M/s. Sitamani Organic Pvt. Ltd., Phase-III GIDC …. Sitamani Organic Pvt. Ltd., Phase-III GIDC Dahej, Bharuch M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. ANNEXURE-IV LIST OF

M/s. Sitamani Organic Pvt. Ltd., Phase-III GIDC Dahej, Bharuch

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd.

ANNEXURE-I PROPOSED TERMS OF REFERENCE Standard TOR of sector specific prescribed by MoEF will be followed.



ANNEXURE-II LIST OF DIRECTORS

Sr. No.

Name of Directors Address & Contact Details

1. Mr.Suresh Chudiwala . 401,New Anand KiranBuilding,ManishaChowkdi ,Old PadraRoad,Baroda- 390007 [email protected]

Mobile No:09427341628 2. Mr.RakeshChudiwala. 404,AnandVatika Residency Nr.Shapath Residency

New Alkapuri, Gotri. [email protected]

Mobile No:09998245505 3. Mr.PrashantChudiwala 401,New Anand KiranBuilding,ManishaChowkdi ,Old

PadraRoad,Baroda- 390021 Mobile No:09879309933 [email protected]

M

M/s. Jyoti Om

PLANT LA

m Chemical R

AYOUT

Research Cent

M/s. Sitam

tre Pvt. Ltd.

mani Organic

c Pvt. Ltd., P

Phase-III GI

A

IDC Dahej, B

ANNEXURE

Bharuch

E-III (A)

M

M/s. Jyoti Omm Chemical RResearch Cent

M/s. Sitam

tre Pvt. Ltd.

mani Organic

c Pvt. Ltd., P

Phase-III GI

IDC Dahej, B

Bharuch

M

M/s. Jyoti Om

SITE PLAN

m Chemical R

N

Research Cent

M/s. Sitam

tre Pvt. Ltd.

mani Organic

c Pvt. Ltd., P

Phase-III GI

A

IDC Dahej, B

ANNEXURE

Bharuch

E-III (B)



ANNEXURE-IV

LIST OF PRODUCTS & CAPACITY

Sr. No.

Product Name Capacity MT/ Month

Group A 10 MT/Month

1. 2-Amino Phenol-4-Methyl Sulfone (APMS) And/Or

2. 4 Hydroxy 3 Aminobenzene n Methyl SulphonamideAnd/Or

3. 4 Hydroxy 3 AminobenzeneSulphonamideAnd/Or

4. 4 Hydroxy 3 AminobenzeneSulphoanilideAnd/Or

5. 4 Hydroxy 3 Aminobenzene 2 carboxySulphoanilideAnd/Or

Group-B 40 MT/Month6. Gamma acidAnd/Or

7. CisBromobenzoateAnd/Or 8. J-acid And/Or 9. 4-Chloro 2-Amino Phenol And/Or 10. Phenyl Gamma acid And/Or 11. 1-Acetyl-4-(4'-

Hydroxyphenyl)PiperazineAnd/Or 12. 1-(2,3-Dichlorophenyl)Piperazine HCl

And/Or 13. 1-(4-Methoxy Phenyl) PiperazineAnd/Or 14. Saccharine SodiumAnd/Or 15. G-salt And/Or 16. 3,5,6 Trichloro Salicylic acid And/Or Group-C 150 MT/Month17. (4-Nitro 2- Amino Phenol)4-NAP And/Or

18. HalazoneAnd/Or 19. (Diethyl Meta Amino Phenol)DEMAP

And/Or 20. Metanilic acid And/Or 21. Tobias acid And/Or 22. N-Methyl J Acid And/Or 23. 2,4 Dichloro benzoic acid & benzoic acid

And/Or 24. 2,4 Dichloro benzoic acid And/Or Group-D 100 MT/Month 25. N-Phenyl J Acid And/Or



26. Peri acid And/Or 27. Phenyl peri acid And/Or 28. Amido G Salt And/Or 29. K acid And/Or 30. Schaeffer's acid And/Or 31 L-Glutamic acid And/Or 32. Chloramine And/Or 33. P-Toluene SulfonamideAnd/Or 34. Ortho Toluene Sulfonamide And/Or 35. Para Chloro Benzene Sulfonamide And/Or 36. (M-Nitro Para Chloro Benzene

Sulfonamide)MNPCBS And/Or 37. 4-Chloro-3-sulfomonyl benzonic acidAnd/Or 38. Sodium NaphthenonateAnd/Or 39. Cis-TosylateAnd/Or 40. Benzyl Bromide And/Or Group-E 300M T/Month41. Sulpho Tobias Acid And/Or 42. 2-chloroethylamine hydrochloride And/Or 43. R-salt And/Or 44. Aniline 2,4 Di sulfonic acid And/Or 45. Aniline 2,5 Di Sulfonic acid And/Or 46. Sulfalinic acid And/Or 47. PTS Urea And/Or 48. PCBS Urea And/Or 49. TetraloneAnd/Or 50.

P-Nitro Benzyl Bromide And/Or 51. T-Butyl Chloride And/Or 52. PTS acidAnd/Or 53. Benzene Sulphonic acid And/Or 54. p-Xylene Sulphonic acid And/Or 55. M-Xylene Sulfonic acid And/Or 56. Cumene Sulfonic acid And/Or 57. Sulfanilamide And/Or 58. PCBSC And/Or 59. Benzene Sulfonyl chloride And/Or 60. M-Nitro, P-chloro benzene Sulfonyl chloride

And/Or 61. α-NaphtholAnd/Or 62. Meta Chloro Aniline And/Or 63. α-Napthyl Amine And/Or 64. Methyl sulfonyl methane And/Or 65. Phenyl Alpha NaphthylamineAnd/Or 66. 2-chloroethylamine hydrochloride And/Or



67. PTSC And/Or 68.

Saccharine from OTSA And/Or 69. Para carboxy benzene Sulfonamide And/Or 70. LasamideAnd/Or 71.

5-chloro Aniline-2,4-Disulphonamide And/Or 72. 2- Chloro ethanol And/Or Group-F 2 MT/Month 73. R & D Products TOTAL ORGANIC PRODUCTS 602 INORGANIC PRODUCT 1. Potassium Chloride 40 2. Magnesium Sulphate 800 3. Plaster Of Paris 300 4. Sodium Bromide 20 5. Ammonium Chloride 50 6. Potassium Permanganate from MnO2

200

TOTAL INORGANIC PRODUCTS 1410



ANNEXURE-V PRODUCTWISE RAW MATERIAL CONSUMPTION

Sr. No.

Name of Product Production quantity

in MT/Month

Name of Raw material

Raw material

consumptionquantity in MT/Month

Group A- 10 MT/Month

1 2-Amino Phenol-4-Methyl Sulfone (APMS)And/Or

p-Chloro Benzene Sulfonyl chloride 14.2Dimethyl sulfate 7.1Sodium bisulfite 12Caustic lye 10Sulphuric acid (98%) 12Nitric acid (98%) 4.3Caustic lye (50 %) 11NaSH (30%) 15HCl 30% 8.5Ice 9Total 103.1

2.

4 Hydroxy 3 Aminobenzene n Methyl SulphonamideAnd/Or

4 chloro 3 nitrobenzene N-methyl sulphonamide 12.4Sodium hydroxide 7.9Sodium hydrogen sulphide 15.8Sodium bisulphite 15.8Hydrochloric acid 14.9Total 66.8

3.

4 Hydroxy 3 AminobenzeneSulphonamideAnd/Or

4 chloro 3 nitrobenzene sulphonamide 12.6Sodium hydroxide 8.5Sodium hydrogen sulphide 17Sodium bisulphite 17Hydrochloric acid 16Total 71.1

4. 4 Hydroxy 3 AminobenzeneSulphoanilideAnd/Or

4 chloro 3 nitrobenzene sulphoanilide 11.82Sodium hydroxide 6.06



Sodium hydrogen sulphide 12.12Sodium bisulphite 12.12

Hydrochloric acid 11.36Total 53.48

5. 4 Hydroxy 3 Aminobenzene 2 carboxySulphoanilideAnd/Or

4 chloro 3 nitrobenzene 2 carboxysulphoanilide 11.56Sodium hydroxide 6.49Sodium hydrogen sulphide 10.39Sodium bisulphite 10.39Hydrochloric acid 19.48Total 58.31

Group-B-40 MT/Month

6. Gamma AcidAnd/Or Amido G acid 57Caustic soda 68ML from G salt 160Total 285

7.

CisBromobenzoateAnd/Or

2,4-Dichloro Acetophenone 37Glycerine 22p-Toluenesulfonic acid 1Bromine 37Ammonia (25 %) 16Sodium Hydroxide 16Benzoyl chloride 37Methanol 4Toluene 2

Total 1738.

J-AcidAnd/Or

Tobias acid 48Oleum (25%) 112Caustic soda lye (50%) 60Total 220

9. 4-Chloro 2-Amino Phenol And/Or

2-Nitro-4-dichlorobenzene 68Caustic lye (50%) 28NaHS solution 30% 148HCl (30%) 72Total 316

10. Phenyl Gamma acid And/Or

Gamma acid 36Aniline 14



Soda Ash 12Dil.H2SO4 60Vacuum salt 54Total 176

11. 1-Acetyl-4-(4'-Hydroxyphenyl)Piperazine And/Or

Sodium hydrosulfite 1.4p-Aminophenol 47.1Bis HCl-65% 79.1Acetic chloride 45.6Na2CO3 solution 14.1Charcoal 1.4HCl solution -30% 2.8Total 191.5

12. 1-(2,3-Dichlorophenyl)Piperazine HClAnd/Or

O-Xylene 80.0Bis HCl 34.72,3 Dichloro Aniline 26.7NaOH 10.7Activated carbon 1.1Hyflow 1.3HCl 30% 6.7Iso Propyl Alcohol(IPA) 133.3Total 294.4

13.

1-(4-Methoxy Phenyl) Piperazine And/Or

4Methoxy Aniline 46.0Bis HCl 82.3Caustic lye 18.4Activated carbon 0.5HCl 30% 16.6Total 163.7

14. Saccharine SodiumAnd/Or Caustic lye 50Chlorine gas 21.2Phthalamide 43.2Caustic lye 26Methanol 41.2Toluene Recycled (from previous batch)+fresh 3.6Total 185.2

15. G-SaltAnd/Or Naphthol 19.35Sulphuric acid 21.45Oleum 33.06Salt 12.10Total 86.0

16. 3,5,6 Trichloro Salicylic acid And/Or

Salicylic acid 25H2SO4 (98%) 110



Chlorine 40.9SO3 79.5Xylene 159.1Ice 43.2Total 457.7

Group-C- 150 MT/Month 17. (4-Nitro 2- Amino Phenol)4-

NAPAnd/Or CaO 28.5

Sulfur 21Caustic lye 99NaSH 34.5DNCB 90Sulfuric acid 6Salt 216Total 495

18.

HalazoneAnd/Or

PCBS 225Sodium Hypochlorate 165HCl (30%) 270Total 660

19.

Diethyl Meta Amino Phenol (DEMAP) And/Or

Metanilic Acid 165Ethyl Chloride 127.5Sodium Hydroxide 112.5Potassium Hydroxide 93.8HCl 90Total 588.8

20. Metanilic AcidAnd/Or Nitro benzene 126Oleum (25%) 252Calcium hydroxide 180HCl (30%) 45Iron powder 126Soda ash 729H2SO4 (98%) 105Total 1563

21. Tobias acid And/Or β-Naphthol 100CSA 169EDC 6Caustic lye 56Liq. Ammonia 241Sodium bisulphite solution 219Ice 94Total 884

22. N-Methyl J AcidAnd/Or J Acid 168



98% Sulphuric acid 67.5SBS 187.5Methyl Amine 217.5Calsolene oil 0.8Total 641.3

23. 2,4 Dichloro benzoic acid & benzoic acid And/Or

Trans Isomer 219.2Nitric Acid (98%) 115.4Soda ash 14.4Total 349

24. 2,4 Dichloro benzoic acidAnd/Or 2,4 Dichloro Toluene 150Nitric acid (98%) 130Soda ash 113HCl 30% 393Ice 250Total 1035

Group-D-100 MT/Month

25.

