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Münster Symposium on
Cooperative Effects
Münster, Germany
May 4th 2012
The Collaborative Research Center(Sonderforschungsbereich) 858“Synergetic Effects in Chemistry - From Additivity towards Cooperativity“
ContactSonderforschungsbereich 858Corrensstraße 40D-48149 Münster, Germanyhttp://www.wwu.de/sfb858
Book of Abstracts
[email protected] /sfb858
Synergetische Effektein der Chemie - von der
Additivität zur Kooperativität
SFB858
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Symposium Schedule Fri May 4th 2012, Aula Schloss of the WWU Münster
Opening Adress
9:55 am Armido Studer Speaker of the SFB 858
10:00 am Shie-Ming Peng Chair: F. Ekkehardt Hahn
National Taiwan University, Taiwan
“Molecular Metal Wires and Related Molecular Materials”
11:00 am Krzysztof Matyjaszewski Chair: N. Seda Kehr
Carnegie Mellon University, Pittsburgh, USA
“Atom Transfer Radical Polymerization - From Mechanism and Synthesis to Materials and Applications”
12:00 am
Postersession
Lunch (~ 12:30 pm) Coffee Break (~ 2:00 pm)
2:30 pm Christopher A. Hunter Chair: Mark P. Waller The University of Sheffield, UK
“The Anatomy of Complex Recognition Interfaces”
3:30 pm David W. C. MacMillan Chair: Ulrich Hennecke Princeton University, USA
“Multi Catalysis in Chemical Synthesis”
4:30 pm Poster Prize Awards Closing Remarks
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Poster Contributions in alphabetical order (presenting author’s surname)
Authors Institution Title
1. Jens Antony, Stefan Grimme* WWU Münster / SFB 858 Fully ab initio protein-ligand interaction energies
with dispersion corrected density functional theory
2. Lukas M. Artner, Nina Bohlke, Jens
Dernedde, Nediljko Budisa,
Christian P. R. Hackenberger*
Freie Universität Berlin Multivalent Protein Scaffolds for Lectin Binding
Studies
3. Stephan Beckendorf, Sören Asmus,
Christian Mück-Lichtenfeld, Olga
García Mancheño*
WWU Münster / SFB 858 Cooperation as key to success:
Now weak C–H∙∙∙Anion interactions can catalyze!
4. Anup Biswas, Suman De Sarkar,
Ludger Tebben, Armido Studer*
WWU Münster Enantioselective cyclopropanation of enals by
oxidative N-heterocyclic carbene catalysis
5. Roberto Blanco-Trillo, Mattias
Leven, Bernd Goldfuss*
Universität Köln Electronegativity governs enantioselectivity: Alkyl-
aryl-cross coupling with fenchol-based Palladium-
Phosphorus-Halide catalysts
6. Teerawut Bootwicha, Erli Sugiono,
Magnus Rueping*
RWTH Aachen Continuous-flow Organocatalytic Asymmetric
Hydrogenations using FTIR Inline Analysis
7. Hannah Schuster, Hanna Bruss, Rémi
Martinez, Andrey P. Antonchick,
Herbert Waldmann*
Max-Planck-Institut für
Molekulare Physiologie
Dortmund
Synthesis of the B-seco Limonoid Scaffold
8. Mark Busch, Sefer Ay, Adam Kubas,
Karin Fink, Stefan Bräse*
Karlsruhe Institute of
Technology (KIT)
Multimetallic Complexes with [2.2]Paracyclophanes
Backbone: Cooperative Effects in Catalysis
9. C. Cebrián, M. Mauro, D.
Kourkoulos, P. Mercandelli, D.
