Magnetocaloric and magnetovolume effects in Fe-based alloys Pablo Alvarez Alonso Department of Material Science and Metallurgic Engineering University of Oviedo 4 July 2011 P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 1 / 48
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Magnetocaloric and magnetovolume effects in Fe-based alloys
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Magnetocaloric and magnetovolume effects in Fe-based alloys
Pablo Alvarez Alonso
Department of Material Science and Metallurgic EngineeringUniversity of Oviedo
4 July 2011
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 1 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 2 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 2 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 2 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 2 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 3 / 48
Magnetocaloric effectOrigin
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 4 / 48
Magnetocaloric EffectDefinition and Theory
Total Entropy ofMetallic Gd underTwo AppliedMagnetic Fields.
Adiabatic TemperatureChange (∆Tadi ) of Gd
Magnetic EntropyChange for GdAl2
Maxwell RelationIsothermal Magnetic Entropy Change
∆SM (T ,H2)P,∆H =
∫ H2
H1
(∂M∂T
)P,H
dH
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 5 / 48
Magnetocaloric EffectDefinition and Theory
Total Entropy ofMetallic Gd underTwo AppliedMagnetic Fields.
Adiabatic TemperatureChange (∆Tadi ) of Gd
Magnetic EntropyChange for GdAl2
Maxwell RelationIsothermal Magnetic Entropy Change
∆SM (T ,H2)P,∆H =
∫ H2
H1
(∂M∂T
)P,H
dH
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 5 / 48
Magnetocaloric EffectDefinition and Theory
Total Entropy ofMetallic Gd underTwo AppliedMagnetic Fields.
Adiabatic TemperatureChange (∆Tadi ) of Gd
Magnetic EntropyChange for GdAl2
Maxwell RelationIsothermal Magnetic Entropy Change
∆SM (T ,H2)P,∆H =
∫ H2
H1
(∂M∂T
)P,H
dH
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 5 / 48
Magnetocaloric EffectDefinition and Theory
Total Entropy ofMetallic Gd underTwo AppliedMagnetic Fields.
Adiabatic TemperatureChange (∆Tadi ) of Gd
Magnetic EntropyChange for GdAl2
Maxwell RelationIsothermal Magnetic Entropy Change
∆SM (T ,H2)P,∆H =
∫ H2
H1
(∂M∂T
)P,H
dH
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 5 / 48
Magnetocaloric EffectMagnetic Refrigeration: Principles and Applications
Applications
ConsumerI Air conditioningI DehumidifiersI RefrigeratorsI Motor refrigerators
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 8 / 48
Magnetovolume Anomalies
Lattice Parameters a andc, and the cell volume Vvs T for Sm2Fe14B
Magnetovolume anomalies: Coupling betweenthe crystal lattice and the magnetism
Extrapolation from the Non-OrderedStateGruneisen relation
αnm (T ) =κΓCp (T )
3V
Magnetostriction
λa = (a− a0)/a0
λc = (c − c0)/c0
ωS = (V − V0)/V0
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 9 / 48
Magnetovolume Anomalies
Lattice Parameters a andc, and the cell volume Vvs T for Sm2Fe14B Magnetovolume anomalies: Coupling between
the crystal lattice and the magnetism
Extrapolation from the Non-OrderedStateGruneisen relation
αnm (T ) =κΓCp (T )
3V
Magnetostriction
λa = (a− a0)/a0
λc = (c − c0)/c0
ωS = (V − V0)/V0
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 9 / 48
Magnetovolume Anomalies
Lattice Parameters a andc, and the cell volume Vvs T for Sm2Fe14B Magnetovolume anomalies: Coupling between
the crystal lattice and the magnetism
Extrapolation from the Non-OrderedStateGruneisen relation
αnm (T ) =κΓCp (T )
3V
Magnetostriction
λa = (a− a0)/a0
λc = (c − c0)/c0
ωS = (V − V0)/V0
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 9 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 10 / 48
R2Fe17 alloysCrystal Structure
Rhombohedral Th2Zn17-type (R3m space group)
YCePrNdSmGdTbDy
Fe1(6c): <<Dumm-bell site>>Oriented along the c-axis
Hexagonal Th2Ni17-type (P63/mmc space group)
G
dTbDyHoErTmYbLuY
Fe1(4f): <<Dumm-bell site>>Oriented along the c-axis
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 11 / 48
R2Fe17 alloysCrystal Structure
Rhombohedral Th2Zn17-type (R3m space group)
YCePrNdSmGdTbDy
Fe1(6c): <<Dumm-bell site>>Oriented along the c-axis
Hexagonal Th2Ni17-type (P63/mmc space group)GdTbDyHoErTmYbLuY