N-Phenyl J Acid And/Or

J Acid 23.5340% Sulfuric acid 40.20SBS 21.24Soda ash 2.29Aniline oil 9.15carbon 0.65Total 97.1

26. Peri acidAnd/Or Sulphuric acid 104.1Naphthalene 91.3Nitric Acid 45.3Lime stone 2.8magnesium 3.9HCl 153.4Iron 5.5Total 406.3

27. Phenyl peri acid And/Or Aniline 32.5Peri acid 77.5Soda ash 25sulfuric acid 35Total 170.0

28. Amido G SaltAnd/Or Sulfuric Acid 19.8B-Napthol 3323% Oleum 34.7Salt 16.5Ammonia 22Total 126

29. K-AcidAnd/Or Sulfuric Acid 24.8Amido G acid 27.5



25% Oleum 8.3Salt 11Total 71.5

30. Schaeffer's AcidAnd/Or Sulfuric Acid 67B-Napthol 61Soda Ash 37.8Total 165.8

31. L-Glutamic acidAnd/Or Monosodium Glutamate 125HCl (30 %) 233Total 358

32. ChloramineAnd/Or PTS Amide 62Caustic lye 60Chlorine 26Total 148

33. P-Toluene SulfonamideAnd/Or PTS chloride 112Ammonia Liquor (25%) 112Caustic Soda 22.5HCl (30%) 68Total 314.5

34. Ortho Toluene Sulfonamide And/Or OTS chloride 112Ammonia Liquor (25%) 112Caustic Soda 23HCl (30%) 68Total 315

35. Para Chloro Benzene SulfonamideAnd/Or

Para Chloro Benzene sulfonyl chloride 112Ammonia Liquor (25%) 112Caustic Soda 22.5HCl (30%) 68Total 314.5

36. M-Nitro Para Chloro Benzene Sulfonamide And/Or

MNPCBSC 109Ammonia Liquor (25%) 110Caustic Soda 23HCl (30%) 68Total 310

37. SABC acid And/Or Para chloro benzoic acid 82CSA 125liquor ammonia 25% 120HCl (30%) 70



Ice 100Total 497

38. Sodium NaphthenonateAnd/Or α-Naphthylamine 52Sulphuric acid (98%) 36HCl (30%) 16Vacuum salt 28Total 132

39. Cis-TosylateAnd/Or Imidazole 15.5CisBromo Benzoate 100.0Dil. H2SO4 30% 153.5Para Toluene sulfonyl chloride 38.5Methanol 200.0Sodium carbonate 10.0Total 517.5

40. Benzyl Bromide And/Or

Benzyl Alcohol 64HBr (48%) 120Soda ash 5Total 189

Group-E-300 MT/Month 41. Sulpho Tobias AcidAnd/Or Tobias acid 181.82

98% sulfuric acid 72.7323% oleum 472.73Ice 909.09Salt 181.82Total 1818.2

42. 2-chloroethylamine hydrochlorideAnd/Or

Monoethalamine 187.5thionyl chloride 412.5NaOH 46.9EDC 562.5Total 1209.4

43. R-salt And/Or

M.L From G-salt 3750Aniline oil make up 45Caustic lye 93Salt 412.5Total 4301

44. Aniline 2,4 Di sulfonic acidAnd/Or Sulfanilic acid 175Oleum 132Total 307

45. Aniline 2,5 Di Sulfonic acidAnd/Or Meatanilic acid 197.425% Oleum 138.1Salt 6Total 341.5

46. Sulfalinic acidAnd/Or Aniline oil 162Sulphuric acid 171



Total 33347. Para Toluene Sulfonyl UreaAnd/Or PTS Amide 184.6

Urea 64.6Soda ash 115.4Total 364.6

48. Para Chloro Benzene Sulfonyl UreaAnd/Or

PCBS Amide 184.6Urea 64.6Soda ash 115.4Total 364.6

49.

TetraloneAnd/Or

α-Naphthol 210ODCB 426Aluminium Chloride 240Total 876

50. P- Nitro Benzyl BromideAnd/Or Para Nitro Toluene 192Bromine 222Methanol 600Dil. HBr solution from Benzyl bromide 240Total 1254

51. T-Butyl Chloride And/Or

Tert-Butyl alcohol 201HCl (gas) 99Total 300

52. P Toluene sulfonic acid And/Or Toluene 180Sulfuric Acid (98%) 174Total 354

53. Benzene Sulphonic Acid And/Or Benzene 132Sulfuric Acid (98%) 168Total 300

54. P-Xylene Sulfonic Acid And/Or P-Xylene 156Sulfuric Acid (98%) 144Total 300

55. M-Xylene Sulfonic Acid And/Or M-Xylene 156Sulfuric Acid (98%) 144Total 300

56. Cumene Sulfonic acid And/Or

Cumene 180Sulfuric Acid (98%) 150Total 330

57. Sulfanilamide (Route-I)And/Or PCBSC 437.5Ammonia Liquor (25%) 625Caustic Soda 200

HCl (30%) 375Total 1637.5

57. Sulfanilamide (Route-II) Sulfanilic acid 300



Thionyl chloride 206Ammonia liq.for SO2 scrubbing 300Solvent 25Total 831

58. Para Chloro Benzene Sulfonyl Chloride And/Or

MCB 160.5CSA 336Ice 300Total 796.5

59.

Benzene Sulfonyl chloride And/Or

Benzene 135CSA 405Ice 600Total 135Total 1140

60. M-Nitro, P-chloro benzene Sulfonyl chloride And/Or

ONCB 186CSA 300Ice 300Total 786

61. α-NaphtholAnd/Or

α-Naphthylamine 360Total 360

62. Meta Chloro Aniline And/Or Meta nitro chlorobenzene 420Iron powder 420HCl (30%) 240Soda ash 90Total 72.6

63. α-Napthyl Amine And/Or

Naphthalene 330Nitric acid (98%) 165.0Sulphuric acid 333HCl (30%) 150Iron 450Soda ash 22.5Ice 180Total 1630.5

64. Methyl sulfonyl methane And/Or Dimethyl sulfoxide 192.9Hydrogen Peroxide (50%) 171.4Toluene 160.7Total 525

65. Phenyl Alpha NaphthylamineAnd/Or

α-Naphthyl Amine 217.5Aniline 139.5Total 357

66. N,N Bis (2-Chloroethyl Amine Hydrochloride) And/Or

Diethanolamine 187.5Thionyl chloride 412.5NaOH 46.9



EDC 562.5Total 1209.4

67. Para Toluene Sulfonyl Chloride(Route-I) And/Or

CSA 199TC 205Ammonia 25% for SO2 scrubbing 232Toluene 157Ethylene dichloride 27Total 819

67. Para Toluene Sulfonyl Chloride(Route-II)

Toluene 153.3CSA 625Total 778.3

68. Saccharine from OTS amide And/Or O-Toluene Sulfonamide 285Potassium Permanganate (50%) 1080Caustic potash lye (50%) 300HCl (30%) 720Total 2385

68. Saccharine from OTS amide And/Or MnO2 sludge 93.8Caustic potash 117.2Chlorine 33.8Total 244.7

69. Para carboxy benzene Sulfonamide And/Or

P-Toluene Sulfonamide 285Potassium Permanganate (50%) 1080Caustic potash lye (50%) 300HCl (30%) 720Total 2385

69. Para carboxy benzene Sulfonamide And/Or

MnO2 sludge 93.8Caustic potash 117.2Chlorine 33.8

Total 244.7

70

LasamideAnd/Or

2,4 Dichloro benzoic acid 240CSA 600EDC 10Ammonia gas 50Methanol 20Ice 400Total 1320



71.

5-chloro Aniline-2,4-DisulphonamideAnd/Or

Meta chloro aniline 150Chloro sulphonic acid 795MIBK 48Ammonia gas 138Acetone 900Ice 900Total 2931

72. 2-Chloro ethanol Hydrochloric acid(30%) 219.5

Ethylene oxide 80.5Total 300TOTAL 6993.6



ANNEXURE-VI MANUFACTURING PROCESS

Group-A10 MT/Month

1. 2-Amino Phenol-4-Methyl Sulfone (APMS)

Brief Manufacturing Process: Stage-I In a reactor, a solution of sodium bisulfate and caustic lye is made. In that, PCBS chloride is dissolved. Now add Dimethyl sulfate at a control rate & temperature. Cool & filter. Dry the filtrate.In a reactor, make the mixture of sulfuric acid and Nitric acid. In it change the dry material fromstage-I at a control rate & temperature, after cooling, quench in Ice. Filter & centrifuge the material. Stage-II In an autoclave, take the above material & caustic lye, reflux the mixture at higher 1050 C temperature & pressure for several4 hours. Release the pressure & cool the reaction mass to roomtemperature.Add sodium hydrosulfide to the above reaction mass & reflux for several hours. Filter thesolution & neutralize by adding HCl (30%) & precipitate the material. Filter & dry the wet cake,we get the final product. Chemical Reaction



Material Balance:

INPUT KG OUTPUT KG

p-Chloro Benzene Sulfonyl chloride 1420 Reaction mass 6730Dimethyl sulfate 710Sodium bisulfite 1200Caustic lye 1000Water 2400Total 6730 Total 6730

Reactor

M

M/s. Jyoti Om

2.4 Hydrox

Brief Manu

Reaction m

Total

p-Chloro bmethyl sulSulphuric Nitric acid

Total

Reaction m

WaterIce

Total

Nitro ProdCaustic lyNaSH (30

Total

Reaction mHCl 30%

Total

m Chemical R

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ufacturing P

mass

benzene lfoneacid (98%

d (98%)

mass

ductye (50 %)%)

mass

Research Cent

benzene n M

Process:

6730

6730

1130) 1200

430

2760

2760

1000900

4660

140011001500

4000

4000850

4850

M/s. Sitam

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Methyl Sulp

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p-Chloro bemethyl sulfEffluent to Drying lossTotal

Reaction m

Total

Sulphuric acid+Nitric(40%) reuseNitro Produ

Total

Reaction m

Total

2-AminophMethyl SulDrying lossEffluent to Total

IDC Dahej, B

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s

mass

c acid educt

mass

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Bharuch

11305400

2006730

2760

2760

32601400

4660

4000

4000

1000300

35504850



Chemical Reaction:



Material Balance:

INPUT KG OUTPUT KG

4 chloro 3 nitrobenzene N-methyl sulphonamide

250Reaction mass 1110

Sodium hydroxide 160Water 700

Total 1110 Total 1110

Sodium hydrogen sulphide 320

4 hydroxy 3 nitrobenzene N-methyl sulphonamide sodium solution 1750

Sodium bisulphite 320Reaction mass 1110Total 1750 Total 1750

4 hydroxy 3 nitrobenzene N-methyl sulphonamide sodium solution

1750

4 hydroxy 3 nitrobenzene N-methayl sulphonamide 2050

Hydrochloric acid 300


4 hydroxy 3 nitrobenzene N-methayl sulphonamide 2050 ML to ETP 1788

Wet cake 262


Wet cake 262 Drying loss 60Product 202

Total 262 Total 262

Reactor

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Reactor

Filter & Centrifuge

Drying

M

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3) 4 Hydrox

Brief Manu

Mixtat 10

Step100 comm

Chemical R

m Chemical R

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benzene Su

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4) 4 Hydroxy 3 Amino benzene Sulphoanilide

Brief Manufacturing Process:

Mixture of 4 chloro 3 Nitro Benzene Sulphonilide is dissolving in sodium hydroxide and H2O at 100 °C-105°C for 12 Hours.

