Northern Petrochemical Company

Northern Petrochemical CompanyHighway 30 West*Clinton, Iowa 52732

February 13, 1985

Mr. David V. Crawford

Waste Manaqement Branch

U. s. Environmental Branch 324 East 11th Street Kansas City, Missouri 64106

Dear Mr. Crawford:

Enclosed with this letter are three copies of the procedure to be

followed durinq further investigations of the area referenced

point 106 in the documents written by T.er r aôn <:ons “1 s> F^C 'Please arrange for review of this document by the staff of EPA

so that investigative work in this area may proceed.

If you have questions relative to this document, ple3se refer them

to Richard Cotton. Mr. Cotton's telephone number is (202) 862 100

His mailing address is contained in copies of the Consent 0

currently being reviewed by EPA.

Sincerely,

u f

Robert E. SchulerSr. Environmental Engineer

NorChem, Clinton Works

1 •- :— K— ; V V_

•' C.U tj (j ftu. L-

oJPSitfUND ScCiiGN

30306259

Superfund

October 30, 1984

Company P0 Box 819 Clinton, IA 52732

1 a aCONSULTANTS, INC.

13709 9 StreetP.O. Box 37332 .

Orraha. Nedrt~2s -2'-- (402) 330-2202

Geralc H. Olson. P.9.James A. Cun.nincn.am.Jonn F. Har'.'.veil. Pa.Charles W. flovey II Keven M. Jefteris

ATTN: Mr. Robert E. Senior Plant

Schuler, P.E.Environmental Engineer

RE: Environmental Monitoring Program Protocol

Site 106 . TChemplex Company, Clinton, IowaTCI Job No. 783558-5

near Mr. Schuler:■n find a revised final draft of the proposed environmental mom-

Attached you wi s EpA Region VII. The proposed scope of work istoring program as requested by US . under Section 3013

intended to satisfy the ^ located

RCRA as they relate to suspec central portion of thein the vicinity of Monitoring Well *106 m

Chemplex Company, Clinton, Iowa plant site.

&.,« you ,.v. any ouestions ,, re9ard to Cached protocol, pUasa do

™t hesitate to contact me immediately.

Very truly yours, -

TERRAC0N CONSULTANTS, INC.

Enel.

JFH'.mpl

^ .v O •. »;ii|945l -f

V~r£®-'- XTo vJ T

• o » ••............ Offices In:Iowa: Cedar Falls. Cedar Raoids. Davenocrt.

Oes Mcines. Starm Laxe Kansas: Wichita. Kansas City

Nebraska: Omaha Oklahoma: Oklahcma City. Tulsa

necnnical. Environmental and Materials Eng

table of contents

Terracon Consultants, Inc.

\)

C)

D)

E)

F)

Introduction......................................................

Program Rationale............................................................

Safety Program............................................................

Scope of Services..........................................................

Task l--Regional Flow Evaluation....................................

Task 2—Subsurface Exploration & Monitoring Program.........

Geotechnical Exploration - Subtask 2.1...............................

Reconnaissance - 2.1 (A)............................... .............

Drilling Methods - 2.1 (B)...................................................

Physical Soil Testing - 2.1 (C)........................................

Decontamination Procedures - 2.1 (D).............................

Hydrogeologic Study - Subtask 2.2..........................................

Monitoring Well Installation - 2.2 (A)........................

Shallow Monitoring Well Nests - 2.2 (A) 1...........

Deep Monitoring Well Nests 2.2 (A) 2......................

Well Security - 2.2 (B)..........................................................

Well Development - 2.2 (C)...............................................

Water Level Monitoring & Aquifer Testing - 2.2 (D)

Analytical Assessment - Subtask 2.3......................................

Groundwater Sampling - 2.3 (A)..........................................

Analytical Testing Program - 2.3 (B).............................

Task 3—Engineering Report.................................................

Project Management.........................................................................................

General Comments...........................................

PAGE1

2

3

3

3

4

4

4

5

5

6

6

6

6

7

8

8

9

10

10

11

11

12

13

y

APPENDIX "B II

Site Area Safety Plan

for Chemplex Company

Revised October 30, 1984

vnti) irs b mi or oi S vor

SITE/AREA SAFETY PLAN

iral

Date Prepared: 10/4/84 Job No.: 784558

Project Name: Chemplex Company

sting Information for Site: Detailed_X___ PreliminarySketchyNone___

saminant Form: GasLiquid X Sludge X Solid

:ainment: DrumPitPondLagoonTankSoi Is X Debris__X:her Landfill cells previously buried; construction detail unknown

•acteristies: CorrosiveFlammableRadioactiveVolatile X Toxic__âctive Other Unknown X

'fective: February 1985pa^^By: David E. Koch

ition: Clinton, Iowa

!l 1

I

i/AREA SPECIFICS

lest Hazard Materials:

Compound Concentration Warning Properties

:ohthalene 25.7% i n pure waste sludae See Attachment “A"-Methylnaohthalene 12.3% i n pure waste sludae See Attachment “A"Tr:‘hy 1 naphthalene 14.0% i n pure waste sludae See Attachment “A"

jBthylene 10.3% i n pure waste s ludae See Attachment "A"idtflB 11.6% in cure waste sludge See Attachment “A"

^Topography' Glaciated area within 5 miles of Mississippi River

:ory::erence TCI #783524, 783602, 733609, 783216, 781586

ual Features:ive burnoff flare adjacent to Site 108; not a fire hazard

.RD ASSESSMENT

UATION:sed upon data research, previous work/monitorinq, and previousrk may be conducted for drilling operations with regard __________lishmg Basin as low hazard areas. Test pit operations into landfill areas should regarded as intermediate hazard areas for personnel and require intense entry

________analytical testing,to Site 106, 108 and the

njtoring. Contaminant characterization done under earlier phases of work expectedy to all work areas as it is primary waste output.

