O,ij!,.?.'iil - Welcome to NewMexico.gov Refinery - Gallup...1994/02/15 · February 15, 1994 Benito Garcia Bureau Chief FEB 2 1 1994 Hazardous and Radioactive Materials Bureau New

February 15, 1994

Benito Garcia Bureau Chief

FEB 2 1 1994

Hazardous and Radioactive Materials Bureau New Mexico Environment Department 525 camino De Los Marquez SUite 4 Santa Fe, New Mexico 87502

Re: Annual Groundwater Report Giant Refining Company - Ciniza Perrrdt No. NMD000333211-2

Dear Mr. Garcia:

O,ij!,.?.'iil INDUSTRIES, INC.

Route 3, Box 7 Gallup, New Mexico 87301

FEB/.. I 1994

As required by the indicated perrrdt, the Annual Grotmdwater Report is enclosed. The report is or9anized as follows:

Sectim I Sectim II Sectim III Sectim IV Sectim V Sectim VI Sectim VII

Well Identificatim Report statistical Analysis Gromdwater MeasurEIIEilt Gromdwater Velocity Groundwater Elevatim cmtour Map Tabulated Analytical Data Ori9inal Analytical Data

The statistical analysis on the Sli series wells indicates that chraniun has exceeded the tolerance limit in f:ltol-3, f:ltol-4, and f:ltol-6.

If you desire additional infonmation, please contact me at (505) 722-0227.

Lynn Shel tan Senior Environmental Coordinator

TLS:sp

cc: Kim Bullerdick, Corporate Counsel, Giant Industries Arizona, Inc. David Pavlich, Mana.9er Health/Safety and Environment R09er Anderson, New Mexico Oil Conservation Division

GIANT REFINING COMPANY CINIZA

AlfflUAL GROUNDWATER REPORT 1-9-9-3

(!()PV

dill

'""

"' I. 'iil!l

II.

'"' III.

, .. IV.

,,,,. v. ''0 VI.

"" VII.

'" ..

ANNUAL GROUNDWATER REPORT

TABLE OF CONTENTS

Well Identification Report

Statistical Analysis

Groundwater Measurements

Groundwater Velocity

Groundwater Elevation Contour Map

Tabulated Analytical Data

Original Analytical Data

February 14, 1994

Prepared By:

Lynn Shelton Senior Environmental Coordinator

Giant Refining Company Ciniza

'•

...

MONITORING WELL IDENTIFICATION REPORT

ENVIRONMENTAL IMPROVEMENT DIVISION HAZARDOUS WASTE SECTION 1190 ST. FRANCIS DRIVE/HAROLD RUNNELS BLDG. SANTA FE, NEW MEXICO 87503

FACILITY NAME Giant Refining Company - Ciniza

EPA I.D. NUMBER NMD000333211-2 ------------------------------------------COUNTY McKinley

--------~----------------------------

WELL NUMBER MW-1 --------------------------------------WELL LOCATION (LONGITUDE) 108° 25' 36"

WELL LOCATION (LATITUDE) 35° 29 I 08 11

NEW MEXICO STATE PLANE (X) 320, 903.76

(Y) 1,636,112.13

AQUIFER NAME Sonsela

AQUIFER CONFINED X UNCONFINED ----

WELL INSTALLATION DATE 10-14-81

DRILLING METHOD Cable

INNER CASING DIAMETER 5.0"

BOREHOLE DIAMETER 10.0"

CASING MATERIAL PVC

METHOD OF DEVELOPMENT Compr

ELEV BOTTOM OF BOREHOLE 6745.80

ELEV BOTTOM OF WELL CASING 6745.80

ELEV BOTTOM OF SCREENED INT 6750.80

ELEVATION OF SCREENED INT 6760.80

SURVEYED ELEV OF CASING TOP 6878.52

DATE OF REPORT 2-14-94 SIGNATURE

NAME (TYPED) Lynn Shelton

,:,..

"'




EPA I.D. NUMBER _____ N_M_D_0_0_0_3~3_3_2_1~1_-=2 ______________________ __

COUNTY McKinley

WELL NUMBER MW-2

WELL LOCATION (LONGITUDE)

WELL LOCATION (LATITUDE)

NEW MEXICO STATE PLANE (X)

(Y)

108° 26' 00"

35° 29 I 43 11

321,035.35

1,636,184.06


AQUIFER CONFINED X

WELL INSTALLATION DATE

DRILLING METHOD

INNER CASING DIAMETER

BOREHOLE DIAMETER

CASING MATERIAL

METHOD OF DEVELOPMENT

ELEV BOTTOM OF BOREHOLE

ELEV BOTTOM OF WELL CASING

ELEV BOTTOM OF SCREENED INT

ELEVATION OF SCREENED INT

SURVEYED ELEV OF CASING TOP

DATE OF REPORT 2-14-94

UNCONFINED

10-15-81

Cable

5.0"

10.0"

PVC

Compr

6741.90

6741.90

6747.90 --------------------------

6757.90

6880.84

SIGNATURE ~ ~ NAME (TYPED) Lynn Shelton

,,

-,dJ

->111'




EPA I.D. NUMBER NMD000333211-2

COUNTY McKinley

WELL NUMBER MW-4




(Y)

108° 26' 54"

35° 29 I 30 11

321,602.07

1,635,066.25

AQUIFER NAME Sonse1a

AQUIFER CONFINED X UNCONFINED





CASING MATERIAL PVC





----

--------------------------




-------------------------

SIGNATURE ~~ J!-~ NAME (TYPED) Lynn Shelton




EPA I. D. NUMBER NMD000333211-2

COUNTY McKinley

WELL NUMBER MW-5




(Y)


AQUIFER CONFINED X


DRILLING METHOD


BOREHOLE DIAMETER

CASING MATERIAL








108° 25' 57"

35° 29 I 43 11

321,233.03

1,636,212.58

UNCONFINED

7-29-86

HLWAG & AIRRT

4.0"

10.0"

PVC

Compr

6746.80

6753.30

6758.30

6768.80

6883.32

SIGNATURE ~~ NAME (TYPED) Lynn Shelton





COUNTY McKinley

WELL NUMBER OW-11




(Y)


AQUIFER CONFINED X

108° 25 I 36 11

35° 29' 08"

323,167,68

1,632,185.21

UNCONFINED ----------------





CASING MATERIAL PVC


ELEV BOTTOM OF BOREHOLE 6773.

ELEV BOTTOM OF WELL CASING 6773.

ELEV BOTTOM OF SCREENED INT 6858.

ELEVATION OF SCREENED INT 6880.

----------------------------



6923.89

SIGNATURE ~~ NAME (TYPED) Lynn Shelton

...





COUNTY McKinley

WELL NUMBER SMW-1



NEW MEXICO STATE PLANE (X) 321 501.32

(Y) 501.43

AQUIFER NAME Ciniza Sand

AQUIFER CONFINED X


DRILLING METHOD


BOREHOLE DIAMETER

CASING MATERIAL








UNCONFINED ----

10-4-85

HWLAG

2.0"

6.5"

SS304

Compr

6832.73

6834.23

6837.23 --------------------------

6857.23

6883.29

SIGNATURE ~~ ~ NAME (TYPED) Lynn Shelton

-





COUNTY McKinley

WELL NUMBER SMW-2



NEW MEXICO STATE PLANE (X) 321....542,80

(Y) 1 635 592.65


AQUIFER CONFINED X UNCONFINED ---------------- ----


DRILLING METHOD HLWAG



CASING MATERIAL SS304




ELEV BOTTOM OF SCREENED INT 6830.13 ---------------------

ELEVATION OF SCREENED INT __________ 6_8_5_0_._1_3 _________ _



6884.44

SIGNATURE ~ J-~ NAME (TYPED) Lynn Shelton

'"





COUNTY McKinley

WELL NUMBER SMW-3

WELL LOCATION (LONGITUDE) 108° 25' 56"

WELL LOCATION (LATITUDE) 35° 29' 40"

NEW MEXICO STATE PLANE (X) 321,397.90

(Y) 1,635,948.75


AQUIFER CONFINED ______ X ________ __ UNCONFINED ------









ELEV BOTTOM OF SCREENED INT 6841.65 -------------------------

ELEVATION OF SCREENED INT 6861.65 ---------------------------



6884.56

SIGNATURE ~ ~ NAME (TYPED) Lynn Shelton





COUNTY McKinley

WELL NUMBER SMW-4




(Y)

108° 26 I 01 II

35° 29' 44"

320,974.85

1,636,153.54








METHOD OF DEVELOPMENT Cornpr







NAME (TYPED) ____ L~y_n_n __ S_h_e_l_t_o_n __ _





COUNTY McKinley

WELL NUMBER SMW-5




(Y)

108° 26' 03"

35° 29' 41"

320,778.61

1,636,054.28


AQUIFER CONFINED ____ x ____________ UNCONFINED












DATE OF REPORT 2-14-94 SIGNATURE

NAME (TYPED) ____ L_y_n_n __ S_h_e_l_t_o_n __ __

,,.

'""'



FACILITY NAME Giant Refining Company


COUNTY McKinley

WELL NUMBER SMW-6

WELL LOCATION (LONGITUDE) 108° 26'

WELL LOCATION (LATITUDE) 35° 29'

NEW MEXICO STATE PLANE (X) 320,839.52

- Ciniza

02"

38"

(Y) 1,635,867.66











ELEV BOTTOM OF SCREENED INT 6810.55 --------------------------

ELEVATION OF SCREENED INT 6830.55 ----------------------------

SURVEYED ELEV OF CASING TOP 6880. 71

DATE OF REPORT 2-14-94 SIGNATURE ~ ~ NAME (TYPED) Lynn Shelton

-

-

-

....

""

Calculation Sheet for Semi-Annual Evaluation of Indicator Parameters

Print Your Name: Lynn Shelton Telephone:(505) 722-0227

EPA ID #: NMD000333211-2 Facility Name: GIANT CINIZA

Date: Spring, 93 Parameter:: pH

Well Number: MW-1 Up or Downgradient:: DOWN

Please list the values calculated for the background parameters on the Background Indicator Parameter Calculation Sheet:

Please list the current values for this monitoring well.

Value

1 1.__ __ 8._84--'l

2 L_l ------'--'8.~81~1

3 L_l __ 8_.8--'l

41 '--_ _____::_:_8 . ...::...J8l

(Value - X(m))2

0.0056251

0.0020251

0.0012251

0.0012251

lx&tat1•••••••·•••••< 35.25I1"P:tal2••••••·<>••••· o.o1o1 I

• t{~)=#: 7.1716161

t(9.}~ 4.3160581

If t(*) absolute is less than t(c) there has not been an increase in the value



Facility Name: GIANT CINIZA EPA ID #: NMD000333211-2


Well Number: MW-2 Up or Downgradient:: DOWN



Value

1 1~__ __ 8_. 7__,9\

2 '--' __ 8_.8___J\

3\ '--__ 8._83-----'\

4 .__I __ 8_.8___J\

1 n : tt~l¥¥ 7.so3o99\

~ . n tf&l$ 4.085878\

(Value - X(m))2

0.000625\

0.001225\

0.004225\

0.001225\

0.0073\


...

-''"'

....


Print Your Name:

Facility Name:

Date: Spring, 93

Well Number:

Lynn Shelton

GIANT CINIZA

MW-4

Telephone:(505) 722-0227

EPA ID #: NMD000333211-2

Parameter:: pH

Up or Downgradient: UP



Value

1 ''---------' 2\,__ __ ___.

8.44\

8.42\

3\ L_ -------'

4\ '--------'

8.49\

< 8.48\

I! ,;,,;;~<~)¥:# -0.29019\

It t(cl# 5. 7581 osl

(Value - X(m))2

0.105625\

0.119025\

0.075625\

t 0.081225\

If t(*) absolute isles's than t(c) there has not been an increase in the value

~ sfLLSiirl~


Print Your Name: Lynn Shelton Telephone :(505) 722-0227



Well Number: MW-5 Up or Downgradient: : DOWN


Please list the currentvalues for this monitoring well.

Value

11.__ __ ___,

2 .__I __ ___,

8.821

8.721

8.821

(Value - X(m))2

0.0030251

0.0020251

0.0030251 3 .__I -----'

4 '--1. -----' 8.951 0.0342251

). t{~).i§ 4. 7528551

=: tCcli# 5.2330161

0.04231


....

..


Print Your Name:

Facility Name:

Date: Spring 93

Well Number:

Lynn Shelt~n

GIANT CINIZA

MW-1

Telephone:(505) 722-0227

EPA ID #: NMD000333211-2

Parameter:: SPEC. COND.

Up or Downgradient: : DOWN



Value

11 .__ __ 1_1_1 o__.l

2lc____1_1_6___,o I

31 115o I L--------'

4lc_ __ 1_1_50---'l

:: ·t.I');s 4.0682oo I 1::::::.;;:; ~(9)$5 4.4222821

(Value - X(m))2

9001

64001

49001

49001

171001

4.5411 . 1425

If t(*) is negative there has not been an increase in the ·value

Signature

-

-

'"'

-




Date: Spring 93 Parameter:: SPEC. COND.




Value

1 '--I __ 1_1_5o__,l

2 '--1 __ 1_1_60__,1

31 '--__ 1_1_80__,1

41 '---__ 1_1_70__,1·

(Value - X(m))2

49001

64001

100001

81001

294001

!·.· .. ·.·.··.·.· ...... ······ ....... . . i~~~ 4.541!

2450

1• • t<~l~ 3.5893081 If t(*) is negative there has not been an increase in the value

I< t.(cl¥= 4.4701341

,.,.

..





Well Number: MW-4 Up or Downgradient:



Value

1 '-1 __ 1_2_40__.1

2l.____1_2_o__,o I

3l.____1_2_o__,o I

4 '-1 __ 1_2_o__,o I

1' c:tt~l$ 2.9608271

I : : tl9l¥= 4.51oo7o I

(Value - X(m))2

256001

144001

144001

144001

688001

If t(*) is negative there has not been an increase in the value

Signature

UP








Value

1 .__I __ 1_0_9---.JO I

21 '--__ 1_1_40__,1

3 .__I __ 1_1_4o__,l

4 .__I __ 1_1_7o__,l

I' :, tf~l¥# 4.o7o286l

t(ili# 4.4100621

(Value - X(m))2

1001

36001

36001

81001

154001

If t(*) is negative there has not been an increase in the value

Signature

..

....

.,.


Print Your Name: Lynn Shelton Telephone 722-0227


Date: Fall,1993 Parameter: : pH




Value

1 9.051

91 2IL_ _ __:_J

3 L_l __ _J

4 L_l __ _J

9.081

9.081

(Value - X(m))2

1 o.o81225 1

1 o.o55225 1

1 o.o99225 1

1 o.o99225 1

36.21 lffi9t?C?/ il 0.3349 I

1: 'i/ttrl§ l3.194171 1

p:j:::: /t<¢l#'l5.746943 1


Signature

DOWN








Value

1 9.091

2 ._I --=--;_:___j

3 IL_ _ __:____J

9.081

9.1 1

9.071 4 L_l _...:.._:___J

(Value - X(m))2

1 o.1o5625 1

1 o.o99225 1

1 o.112225 1

1 o.o93o25 1

36.34 lit?t?L? ·j 0.4101 I

I : nt<t>¥=13.068576 I

l=m::::: ::J<9l¥ l 5. 763730 1


4---- SLf;t;;__

DOWN








Value

8.821

2 11__---=..;_,;:_;;__J

3 IL_ _ __::_:_::.......J

41 L_ _ __::_:_::.......J

8.831

8.8 1

8.8 1

(Value - X(m))2

1 o.oo3o25 1

1 o.oo4225 1

1 o.oo1225 1

1 o.oo1225 1

35.25 l±mar.e:. u l o.oo97 1

l::''::::m::m:::ttrl¥!7.239756 1

r::@m::::::::mJ<¢l#i.:J4.286942 I


Signature

UP

'"

,.,



Facility Name: GIANT CINIZA EPA 10 #: NMD000333211-2





Value

1 8.961

2 I.__ _ ___,

31..._ __ __,

4..._1 __ __,

8.961

91

8.971

(Value - X(m))2

1 o.o38025 1

1 o.o38025 1

1 o.o55225 1

1 o.o42025 1

35.89 l+9ttt.t2 ?l o.1733 1

lr > t<t>#HI3.7294s4 1

f'f: t(¢>f:l5.664584 I

If t(") absolute is less than t(c) there has not been an increase in the value

Signature

DOWN


Print Your Name: Lynn Shelton Telephol)e 722-0227

Facility Name: GIANT CINIZA EPA 10 #: NMD000333211-2

Date: Fall1993 Parameter:: SPEC. COND.




1

l'·t ::::itU¥:1 9.8118os I

l::::::m::::!IUt¢)§:::1 2.797424 I

Value (Value - X(m))2

1o9o I 1oo I

1o8o I o I

1o8o I o I

1 085 I lc______2_s__.l


""'

""' c<if

"' c'l#

'"'



Facility Name: GIANT CINIZA EPA ID#: NMD000333211-2





1

1:::':'% ::::tttl¥17.688292 I

!=:=::::m=::::::::m:=tt¢.l~¥:! 3. 714130 1

Value

11oo I

1110 I

1o9o I

1o9o I

(Value - X(m))2

4oo I

9oo I

1oo I

1oo I

1500 l


Signature

:DOWN








Value

1 114o I

2 ._I __ 1_13_o_JI

31 11301

41 11501

(Value - X(m))2

3soo I

25oo 1

25oo 1

49oo I

455o lx91~H? >I 135oo I

I? : n=«M¥=14.398411 I

1: :::': :Jc9lffi:'l 4.39304o 1


Signature

UP

'"

'"'

" ~

~ .. ,,

"

,,



Facility Name: GIANT CINIZA EPA ID#: NMD000333211-2





1

I t<11¥ l 5.168999 I

I :: :j((;J§ l4.289995 1

Value

1110 I

113o I

1120 I

113o 1

(Value - X(m))2

9oo I

25oo I

16oo I

25oo I

75oo I

If t(") absolute is less than t(c) there has not been an increase in the value

~ SLM ~ure

:DOWN

_,......... (I)

-o (/) c 1- 0 - (I) z :J :::> 0

...c 1-'-./

1.5

1.4

1.3

1.2

1 .1

0.9

0.8

t' ~ r 1 r " " '!'

