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    Department of

    Maritime Technology

    Faculty of Maritime Studies

    and Marine Science

    O.O.Sulaiman, PhD, CEng,CMarEng

    Risk based Multi-hybrid alternative

    Energy for Marine System

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    Risk based Multi-hybrid alternativeenergy for Marine System

    [email protected]

    University Malaysia Terengganu

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    Outline

    Introduction

    Energy Environment and Sustainable Development

    Energy supply and demand Hybrid System

    Reliability and Decision Support Framework

    Conclusion and Recommendation

    References

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    "It does not matter where on Earth you live,everyone is utterly dependent on the

    existence of that lovely, living saltwatersoup. Theres plenty of water in the

    universe without life, but nowhere is therelife without water. The living ocean drivesplanetary chemistry, governs climate and

    weather, and otherwise provides thecornerstone of the life-support system forall creatures on our planet, from deep-sea

    starfish to desert sagebrush. Thats why theocean matters. If the sea is sick, well feel

    it. If it dies, we die. Our future and the stateof the oceans are one."

    Sea Change A Message of the Oceans

    Sylvia Earle, 1995.

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    Introduction

    Man, Environment and Technology Man

    Biosphere- Water, Air and Soil

    The techno sphere Marinesystem, the ship, the port,offshore structure, underwater

    vehicles, surface effect vessel

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    Introduction Increasing/unstable oil price leads to the need of alternative

    energy to supply power to vessel in order to reduce oil usage.

    Impacts of diesel exhaust to the environment.

    Diesel exhaust contains much less unburned or partially burnedhydrocarbons and carbon monoxide.

    The sun represent all source of energy

    Hydrogen is the most abundant elements on the planet There is potential for use of solar and hydrogen gas as a fuel

    source for marine system, and supporting power supply inreducing fuel consumption and diesel exhaust.

    This present discuss the technical, risk and economical aspect

    of hybrid of solar and hydrogen engine that meet sustainabledevelopment for maritime application

    Marine application include systems:

    Marine vehicles for marine transportation ( sea or river): boat,tanker vessel, container ship, offshore supply vessel, bulk carrier

    and ROV, USV.

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    Problems Statement

    1. Increasing of market price for petroleum

    Increasing environmental impact from conventional engine of boat

    Shortage of petroleum sources

    Most marine system use diesel fuel for power

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    Issues Combustion in energy conservation and pollution control Emission from combustion impacts and chemical smog Fossil fuel scarcity and oil dependent world

    Aggressive quest for alternative energy International and local legislation build-up Revolution work to reduce emission of existing and new

    engine Challenge of matching energy efficiency at low pollution Control of emission is linked to traditional factors of

    reliability, fuel economy, per shaft power, capital costand maintenance

    Emission is inherent consequence of powered shipping- Fuel oil burning as main source- Continuous combustion machineries- boilers, gas turbines

    and incinerators etc.. Worldwide focus of fuel-> Exhaust gas emission law by

    IMO and introduction of local rules Emission limits driving adaptation to developnew

    technology Focus is more on, NOx and SOx HC, Cox and PM Consideration involve not only fuel use and design but

    also operational issue

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    Main Threat Freshwater supply and quality both

    surface and groundwater

    Risk and threats to human health

    due to collapse of ecosystemhealth

    Pollution of the lower atmospheredue to combustion of fossil fuelsand biomass burning

    Land/marine interaction (e.g.,eutrophication)

    Environmental flashpoints/security

    Nuclear waste issues

    Long-term and inter-annual climatechange

    Habitat loss and forestfragmentation

    Endangered species and link withfood security and economic impacts

    Sanitation and waste due tourbanization

    Chemical and toxic substances

    Critical environmental zones

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    Impact CategoriesGeneral Impacts The alteration and destruction of habitats and ecosystemsThe effects of sewage on human health Widespread and increasing Eutrophication The decline of living resources Sediments The impacts of Climate Change \ Rising seaHigh ProbabilityHigh-Impact Events: Landbased resources degradation Marine Resource degradation Damages due to disasters Environmental damages:Low probability and slow impact events: Global climate change Stratospheric ozone depletion Persistent organic pollutants