ENVIRONMENTAL MONITORING PROGRAM PROTOCOL

Site #106

Chemplex Company

Clinton, Iowa

TCI Job No. 783558-5

October 30, 1984

Chemplex Company

•PO Box 819Cl inton, IA 52732

ATTN: Mr. Robert E. Schuler, P.E.Senior Plant Environmental Engineer

RE: Environmental Monitoring Program ProtocolSite 106Chemplex Company, Clinton, Iowa TCI Job No. 783558-5

Dear Mr. Schuler:

Attached you will find a revised final draft of the proposed environmental moni

toring program as requested by US EPA Region VII. The proposed scope of work is

intended to satisfy the investigative requirements defined under Section 3013

RCRA as they relate to suspected waste releases from the landfill cells located

in the vicinity of Monitoring Well #106 in the west central portion of the

Chemplex Company, Clinton, Iowa plant site.

Should you have any questions with regard to the attached protocol, please do

not hesitate to contact me immediately.

CONSULTANTS, INC.

13709 3 Street P.O. Box 37332 Omaha. Nec.-aska 63137 (402) 330-2202

Gerald R. Olson, P.E.James A. C-.nningham. P.E. Jonn P Harwell. P.E. Charies W. Fovey II Keven M. Jevieris

Very truly yours,

TERRACON CONSULTANTS, INC.

>s.

John F. Hartwell, P.E. Iowa #9451

James A. Cunningham, P.E. Iowa #7738

Enel.

JFH:mpl

;l^9451 :f->> 1

t * •Offices In:

Iowa: Cedar Falls. Cedar Rapids. Davenport.Des Moines. Storm Lake

Kansas: Wichita. Kansas City Nebraska: Omana Oklahoma: Oklahoma City. Tulsa

Geotechnical. Environmental and Materials Engineers

Terracon Consultants, I

PAGEA) Introduction........................................................................................................................ 1

B) Program Rationale............................................................................................................. 2

C) Safety Program.................................................................................................................... 3

D) Scope of Services............................................................................................................. 3

Task l--Regional Flow Evaluation................................................................ 3

Task 2--Subsurface Exploration & Monitoring Program........................... 4

Geotechnical Exploration - Subtask 2.1................................................. 4

Reconnaissance - 2.1 (A)......................................................................... 4

Drilling Methods - 2.1 (B)..................................................................... 5

Physical Soil Testing - 2.1 (C).......................................................... 5

Decontamination Procedures - 2.1 (D)............................................... 6

Hydrogeologic Study - Subtask 2.2............................................ ............... 6

Monitoring Well Installation - 2.2 (A).......................................... 6

Shallow Monitoring Well Nests - 2.2 (A) 1............................. 6

1 Deep Monitoring Well Nests 2.2 (A) 2........................................ 7

Well Security - 2.2 (B)............................................................................ 8

Well Development - 2.2 (C)...................................................................... 8

Water Level Monitoring & Aquifer Testing - 2.2 (D)................ 9

Analytical Assessment - Subtask 2.3........................................................ 10

Groundwater Sampling - 2.3 (A).............................................................. 10

Analytical Testing Program - 2.3 (B)............................................... 11

Task 3--Engineering Report................................................. ................................. H

E) Project Management.............. .................................................................. .......................... 12

F) General Comments................................................................................................................ 13

TABLE OF CONTENTS

TABLE OF CONTENTS


APPENDIX A

Figure #1 Work Schedule

Figure #2 Location Diagram

Figure #3 Driller's Log Sample

Figure #4 Typical Shallow Monitoring Well Detail

Figure #4A Typical Multi-Staged Well detail

Figure #5 Monitoring Well Detail Legend

Figure #6 Boring Log Sample

Figure #7 Sample Control Document

Figure #8 Chain of Custody

APPENDIX B


ENVIRONMENTAL MONITORING PROGRAM PROTOCOL

SITE 106Terracon Consultants, Inc.

CHEMPLEX COMPANY

CLINTON, IOWA

Revised

October 30, 1984


A) INTRODUCTION

The objective of this study is to obtain detailed stratigraphic and hydrogeolo

gic information with respect to a portion of the Chemplex Company plant site

located due east of the polishing basin in the area of Monitoring Well #106.

The study area is designated as Site #106.

Site #106 is located in the south central portion of the Chemplex Company,

Clinton, Iowa plant site. The study area is approximately 300 feet east of the

plant polishing basin. As part of the Phase I Groundwater Monitoring Program,

Monitoring Well #106 was installed in November, 1981. Hydrocarbon contamination

was observed in Monitoring Well #106 in mid 1983. The purpose of this study is

to obtain additional stratigraphic and hydrogeologic information in the area to

determine the source of groundwater contamination.

Our technical approach for this study is presented under the Scope of Services

section presented herein. The program rationale and a detailed presentation of

the work tasks to be performed are presented along with the discussion of safety

procedures. In addition, a section on project management is included which

discusses quality control procedures for field work and the anticipated sche

dule. A set of attachments includes a diagram of proposed boring locations,

typical monitoring well installation details as well as an example of final,

typed boring logs which contain monitoring well details. A Chain of Custody

documentation is also included.

-1-

Revised

October 30, 1984


B) PROGRAM RATIONALE


The following data acquistion requirements must be fulfilled in order to

accomplish the subsurface and hydrogeclogic assessment.

1. Explore the site geologic conditions to develop detailed cross sections of overburden deposits and bedrock surface in the area. Drilling and sampling procedures should allow for the direct observation for heavily contaminated zones which will in turn assist in the determination ofthe most probable source and avenues of contaminant migration.

2. Explore hydrogeologic conditions by providing suitable instrumentation which will permit the development of horizontal and vertical flow hierarchy, information on ■groundwater flow rates and direction, and the potential influence of released contamination on the regional bedrock aquifer system.

3. Provide suitable instrumentation for obtaining groundwater quality samples from unconsolidated overburden and bedrock monitoring points in order to determine the extent of suspected phase separation of hydrocarbon contaminants released from the landfill area, and to delineate the contaminant plume.

These project requirements will be fulfilled by completion of the tasks

described in the section on Scope of Services. An evaluation of regional flow

characteristics of the uppermost bedrock aquifer will be accomplished through a

review of available literature on adjoining test borings and operating wells and

a limited groundwater sampling and water level measurement program. The

geotechnical and hydrogeologic investigation at this site entails a completion

of five shallow monitoring wells and four nested bedrock wells on an approximate

200 foot grid spacing surrounding Monitoring Well #106.