Hertel, K. Meerholz, C. A. Strassert,
L. De Cola*
WWU Münster Luminescent neutral Platinum Complexes Bearing an
asymmetric N^N^N Ligand for High-Performance
Solution-processed OLEDs
10. Xiao Yun Chen, Helmut Buschmann,
Carsten Bolm*
RWTH Aachen Bioactive Sulfoximines:
Synthesis and Properties of Dapsone analogues
11. Christian A. Citron, Nelson L. Brock,
Patrick Rabe, Jeroen S. Dickschat*
Technische Universität
Braunschweig
The Stereochemical Course and Mechanism of the
IspH Reaction
12. Soumen De, Susnata Pramanik,
Michael Schmittel*
Universität Siegen Reversible ON/OFF Nanoswitch for Organocatalysis:
Mimicking the Locking and Unlocking Operation of
CaMKII
13. Julia V. Dickschat, Slawomir Urban,
Frank Glorius*, F. Ekkehardt Hahn*
WWU Münster / SFB 858 Novel Amphiphilic Germylenes and Stannylenes and
their Reactivity
14. Arne Dickschat, Jinjun Ren, Frederik
Behrends, Wilma Pröbsting, Hellmut Eckert*, Armido Studer*
WWU Münster / SFB 858 Bifunctional Mesoporous Silica Nanoparticals utilizing
click-chemistry: A route to cooperativity
15. Hussein Ali El-Damarany,
Soumen De, Michael Schmittel*
Universität Siegen Synthesis of Molecular Tweezers as Receptors
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Poster Contributions in alphabetical order (presenting author’s surname)
Authors Institution Title
16. Christina Eller, Birgit Wibbeling,
Roland Fröhlich, Gerald Kehr,
Gerhard Erker*
WWU Münster Newly Developed Sulfur-Boron Systems
17. Hugo Fanlo, Sijbren Otto* University of Groningen,
Niederlande
Substrate-Induced Catalyst Formation in Dynamic
Molecular Networks
18. Yingsheng Zhao, Siong Wan Foo,
Susumu Saito*
Nagoya University, Japan Iron/Amino Acid Catalyzed Direct N-Alkylation of
Amines with Alcohols
19. Sabrina Freye, Jakob Hey, Anna
Torras-Galán, Michael John,
Guido H. Clever*
Georg-August Universität
Göttingen
Positive Cooperativity and Allosteric Halide Binding
by an Interpenetrated Double Cage
20. Silke Frömel, Roland Fröhlich,
Constantin G. Daniliuc,
Gerald Kehr, Gerhard Erker*
WWU Münster Application of Halogenating Reagents
in FLP Chemistry
21. Daniela Fuchs, Géraldine Rousseau,
Lisa Diab, Urs Gellrich and Bernhard
Breit*
Albert-Ludwigs-Universität
Freiburg
Cooperative Supramolecular Ligand Catalysis:
Tandem Hydroformylation-Hydrogenation of
terminal Alkenes
22. Takuya Fujimoto, Michio M.
Matsushita, Kunio Awaga*
Nagoya University, Japan Octathio[8]circulene Thin-Film Transistors in Ionic
Liquids
23. Agneyo Ganguly, Yoandris del Toro
Duany, Dagmar Klostermeier*
WWU Münster / SFB 858 Selective and co-operative binding of nucleotide and
DNA co-ordinated by the latch domain guides DNA
processing by T.maritima reverse gyrase
24. Sabrina Gatzweiler, Katharina Graf,
Verena Göker, A. Stephen K.
