MATERIAL SAFETY DATA SHEET · 2015-11-30 · APS 500 Advanced Polymer Sealant 6 Supplier Trade Secret STEL: 0.2 mg/m 3 Sn TWA: 0.1 mg/m3 Sn S* TWA: 0.1 mg/m Sn (vacated) TWA: 0.1

Triangle Fastener Corporation

Conforms to OSHA HazCom 2012 Standard and WHMIS 2015

SAFETY DATA SHEET

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APS 500 Advanced Polymer Sealant

Section 1: IDENTIFICATION

1.1 PRODUCT IDENTIFIER

Product Name: APS 500 Advanced Polymer Sealant

Product Code: Not Available

1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE

Product Use: Sealant

1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEETS

Name/Address: Triangle Fastemer Corporation 1925 Preble Ave Pittsburgh, PA 15233

Telephone Number: (412) 321-5000

1.4 EMERGENCY TELEPHONE NUMBER

Emergency Telephone Number:

CHEMTREC 1-800-424-9300 (US and Canada) INTERNATIONAL + 1-703-527-3887

Section 2: HAZARD(S) IDENTIFICATION

2.1 CLASSIFICATION OF THE CHEMICAL IN ACCORDANCE WITH PARAGRAPH (d) OF 29 CFR 1910.1200 (OSHA HAZCOM2012) Eye Irritation Category 2A Skin Sensitization Category 1 Carcinogenicity Category 1A Reproductive Toxicity Category 1B

2.2 LABEL ELEMENTS ACCORDING TO OSHA HAZCOM2012

2.2a SIGNAL WORD: DANGER!

2.2b HAZARD STATEMENTS Causes serious eye irritation May cause an allergic skin reaction May cause cancer May damage fertility or the unborn child



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2.2c HAZARD PICTOGRAMS

2.2d PRECAUTIONARY STATEMENTS

i. PREVENTION Wash hands thoroughly after handling. Do not breathe vapors/fumes. Do not eat, drink or smoke while using this product. Use in a well ventilated area. Wear impervious gloves/protective clothing/eye protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Contaminated work clothing must not be allowed out of the workplace.

ii. RESPONSE If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a poison center/doctor. If swallowed: Rinse mouth. Do NOT induce vomiting. Get medical advice/attention if you feel unwell. If exposed or concerned: Get medical advice/attention.

iii. STORAGE Store locked up. Store in a well-ventilated place. Keep container tightly closed.

iv. DISPOSAL Dispose of contents/containers in accordance with all local, state, provincial, and federal regulations.

2.3 ADDITIONAL INFORMATION

2.3a HNOC – HAZARDS NOT OTHERWISE CLASSIFIED Not Applicable 2.3b UNKNOWN ACUTE TOXICITY

40.8% of the mixture consists of ingredient(s) of unknown acute toxicity.

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS



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3.1 MIXTURES

Chemical Name CAS Number Weight %

Calcium Carbonate** 1317-65-3 30 – 60%*

Silyl Terminated Polyethers Proprietary 10 – 30%*

Trimethoxyvinylsilane 2768-02-7 0.5 – 1.5%*

Aminoalkoxysilane 1760-24-3 0.5 – 1.5%*

Dibutyltin bis(acetylacetonate) 22673-19-4 0.1 – 1.0%*

Crystalline Silica, Quartz** 14808-60-7 0.1 – 1.0%*

**Inhalation of particulates unlikely due to product’s physical state.

*Means that the component will fall into one of the ranges specified due to batch-to-batch variability and to protect Confidential Business Information.

Section 4: FIRST-AID MEASURES

4.1 DESCRIPTION OF THE FIRST-AID MEASURES

ROUTES OF EXPOSURE DESCRIPTION

Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention immediately.

Skin Contact: In case of contact, immediately flush skin with plenty of soap and water. For minor skin contact, avoid spreading material on unaffected skin. If skin irritation or rash occurs: get medical attention/advice. Take off contaminated clothing and wash before reuse.

Inhalation: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell.

Ingestion: If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical advice/attention.

4.2 MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED

ROUTES OF EXPOSURE DESCRIPTION

Eye Contact: Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva.

Skin Contact: May cause skin irritation. Handling can cause dry skin, discomfort, irritation, and dermatitis. May cause an allergic skin reaction.