-2-

Terracon Consultants. Inc.Revised

October 30, 1984


C) SAFETY PROGRAM

Terracon Consultants, Inc., has significant experience with regard to working in

hazardous and toxic waste contaminated areas, and specifically has significant

experience from work performed at the Chemplex plant in the vicinity of the

polishing basin. The type of contamination anticipated in the landfill area is

believed to be similar to that encountered in the polishing basin investigation

and clean up project. The principal groundwater contaminants appear to be

naphthalene, 1 methyl naphthalene, 2 methyl naphthalene, acenaphthalene, ace-

naphthene, styrene and a number other organic compounds. Although benzene has

generally not been detected in significant amounts in previous site investiga

tions, appropriate safety measures will be taken to minimize the potential for

exposure of personnel working in the area. A Site Area Safety Plan with

Hazardous Substance Data Sheets is included in Appendix B of this protocol.

D) SCOPE OF SERVICES

TASK 1—REGIONAL FLOW EVALUATION

Logs of producing water wells or any test borings available from the Iowa

Geologic Survey located within a three mile radius of the plant site will be

reviewed and evaluated with regard to information on the uppermost usable

bedrock aquifer. Depending upon the number of wells identified, their use and

location relative to the site and the suspected regional flow direction, water

level measurement, groundwater sampling and user interviews may be conducted in

order to evaluate the potential impact of aquifer contamination in the area. A

qualified hydrogeologist or engineer will perform the regional flow evaluation

with on site field data acquisition being performed with the cooperation of

Chemplex Company personal.

-3-

Revised

October 30, 1984



TASK 2—SUBSURFACE EXPLORATION & MONITORING PROGRAM

Nine soil borings instrumented with multiple monitoring wells will be installed

in the area of study. These borings will be positioned in an approximate 200

foot grid spacing centered on Monitoring Well #106. The following is a detailed

description of the major subtasks to be performed.

Geotechnical Exploration - Subtask 2.1

Based upon the information presented in previous reports (TCI Job No. 781566 and

781586), we anticipate encountering weathered dolomite bedrock at a depth of

approximately 60 feet. Overlying the bedrock surface is a complex system of

loess and glacial till derived soils. Shallow groundwater perched within the

loess and glacial till soils may be anticipated. Groundwater was encountered in

Monitoring Well #106 within 10 feet of the ground surface. Considering these

conditions, the drill rig employed at the site will need both auger and rotary

wash boring capabilities. Each of the boring locations proposed on the attached

location diagram (Figure #2) appear to be accessible to truck-mounted drill

rigs.

Reconnaissance - 2.1 (A)

Upon approval of US EPA Region VII of the proposed scope of work, specific

siting of each of the soil borings and groundwater monitoring well locations will be performed during a site reconnaissance conducted jointly by Chemplex ^

Company and Terracon Consultants representatives. At this time, the nine soil

borings will be located and marked with construction staking and flagging. The

locations will be determined to an accuracy of at least + 3 feet horizontally.

Natural ground elevations will be determined at this time to a level of accuracy

of + .1 feet vertically. Similarly, protector pipe elevations with the moni

toring wells installed during this phase of work will be determined recorded

following completion of the monitoring well point. The number and location of

-4-

Revised

October 30, 1984


Terracon Consultants, Inc

these borings may be modified depending upon data obtained as the drilling

program progresses. The approximate location of the proposed borings and moni

toring wells is indicated on the attached location diagram (Figure #2).

Drilling Methods - 2.1 (B)

If possible, the borings will be completed using continuous flight auger ^

drilling methods. Continuous flight augers will be pulled at .5 ...or .10-foot

intervals with minimum rotation to maintain a reasonable sample integrity. Bag;-'-v

samples will be obtained at minimum 5-foot intervals, at major stratigraphic

changes or at noteable contamination zones, whichever interval is less. Four of

the soil borings (at each corner) will be advanced to auger refusal in the dolo

mite bedrock. An attempt will be made to penetrate the bedrock a minimum of 2

feet to confirm the presence of the bedrock. After drilling and measurement of

water levels, each boring will be instrumented with two or more 2-inch diameter

monitoring wells nested in the common hole.

In the case of the four deeper borings, rotary wash boring may be required to

advance the boring and maintain the side of the hole without cave in. Drilling

water will be obtained from an approved plant site source. Drilling fluid addi

tives such as the thin, sejf-degrading drilling fluid (Revert) or the thinnest

workable mix of bentonite drilling fluid may be required to maintain the bore

hole. Temporary casing or hollow stem augers may also be required to maintain _/'

the borehole. Casing and hollow stem augers will be used as needed.

Physical Soil Testing - 2.1 (C) _ ; Jr ^ •

Disturbed soil samples will be obtained'from the soil borings. Representative

soil samples will be selected for routine laboratory testing. This testing will

include moisture content and limited gradation testing. Each soil sample will

be classified in accordance with the Unified Soil Classification System.

-5-

Revised

October 30, 1984



Decontamination Procedures - 2.1 (D)

The working end of each drilling rig used at the site will be decontaminated

prior to arrival at the site and prior to leaving the site at the completion of

the job using a high pressure, hot water detergent spray wash with a high

pressure, hot, clean water rinse. The source of wash water will be the same as

that used for the wash boring drilling fluid.

To minimize the possibility of crosshole contamination, the working end of the

drill rig, drilling rods, augers, tools and samplers will be decontaminated bet

ween borings using the high pressure, hot water wash/rinse cycle described

above. To avoid downhole contamination, well materials will be decontaminated

prior to insertion into the boring using the high pressure, hot water wash/rinse

procedure. Additionally, the monitoring wells will be installed immediately

following completion of the borehole. If undisturbed samples are required,

samplers and rods which are inserted into the hole will be decontaminated using

the either the above described procedure or a hot water detergent scrub with a

dionized water rinse.

HYDROGEOLOGIC STUDY - Subtask 2.2

This portion of the discussion of the scope of work presents the monitoring well

installation procedures as well as well development and groundwater monitoring

procedures.

