Methyl Ethyl Ketone Peroxide Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/15/2014 Version: 1.0 04/15/2014 EN (English US) 1/12 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Name: Methyl Ethyl Ketone Peroxide Synonyms: Organic peroxide Other means of identification: DDM-9; Hipoint 90; MEKP-9 1.2. Intended Use of the Product Use of the Substance/Mixture: For professional use only. 1.3. Name, Address, and Telephone of the Responsible Party Company KwikBond Polymers 923 Teal Drive Benicia, CA 94510 T 866-434-1772 [email protected]1.4. Emergency Telephone Number Emergency Number : (800) 373-7542 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Ox. Liq. 1 H271 Org. Perox. D H242 Acute Tox. 4 (Oral) H302 Skin Corr. 1B H314 Eye Dam. 1 H318 Aquatic Chronic 3 H412 2.2. Label Elements - Informational only. Many do not apply to this product. GHS-US Labeling Hazard Pictograms (GHS-US) : GHS02 GHS03 GHS05 GHS07 Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H242 - Heating may cause a fire H271 - May cause fire or explosion; strong oxidizer H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage H412 - Harmful to aquatic life with long lasting effects Precautionary Statements (GHS-US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P220 - Keep/Store away from clothing, combustible materials, combustibles P221 - Take any precaution to avoid mixing with clothing, combustible materials, combustibles P234 - Keep only in original container P260 - Do not breathe mist, spray, vapors P264 - Wash exposed areas. thoroughly after handling P270 - Do not eat, drink or smoke when using this product P273 - Avoid release to the environment P280 - Wear eye protection, protective clothing, protective gloves P283 - Wear fire/flame resistant/retardant clothing P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all
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Methyl Ethyl Ketone Peroxide Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 04/15/2014 Version: 1.0
04/15/2014 EN (English US) 1/12
SECTION 1: IDENTIFICATION 1.1. Product Identifier
Product Name: Methyl Ethyl Ketone Peroxide
Synonyms: Organic peroxide
Other means of identification: DDM-9; Hipoint 90; MEKP-9
1.2. Intended Use of the Product Use of the Substance/Mixture: For professional use only.
1.3. Name, Address, and Telephone of the Responsible Party
NJTSR (56705700001-5697P) (CAS No) Proprietary < 1 Not classified
Full text of H-phrases: see section 16
Methyl Ethyl Ketone Peroxide Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible). IF exposed or concerned: Get medical advice/attention.
First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area. IF INHALED: Remove
to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Immediately call
a POISON CENTER or doctor/physician.
First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes.
Wash contaminated clothing before reuse. Call a POISON CENTER/doctor/physician if you feel unwell. Immediately call a POISON
CENTER or doctor/physician.
First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or
doctor/physician. Call a POISON CENTER/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Causes severe skin burns and eye damage. Harmful if swallowed.
Symptoms/Injuries After Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical burns.
Symptoms/Injuries After Skin Contact: Corrosive. Causes burns.
Symptoms/Injuries After Eye Contact: Causes serious eye damage.
Symptoms/Injuries After Ingestion: Harmful if swallowed. Swallowing a small quantity of this material will result in serious
health hazard.
Chronic Symptoms: None known.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If medical advice is needed, have product container or label at hand.
SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: Do not use water jet. Use of heavy stream of water may spread fire.
5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Heating may cause a fire.
Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries.
6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Ventilate area.
6.2. Environmental Precautions Prevent entry to sewers and public waters. Avoid release to the environment.
6.3. Methods and Material for Containment and Cleaning Up
For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Do not take
up in combustible material such as: saw dust or cellulosic material.
Methods for Cleaning Up: Collect spillage. Clear up spills immediately and dispose of waste safely.
6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection.
Methyl Ethyl Ketone Peroxide Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling Additional Hazards When Processed: Any proposed use of this product in elevated-temperature processes should be thoroughly
evaluated to assure that safe operating conditions are established and maintained.
Precautions for Safe Handling: Use only outdoors or in a well-ventilated area. Obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not breathe mist/vapors/spray.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed
areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Contaminated work clothing
should not be allowed out of the workplace. Do no eat, drink or smoke when using this product. Wash hands and forearms
thoroughly after handling. Wash contaminated clothing before reuse. Always wash your hands immediately after handling this
product, and once again before leaving the workplace.
7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Proper grounding procedures to avoid static electricity should be followed. Comply with applicable
regulations.
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Store in a well-
ventilated place. Keep container tightly closed. Keep in fireproof place. Store at temperatures not exceeding 37.77°C / 100°F.
Persistence and Degradability May cause long-term adverse effects in the environment.
12.3. Bioaccumulative Potential
Methyl Ethyl Ketone Peroxide
Bioaccumulative Potential Not established.
2,4-Pentanediol, 2-methyl- (107-41-5)
Log Pow < 0.14
Hydrogen peroxide (7722-84-1)
BCF fish 1 (no bioaccumulation)
Methyl ethyl ketone (78-93-3)
Log Pow 0.29
12.4. Mobility in Soil No additional information available
12.5. Other Adverse Effects
Other Information : Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and international
regulations.
Additional Information: Consult manufacturer for disposal. To meet regulatory criteria, the container is considered empty when
less than 3% remains in the container. Hazardous waste due to potential risk of explosion.
Ecology – Waste Materials: Hazardous waste due to toxicity. This material is hazardous to the aquatic environment. Keep out of
sewers and waterways.
SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT
Proper Shipping Name : ORGANIC PEROXIDE TYPE D, LIQUID (Methyl Ethyl Ketone Peroxide, <45%)
Hazard Class : 5.2
Identification Number : UN3105
Label Codes : 5.2
Packing Group : II
ERG Number : 145
14.2 In Accordance with IMDG
Proper Shipping Name : ORGANIC PEROXIDE TYPE D, LIQUID (Methyl Ethyl Ketone Peroxide, <45%)
Hazard Class : 5.2
Identification Number : UN3105
Label Codes : 5.2
EmS-No. (Fire) : F-J
EmS-No. (Spillage) : S-R
14.3 In Accordance with IATA
Proper Shipping Name : ORGANIC PEROXIDE TYPE D, LIQUID (Methyl Ethyl Ketone Peroxide, <45%)
Identification Number : UN3105
Hazard Class : 5
Label Codes : 5.2
ERG Code (IATA) : 5L
SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations
Methyl Ethyl Ketone Peroxide
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Fire hazard
Methyl Ethyl Ketone Peroxide Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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Reactive hazard
Methyl ethyl ketone peroxide (1338-23-4)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2,4-Pentanediol, 2-methyl- (107-41-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory