MANUFACTURED SUBSTANCES IN INDUSTRY Name: MUHAMMAD EIZZUDDIN BIN MOHD SAHAR CLASS: 4 BESTARI
MANUFACTURED SUBSTANCES IN INDUSTRY
Name: MUHAMMAD EIZZUDDIN BIN
MOHD SAHAR
CLASS: 4 BESTARI
OBJECTIVES
UNDERSTANDING THE MANUFACTURE OF
SULPHURIC ACID
SYNTHESISING THE MANUFACTURE OF AMMONIA
AND ITS SALT
UNDERSTANDING ALLOYS
EVALUATING USES OF SYNTHETIC POLYMERS
APPLYING USES OF GLASS AND CERTAIN
CERAMICS
EVALUATING USES OF COMPOSITE MATERIALS
APPRECIATING VARIOUS SYNTHETIC INDUSTRIAL
MATERIALS
SULPHURIC ACID
H2SO4USES OF SULPHURIC ACID:
Sulphuric acid is used to produce chemical fertilizer such as
ammonium sulphate and potassium sulphate, which are highly
soluble in water and can be easily obsorbed by plant.
Car batteries contain sulphuric acid which is used as the electrolyte.
Chemical like paints, dyes and drug use sulphuric acid as one
of their component materials.
,
MANUFACTURING OF SULPHURIC ACID Sulphuric acid is manufactured in industry though contact
process
2. The process contain three stage
STAGE1: Production Of Sulphur Dioxide From Sulphur
Combustion of sulphur or sulphide ores in the air produce
sulphur dioxide SO2.
S(s)+O2(g) SO2(g) sulphur
sulphur dioxide is dried and purified.
STAGE2: Production Of Sulphur Trioxide From Sulphur
Dioxide
The purified sulphur dioxide SO2 and excess air are passed over
vanadium(V)
oxide V2O5 at controlled optimum condition optimum
condition to produce sulphur trioxide SO3.
2SO2(g)+O2(g) 2SO3(g)
The optimum used are
a) Temperature:450-500°C
b) Pressure: 2-3 atmospheres
c) Catalyst: Vanadium(V) oxide
Under controlled optimum conditions, 98% conversion is
possible. Sulphur dioxide and oxygen that have not reacted are
allowed to flow back again over the catalyst in the converter.
STAGE3: Conversion of trioxide to sulphuric acid
Sulphur trioxide SO2 is dissolved in concentrated sulphuric
acid H2SO4 to form oleum
H2S2O7 which is then diluted with water to form sulphuric acid
H2SO4.
SO3(g)+H2SO4(l) H2S2O7(l)
Oleum
H2S2O7(l)+ H2O(l) 2H2SO4(aq)
ii. The two reactions in stage3 are equivalent to adding sulphur
trioxide directly into water.
SO3(g)+H2O(l) H2SO4(aq)
iii. The addition of sulphur trioxide directly into is not carried
out because the reaction is vary vigorous; a lot of heat is given
off. As a result, alarge cloud of sulphuric acid fumes is
produced, which is corrosive and causes severe air pollution.
SULPHUR DIOXIDE AND
ENVIRONMENTAL
POLLUTION
1.Sulphur dioxide is one of the by-product of contact process. It is a
colourless and
poisonous gas with a vary pungent smell.
2.Sulphur dioxide which escape into the air causes air pollution.
3.Sulphur dioxide is an acidic which dissolves in water to form
sulphurous acidic, H2SO3.
In the atmosphere, sulphur dioxide dissolve in water droplets to
form sulphurous acidic.
SO2(g) + H2O(l) H2SO3(aq)
4.Oxidation of sulphur acid by oxygen produce sulphuric acid,
H2SO4, which falls to the
earth as acid rain. Sulphur trioxide is also easily oxidised in the air
to form sulphur
trioxide. Sulphur trioxide dissolve in rainwater to produce
sulphuric acid.
SO3(g) + H2O(l) H2SO4(aq)
AMMONIA AND ITS SALTS
(NH³)USES:
Ammonia is used in the production of liquid fertilizer
solutions which consist of ammonia, ammonium nitrate,
urea and aqua ammonia
Weak ammonia solutions are also widely used as
commercial and household cleaners and detergents.
Ammonia is used by the leather industry as a curing
agent, as a slime and mold preventative in tanning
liquors and as a protective agent for leathers and furs in
storage.
The pulp and paper industry uses ammonia for
pulping wood and as a casein dispersant in the coating
of paper.
As a degreasing agent in aqueous form to remove greasy
stains in the kitchen
PROPERTIES OF AMMONIA GAS
1.The physical properties of ammonia gas include the following:
i.It colourless and has a pungent odour.
ii.It is vary soluble in water and form a weak alkaline solution.
iii.It less dense then water.
iv.It easily liquified (at about 35.5°C) when cool.
2.The chemical properties of ammonia gas:
a) Ammonia gas dissolves in water to form a weak alkali.
NH3(g) + H2O(l)
NH4+(aq) + OH-(aq)
b) The presence of hydroxide icon causes the aqueous solution to
become alkaline. Thus aqueous ammonia solution:
i. Turns red litmus paper blue.
ii.Reacts with acid to form only salt and waterin neutralization
reaction.
NH3(aq) + HCI(aq) NH4CI(aq)
2NH3 + H2SO4(aq) (NH4)2SO4(aq)
iii. Reacts with solution of metallic cations to produce
precipitates.
Fe²+(aq) + 2OH(aq) Fe (OH)2(s)
INDUSTRIAL PROCESS IN THE MANUFACTURE OF
AMMONIA