Monitoring Well Installation - 2.2 (A)

Shallow Monitoring Well Nests - 2.2 (A) 1

The shallow groundwater monitoring well points will be nested within each of

five of the nine borings performed at the site as shown on the attached location

diagram (Figure #2). Typically, 5 to 10 feet of manufactured 2-inch diameter,

-6-


flush-threaded schedule 40 PVC plastic well screen will be installed at the bot

tom of each of these borings. Screen slot size will be .01 inches. Two-inch

diameter, fl ush-threaded schedule 40 solid wall PVC plastic riser pipe will be

attached to the well screen and extend to approximately 2 feet above ground sur

face. Clean, washed (Muscatine #3) select gravel pack will be placed around the

well point to a depth of at least one foot above the top of the lowest well

screen. A minimum of 3 feet of tamped bentonite will be placed above the gravel

pack interval. The depth of these five borings is anticipated to be from 25 to

30 feet. The mean depth of the lower screened interval should be approximately

20 feet below the first encountered groundwater level. A shallow screened

interval will be installed within the same borehole and will be positioned so

that the first encountered groundwater level splits the screened interval. The

bentonite seal discussed above will extend from the top of the lower screen gra

vel pack to the bottom of the gravel pack placed for the upper screen. The

upper screened interval may range from 5 to 10 feet in length and the gravel

pack, which is placed around it, will extend 1 foot above and below the screened

interval. Above the upper screened interval, a minimum of 3 feet thickness of

tamped bentonite seal will be placed and the remainder of the boring will be

grouted using wet or dry cement bentonite grout. If a dry cement bentonite

grout mixture is placed, it will be tamped in the boring. If a wet bentonite

grout is placed, it will be inserted in the boring using bottom tremie grout

techniques. The remainder of the boring will be grouted to minimize the oppor

tunity of downhole contaminant migration from overlying contaminated layers and

the influence of surface water infiltration along the boring annulus.

Deep Monitoring Well Nests 2.2 (A) 2

Depending upon the drilling procedure used and the subsurface conditions encoun

tered at the site, three monitoring well points consisting of 5-foot screened

intervals connected to solid stem riser pipe which extends to ground surface

will be installed in each of the four deep monitoring wells at the location

shown in Figure #2. The first alternative is three monitoring wells nested

within a common borehole. The depth of the lowest screened interval will be

Revised

October 30, 1984


-7-


just above the bedrock surface. The intermsdiate screen will be positioned at a

mean screened depth of 20 feet below the first encountered groundwater and the

upper screened interval will be positioned so that the first encountered ground-

water level splits the screened interval. Gravel pack consisting of Muscatine

#3 select material will be placed in the boring annulus around the screened

interval to a distance of not more than one foot beyond the screened interval in

either direction. The screened intervals will be separated by tamped bentonite

seals to minimize the opportunity for downhole contaminant migration between the

gravel packed intervals. Above the uppermost bentonite seal, wet or dry cement

bentonite grout will be placed to surface in the same fashion as described above

for the shallow monitoring well nest.

An alternative to nesting the 2-inch diameter, fl ush-threaded PVC well points in

a common borehole is to insert single monitoring points in multiple borings.

This procedure may be elected considering the degree of difficulty in drilling

and the degree of contamination in the overlying layers. In this case, each

monitoring well point would be installed at the bottom of each successively more

shallow boring and completed with gravel pack, minimum 3-foot bentonite seal and

grout to the surface.

Well Security - 2.2 (B)

Each monitoring well and monitoring well cluster will be secured using a large

diameter steel protector pipe embedded in the boring annulus a minimum of 2i

feet. The steel protector pipe will be secured with a lockable hinge cap and

key padlock. The keys will remain in the custody of Terracon Consultants until

well development is completed at which time the keys will be turned over to the

custody of the Chemplex project engineer.

Well Development - 2.2 (C)

Following well installation, each well will be developed by introducing

compressed air into the well casing at a point a few feet above the top of

Revised

October 30, 1984


-8-

Terracon Consultants, Incr\cv lieuOctober 30, 1984 .TCI Job No. 783558-5 j

screen. The buoyant effect of compressed air on the water column allows large

volumes of water to be removed from the well in short periods of time. The sub

sequent dramatic lowering of water pressure at the screen is very effective in

dislodging drilling fluid cake and reversing flow of the drilling fluid which

may have migrated short distances into the adjoining aquifer. This method would

be used during the initial stage of well development with the final removal of

sediment and development water being accomplished either by bailing or submer

sible pump.

Well development will continue until the well water is clear or representative

of the surrounding aquifer. A minimum of three times the saturated annulus

standing water volume of the well shall be removed. Water samples shall be

obtained at the beginning, during and near the completion of well development

for field testing of temperature, pH and specific conductance. Following the

removal of three saturated annulus standing water volumes (regardless of

effluent clarity) the well will be considered developed if the field measured

parameters have stabilized.

A minimum two week waiting period will be allowed prior to well purging for ana

lytical sampling.

Water Level Monitoring & Aquifer Testing - 2.2 (D)

Groundwater levels will be recorded at various times during the drilling, soil

sampling, well installation and pre-well sampling period. Water levels encoun

tered during drilling and sampling operation will be recorded on the driller's

log, see Figure #3. Water levels will be recorded prior to beginning develop

ment operations. Following completion of well development, water levels will be

measured and recorded weekly until the first analytical sample is obtained.

Water levels will be measured and recorded prior to purging each well point for

analytical sampling.

-9-

Revised

October 30, 1984



A complete set of water level measurements should be made every two weeks for

the first month and at monthly intervals for the next five months. Frequency of

later water level monitoring will be determined after six months.

Limited aquifer testing in the form of bailing tests will be performed on

selected monitoring well points to determine the average horizontal hydraulic

conductivity of the adjoining aquifer system.

Analytical Assessment - Subtask 2.3

This section describes groundwater sampling procedures and briefly discusses the

analytical sampling program which will be performed by Chemplex Company and

others.

Groundwater Sampling - 2.3 (A)

It was mentioned earlier under Well Development (2.2 (A) 5), that a minimum two

week waiting period will be allowed between completion of well development

operations and collection of the initial analytical groundwater sample. Each

monitoring well will be equipped with a dedicated bottom discharge bailer. The

bailer assembly will consist of a 5-foot long, li-inch diameter schedule 40 PVC

bailer equipped with a Teflon valve seat and a Delrin ball check valve assembly.

The bailer will be suspended from the well point cap using a multiple filament

braided hollow core nylon rope.