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Inhalation: May cause respiratory tract irritation. May cause damage to organs through prolonged or repeated exposure. This product contains crystalline silica. Prolonged or repeated inhalation of respirable crystalline silica from this product can cause silicosis, a serious disabling and fatal lung disease.

Ingestion: May be harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or vomiting.

4.3 INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED

Note to Physicians: Symptoms may not appear immediately.

Specific Treatments: In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible).

Section 5: FIRE-FIGHTING MEASURES

5.1 FLAMMABILITY

Flammability: Not Flammable/Not Combustible by WHMIS/OSHA HAZCOM2012 Criteria

5.2 EXTINGUISHING MEDIA

5.2a. Suitable Extinguishing Media: Treat for surrounding material.

5.2b. Unsuitable Extinguishing Media: Water

5.3 SPECIFIC HAZARDS ARISING FROM THE CHEMICAL

5.3a. Products of Combustion: By heating and fire, harmful vapors/gases may be formed. Nitrogen Oxides(corrosive)

5.3b. Explosion Data

i. Sensitivity to Mechanical Impact: Not Available

ii. Sensitivity to Static Discharge: Not Available

5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS

Keep upwind of fire. Wear full fire fighting turn-out gear(full bunker gear) and respiratory protection (SCBA).



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Section 6: ACCIDENTAL RELEASE MEASURES

6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.

6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP

Methods for Containment: Recover all usable material. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE).

Methods for Cleaning-Up: Dispose of unwanted material properly in accordance with all local, regional, national and international regulations.

Section 7: HANDLING AND STORAGE

7.1 PRECAUTIONS FOR SAFE HANDLING

Handling:

Use in well-ventilated areas. Wear impervious gloves and eye protection. Do not mix with other chemical products, except as indicated by the manufacturers. Do not get in eyes. Do not get on skin or clothing. Do not breathe vapors/fumes. Do not take internally.

General Hygiene Advice: Use good industrial hygiene practices and wear recommended personal protection. Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.

7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

Storage: Store locked up. Keep out of the reach of children. Keep container tightly closed. Store at room temperature and keep containers closed when not in use.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 CONTROL PARAMETER Exposure Guidelines:

Occupational Exposure Limits

Chemical Name OSHA-PEL ACGIH-TLV

Calcium Carbonate** 5 mg/m3 (Resp.) 15 mg/m3 (Total)

5 mg/m3 (Resp.)

Silyl Terminated Polyethers Not Available Not Available

Trimethoxyvinylsilane Not Available Not Available



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Aminoalkoxysilane Not Available Not Available

Dibutyltin bis(acetylacetonate) 0.1 mg/m3 0.1 mg/m3

Crystalline Silica, Quartz** 0.05 mg/m3 0.025 mg/m3 (Resp.)

**Inhalation of particulates unlikely due to product’s physical state. 8.2 EXPOSURE CONTROLS

Engineering Controls: Use ventilation adequate to keep exposures (airborne levels

of dust, fume, vapor, etc.) below recommended exposure limits.

8.3 INDIVIDUAL PROTECTION MEASURES

8.3a. Personal Protective Equipment:

i. Eye/Face Protection: Wear approved eye protection [properly fitted dust- or splash-proof chemical safety goggles/face (face shield)]

ii. Skin Protection:

1. Hand Protection: Wear impervious gloves, such as nitrile.

2. Body Protection: Wear suitable protective clothing.

iii. Respiratory Protection: A NIOSH approved respirator or filtering face piece, such as N95, is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for respiratory protection (Z88.2).

iv. General Health and Safety Measures: Handle according to established industrial hygiene and safety practices.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance (physical state, color, etc.): Opaque Paste

Odor: Mint-like

Odor Threshold: Mild

pH: 7 - 8 Melting point/Freezing point: Not Available Initial boiling point and boiling range: Not Available Flash point: Not Available Evaporation rate (Water=1): Not Available Flammability: Not Flammable/Not Combustible

Upper Flammability/Explosive Limit: Not Available Lower Flammability/Explosive Limit: Not Available Vapor Pressure Not Available



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Vapor Density: Not Available

Relative Density: 1.65 – 1.85 g/mL

Solubility in Water: Insoluble

Partition coefficient: n-octanol/water: Not Available Auto-ignition temperature: Not Available Decomposition Temperature: Not Available Viscosity (cps): Approximately 1,000,000 cP VOC Content: <16 g/L, less water and exempt solvents

Section 10: STABILITY AND REACTIVITY

10.1. REACTIVITY No dangerous reaction known under conditions of normal use.

10.2. CHEMICAL STABILITY Stable under normal storage conditions. Keep dry in storage.

10.3. POSSIBILITY OF HAZARDOUS REACTION No dangerous reaction known under conditions of normal use.

10.4. CONDITIONS TO AVOID Heat. Incompatible materials.

10.5. INCOMPATIBLE MATERIALS Strong oxidizing agents. Water and moisture.

10.6. HAZARDOUS DECOMPOSITION PRODUCTS

Carbon oxides. Nitrogen Oxides (NOx). Aldehydes. Methanol.

