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earch, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail Gas Fraction Control System for a Gas Evolving Electrochemical Reactor Craig E. Nelson - Consultant Engineer
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Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Mar 26, 2015

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Page 1: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Gas Fraction Control System

for a

Gas Evolving Electrochemical Reactor

Craig E. Nelson - Consultant Engineer

Page 2: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Reactor Controller Functional Diagram

Block Diagram for “Bubbleostatic” Operating Mode

-LoopDynamicsCircuit

StandbyCurrentSource

Set Point

+Counter – Anode – Ec – Red

Working – Cathode – EwBlue-Green

Cathodic (“Negative”) current

Bubble

Electric“Eyes”

SensorSupportCircuit

ParameterExtractionCircuit

VoltageControlledPowerSupply

Standby

Page 3: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Reactor Control System Block Diagram

BubbleDetectorSupportCircuit

Signal SmoothingCircuit

ParameterExtractionCircuit

LoopDynamicsCircuit

VoltageControlledCurrentSource

“PID” Loop DynamicsPhotons

V2 V3 V4 V5

Iout

ControllerSet point

V1

Parameter ExtractionDetection StandbyCurrentSource

I1

I2Standby

Det1 Det2

Current DriversPowerSupply

Page 4: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

1. Controller should provide at least a second order transfer function

2. Controller should provide easy adjustability of the transfer function dynamics

Requirements - Loop Dynamics

Page 5: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Loop Dynamics - The PID Controller

Page 6: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Concept 1 – Absolute Amplitude Feedback

Input scaling andoffset

Amplify

Integrate

Differentiate

Output scaling andoffset

“PID” Dynamics

Vin

V4 V5

Vout

Set point

V1

Page 7: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Parameter Extraction

1. Accept signals from one or more concentration sensing sources

2. Pre-process the sensor signal as required

3. Extract various parameters from the concentration sensor as required

4. Scale and offset the parameter signals as required

Page 8: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Typical Bubbleogram 512 Samples

Page 9: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Typical Bubbleogram Descriptive Statistics

Page 10: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Power Spectral Density

Page 11: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Page 12: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Autocorrelation

Page 13: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Page 14: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Current Noise Signal Analysis

Page 15: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Current “Noise” Signal

Page 16: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Current “Noise” Power Spectral Density

Page 17: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Current “Noise” PSD

Page 18: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Current “Noise” Autocorrelation Functions

Page 19: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Current “Noise” Autocorrelation

Page 20: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Cross Comparison – Bubbleogram vs. Current Noise - Waveforms

Page 21: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Waveforms

Bubbleogram Current Noise

Page 22: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Cross Comparison – Bubbleogram vs. Current Noise – Power Spectral Density

Page 23: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Power Spectral Density

Bubbleogram Current Noise

Page 24: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Cross Comparison – Bubbleogram vs. Current Noise – Autocorrelation

Page 25: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Autocorrelation

Bubbleogram Current Noise

Page 26: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

System Control Parameter Extraction - Amplitude

Page 27: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Concept 1 – Absolute Amplitude Feedback

Input scaling andoffset

Signal Smoothing

Absolute Value

Vin

V2

Vout

V1

Page 28: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Concept 2 – Detrended Abs Amplitude Feedback

Bubble Detector

VarianceEstimator + LP Filter

Detrender

BubblesIn

V2

Vout

V1 BoundaryAlarmGenerator

IntegratorV10V9

Integrator Preset

Mean Estimator

Cell Driver

Vset

V4

V3

V7

V5

V2

Median Filter

V1

V2 = median(V1i … V1i+N)mean(V2i …V2i+N)

Var(V2i …V2i+N)

V6

BUsetBLset

V8

V5 = 1 if (V4 > BUset)

V6 = 1 if (V4 < BLset)

V7 = Pu if (V5 =1)

V8 = Pl if (V6 =1)

med(V2i …V2i+N)

Page 29: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

The “Median” Filter

Page 30: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Concept 2 – Bubble Rate Feedback

Input scaling andoffset

Pulse Rate to Amplitude Converter

Differentiator and Limiting Amplifier

Vin

V2Vout

V1

Page 31: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Cell Driver – Block Diagram

Input scaling

Cell DriverPower Amplifier

StandbyController

Vin V6 Vout - Iout

Standby Current Set point

V1 CurrentSensor

V4V3

V2

V8

V7

Cell DriverFeedbackNetwork

DC Power

V5

Standby Mode Select

Current Monitor

Page 32: Nelson Research, Inc. 2142 – N. 88 th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com Gas Fraction Control System for a Gas Evolving Electrochemical.

Nelson Research, Inc. 2142 – N. 88th St. Seattle, WA. 98103 USA 206-498-9447 Craigmail @ aol.com

Summary and Conclusions

A system concept has been developed and presented

A parameter extraction strategy has been presented

These methods can be used to extract gas fraction information from gas bubble sensing devices