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Function generator
Potentiostat
X-Y recorder
Coulomb meter
Monochromator
Halogen lamp
Electrolyte solution
R.E: Ag /AgCl
C.E: Pt W.E: Photoelectrode
In case ofactionspectrummeasurement
O±æc/çè
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ABCDEFGHIJKLM0NOPQRST
I
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UKLM[\VT. Abe, K. Nagai, K. Sekimoto, A. Tajiri, T. Norimatsu, Electrochem. Commun., 7, 1129 (2005).
T. Abe, K. Nagai, K. Sekimoto, A. Tajiri, T. Norimatsu, J. Electroanal. Chem., 583, 327 (2005).
T. Abe, S. Tobinai, K. Nagai, Jpn. J. Appl. Phys., in press.
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Wbú(ûZWX, YZ,íîïðññªòªµó¶T. Abe, K. Nagai, T. Ogiwara, S. Ogasawara, M. Kaneko, A. Tajiri, T. Norimatsu, J. Electroanal. Chem., 587, 127 (2006).
T. Abe, K. Nagai, S. Kabutomori, M. Kaneko, A. Tajiri, T. Norimatsu, Angew. Chem. Int. Ed., 45, 2778 (2006).
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T. Abe, K. Nagai, Org. Electron.,8, 262-271 (2007).
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MNOPQeN#
5.0x10-7
4.0
3.0
2.0
1.0
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[(C
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N] (a
rb. unit)
12008004000
time(sec)
10
8
6
4
2
Halogen lamp
(100 mW/cm2)
N(CH3)3 , 9.6 x 10-7 mol
(1.8 x 10-6 mol/L)
1x 1 cm2 Nafion/H2Pc/PTCBI
50 µm/50 nm/50 ~ 200 nm
Gas sensor
Blank ____
Glass ……
H2Pc/PTCBI(200 nm)/glass ……
Nafion ____
Nafion/H2Pc/PTCBI (50 nm) ____ , ……
Nafion/H2Pc/PTCBI (100 nm) ____ , ……
Nafion/H2Pc/PTCBI (200 nm) ____ , ……
542 mL
9:JKIJJíL%òòMNµñYYª©
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1.5x10-7
1.0
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0.0
![(
CH
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arb
. unit)
700600500400
wavelength (nm)
500 s
400 s
300 s
200 s
100 s
efghi100 µW/cm2
![(CH3)3N]= [(CH3)3N](blank)jk[(CH3)3N](monochromatic light)
1
2
3
!
[(C
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MNOPQeN##K
5.0x10-7
4.0
3.0
2.0
1.0
0.0
[(C
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N] (a
rb. unit)
150001000050000
time(s)
10
8
6
4
2
0
[(C
H3) 3
N]
2x10-7
1
0
[(C
H3) 3
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400003000020000100000
time [s]
80000 90000
2
4 X10 X
5.0x10-7
4.0
3.0
2.0
1.0
0.0
[(C
H3) 3
N] (a
rb. unit)
150001000050000
time (s)
8
6
4
2
0
[(C
H3) 3
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10 X
Nafion/H2Pc/PTCBI (50 nm) 100mWNafion
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ChemPhysChem, 5(5), 716-720 (2004).
J. Electroanal. Chem., 583(2), 327-332 (2005).
Electrochem. Commun., 7(11), 1129-1132 (2005).
J. Electroanal. Chem., 587(1), 127-132 (2006).
Angew. Chem. Int. Ed., 45(17), 2778-2781 (2006).
J. Solid State Electrochem., 11(2), 303-309 (2007).
J. Electroanal. Chem., 599(1), 65-71 (2007).
Org. Electron., 8(2-3), 262-271 (2007).
Dyes and Pigments, 77(2), 437-440 (2008).
Phys. Chem. Chem. Phys., 10(11), 1562-1568 (2008).
Jpn. J. Appl. Phys., in press.
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