Section 11: TOXICOLOGICAL INFORMATION

11.1. LIKELY ROUTES OF EXPOSURE: Skin contact, eye contact, inhalation, and ingestion.

11.2. SYMPTOMS RELATED TO PHYSICAL/CHEMICAL/TOXICOLOGICAL CHARACTERISTICS:

Eye Contact: Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva.

Skin Contact: May cause skin irritation. Handling can cause dry skin, discomfort, irritation, and dermatitis. May cause an allergic skin reaction.

Inhalation: May cause respiratory tract irritation. May cause damage to organs through prolonged or repeated exposure. This product contains crystalline silica. Prolonged or repeated inhalation of



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respirable crystalline silica from this product can cause silicosis, a serious disabling and fatal lung disease.

Ingestion: May be harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or vomiting.

Acute Toxicity(ATEmix= 5,889 mg/kg)

Chemical Name LC50 LD50

Calcium Carbonate Not Available Oral: 6,450 mg/kg, rat


Trimethoxyvinylsilane Not Available Oral: >7,000 mg/kg, rat

Aminoalkoxysilane Not Available Oral: >7,500 mg/kg, rat

Dibutyltin bis(acetylacetonate) Not Available Oral: 1,864 mg/kg, rat

Crystalline Silica, Quartz Not Available Oral: >10,000 mg/kg, rat

Carcinogenicity

Chemical Name Chemical Listed as Carcinogens or Potential Carcinogen

(NTP,IARC,OSHA,ACGIH,CP65)

Calcium Carbonate Not Listed

Silyl Terminated Polyethers Not Listed

Trimethoxyvinylsilane Not Listed

Aminoalkoxysilane Not Listed

Dibutyltin bis(acetylacetonate) Not Listed

Crystalline Silica, Quartz N-2, I-1, O-1, ACGIH-A2, CP65

11.3. DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT AND LONG-TERM EXPOSURE

SHORT-TERM Skin Corrosion/Irritation: May cause skin irritation

Serious Eye Damage/Irritation: Causes serious eye irritation

Respiratory Sensitization: Not Classified

Skin Sensitization: May cause an allergic skin reaction

STOT-Single Exposure: May cause respiratory irritation

Aspiration Hazard: Not Classified

LONG-TERM Carcinogenicity: May cause cancer Germ Cell Mutagenicity: Not Classified Reproductive Toxicity: May damage fertility or the unborn child STOT-Repeated Exposure: Not Classified Synergistic/Antagonistic Effects: Not Classified

Section 12: ECOLOGICAL INFORMATION

12.1. ECOTOXICITY May cause long-term adverse effects to the aquatic environment. Keep from entry into sewers and waterways.



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Ecotoxicity

Chemical Name EC50/NOEC-48 Hours LC50/NOEC-96 Hours

Calcium Carbonate Not Available Not Available


Trimethoxyvinylsilane 168.7 mg/L, Daphnia magna 597 mg/L, Brachydanio rerio

Aminoalkoxysilane 81 mg/L, Daphnia magna 597 mg/L, Brachydanio rerio

Dibutyltin bis(acetylacetonate) 0.0036 mg/L, Daphnia magna Not Available

Crystalline Silica, Quartz Not Available Not Available

12.2. PERSISTENCE AND DEGRADABILITY

Not Available

12.3. BIOACCUMULATIVE POTENTIAL Not Available

12.4. MOBILITY IN SOIL Not Available

12.5. OTHER ADVERSE EFFECTS Not Available

Section 13: DISPOSAL CONSIDERATIONS

13.1. DISPOSAL METHOD Dispose of contents/containers in accordance with all local, state, provincial, and federal regulations

13.2. OTHER DISPOSAL CONSIDERATIONS Not Available

Section 14: TRANSPORT INFORMATION

DOT (U.S.) TDG (CANADA) IATA

UN NUMBER:

Not Regulated

UN NUMBER:

Not Regulated

UN NUMBER:

Not Regulated

UN PROPER SHIPPING NAME:

Not Regulated


Not Regulated


Not Regulated

TRANSPORT HAZARD CLASS (ES):

Not Regulated


Not Regulated


Not Regulated

PACKING GROUP (if applicable):

Not Regulated


Not Regulated


Not Regulated



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SUMMARY: Product is NOT regulated under DOT/TDG and other transportation regulations.

