Monitored Natural Attenuation of Metals and Radionuclide- Contaminated Sites Pat Brady Sandia National Laboratories Mike Truex Pacific Northwest National Laboratory Chuck Newell GSI Karen Vangelas Savannah River National Laboratory Miles Denham Savannah River National Laboratory Sponsored by: DOE EM-22 Attenuation-Based Remedies for Metals and Radionuclide Project (Leads: M. Denham and K. Vangelas, Savannah River National Laboratory ) Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-AC04- 94AL85000.
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Monitored Natural Attenuation of Metals and Radionuclide-Contaminated Sites
Monitored Natural Attenuation of Metals and Radionuclide-Contaminated Sites. Pat Brady Sandia National Laboratories Mike Truex Pacific Northwest National Laboratory Chuck Newell GSI Karen Vangelas Savannah River National Laboratory Miles Denham Savannah River National Laboratory - PowerPoint PPT Presentation
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Monitored Natural Attenuation of Metals and Radionuclide-Contaminated Sites
Pat Brady Sandia National LaboratoriesMike Truex Pacific Northwest National LaboratoryChuck Newell GSIKaren Vangelas Savannah River National LaboratoryMiles Denham Savannah River National Laboratory
Sponsored by: DOE EM-22 Attenuation-Based Remedies for Metals and Radionuclide Project (Leads: M. Denham and K. Vangelas, Savannah River National Laboratory)
Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000.
Volume 3Assessment for RadionuclidesIncluding Isotopes of Cesium, Iodine, Neptunium, Plutonium, Strontium, Technetium, and Uranium
In Preparation
Recent EPA Guidance for MNA of Metals and Radionuclides
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The Scenarios Approach
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Scenarios
Contaminant
Scenario 1 low redox high CEC
Scenario 2 low redox low CEC
Scenario 3 high redox high CEC high Fe
Scenario 4 high redox high CEC
low Fe
Scenario 5 high redox, low CEC high Fe
Scenario 6 high redox, low CEC low Fe
Cr(III) ↓S ↓S
Cr(VI) reduced to Cr(III)
reduced to Cr(III)
99Tc(IV) ↓S ↓S Likely oxidized
to Tc(VII) Likely oxidized
to Tc(VII) Likely oxidized
to Tc(VII) Likely oxidized
to Tc(VII)
99Tc(VII) reduced to Tc(IV)
reduced to Tc(IV)
Pu
U
Pb ↓S ↓S
Cd ↓S ↓S
Zn ↓S ↓S
Ni ↓S ↓S
Cu ↓S ↓S
As ↓S ↓S
Se
90Sr ↑TDS ↑TDS ↑TDS
Nitrate can degrade can degrade
Perchlorate can degrade can degrade
129I
HIGH Mobility
Mobility increases above and below pH7 S Increasing sulfur
decreases mobility
MEDIUM Mobility
Mobility increases above pH7 TDS Increasing TDS
increases mobility
LOW Mobility
Mobility decreases above pH7 and increases below pH7
Transformed to other valence state
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Mechanisms
Sorption Solubility
Microbial Processes
Dilution DegradationDecay
Groundwater Condition
Impact on Sorption
Impact on Solubility
Redox Low: Most uranium compounds are relatively insoluble under low redox conditions High: uranium is generally soluble. U(IV) reoxidizes to U(VI).
CEC Fe Iron oxides are major
sorption sites for uranium
pH Sorption may decrease with decreasing or increasing pH compared to neutral. Clay and iron mineral dissolution and precipitation of amorphous phases changes sorption sites
Changes U complexation and impacts solubility
Sulfur TDS Blank indicates “no major impact”
Example: Uranium
Mechanisms
Sorption Solubility
Microbial Processes
Dilution DegradationDecay
Groundwater Condition
Impact on Sorption
Impact on Solubility
Redox Low: Dissolution of iron oxides can release arsenic into the groundwater As(III) (reduced form) sorption is somewhat lower than As(V) sorption
Low: Generally no insoluble solids except for arsenic sulfides
CEC High CEC may increase sorption
Fe Iron oxide dissolution may be important (see redox discussion)
pH Sorption may decrease with decreasing pH
Possible increases in solubility with decreasing pH
Sulfur Under low redox conditions sulfide compounds result in low solubility
TDS Phosphate or silicate can inhibit sorption
Blank indicates “no major impact”
Example: Arsenic
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Table 9 Remediation Technologies Matrix for Metals in Soils and Groundwater (GWRTAC, 1997)
Reactive barriers (ZVI) ● 4500(4) - Reactive barriers (mulch) ● 400(4) - (●) symbol indicates the treatment technology is applicable to the strategy (1) Costs do not include pretreatment, site preparation, regulatory compliance costs, costs for additional treatment
of process residuals, or profit (2) Density of soil assumed: 100 lb/ft3 (3) Cost for subsurface barriers is for slurry walls; cost is $ per square foot (4) Cost for ZVI and mulch reactive barriers reported as $ per linear foot