MW-1 EC

=-

22 APR 92 22 OCT 92 28 APR 93 29 OCT 93

DATE

, t f ' r 1 f ' f 1 ~ ~ f 1 ' 1 r ~ f tt r 'I''''

UN

ITS

~

0)

'-.I

CX

l tD

--

-'

0)

0

"' N

N

)>

lJ

~kf

:;:o

tD

N

.~ '"' ~

N

N

""" 0 0 -l

~

tD

... N

~

"' 0

I )>

-l

41

fTl

~

"' u

N

I '""

CXl

)>

'""' lJ

:;:

o

"' tD

lN

... ... N

tD

0 ...

0 -l

tD

lN

'" "' '""' """' ... '" ·•

~ '

r-.... (f)

"'0 (j) c 1- 0 - (f) z :J ::J 0

~

..c I-'-"

' r '!

1.5

1.4

1 .3

1.2

1 . 1

0.9

0.8 22 APR 92

' f l "! • •

MW-2 EC

22 OCT 92 28 APR 93 29 OCT 93

DATE

• '1\ •· ~ • • .. '! • ' ~ .. .. l! t! '!! f ' r l

f ~

if) 1-z ::>

' ~ ~

12

1 1

10

9

8

7

6 22 APR 92

"

MW-2 pH

22 OCT 92 28 APR 93 29 OCT 93

DATE

' 1 ~ r" ~' r l r 1 '$ r " r 'I t r '

'

_,........ (1)

"'0 (f) c 1- 0 - (1) z ::J ::J 0

..c c

' ~ f ~

1.5

1.4

1.3

1.2

1 . 1

0.9

0.8 22 APR 92

" ·~ f l • ' • '

MW-4 EC

22 OCT 92 28 APR 93 29 OCT 93

DATE

f ' .. ~ r l ,

' f 1! f ,. . '" f ~ ~ ~ f 1! ! ·~ f ,

... ''"' "' '"' '"' "' " ,,_,.

"'I

oi.!)i

ili '" -~- "' """' ,,. ;'!

lj

0 )>

--l

fTl

r-v

r-v

)>

LJ

:::0

~

r-v

r-v

r-v

0 0 --l

~

r-v

r-v

CX)

)>

LJ

:::0

~

GJ r-v ~

0 0 -1

~

GJ

UN

ITS

~ ~ I ~

u I

,. "

,...... (f)

1J (/) c f- 0 - (f) z :J :::> 0

~

..c f-'-../

l ~

1.5

1.4

1.3

1.2

1 .1

0.9

0.8 22 APR 92

1 '!! ~

' f t

MW-5 EC

22 OCT 92 28 APR 93 29 OCT 93

DATE

v 1 r ' ' J ~ l f 1 ~ ~ ! f ,

f ' f ' ~ 1

~

(/)

!::: z :J

~

10

9.5

9

8.5

8

7.5

7

6.5

6 06 MAR 91

~

MW-5 pH

24 SEP 91 22 APR 92 22 OCT 92 28 APR 93

DATE

'!l ~ l fl 't f 1 ,, ~ ' ' ! '!' ' t ~ '

,......... fl)

1J (f) c 1- [J - fl) z :J :J 0

.c 1-'-../

l! '!I f 1

2.5

2.4

2.3

2.2

2.1

2

1.9

1.8

1.7

1 .6

1.5

1.4

1 .3

1.2

1 . 1

0.9

0.8

!'

OW-11 EC

22 APR 92 22 OCT 92 28 APR 93 29 OCT 93

DATE

~ 1 l 11 ~ ~ l T ~ ' ~ l f ' f "' '

UN

ITS

,.

(})

-..._J

(X

) \.

0 _

.

(})

0

N

N

)>

IJ

;o

tD

N

,,t<Ji

N

N

""' 0 0

0 -l

,. :E

tD

N

"""

I '·~

0 )>

~

-l

4 fT

l ~

"" N

u

V•c/l

i! (X

) I

)>

~

IJ

;o

·.4!1

tD

<.M

TOLERANCE INTERVAL

SMW-3

SMW-4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

MEANMEAN-

RESULT 0.0025 0.0025

MEANMEAN-

RESULT 0.0025 0.0025

MEANMEAN-

RESULT

0.0025 0.0025

MEANMEAN-

RESULT 0.0025 0.0025

* 1/2 of Reporting Limit.

* *

* *

* *

* *

1993

LEAD

0.0016 0.0017

TOL LIMIT 0.005 0.005

0.0018 0.0018

TOL LIMIT 0.005 0.005

0.0015 0.002

TOL LIMIT 0.005 0.005

0.0015 0.002

TOL LIMIT 0.005 0.005

SD SD

UNITS ppm ppm

SD SD

UNITS ppm ppm

SD SD

UNITS ppm ppm

so so

UNITS ppm ppm

0.0017 0.0017

Does not exceed the tolerance limit.


0.0016 0.0015



0.0017 0.0016



0.0017 0.0016



I I

I I

I I

I I

..

TOLERANCE INTERVAL

SMW-3

SMW-4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

MEANMEAN-

RESULT 0.012 0.005

MEANMEAN-

RESULT

D 0.014

.011 0.005

MEANMEAN-

RESULT 0.012 0.005

MEANMEAN-

RESULT 0.02

0.005

* 1/2 of reporting limit.

*

*

*

*

CHROME

0.003 0.0036

TOL LIMIT 0.011 0.011

0.0044 0.005

TOL LIMIT 0.012 0.012 0.012

0.0032 0.0034

TOL LIMIT 0.018 0.012

0.0035 0.004

TOL LIMIT 0.015 0.015

SD SD

UNITS ppm ppm

SD SD

UNITS ppm ppm ppm

SD so

UNITS ppm ppm

SD SD

UNITS ppm ppm

0.004 0.0038

Exceeds the tolerance limit by 9.1 %. Exceeds the tolerance limit by 9.1 %.

0.0039 0.0037

Exceeds the tolerance limit by 16.7%. Does not exceed the tolerance limit.


0.0038 0.0036



0.0059 0.0057

Exceeds the tolerance limit by 33.3%.


I I

I I

I I

,,,

SMW-3

SMW-4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

MEANMEAN-

RESULT 7.9

7.69

MEANMEAN-

RESULT 8.2 8.5

MEANMEAN-

RESULT 8.5

8.74

MEANMEAN-

RESULT 8.2

8.09

TOLERANCE INTERVAL

7.86 7.84

TOL LIMIT 8.163 8.145

8.309 8.330

TOL LIMIT 8.639 8.663

8.425 8.450

TOL LIMIT 9.106 9.124

8.075 8.080

TOL LIMIT 8.657 8.635

pH

so so

UNITS ------

so so

UNITS ------

so so

UNITS ------

so so

UNITS ------

0.1517 0.1524



0.1649 0.1665



0.3405 0.3372



0.2908 0.2773



l I

I I

I I

I I

SMW-3

SMW--4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

TOLERANCE INTERVAL

MEANMEAN-

RESULT 3170

3222.5

MEANMEAN-

RESULT 1300 1270

MEANMEAN-

RESULT 1130 1145

MEANMEAN-

RESULT 1300

1667.5

3226.13 3225.72

TOL LIMIT 3930.430 3889.740

1225 1229.090

TOL LIMIT 1440.960 1436.612

1134.3 1135.270

TOL LIMIT 1305.740 1298.842

1527.5 1540.230

TOL LIMIT 1980.760 1979.830

EC

SD SD

UNITS ------

SD SD

UNITS ------

SD SD

UNITS

------

SD SD

UNITS

------

352.15 332.0105

Does not exceed the tolerance limit. Does not exceed the tolerance limit.

107.98 103.7604


85.72 81.7859



226.63 219.8022


I I

I I

I I

I I

SMW-3

SMW-4

SMW-5

SMW-6

-

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

MEANMEAN-

RESULT 56.75 56.25

MEANMEAN-

RESULT 56.75

56

MEANMEAN-

RESULT 56.5 56.5

MEANMEAN-

TOLERANCE INTERVAL

TEMPERATURE

55 55.16

TOL LIMIT 60.240 60.128

55.5 55.560

TOL LIMIT 61.476 61.160

54.786 55.000

TOL LIMIT 60.490 60.454

54.929 55.030

so so

UNITS degrees degrees

so so


so so


so so

2.619 2.4841


2.988 2.8


2.852 2.7272


3.469 3.2559

I I

I I

I I

411::

'

SMW-3

SMW-4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

TOLERANCE INTERVAL

MEANMEAN-

RESULT 6846.24 6852.43

MEANMEAN-

RESULT 6851.67 6848.99

MEANMEAN-

RESULT 6847.02 6846.98

MEANMEAN-

RESULT 6848.9

6849.01

WATER LEVEL

6850.84 6851.04

TOL LIMIT 6855.000 6855.066

6848.63 6848.670

TOL LIMIT 6851.866 6851.522

6847.23 6847.200

TOL LIMIT 6849.75

6849.563

6856.64 6853.190

TOL LIMIT 6866.7

6863.408

SD SD

UNITS feet feet

SD SD

UNITS feet feet

SD SD

UNITS feet feet

SD SD

UNITS feet teet

2.08 2.0128


1.52 1.4261


1.26 1.1817


5.03 5.1092


I I

I I

I I

I I

,.,

'"' ,.,

.. • -

'ill

TOLERANCE INTERVAL

SMW-3

SMW-4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

MEANMEAN-

RESULT 0.0025 0.0025

MEANMEAN-

RESULT 0.0025 0.0025

MEANMEAN-

RESULT 0.0025 0.0025

MEANMEAN-

RESULT 0.0025 0.0025

* 1/2 of Reporting Limit.

* *

* *

* *

* *

1993

LEAD

0.0016 0.0017

TOL LIMIT 0.005 0.005

0.0018 0.0018

TOL LIMIT 0.005 0.005

0.0015 0.002

TOL LIMIT 0.005 0.005

0.0015 0.002

TOL LIMIT 0.005 0.005

so SD

UNITS ppm ppm

SD so

UNITS ppm ppm

SD SD

UNITS ppm ppm

SD so

UNITS ppm ppm

0.0017 0.0017


0.0016 0.0015


0.0017 0.0016


0.0017 0.0016


I I

I I

I I

I I

'"'~

TOLERANCE INTERVAL

SMW-3

SMW-4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

MEANMEAN-

RESULT 0.012 0.005

MEANMEAN-

RESULT 0.014

D .011 0.005

MEANMEAN-

RESULT 0.012 0.005

MEANMEAN-

RESULT 0.02

0.005

1/2 of reporting limit.

*

*

*

*

CHROME

0.003 0.0036

TOL LIMIT 0.011 0.011

0.0044 0.005

TOL LIMIT 0.012 0.012 0.012

0.0032 0.0034

TOL LIMIT 0.018 0.012

0.0035 0.004

TOL LIMIT 0.015 0.015

SD SD

UNITS ppm ppm

SD SD

UNITS ppm ppm ppm

SD SD

UNITS ppm ppm

SD SD

UNITS ppm ppm

0.004 0.0038

Exceeds the tolerance limit by 9.1 %. Exceeds the tolerance limit by 9.1 %.

0.0039 0.0037

Exceeds the tolerance limit by 16.7%. Does not exceed the tolerance limit. Does not exceed the tolerance limit.

0.0038 0.0036


0.0059 0.0057

Exceeds the tolerance limit by 33.3%. Does not exceed the tolerance limit.

I J

I I

I I

-

SMW-3

SMW-4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

TOLERANCE INTERVAL

MEANMEAN-

RESULT 7.9

7.69

MEANMEAN-

RESULT 8.2 8.5

MEANMEAN-

RESULT 8.5

8.74

MEANMEAN-

RESULT 8.2

8.09

7.86 7.84

TOL LIMIT 8.163 8.145

8.309 8.330

TOL LIMIT 8.639 8.663

8.425 8.450

TOL LIMIT 9.106 9.124

8.075 8.080

TOL LIMIT 8.657 8.635

pH

so so

UNITS ------

so so

UNITS ------

so so

UNITS ------

so so

UNITS

------

0.1517 0.1524


0.1649 0.1665


0.3405 0.3372


0.2908 0.2773


I I

I I

I I

I I

SMW-3

SMW-4

SMW-5

SMW-6

'"

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

TOLERANCE INTERVAL

MEANMEAN-

RESULT 3170

3222.5

MEANMEAN-

RESULT 1300 1270

MEANMEAN-

RESULT 1130 1145

MEANMEAN-

RESULT 1300

1667.5

3226.13 3225.72

TOL LIMIT 3930.430 3889.740

1225 1229.090

TOL LIMIT 1440.960 1436.612

1134.3 1135.270

TOL LIMIT 1305.740 1298.842

1527.5 1540.230

TOL LIMIT 1980.760 1979.830

EC

so so

UNITS ------

so so

UNITS ------

so so

UNITS ------

so so

UNITS ------

352.15 332.0105


107.98 103.7604


85.72 81.7859


226.63 219.8022


I I

I I

I I

I I

SMW-3

SMW-4

SMW-5

SMW-6

..

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

MEANMEAN-

RESULT 56.75 56.25

MEANMEAN-

RESULT 56.75

56

MEANMEAN-

RESULT 56.5 56.5

MEANMEAN-

TOLERANCE INTERVAL

TEMPERATURE

55 55.16

TOL LIMIT 60.240 60.128

55.5 55.560

TOL LIMIT 61.476 61.160

54.786 55.000

TOL LIMIT 60.490 60.454

54.929 55.030

SD SD


SD SD


SD SD


SD SD

2.619 2.4841


2.988 2.8


2.852 2.7272


3.469 3.2559

I I

I

I

SMW-3

SMW-4

SMW-5

SMW-6

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

4-93 11-93

DATE 4-93 11-93

MEANMEAN-

RESULT 6846.24 6852.43

MEANMEAN-

RESULT 6851.67 6848.99

MEANMEAN-

RESULT 6847.02 6846.98

MEANMEAN-

RESULT 6848.9

6849.01

TOLERANCE INTERVAL

WATER LEVEL

6850.84 6851.04

TOL LIMIT 6855.000 6855.066

6848.63 6848.670

TOLLIMIT 6851.866 6851.522

6847.23 6847.200

TOL LIMIT 6849.75

6849.563

6856.64 6853.190

TOL LIMIT 6866.7

6863.408

so so

UNITS feet feet

so so

UNITS feet feet

SD SD

UNITS feet feet

SD SD

UNITS feet feet

2.08 2.0128


1.52 1.4261


1.26 1.1817


5.03 5.1092


I I

I I

I I

I I

..

GIANT REFINING CO.-CINIZA

ANNUAL GROUNDWATER MEASUREMENT

MW¥1 H I 04-28-93 10-29-93

MYViS? H I 04-28-93 10-29-93

, MW'+-4 HI 04-28-93 10-29-93

MW¥9 I 04-28-93 10-29-93

9W911 I 04-28-93 10-29-93

I .'eMV\18~ :1 04-28-93 11-29-93

§MYV~ ?I 04-28-93 11-29-93

§MWB$ il 04-28-93 11-29-93

§M\¥8$. I 04-28-93 11-29-93

G.rountJWatet ~~Yi.(!t;N•···•···•

6878.521 ~ ~----~68:-:-7_3._52--j c=Jiill 6864.61

6880.84 1 ~ 1---_68_7_2._62--~ ~ 6872.65

6882.54 1 ~ l-------=-68--7_6.--=57:-l ~ 6877.10

6883.32 1 c::=JI]IJ r---68_7_1.5--=1-l ~ 6873.53

6923.89 I c=J]]IJ r---69_0_5.8--=8-l ~ 6905.62

6884.56 1 ~8.82 6845.74 32.13 ~----~68::-:-5-::-2.4--:3--l

'--------'

6880.081 ~ 1----68_4_8._84---l ~ 6848.99

681s.o2 1 ~1.oo 6847.02 31.04 1-----68-4-6.-98:-l .__ __ __,

6880.71 I BHE1.81 6848.90 31.61 1-----68-4-9.-1 0:-l

'------'

PW¥1 HII o4-28-93 II 6868.oo I ~ ~----~::=--::-:~--=~-~

I QW8? II o4-28-93 II 6871.oo II 28.64 II 6842.36 1

<:QW8~ I I o4-28-93 I I 6876.oo I I 31.15 I I 6844.85 I

GROUNDWATER VELOCITY

SONSELA AQUIFER

The groundwater velocity in the Sonsela aquifer under the Land Treatment Unit is estimated to be .010395 ft/day (3.794 ft/yr), using the following calculation

v v K I n

= = = = =

(KI/n) Velocity, ft/day Horizontal Hydraulic Conductivity, 0.35 ft/day Potentiometric Gradient, .00297 ft/day Porosity, 10%

"I" was calculated by using the differential elevation between wells MW-2 and MW-4 in 1993.