    Stratospheric ozone depletion:

    - Loss of biodiversity- Freshwater degradation

    - Desertification and land degradation

    - Deforestation and the unsustainable use of forests

    - Marine environment and resource degradation

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    Threat

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    Threat

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    Threat

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    Pollution from Ships

    Release:

    Water pollution Air emission Persistent organism

    Accidental - Grounding ,Stranding, Loss of oil, Hazardouscargo, Noxious liquid, collision with marine mammals

    Operation - Oil spill, Cargo and Bunker fuel, Emission (SOx, NOx, CFC & VOC) Antifouling toxins ,Ballast waterdischarges, Noise, Waste disposal at sea, Dredging@dispersal of soil

    -Intentional-Unintentional

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    Global Warming Potentials by Emission Sources

    0

    2000

    4000

    6000

    8000

    10000

    12000

    GWP (100 Year ITH)

    Cox

    NOx

    CHX

    HFC-134a

    HFC-227ea

    HFC-c-23a

    CF

    Flow process of typical exhaust gascomposition

    Choice of prime mover for marine system

    Internal Combustion and Diesel Engines:

    Steam TurbinesStirling Engines

    Gas Turbines

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    Emission Reduction Potentials

    Recent studies revealed that exhaust emission from ship isresponsible for :

    - 14% of the worldwide NOx emission

    - 8% of world SOx

    Emissions from ocean-going are forecast to increase

    - 9% to 13% by 2010- 20% to 29% by 2020

    Bulk carrier, container and tanker vessels are the three largestcontributors.

    Low exhaust emission diesel engine could achieves a 25% reduction

    in air emissions The IMO, NOx emission limit will reduce the average NOx

    emission factors for ocean-going vessels by:

    - 4.1% for main engines

    - 8.3% for auxiliary engines

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    Regulation Build-up

    UN Agencies

    Local agencies

    (Oil Spills Protocol) - Protocol Concerning Specially ProtectedAreas and Wildlife (SPAW Protocol)Protocol Concerning Pollution from Land-based Sources andActivities (LBS Protocol)

    Agenda 21

    UN Agencies Regulation Cluster

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    IMO Get Serious New Strategies To address greenhouse gas emissions from ships- Adoption of control and prevention measures

    in 2003;

    To address problems associated with the transfer of harmful aquatic organisms in ships' ballastwater adoption of final text of IMO Diplomatic Conference in 2004;

    To support the International Convention on the Control of Harmful Anti-fouling Systems in Ships2001; and

    To address the ongoing implementation of the International Convention on Oil PollutionPreparedness, Response and Co-operation 1990.

    LEGAL INSTRUMENTS AND REGULATION CLUSTER-IMO

    International convention for the prevention of pollution from ships (MARPOL) 1973

    It covers accidental and operational oil pollution as well as pollution by chemicals,goods in packaged form, sewage, garbage and air pollution

    It was modified by the protocol on of 1978 relating to (MARPOL 73/78)

    MARPOL Annex VI Convention - 1997 Technical code for prevention of air emissions from ships Diesel engine test Survey

    Certification of compliance (IAPPC) NOx compliance limit -30% reduction Review of 5 years interval Restriction on use of fluorocarbons on board Carbon dioxide emission from ship Fuel quality SOx Emission Control Areas (SECA)

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    UN Agencies Get Serious

    Galvanize the scientific community

    - set up panel's)/collaborating scientists

    - use existing scientific bodies and research centers

    - use global observing systems

    Tap on informal sources of information related toearly warning

    Dealing with problem of sharing sensitive dataamong countries

    Human capacity Rapid spread of Internet as a tool for information

    compilation, discussion, and dissemination

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    International Maritime Organisation (IMO)New annex to MARPOL cover: Control and management ofBallast water to

    minimize transfer of harmful foreign species Global prohibition ofTBT in antifouling Coating -

    phase out scheduled for 2008 Internationalconvention on oil pollution, Response and

    cooperation (OPRC) - 1990 Policy to combating major incidents or threats ,

    control to prevent, mitigates or eliminates dangerof marine pollution through port to its coastlinefrom a maritime casualty

    Annex protocol under this convention (HNSProtocol) covers marine pollution by hazardous andnoxious substances

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    IMO NOx Compliance

    SOX Emission Control Areas(SECA) Annex VI to MARPOL73/78 limits the sulphurcontent of marine fuel oil to1.5% per mass and will applyin designated SECAs.