Fe1(4f): <<Dumm-bell site>>Oriented along the c-axis
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 11 / 48
R2Fe17 alloysCrystal Structure
Rhombohedral Th2Zn17-type (R3m space group)
YCePrNdSmGdTbDy
Fe1(6c): <<Dumm-bell site>>Oriented along the c-axis
Hexagonal Th2Ni17-type (P63/mmc space group)GdTbDyHoErTmYbLuY
Fe1(4f): <<Dumm-bell site>>Oriented along the c-axis
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 11 / 48
R2Fe17 alloysCrystal Structure
Rhombohedral Th2Zn17-type (R3m space group)
YCePrNdSmGdTbDy
Fe1(6c): <<Dumm-bell site>>Oriented along the c-axis
Hexagonal Th2Ni17-type (P63/mmc space group)GdTbDyHoErTmYbLuY
Fe1(4f): <<Dumm-bell site>>Oriented along the c-axis
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 11 / 48
R2Fe17 alloysCrystal Structure
Rhombohedral Th2Zn17-type (R3m space group)
YCePrNdSmGdTbDy
Fe1(6c): <<Dumm-bell site>>Oriented along the c-axis
Hexagonal Th2Ni17-type (P63/mmc space group)GdTbDyHoErTmYbLuY
Fe1(4f): <<Dumm-bell site>>Oriented along the c-axis
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 11 / 48
R2Fe17 alloysMagnetovolume Anomalies and Magnetocaloric Effect in R2Fe17 alloys
Magnetovolume Anomalies: Causes
Dumb-bell sites
{DFe−Fe 6 2.45 A → Negative exchange InteractionsDFe−Fe ≥ 2.45 A → Positive exchange Interactions
Magnetovolume Anomalies: Effects
Magnetovolume Anomalies
{Anomalous thermal expansionNegative pressure dependence of TC
Magnetic PropertiesR2Fe17 alloys exhibit SOPT
TC arround RT
Large MS
Magnetocaloric Effect in R2Fe17 alloys
H. Chen et al., JM3
320 (2008) 1382-1384
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 12 / 48
R2Fe17 alloysMagnetovolume Anomalies and Magnetocaloric Effect in R2Fe17 alloys
Magnetovolume Anomalies: Causes
Dumb-bell sites
{DFe−Fe 6 2.45 A → Negative exchange InteractionsDFe−Fe ≥ 2.45 A → Positive exchange Interactions
Magnetovolume Anomalies: Effects
Magnetovolume Anomalies
{Anomalous thermal expansionNegative pressure dependence of TC
Magnetic PropertiesR2Fe17 alloys exhibit SOPT
TC arround RT
Large MS
Magnetocaloric Effect in R2Fe17 alloys
H. Chen et al., JM3
320 (2008) 1382-1384
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 12 / 48
R2Fe17 alloysMagnetovolume Anomalies and Magnetocaloric Effect in R2Fe17 alloys
Magnetovolume Anomalies: Causes
Dumb-bell sites
{DFe−Fe 6 2.45 A → Negative exchange InteractionsDFe−Fe ≥ 2.45 A → Positive exchange Interactions
Magnetovolume Anomalies: Effects
Magnetovolume Anomalies
{Anomalous thermal expansionNegative pressure dependence of TC
Magnetic PropertiesR2Fe17 alloys exhibit SOPT
TC arround RT
Large MS
Magnetocaloric Effect in R2Fe17 alloys
H. Chen et al., JM3
320 (2008) 1382-1384
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 12 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 13 / 48
FeZrBCu amorphous alloys
∆SM(T ) for Nanoperm alloys
V. Franco et al., J. Appl. Phys. 100 (2006) 064307
Fe-content variation of TC forNanoperm alloys
P. Alvarez et al., Intermetallics 18 (2010)2464-2467
Magnetic and Magnetocaloric PropertiesBroad Second Order Magnetic Phase Transition
Tunnable Curie Temperatures in the RT Regime
Moderate values of MS
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 14 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 15 / 48
Fabrication
Arc Furnace Melt Spinner
Furnace Ball-Mill
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 16 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 17 / 48
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 20 / 48
Magnetovolume Anomalies and Magnetocaloric Effect of R2Fe17compoundsCrystal and Magnetic Structure
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 32 / 48
Magnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties
2 Experimental TechniquesFabricationStructural and Magnetic Characterization
3 ResultsMagnetovolume Anomalies and Magnetocaloric effect of R2Fe17 compoundsMagnetocaloric Effect in Pseudobinary AxB2 -xFe17 alloysMagnetic Properties and Magnetocaloric Effect of Fe-based amorphous alloys
4 Conclusions
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 36 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysMagnetic Properties
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 37 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysMagnetocaloric Effect
