. . . 40(2) 423-435 (2555) KKU Sci. J. 40(2) 423-435 (2012) Natural Dyed Indigo Silk (indican ( indigo blue indigo blue (leuco form indigo white zinc lime vat 60 indigo blue indigo white indigo white indigo white indigo white indigo blue indigo white 1 47000 E-mail: [email protected]
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Natural Dyed Indigo Silk - KKU Science Journalscijournal.kku.ac.th/files/Vol_40_No_2_P_423-435.pdf · Indigo white is the better for textile dyeing such as cotton. Indigo gave the
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ABSTRACTIndigo blue can be extracted from many tropical plants. It is insoluble pigment in water.
Before dyeing, the indigo blue must be base-oxidized to leuco form (indigo white) which iscolorless and dissolves in water. The process was reduced by reducing agents under alkalinecondition. For industry process, sodium dithionite dissolve in sodium hydroxide were used as
using potassium nicklecyanide as catalyst under nitrogen condition, which was satisfyingoutcome. Zinc lime vat is one of indigo white preparing. Indigo blue, zinc powder, lime andmethanol were reduced indigo bath with lower temperature than 60 C. However, repeating ofdye process can be decomposed the yarn. The process of Indigo blue fermentation was usedash lye and need microorganism for equilibrium, this process used among Japanese, Korean,Laotian and Thai wisdom.
Indigo white is the better for textile dyeing such as cotton. Indigo gave the bluish todark blue color on the cotton, whereas the affinity of for dyes is weaker for third of cotton.Several time in dyeing process can be denature protein of silk. Fabrics of silk are less resistanceunder alkaline condition comparing to cotton. According to chemical structure of Indigo white,the numbers of hydrogen bond between Indigo white and cellulose of cotton are higher thanIndigo white and protein of silk. That result for silk obtains less blue in the indigo natural dye. Sothe improvement of vat substance to mix with pigment in order to reduce the indigo pigmentparticles together in the formation of the lowest alkaline and adding up some essentialcompound to extend the hydrogen bond between Indigo white and silk.
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