Hashmi*
Ruprecht-Karls-Universität
Heidelberg
Dual Activation: a New Concept in Homogeneous
Gold Catalysis
25. Christoph Glotzbach, Roland
Fröhlich, Ernst-Ulrich Würthwein*,
Shohei Saito, Shigehiro Yamaguchi
WWU Münster Oxa-/Aza-Boraphenalenes A Modular Fluorescent
Oligonitrile-Boron System
26. Muxin Han, Bice He,
Guido H. Clever*
Georg-August Universität
Göttingen
Control over the Shape of Coordination Cages by
Ligand Design and Dynamics
27. Johannes Hepperle, Anna Katharina
Bier, Armido Studer*,
Anreas Greiner*
WWU Münster,
Philipps-Universität
Marburg
A New Immobilization Concept For Organocatalysts
By Functionalization Of Polymeric Nanotubes
28. Christine Hofmann,
Peter R. Schreiner*
Justus-Liebig Universität
Giessen
Stereoselective Oxidation of Alcohols using TEMPO-
Peptide catalysts
29. Waldemar Hujo, Stefan Grimme* WWU Münster / SFB 858,
Rheinische Friedrich-
Wilhelms-Universität Bonn
Accurate description of ionic liquids, weak hydrogen
bonds and thermochemistry by dispersion-corrected
density functional theory
30. Yuki Iijima, Ryo Kitaura, Katsuaki
Kawasumi, Kenichiro Itami,
Hisanori Shinohara*
Nagoya University, Japan Bottom-up Fabrication of Graphene Nanoribbons
from Halogenated Aromatic Precursors with
Dnh Symmetry
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Poster Contributions in alphabetical order (presenting author’s surname)
Authors Institution Title
31. Katsuaki Kawasumi, Tomonori
Kajino, Kenji Mochida, Yasutomo
Segawa, Lawrence T. Scott,
Kenichiro Itami*
Nagoya University, Japan Direct π-extension of Polycyclic Aromatic
Hydrocarbons by C–H Functionalization
32. Kathrin Benson, J. El-Gindi, Luisa De
Cola, Hans-Joachim Galla*, Nermin
Seda Kehr*
WWU Münster / SFB 858 Cell Adhesion Behaviour on Enantiomerically
Functionalized Zeolite L Monolayers
33. Jennifer Antonia Krings, Bart Jan
Ravoo*
WWU Münster / SFB 858 Light-Responsive Self-Assembly of Silica-
Nanoparticles
34. Sadhana Kumbhar, Frank D. Fischer,
Mark P. Waller*
WWU Münster / SFB 858 Assessment of weak intermolecular interactions
across QM/MM noncovalent boundaries
35. Manik Lal Saha, Jian Fan,
Michael Schmittel*
Universität Siegen Post-Self-Assembly Functionalization of a Trigonal
Nanoprism: Construction of a Cage-like 3D
Framework and Poly-Nanocage Metallodynamer with
Three Correlated Strands
36. Stefanie C. Lange, Bart Jan Ravoo* WWU Münster / SFB 858 Dynamic and Switchable Receptors in Water
37. Matthias Leiendecker, Mahmud
Hussain, Ke Liu, Jason Law, Daisuke
Ito, Stephanie Wang, Andrew Stern,
Stephen Johnston, Gavin Dunn, Yan-
Ling Zhang, Ben Munoz, Stuart L.
Schreiber*, Alykhan Shamji
Broad Institute of
Harvard and MIT
Identification of an allele-selective, small-molecule
inhibitor of the oncogenic ketoreductase activity of
isocitrate dehydrogenase
38. Pavel Lulchev, Agneyo Ganguly,
Dagmar Klostermeier*
WWU Münster / SFB 858 Identifying key residues of functional inter-domain
interfaces and DNA-binding sites in T. maritima
reverse gyrase.