!LS 2-94

0 :o

<J

!>

e>

O

c-C

:•<o

!>C

>O

0 o

>o

0

0 0

D-O

0 0

0 0

0 0

0

0 0

0 0

Cr 0

I tl .D

GF

." I ('1>

(lli!ilaE

B:

_, 0 --

I I t l

. DIJ::)-

• I

N .JX£1

H • .-JQ

;; I

H

IXO

!•' I

I

c) 0

\ )

~i 1;

(/)

.....:1 ~

P...E--< I:Ll

.0:: E--<Z::E;

<"l.O

::O

0\::S:H~...;t

0\QE

--<::::>

0\ ..--lZ

.O::O

I ::::>

:>E

--<0

Oi:L

lZ..--l

~.....:101

0i:L

lUN

<"lN

\0....-llf")

f'-.f'-.1'--1

'--0

<X

)<X

)<X

)<X

)(J\ \0

\0\0

\0\0

,...-l

..--lN...;tlf"1..--l

I I

I I

I ::s:::s:::s:::s:::s: ::E

:::E:::E

:::E:O

\, \

.!... \ \ • -I I

3"

C)

\ \ \

OW-1 Giant Refining Gallup, New Mexico

Benzene Toluene Ethylbenzene Xylenes (total)

Volatile Organics Method 8240

NO 2.3 NO NO

0.9 1.9 NO 1.6

* Resarnpled OW-1 on June 4, 1993 to verify toluene. ** Resampled OW-1 on July 14, 1993 to verify BTEX.

NO 1.4 NO 0.6

NO ug/L NO ug/L NO ug/L NO ug/L


·1 Parameter


-•••-•·•·24~Rft:~2 •.· R¢$41f

.. 1 ,1-Dichloroethene ND

. ..,

...

2-Butanone 1 ,1 ,1-Trichloroethane Benzene Tetrachloroethene Toluene Ethylbenzene Xylenes (total) Acetone Carbon Disulfide Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride Carbon Disulfide 1 ,1-Dichloroethane 1,2-Dichloroethene (Total) Chloroform 1 ,2-Dichloroethane Carbon Tetrachloride Vinyl Acetate Bromodichloromethane 1,1,2,2-Tetrachloroethane 1 ,2-Dichloropropane Trans-1 ,3-Dichloropropene Trichloroethene Dibromochloromethane 1 ,1 ,2-Trichloroethane Cis-1 ,3-Dichloropropene 2-Chloroethylvinylether Bromoform 2-Hexanone (MBK) 4-Methyi-2-Pentanone (MIBK) Chlorobenzene Styrene

NO ND NO ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

6~~t!~e\••• g~.f?$+~~ i .. R~sQit?·•• •· >R¢stdf>········

NO ND ND

--- ND ND ND ND ND NO NO ND NO ND ND NO NO ND ND ND ND ND ND ND

6.2J ND ND 16 NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND NO ND ND NO ND ND ND NO ND NO ND ND ND ND ND

--- ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

OW-11

··'~~

Chromium Lead Mercury

...

Giant Refining Gallup, New Mexico

Metals Total Metals

NO NO NO

0.010 NO NO NO --- NO

NO mg/L NO mg/L

--- mg/L


General lnorganics

Alkalinity, Bicarb. as CaC03 at pH 4.5

Alkalinity, Carb. as CaC03 at pH 8.3

Chloride pH pH pH pH

Phenolics Sulfate Specific Conductance

at 25 deg.C Specific Conductance



at 25 deg.C

Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic

Halogen as Cl Total Organic



Halogen as Cl Total Dissolved

Solids

Water Elevation

450

ND 160

8.5 ---------

8.5 ND 410

2000

---

---

---2000

10 ---------

170

---

---

---

---6904.56

--- 485

--- NO --- 160

8.12 8.3 8.12 ---8.11 ---

8.2 ---8.1375 ND ND --- 200

1820 1800

1840 ---

1840 ---

1820 ---1830

6.80 4 6.20 ------ ------ ---

0.021 30

0.023 ---

--- ---

--- ---

--- 1100 6905.01 6905.79

--- mg/L

--- mg/L --- mg/L

8.26 units 8.31 units 8.32 units

8.3 units 8.2975 ND mg/L --- mg/L

1840 mhos/c

1870 mhos/c

1820 mhos/c

1880 mhos/c 1852.5 3 mg/L 3 mg/L

--- mg/L --- mg/L

200 ug/L

200 ug/L

--- ug/L

--- ug/L

--- mg/L 6905.62 ft

"' MW-1 GIANT REFINING GALLUP, NEW MEXICO

Chloromethane Bromomethane Vinyl chloride Chloroethane Methylene chloride Acetone Carbon disulfide 1 ,1-Dichloroethene 1 ,1-Dichloroethane 1 ,2-Dichloroethene

(cis/trans) Chloroform 1 ,2-Dichloroethane 2-Butanone 1 ,1 ,1-Trichloroethane Carbon tetrachloride Vinyl acetate


Bromodichloromethane trans-1 ,3-Dichloropropene Trichloroethane Chlorodibromomethane 1 ,1 ,2-Trichloroethane Benzene cis-1 ,3-Dichloropropene 2-Chloroethyl vinyl ether Bromoform 4-Methyl-2-pentanone 2-Hexanone 1 ,1 ,2,2-Tetrachloroethane Tetrachoroethene Toluene Chlorobenzene Ethylbenzene Stryene Xylenes (total) 1 ,1 ,2 Trichloro-1,2,2-

trifluoroethane

1,2-Dibromoethane (EDB) 1 ,2-Dichlorobenzene 1 ,3-Dichlorobenzene

ND NO NO NO NO ND NO NO ND

NO NO NO NO NO NO NO NO ND NO ND NO ND NO ND NO NO ND NO ND ND NO NO ND NO

NO ---NO NO

NO NO NO NO NO NO NO NO NO NO

4.1 J NO 36 NO NO NO NO NO

NO NO NO NO NO NO --- NO NO NO NO NO NO NO NO NO NO NO ND ND NO NO NO NO NO NO NO NO NO NO NO NO --- NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO

--- ------ ------ ------ ---

NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L

NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L ND ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L

--- ug/L

--- ug/L

--- ug/L

--- ug/L

MW-1


.. ,


Metals Total Metals

ND 0.084

ND

0.025 ND 0.004 ND --- ND

ND mg/L .036 mg/L

--- mg/L

~

"" ...

"' ....

.,

... . .,.

....

''<\

•ii

""

""

"" ·AO

""

""

''1'1

•lll

...

""

"'

""

"'

"'

:¥M

·~

... . .,.

411

MW-1 Giant Refining Gallup, New Mexico

General lnorganics

leatam~t~r }·•··· .2g~~i~l ··················.22···.·············.•·.·.·.•.·.·.··a·.····.•.·.·.o····e·.••.c.;s·•••.•.•uT .. •.·••· .• •••t•·.9 ..•... ·· ...•..•. 2.····.•.·.··.·····.· .• ·.• '-"'=~~~'-""'-~-'--.........:.....----'·'-"-·······'-"'···1 ·········• B~§J.ilV ·. · ··· ..

Alkalinity, Bicarb. as CaC03 at pH 4.5 270 ---

Alkalinity, Garb. as CaC03 at pH 8.3 80 ---

Chloride 56 ---pH 8.9 8.76

pH 8.78

pH 8.78

pH 8.74 8.9 8.765

Phenolics 0.02 ---Sulfate 160 ---Specific Conductance

at 25 deg.C 1100 1070

Specific Conductance at 25 deg.C 1090



1100 1080 Total Organic Carbon 15 1.5

Total Organic Carbon 3.0

Total Organic Carbon ---Total Organic Carbon ---Total Organic

Halogen as Cl ND 0.015

Total Organic Halogen as Cl 0.020

Total Organic Halogen as Cl ---

Total Organic Halogen as Cl ---

Total Dissolved Solids 1400 ---

Water Elevation 6871.35 6872.82

322

26 49 8.8 ---------

8.8 ND 150

1110

---

---

---1110

ND

---------

ND

---

---

---

690 6873.52

290CT93

·• Flest.Jit

---

------

9.05 9

9.08 9.08

9.0525 ND ---

1090

1080

1080

1090 1085

ND ND ------

ND

ND

---

---

---6864.61

mg/L

mg/L mg/L units units units units

mg/L mg/L

mhos/c

mhos/c

mhos/c

mhos/c

mg/L mg/L mg/L mg/L

ug/L

ug/L

ug/L

ug/L

mg/L

ft



Chloromethane ND Bromomethane ND Vinyl chloride ND Chloroethane ND Methylene chloride ND Acetone ND Carbon disulfide ND 1 , 1-Dichloroethene ND 1 , 1-Dichloroethane ND 1 ,2-Dichloroethene ND

(cis/trans) Chloroform ND 1 ,2-Dichloroethane ND 2-Butanone ND 1 , 1 , 1-Trichloroethane ND Carbon tetrachloride ND Vinyl acetate ND Bromodichloromethane ND trans-1 ,3-Dichloropropene ND Trichloroethane ND Chlorodibromomethane ND 1 , 1 ,2-Trichloroethane ND Benzene ND cis-1 ,3-Dichloropropene ND 2-Chloroethyl vinyl ether ND Bromoform ND 4-Methyl-2-pentanone ND 2-Hexanone ND 1,1 ,2,2-Tetrachloroethane ND Tetrachoroethene ND Toluene ND Chlorobenzene ND Ethylbenzene ND Stryene ND Xylenes {total) ND

ND ND ND ND ND ND ND ND ND ND

4.3J ND 17 ND ND ND ND ND ND ND

ND ND ND ND --- ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --- ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L

ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L

MW-2


,,..

'"'

.,., t .•


Metals Total Metals

ND ND ND

0.012 ND --

ND ND ND

ND mg/L .003 mg/L

--- mg/L

..


General lnorganics


Alkalinity, Carb. as CaC03 at pH 8.3






at 25 deg.C






Solids

Water Elevation

250

100 64 9.0

9 ND 170

1200

1200 ND

ND

1200

6872.88

---

------

8.67 8.61

8.6 8.61

8.6225 ------

1050

1130

1100

1080 1090

1.60 NO

------

NO

ND

---

---

---6872.05

303 ---

33 ---57 ---8.9 9.09

9.08 9.1

9.07 8.9 9.085

ND ---160 ---

1120 1100

1110

1090

1090 1120 1097.5

1 ND ND ------

ND ND

ND

---

---

680 ---6872.62 6872.65

mg/L


mg/L mg/L

mhos/c

mhos/c

mhos/c

mhos/c

mg/L mg/L mg/L mg/L

ug/L

ug/L

ug/L

ug/L

mg/L

ft

,,,.

,,..

.. ,4

.. '"'

"'

"" ... ,.,


Chloromethane Bromomethane Viny1 chloride Chloroethane


Methy1ene chloride Acetone Carbon disulfide 1,1-Dichloroethene 1,1-Dichloroethane 1,2-Dichloroethene

(cis/trans) Chloroform 1 ,2-Dichloroethane 2-Butanone 1,1,1-Trichloroethane Carbon tetrachloride Viny1 acetate Bromodichloromethane trans-1 ,3-Dichloropropene Trichloroethane Chlorodibromomethane 1 ,1 ,2-Trichloroethane Benzene cis-1 ,3-Dichloropropene 2-Chloroethyl vinyl ether Bromoform 4-Methy1-2-pentanone 2-Hexanone 1,1,2,2-Tetrachloroethane Tetrachoroethene Tolukebe Chlorobenzene Ethylbenzene Stryene Xylenes (total)

ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND

4.7J ND 2.8 ND ND ND ND ND

ND ND ND ND ND ND --- ND ND ND ND. ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND --- ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L

ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L

....

...

MW-4


Metals Total Metals


NO 0.032 NO NO mg/L

NO 0.008 NO NO mg/L

NO --- NO --- mg/L

'"

..


General lnorganics


Alkalinity, Garb. as CaC03 at pH 8.3






at 25 deg.C






Solids

Water Elevation

390

60 19 8.7

8.7 NO 150

1300

1300 12

230

1700 6876.28

---

------

8.6 8.58 8.57 8.57 8.58

NO ---

1130

1130

1130

1130 1130

3.00 NO ------

0.028

0.013

---

---

---6875.15

426 ---

26 ---18 ---8.7 8.82

--- 8.83 --- 8.8 --- 8.8

8.7 8.8125 NO NO 140 ---

1160 1140

--- 1130

--- 1130

--- 1150 1160 1137.5

1 NO --- NO --- ------ ---

NO NO

--- NO

--- ---

--- ---

730 ---6876.57 6877.10

mg/L


mg/L mg/L

umhos/c

umhos/c

umhos/c

umhos/c

mg/L mg/L mg/L mg/L

ug/L

ug/L

ug/L

ug/L

mg/L ft

...

MW-5 Giant Refining Gallup, NM

Chloromethane Bromomethane Vinyl chloride Chloroethane


Methylene chloride Acetone Carbon disulfide 1 , 1-Dichloroethene 1 , 1-Dichloroethane 1 ,2-Dichloroethene

(cis/trans) Chloroform 1 ,2-Dichloroethane 2-Butanone 1 , 1 , 1-Trichloroethane Carbon tetrachloride Vinyl acetate Bromodichloromethane trans-1 ,3-Dichloropropene Trichloroethane Chlorodibromomethane 1 , 1 ,2-Trichloroethane Benzene cis-1 ,3-Dichloropropene

2-Chloroethyl vinyl ether Bromoform 4-Methyl-2-pentanone 2-Hexanone 1,1 ,2,2-Tetrachloroethane

Tetrachoroethene Tolukebe Chlorobenzene Ethylbenzene Stryene Xylenes (total)

NO NO NO NO NO NO NO ND ND

ND ND NO ND ND ND ND NO ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND

NO NO NO NO NO NO NO NO NO NO

5.4 J NO 4.3J NO ND ND ND ND

ND ND NO ND ND ND

--- ND ND ND NO ND NO ND NO ND NO ND ND ND NO ND ND ND ND ND ND ND

NO ND NO ND

--- ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND NO ND

NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L NO ug/L ND ug/L ND ug/L ND ug/L

ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L

ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L

MW-5

,,

Mercury

'"


Metals Total Metals

ND ND ND

ND ND 0.003 ND --- ND

ND mg/L .002 mg/L

--- mg/L


Generallnorganics

Alkalinity, Bicarb. as CaC03 at pH 4.5 310 --- 295 --- mg/L

Alkalinity, Carb. as CaC03 at pH 8.3 100 --- 29 --- mg/L

Chloride 74 --- 66 --- mg/L

pH 9.0 8.86 8.9 8.96 units

pH 8.86 --- 8.96 units

pH 8.88 --- 9 units

pH 8.87 --- 8.97 units

9 8.8675 8.9 8.9725

Phenolics NO --- ND --- mg/L

Sulfate 170 --- 160 --- mg/L

Specific Conductance at 25 deg.C 1200 1170 1130 1110 mhos/c

Specific Conductance at 25 deg.C 1000 --- 1130 mhos/c



1200 1102.5 1130 1122.5

Total Organic Carbon 21 5.20 1 NO mg/L

Total Organic Carbon 5.30 --- NO mg/L

Total Organic Carbon --- --- --- mg/L

Total Organic Carbon --- --- --- mg/L

Total Organic Halogen as Cl 64 0.010 50 NO ug/L

Total Organic Halogen as Cl 0.025 --- ND ug/L

Total Organic Halogen as Cl --- --- --- ug/L

Total Organic Halogen as Cl --- --- --- ug/L

Total Dissolved Solids 1300 --- 700 --- mg/L

Water Elevation 6873.68 6871.61 6871.51 6873.53 ft

Jh Analytical Technologies, Inc.

May 20, 1993

Giant Refining Route 3, Box 7 Gallup, NM 87301

2709-D Pan Amen can Freeway. NE Albuquerque NM 87107 Phone (505) 344-3777 FAX 1505) 344-4413

ATI I.D. 304451

Project NamejNumber: ANNUAL GROUNDWATER

Attention: Lynn Shelton

On 04/29/93, Analytical Technologies, Inc. received a request to analyze aqueous samples. The samples were analyzed with EPA methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses,

~ are enclosed.

EPA Method 8020 analyses were performed by ATI, Albuquerque.

Total Organic Carbon and Total Organic Halides analyses were performed by ATI, Fort Collins.

All other analyses were performed by ATI, Phoenix.

J indicates the value is estimated and below the reporting limit. Methylene Chlorite was detected by EPA Method 8240 in the Trip Blank. It was not detected in any of the client's samples.

If you have any questions or comments, please do not hesitate to contact us at (505) 344-3777.

~<{L-Letitia Krakowski Assistant Project Manager

GJ:td

Enclosure

Gregory R. Jordan Laboratory Manager

Corporate Offices: 5550 Morehouse Drive San Diego. CA 92121 (619) 458-9141

A Analytical Technologies, Inc.