    NOx depends on : Fuel efficiency,

    Large bore, Low speedFuel grade - ISO 8217- DM gradeEmission test - ISO 8178One common limits for all engine- International harmonization ofregulation and equipmentstandards

    New method is being sought tomitigate NOx

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    Reduction method for existing ships

    COx contents for different plants and fuel

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    COx contents for different plants and fuel

    Emission of particulates as afunction of fuel sulphur contentA large part of the differencebetween HFO and DO is relatedto the sulphur, which together

    with water forms particulates

    0

    1

    2

    3

    4

    5

    6

    GTE DFD SSD

    NOx

    SOx

    CO

    CO2/100

    Emission release from prime movers

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    Mitigation Shipboard and waste emission outline Treatment and

    Elimination - Pollution Prevention (P2) or Pollution

    Control-this is backbone of the thrust in achieving cleanship.

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    Energy Source and Fuel Quality

    The quests for an efficient fuel friendly to theenvironment have been recognized in maritimeindustry for a long time in maritime industry.

    Improvements of gasoline and diesel by chemicalreformulation that can lead to decrease in ozone-

    forming pollutants and carbon monoxide emissionshave been employed.

    Inconvenience posed by these reformulationchemicals are performance problems; cold-startability, smooth operation and avoidance of vapor

    lock are disadvantages of using reformulated fuels. Global trend in de-Carbonization of the energy

    system follow the following path: COAL > OIL>NATURAL GAS > HYDROGEN

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    Impact of Using New Fuel

    That technology will transfer sympathetically tothe marine industry via availability of engines,systems and technical assistance.

    Marine craft operation in inland water operationrequires fuel supplied in bulk rendering the NG

    distribution viable. The use of an alternative fuel for vessel

    propulsion will leads to a design review of Powerplant, associated fuel system and propulsiontrain;

    Effectively reshaping areas such as MachineryArrangement, Hull Form, Compartment, CargoDeck, Payloads, Superstructure, Interior Layouts,Escape & Safety, Route Options, etc.

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    Environmental Technology For Emission Reduction

    Alternative energy

    Alternative fuel and dual fuel engines

    Infusion of water mist with fuel and subsequent

    gas scrubbing units for slow speed engines Additional firing chamber

    Potential for gas turbine complex cycle

    Potential for turbocharger diesel engine

    Compound cycle with : gasified fuel, externalcompressor, combustion with pure oxygen

    Exhaust after treatment for medium speedengines

    P i M d D i

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    Prime Movers and Drives

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    Hybrid System

    Major equipment and hardware for the hybridconfiguration are: Semiconductor solar with high efficient storage

    capability Hybrid back- up power design based on integrative

    capability to other alternative power source like wind andhydrogen

    Controller design for power synchronization

    Inverter and other power conversion units selecton basedon power needs

    Solar collector or receiver with high efficiency collectioncapacity Software development and simulation

    Compatibility with conventional power system

    Robust and light weight storage system

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    Typical Solar - Fuel Cell Hybrid

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    Typical Solar/ Fuel Cell Connection

    Ph i l d l f h b id t d i t ti i UMT

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    Physical model of hybrid system under experimentation in UMT

    Collector module need to face south for case of

    photovoltaic, this depends on modular or central

    units modularModule storage unit need maintenance

    The system need power inverter if the load requires

    AC current

    Highlight of relevant procedural differences needed

    Requirements of benefits and issues of using new

    procedures, and incorporating that into the total cost

    Procedure to build on, hybrid system and

    integration system and analyzed

    System successful compliance with all regulations

    Efficiency penalty caused by extra power control

    equipment

    4PT

    T

    Sola collector can be plate or dish type. Stefan` law relatesthe radiated power to temperature and types of surface

    The maximum intensity point of the spectrumof emitted radiation is given by:max2898

    ( )T K max

    2898

    ( )T K max

    2898

    ( )T K max

    2898( )T K

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    The case of Natural Gas Power in Malaysia Malaysia has taken aggressive step in recent year to face challenges of the

    world of tomorrow, and this includes research activities and strategicpartnership.