39. M. Mauro, Luisa De Cola* WWU Münster Luminescent Molecular Assemblies Based on Pt(II)
and Ir(III) Complexes
40. Stefan Minkler, Bruce Lipshutz,
Norbert Krause*
Technische Universität
Dortmund
Gold Catalysis in Micellar Systems:
Application in Natural Product Synthesis
41. Kazuhiro Mouri, Shohei Saito,
Shigehiro Yamaguchi*
Nagoya University, Japan Head-to-Tail Cyclic Thiazole Tetramers: Synthesis,
Structures, and Properties
42. Christian Mück-Lichtenfeld*,
Stefan Grimme*
WWU Münster / SFB 858,
Rheinische Friedrich-
Wilhelms-Universität Bonn
Many-body Deformation Densities provide Insight
into Cooperative Non-Covalent Binding
43. Michael E. Muratore, Masaki
Nakajima, Quentin Lefebvre,
Magnus Rueping*
RWTH Aachen Organocatalytic Carbanion Chemistry – Potassium
tert-Butoxide initiated additions of dithianes and
sulfonyl derivatives to styrenes
44. Kristine Müther, Roland Fröhlich,
Christian Mück-Lichtenfeld, Stefan
Grimme, Martin Oestreich*
Technische Universität
Berlin
Characterization of a Ferrocene-Stabilized Silicon
Cation
45. Nicole Nischan, Wiebke
Stahlschmidt, Volker Haucke,
Christian P. R. Hackenberger*
Freie Universität Berlin Chemoselective Lipidation of Azido-Polypeptides by
the Staudinger-Phosphite-Reaction: Inhibition of
Clathrin-Mediated Endocytosis
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Poster Contributions in alphabetical order (presenting author’s surname)
Authors Institution Title
46. Pascal Nösel, Max M. Hansmann,
A. Stephen K. Hashmi*
Ruprecht-Karls-Universität
Heidelberg
Dual Activation: Gem-Diaurated Species as
“Instant Dual- Activation” Precatalyts
47. Nuria Ortega, Slawomir Urban,
Bernhard Beiring, Frank Glorius*
WWU Münster Ruthenium-NHC Catalyzed Highly Asymmetric
Hydrogenation of Benzofurans
48. Peter Persich, Kévin Micoine,
Alois Fürstner*
Max-Planck-Institut für
Kohlenforschung Mülheim
The Total Synthesis of Isomigrastatin
49. Markus Plois, Robert Wolf* Universität Regensburg,
WWU Münster / SFB 858
C-H Activation and H2 Fixation by Ruthenium(II)
NHC Complexes
50. Marco Potowski, Markus Schürmann,
Hans Preut, Andrey P. Antonchick,
Herbert Waldmann*
Max-Planck-Institut für
Molekulare Physiologie
Dortmund
Selective Programmed One-pot Synthesis of
Complex Molecules Bearing Eight Stereocenters
51. Helene Reeker, Norbert Krause* Technische Universität
Dortmund
Coinage Metal Catalysis in Target-Oriented
Synthesis Illustrated by the Example of a
C-Glycopyranoside
52. Matti Reißmann, André Schäfer,
Thomas Müller*
Carl von Ossietzky Universität
Oldenburg
Silyl Cationic Frustrated Lewis Pairs –
A Progress Report
53. S.B. Riese, M. Weinhart, D. Gröger,
R. Tauber, R. Haag, J. Dernedde*
Charité-Universitäts-medizin
Berlin
Modulation of L-selectin–ligand interaction via
multivalent inhibitors under flow
54. Christian Rösener, Thorsten
Holtrichter-Rößmann, Johannes
Hellmann, Roland Fröhlich, Birgit
Wibbeling, Werner Uhl*,
Ernst-Ulrich Würthwein*
WWU Münster / SFB 858 Generation of Weakly Bound Al−N Lewis Pairs
by Hydroalumination of Ynamines and the
Activation of Small Molecules:
Phenylethyne and Dicyclohexylcarbodiimide
55. Christian Rösner, Katrin
Schünemann, Carl Deutsch,
Norbert Krause*
Technische Universität
Dortmund
Towards the Total Synthesis of
(+)-Goniothalesdiol
56. Rajarshi Samanta, Jonas Lategahn,
Katharina Kulikov,
Andrey P. Antonchick*
Max-Planck-Institut für
Molekulare Physiologie
Dortmund
Organocatalytic and Metal Free Oxidative
C-H Bond Amination at Ambient Temperature
57. Soumen Kumar Samanta,
Michael Schmittel*
Universität Siegen DABCO as a Dynamic Hinge Between Cofacial
Porphyrin Panels and its Tumbling Inside a
Supramolecular Cavity
58. André Schäfer, Thomas Müller* Carl von Ossietzky Universität
Oldenburg
Silyl Cation Mediated Conversion of CO2 into
Benzoic Acid, Formic Acid and Methanol
59. P. Scharf, F. Winckler, J. Müller* WWU Münster / SFB 858 A metal-mediated base pair with a phenanthroline-
derived ligand
60. Stefanie S. Schilson, Petra Keul,
Michael Schäfers, Bodo Levkau,
Günter Haufe*
WWU Münster New Ligands for Sphingolipid Receptor Imaging
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Poster Contributions in alphabetical order (presenting author’s surname)