CLIENT PROJECT # PROJECT NAME

GIANT REFINING CO. (NONE) ANNUAL GROUNm-ilATER

ATI I.D. : 304451

ATI # CLIENT DESCRIPTION

01 ·ow-11 02 MW-1 03 MW-2 04 MW-4 05 MW-5 06 OW-l 07 OW-2 08 OW-3 09 TRIP BLANK

DATE RECEIVED

REPORT DATE

04/29/93

05/20/93

MATRIX DATE COLLECTED

AQUEOUS 04/28/93 AQUEOUS 04/28/93 AQUEOUS 04/28/93 AQUEOUS 04/28/93 AQUEOUS 04/28/93 AQUEOUS 04/28/93 AQUEOUS 04/28/93 AQUEOUS 04/28/93 AQUEOUS 04/05/93

============================================================================

----- TOTALS -----

MATRIX # SAMPLES

AQUEOUS 9

ATI STANDARD DISPOSAL PRACTICE

The samples from this project will be disposed of in thirty (30) days from the date of this report. If an extended storage period is required, please contact

~ our sample control department before the scheduled disposal date.

~

"' '

.. _,

~

"

A Analytical Technologies, Inc. GENERAL CHEMISTRY RESULTS


PARAMETER

GIANT REFINING CO. (NONE) ANNUAL GROUNDWATER

UNITS 01 02

ATI I.D. : 304451

DATE RECEIVED

REPORT DATE

03 04

04/29/93

05/20/93

05 -----------------------------------------------------------------------------CARBONATE (CAC03) MG/L <1 26 33 26 29 BICARBONATE (CAC03) MG/L 485 322 303 426 295 HYDROXIDE (CAC03) MG/L <1 <1 <1 <1 <1 TOTAL ALKALINITY (AS CAC03) MG/L 485 348 336 452 324 CHLORIDE (EPA 325.2) MG/L 160 49 57 18 66 CONDUCTIVITY, (UMHOS/CM) 1800 1110 1120 1160 1130 PH (EPA 150.1) UNITS 8.3 8.8 8.9 8.7 8. 9 PHENOLICS, TOTAL (EPA 420.1) MG/L <0.005 <0.005 <0.005 <0.005 <0.005 SULFATE (EPA 375.2) MG/L 200 150 160 140 160 T. DISSOLVED SOLIDS (160.1) MG/L 1100 690 680 730 700

'I

,

'

..

A Analytical Technologies, Inc. GENERAL CHEMISTRY RESULTS


PARAMETER

GIANT REFINING CO. (NONE) ANNUAL GROUND\tV"ATER

UNITS 06 07

ATI I.D. : 304451

DATE RECEIVED : 04/29/93

REPORT DATE : .. 05/20/93

08 -----------------------------------------------------------------------------CARBONATE (CAC03) MG/L 22 <1 <1 BICARBONATE (CAC03) MG/L 387 662 660 HYDROXIDE (CAC03) MG/L <1 <1 <1 TOTAL ALKALINITY (AS CAC03) MG/L 409 662 660 CHLORIDE (EPA 325.2) MG/L 41 42 41 CONDUCTIVITY, (UMHOS/CM) 1260 1220 1260 PH (EPA 150.1) UNITS 8.7 8.1 8.2 SULFATE (EPA 375.2) MG/L 210 19 16 T . DISSOLVED SOLIDS (160.1) MG/L 870 1100 840

A Analytical Technologies, Inc. GENERAL CHEMISTRY - QUALITY CONTROL

CLIENT GIANT REFINING CO. PROJECT # (NONE) PROJECT NAME ANNUAL GROUNDWATER AT! I. D. : 304451

-----------------------------------------------------------------------------SAMPLE DUP. SPIKED SPIKE %

PARAMETER UNITS AT! I. D. RESULT RESULT RPD SAMPLE CONC REC -----------------------------------------------------------------------------CARBONATE MG/L 30401101 <1 <1 NA NA NA NA

~ BICARBONATE MG/L 212 210 0.9 NA NA NA HYDROXIDE MG/L <1 <1 NA NA NA NA

• TOTAL ALKALINITY MG/L 212 210 0.9 NA NA NA CARBONATE MG/L 30445105 29 29 0 NA NA NA BICARBONATE MG/L 295 297 0.7 NA NA NA

' HYDROXIDE MG/L <1 <1 NA NA NA NA TOTAL ALKALINITY MG/L 324 326 0.6 NA NA NA

" CHLORIDE MG/L 30445104 18 18 0 44 25 104 CONDUCTIVITY(UMHOS/CM) 30403301 1260 1270 0. 8 . NA NA NA PH UNITS 30401101 7. 7 7.7 0 NA NA NA

" PH UNITS 30445105 8.9 8.9 0 NA NA NA PHENOLICS, TOTAL MG/L 30549904 <0.005 <0.005 NA 0.025 0.025 100

·• SULFATE MG/L 30549909 38 38 0 76 38 100 SULFATE MG/L 30549905 190 180 5 410 200 110

" TOTAL DISSOLVED SOLIDS MG/L 30444401 390 390 0 NA NA NA ~

.,

% Recovery = (Spike Sample Result - Sample Result) X 100

Spike Concentration

RPD (Relative Percent Difference) = (Sample Result - Duplicate Result) X lOG

Average Result

A AnalyticaiTechnologies,lnc.

GENERAL CHEMISTRY RESULTS

•cLIENT GIANT REFINING .PROJECT # (NONE) PROJECT NAME: ANNUAL GROUNDWATER

ATI I.D. 304451 DATE RECEIVED: 04/29/93 REPORT DATE 05/20/93

4-------------------------------------------------------------------------------PARAMETER UNITS 01 02 03 04 05 ·-------------------------------------------------------------------------------TOTAL ORGANIC CARBON ~

MG/L 4 <1. 0 1 1 1


GENERAL CHEMISTRY - QUALITY CONTROL

~LIENT

't>ROJECT # PROJECT NAME: "l

PARAMETER

GIANT REFINING (NONE) ANNUAL GROUNDWATER

UNITS ATI I.D. SAMPLE RESULT

DUP. RESULT

ATI I. D.: 304451

RPD SPIKED SAMPLE

SPIKE CONC. REC

~-------------------------------------------------------------------------------;oTAL ORGANIC CARBON MG/L 30445101 4 4 0 NA NA NA

(Spike Sample Result - Sample Result) % Recovery ------------------------------------- X 100

Spike Concentration

(Sample Result - Duplicate Result) ~PD (Relative Percent Difference = ---------------------------------- X 100

Average Result



•CLIENT GIANT REFINING PROJECT # {NONE) PROJECT NAME: ANNUAL GROUNDWATER

PARAMETER UNITS 01

TOTAL ORGANIC HALIDES MG/L 30

.,

ATI I.D. 304451 DATE RECEIVED: 04/29/93 REPORT DATE 05/20/93

02 03 04

<20 <20 <20

05

50



::LIENT ~ROJECT # J'ROJECT NAME:

PARAMETER

GIANT REFINING (NONE)

ANNUAL GROUNDWATER

UNITS ATI I.D. SAMPLE RESULT

DUP. RESULT

ATI I.D.: 304451

RPD SPIKED SAMPLE

SPIKE CONC. REC

~-------------------------------------------------------------------------------~OTAL ORGANIC HALIDES MG/L 30445102 <20 NA NA 400 400 100

(Spike Sample Result - Sample Result) ~% Recovery = ------------------------------------- X 100

Spike Concentration

(Sample Result - Duplicate Result) •RPD (Relative Percent Difference = ---------------------------------- X 100

Average Result

~Analytical Technologies, Inc. METALS RESULTS

, CLIENT PROJECT #

""" PROJECT NAME

.. ,. PARAMETER

GIANT REFINING CO. (NONE)

ANNUAL GROUNDWATER

UNITS 01 02

ATI I.D. : 304451

DATE RECEIVED

REPORT DATE

03 04

04/29/93

05/20/93

05 r~ -----------------------------------------------------------------------------

SILVER (EPA 200.7/6010) MG/L <0.010 <0.010 <0.010 <0.010 <0.010 "" ARSENIC (200.7/6010) MG/L <0.1 <0.1 <0.1 <0.1 <0.1

BARIUM (EPA 200.7/6010) MG/L <0.010 <0.010 0.015 0.016 0.015 .,... CALCIUM (EPA 200.7/6010) MG/L 4.8 1.1 0.9 1.5 1.4

CADMIUM (200.7/6010) MG/L <0.005 <0.005 <0.005 <0.005 <0.005 ··~ CHROMIUM (EPA 200.7/6010) MG/L <0.010 <0.010 <0.010 <0.010 <0.010 .,.. MERCURY (EPA 245.1/7470) MG/L <0.0002 <0.0002 <0.0002 <0.0002 <0.0002

POTASSIUM (EPA 200.7/6010) MG/L 1 . 1 <1.0 <1.0 <1 .. 0 1.5 ·"" MAGNESIUM (EPA 200.7/6010) MG/L 0.6 0.2 0.1 0.3 0.2 ..,. MANGANESE (EPA 200.7/6010) MG/L <0.010 <0.010 <0.010 <0.010 <0.010

SODIUM (EPA 200.7/6010) MG/L 421 260 275 295 279 ,. LEAD (200.7/6010) MG/L <0.10 <0.10 <0.10 <0.10 <0.10

SELENIUM (200.7/6010) MG/L <0.1 <0.1 <0.1 <0.1 <0.1 ""' .. ...

A Analytical Technologies, Inc. METALS RESULTS

CLIENT "" PROJECT #

PROJECT NAME

GIANT REFINING CO. (NONE) ANNUAL GROUNDWATER

,,, PARAMETER

""' CALCIUM (EPA 200.7/6010) .. , POTASSIUM (EPA 200.7/6010)

MAGNESIUM (EPA 200.7/6010) "" SODIUM (EPA 200. 7/6010)

UNITS

MG/L MG/L MG/L MG/L

06

3.6 2.1 4.5 326

07

8.7 <1. 0 3.7 336

ATI I.D. : 304451

DATE RECEIVED 04/29/93

REPORT DATE 05/20/93

08

9.5 <1. 0 3.6 340

A Analytical Technologies, Inc. METALS - QUALITY CONTROL

CLIENT .·.,a PROJECT #

PROJECT NAME

GIANT REFINING CO. (NONE) ANNUAL GROUNDWATER ATI I.D. : 304451


PARAMETER UNITS ATI I.D. RESULT RESULT RPD SAMPLE CONC REC -----------------------------------------------------------------------------

"" SILVER MG/L 30445105 <0.010 <0.010 NA 1. 02 1. 00 102 ARSENIC (ICAP) MG/L 30445105 <0.1 <0.1 NA 1.0 1.0 100 BARIUM MG/L 30445105 0.015 0.015 0 1. 04 1. 00 102 CALCIUM MG/L 30445103 0.9 0.9 0 48.7 50.0 96 CALCIUM MG/L 30496402 67.0 69.2 3 117 50.0 100

. ., CADMIUM MG/L 30445105 <0.005 <0.005 NA 0.996 1. 00 100 CHROMIUM MG/L 30445105 <0.010 <0.010 NA 0.982 1. 00 98 ,,_.,.

MG/L MERCURY 30550701 <0.0002 <0.0002 NA 0.0049 0.0050 98 POTASSIUM MG/L 30445103 <1.0 <1. 0 NA 48.2 50.0 96 MAGNESIUM MG/L 30445103 0.1 0.1 0 23.4 25.0 93 - MANGANESE MG/L 30445105 <0.010 <0.010 NA 1.02. 1.00 102 SODIUM MG/L 30445103 275 277 0.7 364 100 89 LEAD MG/L 30445105 <0.10 <0.10 NA 1. 01 1. 00 101 SELENIUM (ICAP) MG/L 30445105 <0.1 <0.1 NA 1 . 1 1. 00 110

~ % Recovery = (Spike Sample Result - Sample Result) X 100

Spike Concentration

RPD (Relative Percent Difference) = (Sample Result - Duplicate Result) X 100

Average Result


GAS CHROMATOGRAPHY RESULTS

~EST

:LIENT PROJECT # J;ROJECT NAME:

BTEX, MTBE (EPA 8020) GIANT REFINING {NONE) ANNUAL GROUNDWATER

~AMPLE

I.D. # CLIENT I.D. MATRIX DATE DATE

SAMPLED EXTRACTED

ATI I.D.:

DATE ANALYZED

304451

OIL. FACTOR

~------------------------------------------------------------------------------06 07 08

'flARAMETER

"' >ENZENE • .,II'QLUENE

OW-l OW-2 OW-3

ETHYLBENZENE ~OTAL XYLENES

iETHYL-t-BUTYL ""

ETHER

~ROMOFLUOROBENZENE (%)

,,..

AQUEOUS AQUEOUS AQUEOUS

UNITS

UG/L UG/L UG/L UG/L UG/L

04/28/93 04/28/93 04/28/93

06

<0.5 2.3

<0.5 <0.5 <2.5

95

NA NA NA

07

<0.5 <0.5 <0.5 <0.5 <2.5

91

05/03/93 05/03/93 05/03/93

08

<0.5 <0.5 <0.5 <0.5 <2.5

92

1 1 1



~EST

.LANK I. D. 'eLIENT PROJECT # : ""ROJECT NAME:

REAGENT BLANK

BTEX, MTBE (EPA 8020) 050393 GIANT REFINING (NONE)

ANNUAL GROUNDWATER

ATI I.D. DATE EXTRACTED DATE ANALYZED DILUTION FACTOR:

304451 NA 05/03/93 1

~------------------------------------------------------------------------------PARAMETER UNITS ~------------------------------------------------------------------------------

IENZENE "foLUENE ,~THYLBENZENE

'OTAL XYLENES ~ETHYL-t-BUTYL ETHER

~ROMOFLUOROBENZENE (%)

UG/L <0.5 UG/L <0.5 UG/L <0.5 UG/L <0.5 UG/L <2.5

91


GAS CHROMATOGRAPHY - QUALITY CONTROL

MSMSD ·:-;4

TEST BTEX, MTBE (EPA 8020) ATI I.D. 304451 .MSMSD # 30444511 DATE EXTRACTED: NA ~LIENT GIANT REFINING DATE ANALYZED 05/03/93

~4 SAMPLE MATRIX AQUEOUS PROJECT # (NONE) REF. I. D. 30444511

"">ROJECT NAME: ANNUAL GROUNDWATER UNITS UG/L -------------------------------------------------------------------------------~ARAMETERS

11ENZENE ~OLUENE

~THYL BENZENE <illf'OTAL XYLENES METHYL-t-BUTYL ETHER

SAMPLE RESULT

<0.5 <0.5 <0.5 <0.5 <2.5

CONC SPIKE

10 10 10 30 20

SPIKED SAMPLE

9.8 10 10 30 22

REC

98 100 100 100 110

DUP SPIKE

9.7 10 10 30 21

DUP % REC

97 100 100 100 105

RPD

1 0 0 0 5


GCMS - RESULTS

·•

TEST : VOLATILE ORGANICS (EPA 8240)

CLIENT PROJECT #

,,.,. PROJECT NAME CLIENT I.D.

~ SAMPLE MATRIX

COMPOUNDS

""' CHLOROMETHANE BROMOMETHANE

~ VINYL CHLORIDE

GIANT REFINING CO. (NONE) ANNUAL GROUNDWATER OW-11 AQUEOUS

, CHLOROETHANE METHYLENE CHLORIDE

,., ACETONE CARBON DISULFIDE

~ 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE ... 1,2-DICHLOROETHENE (TOTAL)

.. CHLOROFORM 1,2-DICHLOROETHANE

~ 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE

"" CARBON TETRACHLORIDE '" VINYL ACETATE

BROMODICHLOROMETHANE "' 1,1,2,2-TETRACHLOROETHANE

1,2-DICHLOROPROPANE '" TRANS-1 1 3-DICHLOROPROPENE ~ TRICHLOROETHENE

DIBROMOCHLOROMETHANE .. 1 1 1,2-TRICHLOROETHANE

BENZENE ,,.,. CIS-1 1 3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM

~ 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK)

"' TETRACHLOROETHENE ,4

TOLUENE CHLOROBENZENE

.• ETHYLBENZENE STYRENE

''" TOTAL XYLENES

SURROGATE PERCENT RECOVERIES

1,2-DICHLOROETHANE-D4 (%) ... BROMOFLUOROBENZENE (%) ,., TOLUENE-DB (%)

ATI I.D. 30445101

DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

04/28/93 04/29/93 N/A 05/06/93 UG/L

1

RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

90 100 98

"'"' A Analytical Technologies, Inc. ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)


ATI I.D. : 30445101

~ -----------------------------------------------------------------------------COMPOUNDS RESULTS

"' NO ADDITIONAL COMPOUNDS

....

2h AnalyticaiTechnologies,lnc.

GCMS - RESULTS

TEST VOLATILE ORGANICS (EPA 8240)

CLIENT ~ PROJECT # ,,. PROJECT NAME

CLIENT I. D. ... SAMPLE MATRIX

, COMPOUNDS

.. CHLOROMETHANE BROMOMETHANE

'" VINYL CHLORIDE

GIANT REFINING CO. (NONE) ANNUAL GROUNDWATER MW-1 AQUEOUS

.,. CHLOROETHANE METHYLENE CHLORIDE

. ., ACETONE CARBON DISULFIDE

• 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE .. 1,2-DICHLOROETHENE (TOTAL)

,. CHLOROFORM 1,2-DICHLOROETHANE

.,. 2-BUTANONE (MEK) 1,1,1~TRICHLOROETHANE ... CARBON TETRACHLORIDE

.,. VINYL ACETATE BROMODICHLOROMETHANE

.,. 1, 1, 2, 2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE

"' TRANS-1,3-DICHLOROPROPENE • TRICHLOROETHENE

DIBROMOCHLOROMETHANE ~ 1,1,2-TRICHLOROETHANE

BENZENE .... CIS-1,3-DICHLOROPROPENE

.. 2-CHLOROETHYLVINYLETHER BROMOFORM

" 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK)

" TETRACHLOROETHENE TOLUENE CHLOROBENZENE

... ETHYLBENZENE STYRENE

" TOTAL XYLENES


1,2-DICHLOROETHANE-04 (%) " BROMOFLUOROBENZENE (%) ~ TOLUENE-OS (%)

ATI I.D. 30445102


04/28/93 04/29/93 N/A 05/06/93 UG/L

1

RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

101 97 96

A AnalyticaiTechnologies,ln<A_DDITIONAL COMPOUNDS (SEMI-QUANTITATED)

~TEST : VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 30445102

'""' COMPOUNDS RESULTS

NO ADDITIONAL COMPOUNDS

"'

..