Step-2, mother liquor of step-1 is added in sodium hydrogen sulphide and sodium bisulphite at

100 °C-105°C. Then after filter the mixture and collect the filter mass.Maintain pH 7 of

collected filter mass using HCl. After filter, we get pure commercial product 4Hydroxy 3

Amino Benzene Sulphonilide

Chemical Reaction:



Material Balance:

INPUT KG OUTPUT KG

4 chloro 3 nitrobenzene sulpho anilide





4 hydroxy 3 nitrobenzene sulpho anilide -sodium solution 1812


4 hydroxy 3 nitrobenzene sulpho anilide -sodium solution

18124 hydroxy 3 amino benzene sulpho anilide 2112



4 hydroxy 3 amino benzene sulpho anilide 2112 ML to ETP 1768

Wet cake 344



Total 344 Total 344

M.S. Reactor

Reactor

Reactor

Filter & Centrifuge

Drying

M M/s. Jyoti Om

5) 4 Hydrox

Brief Manu

Chemical R

m Chemical R

xy 3 Aminob

ufacturing P

Reaction:

Research Cent

benzene 2 c

Process:

M/s. Sitam

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carboxySulp

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phoanilide

c Pvt. Ltd., P

Phase-III GI

IDC Dahej, B

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Material Balance:

INPUT KG OUTPUT KG

4 chloro 3 nitrobenzene 2 carboxy sulpho anilide





4 hydroxy 3 nitrobenzene 2 carboxy sulpho anilide -sodium solution 1896


4 hydroxy 3 nitrobenzene 2 carboxy sulpho anilide -sodium solution

18964 hydroxy 3 amino benzene 2 carboxy sulpho anilide 2496



4 hydroxy 3 amino benzene 2 carboxy sulpho anilide

2496ML to ETP 2096Wet cake 400



Total 400 Total 400

M.S. Reactor

Reactor

Reactor

Filter & Centrifuge

Drying

M

m

r

Au

D

M/s. Jyoti Om

Group-B 40

6. Gamma a

Brief Manu

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Chemical R

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&

Phase-III GI

compound. lation with in methanol

Fusion mass

Total

Wet cakeEffluent to ETP

Total

Gamma acidDrying loss

Total

IDC Dahej, B

Glyce to cobenzoylchl

l andtoluene

Bharuch

ompound oride in

e solvent

3425

3425

16005825

7425

1000600

1600



Material Balance:

8. J-acid

Brief Manufacturing Process: Stage-I In a reactor, take Oleum (25%) and charge Tobias acid in it. Reflux for several hours and drown in water. Filter the cake. Stage-II In a reactor, take caustic lye & add above cake in it. Reflux for several hours. Charge the fusion mass to another reactor containing H2SO4 (40%). Filter the material. Dry, pulverize & pack.

Chemical reaction:

Stage 1&2:INPUT KG OUTPUT KG2,4-Dichloro Acetophenone 468Glycerine 273p-Toluenesulfonic acid 16 Methanol recovered 1900Bromine 468 Methanol loss 50Ammonia (25 %) 195 Toluene recovered 1920Sodium Hydroxide 200 Toluene loss 30Benzoyl chloride 468 Effluent 830

Methanol 1950 Trans Isomer reuse 758Toluene 1950 product 500


Reactor



Material Balance:

9.4-Chloro 2-Amino Phenol


Stage-I

In a reactor take 2-nitro-4-dichlorobenzen and caustic lye. Reflux for several hours. filter the solution.

Stage-II

Add sodium hydrosulfide solution in the above ML at a controlled rate and tempreture.After the

addition is completed, filter the solution and add HCl (30%)to bring the pH .filter the material out from

the ML Dry and pack.

Stage-IINPUT KG OUTPUT KGTobias acid 1200Oleum (25%) 2800 Reaction mass 4000


Reaction mass 4000 Wet cake 2250Water 2000

Dil. H2SO4 (50%) 3750


Stage-IIWet cake 2250 Reaction mass 7500Caustic soda lye (50%) 1500Dil. H2SO4 (50%) 3750Total 7500 Total 7500

Reaction mass 7500 J-Acid 1000Drying Loss 200Effluent to ETP 6300


Reactor

Filteration

Reactor

Filteration



Chemical Reaction:

Material balance:

Stage-IINPUT KG OUTPUT KG

2-Nitro-4-dichlorobenzene


Caustic lye (50%) 700


Stage-IIReaction mass 2400 Reaction mass 6100NaHS solution 30% 3700


Reaction mass 6100 Wet cake 1200HCl (30%) 1800 Effluent to ETP 6700


Wet cake 1200 4-Chloro 2- Amino Phenol 1000Drying loss 200


Reactor-2

Filtration

Reactor-1

Drying



10. Phenyl Gamma Acid


In a reactor make soda ash solution. In it add Gamma acid and aniline. Reflux for several hours.Add vacuum salt to the reaction mass. Now add dilute sulphuric acid in the filtered solution. Atthat time the ammonia is released which is recovered as liquor ammonia. After that, filter the material. Dry & pack.

Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KG

Gamma acid 900

Aniline 350 Reaction mass 1500

Soda Ash 300Ammonia Solution (25%) 250

Water 200Total 1750 Total 1750

Reaction mass 1500Water 1700 Effluent to ETP 4800Dil.H2SO4 1500 Wet Cake 1250Vacuum salt 1350Total 6050 Total 6050

Wet Cake 1250 Phenyl Gamma Acid 1000Drying loss 250


Reaction vessel

Drying

Isolation cum filter

M

M/s. Jyoti Om

11.1-Acetyl

Brief Manu

m Chemical R

l-4-(4'-Hydr

ufacturing P

Research Cent

roxyphenyl)

Process:

M/s. Sitam

tre Pvt. Ltd.

)Piperazine

mani Organic

c Pvt. Ltd., P

Phase-III GI

IDC Dahej, B

Bharuch

M

M

M/s. Jyoti Om

Chemical R

Material Ba

INPUT

Sodium hydp-AminopheBis HCl-65%WaterAcetic chlorTotal

Reaction maNa2CO3 sol

Total

Warer washReaction maCharcoalHCl solutionTotal

WaterReaction ma

Total

m Chemical R

Reaction:

alance:

drosulfiteenol%

ride

asslution

esass

n -30%

ass

Research Cent

KG

3100168

7097

438

43830

468

80468

36

557

30555

585

M/s. Sitam

tre Pvt. Ltd.

Cen

Re

Cen

Puri

mani Organic

ntrifuge

eactor

ntrifuge

ification

c Pvt. Ltd., P

OUTPU

Reaction

Total

Reaction

Total

CharcoaReaction

Total

ProductEffluentEvaporaTotal

Phase-III GI

UT

n mass

n mass

al recoveryn mass

tation loss

IDC Dahej, B

KG

Bharuch

438

438

468

468

2555

557

85480

20585



12. 1-(2,3-Dichlorophenyl)Piperazine HCl


1) Install 2.0 L cap 4-neck RBF with Condenser, T P, stirrer and Heating Mental. 2) At R. T, charge Xylene, Bis. HCl (Handle with carefully, Use PPE) under stirring. 3) Start heating to reach the temp 45°C. 4) Start addition of DCA gradually between 45°C in 1 hr. 5) After addition of DCA, raise the temperature at 50°C. 6) Maintain temperature between 50°C for 48 hrs. Send IP for GC. DCP:95%(NLT). If results not ok repeat the IP sample after every 8 hrs. 7) After reaction is complete, cool the reaction mass to 35°C. Add 1000 ml DM water in 1hr. cool the reaction to 20-25°C. Stir or 1 hr. 8) Filter the reaction wash the bed with 100 ml water. Separate the layer.Upper organic layer-uses it for step no. 12. Lower aq. Layer is the having product (pH-6.5). 9) Xylene layer wash with 50 ml DM water and separate layers.Upper organic layer-for Xylene recovery after getting neutral pH with water wash.Lower aq. Layer is the having product. Mix with aq. Layer of step no.11. 10) Extract the aq. Acetic layer (from step no.13) + 1 L clean RBF. 11) Basify the reaction with caustic layer to pH + 11-13. Stir for 30 min at 20-25°C. 12) Separate the layers. Keep the aq. Layer aside. (Note: keep emulsion with the organic layer, add carbon in upper organic layer (having emulsion) and stir for 1 hr. 13) Filter the reaction through high flow bed and give the bed wash with Toluene. Suck drywell. 14) Separate the aq. Layer from the ML+WML of step no. 17. Acidify the reaction with con. HCl (35%) below 50-60°C to achieve pH: 1-2. Start heating to remove water completely from reaction azetropically. (It will take about 7-9 hrs.) 15) Heating stops and cools to room temperature

Chemical Reaction:

NH2

Cl

Cl

2,3-dichloroanilineM.W: 162.01

Cl

HN

Cl H Cl

2-chloro-N-(2-chloroethyl)ethanamine hydrochloride

M.W: 178.48

N

NH

Cl

Cl

H Cl

1-(2,3-dichlorophenyl)piperazine hydrochloride

M.W: 267.58

1-(2,3-dichlorophenyl) piperazine hydrochloride



Material Balance:

13.1-(4-Methoxy Phenyl) Piperazine


1) 100 g of p-aminophenol is taken in a mixture of 280 ml water and 180 ml water and 168gBis (2-

Chloroethylamine) hydrochloride added. (Actually Bis HCl solution of 65%strength is used and water

adjusted accordingly.

2) At reflux and under nitrogen 106 ml caustic lye solution is added over 9 hr maintain pH between 6 -

6.1.

3) Sodium hydrosulfite is added to decolorize the reaction mass to pale yellow color.

4) After maintain for 2 hrs, methanol 100 ml is added and stirred for 1 hr. the acetate saltthat

precipitates out is filtered and washed with methanol.

INPUT KG OUTPUT KG

O-Xylene 600 Reaction mass 1060Bis HCl 260

2,3 Dichloro Aniline 200Total 1060 Total 1060

Reaction mass 1060 Organic Aq. Mass 610DM water 150 Recovered Xylene 580

Xylene loss 20Total 1210 Total 1210

NaOH 80Organic Aq. Mass 610 Filtered solution 684Activated carbon 4 Carbon filter 20Hyflow 10Total 704 Total 704

HCl 30% 50 Product w/c 360Filtered solution 684 Effluent to ETP 374

Total 734 Total 734

Product w/c 360 Product 300IPA 1000 Recovered IPA 940Activated carbon 4 IPA loss 60

Carbon sludge 10Drying loss 54


DCP Reflux

Disolution

Filtration

Isolation & Filtration

Purification

M

w

M/s. Jyoti Om

5) The abo

dissolving 3

6) After mai

and maintain

7) The M1 c

8) M1 crude

crude, 500

added to dec

sodium hyd

colored filte

with methan

Chemical R

m Chemical R

ve acetate s

0 g in 150 m

intaining at

ned for 0.5 h

crude obtaine

e is purified

ml of meth

colorize, 10%

drosulfite so

ered is coole

nol and dried

Reaction:

Research Cent

salt is taken

ml water, is a

pH 8-8.2 for

hr.

ed is centrifu

d by charcoa

anol-water m

% active cha

lution added

ed under Nitr

d inoven at 4

M/s. Sitam

tre Pvt. Ltd.

n in 500 m

added gradua

r around 1 h

uged, washe

al treatment

mix is requ

arcoal added

d to decolor

rogenatmosp

45-50°C.

mani Organic

ml water and

ally to bring

hr the pH of

ed with water

in a mix of

uired).pH is

d and refluxe

rize thepink

phere and fil

c Pvt. Ltd., P

d soda ash

g pH to aroun

the solution

r and then w

f 3:2 methan

first adjuste

ed. After 1h

kish color fi

ltered to giv

Phase-III GI

solution pr

nd 8-8.2.

n is shifted to

with methano

nol water so

ed to 5-5.5,

hr the solutio

filtrate. The

ve pure M1.

IDC Dahej, B

epared sepa

o 5-5.5using

ol.

olution (for1

sodium hyd

on is filtered

white to lig

The cake is

Bharuch

aratelyby

g dil HCl

100 g k3

drosulfite

d hot and

ght pink

s washed

M

M

M/s. Jyoti Om

Material Ba

14.SacchariBrief Manu

In a reactor

scrubbed in

crystallize.

