Municipal Solid Waste Composting JICA Ex Participants Association of Solid Waste Management One day workshop, Colombo , 18 th February 2016 Dr Anurudda Karunarathna Senior Lecturer in Environmental Engineering Department of Agricultural Engineering University of Peradeniya 077 297 6234 [email protected]
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Municipal Solid Waste Composting
JICA Ex Participants Association of Solid Waste Management One day workshop, Colombo , 18th February 2016
• Decomposition of heterogeneous organic matter by a mixed microbial population in a moist, warm, aerobic environment to a state sufficiently stable for nuisance-free storage and utilization (Gray & Biddlestone, 1974).
• Compost systems can be classified on three general bases:
1. Oxygen status (aerobic & anaerobic)
2. Temperature (Mesophilic 15-40 OC & Thermophilic 45-65 OC)
3. Technological approach (static pile or windrow, and mechanical or "enclosed" composting)
Definition of composting process
Compostingprocess
Rapidly degradable organic matter (carbohydrate, protein, lipids, etc. + chemical energy)
Slowly degradable organic matter (cellulose, lignin, wax etc. + chemical energy)
• For most organic waste, it will vary from 60 to 80%, depending on the composition of the wastes, the season of the year, and the humidity and weather conditions
Moisture content
Ash
Dry matter
Biodegradable/ combustible
Moisture
Change of MC & FC during composting
0
10
20
30
40
50
60
70
80
0 14 28 42 56 70 84 98 112
Mo
iatu
re C
on
ten
t (W
/W)
Days
Available MC % MC at Field Capacity
Particle size and size distribution
Proximate analysis: determination of combustible components of waste includes analysis of moisture content, volatile combustible matter, fixed carbon and ash.
Ultimate analysis: involves the determination of the percent of C, H, O, N, S, ash and halogens. ◦ to characterize the chemical composition of the organic matter in waste ◦ to define the proper mix of waste materials to achieve suitable C/N ratios for
biological conversion processes.
Chemical properties
8
• The principal organic waste components in MSW are often classified as rapidly and slowly decomposable
Biodegradability
9
Component Volatile solids (VS) % of total
solids (TS)
Lignin content (LC) % of VS
Biodegradable fraction (BF)
Food wastes 85 - 90 0.4 0.82
Paper Newsprint Office paper Cardboard
94 96.4 94
21.9 0.4
12.9
0.22 0.82 0.47
Yard wastes 50 - 90 4.1 0.72
Biodegradation- Volatile solid (VS)
0
10
20
30
40
50
60
70
80
0 20 40 60 80 100 120
VS
(%)
Days
• In Germany, the biodegradability is defined either with the respiration activity (AT4) or gas formation potential (GB21).
Solid biodegradability- measurement
11
Organic Material Breakdown Rate
Group I
Sugars
Starches, glycogen, pectin, fatty acids and
glycerol
Lipids, fats, and phospholipids
Amino acids
Nucleic acids
Protein
Readily degradable
Group II
Hemicellulose and cellulose
Chitin
Low molecular weight
Aromatics and aliphatics
Slower to degrade
(more relevant during
maturation)
Group III
Lignocellulose
Lignin
Usually resistant
The Relative Microbiological Breakdown Rates
1) pH
2) Moisture content
3) Aeration (oxygen consumption) rates
4) Temperature & Heat evolution
evaporative cooling, etc., are governed by biochemical properties of the substrate and the type of microbial activities taking place during the degradation processes.
5) Degradation processes, which in turn depend on particle size and pile height.
6) Permeability
7) Composition
Parameters governing the composting
• Combined activities of a rapid succession of microbial populations, each suited to a particular environment for a relatively limited duration of time and being active in the degradation process of one particular type or group of organic material.
Bacteria (mesophyllic and thermophyllic)
Actinomycetes
Fungi
Protoza
Rotifers
Biological Aspects of Composting
Food Web of a Compost pile
Organic Residue
Primary Consumers
bacteria, fungi, actinomycetes
Secondary Consumers
nematodes, protozoa, rotifera,
Tertiary Consumerscentipedes, mites, beetles
Nutrients required for micro-organisms
Nitrogen
Phosphorous
Potassium
Magnesium
Sulphur
Calcium
Other elements
• The ideal C/N ratio for composting of MSW generally falls in the range of 20:1 to 25:1 The experimental values obtained in the Sri Lankan studies varied between 20-33:1
• Feedstock, gradually reducing to between 9-10:1 after 60 days of composting
• C/N ratio of 10 to be ideal for mature compost
Carbon: Nitrogen ratio
pH
0
1
2
3
4
5
6
7
8
9
0 1 0 2 0 3 0 4 0
D ay s
pH
Typical Values of pH Variation with Time
• Experiment conducted on an engineering model, a vertical reactor obtained values of 0.36 to 0.39 m3 of air per day per kg of volatile solids
Aeration Rates
Natural Air Circulation
in a Compost Windrow
The Temperature time Pattern in relation to Biological Activities
0
10
20
30
40
50
60
0 5 10 15 20 25
Time in days
Tem
pera
ture
0 C
a b c d
Temperature Variations with Time with Indicating the
Stages of the Composting Process
1. Psychrophilic-mesophilic-- Microbes multiply exponentially; give off heat; pile warms up.
2. Thermophilic or “hot” phase -- Bacteria consume ‘easy’ food; pile heats rapidly; H2O, heat, CO2 given off in large amounts.
3. Cool-down – Microbes run out of food and/or oxygen; pile cools; may be re-activated by turning, introducing air, and/or adding water.
4. Curing – At ambient temps; actinomycetes and fungi multiply; slow breakdown of cellulose & lignins. Humic compounds form. Mineralization of N to NO3.
Phases
• 300 components were evaluated and classified and 18 chemicals were found to be of special importance and thus well-suited as control parameters in emissions.
• Methane
• Ammonia
• Benzene
• Xylole
• Trichlorethene
• Tetrachorethene
• limonene and
• Ethanol
Gas Emissions During composting MSW
• Highest emissions occur during the self-heating stage in the first days of the rotting process. At this stage, the waste gas emits a range of volatile pollutants taking about two weeks to complete.
• During the whole composting process, readily degradable carbon compounds such as alkanes, aldehydes, alcohols, etc., are present in the waste air. These are volatile metabolites, which can be removed through biological air filters.
• Referring to its efficiency, a comparison of the content of the pollutants before and after the bio-filters indicate a reduction of about 60% as a mean value with cleaning efficiencies varying between 0% and 100% depending on the substance.
• Dioxine and most heavy metals are in the concentration range of the natural environment.
Type of emmisions
Compost production
Aspect Preferred condition Remarks
MSW characteristics Organic fraction of MSW Kitchen waste, food waste, garden waste, paper and small amount
of non-degradable/ long-term degradable materials may present
Particle size 25-75 mm for optimum results Smaller particles increases the density thus reduce the air
movement inside the pile, larger particles takes long time to
disintegrate and decompose
C:N ratio 25 to 50 C:N ratio above the limit prolong the decomposition and very low
C:N ratio of feedstock may impend anaerobic condition and
ammonia leaching
Blending & seeding 1-5 % Addition of partly decomposed matter accelerate the
decomposition at early stages, especially when the feedstock is