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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION Mike See Ph.D. Bayer CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 n r, o APRI 4 2D1I Dear Dr. See: Subject: Increased Application Rate to Soybeans Liberty 280 SL Herbicide EPA Registration No. 264-829 Your Application Dated August 24, 2010 The amendment referred to above, submitted in connection with registration under section 3(c)(7)(A) of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA), is acceptable provided that you: 1. Submit/cite all data required for registration/reregistration of your product under FIFRA section 3(c)(5) or 4(a) when the Agency requires all registrants of similar products to submit such data. 2. Submit one (1) copy of your final printed labeling before you release the product for shipment. If these conditions are not complied with, the registration will be subject to cancellation in accordance with FIFRA section 6(e). Your release for shipment of the product bearing the amended labeling constitutes acceptance of these conditions. A stamped copy of the label is enclosed for your records. If you have any questions concerning this letter please contact Mr. James Stone at 703-305-7391. Sincerely yours, Kathryn V. Montague Product Manager (23) Herbicide Branch Registration Division (7505P) Enclosure
20

Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

Mar 16, 2018

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Page 1: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHINGTON, D.C. 20460

OFFICE OF CHEMICAL SAFETYAND POLLUTION PREVENTION

Mike See Ph.D.Bayer CropScience LPP.O. Box 12014, 2 T.W. Alexander DriveResearch Triangle Park, NC 27709

n r, o APR I 4 2D1IDear Dr. See:

Subject: Increased Application Rate to SoybeansLiberty 280 SL HerbicideEPA Registration No. 264-829Your Application Dated August 24, 2010

The amendment referred to above, submitted in connection with registration undersection 3(c)(7)(A) of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA), isacceptable provided that you:

1. Submit/cite all data required for registration/reregistration of your product underFIFRA section 3(c)(5) or 4(a) when the Agency requires all registrants of similar products tosubmit such data.

2. Submit one (1) copy of your final printed labeling before you release the product forshipment. If these conditions are not complied with, the registration will be subject tocancellation in accordance with FIFRA section 6(e). Your release for shipment of the productbearing the amended labeling constitutes acceptance of these conditions.

A stamped copy of the label is enclosed for your records.

If you have any questions concerning this letter please contact Mr. James Stoneat 703-305-7391.

Sincerely yours,

Kathryn V. MontagueProduct Manager (23)Herbicide BranchRegistration Division (7505P)

Enclosure

Page 2: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

r

Liberty® 280 SL HERBICIDEA non-selective herbicide for post emergence broadcast use on canola, corn, cotton, and soybean designated asLibertyLink®. Liberty 280 SL Herbicide may be used for weed control in non- LibertyLink® cotton when applied with ahooded sprayer in-crop. Liberty 280 SL Herbicide may also be applied as a broadcast burndown application beforeplanting or prior to emergence of any conventional or transgenic variety of canola, corn, cotton, rice, soybean or sugarbeet. Liberty 280 SL Herbicide may be used for post emergence weed control in apples, berries, grapes, and tree nuts.Liberty 280 SL Herbicide may also be applied for potato vine desiccation.

OTHER INGREDIENTS: 75.5%

*CAS Number 77182-82-2 TOTAL 100.00%"Equivalent to 2.34 pounds of active ingredient per U.S. gallon.

EPA Reg No. 264-829 EPA Est. No. 264-MI-001

EPA Est. No. 407-IA-2

KEEP OUT OF REACH OF CHILDRENWARNING - AVISO

Si usted no entiende la etiqueta, busque a alguien para que se la explique a us ted en detalle.(If you do not understand the label, find someone to explain it to you in detail.)

For MEDICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577

For PRODUCT USE Information Call 1-866-99BAYER (1-866-992-2937)

FIRST AID

IF IN EYES:

IF ON SKIN OR CLOTHING:

IF SWALLOWED:

• Hold eye open and rinse slowly and gently with water for 15-20 minutes.

• Remove contact lenses, if present, after the first 5 minutes, then continue rinsing ey^e.

• Get medical attention if irritation develops or persists.

• Take off contaminated clothing.

• Wash skin immediately with plenty of soap and water.

• Get medical attention.

• Rinse mouth thoroughly with plenty of water.

• Do not induce vomiting.

• Get medical attention immediately.HOT LINE NUMBER: Have the product container or label with you when calling a poison controltreatment. Call 1-800-334-7577 for emergency medjcal treatment information. .NOTE TO PHYSICIAN: If this product is ingested, endotracheal intubation and gastric lavagepossible, followed by charcoal and sodium sulfate administration. Additionally, call 1-800-334-7577

A n n i P rr i D'APR 1 4 20V1

Under the 5?efe?sl Insecticide,B'tmateida, sad Hodeniicide Act,••u* ~ffli«:;cedv fiff to.e pesticida

fS^f&^~%2C\center or doctor, or when going for

should be performed as soon asimmediately for further information.