Immediately before sampling, the groundwater level will be measured and

recorded. Monitoring wells will then be purged by pumping or bailing a volume

of water equivalent to three times the calculated volume of standing water in

the well casing. Sufficient volume of water will be collected from each moni

toring well to allow all specified analysis to be performed. Should well

recharge within a 10 hour period be insufficient to generate the volume of water

required for specified analysis, a reduction in the minimum purged volume will

be considered.

-10-


Groundwater samples will be collected by Chemplex Company personnel trained in

use of water level measurement devices, sampling equipment and documentation

procedures. Duplicate samples will be obtained for the initial analytical

sampling round. One set of samples will be analyzed at the Chemplex Company

laboratory and the second set will be transported to a qualified, independent

analytical laboratory contracted by Chemplex Company for confirmation testing.

The use of duplicate samples and analysis on additional sampling rounds will be

determined based upon the results obtained from the initial round.

Analytical Testing Program - 2.3 (B)

The sample containers for the initial sampling round will be provided by

Chemplex Company and the contract laboratory. For each duplicate sample set,

the environmental sample control sheet shown in Figure #7 will be completed.

For each duplicate sample, completed Chain of Custody records shown in Figure #8

will accompany the sample through the transportation and testing process.

Samples retained by Chemplex Company will be analyzed for hydrocarbon content

using High Pressure Liquid Chromatography (HPLC) following Chemplex test proce

dure STP-X-210. Each groundwater sample will be analyzed for benzene, toluene,

styrene, naphthalene, fluorene, phenanthrene, anthracene, and pyrene. Samples

will generally be reported in parts per rniljion concentrations.

\ >-

Duplicate split samples which are sent to the contract laboratory will be ana

lyzed for the same hydrocarbon compounds using existing EPA standard procedures.

We understand that QC/QAP presentations will be forwarded to US EPA Region VII

office prior to commencement of field sampling activities.

TASK 3 - ENGINEERING REPORT

Revised

October 30, 1984


As in Phase I through IV investigations, a written report will be prepared which

presents the information obtained under the work tasks described above. The

impact of regional flow data, stratigraphic, hydrogeologic and analytical test

data will be used to assess the potential for local and regional migration of

-11-

Revised

October 30, 1984



contaminant released in the area of Monitoring Well #106. The report will present

our analysis of the source of the contamination encountered in Monitoring Well

#106 and will provide a relatively detailed description of containment and reco

very procedures which may be suited for controlling migration of the released

contamination if conclusions of this nature can be drawn. We anticipate

approximately 15 working days will be required to complete this report. The

report preparation will start following receipt of the analytical test data and

at least three groundwater level monitoring rounds.

E) PROJECT MANAGEMENT

The tasks described above will be performed by or under the direction of

Terracon Consultants, Inc. All field work including verification of surveying,

drilling procedures, monitoring well installation procedures and well develop

ment will be conducted in the presence of a project field engineer or project

field geologist. The first round of groundwater sampling and each of the first

three rounds of water level measurement will be performed under the direction of

the project engineer/geologist. The project engineer/geologist will be respon

sible for compiling the geologist field journal. A copy of the geologist's

field journal will be included with the final engineering report along with

descriptive photographs taken at the site during field operations.

The project work schedule shows the breakdown of tasks to be performed along

with the sequential flow of work (See Figure #1). The schedule should be con

sidered as a proposed guideline only, as actual conditions in the field will

most likely require modification of the actual scope of work. Weather con

ditions during the late fall and winter months are anticipated to cause delays

in the execution of work. Delays due to extreme weather conditions have not

been considered in producing the attached work schedule.

-12-

October 30, 1984TCI Job NO. 783558-6 Terracon Consultants,

F) GENERAL COMMENTS

The procedures presented in this protocol are based upon data obtained from pre

vious studies at the site as well as other information not necessarily discussed

herein. This protocol has been prepared for the exclusive use of our client for

the specific application to the project discussed and has been prepared in

accordance with generally accepted geotechnical engineering practices. No other

warranty, expressed or implied, is made. In the event that any changes in the

nature, design or location and configuration of the study area as outlined in

this report are determined, the procedures contained in this protocol may not be

considered valid unless the changes are reviewed and modified or verified in

writing by the geotechnical engineer.

JFH:mpl

-13-

Inc.

TASK1 Regional Flow

2 Subsurface Exploration

Geotechnical

Recon.---------

Dri11ing--------------------

Soil Testing-------------

Decon____________ __

Hydrogeologic

Shallow Wells-----------

Deep Wells----------------

Well Security-----------

Development --------------

W.L. Mon.------------------

Aquifer Test.------------

Analytical

Sampling-------------------

Testing------------------ —

3 Engineering Report

Analysis ------------------

Prelim. Report---------

Client Review----------

EPA Review-------- -------

Final Report------------

O 19 20 29 9 to IS 20 29 S <0 19 20 29

Mar 85June 85

Feb 859 10 19 20 2 9

Mar 85

9 lO >9 2)

Apr 85 May 85

9 10 19 20 29U IQ 19 20

O Proposed Shallow Monitoring Well Location (Double Screen Above Bedrock) (5)

• Existing Monitoring Well #106

<§b Proposed Deep Monitoring Well Location (Triple Screen Above Bedrock) (4)

(Figure #2)

GROUNDWATER CONTAMINATION STUDY SITE .106

CHEMPLEX COMPANY XLINTON, IOWA JFH

Terracon Consultants, Inc,i!

(lll.=10Q,j 10/1/841783558-6

engineer driller

helper .

RIG NO. _

SURFACE ei.ev. ____

BORING STARTED __

boring completed

STATION _______ _

OFFSET ____________

SAMILL1NG

SIZE I >/,' ID 2* OD HAMMER: MOfl DROP: 30'

ST SIZE------------ - ST. SIZE___casing used _____ size

water level o w ■ ATIONS-------- ws OR WD

-------- BCR ACR

-------- AB---------------- Hr. AB

WLWLWLWL

—- ' ^------------------------ -----------------------------------__ WEATHFR

£

aEnA

Elevin orlion

M.i *9Cl JS sA A

PENETRATION KEC'OKI)R Qp Screen Length ft./ Top Screen

Gravel Pack Top / Q.Seal Length ft

So

il Ph

Od

or

*

£6X

6

Split Spoon Blows

Leng

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,

in Fe

et

oE - u 5 * A

u CC o a.