GCMS - RESULTS


CLIENT - PROJECT # ""' PROJECT NAME

CLIENT I.D. .,. SAMPLE MATRIX

COMPOUNDS

,,. CHLOROMETHANE BROMOMETHANE

~ VINYL CHLORIDE CHLOROETHANE


ANNUAL GROUNDWATER MW-2 AQUEOUS

• METHYLENE CHLORIDE ,,. ACETONE

CARBON DISULFIDE ""' 1,1-DICHLOROETHENE

1,1-DICHLOROETHANE ~ 1,2-DICHLOROETHENE (TOTAL)

"" CHLOROFORM 1,2-DICHLOROETHANE


~ CARBON TETRACHLORIDE VINYL ACETATE

'"" BROMODICHLOROMETHANE ""1,1,2,2-TETRACHLOROETHANE

1,2-DICHLOROPROPANE ,,., TRANS-1, 3-DICHLOROPROPENE • TRICHLOROETHENE

DIBROMOCHLOROMETHANE " 1 1 1, 2-TRICHLOROETHANE

BENZENE • CIS-1,3-DICHLOROPROPENE

2-CHLOROETHYLVINYLETHER ... BROMOFORM

,., 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK)

"" TETRACHLOROETHENE TOLUENE ,.,. CHLOROBENZENE

,. ETHYLBENZENE STYRENE

"'" TOTAL XYLENES


1,2-DICHLOROETHANE-D4 (%) • BROMOFLUOROBENZENE (%)

TOLUENE-DB (%) ..

ATI I.D. 30445103


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

101 99 98

04/28/93 04/29/93 N/A 05/06/93 UG/L

1

A Analytical Technologies, Inc. ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)


ATI I.D. : 30445103


. -----------------------------------------------------------------------------NO ADDITIONAL COMPOUNDS


GCMS - RESULTS

··~ TEST : VOLATILE ORGANICS (EPA 8240)

CLIENT .. PROJECT #

PROJECT NAME "' CLIENT I. D.

SAMPLE MATRIX "


ATI I.D. 30445104


04/28/93 04/29/93 N/A 05/06/93 UG/L

1 ~ -----------------------------------------------------------------------------

COMPOUNDS RESULTS ~ -----------------------------------------------------------------------------.... CHLOROMETHANE

BROMOMETHANE , VINYL CHLORIDE

CHLOROETHANE ~ METHYLENE CHLORIDE

ACETONE ""' CARBON DISULFIDE • 1,1-DICHLOROETHENE

1,1-DICHLOROETHANE ., 1,2-DICHLOROETHENE (TOTAL)

CHLOROFORM "' 1, 2-DICHLOROETHANE .,. 2-BUTANONE (MEK)

1,1,1-TRICHLOROETHANE ~ CARBON TETRF_CHLORIDE

VINYL ACETATE "' BROMOD I CHLOROMETHANE ,. 1,1, 2, 2-TETRACHLOROETHANE

1,2-DICHLOROPROPANE ""' TRANS-1 I 3-DICHLOROPROPENE

TRICHLOROETHENE ·"' DIBROMOCHLOROMETHANE

1,1,2-TRICHLOROETHANE ""' BENZENE • CIS-1, 3-DICHLOROPROPENE

2-CHLOROETHYLVINYLETHER "'BROMOFORM

..... 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK)

"' TETRACHLOROETHENE TOLUENE

"" CHLOROBENZENE ETHYLBENZENE

""'STYRENE .. TOTAL XYLENES

SURROGATE PERCENT RECOVERIES w

1,2-DICHLOROETHANE-D4 (%) ""' BROMOFLUOROBENZENE (%)

TOLUENE-DB (%)

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

97 95 95

A Analytica1Technologies,ln2illDITIONAL COMPOUNDS (SEMI-QUANTITATED)

.. TEST : VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 30445104

""COMPOUNDS RESULTS

"'"" NO ADDITIONAL COMPOUNDS

.,


GCMS - RESULTS

~TEST : VOLATILE ORGANICS (EPA 8240)

CLIENT ,., PROJECT #

PROJECT NAME ·• CLIENT I. D.

SAMPLE MATRIX

COMPOUNDS

CHLOROMETHANE ,.. BROMOMETHA.NE

.• VINYL CHLORIDE CHLOROETHANE


• METHYLENE CHLORIDE ACETONE

"" CARBON DISULFIDE .~ 1,1-DICHLOROETHENE

1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM

• 1,2-DICHLOROETHANE ,,. 2-BUTANONE (MEK)

1,1,1-TRICHLOROETHANE • CARBON TETRACHLORIDE

VINYL ACETATE "' BROMODICHLOROMETHANE 4

1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE

.,. TRANS-1, 3-DICHLOROPROPENE TRICHLOROETHENE

"·"' DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE

"' BENZENE ~ CIS-1,3-DICHLOROPROPENE

2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK)

""' 4-METHYL-2-PENTANONE (MIBK) .,,. TETRACHLOROETHENE

TOLUENE ~,. CHLOROBENZENE

ETHYLBENZENE ""STYRENE

TOTAL XYLENES


·t,!!>f

1,2-DICHLOROETHANE-04 (%) 1

BROMOFLUOROBENZENE (%) TOLUENE-OS (%)

ATI I.D. 30445105


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

97 96 97

04/28/93 04/29/93 N/A 05/06/93 UG/L

1



ATI I.D. : 30445105

COMPOUNDS RESULTS

"" -----------------------------------------------------------------------------NO ADDITIONAL COMPOUNDS

,,.

'"'

,.,.

,., ..

,..,


GCMS - RESULTS

.. ,., TEST : VOLATILE ORGANICS (EPA 8240)

CLIENT "" PROJECT #

PROJECT NAME "'"CLIENT I.D.

SAMPLE MATRIX

COMPOUNDS

GIANT REFINING CO. (NONE) ANNUAL GROUNDWATER TRIP BLANK AQUEOUS

ATI I.D . 30445109


RESULTS

04/05/93 04/29/93 N/A 05/06/93 UG/L

1

1 -----------------------------------------------------------------------------CHLOROMETHANE """ BROMOMETHANE

VINYL CHLORIDE "" CHLOROETHANE • METHYLENE CHLORIDE

ACETONE 1 CARBON DISULFIDE • 1,1-DICHLOROETHENE

1,1-DICHLOROETHANE ~ 1,2-DICHLOROETHENE (TOTAL)

CHLOROFORM "' 1, 2-DICHLOROETHANE

2-BUTANONE (MEK) ~ 1,1,1-TRICHLOROETHANE

4 CARBON TETRACHLORIDE VINYL ACETATE

1 BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE

""' 1,2-DICHLOROPROPANE ,. TRANS-1, 3-DICHLOROPROPENE

TRICHLOROETHENE ~ DIBROMOCHLOROMETHANE

1,1,2-TRICHLOROETHANE .. BENZENE , CIS-1, 3-DICHLOROPROPENE

2-CHLOROETHYLVINYLETHER .,., BROMOFORM

2-HEXANONE (MBK) '""' 4 -METHYL- 2-P ENTANONE ( MIBK)

TETRACHLOROETHENE ""' TOLUENE ·"" CHLOROBENZENE

ETHYLBENZENE ""'STYRENE ,. TOTAL XYLENES


• 1,2-DICHLOROETHANE-D4 (%) .,.. BROMOFLUOROBENZENE (%)

TOLUENE-DB (%)

<10 <10 <1 <1

3 J <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

99 97 97

.. 2h Analytical Technologies, Inc. ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)


ATI I.D. : 30445109

COMPOUNDS RESULTS


~Analytical Technologies, Inc. GCMS - RESULTS

REAGENT BLANK


,., CLIENT PROJECT #


"' PROJECT NAME CLIENT I.D.

ANNUAL GROUNDWATER REAGENT BLANK

COMPOUNDS ,,.

,.., CHLOROMETHANE BROMOMETHANE

"" VINYL CHLORIDE ,,. CHLOROETHANE

METHYLENE CHLORIDE ., ACETONE.

CARBON DISULFIDE • 1,1-DICHLOROETHENE

1,1-DICHLOROETHANE .. 1,2-DICHLOROETHENE (TOTAL)

A CHLOROFORM 1,2-DICHLOROETHANE


""' CARBON TETRACHLORIDE ,,. VINYL ACETATE

BROMODICHLOROMETHANE '"' 1, 1 f 2 I 2 -TETRACHLOROETHANE

1,2-DICHLOROPROPANE "" TRANS-1, 3-DICHLOROPROPENE "' TRICHLOROETHENE

DIBROMOCHLOROMETHANE ,,. 1, 1, 2-TRICHLOROETHANE

BENZENE ,,. CIS-1, 3-DICHLOROPROPENE

2-CHLOROETHYLVINYLETHER BROMOFORM

""' 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK)

" TETRACHLOROETHENE TOLUENE

""' CHLOROBENZENE .,. ETHYLBENZENE

STYRENE "" TOTAL XYLENES


1,2-DICHLOROETHANE-D4 (%) "" BROMOFLUOROBENZENE (%)

TOLUENE-DB (%) , ..

ATI I. D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

99 99 97

304451 05/06/93 05/06/93 UG/L N/A

'+;f'

A Analytical Technologies, Inc. GCMS - RESULTS

REAGENT BLANK


"" CLIENT PROJECT #


"' PROJECT NAME CLIENT I.D.

ANNUAL GROUNDWATER REAGENT BLANK

, COMPOUNDS

·~ CHLOROMETHANE BROMOMETHANE

"'' VINYL CHLORIDE ,.. CHLOROETHANE

METHYLENE CHLORIDE "" ACETONE

CARBON DISULFIDE ~ 1,1-DICHLOROETHENE

1,1-DICHLOROETHANE "' 1,2-DICHLOROETHENE (TOTAL) ,.. CHLOROFORM

1,2-DICHLOROETHANE "" 2-BUTANONE (MEK) ""' 1, 1, 1-TRICHLOROETHANE

CARBON TETRACHLORIDE .,. VINYL ACETATE

BROMODICHLOROMETHANE ""' 1, 1, 2 I 2 -TETRACHLOROETHANE

1,2-DICHLOROPROPANE ''" TRANS-1, 3-DICHLOROPROPENE "" TRICHLOROETHENE

DIBROMOCHLOROMETHANE ·~ 1, 1, 2-TRICHLOROETHANE

BENZENE ""' CIS-1,3-DICHLOROPROPENE ... 2-CHLOROETHYLVINYLETHER

BROMOFORM "" 2-HEXANONE (MBK)

4-HETHYL-2-PENTANONE (MIBK) ~ TETRACHLOROETHENE . .,. TOLUENE

CHLOROBENZENE ., ETHYLBENZENE

STYRENE "" TOTAL XYLENES



TOLUENE-DB (%) ""

ATI I.D. DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

98 99 97

304451 05/06/93 05/06/93 UG/L N/A


QUALITY CONTROL DATA

• TEST : VOLATILE ORGANICS (EPA 8240)

."' CLIENT ,. PROJECT #

PROJECT NAME A\1 REF I .D.

GIANT REFINING CO. (NONE) ANNUAL GROUNDWATER 30445101

ATI I.D.

DATE ANALYZED SAMPLE MATRIX UNITS

304451

05/06/93 AQUEOUS UG/L

DUP. DUP.

"'COMPOUNDS SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

-----------------------------------------------------------------------------'''.j~J 1,1-DICHLOROETHENE <1 50 44 88 50 100 13 ,. TRICHLOROETHENE <1 50 45 90 48 96 6

CHLOROBENZENE <1 50 48 96 49 98 2 "TOLUENE <1 50 50 100 53 106 6

BENZENE <1 50 50 100 52 104 4


Spike Concentration

~RPD (Relative% Difference)= (Spiked Sample- Duplicate Spike) Result Sample Result

X 100 Average of Spiked Sample



""TEST VOLATILE ORGANICS (EPA 8240)

., CLIENT 4 PROJECT #

PROJECT NAME ,. REF I. D.

GIANT REFINING CO. (NONE) ANNUAL GROUNDWATER 30445509

ATI I.D.


304451


DUP. DUP.

""'COMPOUNDS SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

-----------------------------------------------------------------------------·"'~ 1,1-DICHLOROETHENE <1 50 46 92 51 102 10

TRICHLOROETHENE <1 50 45 90 48 96 6 .... CHLOROBENZENE <1 50 46 92 48 96 4

.,. TOLUENE <1 50 48 96 51 102 6 BENZENE <1 50 48 96 51 102 6 ...

% Recovery ; (Spike Sample Result - Sample Result) X 100

Spike Concentration

~RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result


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NETWORK PROJECT MANAGER: BETH PAOFFITI

COMPANY: Analytical Technologies, Inc. ADDRESS: 2709-D Pan American Freeway, NE

Albuquerque, NM 87106

~E: PROJECT MANAGER:

Y SAMPLEID DATE TIME MATRIX

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PROJECT NUMBER: ~4qc:;-{ f--TOTAL_NUMBE~~~-CON!~I~ERS _ _l_2~L~~Nc~~~s I ~tJ ,_Ji__l~~l.S

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Signature: Tune:

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MSD BLANK RECEIVED GOOD CON D./COlD Analyucall echnolog1es, Int.

RUSH! 301...\L\s- \ PHOENIX Albuquerque BARRINGER RECEIVED BY: LAB J.

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Company: ('I\

l1Il_- 1 t\X 1-------+-' Company:

ATI Labs: San Diego (619) 456·9141 • Phoenix (602) 496k4oo • Seanle)~s) 228·8335 • Pensacola (904) 474-1001 • Portland (503) 684-0447 • Albuquerque (505) 344-3m DISTRIBUTION: Whrte, Canary. ATI • Pink· ORIGINATOR

J

I i : ' ~ ' '" t j i t ,J ' . ~ A AnolylicniTechnologies,lnc Albuquerque, NM Chain of Custody

NETWORK PROJECT MANAGER: BETH PROFFITI



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DUE DATE: G.:JO Lk-qo 3 ---- Signature: g,),~t~~~ RUSH SURCHARGE: Printed Name: Date: {' hf: > ti-1• I CLIENT DISCOUNT: -- % ,-... z-f3 Comparr: j J 3 )u r-e -{~X ;t/J::

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4~ Analytical Technologies, Inc.

May 20, 1993

Giant Refining Co. Route 3, Box 7 Gallup, NM 87301

2709-D Pan American Freeway, NE Albuquerque NM 87107 Phone (505) 344-3777 FAX (505) 344-4413

ATI I. D. 304455

Project NamejNumber: ANNUAL GRDWTR


On 04/30/93, Analytical Technologies, Inc. received a request to analyze aqueous samples. The samples were analyzed with EPA

.• methodology or equivalent methods. The results of these analyses and the quality control data, which follow each set of analyses, are enclosed.

"'

Total Organic Carbon and Total Organic Halides analyses were performed by ATJ, Fort Collins.

All other analyses were performed by ATI, Phoenix.

If you have any questions or comments, contact us at (505) 344-3777.

~J/d@Jsk Letitia Krakowski Assistant Project Manager

GJ:td

Enclosure

please do not hesitate to

~::~d::f-Laboratory Manager

Corporate Offices: 5550 Morehouse Drive San Diego. CA 92121 (::19) 458-:;;·,::i

..

2h Analytical Technologies, Inc.

CLIENT GIANT REFINING CO. DATE RECEIVED 04/30/93 PROJECT # (NONE) PROJECT NAME ANNUAL GRDWTR REPORT DATE 05/20/93

ATI I.D. : 304455

-----------------------------------------------------------------------------ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED -----------------------------------------------------------------------------01 02 03 04 05 06 07 08 09 10

SMW-3 (TOTAL) SMW-3 (DISSOLVED) SMW-4 (TOTAL) SMW~4 (DISSOLVED) SMW-5 (TOTAL) SMW-5 (DISSOLVED) SMW-6 (TOTAL) SMW-6 (DISSOLVED) SMW-4D (TOTAL) SMW-4D (DISSOLVED)

AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS

04/29/93 04/29/93 04/29/93 04/29/93 04/29/93 04/29/93 04/29/93 04/29/93 04/29/93 04/29/93

============================================================================ TOTALS -----

¥lATRIX # SAMPLES

AQUEOUS 10


The samples from this project will be disposed of in thirty (30) days from ~he date of this report. If an extended storage period is required, please conta2~ our sample control department before the scheduled disposal date.