    One example is partnership with the Japanese Government forconstruction on sustainable energy power station in the Port Klang powerstation, Pasir Gudang power station, Terengganu Hydro-electric powerstation and Batang Hydro-electric power station which are main supply tomajor Malaysian port.

    Where power station are upgraded the power station by demolishing the

    existing aging, inefficient and high emission conventional natural gas/oil-firedplant (360MW) and installing new 750MW high efficiency and environmentfriendly combined cycle gas fired power plant built at amount of JPY 102.9billion.

    The total capacity of power generation of 1,500MW is equal to 14% oftotal capacity of Tenaga National (TNB) in peninsula Malaysia of 10,835MW

    and indeed this power station is one of the best thermal power stationswith highest generation efficiency in Malaysia of more than 55%.

    The rehabilitation, the emissions of Nitride oxide (NOx) is reduced by60%, Sulfur dioxide (SO2) per unit is reduced by almost 100% and Carbondioxide (CO2) emission is reduced by 30%. Port operation energydemands are for transportation, hot

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    Combine Cycle Engine

    O ti f LNG P l i S t

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    Option for LNG Propulsion System

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    PRINCIPLE PARTICULAR SHIP

    SYSTEM

    LOA 45.500m (149.28ft)

    LBP 41.801m (137.14ft)

    Breadth Moulded 10.900m (35.76ft)Depth Moulded 3.200m (10.50ft)

    Design draft 2.500m (8.20ft)

    Scantling Draft 2.500m (8.20ft)

    Design Speed 11 KNOTS

    Complement 20 MEN

    Main Engine CUMMINS KTA19-M3

    640HP@1800RPM x 2 UNITS

    Gear Box WAF 364 L RATIO 4.481 : 1

    Generator 80KW x 2 UNITS

    Port of Registry KUCHING

    Flag MALAYSIA

    Navigation Area UNRESTRICTED

    F.O Capacity 72 TONNES

    Long Range F.OTK Capacity 226TONNES

    F.W Capacity 80 TONNES

    F.W Cargo TK Capacity 367 TONNES

    B.W. Capacity 95 TONNES

    DC Supply (24V DC)for electronicequipments such as :Radionavigation aidsalarms,

    emergency lights,radio navigational aids,navigational lights andother emergency lighting oads onboard the vessel.

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    Graphs of sea surface temperature in

    Malaysia in 2008

    26.20

    26.40

    26.60

    26.80

    27.00

    27.20

    27.40

    0 2 4 6 8 10 12 14

    Sea Surface Temperature

    Graph of sea surface temperature in

    Malaysia in 2009

    Solar Energy Solar Radiation

    Malaysia is a country which lies entirely in the equatorial region and experience asubstantial amount of solar radiation throughout the year.The amount of solar radiation throughout the year of 2008 and 2009 taken fromMeteorology Department are shown below.

    S l P d B tt E ti ti

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    Solar Power and Battery Estimation Power Requirement

    Total power requirement for 24V DC is calculated to for the solar panels systemsupply -> Total = 2015 watts

    Solar Panel Requirements Solar panels will be used to supply power of 24 volts DC from 2 banks of 24 volts 200

    ampere hour batteries. A diesel generator is assumed to deliver the balance of system needs. The generator will generate 1kWh for every 0.3 liters of fuel. As natural losses are also taken into consideration, the result must be multiplied by 1.2,

    assuming 80% of efficiency

    The power requirement is determined to be 2015 watts x 24 hours = 48.4kWh/day.

    This load is multiplied by 1.2, ->48.4kWh x 1.2 = 58.1kWh per day.

    It is assumed that the solar panels received 8 hours of solar radiation. So the power willbe divided by 8 hours is 58.1/8 = 7.26kW.