Chemical R

INPUT

4MABis HClWaterCaustic lye

Total

Reaction mActivated c

Total

HCl 30%Filtered solu

Total

Product w/c

Total

m Chemical R

alance:

ine Sodium ufacturing P

r, Phthalic

n water to f

Reaction:

assarbon

ution

c

Research Cent

Process:

anhydride a

for ammonia

KG

100179180

40

499

4991

500

36498

534

100

100

M/s. Sitam

tre Pvt. Ltd.

and urea ar

a liquor .aft

0900

9

91

0

68

4

0

0

mani Organic

e heated .d

ter completi

Reactor

Filtration

Isolation &Filtration

Drying

c Pvt. Ltd., P

during proce

ion of react

R

F

P

PD

&

Phase-III GI

ess ammonia

tion ,the ma

OUTPUT

Reaction ma

Total

Filtered soluCarbon slud

Total

Product w/cEffluent

Total

ProductDrying loss

Total

IDC Dahej, B

a releases w

aterial is co

KG

ass

utiondge

Bharuch

which is

oled to

G

499

499

4982

498

100434

534

8713

100

M


M/s. Sitam

tre Pvt. Ltd.

mani Organic

c Pvt. Ltd., P

Phase-III GI

IDC Dahej, B

Bharuch



Material Balance:

INPUT KG OUTPUT KGMethyl anthranilate 930 Reaction mass 3430Water 1000Conc. HCl 1200Sulfuric acid 300Total 3430 Total 3430

Sodium Nitrite 420Cucl3 70

Water 500 Reaction mass 4420

Reaction mass 3430Total 4420 Total 4420

Reactor

Reactor

INPUT KG OUTPUT KGPhthalic Anhydride 1000 Ammonia liquor 460Urea 405 CO2 gas 290Water 345 Phthalimide 1000


Reactor & Crystallization

INPUT KG OUTPUT KGCaustic lye 1250 Reaction mass 4080Chlorine gas 530Water 2300


Reaction mass 4080 Reaction mass 6840Phthalamide 1080Caustic lye 650Methanol 1030Total 6840 Total 6840

Reaction mass 6840 Mix. Solvent waste 200Water 1000 Distillation waste 3Toluene Recycled (from previous batch)+fresh 90 Recovered Toluene recycled 85

Aqueous component to ETP 6642Methyl anthranilate 1000


Reactor

Reactor

Reactor

M

H

M/s. Jyoti Om

15. G-salt

Brief ManuThe mixtureit while macompletion quantity of carried out aHDPE bags.

Chemical R

Reaction massChlorine gasToluene (RecySO2 gas

Total

Reaction massAmmonia gas

Water

Total

Reaction massConc. HCl

Total

Reaction massWater wash

Total

m Chemical R

ufacturing Pe of oleum 2aintain tempof Bita-Napsalt is adde

along with st.

Reaction:

ycled+Fresh)

Research Cent

Process: 25% and sulfperature belphthol charg

ed into it. Thtirring. Mass

44225

15070

687

65425

115

7940.

2670.100

3670.

3670.100

4670.

M/s. Sitam

tre Pvt. Ltd.

furic acid arow 60 0 Cging. the mhe drowned s is filtered t

20500000

70

4050

50

.0

.000

.0

.000

.0

mani Organic

re received inC. make up mass is then

mass heatethrough nutc

Reactor

Reactor

Reactor

Centrifuge

c Pvt. Ltd., P

n sulfonatoroleum is c

n reacted at ed with steamche filter and

ReNiSOCl

To

AReAmToCuReTo

Re

To

ASa

To

Phase-III GI

r. Bita-Naphcharged to

elevated tem, if requird then centri

eaction massitrogen gas to scO2 to Ammonia l2 to Scrubber

otal

queous componecovered Toluenmmonia to scruboluene loss ucl3 recoveryeaction massotal

eaction mass

otal

queous ML to Eaccharin

otal

IDC Dahej, B

hthol is chargthe sulfonat

emperature.Rrednatural coifuged and p

crubbertrap

nent to ETPnebber

ETP

Bharuch

ged in to tor after Required ooling is

packed in

6540170110

50

6870

37001480

202050

2670.07940.0

3670.0

3670.0

36701000

4670



Material Balance:

16) 3,5,6Trichloro Salicylic acid


Stage: I

In a reactor takesulphuric acid add salicylic acid in it. Forge chloride gas at a controlled rate and temperature for several hours. In pressure of SO3 and Iodine as catalyst after completion the material in Ice.

Stage-II

In the above vessel add xyleme and stir for several hours at higher temperature separate the organic layer to anther reactor to here Xylen is distilled out to from the catalyst of the product .Dry and pack the material.

Chemical Reaction:

INPUT kg OUTPUT kgB-Naphthol 484 Reaction mass 1847Sulphuric acid 536Oleum 827


Reaction mass 1847 Evaporation Loss 368Water 2016 reaction mass 3798Pottasium Chloride 302

Total 4165.31 Total 4165

Reaction mass 3798 Spent Acid for R-Salt 2500wet cake 1298


wet cake 1298 M.L to reuse/CETP 298G- salt 1000.0


Centrifugation

Sulfonator

Isolation

Filtration

M

Hp

M/s. Jyoti Om

Material B

Group-C15

17. 4-NAP

Brief Manu

Take water Heat and mapress and mChemical R

Stage-IINPUT

Salicylic aciH2SO4 (98%ChlorineSO3IodineWaterIceTotal

Reaction maIce

Total

Stage-II

Quenched mXylene

Total

Reaction ma

Total

m Chemical R

Balance:

50 MT/Mont

ufacturing P

in reactor . aintain tempass of 4-NA

Reaction:

id %)

ass

mass

ass

Research Cent

th

Process:

Add sulfur perature. Mak

AP is collecte

KG

5502420900

17501

110050

6771

6771900

7671

6121

3500

9621

4380

4380

M/s. Sitam

tre Pvt. Ltd.

&NaSH in ke isolation

ed separately

Q

S

D

mani Organic

DNCB for rin water and

y.ML gose to

Reactor

Quenching

Layer eperation

Distillation

c Pvt. Ltd., P

reduction pud sulphuric ao ETP for tre

OU

Re

To

QuHC

To

ReH2Iod

To

ReXyProXybat

To

Phase-III GI

urpose and Cacid and salteatment.

UTPUT

eaction mass

otal

uenched masCl (30%)

otal

eaction mass2SO4 (90%)dine recovery

otal

ecovered Xylylene lossoductylene used fotch

otal

IDC Dahej, B

CaO and cat .Then mass

K

s

y

lene

or next

Bharuch

austiclye. s is filter

KG

6771

6771

61211550

7671

43805240

1

9621

300050

880

450

4380



Material Balance:

18.Halazone


In a reactor, a solution of Sodium hydrochloride is made. In that PCBS is added at a controlledrate and

temperature. After the addition is completed, the mass is allowed to cool. The solution is neutralized

with HCl for precipitation. The precipitates are filtered, dried & packed.

Chemical Reaction:

Material Balance:

In-put kg Out-put kgWater 520 4-NAP 500CaO 95 Effluent ETP 1670Sulfur 70Caustic lye 330NaSH 115DNCB 300Sulfuric acid 20Salt 720

TOTAL 2170 Total 2170

Isolation & Filtration

INPUT KG OUTPUT KGPCBS 1500Sodium Hypochlorate 1100 Reaction mass 4400HCl (30%) 1800


Reaction mass 4400 Halazone 1000Effluent for ETP 3200Evapration loss loss 200

Total 4400 total 4400

Reactor & Neutralization

Filteration & Drying

M M/s. Jyoti Om

19) Diethyl Brief Manu

Chemical R

m Chemical R

Meta Aminufacturing P

Reaction:

Research Cent

no Phenol Process:

M/s. Sitam

tre Pvt. Ltd.

mani Organic

c Pvt. Ltd., P

Phase-III GI

IDC Dahej, B

Bharuch



Material Balance:

20) Metanilic Acid


Stage-I In a reactor Oleum (25%) is taken and Nitrobenzene is charged in it at a controlled rate andtemperature. After that drawn the sulfo mass in water. Add lime slurry to neutralize the reactionmass. Filter the solution to remove gypsum. Stage-II In a reactor, a mixture of Iron & HCl (30%) is made. In that sulfo mass is slowly added. Filterthe ML & add H2SO4 (98%) to bring the pH 1.5. cool the reaction mass, filter, centrifuge & getthe final product.

INPUT KG OUTPUT KGMetanilic Acid 1100Ethyl Chloride 850 Reaction mass 3700Water 1000Sodium Hydroxide 750Total 3700 Total 3700

Reaction mass 3700 Reaction mass 1200ML to ETP 2500


Reaction mass 1200 Reaction mass 2825Potassium Hydroxide 625Water 1000Total 2825 Total 2825

Reaction mass 2825 Reaction mass 3425HCl 600Total 3425 Total 3425

Reaction mass 3425 Wet cake 1425ML to ETP 2000


Wet cake 1425 DEMAP 1000Loss 425


Reaction vessel

Filter Nutch

Reaction vessel

Neutralization

Filter Nutch

Drying



Chemical Reaction:



Material Balance:

21.Tobias acid


In a reactorB-naphthol is dissolved in EDC. In that CSA is charged at a controlled rate and

temperature .After that, the sulfomass is quenched in (Ice + water) . Now addcaustic lye so as to

neutralize the reactor mass. Separate the organic layer from EDC and take reactor mass . separate the

organic layer from EDC and take is to autoclave. In autoclave add liquor ammonia and the reaction is

carried out under specific pressure and temperature ,in presence of sodium bisulfite as catalyst .after the

reaction is complete the excess ammonia is recovered and the reaction mass is drowned in acidic

medium to precipitate the material .material is filtered ,dried and packed.


Nitro benzene 840 Reaction mass 6520Oleum (25%) 1680Water 2800

Calcium hydroxide 1200Total 6520 Total 6520

Stage-IIReaction mass 6520 ML 4120

Gypsum 2400


ML 4120 Reaction mass 5710HCl (30%) 300Iron powder 840Soda ash 450Total 5710 Total 5710

Reaction mass 5710 Ferric chloride sludge 2000ML 3710


ML 3710 Metanilic acid 1000

H2SO4 (98%) 700 Drying loss 200

Effluent to ETP 3210Total 4410 Total 4410

Reactor-1

Filtration

Reactor-2

Isolation & Filtration and

Drying

Filter press



Chemical Reaction:



Material Balance:

22.N-Methyl J Acid

Brief Manufacturing Process: J acid is reacted with 40% Sulphuric acid and SBS. Then reacted mass is filtered in filter press.Inorganic salt is removed out from the filter press. Clear liquid is isolated in isolator and addmethyl amine &calsolene oil. Then again filtered it and give carbon treatment to purify theproduct. ML goes to dryer for drying purpose and then blended it and get the final product.Effluent goes to ETO for treatment.

INPUT KG OUTPUT KGβ-Naphthol 800 Reaction mass 5475

CSA 1350HCl (30%) for reuse 675

EDC 3500Water 500


Water 1500 EDC recovered 3450

Ice750

EDC evaporation loss 50

Caustic lye 450 Reaction mass 4675Reaction mass 5475Total 8175 Total 8175

Reaction mass 4675

Liq. Ammonia 1925

Ammonia recovered & scrubbed 1550

Sodium bisulphite solution 1750 Reaction mass 5000

Extration water for reuse 1800


Reaction mass 5000Ammonium bisulphite solution 1050

HCl(30%) 675 Wet cake 1300Ammonia liq. 750 ML to ETP 4075


Wet cake 1300 Tobias acid 1200Drying loss 100


Reactor

Quenching

Amination

Drying

Isolation

M

M

rt

M/s. Jyoti Om

Chemical R

Material Ba

23.2,4Dichl

Brief Manu

In a reactor it. Reflux foin the M.L iremaining Mthe products

INPUT

J Acid

SBSMethyl Am

Total

Reaction m98% SulphuCalsolene oWaterTotal

Wet cake

Total

m Chemical R

Reaction:

alance:

oro Benzoic

ufacturing P

,taking fumior several hois filtered to ML, add mos.

KG

mine

3

ass 2uric acidoil

25

Research Cent

c acid & Ben

Process:

ing nitric acours. Separatget clear sol

ore soda ash

G

1120

12501450

3820

2820450

520005275

1800

1800

M/s. Sitam

tre Pvt. Ltd.

nzoic acid r

id and add trte the organlution. Add to get furthe

Reacto

Filter PreIsolatio

FiltrationDryin

mani Organic

recovery

rans isomer ic layer fromsoda ash to

er pH and iso

or

ess & on

n & g

c Pvt. Ltd., P

received from acid layerget desired polated 2,4- D

OUTPUT

Reaction mMethyl Amrecovered rnext batch

Total

Effluent to Wet cake

Total

N-Methyl JDrying loss

Total

Phase-III GI

om cis-Bromr. The organpH and isolaDichloro Ben

massmine reused in

ETP

J Acids

IDC Dahej, B

mo benzoate nic layer is qated benzoicnzoic acid .D

KG

2820

1000

3820

34751800

5275

1000800

1800

Bharuch

steam,in quenched c acid. In Dry both



Chemical Reaction

Material Balance:

24) 2,4Dichloro benzoic acid


In a reactor 2,4dichloro toluene and nitric acid is taken. The mixture is refluxed for several hours.