6* 6* ft* 6*Grout Length ft./ Top of Pine

We 11 Marking /Protector Pipe Yes/No./ Lock Yes/No1 F -------- y

Sample Description

FIG

UR

E 3.

1

24 Hr. ABABBREVIATIONS

A S • Auger Simple M S • Hollow 5tcm Auger S.T - SheIby Tube S S • Split Spoon D.B * Diamond Bit P.A • Power Auger R.B. - Rock Bit W.S. ■ While Simpling W.D. • While Drillini B C.R ■ Beforing Cuing

RemovalA C H - After Cuing

RemovalA.B. • After Boring

DRILL CREW CHECK LIS

Topsoil Thickncu

Fill Thickncu

CAVE IN LEVEL:

While Drilling and Sampling .

After Boring Completion .

water loss:

At--------------- To

Percent Lois _____

At --------------- To .

Percent Lo»i

BOULDERS OR OBSTRUCTK

At —_______ To -

At ----------- --- To

ARTESIAN PRESSURE:

Depth

Height of Soil Rite In Casing _______

Figure 4

MONITORING WELL INSTALLATION DETAILS

IDEALIZED STRATIGRAPHIC

PROF ILE*

SHALLOWWELL

TYPICAL SHALLOW MONITORING WELL DETAIL CHEMPLEX COMPANY

CLINTON, IOWA

TYPICAL WELL DETAILS

Well Cap

2" I.D. Schedule 40 PVC Plastic, Well Casing

Bentonite/Sand GroutMixtureBentonite Seal(3' typical thickness)Non-Glued, Flush-ThreadedJoint

Select Gravel Pack

5 feet, 2" I.D., Schedule 40, PVC Plastic, .01" Factory-Slotted Well Screen

Bottom Cap

JFH


10-1-84 |784558-6

Figure rr4A

40'

30'

20'

10'

8" Diameter, 5' Steel Protective

JM-

Wk

..."cal multi-staged well oetail

BEDROCK GEOHYDROLOGICAL ASSESSMENTPART 2CHEMPLEX COMPANY CLINTON, IOWA

DM Office


nr* I h IS ^ t7fl?574j=A

FIGURE 5.

MON I TOR ING WELL OETAll i EGENf)

OESCRIPT ION

Natural Ground Surface Elevation

Zone of Well Casing Sealed by

Fill Soil Auger Cuttings

Bentonite Seal- Grout Interface

Zone of Well Casing and Pelletized

Bentonite Seal (Min. 3' Thickness)

Sand Pack- 8entonite Seal Interface

Zone of Well Casing and Sand Filter

Pack

Elevation of Top of We I I Screen

Zone of Well Screen and Sand Filter

Pack

Elevation of Bottom of Well

PtMUOl

r

<

... r V £•£?*.

673. 1

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( ft. )

(ft. )

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fEflrtACON CONSUL TAN fs INC

FIGURE 7.

INC.TERR ACON CONSULTANTS,

Project_____

TCI Job No.

Collector's Sample No.

ENVIRONMENTAL SAMPLE CONTROL

HAZARDOUS MATERIALS

Company's Name Telephone No. ( )

AddressNumber Street City State Zip Code

Co I Iector1s NameSignature

Telephone No. ( )

Date Sampled Time Sampled hours

Sample Point Type: Soil 8oring ______ Sediment

Sludge ______ Surface Water

Other ___

Surface SoiI

Ground Water

Sample Location:

Field In formation/Remarks:

Sample Allocation:

1)________________________ __________________

Name of Organization

2) ____________________________________Name of Organization

3)Name of Organization

CONSTRUCTION SERVICES

ELO ENGINEERING ANO TESTING

1 •

Figure #8 Collector's Sample

CHAIN Of CUSTOOY RECORD

Location of Sampling

Shipper Name:

Address: Number Street . City State Zip Code

Collector's Name:Telephone: ( )Signature

Date SampledTime Sampled hours

e of Process Producing Waste

Id Information

ProducerHauler _______ Disposal Site

Other: Sample

jr<QUlSHeo BY

ealeo

RECEIVED BY

UNSEALED f-

’date TIME REASON FOR CHANGE OF CUSTOOY

unsealed I | SEALED

.INOUISHEO av RECEIVED 8Y OATE TIME REASON FOR CHANGE OF CUSTOOY

EALEO unsealeo( j SEALEO UNSEALEOP

.INQUISMEO av RECEIVED 8V OATE TIME REASON FOR CHANGE OF CUSTOOY

EALEO UNSEALECi | sealed UNSEA LEDp

.inquisheo av receiveo av

unsealed)

OATE TIME REASON FOR CHANGE OF CUSTOOY

EACEO UNSEALEq ]sealed

,IÛUtSl-»£0 8Y RECEIVEO 8V

unsealeoP

oa r£ TIME REASON FOR CHANGE OF CUSTODY

SAl.^tjv. unsea lecT- |sealed

.in^Bico av RECEIVED aY OATE TIME REASON FOR CHANGE OF CUSTOOY

ealeo UNSEALEOl—,“I SEALED UNSEALED!-

APPENDIX "B


for Chemplex Company

Revised October 30, 1984

SITE/AREA SAFETY PLAN

GENERAL

Date Effective: February 1985 Date Prepared: 10/4/84 Job No.: 784558prepared By: David E. Koch Project Name: Chemplex Company

Location: Clinton, Iowa_____________________________________________________ _

Existing Information for Site: Detailed X PreliminarySketchyNone___

Contaminant Form: GasLiquid X Sludge X Solid

Containment: DrumPitPondLagoonTankSoils X Debris X Other Landfill cells previously buried; construction detail unknown

Characteristics: CorrosiveFlammableRadioactiveVolatile X Toxic__Reactive Other Unknown X

SITE/AREA SPECIFICS

Highest Hazard Materials:

Compound Concentration Warning Properties

Naphthalene 25.7% in pure waste sludqe See Attachment "A"1-Methyl naphthalene 12.3% in pure waste sludqe See Attachment “A"2-Methyl naphthalene 14.0% i n pure waste sludqe See Attachment "A"

^ Acenapthylene 10.3% in pure waste s ludqe See Attachment "A"VIndene 11.6* in pure waste sludqe See Attachment “A"

Site: Topography Glaciated area within 5 miles of Mississippi River

History:Reference TCI #783524, 783602, 783609, 783216, 781586

Unusual Features:Active burnoff flare adjacent to Site 108; not a fire hazard

HAZARD ASSESSMENT

EVALUATION:Based upon data research, previous work/monitorinq, and previous analytical testing, work may be conducted for drilling operations with regard to Site 106, 108 and the Polishing Basin as low hazard areas. Test pit operations into landfill areas should be regarded as intermediate hazard areas for personnel and require intense entry monitoring. Contaminant characterization done under earlier phases of work expected"

B^to apply to all work areas as it is primary waste output..

