22 nd October 2004 G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries LAMNET Workshop - Biomass opportunities in Venezuela LAMNET Workshop Biomass Opportunities in Venezuela Modern Bio-energy Schemes for Industrial Developing Countries European Biomass Industry Association Dott. Giuliano Grassi EUBIA Secretary General [email protected]www.eubia.org
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Modern Bio-energy Schemes for Industrial Developing Countries
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22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
LAMNET Workshop
Biomass Opportunities in Venezuela
Modern Bio-energy Schemes for Industrial Developing Countries
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Main bioenergy routes
Wet biomass(organic waste, manure, etc.)
Solid biomass(wood, straw, peat, etc.)
Sugar and starch plants(sugar beet, sweet sorghum, cereals, etc.)
Oil crops(rape, sunflower, etc.)
Fuel gasBiogas Pyrolytic oil
Vapour Heat Electricity
Sugar
Crushing &RefiningGasification Pyrolysis
Process Space & water heating Electric devices Transport
Liquid biofuels
Cogeneration
Extraction & HydrolysisCombustion
Anaerobic fermentation Hydrolysis
Ethanol
Fermentation
ETBE Biodiesel
Transesterification
m
Vegetable oil
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Bioenergy : a wide and complex sector
Biomass
Production
Conversion
&
Up-grading
Utilisation
F e r t i l i s e rd i s t r i b u t i n gm a c h i n e s
P la n t i n gM a c h i n e s
H a r v e s t i n gm a c h i n e s T r a n s p o r t
D r y i n gM a c h i n e s C h i p p i n g
T r a n s p o r t e rF e e d i n gM a c h i n e s
S t o r a g eP e l l e t i s a t i o n& b r i q u e t t i n gt e c h n .
C o m m i n u t i o nP u l v e r i s i n gm a c h i n e s
C a n e c r u s h i n gM a c h i n e s
F l u i d i s e d b e d d r y i n g M a c h in e s
P e l l e t i s a t i o nB r i q u e t t i n gm a c h i n e s
S u g a re x t r a c t i o nm a c h i n e s +c o n c e n t r a t i o n
S e e d i n gm a c h i n e s
B io m a s sp o w e r e dC o m b u s t o r s
F l u i d i s e d – B e dC o m b u s t o r sb o i l e r s
A n a e r o b i cd i g e s t i o n( b i o g a s )
A t m o s p h e r i cg a s i f i c a t i o n
P r e s s u r i s e dg a s i f i c a t i o n
F l a s h - p y r o l y s i s P l a s m a - c h e m i c a l c o n v e r s i o n
B io -h y d r o g e nt e c h n o l o g y
B i o - g a sp u r i f i c a t i o n
B io m a s sd e r i v e d g a sp u r i f i c a t i o n
H y d r o g e np u r i f i c a t i o n
B i o - c r u d e - o i li m p r o v e m e n t
B C O h y d r ot r e a t m e n t H y d r o g e n
f r o m B C Ot e c h n o l o g y
E T B Ep r o d u c t i o nt e c h n o l o g y
M e t h a n o ls y n t h e s i s
H e a t i n g s t o v e sP o w e r p r o d . b y g a st u r b i n e s f u e l l e dw i t h b i o m a s sp o w d e r
P o w e r g e n . b ya d v a n c e d s t e a m -c y c l e s o r i n d i r e c tG T c y c l e s
P o w e r g e n e r a t i o nb y t u r b i n e sc o m b i n e d - c y c le s
P o w e r g e n . b yd i e s e l f u e l l e dw i t h b i o - c r u d e - o i l
U s e o fb i o e t h a n o l f o rc o g e n e r a t i o n
U s e o f b i o e t h a n o lf o r g a s o l i n er e f o r m u l a t i o n
B io e t h a n o lc o o k i n g s t o v e s
I n t e g r a t i o n o f b i o e n e r g y w i t h p e t r o l e u m r e f i n e r i e s
B io e t h a n o l d i r e c tu s e i n f u e l - c e l lg e n e r a t o r s
S t i r l i n gg e n e r a t o r s
E m is s io n s c o n t r o l t e c h n o l o g y
E le c t r o n i c s t e c h .f o r s y s t e me f f i c i e n c y im p r o v .