PRECAUTIONARY STATEMENTS

HAZARDS TO HUMANS AND DOMESTIC ANIMALS

WARNINGMay be fatal if absorbed through skin. Causes substantial but temporary eye injury. Harmful if swallowed. Do not get in eyes, on skin,or on clothing. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

Personal Protective Equipment (PPE)Some materials that are chemical-resistant to this product are listed below. If you want moreppjions, follow the ^instructions for (

category C on an EPA chemical resistance category selection chart. „ * ( j < i' " "• pe

M-388802-01-1

Page 3: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

?>oewApplicators and other handlers must wear:

Coveralls worn over short-sleeved shirt and short pants; chemical-resistant gloves such as barrier laminate, butyl rubber >14 mils, nitrilerubber >14 mils, neoprene rubber >14 mils, polyvinyl chloride (PVC) >14 mils, orViton® >14 mils; chemical resistant footwear plussocks; protective eyewear (goggles, face shield or safety glasses). Wear a chemical resistant apron when mixing/loading and cleaningequipment.

Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product's concentrate. Donot reuse them. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables exist, usedetergent and hot water. Keep and wash PPE separately from other laundry.

Mixers/loaders supporting aerial applications must wear a dust/mist filtering respirator (MSHA/NIOSH approval number prefix TC-21C),or a NIOSH approved respirator with any N, R, P or HE filter.

Engineering control statement:

When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets the requirements listed in the Worker Protection

Standard (WPS) for agricultural pesticides [40 CFR 170.240(d) (4-6)], the handler PPE requirements may be reduced or modified asspecified in the WPS.

USER SAFETY RECOMMENDATIONSUsers should:Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet.Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, washthoroughly and change into clean clothing.

ENVIRONMENTAL HAZARDS

Do not apply directly to water or to areas where surface water is present. Do not apply to intertidal areas below the mean high watermark. Do not contaminate water by cleaning of equipment or disposal of equipment wash waters.

This pesticide is toxic to vascular plants and should be used strictly in accordance with the drift and run-off precautions on this label inorder to minimize off-site exposures.

Under some conditions, this product may have a potential to run-off to surface water or adjacent land. Where possible, use methodswhich reduce soil erosion, such as no till, limited till and contour plowing; these methods also reduce pesticide run-off. Use ofvegetation filter strips along rivers, creeks, streams, wetlands, etc. or on the downhill side of fields where run-off could occur tominimize water runoff is recommended.

STORAGE AND DISPOSAL

Do not contaminate water, food, or feed by storage or disposal.

PESTICIDE STORAGE: Do not use or store near heat or open flame. Keep the container tightly closed and dry in a cool, well-ventilated place. Storage temperature should not exceed 125°F. If storage temperature for bulk Liberty® 280 SL Herbicide is below32°F, the material should not be pumped until its temperature exceeds 32° F. Protect against direct sunlight.

PESTICIDE DISPOSAL: Wastes resulting from the use of this product may be disposed of on-site or at an approved waste disposalfacility.

CONTAINER DISPOSAL:

[Rigid, Non-refillable containers small enough to shake (i.e., with capacities equal to or less than 5 gallons)]Non-refillable container. Do not reuse or refill this container. Offer for recycling, if available. Triple rinse container (or equivalent)promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10seconds after the flow begins to drip. Fill the container 1/4 full with water and recap. Shake for 10 seconds. Pour rinsate into applicationequipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat thisprocedure two more times. Once container is rinsed, then offer for recycling or reconditioning; or puncture and dispose of in a sanitarylandfill, or by incineration; or, if allowed by State and local authorities, by burning. If burned, stay out of smoke.

[All refutable container types (containers with capacities greater than 50 Ibs)]Refillable container. Refill this container with pesticide only. Do not reuse this container for any other purpose. Cleaning before refillingis the responsibility of the refiller. This is a sealed returnable container to be used only for Liberty® 280 SL Herbicide. When thiscontainer is empty, it must not be opened, cleaned, or discarded. Empty containers must be returned to the original purchase location.

[Bottom discharge Intermediate Bulk Container (IBC) (containers with capacities greater than 50 Ibs)]

Refillable container. Refill this container with pesticide only. Do not reuse this container for any other purpose. Cleaning before refillingis the responsibility of the refiller. Pressure rinsing the container before final disposal is the responsibility of the person disposing of thecontainer. Empty the remaining contents from the Intermediate Bulk container (IBC) into application equipment or mix tank. Raise thebottom of the IBC by 1.5 inch on the side which is opposite of the bottom discharge valve to promote more complete product removal.Completely remove the top lid of the IBC. Use water pressurized to at least 40 PSI to rinse all interior portions. Continuously pump ordrain rinsate into application equipment or rinsate collection system while pressure rinsing. Continue pressure rinsing for 2 minutes oruntil rinsate becomes clear. Replace the lid and close bottom valve. Contact your Ag retailer or Bayer CropScience for container return,disposal and recycling recommendations.