Decontamination Procedures:

Personnel: Disposable Tyvek clothing, wash before eating (off site), shower as soon as possible at end of day's work. Standard procedures.

sonnel Protective Equipment Detergent wash of rubber boots and gloves

Sampling Equipment High pressure hot water detergent wash with methanol rinse.

Support Equipment High pressure hot water detergent wash with methanol rinse.

Decon Materials Required: Methanol, clean source of water, Alconox detergent,DOT 55-gallon drums for stand-by.

Special Hazards: Plant fire; signified by fire siren.

EMERGENCY PROCEDURES

High Hazard Materials (known or anticipated)

:ame

khthalenesSene

Benzene

ACUTE EXPOSURE SYMPTONSReference Printout_____Reference Printout_____Reference Printout

FIRST AIDReference Printout Reference Printout Reference Printout

Location of Nearest Working Phone: Ethylene Control Unit

Other Emergency Communications: Plant Engineering Building

EMERGENCY TELEPHONE NUMBERS:

NAME/LOCATION PHONE #

Ambulance Clinton Medical Transport 242-5742Fire Chemplex/Clinton /242-0125Pol ice Clinton 242-5742Hospital Jane Lamb Memorial/Clinton 243-1131

St. Joseph Mercy Hospital 243-5500Environment^ : Iowa Department of Waster,Air,and Waste Management 319-653-2135

US EPA Reqion VII 816-374-6864Uti1ities: Plant

Underground Plant Location Service, Inc. 1-800-242-8983

OPERATIONAL PROCEDURES

Site Command and Control (include sketch or map as appropriate):

Perimeter ControlEstablished by plant fence

paging Area Old fire control area SW of flare, decon area same

Heavy Equipment Requirements CME 750 or equivalent equipment, water truck, backhoe

Personnel Protection

General Level of Protection Required: ABC to D Modified

Modification or Specialized Equipment: Level C based on previous work historybut with respiratory equipment on stand-by at drill rig. Level C for test pit work with SCBA available.

Detection Equipment:TLV Bacharach in conjunction with benzene and naphthalene colorimetric detectors, 02 and LEL

Communications:Hand signals, emergency air horn, headset radios if needed.

Tentative Team Personnel

Name Position Medical (Date)Dave Koch Safety Officer/Technician Prior to MobilizationKeith Potts Safety Technician it

bay Healey Senior Crew Member II

*0 Be Named Crew II

To Be Named Crew II

Other Personnel:

Name Agency/Company RestrictionsNone at this time ___________________________________

Monitoring Procedures:Total hydrocarbon checks to be made periodically in accordance with TCI ~,'-~ "Environmental Safety Procedures11 .Testing to be conducted at “waist-to-f ace" working zone. Utilize Bacharach TLV Sniffer, colorimetric tubes and O2 /LEL

~TTRrtFTT-------------------------------------------------------------------- - ~

ADDITIONAL RESOURCES:

Name Agency/Company Telephone No.

Route to Hospital Highway 30 to Manufacturing Drive. Left to Bluff Boulevard. "* Right to Hospital, approximately one mileAlternative Highway 30 to 16th Avenue North (approx. 5 miles); Left to Hospital, one block.

EQUIPMENT CHECKLIST

Protective and Safety Equipment:

MSA Dual Purpose PD (1)SC8A________Escape Mask Full Face MSA (2); Willson"!?! Canister As Needed Hardhat

Spare Cylinders (1)

Face ShieldTTT______Safety GlassesA1J Gloves: Inner Neoprene Chem

"(3)

Gas Mask Respirators MSA Backmount (2)Half Face MSA (5); Willson (8); Norton (2) Cartridge OV as needed

Ear ProtectionChem Goggles T3T

N/A

Chem Resist Coveralls Polylaminated Splash Aprons PVC as needed Boots

Butyl Outer Cloth

RubberSplash Suits Tyvek

Fully Encapsulated Suitsîrst Aid Eguipment________________

Wash Station At Rig/trailer |ty Harness_

"N/XBoot/Shoe Covers N/A

As needed

On-site trai ler____________________________ ___________~ Fire Extinguisher Trailer/Rig (1 ea.) ______ Special Tools As needed

Final Report To:Robert Schuler, Chemplex Date 10-9-84

Post Site Medicals

Plan Approved By Date 10-9-84David E. Koch, S.O.

A

JlT13—1,

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MW #106

X^ \x

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sX /

xc

200 1

<2>- 200’ &

O Proposed Shallow Monitoring Well Location (Double Screen Above Bedrock) (5)

• Existing Monitoring Well #106

<fi> Proposed Deep Monitoring Well Location (Triple Screen Above Bedrock) (4)

"*■ Staging and Entry Areas

(Figure #2)

GROUNDWATER CONTAMINATION STUDY SITE 106

CHEMPLEX COMPANY CLINTON, IOWA


JFH r=100c 10/1/84 783558-6

ATTACHMENT A-l

HAZARDOUS SUBSTANCE DATA SHEET

m OF

Common:

SUBSTANCE:

White tar,

Naphthalene; 1-, 2-methyl naphthalene

tar camphor________ Chemical C3.0 Hg

I. PHYSICAL/CHEMICAL PROPERTIES SOURCE

Normal physical state: Molecular weight DensitySpecific Gravity Solubility: (water) Solubi1ity:Boiling Point Melting Point Vapor Pressure Vapor Density Flash Point Autoignition point Odor Threshold LEL 0.9%UEL 579%