    As 230 watts 20 volts solar panels are used;

    Power required / power supported by solar panel = amount of solar panels 7260 / 230 = 31.5 ~ 32 solar panels. Battery Storage Requirement

    Total load / System nominal voltage = 58.1 kWh / 24 V = 2420 Ah

    The amount of batteries required if 24 V 200 Ah batteries are used, the battery

    storage requirement is divided by 200, where; 2420 Ah / 200 Ah = 12.1 ~ 13

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    Power and Fuel Savings It is known that the north-east monsoon season is between the months of

    November to March. So for 5 months, the generator must produce 4/8 to

    7/8 of the system needs. During the 7 months of dry season, the generator is estimated to only

    produce 1/8 to 4/8 of the system needs.

    Without the PV system, the generator would have to provide 58.1 kWhper day for the whole 365 days in a year.

    So if 58.1 multiplied by 365 days would results in 21206.5 kWh of annual

    generator output. For the maximum use of PV system during dry season, the PV system

    saves; 21206.5 kWh 9233.0 kWh = 11973.5 of generation by generator.

    It is estimated that 1 kWh uses 0.3 liters of fuel.

    For 9233.0 kWh generator output, the generator is using 2769.9 liters offuel per year. If the vessel is using the generator for the whole powersupply, Total generator output x total days in a year = total power per year.

    To determine the total fuel saved; (Total fuel used by generator alone) (Total fuel used by generator with

    support of solar PV system)= total fuel saved

    Power and Fuel savings

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    Power and Fuel savings The balance of the system needs would be provided by

    diesel generator. The total power supplied by generatorwithout support from solar PV system is obtained by using

    the formula shown below; Total generator output x total days in a year = total power per

    year

    The power supplied by generator with support of solarfor both seasons are calculated to the power saved by

    using solar is obtained. The power and fuel saved is then changed into monetary

    values and percentages.

    Overall percentage fuel consumption by both main

    engine and generator, is 0.66%. Even though the percentage of saved fuel is small, fora long term consideration, it would really help insaving the environment due to the saved fuel aslesser fuel used would reduce the exhaust.

    7 months of dry season(A il O b ) 5 months of wet season

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    (April October)

    Hours Power produced by

    generator

    Power

    requirement

    for 7 months

    1/8 1/8 x 58.1 = 7.3

    kWh

    7.3 kWh x

    214days =

    1562.2 kWh

    2/8 2/8 x 58.1 = 14.5

    kWh

    14.5 kWh x

    214days =

    3101.0 kWh

    3/8 3/8 x 58.1 = 21.8

    kWh

    21.8 kWh x

    214days =

    4665.2 kWh

    4/8 4/8 x 58.1 = 29.05

    kWh

    29.5 kWh x

    214days =

    6216.7 kWh

    Hours Power

    produced by

    generator

    Power

    requirement for

    5 months

    4/8 4/8 x 58.1 =

    29.1 kWh

    29.1 kWh x 151

    days = 4394.1

    kWh

    5/8 5/8 x 58.1 =

    36.3 kWh

    36.3 kWh x 151

    days = 5481.3

    kWh

    6/8 6/8 x 58.1 =

    43.6 kWh

    43.6 kWh x 151

    days = 6583.6

    kWh

    7/8 7/8 x 58.1 =

    50.8 kWh

    50.8 kWh x 151

    days = 7670.8

    kWh

    5 months of wet season(November March)

    Money saved, assuming liter of diesel today

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    Total Annual Generator Output

    Wet season Dry season Total Annual

    Generator

    Output

    4/8 = 4394.1

    kWh

    4/8 = 6216.7

    kWh

    10610.8 kWh

    5/8 = 5481.3

    kWh

    3/8 = 4665.2

    kWh

    10146.5 kWh

    6/8 = 6583.6kWh

    2/8 = 3101.0kWh

    9684.6 kWh

    7/8 = 7670.8

    kWh

    1/8 = 1562.2

    kWh

    9233.0 kWh

    Generation by

    generator

    Total

    Annual

    Genera

    tor

    Output

    Energy

    saved

    by

    using

    solar

    panels

    Fuel

    saved

    (liters)

    Money

    saved

    (RM)Wet

    season

    (5

    months)

    Dry

    season

    (7

    months)