Page 4: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

DIRECTIONS FOR USEIt is a violation of Federal law to use this product in a manner inconsistent with its labeling.

Do not use this product until you have read the entire label. Do not apply this product in a way that will contact workers or otherpersons, either directly or through drift. Only protected handlers may be in the area during application.

For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation.

In the State of New York Only: Not For Use In Nassau and Suffolk Counties.

AGRICULTURAL USE REQUIREMENTS

Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. This Standard containsrequirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses; and handlers of agriculturalpesticides. It contains requirements for training, decontamination, notification, and emergency assistance. It also contains specificinstructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE), and restricted-entryintervals. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard.Do not enter or allow worker entry into treated areas during the restricted entry-interval (REI) of 12 hours.

PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact withanything that has been treated, such as plants, soil, or water, is: coveralls worn over short-sleeved shirt and short pants; chemicalresistant gloves such as barrier laminate, butyl rubber >14 mils, nitrile rubber >14 mils, neoprene rubber >14 mils, polyvinyl chloride(PVC) >14 mils, orViton® >14 mils; chemical resistant footwear plus socks; protective eyewear (goggles, face shield or safety glasses).

IMPORTANT CROP SAFETY INFORMATION

READ BEFORE USING THIS PRODUCT

Liberty 280 SL Herbicide may be applied as a burndown treatment prior to planting or prior to emergence of any conventional ortransgenic variety of canola, corn, cotton, rice, soybean or sugar beet.

Post emergence row crop applications of Liberty 280 SL Herbicide may be made only to crops tolerant to the active ingredient in thisproduct. Bayer CropScience does not warrant the use of this product on crops other than those designated as LibertyLink to safelywithstand the application of Liberty 280 SL Herbicide.

The basis of selectivity of Liberty 280 SL Herbicide in crops is the presence of a gene in LibertyLink crops which results in a plant that istolerant to the active ingredient of Liberty 280 SL Herbicide. Crops not containing this gene will not be tolerant to Liberty 280 SLHerbicide and severe crop injury and/or death may occur. Do not allow spray to contact foliage or green tissue of desirable vegetationother than crops tolerant to the active ingredient in this product.

Liberty 280 SL Herbicide may be applied to conventional or other transgenic cotton not tolerant to the active ingredient in Liberty 280SL Herbicide using a hooded sprayer.

Applications to apples, berries, tree nuts, and vines should avoid contact of Liberty 280 SL Herbicide solution, spray, drift or mistwith green bark, stems, or foliage, as injury may occur to trees, berries and vines. Only trunks with callused, mature brown bark shouldbe sprayed unless protected from spray contact by nonporous wraps, grow tubes or waxed containers. Contact of Liberty 280 SLHerbicide with parts of trees, berries or vines other than mature brown bark can result in serious damage.

INFORMATIONLiberty 280 SL Herbicide is a water-soluble herbicide for application as a foliar spray for the control of a broad spectrum of emergedannual and perennial grass and broadleaf weeds in LibertyLink® canola, LibertyLink® corn, LibertyLink® cotton, and LibertyLink®soybean, and in apples, berries, grapes, and tree nuts. Liberty 280 SL Herbicide may also be applied for potato vine desiccation.Liberty 280 SL Herbicide may also be applied as a broadcast burndown application before planting or prior to emergence of anyconventional or transgenic variety of canola, corn, cotton, rice, soybean or sugar beet.

Liberty 280 SL Herbicide is only foliar-active with little or no activity in soil. Weeds that emerge after application will not be controlled.Apply Liberty 280 SL Herbicide to actively growing weeds as described in the Weed Control Recommendations for Row Crops sectionto get maximum weed control. Uniform, thorough spray coverage is necessary to achieve consistent weed control. Necrosis of leavesand young shoots occur within 2 to 4 days after application under good growing conditions.

• Liberty 280 SL Herbicide is rainfast four (4) hours after application to most weed species; therefore, rainfall within four (4)hours may necessitate retreatment or may result in reduced weed control.

• Applications should be made between dawn and 2 hours before sunset to avoid the possibility of reduced lambsquarters andvelvetleaf control.

• Weed control may be reduced if application is made when heavy dew, fog and mist/rain are present; or when weeds are understress due to environmental conditions such as drought, cool temperatures or extended periods of cloudiness.

• To maximize weed control, do not cultivate from 5 days before an application to 7 days after an application.

Page 5: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

ROTATIONAL CROP RESTRICTIONS*

Rotational crop planting intervals following application of Liberty 280 SL Herbicide are listed below. Failure to comply With theserestrictions may result in illegal residues in rotated crops.