X Gas ________ Liquid Volati le Solid128 Hazardlinem

IIT7I45 @ 5

.003 G @ 20C(3 "

424°F@ 1 atm. 5165°-176°F

.05 mmHq 20C 477 Î74*Fg7g3p

.3 ppm "

II. PERMISSIBLE EXPOSURE LIMITS

10 ppm OSHA/ACGIH to prevent eye irritation 15 pom ACGIH

500 ppm OSHA/NIOSH

CERCLA: Toxicity 2 Ignitabi 1 ity__2Reactivity 0 Persistence_________ 3

III.HAZARD CHARACTERISTICS

Entry: Inhalation YesIngestion YesSkin/eye Absorption Yes Skin/eye Contact YesOther:Carcinogen Experimental

Incompatibilities Not applicable to si

Radioactive No Alpha Radiation Beta Radiation Gamma Radiation

Site Hazard Rationale

Low Low Odor Threshold; DilutionLow_____ Dilution, Previous MonitoringLow_____ Previous MonitoringLow_____ Previous Monitoring

IV. PROTECTIVE CLOTHINGSplash GarmentsPolylaminated Tyvek_______________________________________Boots ________Rubber_______________________________________________ ________________ _Gloves! Inner Neoprene Outer Butyl Work(Eye Protection Goggles, safety glasses with side shields or visors. Eye wash. Respiratory: Organic vapor cartridge with dust filters on air-purifying, half-face

respirators_____________________________________ _____________________

ATTACHMENT A-2


AME OF SUBSTANCE:

ommo n:

Acenaphthylene

PNA Chemical


Normal physical state: Molecular weight DensitySpecific Gravity Solubility: (water) Solubility:Boiling Point Melting Point Vapor Pressure Vapor Density Flash Point Autoignition point Odor Threshold LEL UEL

Gas ________ Liquid X SolidT52.2______ Hazard!inem

.8988 & ~insoluble @ 20C

<a509^52?°F @1 atm198°-199°F_______

N/A rrmHq §

Not applicable Not applicable


None Established None Established None Established

CERCLA: Toxicity 3 Iqnitability 1 Reactivity0

III.HAZARD CHARACTERISTICSSite Hazard

Persistence 3

Rationale

Entry: Inhalation No_____ ____________ _________________Ingestion . Yes Low flecon Procedure'Skin/eye Absorption NoSkin/eye Contact NoOther:

Incompatibilities

Radioactive No Alpha Radiation_ Beta Radiation _ Ganrna Radiation

IV PROTECTIVE CLOTHINGSplash Garments Polylaminated TyvekBoots RubberGloves: Inner Neoprene Outer Butyl WorkEye Protection VisorRespiratory Half-face air-purifyinq respirator with organic vaoor

cartridges and dust filters.

ATTACHMENT A-3


NAME OF SUBSTANCE: Benzene

Common: Benzol, Coal Naphtha___________ Chemical Cg Hg


Normal physical state: Molecular weight DensitySpecific Gravity Solubility: (water)Solubi1ity:Boiling Point Melting Point Vapor Pressure Vapor Density Flash Point Auto ignition point Odor Threshold LEL .33%UEL~~~ 7.1%


___ Gas X Liquid Solid78.08____________ ____ Hazardlinem

.8790 tT 17820 ppm @ 2UC "

(3 “IT

176°F0 1 atm "“ 42°F 17

75 mmHq 20C "2.8 0 “

T2*F 17928aF "

1.5-5 ppm ^

TWA 10 ppm OSHA/ACGIH , 25 ppm OSHA ceiling ___________________________STEL 25 ppm ACGIH; 50 ppm OSHA 10-min. ceiling; 10 ppm NIOSH 60-min. ceiling IDLH 2000 ppm OSHA/NIOSH ~ "—

CERCLA: Toxicity 3 Ignitabi1ity 3 Reactivity 0 Persistence 1

III.HAZARD CHARACTERISTICS

Entry: Inhalation YesIngestion YesSkin/eye Absorption YesSkin/eye Contact YesOther:

Site Hazard Rationale

LowLowLowLow

Negligible in sludge waste Negligible in sludge waste Negligible in sludge waste Negligible in sludge waste

Incompatibilities Strong oxidizers, sulfuric acid, zinc in steam

Radioactive No Alpha Radiation Beta Radiation Gamma Radiation

IV. PROTECTIVE CLOTHINGSplash Garments Poly laminated T.yvek or SaranexBoots Viton, Butyl RubberGloves: Inner Neoprene Outer Viton, Butyl WorkEye Protection GoqqlesRespiratory: Full-face organic vapor respirator to aDDroximately 5 DDm,

suDplied air resoirator 0 10 ppm above background

HAZARDOUS SUBSTANCF data sheft

name of SUBSTANCE: Indene

Co,rnrnon:__Indonaphthene r, . .- ------- Chemical Cq f-ig

I. PHYSICAL/CHEMICAL PROPERTIES

Normal physical state- Molecular weight DensitySpecific Gravity Solubility: (water)Solubi1ity:

SOURCE

Gas"116.17"

_Liquid _gm/ml "Hazard lTne"

Solid

”1.006insoluble

T

Boiling Point Melting Point Vapor Pressure Vapor Density Flash Point Auto ignition point Odor Threshold LEI Combustible DEL'Uombustib Ip

~359^F~@~T'atm'29T

N.A. mmHq

T73°F

H. PERMISSIBLE EXPOSURE LIMITS

10 ppm ACGIH is ppm ACGIH None Specified

CERCLA: Toxicity__2___lgni-tability

III.HAZARD CHARACTERISTICSReactivity 0 Persistenre 2

Site Hazard

YesYesNo

LowLow

Rationale

Only irritants at site concentrations

Yes

jHtry: InhalationIngestionSkin/eye Absorption"Skin/eye Contact ' ,e;s , ----------------------------------------------------

Incompatibilities K— -----------

Radioactive Alpha Radiation Beta Radiation Gamma Radiation

No

IV. PROTECTIVE CLOTHING Splash GarmentsBoots__Gloves: Inner

■>.. E-/e Protection" Respiratory:

_D;vek,; Regular or Polv1aminJfow

^°Pref1e jOutlr RubberWork

L

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