    4/8=

    4394.1

    kWh

    4/8 =

    6216.7

    kWh

    10610.8

    kWh

    10595.7

    kWh

    3178.7 3178.7

    x 2.0 =

    6356.2

    5/8 =

    5481.3

    kWh

    3/8 =

    4665.2

    kWh

    10146.5

    kWh

    11060.0

    kWh

    3318.0 3318.0

    x 2.0 =

    6636.0

    6/8 =

    6583.6

    kWh

    2/8 =

    3101.0

    kWh

    9684.6

    kWh

    11521.9

    kWh

    3456.6 3456.6

    x 2.0 =

    6913.2

    7/8 =7670.8

    1/8 =1562.2

    9233.0kWh

    11973.5kWh

    3592.1 3592.1x 2.0 =

    Money saved, assuming liter of diesel todaycost RM2.00;

    cost RM2.00;

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    Overall Savings Percentages

    Generation by generator Total

    Annual

    Generator

    Output

    Energy

    saved by

    using solar

    panels

    Fuel saved

    (liters)

    Savings

    percentageWet season

    (5 months)

    Dry season

    (7 months)

    4/8= 4394.1

    kWh

    4/8 = 6216.7

    kWh

    10610.8

    kWh

    10595.7

    kWh

    3178.7 50%

    5/8 = 5481.3

    kWh

    3/8 = 4665.2

    kWh

    10146.5

    kWh

    11060.0

    kWh

    3318.0 52%

    6/8 = 6583.6

    kWh

    2/8 = 3101.0

    kWh

    9684.6 kWh 11521.9

    kWh

    3456.6 54.3%

    7/8 = 7670.8

    kWh

    1/8 = 1562.2

    kWh

    9233.0 kWh 11973.5

    kWh

    3592.1 56.5%

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    Overall Cost EstimationCost Properties With Solar Without Solar

    Investment Cost i) Boat -RM8000000.00 -RM8000000.00

    ii) Total investment

    on Solar

    -RM97280.30 non

    Maintenance Cost

    (With 1.5%

    increment)

    i) Machinery and

    Hull

    -RM96000.00 -RM96000.00

    ii) PV system (solar) -RM3119.80 Non

    Operation Cost Fuel Oil -RM1200000 (minus

    fuel saved by using

    solar)

    -RM1200000.00

    Salvage Value

    (After 20 years with

    5% of depreciation)

    +RM2364293.63 +RM2335911.98

    Income +RM2555000.00 +RM2555000.00

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    Cash flow for vessel with solar PV systemCash Flow Diagram for vessel without solar.

    The positive direction shows that the profit (debit) and negative direction shows thatexpenditure (credit).

    Annual Average Cost (AAC)

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    Annual Average Cost (AAC) Annual Average Cost (AAC) between the original vessel and the solar

    assisted vessel is analyzed.

    Without solar PV system; AAC (NPV) = 1139930.9

    With solar PV system;

    AAC (NPV) = 1134128.5

    From the results, both of the vessels are found profitable due to the

    positive values. The ACC for vessel with solar PV system is found to be lower than the

    ACC for the original vessel. The result shows that using solar PV system onthe vessel is more economical rather than to use diesel generator alone.

    Return investment is carried out to determine the numbers of years that

    the investment will be recovered. The capital investment recovery can bedetermined as shown;

    Investment cost for boat with solar PV system = RM97280.30

    Cost saved = RM7184.20

    Investment recovered =RM97280.30/RM7194.20

    = 13.5years

    H d / F l C ll E

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    Hydrogen / Fuel Cell Energy Operation of hydrogen power

    Capacity and efficiency - weight to power ratio

    Advantages and disadvantage of hydrogen engine Comparison between hydrogen engine and conventional

    engine of boat

    Operation and maintenance cost

    Name : Nemo H2

    Type : Hydrogen Powered Canal Boat

    Manufacturer : Lovers Boat Company atAmsterdam

    Operation : Completing 100 trips

    without refueling but it ismust be connected withhydrogen dispensing station

    Cost : 3 millions euro

    H d / F l C ll E

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    Types Electrolyte Operating

    temperature

    Alkaline Potassium

    hydroxide

    50-200

    Polymer Polymer

    membrane

    50-100

    Direct

    methanol

    Polymer

    membrane

    50-200

    Phosphoric

    acid

    Phosphoric

    acid

    160-210

    Moltencarbonate Lithium andpotassium

    carbonate

    600-800

    Solid oxide Ceramic

    compose of

    calcium

    500-1000

    Hydrogen is the simplest element.An atom of hydrogen consists onlyone proton and one electron