Rotational Crop

Canola, Corn, Cotton, Rice, Soybeans, and Sugarbeets

Root and Tuber Vegetables, Leafy Vegetables,Brassica Leafy Vegetables and Small Grains (barley,buckwheat, oats, rye, teosinte, triticale, and wheat).

All Other Crops

Plant Back Interval (Minimum Rotational Crop PlantingInterval from Last Application)

May be planted at any time

70 Days

180 Days

*See Application Directions for Potato Vine Desiccation for Rotational Crop Restrictions specifically after Liberty 280 SL Herbicideapplications to potatoes.

WEED CONTROL RECOMMENDATIONS FOR ROW CROPSRates in ounces of formulated product per acre for the control of weeds at selected heights are shown in the weed control tables. Inweed populations with mixed species, apply at a rate needed for the species that requires the highest rate.

Broadleaf Weed ControlMaximum Weed Height

or Diameter

Weed Species! Amaranth, Palmer2

Anoda, spurredBeggarweed, FloridaBlack medicBlueweed, TexasBuckwheat, wildBuffaloburBurcucumberCatchweed bedstraw(cleavers)CarpetweedChickweed, commonCocklebur, commonCopperleaf, hophornbeamCotton, volunteer1

Croton, tropicCroton, woollyEcliptaDevil's clawFleabane, annualGalinsoga, hairyGalinsoga, small flowerGroundcherry, cutleafGeranium, cutleafHempnettleHorsenettle, Carolina3

JimsonweedKnotweedKochia2

Ladysthumb" Lambsquarters, common2

Mallow, commonMallow, VeniceMarestail3

i (In22floz/A

33455666

2

46646324266644426346446S

:hes)29 fl OZ/A*"

455777710

4

68146854648875664105614668

6-12

Weed SpeciesMorningglory, smallflower2

Morningglory, tall2

Mustard, wildNightshade, blackNightshade, eastern blackNightshade, hairyPennycress (stinkweed)Pigweed, redroot2

Pigweed, prostrate2

Pigweed, spiny2

Pigweed, smooth2

Pigweed, tumble2

PuncturevinePurslane, commonPusley, FloridaRagweed, commonRagweed, giantSenna coffeeSesbania, hempShepherd's-PurseSicklepod (Java bean)Sida, pricklySmartweed, PennsylvaniaSmellmelonSowthistle, annualSoybeans, volunteer1

Spurge, prostrateSpurge, spottedStarbur, bristlySunflower, commonSunflower, prairieSunflower, volunteerThistle, Russian3

Maximum 1or Di

22floz/A46446643

3

33342S66466446466224636S

Weed Heightameterihes)

29 fl oz/A*68668864

4

44464

31012688651468844614510

6-12

Page 6: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

Broadleaf Weed Control!

i

Weed Species; Marshelder, annual| Morningglory, entireleaf2

', Morningglory, ivyleaf2

' Morningglory, pitted2

, Morningglory, sharppod2

Maximum Weed Heightor Diameter

(Inches^22 fl oz/A 29floz/A'b

4 66 86 86 82 4

Weed SpeciesVelvetleaf2

Waterhemp, common2

Waterhemp, tall2

Maximum Weed Heightor Diameter

L - i!"?hes)22floz/A 29 fl or/A*6

3 44 54 5 j

In cotton, Liberty 280 SL Herbicide may be applied at 29 fl oz/A three times per season.Do not apply more than 22 fl oz/A of Liberty 280 SL Herbicide post emergence in a single application to canola and corn.Indicates suppressionVolunteer LibertyLink crops from the previous season will not be controlled.For applications to corn, tank mixing with atrazine may enhance weed control of this species.May require sequential applications for control.

Grass Weed ControlMaximum Weed Height

or Diameter(Inches)

Weed SpeciesBarley, volunteer3

Barnyardgrass

| Bluegrass, annual

Corn, volunteer1

Crabgrass, large2

Crabgrass, smooth2

Cupgrass, woolly

Foxtail, bristlyFoxtail, giantFoxtail, greenFoxtail, robust purple

Foxtail, yellow2

Goosegrass3

22 fl oz/A33

3

10

3

3

6

6666

3

2

29 fl or/A*45

5

12

5

512

812128

4

3

Weed SpeciesMillet, wild-prosoMillet, proso volunteerOat, wild2

Panicum, fall

Panicum, Texas

Rice, redRice, volunteer1

Sandbur, field2

ShattercaneSignalgrass, broadleafSprangletop

Sorghum, volunteer

Stinkgrass

Maximum Weed Heightor Diameter

(Inches)22 fl oz/A

66

3

3

4

4

4

S

6

3

4

6

4

29 fl oz/A*b

7 !7

4

5 ,

6

6 ,

6 !

2 ,

8 .