Quench the material in ice. Add soda ash to neutralize the ML and precipitate the material .Filter the

material ,dry and pack

Chemical Reaction:

Trans Isomer 760 Reaction mass 1160Nitric Acid (98%) 400


Reaction mass 1160 ML 2660Water 1500


ML 2660 Nitric acid (60%) for reuse 700Soda ash 50 Benzoic acid 260

2,4-Dichloro Benzoic acid 260Drying loss 240Effluent for ETP 1250


Reactor

Separation &Quenching

Filtration & Isolation

and Drying

M

M

M/s. Jyoti Om

Material Ba

Group-D-10

25.N-Pheny

Brief Manu

J acid is reInOrganic saand soda ashfor drying pu

Chemical R

m Chemical R

alance:

00 MT/Mon

yl J Acid

ufacturing P

eacted with alt is removeh. Then agaurpose and t

Reaction:

Research Cent

nth

Process:

40% sulphued out from in filtered itthen blended

M/s. Sitam

tre Pvt. Ltd.

uric acid anthe filter pre

t and give cad it and get th

mani Organic

nd SBS. Thess. Clear liqarbon treatmhe final prod

c Pvt. Ltd., P

en reacted quid is isola

ment to purifduct. Effluen

Phase-III GI

mass is filtated is isolatofy the produnt goes to ET

IDC Dahej, B

tered in filteor and addan

uct.ML goes TP for treatm

Bharuch

er press. niline oil to dryer

ment.

M

M

M/s. Jyoti Om

Material Ba

26.Peri Acid

Brief Manu

Chemical R

INPUTJ Acid40% Sulfuric aSBSSoda ashAniline oilcarbonwater

TOTAL

m Chemical R

alance:

d

ufacturing P

Reaction:

acid

Research Cent

Process:

KG720.01230.0650.070.0

280.020.0

4900.0

7870.0

M/s. Sitam

tre Pvt. Ltd.

0

0

0

Isola

mani Organic

ation & Filtrati

c Pvt. Ltd., P

OU

N-EfCa

TO

ion

Phase-III GI

UTPUT

-Phenyl J Acidffluent to ETParbon

OTAL

IDC Dahej, B

KG

342

78

Bharuch

06079020

870.0

M

M

F

M/s. Jyoti Om

Material Ba

27.Phenyl p

Brief Manu

Step:- 1Am

distillation u

Step:- 2 Iso

Filter, centri

Chemical R

Sulphuric acidNaphthalene

Total

Reaction massNitric AcidLime stoneMgOTotal

Reaction massIronHCl

Total

Reaction massSulphuric acidCold water

Total

m Chemical R

alance:

peri acid

ufacturing P

mination: Per

using Soda a

lation: Dum

ifuge, crushi

Reaction:

Input

Research Cent

Process:

ri acid is con

ash.

mp the mass i

ing and pack

kg446.00

584

1030

10302901825

1363

126798235

2284

1738220410

2368

M/s. Sitam

tre Pvt. Ltd.

ndensed with

nto water wi

king.

0S

C

mani Organic

h Aniline an

ith sulfuric a

Sulfonation

Nitration

entrifugation

Reduction

c Pvt. Ltd., P

nd excess an

acid and pro

Reactio

Total

ReactioEvaprat

Total

ReactioEvaporaFeCl3 sTotal

Effluenperic acCo-prod

Total

Phase-III GI

niline is dist

duct will com

Outputon mass

on masstion loss

on massation losssludge

nt to ETPcidduct Laurent acid

IDC Dahej, B

tilled out wit

me out on co

d

Bharuch

th steam

ooling.

kg1030

1030

126795

1363

1738135411

2284

1368640360

2368

M

M

Nt

w

M/s. Jyoti Om

Material Ba

28.Amido G

Brief Manu

Srep1: SulfNaphthol slotime. TempeStep 2 Isolawater. Salt iStep3 AmiandtemperatStep 4 Isolcrushing and

Chemical R

INAnilinePeri acidWaterSoda ashTotal

Reaction maswatersulfuric acidTotal

m Chemical R

alance:

G Acid

ufacturing P

fonation: Taowly so as toerature is be ation: this sus to be addeination: takture is to be lation: Dumd packing.

Reaction:

NPUT

s

Research Cent

Process:

ake Sulphuro maintain braised to 80

ulfonated mad to crystalli

ke ammoniaraised 125 0

mp the mass

kg325.0775.0200.0250.0

1550.0

1300.0550.0350.0

2200.0

M/s. Sitam

tre Pvt. Ltd.

ric acid intobelow 300 C00 C slowly aass is to be dize the produa is anothe0 C Maintains into water

IsoFi

Cen

AnD

mani Organic

o a reactor. AC . Start addin

and maintaindumped into uct on coolinr reactor a

n till the reacr product wi

olation and iltration & ntrifugation

imation and Distillation

c Pvt. Ltd., P

Add into it ng Oleum 23n for 12 houother vessel

ng. and add thection compleill come ou

AmRea

Tot

EvaEffPheTot

Phase-III GI

proportiona3% slowly o

urs. l into a meas

e sulfonatedetes. ut on coolin

OUTPUmmonia liquoraction mass

tal

aporationfluent to ETPenyl peri acidtal

IDC Dahej, B

ate quantity oovercertain p

sured quality

d product i

ng. Filter ce

UT

Bharuch

ofBETA period of

yof

into this

ntrifuge,

kg250.0

1300.0

1550.0

70.01130

1000.02200.0

M

M

M/s. Jyoti Om

Material Ba

29. K-acid

Brief Manu

Stage 1&2:INPUTSulfuric AcidB-Napthol 23% Oleum

TotalReaction massWater SaltTotal

Reaction massAmmoniaWater for AmmTotal

WaterReaction massTotal

Reaction mass

Total

m Chemical R

alance:

ufacturing P

monia scrubbing

Research Cent

Process:

KG360600630

15901590

375300

2265

2265300400

2965

37525652940

2940

2940

M/s. Sitam

tre Pvt. Ltd.

Cen

Su

I

A

I

mani Organic

ntrifugation

ulfonation

Isolation

Animation

Isolation

c Pvt. Ltd., P

OUTP

Reactio

TotalReactio

Total

Reactio

AmmoTotal

Reactio

Total

AmidoML to Total

Phase-III GI

PUT

on mass

on mass

on mass

onia liquor reuse

on mass

o G Acidreuse/CETP

IDC Dahej, B

and recover

Bharuch

KG

1590

15902265

2265

2565

4002965

2940

2940

100019402940

M

M

3

t

M/s. Jyoti Om

Chemical R

Material Ba

30. Schaeffe

Brief Manu

β- Naphthol

temperature

containing s

and then cen

Chemical R

m Chemical R

Reaction:

alance:

er's acid

ufacturing P

l is charged

for complet

soda ash to

ntrifuged and

Reaction:

Research Cent

Process:

d in sulfonat

tion of sulfo

precipitate o

d packed in H

M/s. Sitam

tre Pvt. Ltd.

tor having s

nation. The

out the final

HDPE bags

mani Organic

sulfuric acid

sulfonated m

l product. T

with PE line

c Pvt. Ltd., P

d. The sulfo

mass is drow

The product,

er.

Phase-III GI

onated mass

wned in wate

thus precip

IDC Dahej, B

s is heated t

er indrownin

pitated out is

Bharuch

tocertain

ng vessel

s filtered

M

M

3

p

M/s. Jyoti Om

Material Ba

31. L-Gluta

Brief Manu

In a Reactorprecipitate L

Chemical R

Stage 1&2:

INPUT98% Sulfuric AB-Napthol

Total

Reaction massWater Soda AshTotal

Reaction mass

Total

Wet cake

Total

m Chemical R

alance:

amic acid

ufacturing P

r, MonosodiL-Glutamic A

Reaction:

Acid

Research Cent

Process:

ium GlutamAcid. The Pr

KG670610

1280

1280732378

2390

2390

2390

1000

1000

M/s. Sitam

tre Pvt. Ltd.

mate is dissolroduct is filt

S

DNeu

FiCe

Crush

mani Organic

lved in wateered, dried &

ulfonation

Drowning, tralization & Cooling

iltration & entrifuging

hing & Packing

c Pvt. Ltd., P

er & filtered& packed.

OUT

React

Total

React

Total

Wet cML toTotal

Produ

Total

g

Phase-III GI

d. In that HC

PUT

tion mass

l

tion mass

l

cakeo CETPl

uct

l

IDC Dahej, B

Cl (30%) isa

KG

Bharuch

added to

G

1280

1280

2390

2390

100013902390

1000

1000



Material Balance:

32.CHLORAMINE T


In a reactor, PTS Amide is dissolved in a solution of caustic soda. In that chlorine gas is purgedat a

controlled rate and temperature. After that, the solution is filtered & dried.

Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KG

Monosodium Glutamate 75 Reaction mass 215HCl (30 %) 140Total 215 Total 215

To ETP 125Reaction mass 215 Wet cake 90Total 215 Total 215

Wet cake 90 Moisture removal 30L-Glutamic acid 60

Total 90 Total 90

Reactor (Room Temperature)

(Stirring-2 Hrs.)

Centrifuge

FBD (Dryer)

INPUT KG OUTPUT KGPTS Amide 620Caustic lye 600 Reaction mass 2980Chlorine 260Water 1500Total 2980 Total 2980

Reaction mass 2980 Product 1000Effluent for ETP 1980


Reactor




33.P-Toluene Sulfonamide


In a reactor, ammonia liquor is taken and PTSC is charged at controlled rate and temperature. After the

completion of addition and reaction , the material is filtered and dried.

Chemical Reaction:

Material Balance:

34) Ortho Toluene Sulfonamide

Brief Manufacturing Process: In a reactor, liquor ammonia is taken. OTS chloride is added at a controlled rate& temperature after completion the material is filtered & dried. Chemical Reaction:

INPUT KG OUTPUT KGPTS chloride 1120 Recovered Ammonia 180Ammonia Liquor (25%) 1120 Reaction mass 3965Caustic Soda 225HCl (30%) 680Water 1000Total 4145 Total 4145

Reaction mass 3965 Effluent to ETP 2940Product 1000Sludge to solid waste 25


Reactor

Filteration & Dryer



Material Balance:

35) Para Chloro Benzene Sulfonamide


In a reactor ,liquor ammonia is taken. PCBSC is charged at a controlled rate &temperature

Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KGOTS chloride 1120 Recovered Ammonia 180Ammonia Liquor (25%) 1120 Reaction mass 3965Caustic Soda 225HCl (30%) 680Water 1000Total 4145 Total 4145



Reactor

Filteration & Dryer

INPUT KG OUTPUT KGPara Chloro Benzene sulfonyl chloride

1120Recovered Ammonia 180

Ammonia Liquor (25%) 1120 Reaction mass 3965Caustic Soda 225HCl (30%) 680Water 1000Total 4145 Total 4145



Reactor

Filteration & Dryer



36.M-Nitro Para Chloro Benzene Sulfonamide


In a reactor , liquor ammonia is taken. Sulfonyl chloride is charged at a controlled rate and temperature. After addition ,the material is filtered and dried to get the sulfonamide. Chemical Reaction:

Material Balance:

37.SABC Acid


In a reactor, CSA is taken and Para chloro benzoic acid is charged under controlled rate and temperature .after addition, thesulfomassis quenched in ice and the intermediate is filtered the intermediate. the reactor at controlled rate and temperature after addition the product is filtered and dried.

INPUT KG OUTPUT KGMNPCBSC 1090 Recovered Ammonia 160Ammonia Liquor (25%) 1100 Reaction mass 3935Caustic Soda 225HCl (30%) 680Water 1000Total 4095 Total 4095

Reaction mass 3935 Effluent to ETP 2890MNPCBSA 1000Sludge to solid waste 45


Reactor

Filteration & Dryer



Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KGPara chloro benzoic acid/ortho chloro benzoic acid

820Sulfo mass 1870

CSA 1250 .HCl (30%) 670Water for HCl scrubbing 470


Sulfo mass 1870 Intermediates 1200Ice 1000 Dil.H2SO4 (30%) reused 1670


STAGE-II

Intermediates 1200 Recovered Ammonia 220liquor ammonia 25% 1200 Reaction mass 2880HCl (30%) 700


Reaction mass 2880 Effluent to ETP 1530para SABC Acid/Ortho SABC acid 1000Drying loss 350


Reactor-1

Reactor-2

Quenching & Filtration

Filtration & Drying



38. Sodium Naphthenonate


Stage-I

In a ball mill, take sulfuric acid and alpha-Naphthol amine and heat for several hours .after that take the

material down in cooling trays.