A general view of ∆SM(T )curves for Nanoperm alloys
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 38 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysMagnetocaloric Effect
A general view of ∆SM(T )curves for Nanoperm alloys
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 38 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysMagnetocaloric Effect
RCP1(H) for FeZrBCu amorphousalloys
Metallic Gd (µ0H = 5 T)
RCP1 = 687 Jkg−1
RCP2 = 503 Jkg−1
RCP3 = 402 Jkg−1
Width of the ∆SM(T ) Curves
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 39 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysMagnetocaloric Effect
RCP1(H) for FeZrBCu amorphousalloys
Metallic Gd (µ0H = 5 T)
RCP1 = 687 Jkg−1
RCP2 = 503 Jkg−1
RCP3 = 402 Jkg−1
Width of the ∆SM(T ) Curves
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 39 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysMaster Curve
Master Curve for Fe86Zr7B6Cu1amorphous alloy
Comparation of the MasterCurves for the FeZrBCuamorphous alloys
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 40 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysMaster Curve
Master Curve for Fe86Zr7B6Cu1amorphous alloy
Comparation of the MasterCurves for the FeZrBCuamorphous alloys
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 40 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysComposite Compounds: an Effective way to Improve the RCP Via the ∆SM (T ) Broadening
Past: Low TemperatureMagnetic Composites
T. Hashimoto et al., J. Appl. Phys. 62 (9)(1987) 3873-3878
Recent: RCP Improvement aroundRT by Using Magnetic Composites
R. Caballero-Flores et al., Appl. Phys. Lett. 98 (2011) 102505
Further CommentsRCP Optimization for a Two-PhaseMagnetic Composite
Shape of ∆SM (T )
δTC
Weight Fraction of Both Phases
Applied Magnetic Field
The Maximum Refrigeration Efficiency isattained with Constant Magnetic EntropyChange curves.
A.M. Tishin and Y.I. Spichkin. Magnetocaloric Effectand Its Applications. Series in Condensed MatterPhysics, 1 edition (2003).
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 41 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysComposite Compounds: an Effective way to Improve the RCP Via the ∆SM (T ) Broadening
Past: Low TemperatureMagnetic Composites
T. Hashimoto et al., J. Appl. Phys. 62 (9)(1987) 3873-3878
Recent: RCP Improvement aroundRT by Using Magnetic Composites
R. Caballero-Flores et al., Appl. Phys. Lett. 98 (2011) 102505
Further CommentsRCP Optimization for a Two-PhaseMagnetic Composite
Shape of ∆SM (T )
δTC
Weight Fraction of Both Phases
Applied Magnetic Field
The Maximum Refrigeration Efficiency isattained with Constant Magnetic EntropyChange curves.
A.M. Tishin and Y.I. Spichkin. Magnetocaloric Effectand Its Applications. Series in Condensed MatterPhysics, 1 edition (2003).
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 41 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysComposite Compounds: an Effective way to Improve the RCP Via the ∆SM (T ) Broadening
Past: Low TemperatureMagnetic Composites
T. Hashimoto et al., J. Appl. Phys. 62 (9)(1987) 3873-3878
Recent: RCP Improvement aroundRT by Using Magnetic Composites
R. Caballero-Flores et al., Appl. Phys. Lett. 98 (2011) 102505
Further CommentsRCP Optimization for a Two-PhaseMagnetic Composite
Shape of ∆SM (T )
δTC
Weight Fraction of Both Phases
Applied Magnetic Field
The Maximum Refrigeration Efficiency isattained with Constant Magnetic EntropyChange curves.
A.M. Tishin and Y.I. Spichkin. Magnetocaloric Effectand Its Applications. Series in Condensed MatterPhysics, 1 edition (2003).
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 41 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysComposite Compounds: an Effective way to Improve the RCP Via the ∆SM (T ) Broadening
Past: Low TemperatureMagnetic Composites
T. Hashimoto et al., J. Appl. Phys. 62 (9)(1987) 3873-3878
Recent: RCP Improvement aroundRT by Using Magnetic Composites
R. Caballero-Flores et al., Appl. Phys. Lett. 98 (2011) 102505
Further CommentsRCP Optimization for a Two-PhaseMagnetic Composite
Shape of ∆SM (T )
δTC
Weight Fraction of Both Phases
Applied Magnetic Field
The Maximum Refrigeration Efficiency isattained with Constant Magnetic EntropyChange curves.