5

6

8 ,

6Johnsongrass, seedling Wheat, volunteer2

Junglerice Witchgrass

* In cotton, Liberty 280 SL Herbicide may be applied at 29 fl oz/A three times per season.b Do not apply more than 22 fl oz/A of Liberty 280 SL Herbicide post emergence to canola and corn.S Indicates suppression1 Volunteer LibertyLink crops from the previous season will not be controlled. A timely cultivation 7 to 10 days after an application and/or

retreatment 10-21 days after the first application is recommended for controlling dense clumps of volunteer com or rice.2 For best control of yellow foxtail, field sandbur, crabgrass, and wild oats, treat prior to tiller initiation.3 A sequential application may be necessary for control.

Page 7: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

)Biennial and Perennial Weeds

For control of the biennial and perennial weeds listed below, tank mix partners or sequential applications of Liberty280 SL Herbicide are recommended (22 fl oz/A followed by 22 fl oz/A).

AlfalfaArtichoke, JerusalemBermudagrassBindweed, fieldBindweed, hedgeBluegrass, KentuckyBlueweed, TexasBromegrass, smoothBurdockBursage, woolyleafChickweed, Mouse-ear

Clover, AlsikeClover, redDandelionDock, smoothDogbane, hemp*Goldenrod, gray*Johnsongrass, rhizomeMilkweed, common*Milkweed, honeyvine*Muhly, wirestem*Nightshade, silverleaf

Nutsedge, purple*Nutsedge, yellow*OrchardgrassPoinsettia, wildPokeweedQuackgrass*Sowthistle, perennialThistle, bullThistle, CanadaTimothy*Wormwood, biennial

*Suppression Only

APPLICATION AND MIXING PROCEDURESGround Application: Liberty 280 SL Herbicide should be applied broadcast in a minimum of 15 gallons of water per acre. Under denseweed/crop canopies, 20 to 40 gallons of water per acre should be used so that thorough spray coverage will be obtained. Apply Liberty280 SL Herbicide using nozzles and pressures that generate MEDIUM (about 250 to 350 microns) spray droplets category as reportedby the nozzle manufacturer and in accordance to ASABE S 572. Do not use nozzles and pressures that result in COARSE sprays.FINE sprays should also be avoided to minimize spray drift risk. Boom height should be based on nozzle manufacturerrecommendations. See the Spray Drift Management section of this label for additional information on proper application of Liberty 280SL Herbicide.

Aerial Application: Poor coverage will result in reduced weed control. For optimal weed control, apply Liberty 280 SL Herbicide in aminimum of 10 gallons per acre. Apply Liberty 280 SL Herbicide using nozzles and pressures that generate MEDIUM (about 300 to 400microns) spray droplets category as reported by the nozzle manufacturer and in accordance to ASABE S 572 based upon the selectedair speed. Do not use nozzles and pressures that result in COARSE sprays. FINE sprays should also be avoided to minimize spray driftrisk. See the Spray Drift Management section of this label for additional information on proper application of Liberty 280 SL Herbicide.

COMPATIBILITY TESTING

If Liberty 280 SL Herbicide is to be mixed with pesticide products not listed on this label, test the compatibility of the intended tankmixture prior to mixing the products in the spray tank. The following procedure assumes a spray volume of 25 gallons per acre. Forother spray volumes, adjust the amount of the water used accordingly. Check compatibility as follows:

1. Place 1.0 pint of water from the source that will be used to prepare the spray solution in a clear 1 -quart jar.2. For each pound of a dry tank mix partner to be applied per acre, add 1.5 teaspoons to the jar.3. For each 16 fl oz of a liquid tank mix partner to be applied per acre, add 0.5 teaspoon to the jar.4. For each 16 fl oz of Liberty 280 SL Herbicide to be applied per acre, add 0.5 teaspoon to the jar.5. After adding all the ingredients, place a lid on the jar and tighten. Invert 10 times to mix.6. Let the mixture stand for 15 minutes, and evaluate the solution for uniformity and stability. Look for separation, large flakes,

precipitates, gels, heavy oily film on the jar, or other signs of incompatibility. If the tank mix partners are not compatible, do notuse the mixture in a spray tank.

7. After compatibility testing is complete, dispose of any pesticide wastes in accordance with the Storage and Disposal section ofthis label.

Page 8: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

MIXING INSTRUCTIONS

Tank Mix Recommendations: Liberty® 280 SL Herbicide may be applied in tank mix combinations with labeled rates of otherproducts provided these other products are labeled for the timing and method of application for the crop to be treated. The tank mixpartner must be used in accordance with the label limitations and precautions. No label dosage rates may be exceeded. Liberty® 280SL Herbicide cannot be mixed with any product containing a label prohibition against such mixing. Refer to the specific crop section forrate recommendations and other restrictions.

Liberty 280 SL Herbicide must be applied with properly calibrated and clean equipment. Liberty 280 SL Herbicide is formulated to mixreadily in water. Prior to adding Liberty 280 SL Herbicide to the spray tank, ensure that the spray tank is thoroughly clean, particularly ifa herbicide with the potential to injure crops was previously used (see Cleaning Instructions).

Mix Liberty 280 SL Herbicide with water to make a finished spray solution as follows:1. Fill the spray tank half full with water.2. Start agitation.3. If mixing with a flowable/wettable powder tank mix partner. Prepare a slurry of the proper amount of the product in a small

amount of water. Add the slurry to the spray tank4. Add the appropriate amount of ammonium sulfate (AMS) to the spray tank.5. If mixing with a liquid tank mix partner, add the liquid mix partner next.6. Complete filling the spray tank with water.7. Add the proper amount of Liberty 280 SL Herbicide and continue agitation.8. If foaming occurs, use a silicone-based antifoam agent.

Ensure that all spray system lines including pipes, booms, etc. have the correct concentration of spray solution by flushing out the spraysystem lines before starting the crop application.

If tank mix partners recommended on this label are added, maintain good agitation at all times until contents of the tank are sprayed. Ifthe spray mixture is allowed to settle, thorough agitation is required to resuspend the mixture before spraying is resumed. Keep bypassline on or near bottom of tank to minimize foaming. Screen size in nozzles or line strainers must be 50 mesh or larger.

CLEANING INSTRUCTIONS

Before using Liberty 280 SL Herbicide, thoroughly clean bulk storage tank, refillable tank, nurse tanks, spray tank, lines, and filter,particularly if a herbicide with the potential to injure crops was previously used. Equipment should be thoroughly rinsed using acommercial tank cleaner.

After using Liberty 280 SL Herbicide, triple rinse the spray equipment and clean with a commercial tank cleaner before using for cropsnot labeled LibertyLink. Make sure any rinsate or foam is thoroughly removed from spray tank and boom. Rinsate may be disposedfollowing the pesticide disposal directions on this label.

SPRAY DRIFT MANAGEMENT

Spray drift may result in injury to non target crops or vegetation. To avoid spray drift, do not apply when wind speed is greater than 10MPH or during periods of temperature inversions. Do not apply when weather conditions, wind speed, or wind direction may causespray drift to non-target areas. AVOIDING SPRAY DRIFT AT THE APPLICATION SITE IS THE RESPONSIBILITY OF THEAPPLICATOR.

• All aerial and ground application equipment must be properly maintained and calibrated using appropriate carriers.• For all non-aerial applications, wind speed must be measured adjacent to the application site, on the upwind side, immediately

prior to application.

Sensitive Areas: The pesticide should only be applied when the potential for drift to adjacent sensitive areas (e.g., residential areas,bodies of water, known habitats for threatened or endangered species, non-target crops) is minimal (e.g., when wind is blowing awayfrom the sensitive areas).

Do not apply under circumstances where possible drift to unprotected persons or to food, forage, or other plantings that might bedamaged or crops thereof rendered unfit for sale, use or consumption can occur.

Aerial Drift Management: The following drift management requirements must be followed to avoid off-target drift movement from aerialapplications to agricultural field crops.

1. The distance of the outer most nozzles on the boom must not exceed 3/4 the length of the wingspan or rotor.2. Nozzles must always point backward parallel with the air stream and never be pointed downwards more than 45 degrees.

Where states have more stringent regulations, they should be observed. The applicator should be familiar with and take into accountthe information covered in the Aerial Drift Reduction Advisory Information.

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AERIAL DRIFT REDUCTION ADVISORY INFORMATION

Information on Droplet Size: The most effective way to reduce drift potential is to apply large droplets. The best drift managementstrategy is to apply the largest droplets that provide sufficient coverage and control. Applying larger droplets reduces drift potential, butwill not prevent drift if applications are made improperly, or under unfavorable environmental conditions (see Wind, Temperature andHumidity, and Temperature Inversions below). AVOIDING SPRAY DRIFT AT THE APPLICATION SITE IS THE RESPONSIBILITY OFTHE APPLICATOR.

Controlling Droplet Size:

• Volume - Use high flow rate nozzles to apply the highest practical spray volume. Nozzles with higher rated flows produce largerdroplets.

• Pressure - Do not exceed the nozzle manufacturer's recommended pressures. For many nozzle types lower pressure produceslarger droplets. When higher flow rates are needed, use higher flow rate nozzles instead of increasing pressure.

• Number of nozzles - Use the minimum number of nozzles that provide uniform coverage.

• Nozzle Orientation - Orienting nozzles so that the spray is released parallel to the airstream produces larger droplets thanother orientations and is the recommended practice. Significant deflection from horizontal will reduce droplet size and increasedrift potential.

• Nozzle Type - Use a nozzle type that is designed for the intended application. With most nozzle types, narrower spray anglesproduce larger droplets. Consider using low-drift nozzles. Solid stream nozzles oriented straight back produce the largestdroplets and the lowest drift.

• Boom Length: For some use patterns, reducing the effective boom length to less than 3/4 of the wingspan or rotor length mayfurther reduce drift without reducing swath width.