Stage-II

In a reaction mix the above material in water to get clear solution and filter the solution add some

HCl(30%) in it and add vacuum salt to make sodium naphtheonate filter the material. Dry and pack.

Chemical Reaction:



Material Balance:

39.Cis-Tosylate Brief Manufacturing Process: Stage-I In a reactor, taken water and dissolved Imidazole in it. Cis-bromo benzoate and heat upto reflux . reflux for surreal hours. Cool down and filter the solution add H2SO4(30%) to neutralize the solution .filter and dry the material we get Cis –Imidazde alcohol. In the filtered ML ,add further H2SO4 (30%) to turn pH acidic filter and dry the material ,we get benzoic acid. Stage-II In a reactor dissolve p-Toluene sulfonyl chloride in methanol add cis – Inidazol alcohol in it, in pressure of sodium carbonate . after the reaction is completed, filter the solution to get cis-Tosylatedand from the ML methanol will be recovered by distillation .Dry the product and pack. Chemical Reaction: Stage-I

Stage-I

INPUT KG OUTPUT KG

α-Naphthylamine 650

Sulphuric acid (98%)

450 Naphthionic acid 1100


Stage-IINaphthionic acid 1100 Reaction mass 3100Water 2000


Reaction mass 3100 Sodium Naphtheonate 1250HCl (30%) 200 Effluent to ETP 2400Vacuum salt 350Total 3650 Total 3650

Ball Mill

Reactor

Filteration



Stage-II

Material Balance:


Imidazole 155 Reaction mass 1600Cis Bromo Benzoate 1000Water 445


Dil. H2SO4 30% 1535 Benzoic acid 270Reaction mass 1600 HBr 30% 600

Effluent to ETP 1430Wet cake 835


Wet cake 835Cis Imidazole alcohol 665Drying loss 170

Total 835 Total 835

Stage-II

Cis Imidazole alcohol 665 Reaction mass 3150Para Toluene sulfonyl chloride 385Methanol 2000Sodium carbonate 100


Reactor

Neutralization & Filtration

Dryer

Reactor



40.Benzyl Bromide

Brief Manufacturing Process: In a reactor Benzyl alcohol is taken and HBr (48%) is charged in it at controlled rat & temperature. After that Organic layer is separated and distilled to get pure Benzyl bromide.

Chemical Reaction:

Material Balance:

Reaction mass 3150 Recovered Methanol 1900Wash water 500 Solvent loss 100

Effluent to ETP 450Wet cake 1200


Wet cake 1200 Cis-Tosylate 1000Drying loss 200


Dryer

Distillation

INPUT KG OUTPUT KGBenzyl Alcohol 640HBr (48%) 1200 Dil. HBr for reuse 800

Reaction mass 1040


Reaction mass 1040 Benzyl Bromide 1000

Soda ash 50Water 200 Effluent for ETP 290Total 1290 Total 1290

Reactor

Distillation

M

vvvv

M

M/s. Jyoti Om

Group-E-3041.Sulpho TBrief Manui. Charge suii. Add slowiii. Maintainiv. After 12 v. Charge wvi. Add salt vii. When teviii. After wix. Pack the Chemical R

Material Ba

INTobias acid98% sulfuric acid 23% oleumIceSalt

T

m Chemical R

00 MT/MonTobias Acidufacturing Pulphuric acid wly oleum to n the temperahrs reaction

whole mass toto it.

emperature bwater is drain

material. Reaction:

alance:

NPUT

TOTAL

Research Cent

nth d Process:

and Tobias it. Maintain

ature for 12 n is completeo drawing ve

become 20° -ned from nut

kg1000400260050001000

10000

M/s. Sitam

tre Pvt. Ltd.

acid to sulfon the temperahrs.

ed. essel.

-25 °C. Transche take ma

Reactor & C

mani Organic

onator. ature while a

nsfer the whoass for centr

Centrifugation

c Pvt. Ltd., P

adding oleum

ole mass to nrifuging.

Sulpho tobiasdil. Sulphuric

Phase-III GI

m.

nutsche.

OUTPUTs acidc acid for reuse

TOTAL

IDC Dahej, B

kg165835

100

Bharuch

g5050

000

M

pr

M

M/s. Jyoti Om

42. 2-chloroBrief ManuIn a dry GLplaced of Threaction is vcooled massafter all the Chemical R

Material Ba

43. R-Salt

Brief Manu

Chemical R

INPUTMonoethalamithionyl chloridNaOHEDC

Total

m Chemical R

oethylamineufacturing PL fitted with

hionyl chlorvery exothes over a peridiethaonlam

Reaction:

alance:

ufacturing P

Reaction:

ine de

Research Cent

e hydrochloProcess: a sealed me

ride and ethyrmic .Monoiod of an hou

mine has been

Process:

KG1022

230

64

M/s. Sitam

tre Pvt. Ltd.

ride

echanicals stylene dichlo

oethanol amur, during wn added, the

00202500

45

mani Organic

tirrer, an effioride. Throumine is addewhich time th

cooling is st

Reacto

c Pvt. Ltd., P

ficient refluxughout ,theened through there is a coptop and the r

r

Phase-III GI

x condenser ntire period the flask anpious evolutireaction mix

OUTPUTfinishe proEDC recoEDC lossNaSO4 byHCl

Total

IDC Dahej, B

,andadditionof operation

nd slow addiion of sulfurxture.

T Koduct

overy

y product

Bharuch

n flask is n ,as the ition the r dioxide

KG1602752540

145

645

M

M

M/s. Jyoti Om

Material Ba

44. Aniline Brief Manu

Chemical R

InM.L From G-saAniline oil makWaterTotal

Reaction mass

To

filtrate massCaustic lyeWaterTotal

AnilineSalt

Total

m Chemical R

alance:

2,4 Di sulfoufacturing P

Reaction:

nputaltke up

otal

Research Cent

onic acid Process:

Quantity (kg2500301502680

2680

2680

184362

1002005

2005275

2280

M/s. Sitam

tre Pvt. Ltd.

g)

Comp

NutcC

NutcC

mani Organic

plex formation

ch Filration & entrifuging

ch Filtration & entrifuging

Distilled

c Pvt. Ltd., P

React

Total

Efflue

Filtrat

n

Anilin

Total

Dil H2AnilinR-saltTotal

Phase-III GI

Outpution mass

ent to ETP

te massTotal

ne

2SO4 reuse ne oil for recovet

IDC Dahej, B

Quant26

26

8

1826

20

20

20ery 2

222

Bharuch

tity (kg)680

680

837

843680

005

005

05525200280

M

M

M

M/s. Jyoti Om

Material Ba

45. Aniline Brief Manu

Chemical R

Material Ba

ISulfanilic acidOleum

Total

Reaction massWaterTotal

sulfo mass

Total

INPMeatanilic acid25% Oleum

Total

Reaction massSalt WaterTotal

Reaction mass

Total

m Chemical R

alance:

2,5 Di Sulfoufacturing P

Reaction:

alance:

INPUTd

s

PUTd

Research Cent

onic acid Process:

kg583440

1023

10215002523

2523

252

KG658

460.2

1118

111820

15002638

2638

2638

M/s. Sitam

tre Pvt. Ltd.

23

23

Su

I

FilCen

Sulfo

Iso

FiltrCentr

mani Organic

ulfonation

Isolation

ltration & ntrifugation

onation

olation

ration & rifugation

c Pvt. Ltd., P

Reaction

Total

sulfo mas

Total

Dil H2SOAniline 2Total

Reactio

Total

Reactio

Total

Dil. H2Anilin

Total

Phase-III GI

OUTPUTmass

ss

O4 for reuse2,4 Di Sulfonic

OUTPUTon mass

on mass

2SO4 for reusee 2,5 Di Sulfon

IDC Dahej, B

Acid

T

nic Acid

Bharuch

kg1023

1023

2523

2523

152310002523

KG1118

1118.24

2638

2638

16381000

2638

M

t

M

M/s. Jyoti Om

46.Sulfalini

Brief Manu

In a ball-milthe mixture

Chemical R

Material Ba

47.Para Tol

Brief Manu

In a reactor,allowed to c

Chemical R

INPUTAniline oilSulphuric a

Total

m Chemical R

ic acid

ufacturing P

ll, aniline &is allowed to

Reaction:

alance:

luene Sulfon

ufacturing P

, Urea is takcool & crysta

Reaction:

cid (98%)

Research Cent

Process:

sulfuric acio cool to for

nyl Urea

Process:

en and heateallize.

KG5457

111

M/s. Sitam

tre Pvt. Ltd.

d is taken. Trm sulfanilic

ed to melt. In

G00

10

mani Organic

The mixture acid powde

n that PTSC

Sulfon

c Pvt. Ltd., P

is heated to er.

C is charged

nation

Phase-III GI

a higher tem

slowly. Afte

OUTPU

SulphanWater Evapora

Total

IDC Dahej, B

mperature A

er that,the m

UT

nilic acid

ation loss

Bharuch

fter that,

mixture is

KG

1000

1101110



Material Balance:

48.Para Chloro Benzene Sulfonyl Urea

Brief Manufacturing Process: In a reactor, Urea is taken and heated to melt. In that PCBS Chloride is added veryslowly. After that, the mixture is allowed to cool & crystallize.

Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KGPTS Amide 800

Urea 280Ammonia Liq.to Scrubber 480

Soda ash 500 PTS Urea 1300Water for ammonia scrubbing 400 CO2 to scrubber 200Total 1980 Total 1980

Reactor

INPUT KG OUTPUT KGPCBS Amide 800

Urea 280Ammonia Liq.to Scrubber 480

Soda ash 500 PCBS Urea 1300Water for ammonia scrubbing 400 CO2 to scrubber 200Total 1980 Total 1980

Reactor



49.Tetralone


In a reactor a mixture of α-Naphthol, ODCB and Aluminum chloride is refluxed for severalhours. After that, the reaction mixture is quenched & ice and the organic layer is separated. Theexcess ODCB is distilled out and the material is allowed to cool and crystallize to form the product.

Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KGα-Naphthol 700ODCB 1420 Reaction mass 2920Aluminium Chloride 800


Ice 3000 Reaction mass 5920Reaction mass 2920Total 5920 Total 5920

Reaction mass 5920 Recovered ODCB 700AlCl3 solution 3800

Reaction mass 1420Total 5920 Total 5920

Reaction mass 1420 Product 1000ETP sludge 420


Quenching

Distillation

Crystallization

Reactor



50. P-Nitro Benzyl Bromide


In a reactor, Para Nitro Toluene is dissolved in methanol. In that Bromine is charged under UVlight. After completion, the solution is filtered and chilled to form crystals. The crystals are driedto get para nitro benzyl bromide.

Chemical Reaction:

Material Balance:

51.T-Butyl Chloride


In a reactor Tert-Butyl Alcohol is taken. Under stirring and chilling HCl gas from other productstreams, is purged in the Alcohol to for Tert-Butyl chloride and distilled to purify.

INPUT KG OUTPUT KGPara Nitro Toluene 640Bromine 740 Reaction mass 3100

Methanol 2000

HBr solution (48%) reuse in benzyl bromide 1080

Dil. HBr solution from Benzyl bromide 800Total 4180 Total 4180

Reaction mass 3100 Recovered Methanol 1800Methanol Evaporation loss 200Wet Cake 1100


Wet Cake 1100 PNBBr 1000Drying loss 100


Reactor

Distillation




Chemical Reaction:

Material Balance:

52.Para Toluene Sulfonic Acid


In a reactor toluene and sulfuric acid is taken. The mixture is refluxed for specific time and thenallowed to cool to from PTS acid crystals. Chemical Reaction:

INPUT KG OUTPUT KGTert-Butyl alcohol 800HCl (gas) 395

Tert-Butyl chloride 1195


Reactor



Material Balance:

53.Benzene Sulphonic acid


In a reactor benzene and sulfuric acid is taken. The mixture is heated to reflux fora specific time. After completion, the mixture is allowed to cool to for BSA crystals.

Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KGToluene 600Sulfuric Acid (98%) 580 Reaction mass 1180


Reaction mass 1180 Recovered Toluene 65PTS Acid 1000Evaporation water loss 115


Reactor

Distillation

INPUT KG OUTPUT KGBenzene 440 Product 1000Sulfuric Acid (98%) 560


Reactor



54. p-Xylene Sulphonic acid


In a reactor p-Xylene & sulfuric acid is taken. The mixture is heated to reflux for a specific time. The mixture is heated to reflux for a specific time. The mixture is allowed to coolto from the crystal.