    Potential fuel of vehicle engine inthe future. It is considered a near

    perfect energy storage medium, asit can be created from fossil ornon-fossil sources

    It does not emit carbon monoxidebut only produce pure water as

    exhaust. Hydrogen Gas Production

    There are many method toproduce hydrogen gas such as

    steam reforming, coal gasification,and electrolysis process

    Table 2: Type of electrolyte fuel cell

    Hydrogen / Fuel Cell Energy

    Hydrogen Power

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    i. Steam Reforming

    These are produced from methane, CH4 which is the mainconstituent of natural gas. A mixture of methane and watervapour at elevated temperature under strong endothermic

    reaction,CH4 + H20 CO + 3H2 - H

    0

    Enthalpy change,H0 = 253.3 kJ mol-1 at ambient pressure

    (0.1 MPa)

    ii. Coal Gasification

    It only makes sense as a centralized production option, dueto economies of scale.

    The resulting products are in energy terms which are 48%hydrogen, 40% carbon and 10% water vapour.

    iii. Electrolysis Process

    Electrolysis is a commercially viable technology forproducing hydrogen.

    It is a viable option for decentralized production.

    The main cost associated with this option is the electricity

    y g

    2H2->4e- +4H+

    4h+ +4e- +O2->2H20

    2H2+02 -> 2H20 +Heat

    Combustive characteristics of

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    hydrogen engine

    Wide range of flammability

    Low ignition energy

    Small quenching distance

    High auto ignitiontemperature

    High diffusivity

    Very low density

    Efficiency calculation

    can be done through the

    following formula:

    G= H*T *Si

    (5)

    Where:

    Ec=EMF, G =Gibbs function

    nF=Number of Faraday

    transfer in the reaction,

    H= Enthalpy,T=Absolute temperature,

    S=Entropy change

    i=Ideal efficiency

    C

    nF

    GE g

    Fuel delivery system Central Injection or Carburetted

    Systems Port Injection Systems

    Direct Injection Systems

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    v. Emission

    The combustion of hydrogen with oxygen produces water as its only product:

    2H2+ O2 = 2H2O

    The combustion of hydrogen with air however can also produce oxides ofnitrogen (NOx):

    H2+ O2 + N2 = H2O + N2 + NOx

    The oxides of nitrogen are created due to the high temperatures generatedwithin the combustion chamber during combustion process

    The amount of NOx is formed depends on:

    a) Air/fuel ratiob) Engine compression ratio

    c) Engine speed

    d) Ignition timing

    Power output

    The theoretical maximum power output from a hydrogen engine depends on the

    air/fuel ratio and fuel injection method used. Air/fuel ratio for hydrogen is 34:1. At this air/fuel ratio, hydrogen will displace 29% of

    the combustion chamber and leaving only 71% for the air.

    Typically hydrogen engines are designed to use about twice as much air astheoretically required for complete combustion.

    At this air/fuel ratio, the formation of NOx is reduced to near zero.

    Reliability and Decision Support Framework

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    y pp

    Since options are many and money will beinvolve, it is better to use IMO FSA

    HAZOP method for various decision onalternatives.