• Application Height: Applications should not be made at a height greater than 10 feet above the top of the largest plants unlessa greater height is required for aircraft safety. Making applications at the lowest height that is safe reduces exposure of dropletsto evaporation and wind.

Swath Adjustment: When applications are made with a crosswind, the swath will be displaced downward. Therefore, on the up anddownwind edges of the field, the applicator must compensate for this displacement by adjusting the path of the aircraft upwind. Swathadjustment distance should increase, with increasing drift potential (higher wind, smaller drops, etc.)

Wind: Drift potential is lowest between wind speeds of 2 -10 mph. However, many factors, including droplet size and equipment typedetermine drift potential at any given speed. Applications should be avoided below 2 miles per hour due to variable wind direction andhigh inversion potential. NOTE: Local terrain can influence wind patterns. Every applicator should be familiar with local wind patternsand how they affect spray drift.

Temperature and Humidity: When making applications in low relative humidity, set up equipment to produce larger droplets tocompensate for evaporation. Droplet evaporation is most severe when conditions are both hot and dry. Avoid spraying duringconditions of low humidity and/or high temperatures.

Temperature Inversions: Do not make aerial or ground applications into areas of temperature inversions. Temperature inversionsrestrict vertical air mixing, which causes small suspended droplets to remain in a concentrated cloud. This cloud can move inunpredictable directions due to the light variable winds common during inversions. Temperature inversions are characterized byincreasing temperatures with altitude and are common on nights with limited cloud cover and light to no wind. They begin to form as thesun sets and often continue into the morning. Their presence can be indicated by ground fog; however, if fog is not present, inversionscan also be identified by the movement of smoke from a ground source or an aircraft smoke generator. Smoke that layers and moveslaterally in a concentrated cloud (under low wind conditions) indicates an inversion, while smoke that moves upward and rapidlydissipates indicates good vertical air mixing.

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APPLICATION DIRECTIONS FOR BURNDOWN USELiberty 280 SL Herbicide may be applied as a burndown treatment prior to planting or prior to emergence of any conventional ortransgenic variety of canola, corn, cotton, rice, soybean or sugar beet. Apply a minimum of 29 fl oz/A of Liberty 280 SL Herbicide forburndown of existing weeds just prior to planting or prior to emergence of canola, corn, cotton, rice, soybean, or sugar beets. For bestresults, apply to emerged, young, actively growing weeds. Warm temperatures, high humidity, and bright sunlight improve theperformance of Liberty 280 SL Herbicide. Weed control may be reduced when applications are made to weeds under stress due todrought or cool temperatures.

• In cotton, if environmental conditions prevent timely applications, a single application may be made of up to 43 fl oz/A of Liberty280 SL Herbicide. If more than 29 fl oz/A are used in any single application, the season total may not exceed 72 fl oz/A,including all application timings.

• In soybean, if environmental conditions prevent timely applications, a single application may be made of up to 36 fl oz/A ofLiberty 280 SL Herbicide.. If 29-36 fl oz/A are used in a single burndown application, one additional in-seasonapplication may be made at up to 29 fl oz/A. The season total may not exceed 65 fl oz/A, including all applicationtimings.

• In canola, corn, rice and sugar beets, if environmental conditions prevent timely applications, a single application may bemade of up to 36 fl oz/A of Liberty 280 SL Herbicide. No additional applications of Liberty 280 SL Herbicide may be madepost emergence to the crop during the growing season.

Cotton Use Pattern 1

Cotton Use Pattern 2

Soybean Use Pattern

Canola, Corn, Rice,Sugar beets

Burndown

29 fl oz/A

30-43 fl oz/A

29-36 fl oz/A

29-36 fl oz/A

In-Season Applications

2 applications at 22-29 floz/A

1 application at 22-29 fl oz/A

1 application at 22-29 fl oz/A

None

Season Max

87 fl oz/A

72 fl oz/A

65 fl oz/A

36 fl oz/A

APPLICATION DIRECTIONS FOR USE ON CANOLAApply Liberty 280 SL Herbicide only to canola labeled as LibertyLink. Uniform, thorough spray coverage is necessary to achieveconsistent weed control.

APPLICATION RATE AND TIMING

For best results, apply to emerged, young, actively growing weeds. Warm temperatures, high humidity, and bright sunlight improve theperformance of Liberty 280 SL Herbicide. Weed control may be reduced when applications are made to weeds under stress due todrought or cool temperatures. For optimal yield, early season weed removal is important.

Applications of Liberty 280 SL Herbicide on canola may be made from the cotyledon stage up to the early bolting stage of the canola.Slight discoloration of the canola may be visible after application. This effect is temporary and will not influence crop growth, maturity oryield

Apply Liberty 280 SL Herbicide at 22 fl oz/A per application. A second application of Liberty 280 SL Herbicide may be needed to controlweeds that have not yet emerged at the time of application.