Authors Institution Title
61. Benjamin Schinor, Günter Haufe* WWU Münster Fluorinated Tranylcypromine Analogues as New
Monoamine Oxidase Inhibitors
62. Birgitta Schirmer, Muhammad Sajid,
Annika Klose, Timothy H. Warren,
Gerhard Erker, Stefan Grimme*
WWU Münster A new persistent N-Oxyl Radical and the
Activation of SO2 – New Activation Reactions
with Frustrated Lewis Pairs
63. Ruth K. Schmidt, K. Müther, C.
Mück-Lichtenfeld, S. Grimme, M.
Oestreich*
Technische Universität Berlin The Danger of Hidden Proton Catalysis with
Strong Lewis Acids in Silylium Ion-Catalyzed
Challenging Diels-Alder Reactions
64. Markus Schmidtendorf,
F. Ekkehardt Hahn*
WWU Münster / SFB 858 Synthesis of Supramolecular Structures containing
NR,NR- and NH,Osubstituted Dicarbene Building
Blocks
65. Nils Schröder, Joanna Wencel-
Delord, Frank Glorius*
WWU Münster High Yielding, Versatile and Practical
[Rh(III)Cp*]-catalyzed ortho-bromination and
iodination of arenes
66. Sören M. M. Schuler,
Peter R. Schreiner*
Justus-Liebig Universität
Giessen
In situ generated dioxirane organocatalysts in
enantioselective epoxidation reactions
67. Zhanhu Sun, Markus Albrecht*,
Roland Fröhlich
RWTH Aachen Amide-functionalized1Quinoline Derivatives as
Receptors for Anions
68. Daniel Thiel, Jan Deska* Universität Köln A Desymmetrization/ Ring Expansion Strategy
Towards Substituted Pipecolic Acids
69. Carlos Vila, Uxue Uria,
Magnus Rueping*
RWTH Aachen Direct azidation of allylic alcohols with TMSN3
70. Raffael C. Wende, Christian E.
Müller, Radim Hrdina,
Peter R. Schreiner*
Justus-Liebig Universität
Giessen
Evolution of Asymmetric Organocatalysis –
Retrocatalysis and the Multicatalyst Approach
71. Thomas Wiegand, Hellmut Eckert*,
Olga Ekkert, Annika Klose,
Muhammad Sajid, Gerald Kehr,
Roland Fröhlich, Gerhard Erker,
Stefan Grimme
WWU Münster / SFB 858 New Insights into Frustrated Lewis Pairs by
Modern Solid-State NMR Techniques and DFT
calculations
72. Marcel Wieteck, Tobias Lauterbach,
A. Stephen K. Hashmi*
Ruprecht-Karls-Universität
Heidelberg
Dual Activation: Gold-Catalyzed Synthesis of
Dibenzopentalenes
73. Nathalie E. Wurz, Frank Glorius* WWU Münster Highly enantioselective intermolecular Stetter
reaction of simple α,β-unsaturated esters –
synthesis of α-chiral γ-ketoesters
74. Weibo Yang, Yang Yu,
A. Stephen K. Hashmi*
Ruprecht-Karls-Universität
Heidelberg
Gold(I)-Catalyzed Novel Rearrangement of 3-
Silyloxy-1,5-enynes: Synthesis of
Benzo[b]furanandBenzo[b]thiophene Derivatives