4 Analytical Technologies, Inc. GENERAL CHEMISTRY RESULTS

CLIENT ,.,. PROJECT # ·"" PROJECT NAME

··~ PARAMETER

GIANT REFINING CO. (NONE) ANNUAL GRDWTR

UNITS 01 03

ATI I.D. : 304455



05 07 09 -----------------------------------------------------------------------------40 CARBONATE (CAC03) MG/L <1 <1 10 <1 <1 BICARBONATE (CAC03) MG/L 630 420 335 591 426 " HYDROXIDE (CAC03) MG/L <1 <1 <1 <1 <1

·"' TOTAL ALKALINITY (AS CAC03) MG/L 630 420 345 591 426 CHLORIDE (EPA 325.2) MG/L 70 61 61 90 60 .,. CONDUCTIVITY, (UMHOS/CM) 3170 1310 1130 1760 1300 PH (EPA 150.1) UNITS 7.9 8.2 8.5 8.2 8.2 ·"' SULFATE (EPA 375.2) MG/L 1000 180 140 220 180

. .., T . DISSOLVED SOLIDS (160.1) MG/L 2300 840 770 1100 840 TOTAL ORGANIC CARBON MG/L 3 3 8 2 4 "' TOTAL ORGANIC HALIDES MG/L 40 40 90 < 20 90

...

A AnolyticoiTechnologies,lnc. GENERAL CHEMISTRY - QUALITY CONTROL

CLIENT GIANT REFINING co. PROJECT JL (NONE) "' "It

PROJECT NAME ANNUAL GRDWTR ATI I. D. : 304455


PARAMETER UNITS ATI I. D. RESULT RESULT RPD SAMPLE CONC REC -----------------------------------------------------------------------------CARBONATE MG/L 30445501 <1 <1 NA NA NA NA BICARBONATE MG/L 630 629 0.2 NA NA NA

~ HYDROXIDE MG/L <1 <1 NA NA NA NA TOTAL ALKALINITY MG/L 630 629 0.2 NA NA NA CHLORIDE MG/L 30445509 60 59 2 163 100 103 CONDUCTIVITY(UMHOS/CM) 30445501 3170 3240 2 NA NA NA PH UNITS 30445501 7.9 8.0 1 NA NA NA ". SULFATE MG/L 30445501 1000 1000 0 2000 990 101 TOTAL DISSOLVED SOLIDS MG/L 30445507 1100 1100 0 NA NA NA "' TOTAL ORGANIC CARBON MG/L 30445501 3 3 0 NA NA NA TOTAL ORGANIC HALIDES MG/L 930422902 < 20 NA NA 400 400 100

% Recovery = (Spike Sample Result - Sample Result) ------------------------------------ X 100 Spike Concentration

RPD (Relative Percent Difference) = (Sample Result - Duplicate Result) ---------------------------------- X lOC

Average Result


CLIENT "' PROJECT #

PROJECT NAME

GIANT REFINING CO. (NONE) ANNUAL GRDWTR

ATI I.D. : 304455

DATE RECEIVED

REPORT DATE

04/30/93

05/20/93 -----------------------------------------------------------------------------PARAMETER UNITS 01 02 03 04 05

4 CALCIUM (EPA 200.7/6010) MG/L 43.5 4.2 CHROMIUM (EPA 200.7/6010) MG/L 0.012 0.014 0.020

"'•"f! POTASSIUM (EPA 200.7/6010) MG/L <l. 0 <l. 0 MAGNESIUM (EPA 200.7/6010) MG/L 15.6 1.4 < ..

SODIUM (EPA 200.7/6010) MG/L 820 318 LEAD (200.7/6010) MG/L <0.10 <0.10 <0.10


CLIENT PROJECT #

"' PROJECT NAME

PARAMETER

METALS RESULTS


ANNUAL GRDWTR

UNITS 06 07

ATI I.D. : 304455

DATE RECEIVED

REPORT DATE

08 09

04/30/93

05/20/93

10 -----------------------------------------------------------------------------CALCIUM (EPA 200.7/6010) MG/L 3.4 9.6 4.6 CHROMIUM (EPA 200.7/6010) MG/L 0.012 0.011 POTASSIUM (EPA 200.7/6010) MG/L 1.3 <1.0 <1. 0 ¥..AGNESIUM (EPA 200.7/6010) MG/L 1.5 3.2 1.5 SODIUM (EPA 200.7/6010) MG/L 256 443 321 LEAD (200.7/6010) MG/L <0.10 <0.10

4 AnolyticoiTechnologies, Inc. METALS - QUALITY CONTROL

CLIENT "" PROJECT #

PROJECT NAME

GIANT REFINING CO. (NONE) ANNUAL GRDWTR · ATI I.D. : 304455

... SAMPLE DUP. SPIKED SPIKE %

PARAMETER UNITS ATI I.D. RESULT RESULT RPD SAMPLE CONC REC -----------------------------------------------------------------------------... CALCIUM MG/L 30551402 16.6 16.2 2 65.1 50.0 97 CHROMIUM MG/L 30550801 0.018 0.016 12 0.898 1.00 88 .... POTASSIUM MG/L 30551402 13.8 13.6 1 62.6 50.0 98 .,. MAGNESIUM MG/L 30551402 6.4 6.4 0 30.8 25.0 98 SODIUM MG/L 30551402 1060 1050 0.9 1480 500 84

·~ LEAD MG/L 30445105 <0.10 <0.10 NA 1. 01 1. 00 lOl

~ % Recovery = (Spike Sample Result - Sample Result) ------------------------------------ X 100 Spike Concentration

RPD (Relative Percent Difference) = (Sample Result - Duplicate Result) ---------------------------------- X :0:

Average Result

"'

A AnolyticoiTechnologies,lnc.

GCMS - RESULTS


CLIENT PROJECT # PROJECT NAME CLIENT I.D. SAMPLE MATRIX

COMPOUNDS

CHLOROMETHANE BROMOMETHANE

GIANT REFINING CO. (NONE) ANNUAL GRDWTR SMW-3 (TOTAL) AQUEOUS

VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE C.~BON DISULFIDE 1 1 1-DICHLOROETHENE 1 1 1-DICHLOROETHANE 1 1 2-DICHLOROETHENE (TOTAL) CHLOROFOR..~ 1 1 2-DICHLOROETHANE 2-BUTl•.NONE (MEK) 1 1 1 1 1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1r1r2 1 2-TETR..~CHLOROETHP_~E 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1 1 1 1 2-TRICHLOROETHANE BENZENE CIS-1,3-DICELOROPROPENE 2-CF~OROETHX~VINYLETHER BR0!10FORM 2-HEY.A..NONE ( Y.:.BK) 4-METHYL-2-PENTANONE (:HIBK) TETRAChLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TO~.?.L XYLENES


1 1 2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) TOLUENE-DB (%)

ATI I.D. 30445501


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

101 101 101

04/29/93 04/30/93 N/A 05/05/93 UG/L

1

A AnalyticaiTechnologies, Inc. ADDITIONAL COMPOUNDS ($~~I-QUANTITATED)


ATI I.D. : 30445501

""' COMPOUNDS RESULTS


...


GCMS - RESULTS


CLIENT PROJECT # PROJECT NAME CLIENT I.D. SA.~PLE MATRIX

COMPOUNDS


GIANT REFINING CO. (NONE) ANNUAL GRDWTR SM""w-4 (TOTAL) AQUEOUS

VINYL CHLORIDE CHLOROETFJ>...NE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACET_14_TE BROMODICHLOROMET~~E 1,1,2,2-TETRACHLOROETRANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHt~VINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES


1,2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) TOLUENE-DB (%)

ATI I.D. 30445503


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <l

97 100 99

04/29/93 04/30/93 N/A 05/05/93 UG/L

1


~ TEST VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 30445503

" COMPOUNDS RESULTS


A Analytica!Technologies,lnc.

GCMS - RESULTS


...

CLIENT PROJECT # PROJECT NA.11E CLIENT I.D . S.AYJ.PLE MATRIX

COMPOUNDS



VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE

.,. 1, 1-DICHLOROETHENE 1 1 1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM

'"' 1, 2-DICHLOROETHANE 2-BUTANONE (MEK) 1 1 1,1-TRICHLOROETHANE

·"'" Ci\R30N TETR..Z\.CHLORIDE VINYL ACETATE BROMODICHLOROMET~~E

4i 1,1 1 2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICh'LOROETHENE

~ DIBROMOCHLOROMETHANE 1,1 1 2-TRICHLOROETHANE BENZENE

·"' CIS-1, 3-DICHLOROPROPENE 2-CHLOROETHl'LVINY'LETHER

.. BROMOFORM 2-HEXANONE (MBK)

"' 4-METHYL-2-PENT-~ONE (MIBK) TETRACHLOROETHENE TOLUENE

"" CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES


,. 1, 2-DICHLOROETHANE-D4 (%) BROMOFLUOROBENZENE (%) TOLUENE-DB (%)

ATI I.D. 30445505

DATE S.Al>'f..PLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

96 100 99

04/29/93 04/30/93 N/A 05/05/93 UG/L

1

-A Analytical Technologies, Inc.

ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)


ATI I.D. : 30445505

COMPOUNDS RESULTS


2h AnalyticaiTechnologies,lnc.

GCMS - RESULTS


CLIENT PROJECT :fl: PROJECT NAME CLIENT I. D. SAMPLE MP.TRIX

COMPOUNDS

CHLOROMETHANE "" BROMOMETHANE

VINYL CHLORIDE CHLOROETHANE


. .., METHYLENE CHLORIDE ACETONE

.. C_i\.RBON DISULFIDE v<l 11 1-DICHLOROETHENE

1,1-DICHLOROETHANE ,. 1,2-DICHLOROETHENE (TOTAL)

CHLOROFORJ1 ~ 1,2-DICHLOROETHANE

2 -BUTA.I\lONE ( MEK) 1,1,1-TRICHLOROETHANE

.... CARBON TETRACHLORIDE VINYL ACETATE

.. BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE

""' 1,2-DICHLOROPROPANE ,.. TR.~S-1,·3-DICHLOROPROPENE

TRICHLOROETHENE "" DIBROMOCF..LOROMETHANE

1,1,2-TRICHLOROETHANE ~ BENZENE "" CIS-1, 3-DICHLOROPROPENE

2-CHLOROETHYLVINYLETHER " BROMOFOR..'t1

2-HEXfu'WNE (MBK) "" 4 -KETHYL-2-PENTANONE (MIBK) .,. TETRACHLOROETHENE

TOLUENE ""' CHLOROBENZENE

ETHYLBENZENE " STYRENE _, TOTAL XYLENES

SURROGATE PERCENT RECOVERIES ,.

l,2-DICHLOROETHANE-D4 (%) ·~ BROMOFLUOROBENZENE (%)

TOLUENE-DB (%)

ATI I.D. 30445507

DATE S.Altf_FLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS DILUTION FACTOR

RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

105 98 97

04/29/93 04/30/93 N/A 05/06/93 UG/L

1

A AnalyticaiTechnologies,lnc. ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)

. .., TEST : VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 30445507

"" COMPOUNDS RESULTS


""

4 Anolytico!Technologies,lnc.

GCMS - RESULTS

TEST : VOh~TILE ORGANICS (EPA 8240)

CLIENT PROJECT # PROJECT NA..l'1E CLIENT I.D. SAMPLE MATRIX

COMPOUNDS


GIANT REFINING CO. (NONE) ANNUAL GRDWTR SMW-4D (TOTAL) AQUEOUS

VINYL CHLORIDE CHLOROETH...l\NE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1, 1-DICh"LOROETHENE 1,1-DICHLOROETH...l\NE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETH...l\NE CARBON TETRACHLORIDE VINYL ACET_!1,.TE BROMODICh"LOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1, ·3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE. 1,1,2-TRICF~OROETHANE BENZENE CIS-1,3-DICF~OROPROPENE 2-CHLOROEThrLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METhlL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES



ATI I.D. 30445509


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

102 96 97

04/29/93 04/30/93 N/A 05/06/93 UG/L

1

- A AnalyticalTechnologies,lnc. ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)


ATI I.D. : 30445509

------------------------------------------------;~~;~;~----------------------- COMPOUNDS -----------------------------------------------------------------------------. .,.. NO ADDITIONAL COMPOUNDS

·.~

""

A Analytica!Technologies,lnc. GCMS - RESULTS

REAGENT BLANK


CLIENT PROJECT # PROJECT NAME CLIENT I.D.

COMPOUNDS



ANNUAL GRDWTR REAGENT BLANK

VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CP~BON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CELOROFOR..'t-1 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE C.~~BON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHJL~E 1,2-DICP~OROPROPANE T~~S-1,3-DICHLOROPROPENE TRICHLOROETHENE DI3ROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFOR.M 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE ChLOROBENZENE ETHYLBENZENE ST:::"RENE TOT.~ XYLENES




RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

99 100 100

304455 05/05/93 05/05/93 UG/L N/A

A AnalyticaiTechnologies,lnc. GCMS - RESULTS

REAGENT BLANK


CLIENT '~* PROJECT #

PROJECT NAME CLIENT I.D.

COMPOUNDS


ANNUAL GRDWTR REAGENT BLANK


RESULTS

304455 05/06/93 05/06/93 UG/L N/A

'~ -----------------------------------------------------------------------------CHLOROMETHANE "" BROMOMETHANE

VINYL CHLORIDE CHLOROETHANE

"'" METHYLENE CHLORIDE ACETONE

"' CARBON DISULFIDE .... 1, 1-DICHLOROETHENE

1,1-DICHLOROETHANE .. 1, 2-DICHLOROETHENE (TOTAL)

CHLOROFORM ... 1,2-DICHLOROETK~E

." 2-BUTANONE (MEK) 1,1,1-TRICHLOROETFJlliE

·"" CARBON TETRACHLORIDE VINYL ACETATE

" BROMODICHLORO~ETHANE ... 1' 1, 2 I 2-TETFL~CHLOROETHANE

1,2-DICHLOROPROPANE ·"0 TRANS-1, 3-DICHLOROPROPENE

TRICHLOROETHENE . ., DIBROMOCHLOROMETHA.~E

1,1,2-TRICHLOROETHA.~E BENZENE

.,.. CIS-1, 3-DICHLOROPROPENE 2-CHLOROETh~VINYLETHER

"' BROMOFORl-1 ... 2-HEXANONE (Y..BK)

4-METHYL-2-PENTANONE (MIBK) "' 'I'ETRACHLOROETHENE

TOLUENE ... CHLOROBENZENE

ETHYLBENZENE STYRENE

.,. TOTAL XYLENES



TOLUENE-DB (%)

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

98 99 97




CLIENT PROJECT # PROJECT NAME REF I.D.

GIANT REFINING CO. (NONE) ANNUAL GRDWTR 30549805

ATI I.D.

DATE ANALYZED SAMPLE M.l!..TRIX UNITS

304455


-~ -----------------------------------------------------------------------------

,,

" ,,.

"'

411

COMPOUNDS

1,1-DICHLOROETHENE TRICHLOROETHENE CHLOROBENZENE TOLUENE BENZENE

DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC.

<1 50 44 88 50 100 <1 50 45 90 48 96 <1 50 48 96 49 98 <1 50 50 100 53 106 <1 50 50 100 52 104


RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result

-------------------------------- X 100 Average of Spiked Sample

RPD

13 6 2 6 4

'"I

""

"" ~ .. """






: ANNUAL G. W. 30445509

ATI I.D.

DATE ANALYZED SA.~LE MATRIX UNITS

DUP.

304455

: 05/06/93 : AQUEOUS

UG/L

DUP. SAMPLE CONC. SPIKED % SPIKED %

COMPOUNDS RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD -----------------------------------------------------------------------------1,1-DICHLOROETHENE <1 50 46 92 51 102 10 TRICHLOROETHENE <1 50 45 90 48 96 6 CHLOROBENZENE <1 50 46 92 48 96 4 TOLUENE <1 50 48 96 51 102 6 BENZENE <1 50 48 96 51 102 6




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REUNOUISHED BY: ' 2. Signature: T1me:

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Company:

RECEIVED BY: (LAB} 2.

IP:!J~ )oo5 P~~ Name: v pale:d __thTU.b e. s uw.s ~- --r3) 93 companA-n---_Q hi_

AT II nil~ Snn [~c·c1o (f>l'l) 4~>1\ ~~ 141 • l'honnix (GO?) 4% -1400 • Snnlllo (?OG) 7?fl HJ:J~> • l'c•ns;1cola (90•1) 4/410ll1 • l'mlland (~,O:J) fiM 0•14/ • Alhuqucrquo (505) 344-JTn DISTniDUTION: Whnc, Cnnary ·All • Pink- OnJGINATOn

Jh Analytical Technologies, Inc. 2709-0 Pan American Freeway. NE Albuquerque NM 87107

Phone (505) 344-3777 FAX (505) 344-4413

ATI I.D. 311307

December 2, 1993

Giant Refining Company Route 3, Box 7 Gallup, NM 87301

Project NamefNumber: SEMI-A. GDWTR


On 11/02/93, Analytical Technologies, Inc., (ADHS License No.

AZ0015), received a request to analyze aqueous samples. The

samples were analyzed with EPA methodology or equivalent methods.

The results of these analyses and the quality control data, which

follow each set of analyses, are enclosed.

Two bottle were received for each sample for electrical

conductivity analysis. At the client's request, both bottles

were analyzed. The results were as follows:

Sample

OW-11 MW-1 MW-2 MW-4 MW-5

EC; Bottle #1 (UMHOS/cm)

1840/1870 1090/1080 1100/1110 1140/1130 1110/1130

EC; Bottle #2 (UMHOS/cm)

1820/1880 1080/1090 1090/1090 1130/1150 1120/1130

EPA Method 150.1 and 8020 analyses were performed by Analytical

Technologies, Inc., Albuquerque, NM.

Total Organic Carbon and Total Organic Halide analyses were

performed by Analytical Technologies, Inc., 225 Commerce Drive,

Fort Collins, CO.

