMR spectra of all new compounds. Table of bond lengths for VHF 2 (X-ray crystallographic data). Exponential fit of the decay over time of the VHF 7 absorbance at the longest-wavelength absorption maximum. Content NMR spectra of compounds 8, 10, 12, 14, 15, 17, 19, 22 ................................................................. S2 X-ray crystallographic data for VHF 2 ............................................................................................ S14 UV–vis absorption spectra of DHA 8 and VHF 7 ........................................................................... S15
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S1
Supporting Information
for
On the bromination of the dihydroazulene/vinylheptafulvene
photo-/thermoswitch
Virginia Mazzanti1,2
, Martina Cacciarini1,3
, Søren Lindbæk Broman1, Christian R. Parker
1, Magnus
Schau-Magnussen1, Andrew D. Bond
4 and Mogens Brøndsted Nielsen
1*
Address: 1
Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100
Copenhagen Ø, Denmark, 2Sino-Danish Center for Education and Research (SDC), Niels Jensens
Vej 2, DK-8000 Aarhus C, Denmark 3Department of Chemistry, University of Florence, via della
Lastruccia 3-13, I-50019, Sesto F.no, Italy and 4Department of Physics, Chemistry and Pharmacy,
University of Southern Denmark, Campusvej 55, DK-5230 Odense M, Denmark