A d v a n c e d e l e c t r .g e n e r a t o r st e c h n o lo g y
B i o g a s c o g e n e r a t i o n t e c h .
S e a - w a t e rd e s a l i n a t i o n t e c h .
I m p r o v e m e n t( e f f i c i e n c y & r e l i a b i l i t y )
o f e n d - u s e t e c h . : s t o v e s , r e f r i g e r a t o r s , f r e e z e r s , w a t e r p u r i f i c a t i o n , l i g h t , e l e c t r i c m o t o r
F a s t f e r m .t e c h n o lo g y
C h a r c o a lt e c h n o l o g y
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Solid bio-fuels (1)
Resources Pre treatment Utilisation
• Chipping
• Pelleting
• Briquetting
• Stoves
• Boilers
• Lignocellulosics
• Starch
• Sugar
•Heat
•CHP
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Solid bio-fuels (2)
ResourcesSawdust Others…
Woodchips
Straw
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Solid bio-fuels (3)
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Solid bio-fuels (4)
Pelleting equipment
Flat die (left) and ring die (right)
Source: Amandus Kahl; Salmatec; Larus Impianti
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Solid bio-fuels (5)
Pelleting equipment
Source: Sprout Matador
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Solid bio-fuels (6)
Pelleting plant scheme (10-12 t/h)
Source: Promill Stolz
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Solid bio-fuels (7)
Briquetting equipment
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Solid bio-fuels (8)
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Heat productionPellet stoves
Pellet boilers
Pellet burner
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Improvement of the economicsthrough integrated biomass processing
List of typical integrated projects:
1. Sweet sorghum integrated scheme
2. Small scale ethanol and power production:Haiti / Santo Domingo example
3. ECHI-T:- large bio-ethanol project from Sweet Sorghum in China and Italy- potential project in Romania under discussion
4. Technologies for CHP from biomass resources
5. Multi fuel fired CHP plant
6. Large CC ethanol-fuelled power plant
7. Cogeneration plant with simulatneous integrated production of bio-ethanol and bio-methanol from sugar cane or sweet sorghum for gasoline reformulation
8. Large Scale Integration of Bioenergy with Petrochemical Complex
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
• Suitable to different climatic and soil conditions (pH 5.0-8.5)
• Wide range of derived products
• High productivity (25 to 45 dry ton biomass / ha)
Average productivity:
• Grains: 5 ton/ha
• Bagasse (dry): 15 ton/ha
• Sugar: 7 ton /ha
• Leaves: 1.9 ton/ha
• Roots: 2.5 ton/ha
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
ECHI-T (3)Project overview
• Sweet Sorghum variety selections, and evaluation of productivity• Possible configuration (lay-out) and preliminary characteristics of the
three complexes• Available commercial technologies• Prelim. main characteristics and dimensions• Prelim. investment costs• Logistics needed by the integrated complexes• Costs associated to the Sweet Sorghum production• Co-product values• Techno-economic assessment in China and Italy
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
ECHI-T (4)Schedule of quantities produced:Basilicata(in t/year unless stated otherwise) DDG
2940
Grains Ethanol from grains Total ethanol8400 2688 42202
CO2 from grains2604
CO2 left for sale40389
Ethanol from juice39514
Plantation Sugar CO2 to methanol Methanol7000 ha 84000 0 0
CO2 from juice37785
Hydrogen0
Pellets to carbonisation Charcoal0 0
Activated coal0
Dry bagasse Pellets to pulp for paper Pulp for paper98000 0 0
Pellets to co-generation Electricity Electricity to S.S. proces96675 115 GWh/year 6 GWh/year
Pellets as animal feed Electricity left for sale1325 109 GWh/year
Steam to process97409
= Products available for salethat leave the biomass-complex
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
ECHI-T (8)Conclusion
• The scheme is technically feasible and in some situtations also economically feasible (Romania project)
• In the future, bio-methanol production in parallel to ethanol should be a recommended target (0.7 kg biomethanol / 1 kg bioethanol) to delay the CO2 emissions to the atmosphere
• Integration with other crops to extend bioethanol production time, toreduce investments and to increase the availability of bio-pellets
• Integrated juice extraction and pelletisation would be an advantage (under investigation now)
• Hydrogen massive production from biomass can be commercially implemented from now utilising less efficient technologies but economically approaching the marginal cost of hydrogen production from natural gas (@ 7$/MMBTU)
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Technologies for CHP from biomass resources (1)
Demonstration technologies:those based on advanced gasification/turbines, flash pyrolysis plants, Diesel, which still present some risks but could become commercial in a near future.