Chemical Reaction:

Material Balance:

55.M-Xylene Sulfonic acid Brief Manufacturing Process: In a reactor, M-Xylene and sulfuric acid is taken. The mixture is heated to reflux for a specific time. The mixture is allowed to cool to from the crystal.

INPUT KG OUTPUT KGP-Xylene 520 P-Xylene Sulfonic Acid 1000Sulfuric Acid (98%) 480


Reactor

H2SO4

Sulfuric acidM.W:98

RefluxH2O

WaterM.W:18

CH3

P-Xylene sulfonic acid

SO3H

CH3

P-Xylene sulfonic acidM.W: 186

CH3

CH3

MW: 106

P-Xylene



Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KGM-Xylene 520 M-Xylene Sulfonic Acid 1000Sulfuric Acid (98%) 480


Reactor

H2SO4

Sulfuric acidM.W:98

RefluxH2O

WaterM.W:18

CH3

M-Xylene sulfonic acid

SO3H

CH3

P-Xylene sulfonic acidM.W: 186

CH3

MW: 106

M-Xylene

CH3



56.Cumene Sulfonic acid Brief Manufacturing Process: In reactor, sulfuric acid and Cumene is taken. The mixture is heated to reflux for a specific time. After that the mixture is allowed to cool to from crystals.

Chemical Reaction:

Material Balance:

57. Sulfanilamide Brief Manufacturing Process: Route-I In an autoclave ,PCBSC and ammonia liquor are taken and are heated under highpressure . after completion ,the material is filtered and dried. Route-II Sufanillic acid is first treated with Thionyl chloride in pressure of solvent and temperature after addition, the desired product is filtered and dried.

INPUT KG OUTPUT KGCumene 600 Cumene Sulfonic Acid 1000Sulfuric Acid (98%) 500 Evaporation water loss 100


Reactor



Chemical Reaction:

Material Balance:

Route-IINPUT KG OUTPUT KGPCBSC 1750 Reaction mass 4250Ammonia Liquor (25%) 2500Total 4250 Total 4250

Reaction mass 4250 Ammonia liq. Recovered 1500Caustic soda 800 Reaction mass 5050Water 1500Total 6550 Total 6550

Reaction mass 5050 Reaction mass 6550HCl 30% 1500Total 6550 Total 6550

Reaction mass 6550 Effluent to ETP 5000Product 1200Drying loss 350


Filteration & Dryer

Amination

Ammonia Recovery

Isolation



58.Para Chloro Benzene Sulfonyl Chloride

Brief Manufacturing Process: In a reactor, CSA is taken & MCB is added at a controlled rate & temperature. After completion,the sulfo mass is quenched in ice & the PCBSC is filtered. PCBSC is either recrystallized to forpure PCBSC or processed further to PCBS Amide or Sulfanilamide.

Chemical Reaction:

Material Balance:

(Route-2)INPUT KG OUTPUT KGSulfanilic acid 1200 Reaction mass 3275Thionyl chloride 825 HCl for reuse 950

Solvent 2000Ammonum sulfite solution for reuse in other product 1650

Ammonia liq.for SO2 scrubbing 1200Water for HCl scrubbing 650Total 5875 Total 5875

Reactor

INPUT KG OUTPUT KGMCB 535 Sulfo mass 1485CSA 1120 HCl (30%) 770

Water 600


Sulfo mass 1485Ice 1000 PCBSC 1000

Dil. H2SO4 reused 1485


Reactor




59. Benzene Sulfonyl chloride Brief Manufacturing Process: In a reactor CSA is taken and benzene is added and temperature. After addition,the sulphomass is quenched in ice and inorganic layer is separated and distilled to get BSC.

Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KGBenzene 450CSA 1350 Sulfo mass 1590

HCl (30%) 710Water 500


Sulfo mass 1590 Reaction mass 1040

Ice 2000

Dil.H2SO4 (15-20%) reused 2550


Reaction mass 1040Solid waste 40

BSC 1000Total 1040 Total 1040

Reactor

Distillation

Quenching



60.M-Nitro, P-chloro Benzene Sulfonyl chloride

Brief Manufacturing Process: In a reactor ,CSA is taken and ONCB is charged at a controlled rate andtemperature after addition, the sulphomass is quenched in ice and material is filtered to get thesulfonyl chloride.

Chemical Reaction:

Material Balance:

61. α-Naphthol Brief Manufacturing Process: In a reactor, take water and add α-Naphthyl amine and reflux for several hours. Distilled of pureproduct and residue for ETP/solid waste.

Chemical Reaction:

INPUT KG OUTPUT KGONCB 620CSA 1000 Sulfo mass 1450

Dil. HCl (30%) 570Water 400


Sulfo mass 1450Ice 1000

Dil. H2SO4 (15-20%) 1450Product 1000


Reactor

Quenching & Filteration



Material Balance:

62.Meta Chloro Aniline Brief Manufacturing Process: In a reactor, a mixture of Iron and HCl (30%) is made. In that MNCB is charged slowly. Afterthat add soda ash to neutralize, filter and removed iron sludge. Distill the ML to get pure MCA. Chemical Reaction:

Material Balance:

INPUT KG OUTPUT KGα-Naphthylamine 1200Water 600 Reaction mass 1680Water for Ammonia scrubbing 450 Recovered Ammonia 25% 570


Reaction mass 1680 Product 1000

Solid waste 130Distilled water for reuse 550


Reactor

Distillation

INPUT KG OUTPUT KG

Meta nitro chlorobenzene

1400

Iron powder 1400 Reaction mass 3600HCl (30%) 800


Reaction mass 3600 Reaction mass 3900Soda ash 300Total 3900 Total 3900

Reaction mass 3900

Ferric chloride sludge+ sludge drying loss 2900

Product 1000Total 3900 Total 3900

Reactor

Neutralization

Distillation



63. α-Napthyl Amine Brief Manufacturing Process: Stage-I In a reactor, a mixture of Nitric acid & Sulphuric acid is made. In that, Naphthalene is charged ata controlled rate & temperature. After that the nitro mass is quenched in ice, filter the material. Stage-II In a reactor, a mixture of Iron powder & HCl (30%) is made. Add the above product from stage-Iin this mixture slowly. Add soda ash to make the mixture alkaline. Now filter the ML to removethe iron sludge. Distill the ML and crystalline to get pure α- NapthylAmine .

Chemical Reaction:

Material Balance:


Naphthalene 1100

Nitric acid (98%) 550 Reaction mass 2760

Sulphuric acid 1110


Reaction mass 2760 1-Nitro Napththalone 1450

Ice 600(H2SO4+HNO3)40% for reuse 1910


Reactor

Quenching & Filteration

Stage-II1-Nitro Napththalone 1450 Reaction mass 3525HCl (30%) 500Iron 1500Soda ash 75Total 3525 Total 3525

Reaction mass 3525 α-Napthyl Amine 1000

Ferric Chloride sludge 2525Total 3525 Total 3525

Reactor

Distillation & Filtration

M

Dm

M

A

M/s. Jyoti Om

64.Methyl s

Brief ManuDimethyl sumethlsulfon

Chemical R

Material Ba

65.Phenyl ABrief ManuIn a closed Ammonia is

Chemical R

INPUT

Dimethyl su

Hydrogen P(50%)Toluene

Total

m Chemical R

sulfonyl met

ufacturing Pulfoxide is reylmethane.

Reaction:

alance:

Alpha Naphufacturing Preactor Ani

s reacted in w

Reaction:

ulfoxide

Peroxide

Research Cent

thane

Process: eacted with

hthylamine Process: line & α-Nawater at liqu

KG

180

160

150

490

M/s. Sitam

tre Pvt. Ltd.

hydrogen pe

aphthylaminor Ammonia

Rea

mani Organic

eroxide in pr

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actor

c Pvt. Ltd., P

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The mixturethe product

OUT

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distilreuseSolvOrgaProd

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vent Recover

ll water for ed

vent lossanic Residueduct

al

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d for severalcrystallize.

KG

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490

Bharuch

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M

M

M

M/s. Jyoti Om

Material Ba

66.N,N BIS

Brief Manu

Chemical R

Material Ba

INPUT

α-NaphthyAmineAnilineWater

Total

Reaction m

Total

INPUT

DiethanolaThionyl chNaOHEDC

Total

Reaction m

Total

m Chemical R

alance:

(2-CHLOR

ufacturing P

Reaction:

alance:

KG

yl

mass

amine hloride

mass

Research Cent

ROETHYL

Process:

G

725465300

1490

1160

1160

KG

10022025

300

645

645

645

M/s. Sitam

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AMINE HY

R

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Glass LinedReactor

Distillation Filtration

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LORIDE)

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RA

T

PN

ET

n

d

&

Phase-III GI

OUTPUT

Reaction mAmmonia

Total

Phenyl AlpNaphthylam

ETP wasteTotal

OUTPUT

Reaction m

Total

EDC RecoEDC lossNa2SO3HCl 25%ProductTotal

IDC Dahej, B

KG

massLiquor

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T

mass

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1160330

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1601160

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645

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145160645



67.Para Toluene Sulfonyl Chloride Brief Manufacturing Process: Route-I Toluene is charged in a mixture of CSA + TC + Solvent at controlled rate & temperature. Aftercompletion, the sulfo mass is distilled under high vacuum & crystallized to get PTS chloride. Route-II In a reactor, CSA is taken & catalyst is added to it. After cooling toluene is added at controlledrate & temperature. After completion, the sulfo mass is quenched in ice & the product is filtered.OTSC is separated out from PTSC by centrifuge. PTSC is recrystallized to get final product.OTSC is sent for further process to from OTS Amide. Route-III In a reactor, CSA is taken & chilled under controlled rate & temperature, toluene is added. Sulfomass is quenched in ice & organic layer is separated from sulphuric acid. The organic layer isagain chilled to separate out PTSC & solid PTSC is centrifuged. OTSC is sent for furtherprocessing to OTS amide & PTSC is recrystalized

Chemical Reaction:

Material Balance:

Route-IINPUT KG OUTPUT KGCSA 728 Dil.HCl (30%) 1518TC 750 Reaction mass 3180

Solvent 2000Ammonium Sulphite solution 2080

Water for HCl scrubbing 1875Ammonia 25% for SO2 scrubbing 850Toluene 575Total 6778 Total 6778

Reaction mass 3180 PTS chloride 1100Recovered solvent 1425Solvent evaporation loss 100Solvent for recycle 555


Reactor

Distillation



68.Saccharine from OTS amide

Brief Manufacturing Process: In a reactor, solution of OTS amide and caustic potash lye is prepared .In it potassium permanganate solution is added under vigorous stringing .After completion the reaction mass is filtered and the filtered solution is taken in another reactor. In it, pure HCl (30%) is added to precipitate the material. The material is filtered, dried, pulverized and packed.

Chemical Reaction:

Material Balance:

Route-II toluenesulfonylchloride mix

INPUT KG OUTPUT KG

Toluene736

Dil.HCl (30%) for reuse

2150

CSA 3000 Reaction mass 1440

Ice 3000

Dil. H2SO4 (26-28%)

for reuse 3646Water 500


Reaction mass 1440 PTSC 440OTSC 1000


Reactor

Centrifuge



69. Para carboxy benzene Sulfonamide Brief Manufacturing Process: In a reactor, PTS Amide is dissolved in caustic soda solution in it. Potassium Permanganatesolution is charged at a controlled rate & temperature. After that the solution is cooled and in itHCl (30%) is added at a controlled rate & temperature to precipitate the material. The material isfiltered, centrifuged, dried & packed.

Chemical Reaction:

INPUT KG OUTPUT KG

O-Toluene Sulfonamide 950

Potassium Permanganate (50%)


Caustic potash lye (50%) 1000Water 1500


Reaction mass 7050MnO2 sludge (used in next batch) MnO2-1000+ water-1030 2030

ML 5020Total 7050 Total 7050

ML 5020KCl solution (KCl-850+water-6220) 6170

HCl (30%) 2400 Wet cake 1250Total 7420 Total 7420

Wet cake 1250 Product 1000Drying loss 250


Reaction vessel

Filtration

Isolation

Drying



Material Balance:

70.Lasamide Brief Manufacturing Process: Stage: I In a reactor ,2,4 Dichloro toluene and nitric acid are refluxed .under pressure for several hours .after that down in water and bring pH 6.5 by soda ash .filter the material and dry ,we get 2,4-Dichloro benzoic acid. Stage-II: In a reactor C.S.A is taken and 2,4 –DCBA is charged in it at controlled Rate and temperature after that , the sulfa mass in ICE. Filter the material ,we get lasyl chloride.