All other analyses were performed by Analytical Technologies,

Inc., 9830 S. 51st Street, Suite B-113, Phoenix, AZ.


4 Analytical Technologies, Inc.

~w4 ~LIENT : .r'ROJECT #

""'PROJECT NAME:

GIANT REFINING CO. (NONE) SEMI-A. GDWTR

ATI I.D.: 311307

DATE RECEIVED: 11/02/93


----------------------------------------------------------------------------------ATI # CLIENT DESCRIPTION MATRIX DATE COLLECTED

01 OW-11 AQUEOUS 10/29/93

02 MW-1 AQUEOUS 10/29/93

03 MW-2 AQUEOUS 10/29/93

04 MW-4 AQUEOUS 10/29/93

05 MW-5. AQUEOUS 10/29/93

06 OW-l AQUEOUS 10/29/93

==================================================================================

----TOTALS----

MATRIX # SAMPLES

AQUEOUS 6


The samples from this project will be disposed of in thirty (30) days from thE

date of this report. If an extended storage period is required, please contact

our sample control department before the scheduled disposal date.

~Analytical Technologies, Inc.

Giant Refining Company December 2, 1993 Page Two

If you have any questions or comments, please do not hesitate to

contact us at (505) 344-3777.

Manager

LAK: jd

Enclosur~

dh Analytical Technologies, Inc.


,.,. CLIENT PROJECT #

"" PROJECT NAME:

~

PARAMETER


ATI I.D. DATE RECEIVED: DATE ANALYZED:

UNITS 1A 1B 1C

311307 11/02/93 11/04/93

1D - -------------------------------------------------------------------------------PH ( 150 .1) UNITS 8.26 8.31 8.32 8.30



CLIENT PROJECT #

.,. PROJEC'J! NAME:

PARAMETER



UNITS 2A 2B 2C

311307 11/02/93 11/04/93

2D

'~ -------------------------------------------------------------------------------PH (150.1) UNITS 9.05 9.00 9.08 9.08

th Analytical Technologies, Inc.


"" CLIENT PROJECT #

.,.,. PROJECT NAME:

PARAMETER


UNITS 3A

ATI I. D. DATE RECEIVED: DATE ANALYZED:

3B 3C

311307 11/02/93 11/04/93

3D

- -------------------------------------------------------------------------------PH (150.1) UNITS 9.09 9.08 9.10 9.07



. ,. CLIENT PROJECT # .... PROJECT NAME:

PARAMETER

PH (150.1)

·•

GIANT REFINING CO . (NONE) SEMI-A. GDWTR


UNITS 4A 4B

UNITS 8.82 8.83

4C

311307 11/02/93 11/04/93

8.80

4D

8.80



. .., CLIENT PROJECT #

,. PROJECT NAME:

PARAMETER

PH (150.1)

GIANT REFINING CO . (NONE) SEMI-A. GDWTR

UNITS

UNITS


SA 5B

8.96 8.96

5C

311307 11/02/93 11/04/93

9.00

50

8.97

cc ..

l

4 Anolytico!Technologies, Inc.


CLIENT >~ PROJECT # ,. PROJECT NAME:

PARAMETER

PH (150.1)


UNITS

UNITS

ATI I.D.

31130704

ATI I. D. :

SAMPLE RESULT

8.82

DUP. RESULT

8.80

311307

RPD

0.2

(Sample Result - Duplicate Result)

RPD (Relative Percent Difference) = ---------------------------------- X lOC Average Result



CLIENT """PROJECT #

PROJECT NAME: "'"'

PARAMETER


UNITS ATI I.D.

ATI I.D.:

SAMPLE RESULT

DUP. RESULT

311307

RPD

"~ --------------------------------------------------------------------------------PH (150.1) UNITS 31130705 8.96 9.00 0.4


RPD (Relative Percent Difference) = ---------------------------------- X 100 Average Result

""

~ Analytical Technologies, Inc.


CLIENT PROJECT # PROJECT NAME:

PARAMETER


UNITS ATI I. D.

ATI I. D.:

SAMPLE RESULT

DUP. RESULT

311307

RPD

""' PH (150.1) UNITS 31130701 8.32 8.26 0.7


RPD (Relative Percent Difference) = ---------------------------------- X lOC Average Result




GIANT REFINING CO. (NONE) SEMI-A.GDWTR

ATI I.D. : 311307

DATE RECEIVED

REPORT DATE

11/02/93

12/02/93

-----------------------------------------------------------------------------PARAMETER UNITS

CONDUCTIVITY, (UMHOS/CM) PHENOLICS, TOTAL (EPA 420.1) MG/L

01 02 03

1840 1090 1100 <0.005 <0.005

04 05

1140 1110 <0.005

,.,'<#




GIANT REFINING CO. (NONE) SEMI-A.GDWTR ATI I.D. : 311307

------- -----------------------------------------------------------------------SAMPLE DUP. SPIKED SPIKE %

PARAMETER UNITS ATI I. D. RESULT RESULT RPD SAMPLE CONC REC

-----------------------------------------------------------------------------CONDUCTIVITY(UMHOS/CM) 31151801 990 1000 1 NA NA NA

PHENOLICS, TOTAL MG/L 31149914 <0.005 <0.005 NA 0.024 0.025 96

PHENOLICS, TOTAL MG/L 31149915 <0.005 <0.005 NA 0.026 0.025 104

% Recovery = (Spike Sample Result - Sample Result)

------------------------------------ X 100 Spike Concentration


Average Result

2b, Analytical Technologies, Inc. TOTAL ORGANIC CARBON Method 415.2

Lab Name: Analytical Technologies, Inc.

Client Name: ATI-NM

Client Project ID: GRC -- 311307

Lab Workorder Number: 93-11-016

Volume

Sample Lab Sample Injected TOC

ID ID (mL) Cone. (mg/L)

Reagent Blank RB 93-11-016 1 < 1.0

311307-1 93-11-016-01 1 3

93-11-016-01DUP 1 3

311307-2 93-11-016-02 1 < 1.0

93-11-016-02DUP 1 < 1.0

311307-3 93-11-016-03 1 < 1.0

93-11-016-03DUP 1 < 1.0

311307-4 93-11-016-04 1 < 1.0

93-ll-016-04DUP 1 < 1.0

311307-5 93-11-016-05 1 < 1.0

93-11-016-05DUP 1 < 1.0

Date Collected: 10/29/93

Date Analyzed: 11/08/93

Sample Matrix: Water

TOC RPD AVG

< 1.0 N/A

3 0

< 1.0 N/A

< 1.0 N/A

< 1.0 N/A

< 1.0 N/A


TOTAL ORGANIC HALIDE Modified Method 9020 TOX

Lab Name: Analytical Technologies, Inc. Date Collected: 10/29/93

Client Name: ATI-NM Date Extracted: 11/05/93

Client Project ID: GRC -- 311307 Date Analyzed: 11/05/93

Lab Workorder Number: 93-11-016 Sample Matrix: Water

Sample Lab Sample Sample TOX

ID ID Volume (mL) Cone. (ug/L)

Reagent Blank WRB93-11-016 100 <20

311307-1 93-11-016-01 100 200

93-11-016-01DUP 100 200

311307-2 93-11-016-02 100 <20

93-11-016-02DUP 100 <20

311307-3 93-11-016-03 100 <20

93-11-016-03DUP 100 <20

311307-4 93-11-016-04 100 <20

93-11-016-04DUP 100 <20

311307-5 93-11-016-05 100 <20

93-11-016-05DUP 100 <20


METALS RESULTS

CLIENT ?ROJECT f ?ROJECT NAME


ATI I.D. : 311307

DATE RECEIVED

REPORT DATE

11/02/93

12/02/93

-----------------------------------------------------------------------------?-~TER

C3ROMIUM (EPA 200.7/6010) ~~ (EPA 239.2/7421)

UNITS

MG/L MG/L

01 02 03 04 05

<0.010 <0.010 <0.010 <0.010 <0.010 <0.002 0.036 0.003 <0.002 0.002

,,



METALS - QUALITY CONTROL

GIANT REFINING CO. (NONE) SEMI-A.GDWTR ATI I. D. : 311307

-----------------------------------------------------------------------------

PARAMETER

CHROMIUM LEAD

SAMPLE DUP. SPIKED SPIKE %

UNITS ATI I.D. RESULT RESULT RPD SAMPLE CONC REC

MG/L MG/L

31155503 <0.010 <0.010 NA 1.04 1.00 104 31159801 0.002 0.002 NA 0.048 0.050 92


Spike Concentration


Average Result



-··

TEST CLIENT PROJECT # PROJECT NAME:

BTEX, MTBE (EPA 8020) GIANT REFINING CO. (NONE) SEMI-A. GDWTR

-~ SAMPLE I.D. # CLIENT I.D. MATRIX

06 OW-l

· PARAMETER

BENZENE TOLUENE ETHYLBENZENE

·~ TOTAL XYLENES METHYL-t-BUTYL ETHER

BROMOFLUOROBENZENE (%)

AQUEOUS

UNITS


DATE SAMPLED

10/29/93

06

<0.5 <0.5 <0.5 <0.5 <2.5

103

ATI I. D.: 311307

DATE EXTRACTED

NA

DATE ANALYZED

11/04/93

DIL. FACTOR

1


• TEST

,.>6 BLANK I.D. CLIENT PROJECT # PROJECT NAME:


REAGENT BLANK

BTEX, MTBE (EPA 8020) 110493 GIANT REFINING CO. (NONE) SEMI-A. GDWTR

ATI I.D. DATE EXTRACTED DATE ANALYZED DILUTION FACTOR:

311307 NA 11/04/93 1

.. -------------------------------------------------------------------------------PARAMETER

•• BENZENE TOLUENE

·• ETHYLBENZENE TOTAL XYLENES

., METHYL-t-BUTYL ETHER

BROMOFLUOROBENZENE (%)

UNITS


<0.5 <0.5 <0.5 <0.5 <2.5

103

-· ,,,.

"" ..


GAS CHROMATOGRAPHY - QUALITY CONTROL

TEST MSMSD # CLIENT PROJECT #

- PROJECT NAME:

PARAMETERS

MSMSD

BTEX, MTBE (EPA 8020) 31130706 GIANT REFINING CO. {NONE) SEMI-A. GDWTR

SAMPLE RESULT

CONC SPIKE

ATI I.D. DATE EXTRACTED:

311307 NA 11/04/93 AQUEOUS 31130706 UG/L

DATE ANALYZED SAMPLE MATRIX REF. I.D. UNITS

SPIKED ~ 0

SAMPLE REC DUP DUP

SPIKE ~ 0 REC RPD

-------------------------------------------------------------------------------BENZENE <0.5 10 11 110 10 100 10

TOLUENE <0.5 10 11 110 9.9 99 11

ETHYL BENZENE <0.5 10 11 110 10 100 10

TOTAL XYLENES <0.5 30 33 110 30 100 10

METHYL-t-BUTYL ETHER <2.5 20 20 100 20 100 0

(Spike Sample Result - Sample Result)

% Recovery = ------------------------------------- X 100 Spike Concentration


RPD (Relative Percent Difference) = X 10C

Average Result

"'


GCMS - RESULTS



COMPOUNDS


GIANT REFINING CO. (NONE) SEMI-A.GDWTR OW-11

: AQUEOUS

VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES



ATI I.D. 31130701

DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS

: 10/29/93 11/02/93 N/A 11/10/93

DILUTION FACTOR : UG/L

1

RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

105 99 101

,,

2k Analytical Technologies, Inc.

r:r::::ST


VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 31130701

~ -----------------------------------------------------------------------------CO~..POUNDS

RESULTS

~W ADDITIONAL COMPOUNDS


GCMS - RESULTS


CLIENT <·• PROJECT #


... PROJECT NAME CLIENT I.D. MW-1

.• SAMPLE MATRIX AQUEOUS

COMPOUNDS

~HLOROMETHANE

ROMOMETHANE

••

• INYL CHLORIDE ~HLOROETHANE

1ETHYLENE CHLORIDE , A-CETONE

CARBON DISULFIDE -• l, 1-DICHLOROETHENE

:. , 1-DICHLOROETHANE <,2-DICHLOROETHENE (TOTAL)

.• 'HLOROFORM ,~-DICHLOROETHANE

., 2-BUTANONE ( MEK) 1,1,1-TRICHLOROETHANE

CARBON TETRACHLORIDE

VINYL ACETATE BROMODICHLOROMETHANE

-~ 1, 1 , 2 , 2 -TETRACHLOROETHANE

1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE

... TRICHLOROETHENE DIBROMOCHLOROMETHANE

1,1,2-TRICHLOROETHANE

BENZENE '" CIS-1, 3-DICHLOROPROPENE

2-CHLOROETHYLVINYLETHER

BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK)

TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES



ATI I.D. 31130702


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

101 98 97

: 10/29/93 11/02/93 N/A 11/10/93 UG/L

1



T~ST VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 31130702

-----------------------------------------------------------------------------COMPOUNDS RESULTS

-----------------------------------------------------------------------------NO ADDITIONAL COMPOUNDS

4 AnolyticoiTechnologies,lnc.

GCMS - RESULTS

~EST : VOLATILE ORGANICS (EPA 8240)

:LIENT ?ROJECT # ?ROJECT NAME :::LIENT I.D. SAKPLE MATRIX

:OM:POUNDS

2HLOROMETHANE 3ROMOMETR..JlliE

GIANT REFINING CO. (NONE) SEMI-A.GDWTR MW-2 AQUEOUS

-IINYL CHLORIDE 2HLOROETHANE 21ETHYLENE CHLORIDE -~CETONE

CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CAqBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES



ATI I.D. 31130703


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

111 99 110

10/29/93 11/02/93 N/A 11/10/93 UG/L

1

4 AnalyticaiTechnologies,lnc.


~~ST : VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 31130703

-----------------------------------------------------------------------------COMPOUNDS RESULTS

-----------------------------------------------------------------------------:;o ADDITIONAL COMPOUNDS

,,

,,

••


GCMS - RESULTS

~~ST : VOh~TILE ORGANICS (EPA 8240)

CI.IENT ?:?.OJECT # ?:?.OJECT NAME CLIENT I.D. SAMPLE MATRIX

COMPOUNDS

CHLOROMETHANE 3ROMOMETHANE

GIANT REFINING CO. (NONE) SEM.I-A.GDWTR MW-4 AQUEOUS

\~INYL CHLORIDE CHLOROETHANE ~·~ETHYLENE CHLORIDE _:':._CETONE CARBON DISULFIDE l,1-DICHLOROETHENE l,1-DICHLOROETHANE l,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE ~iiNYL ACETATE 3ROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENE$



ATI I.D. 31130704

DATE SAMPLED DATE RECEIVED DATE EXTRACTED DATE ANALYZED UNITS

10/29/93 : 11/02/93

N/A : 11/10/93

UG/L DILUTION FACTOR : 1

RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

107 100 99



~~3T VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 31130704

-----------------------------------------------------------------------------CCMPOUNDS RESULTS

-----------------------------------------------------------------------------~W ADDITIONAL COMPOUNDS

,,


GCMS - RESULTS


CLIENT ·· GIANT REFINING CO. PROJECT # (NONE) PROJECT NAME SEMI-A.GDWTR CLIENT I.D. MW-5 SAMPLE MATRIX : AQUEOUS

COMPOUNDS

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CIU,OROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES



ATI I.D. 31130705


RESULTS

. <10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

110 99 100

10/29/93 11/02/93 N/A 11/10/93 UG/L

1



~~ST VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 31130705

COMPOUNDS RESULTS

-----------------------------------------------------------------------------,, NO ADDITIONAL COMPOUNDS

.,


GCMS - RESULTS

REAGENT BLANK


CLIENT PROJECT # PROJECT NAME CLIENT I.D.

GIANT REFINING CO. (NONE) SEMI-A.GDWTR REAGENT BLANK

COMPOUNDS

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE C-~BON TETRACHLORIDE VINYL ACETATE 3ROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES




RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

105 100 98

311307 11/10/93 11/10/93 UG/L N/A

"



~~3T : VOLATILE ORGANICS (EPA 8240)

CLIENT ?ROJECT # ?ROJECT NAME ?\:SF I.D.

GIANT REFINING CO. (NONE) SEMI-A.GDWTR 31149911

ATI I.D.


311307


-----------------------------------------------------------------------------DUP. DUP. SAMPLE CONC. SPIKED % SPIKED %

COMPOUNDS RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

-----------------------------------------------------------------------------1,1-DICHLOROETHENE <1 so 47 94 49 98 4

TRICHLOROETHENE <1 so 44 88 43 86 2

C:!LOROBENZENE <1 so 49 98 47 94 4

'?OLUENE <1 so 47 94 47 94 0

3:::NZENE <1 so 44 88 4S 90 2





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4 Anolylico/Technologies,lnc. Albuquerque, NM Chain of Custody DATE\\\~q~ PAGEl OFl_

NETWORK PROJECT MANAGER: BETH PROFFITI ANALYSIS REQUEST . ······· •.::·> .

COMPANY: Analytical Technologies, Inc. ~ s

············.•·.·.·. 0 e N I' ADDREss: 2709-D Pan American Freeway, NE Ul

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Albuquerque, NM 87107 .., 0 0

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.. ·<< PRQJECTINFQAtd~TIQN ·.· .. .·· !·-·< ? SAMPLE RECEIPT SAMPI.£S SENT TO: _{J_EUNOUISHED BY:'· • •1. · · ••••REUNCUISHEDBY:••: > > 2.'···· ...