    RISK = Hazard (Toxicity) x Exposure (an

    estimate on probability that certaintoxicity

    will be realized)

    For example:

    Use of X rays has a high AQ (Highbenefit, low risk)

    Use of Thalidomide has a small AQ(Small benefit, high risk)

    Nuclear war has a very small AQ(No benefit, very high risk)

    Qualitative analysis: FMEA, what if , PrHA

    Quantitative analysis: Frequency and

    consequence, cost benefit andsustainability

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    Reliability and Decision Support Framework

    Goal Based

    System assessment

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    Reliability and Decision Support Framework

    Scena

    rio

    Probabi

    lity

    Conse

    quence

    Cumulative

    Probability

    S1 P1 C1 P1=P1+P2

    S2 P2 C2 P2=P3+P2

    Si Pi Ci Pi=Pi+3+Pi

    Sn+1 Pn+1 Cn+1 Pn-1=Pn+Pn+1Sn Pn Cn Pn=Pn

    Table 5: components of risk and reliability analysis

    n=N

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    Risk Management and CBA

    Risk management is the evaluation ofalternative risk reduction measures

    and the implementation of thosethat appear cost effective

    It must be remember that :

    Zero discharge = zero risk, but thechallenge is to bring the risk toacceptable level and at the sametime, derive the max. benefit

    Cost Benefit Analysis Cost BenefitAnalysis:Maximizing both economic Maximizingboth economicreturn and environmental return andenvironmentalprotection

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    Sustainability and maritime

    MARITIME INDUSTRY IN NEW WORLDCHARACTERIZED BY SUSTAINABILITY

    CAPACITY BUILDING , EFFICIENCYOPTIMIZATION OF DEVELOPMENT ,

    PRACTICE AND OPERATIONS THAT MEETSTHE NEEDS OF THE PRESENT GENERATION

    WITHOUT COMPROMISSING THE ABILITY OFFUTURE GENERATION TO MEET THEIR NEED

    Advantages of Maintaining Quality

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    Advantages of Maintaining Quality

    Good environmental quality is essential for sustaining coastal andmarine ecosystems

    The health of coastal and marine ecosystems is affected by water Compliance with all applicable environmental laws and regulations; No significant adverse environmental impacts; Wastes treated or destroyed on board to the extentpracticable; No inappropriate dependence on shore facilities forwaste off-load and disposal; Minimal energy consumption; Minimal logistical costs for waste management; and Minimal use of hazardous materials.

    **Reducing emission will make ship to meet future local andinternational emission regulation.

    ** System that meet environmental requirement will be able tomeet requirement of GREEN PASSPORT concept for ships

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    The future towards clean ship operation The development of new measuring equipment for emission

    control will continue in the coming years, and especially techniques

    like HAM and EGR The concern of local authorities will change from focusing on NOx

    and SOx to include also smoke, in particular. The IMO Annex VI unconditional ratification for NOx IN 2003 and

    the recent inclusion of SOx is sign for more environmentalrestriction in future

    Local rules that encourage the use of emission cutting means, such

    as SCR reactors, through harbour fee reductions will becomemore dominant than today.

    SCR units are preferably installed during the construction of thevessel, however, retrofitting is has been successfully practiced

    The challenge to ship-owners will increase as vessels are requiredto have, or be prepared for, emission control equipment.

    The sulphur content in fuel will be reduced, and vessel tanksystems have to be prepared for dual fuel and dual cylinder lube oilsystems.

    In some areas, the operating profile of the ship will have to beadapted to local rules for reduced smoke emission.

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    Best Practice for Operation of Machineries

    Recover energy from hot gases Reduce energy from hot liquid

    Reuse hot wash water

    Add effects to existing evaporators

    Use liquefied gases as refrigerants

    Recompress vapor for low pressure steam

    Generate low pressure steam from flash

    operation Use waste heat for absorption to reduce heat

    loss

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    Management Responsibility

    Maintain air- conditioner efficiency and reduce heatedand cooled space

    Maintain boiler efficiency

    Use nature ventilation whenever and whereverpossible, reduce air infiltration and seal leaks in pipesand ducts

    Raise office temperatures in summer

    Lower office temperature in winter

    Use shading efficiently

    Close windows and other air leaks

    Do not use light necessarily

    Turn off office equipment that is not use

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    Conclusion

    The use of hybrid system solar panels willgive benefit vessel in reduction of fuelconsumption and the environment.

    It is important to experiment and simulate

    the system for the environment it will bedeploy for better reliability. Scientific based risk and reliability and

    sustainability analysis analysis is encouragedto be performed prior deployment

    Different types of solar panels can be takeninto consideration to improve theperformance of the system.

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    THANK YOU