Commercial technologies:already well established, offering garantee of high performances and good efficiency, time-life, reliability, and noxious emissions control.
Commercial technologies can be further divided in three categories:
1. small capacity cogeneration plants. Examples:Energidalen-Energiproject AB / Sweden (500 kWe, 2000 kWth)Martezo down-draft gasifier (100 - 400 kWe, 200 - 800 kWth)
2. medium capacity cogeneration plants (ranging from 5 to 20 Mwe)
3. large capacity cogeneration plants (more than 20 Mwe)
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Technologies for CHP from biomass resources (2)
Combustion chamber with movable grid system
Combustion chamber type TRF with movable grid system.
It can be fueled with peat, chips, forest residue, bark and sawdust with a moisture content of 35-60 %
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Technologies for CHP from biomass resources (3)
Combustion chamber with movable grid and “sprider stokers” feeding system
Combustion chamber type TRT with movable grid system and sprinder-stockers injectors. It can be fueled with pellets, briquettes, peat, chips with a moisture content up to 35 %.
For a unit of 6 Mwe the typical plant characteristics are:
Inlet conditions 40 bar - 480 °CNet Power 5500 kWePower for auxiliaries 500 kWeSteam mass flow 28 t/hInlet heat power 26 MWElectrical efficiency 21%Specific investment 1350 $Nox Emission < 150 - 200 mg/Nm3
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Technologies for CHP from biomass resources (4)
Fluidised bed combustion chamberModern technology and now largely utilised for capacity over 7 MWe and presents 2 main configurations:
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Technologies for CHP from biomass resources (7)Investments
Total investment and other cost related to the to the 10 MW cogeneration plant
Typical biomass cogeneration system costs:
Installed Power [MWe] 10CAPITAL COST
Turbine Generator 6.000.000Boiler 7.500.000Boiler Feed Conveyor 250.000Truck Dumper 450.000Front End Loader 450.000Raw Wood Drag Chain Conveyor 300.000Raw Biomass Belt Conveyor 200.000Disc Screen 350.000Hammermill 300.000Sized Wood Belt Conveyor 500.000Storage Silo 1.700.000
Total Capital Cost 18.000.000
Electric Power Production [MWe] 10
Thermal Power Production [MWth] 24
Investment (civil works not included) [M$] 18
Working time of the plant [h] 7000
Electric Energy Production [MWh] 70000
Thermal Energy Production [MWh] 170000
Biomass Consumption [t/y] 64.000
Electric Energy Selling Price [$/kWh] 0.130
Thermal Energy Selling Price [$/kWh] 0.02
Biomass Purchase Price [$/kg] 0.05
Annual Fixed Cost [M$/y] 1.8
Life of the plant 20
Total Revenues [M$/y] 9.4
Total Operative Costs [M$/y] 5
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Technologies for CHP from biomass resources (8)Employment and specific investment
Estimated manpower requirements (direct jobs) for the biomass production and for the operation and maintenance of a 10 [Mwe] plant are shown in the tables here below
Type of Intensive Energy Crop
Cultivated area needed for 1 job [ha]
Manpower needed for the production of 1TOE [hr]
Short Rotation Forestry (*)
~ 60 3.7
Herbaceous crops ~ 120 1.9
Sugar Crop (Sweet-sorghum)(**)
~ 85 1.6
(*) Those data enclose the preparation of planting material, storage, transport. One ton of dry biomass is assumed to have an energy content of ~ 0.43 TOE. Average Labour requirements(1995) for modern production, mechanised harvesting, transport (average distance 20km) and management for sugar cane activity in Brasil (about 25,000 ha/yeld 75 t/ha year): 1 job per 21 ha.