INPUT KG OUTPUT KG

P-Toluene Sulfonamide 950

Potassium Permanganate (50%)


Caustic potash lye (50%) 1000Water 1500


Reaction mass 7050in next batch) (MnO2-1000 + water-1030) 2030

ML 5020Total 7050 Total 7050

ML 5020KCl solution (KCl-850 + water-6220) 6170

HCl (30%) 2400 Wet cake 1250Total 7420 Total 7420

Wet cake 1250 P-Chloro Benzene 1000Drying loss 250


Reaction vessel

Filtration

Drying

Isolation



Chemical Reaction:

Material Balance:

Stage-I2,4 Dichloro benzoic acid

1200Sulfo mass 3600

CSA 3000 HCl 30% 2600Water 2000


Sulfo mass 3600 Dil.H2SO4 (30%) 4100Ice 2000

Lasyl chloride w/c 1500


Stage-IILasyl chloride w/c 1500 Reaction mass 5100EDC 3600


Reactor


Reactor



71.5-chloro Aniline-2,4-Disulphonamide Brief Manufacturing Process: In a reactor, Meta chloro aniline is charged in Chloro Sulfonic Acid. After completion, the sulfomass is quenched in Ice & filtered to get Chloro Compound. Chloro Compound is dissolved in MIBK & filtered. In it, Ammonia Gas is purged to get DSA compound. The solution is filtered to get DSA compound and MIBK is reused in next batch. DSA is further purified by dissolving it in Acetone. The Solvent solution is filtered and Solvent is distilled to recover the product. The product is dried, pulverized & packed.

Chemical Reaction:

Reaction mass 5100 EDC recovered 3550Ammonia gas 250 EDC loss 50

Lasamide crude 1750Total 5350 Total 5350

Stage-IIILasamide crude 1750 Reaction mass 5750Methanol 4000


Reactor

Separation & Filtration

Reaction mass 5750 Methanol recovered 3500Methanol loss 100Mixture of Methanol and product used in next batch 650Lasamide 1500


Distillation



Material Balance:

72.2-Chloroethanol

Brief Manufacturing Process: Take HCl (30%) in a reactor and chill. Pass ethylene oxide gas in it under chilling .After completion, filter the material and pack.

INPUT KG OUTPUT KG

Meta chloro aniline 500 Sulfo mass 2600Chloro sulphonic acid 2650 HCl 30% 1850water 1300Total 4450 Total 4450

Sulfo mass 26005-Chloro aniline 2,4-disulphonyl chloride 1200

Ice 3000 Dil. H2SO4 reuse 4400


INPUT KG OUTPUT KG

5-Chloro aniline 2,4-disulphonyl chloride 1200 Reaction mass 4880MIBK (Recycled+Fresh) 3220Ammonia gas 460


Reaction mass 4880 Recovered MIBK 3060loss MIBK 160Crude wet cake 1660


Stage-IIIINPUT KG OUTPUT KG

Crude wet cake 1660 Product 1000Acetone 3000 Acetone recovered 2500

ML to be recycled 860Drying loss 300


Sulphonation


Reactor

Filtration

Purification



Material Balance

Chemical Reaction

Inorganic Product:

1) POTASSIUM CHLORIDE

Brief Manufacturing Process: Potassium chloride solution received is taken to concentration vessel, where it is heated to distil out water .the material is cooled to from the crystals.

Chemical Reaction:

KCl (20%)SolutionKCl + H2O

Material Balance:

2) MAGNESIUM SULPHATE

Brief Manufacturing Process: In Dilute sulphuric acid ,charge magnesite are with vigorous stirring after that filter the solution through filter press and allow to cool to get crystals.

INPUT KG OUTPUT KG

Hydrochloric acid(30%)

1202-Chloroethanoal 164

Ethylene oxide 44

Total 164 Total 164

INPUT KG OUTPUT KG

KCl solution 2000 KCl 400

Distilled water 1600Total 2000 Total 2000

Distillation

M

3

R

b

M/s. Jyoti Om

Chemical R

MgO + H2S

Material Ba

3)PLASTER

Brief ManuRoasting the

Chemical R

Gypsum

Material Ba

4)Sodium B

Brief ManuIn there is abromide sol

INPUT

Dil. H2SO4%

Magnesite OTotal

Filtered ma

Total

m Chemical R

Reaction:

SO4.H2O

alance:

R OF PARI

ufacturing Pe Gypsum to

Reaction:

Ros

alance :

Bromide

ufacturing Pany excess Hlution . The

KG

4 40 50

Ore 1262

ass 52

52

Research Cent

M

IS

Process: o get Plaster

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Process: Hbr in the pr

solution is c

000

200200

200

200

C

M/s. Sitam

tre Pvt. Ltd.

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P + water e

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Crystallizati

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M

T

GEMS

T

n

ion

c Pvt. Ltd., P

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ll be treated dium bromide

OUTPUT

Filtered mass

ML for reuse

Total

Gypsum sludEvaporation Magnesium Sulphate

Total

Phase-III GI

with caustice powder.

KG

s 5

e 16

dgeloss

4

5

IDC Dahej, B

c soda to get

200

0006200

300100

4800

5200

Bharuch

t sodium



Chemical Reaction:

NaOH + HBr NaBr + H2O

Material Balance :

5)Ammonium Chloride

Brief Manufacturing Process: From sulfonamide production, after solvent recovery, the residue is heated up .ammonia chloride get sublimates and controlled, the remaining residue is sent as solid waste.

Chemical Reaction:

Solvent residue NH4Cl + Solid waste

Material Balance:

6)Potassium Permanganate from MnO2 Sludge

Brief Manufacturing Process: In rotary kiln, MnO2 Sludge and caustic potash is taken rotated for several hours .In another reactor water is taken and potassium manganesefrom stage-I is dissolved in it and chloride gas is purged in to the ML. After the ML is filtered and clear solution is concentrated to a creation level and cooled . the

INPUT KG OUTPUT KG

HBr 20% 2000 NaBr solution 2200

Caustic soda 200Total 2200 Total 2200

NaBr solution 2200 NaBr Powder 600ML to reuse 200Distilled water 1400


Reactor

Purification

INPUT KG OUTPUT KG

Solvent Residue 1000

Ammonium chloride 800

Residue 200Total 1000 Total 1000

Heating



crystals of potassium chloride forms which are filtered out . the remaining ML is again concentrated so as to from 50 % potassium permanganate solution which is used in further process. Chemical Reaction:

Stage-I

2MnO2 +4KOH +O2 Heat 2K2MnO4 + 2H2O

Stage-II

2 K2MnO4 + Cl2 2KMnO4 + 2 KCl

Material Balance:

MnO2 sludge 500Potassium Manganate 1125

Caustic potash 625Total 1125 Total 1125

Potassium Manganate 1125 Reaction mass 4125Water 3000


Reaction mass 4125

Potassium Permanganate 50% solution 1600

Chlorine 180 Potassium chloride 425Distilled water 2280


Purging & Filtration

Rotary klin

Reactor



ANNEXURE-VII

DETAILS OF WATER CONSUMPTION AND WASTE WATER GENERATION DETAILS OF WATER CONSUMPTION Sr. No. Section Total in KL/day 1. Domestic 6 2. Industrial Process 41 Washing 2 Boiler 4 Cooling 3 Gardening 0 Total

(Industrial) 50

Total(Industrial + Domestic)

56

DETAILS OF WASTE WATER GENERATION Sr. No. Section Total in KL/day 1. Domestic 4* 2. Industrial Process 46 Washing 2 Boiler 1 Cooling 1 Gardening 0 Total (Industrial) 50 Total(Industrial +

Domestic) 50

* Will be treated in STP and used for gardening purpose.



WATER BALANCE DIAGRAM

GARDENING

C.E.T.P/G.I.D.C Drainage

G.I.D.C (56 KL/day)

PROCESS 41 KL/day

COOLING 3KL/day

BOILER 4 KL/day

DOMESTIC 6 KL/day

BLOW DOWN 1 KL/day

BLOW DOWN 1 KL/day

E.T.P 50 KL/day

STP 4 KL/day

TO ETP 46 KL/day

WASHING 2 KL/day

M

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EFFLUENT

Sr. No.

Para

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m Chemical R

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Research Cent

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ANNEXURE-IX

DETAILS OF HAZARDOUS WASTE GENERATION & DISPOSAL Sr. No.

Type of Waste

Category Hazardous waste generation Quantity

Method of Disposal

1 ETP waste 35.3 25 MT/Month Collection, Storage, Transportation, disposal at TSDFsite.

2. Used/Spent Oil 5.1 0.5 MT/M Collection, Storage, transportation, Reuse

3. Distillation Residue 28.1 11 MT/Month Collection, Storage, Transportation, disposal at Co-Processing or Incineration Facilitysite.

4. Discarded Bags & Liners / Empty Drums containers

33.3

5000 NOS/M Collection, Storage, transportation, Reuse for captiveuse.

5. Spent Carbon 28.2 2 MT/Month Collection, storage, transportation&DisposalatCo-Processing or Incineration Facility



ANNEXURE-X

ELECTRICITY & FUEL CONSUMPTION

Sr. No.

Particulars Remarks

FUEL 1. Type of Fuel Bio Coal 2. Consumption rate 8 T/Day 3. Source of supply local purchase ENERGY 1. Type of Energy Electricity 2. Connected Load 450 HP 3. Source of supply DGVCL/Torrent



ANNEXURE-XI DETAILS OF STACK AND VENTS FUEL GAS EMISSION Sr.No

Stack Attached To

Stack Height (M)

Type of Fuel

Fuel Consumption

Type of Emission

Permissible Limit

1. Boiler (2TPH)

20 Bio Coal

5 T/day

PM SO2

NOx

150 mg/NM3

100 PPM 50 PPM

2. Thermo Pack (3 Nos.) (2 Lack cal each)

20 3 T/day PM SO2

NOx

150 mg/NM3

100 PPM 50 PPM

3. D.G set (one)250KVA

11 Diesel 150 Lit/Hr SPM SO2

NOx

150 mg/NM3

100 PPM 50 PPM

PROCESS EMISSION

Sr.No. Stack attached to

Stack Height (M)

APCM Probable Pollutant Emission

Permissible Limits

1. Reactor 11 Water Scrubber followed by Alkali Scrubber

HCl NOx

NO2

HBr

20 mg/Nm3

25 mg/Nm3

25 mg/Nm3

20mg/Nm3 2. Reactor 11 Water Scrubber

followed by acid scrubber

NH3 175 mg/Nm3



ANNEXURE-XII LIST OF HAZARDOUS CHEMICAL Sr. No.

Name of Chemical

1. Phenol 2. Sulphuric acid 3. Methanol 4. Phosphoric Acid 5. Toluene 6. Potassium Hydroxide 7. Sodium hydroxide 8. Hydrochloric acid 9. Iso Propyl Alcohol(IPA) 10. Soda Ash 11. Ammonia 12. Bromine 13. Sodium SulfhydrateNaSH

(30%) 14. Chloro sulfonic acid 15. Caustic Soda Lye 16. Chlorine 17. Oleum 23% 18. Sodium Hydrosulfite 19. Acetyl Chloride

20. Acetyl Chloride

21. Thionyl Chloride

22. HBr (48%)

23. Sulfur trioxide 24. Sulfur dioxide

M M/s. Jyoti Om

GIDC TRA

m Chemical R

ANSFER LE

Research Cent

ETTER

M/s. Sitam

tre Pvt. Ltd.

mani Organic

c Pvt. Ltd., P

Phase-III GI

IDC Dahej, B

ANNEXUR

Bharuch

RE-XIII

M


M/s. Sitam

tre Pvt. Ltd.

mani Organic

c Pvt. Ltd., P

Phase-III GI

IDC Dahej, B

Bharuch

M/s. Sitamani Organic Pvt. Ltd., Phase-III GIDC …. Sitamani Organic Pvt. Ltd., Phase-III GIDC Dahej, Bharuch M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. ANNEXURE-IV LIST OF

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