A.M. Tishin and Y.I. Spichkin. Magnetocaloric Effectand Its Applications. Series in Condensed MatterPhysics, 1 edition (2003).
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 41 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysA Concrete Two-Phase Composite based on amorphous FeZrCuB ribbons: EXAMPLE 1
∆SM(T ) curves of ComponentA (Fe90Zr9B1) and B (Fe87Zr6B6Cu1)
∆SM(T ) curves of the CompositeSystem 0.4 A + 0.6 B
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 42 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysA Concrete Two-Phase Composite based on amorphous FeZrCuB ribbons: EXAMPLE 2
∆SM (T ) for the two-ribbon system0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
Increase of δTFWHM for the Two-Phase System
0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
Resulting RCP for the Two-Phase System
0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
RCP ≈ 95% of Metallic Gd
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 43 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysA Concrete Two-Phase Composite based on amorphous FeZrCuB ribbons: EXAMPLE 2
∆SM (T ) for the two-ribbon system0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
Increase of δTFWHM for the Two-Phase System
0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
Resulting RCP for the Two-Phase System
0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
RCP ≈ 95% of Metallic Gd
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 43 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysA Concrete Two-Phase Composite based on amorphous FeZrCuB ribbons: EXAMPLE 2
∆SM (T ) for the two-ribbon system0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
Increase of δTFWHM for the Two-Phase System
0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
Resulting RCP for the Two-Phase System
0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
RCP ≈ 95% of Metallic GdP. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 43 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysFlattening of the ∆SM (T ) Curve
Flattening of ∆SM(T ) for the system0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 44 / 48
Magnetic Properties and Magnetocaloric Effect of Fe-based amorphousalloysFlattening of the ∆SM (T ) Curve
Flattening of ∆SM(T ) for the system0.5 A (Fe87Zr6B6Cu1) + 0.5 B (Fe90Zr8B2)
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 45 / 48
Conclusions
The R2Fe17 alloys cell volume decreases when the temperature is increased in themagnetically oredered state, with a minimum located around TC . The magnetostriction iscorrelated with the total Fe-magnetic moments.
The MCE depends on the magnetic structure:Ferromagnetic→ single-peak magnetic entropy change;Ferrimagnetic→ double-peak with opposite sign;Ce2Fe17 → double-peak with the same sign.
The Curie temperature is largely decreased with pressure ( dTCdP ≈ −10 K/kBar for Tm2Fe17
alloy).
The microstructure is modified by ball-milling without changes in either the magnetic norcrystal structures.Grain breaking (nanosized scale)→ Curie temperature distribution and wider |∆SM |(T )curves.
AxB2 -xFe17 alloys have been synthesized in the rhombohedral phase. The Curietemperatures, RCP and ∆SM are tuned combining different rare-earths.
Temperature of the maximum magnetic entropy change of FeZrBCu amorphous alloys istuned by changes in the %Fe. Spreading of the |∆SM |(T ) curve as wider as 230 K.
Optimizing the selection of both, the δTC of the two Nanoperm alloys which form a two-phasecomposite system and their relative weight fraction→ enhancement of the Relative CoolingPower due to the increase of δTFWHM of the ∆SM and flattening of the ∆SM (T ) curves (up to100 K for µ0∆H = 5 T).
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 46 / 48
GRACIAS POR VUESTRA ATENCION
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 47 / 48
Perspectives
Synthesize Y2Fe17 in both rhombohedral and hexagonal crystal structures, andGd2Fe17, Tb2Fe17 and Dy2Fe17 in hexagonal crystal structure.
Y2Fe17, Pr2Fe17 and Nd2Fe17 alloys exhibit the largest magnetic entropy change values→combination of these alloys or synthesis of PrNdFe17 pseudobinaries to optimize the MCEproperties.
Due to the change of the Tm2Fe17 Curie temperature with pressure, and that Tm2Fe17exhibits magnetovolume anomalies, it would exhibit a large magneto-barocaloric effect.
Ball-milling provokes a broadening of the magnetic transitions→ The Tm2Fe17spin-reorientation would not occur over a critical pressure→ Study the MCE when themagnetic anisotropy is along the uniaxial direction.
Measure the temperature dependence of the heat capacity in FeZrBCu alloys to determinethe adiabatic temperature change. Optimize the total entropy of combined two-ribbonssystems to enhance the adiabatic temperature change.
P. Alvarez (University of Oviedo) MCE and magnetovolume effects in Fe-based alloys 04/07/11 48 / 48