PROJECT NUMBER: ?J l '.~I TOTAL NUMBER OF CONTAINERS 57<.) SAN DIEGO \. ~~:\~~ ~~:*~~

SlgnallJre: nme:

X. PROJECT NA~:._ GR.L

FT.COWNS

CHAIN OF CUSTODY SEALS tV/ I~ RENTON Prinl8dmQ: ~ Prinl8d Name: Date

_QG:-LEVEL~ IV INTACT? - ~li·q PENSACOLA ~A ~-'\ (\.3

( _nr. ,.., .. .,. '~"'-MS MSD BLANK RECEIVEO..'fQQ9. COND.£0LD Analytical Technologies, Inc. CompaJ-11 , ......... Albuquerque !t(h..;r{\..1....

TAT:"sJ:ANDAAn_) AUSHI LAB NUMBER 1 j - t 1 . ( ) I (,_ PHOENIX

'e,c:, ··.;_;: .eii{ ,<_ii_~i )' ,-.',}. / ],,;:.;]~\;i BARRINGER RECEIVED BY: CLABl.> < V: \ :. RECEIVED BY: CL.AB 2.

'i:'''"·,(, ~~~IIJrt: Time: Sig~re: Time:

DUE DATE: \\\\1~\~~ ~~~J"Dt-~~t-\ FIBEROJANT /., /'.t~ tiLl, t1 '/]0 I

· RUSH SURCHARhE: 1

-~w ~~ ~- Printed Name: Date: I Pf111ted Name: Date:

~~ vcr>nea..6.. 'J;I,..., (Lff, Y ):,, !1/i

CUENT DISCOUNT: - %~~~-~l"al6--~~·

CoJ/;~: Company:

~-\>e~<:l"'~~.o :.:.r-~ ~ ~ ' ·j_f h.-, rv. ./! 7ffc· . C\.f'OO.y = I:i Q '"· .

- - -· •••• - nc_ __ ,_ oNVt\ AN> AAM. ~noNLo /?MI??A.A~'\. Pensacola 19041474-1001 • Portland (503)6844147. Albuquerque (505) 344-3m DISTRIBUTION: Whle, Canary. ATt. Pink. ORIGINATOR

.£ t: ... j :, ~-. ·,:.·~

t ~ -~ t .. "' ~

A AnolylicoiTechnologies,lnc. Albuquerque, NM Chain of Custody DATE\\ ~\u PAGEL OFj_

NETWORK PROJECT MANAGER: BETH PROFFITT

COMPANY: Analytical Technologies, Inc.

ADDRESS: 2709-0 Pan American Freeway, NE Albuquerque, NM 87107

CLIENT PROJECT MANAGER:

< < : .: SAMPlE 10 I DATE I TIME

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PROJECT NUMBER: 3 ~()j . .. . TOTAL NUMBER OF CONTAINERS Sig rure~ r\ Time: Signature: Time:

·· ~ """ ""~ --- \H._\.\ ..tlli.a_ \1-1 s-~--- .~- -- ~-- --~- ----

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PHOENIX

DUE DATE:--~-~~~--RUSH SURCHARGE: 0'\ ~~ dQ\o.. ~~ Printed Harne:

~IE IT DISCOUNT: -11. ~~ ~~~- ~---t-b-:=::::=:-------~~~~~~::._~dS_~

O'Nl...~~ CJ\.... 3\1~-z~d...-40'-~f.P~ Company:

I <"\r6... crra \..X::O.___..J:l..\t"X;._c~c\. ~).0\ \ 13ol-~, ~ ~~~- ,4'1-r

ATI labs: San DWl\o (619) 458-9141 • Phoenix (602) 496-Moo • Seattle (206J-22~s • Pensacola (904) 474-1001 • Portland (503) 634-0447 • Albuquerque (505) 344-Jm [)STRIBU110N: WMe, Canary· All • Pink· ORIGIN A TOR

Jh AnalyticaiTechnologies, Inc.

December 20, 1993

Giant Refining Company Route 3, Box 7 Gallup, NM 87301

2709-D Pan American Freeway. NE Albuquerque NM 87107

Phone (505) 344-3777 FAX (50.5) ]44-441 <

ATI I.D. 312300

Project Name/Number: SEMI-ANNUAL (NONE)


On 12/01/93, Analytical Technologies, Inc., (ADHS License No.

AZ0015), received a request to analyze aqueous samples. The

samples were analyzed with EPA methodology or equivalent methods.

The results of these analyses and .the quality control data, which

follow each set of analyses, are enclosed.

Sample 31130004 A and B bottle contained a large headspace. Less

than half of the bottle contained sample.

EPA Method 150.1 was performed by Analytical Technologies, Inc.,

Albuquerque, NM.

Total Organic Carbon and Total Organic Halide analyses were

performed by Analytical Technologies, Inc., 225 Commerce Drive,

Fort Collins, CO.

All other analyses were performed by Analytical Technologies,

Inc., 9830 S .. 51st Street, Suite B-113, Phoenix, AZ.

If you have any questions or comments, please do not hesitate to

contact us at (505) 344-3777.

~~-Letltla Krakowskl, Ph.D. Project Manager

MR:jd

Enclosure

H. Mitchell Rub tein, Laboratory Manager


.,·

4h Analytical Technologies, Inc.

CLIENT GIANT REFINING CO.

PROJECT # (NONE) PROJECT NAME SEMI-ANNUAL

ATI I.D. : 312300

ATI :fi CLIENT DESCRIPTION

01 02 03 04

SMW-3 SMW-4 SMW-5 SMW-6



MATRIX DATE COLLECTED

AQUEOUS AQUEOUS AQUEOUS AQUEOUS

11/30/93 11/30/93 11/30/93 11/30/93

=================~====================================

======================

TOTALS -----

MATRIX # SAMPLES

AQUEOUS 4


The samples from this project will be disposed of in thirty (30) days from t

date of this report. If an extended storage period is required, please conta

our sample control department before the scheduled disposal date.

~• ~ AnalyticaiTechnologies, Inc.


• CLIENT PROJECT # PROJECT NAME:

GIANT REFINING CO. (NONE} SEMI-ANNUAL


312300 12/01/93 12/02/93

. -------------------------------------------------------------------------------PARAMETER UNITS lA 1B 1C 1D

PH (150.1) UNITS 7.66 7.68 7.71 7.72

A AnolyticoiTechnologies, Inc.


~LIENT

>ROJECT # 2ROJECT NAME:

GIANT REFINING CO. (NONE) SEMI -ANNUAL


312300 12/01/93 12/02/93

~ -------------------------------------------------------------------------------)ARAMETER UNITS 2A 2B 2C 2D

PH (150.1) UNITS 8.52 8.48 8.48 8.52



CLIENT PROJECT # :

.,, PROJECT NAME:

GIANT REFINING CO. (NONE) SEMI-ANNUAL


312300 12/01/93 12/02/93

~~ -------------------------------------------------------------------------------PARAMETER UNITS 3A 3B 3C 3D

PH (150.1) UNITS 8.74 8.71 8.76 8.76



:LIENT •ROJECT #

PROJECT NAME:

>ARAMETER

.. ,., PH ( 15 0 . 1)


UNITS

UNITS


4A 4B

8.14 8.15

4C

312300 12/01/93 12/02/93

8.05

4D

8.00



·"" 2LIENT PROJECT #

""' PROJECT NAME:

.,. PARAMETER

~ PH ( 150. 1)

GIANT REFINING CO. (NONE) SEMI -ANNUAL

UNITS

UNITS

ATI I.D.

31230001A

ATI I. D.:

SAMPLE RESULT

7.66

312300

DUP. RESULT RPD

7.75 1.17


RPD (Relative Percent Difference) = ----------------------------------X 100

Average Result

"' 2h Analytical Technologies, Inc.


.. ,. :LIENT PROJECT #

*'" PROJECT NAME:

- PARAMETER

PH (150.1}

GIANT REFINING CO . (NONE} SEMI-ANNUAL

UNITS

UNITS

ATI I.D.

31230003A

ATI I. D.:

SAMPLE RESULT

8.74

312300

DUP. RESULT

8.80

RPD

0.68


RPD (Relative Percent Difference) = Average Result

X 100



CLIENT GIANT REFINING CO. PROJECT # : (NONE) PROJECT NAME : SEMI-ANNUAL

PARAMETER

SPECIFIC CONDUCTANCE REP 2 REP 3 REP 4

UNITS

UMHO/CM UMHO/CM UMHO/CM UMHO/CM

01

3220 3250 3190 3230

02

1260 1270 1280 1270

ATI I.D. : 312300

DATE RECEIVED

REPORT DATE

03

1140 1140 1150 1150

04

1670 1650 1680 1670

12/01/93

12/20/93

2h Analytical Technologies, Inc. GENERAL CHEMISTRY - QUALITY CONTROL

CLIENT PROJECT # ?R.OJECT NAME

GIANT REFINING CO. (NONE) SEMI-ANNUAL ATI I.D. : 312300

---------------------------------------~-------------------------------------


. ? .r..R.l\METER UNITS ATI I.D. RESULT RESULT RPD SAMPLE CONC REC

SPECIFIC CONDUCTANCE - UMHO/CM 31230001 3220 3250 0.9 NA NA NA




Average Result

A Analytical Technologies, Inc. TOTAL ORGANIC HALIDE

Modified Method 9020 TOX

Lab Name: Analytical Technologies, Inc. Date Collected: 11/30/93

Client Name: ATI-NM Date Extracted: 12114/93

Client Project ID: GRC -- 312300 Date Analyzed: 12114/93

Lab W orkorder Number: 93-12-012 Sample Matrix: Water

Sample Lab Sample Sample TOX TOX

ID ID Volume {rnL Cone. (ug/L_) AVG

Reagent Blank WRB93-12-012 100 <20

312300-1 93-12-012-01 100 30

93-12-012-01DUP 100 30 30

312300-2 93-12-012-02 100 <20

93-l2-0l2-02DUP 100 <20 < 20

312300-3 93-12-012-03 100 <20

93-12-0l2-03DUP 100 <20 < 20

312300-4 93-12-012-04 100 20

93-12-012-04DUP 100 20 20

RPD

0

N/A

N/A

0


TOTAL ORGANIC CARBON

Method 415.2

Lab Name: Analytical Technologies, Inc.

Client Name: ATI-NM

Client Project ID: GRC -- 312300

Lab WorkorderNumber: 93-12-012

Volume

Sample Lab Sample Injected TOC

ID ID (mL) Cone. (mg/L)

Reagent Blank RB 93-12-012 1 < 1.0

312300-1 93-12-012-01 1 2

93-12-012-0lDUP 1 2

312300-2 93-12-012-02 1 < 1.0

93-12-0 12-02D UP 1 < 1.0

312300-3 93-12-012-03 1 < 1.0

93-12-012-03DUP 1 < 1.0

312300-4 93-12-012-04 1 < 1.0

93-12-012-04DUP 1 < 1.0

Date Collected: 11/30/93

Date Analyzed: 12/10/93

Sample Matrix: Water

TOC RPD

AVG

< 1.0 N/A

2 0

< 1.0 N/A

< 1.0 N/A

< 1.0 N/A




PARAMETER

CHROMIUM (EPA 200.7/6010) LEAD (EPA 239.2/7421)

UNITS

MG/L MG/L

ATI I.D. : 312300

DATE RECEIVED

REPORT DATE

01 02 03 04

<0.010 <0.010 <0.010 <0.010 <0.002 <0.002 <0.002 <0.002

12/01/93

12/20/93

A Analytical Technologies, Inc. METALS - QUALITY CONTROL

CLIENT PROJECT # ?ROJECT NAME

GIANT REFINING CO. (NONE) SEMI -ANNUAL ATI I.D. : 312300

------~------------------------------------------------------7---------------

?ARAHETER

CHROMIUM LEAD


UNITS ATI I.D. RESULT RESULT RPD SAMPLE CONC REC

MG/L MG/L

31252703 <0.010 <0.010 NA 0.986 1.00 99 31230001 <0.002 <0.002 NA 0.048 0.050 96


Spike Concentration

RPD (Relative Percent Difference) = (Sample Result - Duplicate Result) X 1(

Average Result

4· Analytical Technologies, Inc.

GCMS - RESULTS


CLIENT PROJECT # PROJECT Nk'1E CLIENT I.D. SAMPLE MATRIX

COMPOUNDS


GIANT REFINING CO. (NONE) SEMI-ANNUAL SMW-3 AQUEOUS

VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-:-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE Ck~BON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES


1,2-DICHLOROETHANE-04 (%) BROMOFLUOROBENZENE (%) TOLUENE-DB (%)

ATI I.D. 31230001


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10· <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

100 100 101

11/30/93 12/01/93 N/A 12/08/93 UG/L

1

A AnalyticalTechnologies,lncADDITIONAL COMPOUNDS (SEMI-QUANTITATED)

T~ST : VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 31230001

COMPOUNDS RESULTS

!.;O ADDITIONAL COMPOUNDS

·"" A Analytical Technologies, Inc.

GCMS - RESULTS


CLIENT PROJECT # PROJECT NA..l'1E CLIENT I.D. SAMPLE MATRIX

COMPOUNDS



VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1 1 1-DICHLOROETHENE 1 1 1-DICHLOROETHANE 1 1 2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1 1 1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1 1 2-DICHLOROPROPANE TRANS-1 1 3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1 1 1 1 2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES



ATI I.D. 31230002


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

101 99 101

11/30/93 12/01/93 N/A 12/08/93 UG/L

1

4 AnolyticoiTechnologies,lnc. ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)


ATI I.D. : 31230002

COMPOUNDS RESULTS



GCMS - RESULTS


CLIENT PROJECT # "PROJECT NA.l'1E CLIENT I.D. SAMPLE MATRIX

COMPOUNDS



VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-BUTANONE (M.EK) 1,1,1-TRICHLOROETHA.NE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETK~~E

1,1,2,2-TETRA.CHLOROETHA.NE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHA.NE 1,1,2-TRICHLOROETHA.NE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES



ATI I. D. 31230003


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

101 99 101

11/30/93 12/01/93 N/A 12/08/93 UG/L

1

A AnalyticaiTechnologies,lnc.ADDITIONAL COMPOUNDS (SEMI-QUANTITATED)

=~ST : VOLATILE ORGANICS (EPA 8240)

ATI I.D. : 31230003

COMPOUNDS RESULTS

~D ADDITIONAL COMPOUNDS

·?


GCMS - RESULTS



COMPOUNDS


GIANT REFINING (NONE) SEMI-ANNUAL SMW-6 AQUEOUS

VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFORM 1,2-DICHLOROETHANE 2-SUTANONE (MEK) 1,1,1-TRICHLOROETHANE CP~BON TETP~CHLORIDE

VINYL ACETATE BROMODICHLOROMETHANE 1,1,2,2-TETRACHLOROETHANE 1,2-DICnLOROPROPANE T~~S-1~3-DICHLOROPROPENE

TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

co.



ATI I.D. 31230004


RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

100 100 101

11/30/93 12/01/93 N/A 12/08/93 UG/L

1



ATI I.D. : 31230004


-----------------------------------------------------------------------------NO ADDITIONAL COMPOUNDS

2h Analytical Technologies, Inc. GCMS - RESULTS

REAGENT BLANK


CLIENT PROJECT # ?ROJECT NAME CLIENT I.D.

COMPOUNDS


GIANT REFINING CO. (NONE) SEMI-ANNUAL REAGENT BLANK

VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1,1-DICHLOROETHENE 1,1-DICHLOROETHANE 1,2-DICHLOROETHENE (TOTAL) CHLOROFOR..l'1 1,2-DICHLOROETHANE 2-BUTANONE (MEK) 1,1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETK~E

1,1,2,2-TETRACHLOROETHANE 1,2-DICHLOROPROPANE TRANS-1,3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1,2-TRICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-CHLOROETHYLVINYLETHER BROMOFORM 2-HEXANONE (MBK) 4-METHYL-2-PENTANONE (MIBK) TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES




RESULTS

<10 <10 <1 <1 <5 <10 <1 <1 <1 <1 <1 <1 <10 <1 <1 <10 <1 <1 <1 <1 <1 <1 <1 <1 <1 <10 <5 <10 <10 <1 <1 <1 <1 <1 <1

101 100 101

312300 12/08/93 12/08/93 UG/L N/A

""





COMPOUNDS

GIANT REFINING CO. (NONE) SEMI-ANNUAL 31230004

SAMPLE CONC. RESULT SPIKED

ATI I. D.


DUP. SPIKED % SPIKED SAMPLE REC.SAMPLE

312300


DUP. %

REC. RPD

-----------------------------------------------------------------------------1,1-DICHLOROETHENE <1 50 53 106 53 106 0

TRICHLOROETHENE <1 50 51 102 48 96 6

CHLOROBENZENE <1 50 51 102 50 100 2

TOLUENE <1 so 51 102 49 98 4

BENZENE <1 50 51 102 51 102 0


Spi~e Concentration



..

~ Ana lytico ITechnologies,lnc., Albuquerque, NM

~ San Diego • Phoen1x • &3attle • Pensacola • Ft. Collins • Portland • Albuquerque

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'J/'7vv7 6- ~ 7V w _,/ . tV A1

PHONE: (5?;5") 7-z--z.. oZ-z.J 7

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FAX: C (7J 5) L. z_-z... o '2-1 o

BILL TO: C; /J-../r COMPANY: P'-r-s ~X 7 ADDRESS: '(;{ A-LL-VI" 'tvn1 f' ?'}tJ I

(NORMAL)

i, " t ' j

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CHAIN OF CUSTODY

Date:

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