(**) Estimated labor requirments for production , harvesting, mechanical sugar juice separation and transport of the products (grains, sugar-juice, bagasse derived from sweet sorghum plantations) to the processing factories and management is: 1 jobs per 30 ha of plantation.
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Technologies for CHP from biomass resources (9)Employment (10 MWe)
Number of Directs Jobs Required
Activity 1 MWe 5 MWe 10 MWe 30 MWe
Reception + pre-treatment of biomass 12 16 20 20
Conversion of biomass (gasification/pyrolysis)
4 8 8 12
Power Generation 4 4 4 8
Total Number of Direct Jobs 20 28 32 44
SR Forestry crops Herbaceous Crops SRF Forestry crops
Herbaceous crops
Production of biomass 47 24 54 28
Reception, pretreatment of biomass
5 5 20 20
Conversion (Gasification/pyrolysis)
- - 8 8
Electricity generation (four shift)
20 20 4 4
Total number of jobs 72 49 86 60
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Multi fuel fired CHP plant (1)
1st CHP plant in Denmark using a combination consisting of waste, wood chips, straw and natural gas
Fuel distribution in 1998:
• 550,000 t wastes
• 31,000 t straw
• 26,000 t wood chips
• 3,200 t wood pellets
• 2,000 t different bio-fuels
• 3,7 mio m3 natural gas
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Cogeneration plant with simulatneous integrated production of bio-ethanol and bio-methanol from sugar cane or sweet sorghum for gasoline reformulation (1)
The synthesis of methanolMethanol (CH3OH) is synthesized by a catalyzed reaction of carbon monoxide with hydrogen:CO + 2H2 → CH3OH
Methanol production by CO2 hydrogenation : 1 ton CO2
829 [kWhth]+
0.137 [ton] of H2
0.727 [ton] of Methanol+
WATER
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Cogeneration plant with simulatneous integrated production of bio-ethanol and bio-methanol from sugar cane or sweet sorghum for gasoline reformulation (2)
Basic chemistry of alcohol fuels CHEMICAL FORMULAE
Ethanol CH3CH2OH or (C2H5OH)
Methanol CH3OH
Ethane CH3 CH3 (or C2H6)
Ethyl Tertiary Butyl Ether (ETBE) (CH3)3COC2H3
Methyl Tertiary Butyl Ether (MTBE) (CH3)3COCH3
Methane CH4
Gasoline C4 to C12
Physiscal Properties of some bio-fuels and gasolinePhysical Properties Ethanol Methanol MTBE ETBE Gasoline
Molecular Weight 46.07 32.04 88.15 102.18 n.a
Specific Gravity [kg/dm3] @ 15[°C] 0.794 0.796 0.740 0.72-0.78
Boiling Point [°C] 78 65 27- 225
Pump Octane Number (Neat / Blended) 97 / 111 98 / 115 72 – 76 / na
Latent Heat of vaporisation [kJ/kg] 920 1176 348
Heating Value [kJ/kg] 26700 19920 35270 36030 41840 -44164
Stoichiometric air - fuel weight 9.00 6.45 11.69 12.10 14.7
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Cogeneration plant with simulatneous integrated production of bio-ethanol and bio-methanol from sugar cane or sweet sorghum for gasoline reformulation (3)
Process chemistry to obtain MTBE and ETBE:
Isobutylene(≅ 64%) Methanol(≅ 36% in volume) MTBE
CH3 CH3⏐ ⏐C ⎯ CH3 + CH3OH ⇔ CH3 ⎯ O ⎯ C ⎯ CH3⏐⏐ ⏐CH2 CH3
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Cogeneration plant with simulatneous integrated production of bio-ethanol and bio-methanol from sugar cane or sweet sorghum for gasoline reformulation (4)