14.1. ENVIRONMENTAL HAZARDS Not Available

14.2. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE Not Available

14.3. SPECIAL PRECAUTIONS FOR USER Do not handle until all safety precautions have been read and understood.

Section 15: REGULATORY INFORMATION

15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATIONS SPECIFIC FOR THE CHEMICAL

Canada: This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations and the SDS contains all the information required by the Hazardous Products Regulations.

US: SDS prepared pursuant to the Hazard Communication Standard (29 CFR 1910.1200) HazCom 2012

15.2. US FEDERAL INFORMATION:

SARA TITLE III

CHEMICAL NAME SECTION 302

(EHS) TPQ (LBS) SECTION 304 EHS RQ (LBS)

CERCLA RQ (LBS)

SECTION 313 (TRI)

Calcium Carbonate Not Listed Not Listed Not Listed Not Listed

Silyl Terminated Polyethers Not Listed Not Listed Not Listed Not Listed

Trimethoxyvinylsilane Not Listed Not Listed Not Listed Not Listed

Aminoalkoxysilane Not Listed Not Listed Not Listed Not Listed

Dibutyltin bis(acetylacetonate) Not Listed Not Listed Not Listed Not Listed

Crystalline Silica, Quartz Not Listed Not Listed Not Listed Not Listed

15.3. US STATE RIGHT TO KNOW LAWS:

California Proposition 65:

WARNING: This product can expose you to chemicals including crystalline silica, which is known to the State of California to cause cancer, and methanol, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.

Other U.S. States “Right to Know” Lists:

Calcium Carbonate: CAS#1317-65-3 Silyl Terminated Polyethers: CAS# N/A Trimethoxyvinylsilane: CAS#2768-02-7 Aminoalkoxysilane: CAS#1760-24-3 Dibutyltin bis(acetylacetonate): CAS#22673-19-4 Crystalline Silica, Quartz: CAS#14808-60-7

http://www.p65warnings.ca.gov/



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15.4. GLOBAL INVENTORIES

Chemical Name USA TSCA Canada DSL/NDSL

Calcium Carbonate Yes NDSL

Silyl Terminated Polyethers Yes DSL

Trimethoxyvinylsilane Yes DSL

Aminoalkoxysilane Yes DSL

Dibutyltin bis(acetylacetonate) Yes DSL

Crystalline Silica, Quartz Yes DSL

15.5. NFPA AND HMIS RATINGS:



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15.6. SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:

CP65 California Proposition 65

OSHA (O) Occupational Safety and Health Administration

ACGIH (G) American Conference of Governmental Industrial Hygienists

• A1 – Confirmed human carcinogen

• A2 – Suspected human carcinogen

• A3 – Animal carcinogen

• A4 – Not classifiable as a human carcinogen

• A5 – Not suspected a human carcinogen

IARC (I) International Agency for Research on Cancer

• 1 – The agent (mixture) is carcinogenic to humans



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• 2A – The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals.

• 2B – The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals.

• 3 – The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.

• 4 – The agent (mixture, exposure circumstance) is probably not carcinogenic to humans.

NTP (N) National Toxicology Program

• 1 – Known to be carcinogens

• 2 – Reasonably anticipated to be carcinogens

Section 16: OTHER INFORMATION

Date of Preparation: May 5, 2015

Version: 1.2

Revision Date: June 15, 2020

Disclaimer: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products.

Prepared by: Triangle Fastemer Corporation Phone: (412) 321-5000 http://www.trianglefastener.com/

End of Safety Data Sheet

MATERIAL SAFETY DATA SHEET · 2015-11-30 · APS 500 Advanced Polymer Sealant 6 Supplier Trade Secret STEL: 0.2 mg/m 3 Sn TWA: 0.1 mg/m3 Sn S* TWA: 0.1 mg/m Sn (vacated) TWA: 0.1

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