Due to the differences in molecular weight of ETBE and MTBE, and the differences in the reaction stoichiometry, the amounts of alcohol and isobutylene required are quite different in each case. The amounts of reactant required to make 1,000 gallons of the ether are shown in the following relationships:Ethanol + Isobutylene = ETBE1054 kg 1564 kg 2845 kg (Theretical yield)
Methanol + Isobutylene = MTBE1017 kg 1786 kg 2803 kg (Theretical yield)
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Cogeneration plant with simulatneous integrated production of bio-ethanol and bio-methanol from sugar cane or sweet sorghum for gasoline reformulation (5)
Isobutylene is currently derived from two major sources: steam cracking for ethylene manufacture and fluid cat cracking for FCC gasoline, distillate, etc manufacture. Isobutylene supplies can also be made available by isomerizing surplus N-Butane to isobutane, the dehydrating the isobutane to isobutylene (but with high investment: 250 M$ min.); see Figure below (H2 plant).
Because the basic process chemistry is the same, ETBE can be manufactured with the same catalytic reaction and essentially the same process unit as MTBE.
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Cogeneration plant with simulatneous integrated production of bio-ethanol and bio-methanol from sugar cane or sweet sorghum for gasoline reformulation (6)
Biomethanol production integrated with bioETOH production from sugar cane
Bio Ethanol Plant
Sugar Cane Production∼ 11,000 ha
Washing Milling & Screening
Ethanol Distillation(50,000 ton/yr) Fermentation
Sugar Juice Preparation
Bio-MethanolProduction Plant (1st
Option)
H2Unit(*) (Electroliser) needs ∼ 225,000,000
[kWh/yr]Catalytic CO2
Hydrogenation Unit** Generator(***) of Process
Steam(48,000,000
[kWhth])
Methanol Production ∼ 35,000 [ton/yr]
HEAT(**) =29,000,000[kWhth/y]
BagasseDRYER
(50% ⇒ 10% Humidity)
Heat ∼ 19,000 MWhth/y
Night Hydro-elecricity (0.01
[$/kWh])
Stillage
Bagasse
Bagasse fuel for EthanolProduction
Excess of bagasse(11,000 dry ton/y)
CO2 = 47,000 ton/y
Bio-MethanolProduction Plant (2nd
Option)
Catalytic CO2Hydrogenation Unit**
Cogeneration UNIT
(20 [MW] η = 30%)
.H2 = 5,050 ton/yr Process
HEAT =29,000,000[kWhth/y]
Methanol Production
∼ 35,000 [ton/yr]
CO2 = 47,000 ton/y
Excess of bagasse(100,000 dry ton/y)
Electrical Energy139,000 [MWhe/y]
H2 = 5,050 ton/yr
H2Unit (Electroliser) needs ∼ 225,000,000
[kWh/yr]
Heat for selling121,000 [MWhe/y]
For sale
BagasseDRYER
(50% ⇒ 10% Humidity)
Heat 175,000 [MWh]Night Hydro-
elecricity (0.01 [$/kWh])
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (1)
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (2)
OIL REFINING
Basic refining process of heavy oil into light oil and the conversion of distillation residues, consists of cracking the molecules to increase the hydrogen content and to decrease the carbon content of the derived products with expenses of energy (endothermic process)
OIL REFINING
Heavy – oilMedium – oil
Gasoline(Methane)
H2 CONTENT (wt)
11%12%14%
(25%)
Main “ingredients” for refining processes:
Temperature Pressure Hydrogen Catalyst
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (3)
Crude oil
Scheme of a Typical Oil Refining Unit
440° C
10° C
Heat
Gasoline (45-7 %)
Jet fuel and kerosene (10.1 %)
Heating and diesel fuels(22.3 %)
Industrial fuel oil (5-7 %)
Lubrificating oils, waxes,and greases (1-3%)
Petroleum coke (4.3 %)
Asphalts (3.1 %)
Others (3.3 %)Residue is removed and processed
Coking
Vapor recovery
Catalistic cracking
Alkylation
Extraction
Gas for fuels and chemicals (4.2 %)
DistillationUnit
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (4)
HEAVY-OIL PROCESSING
VIS-BREAKINGThermal processing to obtain
Commercial Heavy-Fuel1st STEP
PRE-TREATMENT & DEEP REFININGCatalystic Craking at high temperature (450°C)
And hydrogen pressure (15-80 BAR)2nd STEP
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (5)
2 MIO t/yVery Heavy Fuel(not commercial)
Thermal treatment of VIS - Breaking Biomass Inputs
60.000 t/y gas 100.000 t/ygasoline
1,840,000 t/y of Heavy Fuel but of commercial quality
First Refining Process of de-asphalting
Hydrorefining Pre - Pretreatment
Deep – Refining (decarbonication & Hydrogenation)
~ 1 MIO t/y of Light Fuel
Bitumen ~ 0.8 MIO t/y
MarketProducts
Biomass Inputs
Proposed Process for a newsmall Maoming Refinery
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (6)
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (8)
Crude - Oil Bioenergy Inputs
0.8 mio t/yBitumen
Charcoal Pellets
Bio-Syn-Gas
Gas Purification & Membrane Separation
Gas/SteamC.C. powerGeneratorη ~40%
C = 50MWe
Processing of the 2 MIO t/Yof very heavy oil by
VIS-Breaking+
HidrorefiningPre-treatment
+Cathalytic-craking
To obtain
Biomass
~1 mio t/yLight-fuels
Market Products
High pressure steam
Low pressure steam
Power
H2
Biohydrogen (99.8)
Bioelectricity
Heat Vis-Breaking Process
Heat CathalysticCraking Process
SteamReforming
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (9)
• Heat (steam)• Electricity• Hydrogen
Potential bioenergy Contribution to supply the energy inputs for refining
• 0.4 MTOE/y (Refinery capacity = 2 MTOE/y)
• 2 MTOE/y (Refinery capacity = 10 MTOE/y)
Large amount of energy input is needed(Process η =80%)
Most promising Biomass Resource: • cost similar to Natural Gas (~ 200$/TOE)• easily handled, transported, stored
BIO-PELLETS
• 0.85 mio t/y (Refinery capacity = 2 MTOE/y)
• 4.2 mio t/y (Refinery capacity = 10 MTOE/y)
Amount of Biopellets needed per year
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela
Large Scale Integration of Bioenergy with Petrochemical Complex (10)
Major Benefits deriving from the use of Bioenergy for Crude-oil Refining
• Benefits for the oil-importing Country balance of payment, due to the substitution of valuable $ imported hydrocarbons with localcompetitive biomass energy resources valued in local currency.
• The substitution an utilization of 20% renewable biomass energy resources decrease, of 20% the CO2 emission into the atmosphere
• The production and supply of biopellets to the refinery generates many diversified jobs and supplementary income forrural population (rural development impact)
22nd October 2004
G.Grassi - Modern Bio-energy Schemes for Industrial Developing Countries
LAMNET Workshop - Biomass opportunities in Venezuela