RESTRICTIONS TO THE DIRECTIONS FOR USE ON CANOLA

• DO NOT use on canola in the states of Alabama, Delaware, Georgia, Kentucky, Maryland, New Jersey, North Carolina, SouthCarolina, Tennessee, Virginia and West Virginia.

• DO NOT apply more than two applications of Liberty 280 SL Herbicide per growing season. Sequential applications should beat least 10-14 days apart.

• DO NOT apply Liberty 280 SL Herbicide within 65 days of harvesting canola.

• DO NOT apply more than 44 fl oz/A of Liberty 280 SL Herbicide per growing season.

• If Liberty 280 SL Herbicide was used in a burndown application, no post emergence applications may be applied to the crop.

• DO NOT graze the treated crop or cut for hay.

• DO NOT apply Liberty 280 SL Herbicide if canola shows injury from prior herbicide applications or environmental stress(drought, excessive rainfall, etc.).

• DO NOT apply this product through any type of irrigation system.

• Refer to the "Rotational Crop Restrictions" section under the "Information" heading of this label for the appropriate rotationalcrop plant back intervals.

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< ') (.SPRAY ADDITIVES

Liberty 280 SL Herbicide must be applied with ammonium sulfate (AMS). Use only fine feed grade or spray grade AMS at 3 pounds peracre. Anti-foams or drift control agents may be added if needed. Use of additional surfactants or crop oils may increase risk of cropresponse.

CANOLA TANK MIX RECOMMENDATIONS

Liberty 280 SL Herbicide at 22 fl oz/A plus AMS may be used in tank-mix combination with certain herbicides for improved control oflarger than labeled grasses. Liberty® 280 SL Herbicide may be applied in tank mix combinations with labeled rates of other productsprovided these other products are labeled for the timing and method of application for the canola to be treated. The tank mix partnermust be used in accordance with the label limitations and precautions. No label dosage rates may be exceeded. Liberty® 280 SLHerbicide cannot be mixed with any product containing a label prohibition against such mixing. The AMS rate may be reduced to 1.5Ib/A when Liberty 280 SL Herbicide is tank mixed with a reduced rate of one of the grass herbicides specified below.

Tank Mix Partner

Assure® II

Poast®

Select® 2EC

Select Max™

Rate (fl oz/A)

4 - 5 fl oz/A

6 - 8 fl oz/A

2 - 3 f I oz/A

4 - 6 fl oz/A

APPLICATION DIRECTIONS FOR USE ON FIELD CORN AND SILAGE CORNV • '•"• - • • • - • ' • ' • • - • • • - , . . . . . • . • : . . , - . . . . . . . . . . . . . . . - • . . - . . - • - . . • . - . I

Apply Liberty 280 SL Herbicide only to corn labeled as LibertyLink. Uniform, thorough spray coverage is necessary to achieveconsistent weed control.

APPLICATION RATE AND TIMING

For best results, apply to emerged, young, actively growing weeds. Warm temperatures, high humidity, and bright sunlight improve theperformance of Liberty 280 SL Herbicide. Weed control may be reduced when applications are made to weeds under stress due todrought or cool temperatures. For optimal yield, early season weed removal is important.

Applications of Liberty 280 SL Herbicide on corn may be made with over-the-top broadcast or drop nozzles from emergence until cornis 24 inches tall or in the V-7 stage of growth, i.e., 7 developed collars, whichever comes first. For corn 24 inches to 36 inches tall, onlyapply Liberty 280 SL Herbicide using ground application and drop nozzles and avoid spraying into the whorl or leaf axils of the cornstalks. Applications of Liberty 280 SL Herbicide following the use of soil-applied insecticides will not injure corn.

Apply Liberty 280 SL Herbicide at 22 fl oz/A per application. A second application of Liberty 280 SL Herbicide or a tank mix applicationwith a residual herbicide will be needed to control weeds that have not yet emerged at the time of application.

RESTRICTIONS TO THE DIRECTIONS FOR USE ON FIELD CORN AND SILAGE CORN• DO NOT apply Liberty 280 SL Herbicide within 60 days of harvesting corn forage and within 70 days of harvesting corn grain

and corn fodder.

• DO NOT apply more than two applications of Liberty 280 SL Herbicide to the corn crop. Sequential applications should be atleast 10-14 days apart.

• DO NOT apply more than 44 fl oz/A of Liberty 280 SL Herbicide on corn per growing season.

• If Liberty 280 SL Herbicide was used in a burndown application, no post emergence applications may be applied to the crop.

• DO NOT use nitrogen solutions as spray carriers. A silicone-based antifoam agent may be added if needed.

• DO NOT apply Liberty 280 SL Herbicide if corn shows injury from prior herbicide applications or environmental stress (drought,excessive rainfall, etc.).

« DO NOT apply this product through any type of irrigation system.

• Refer to the "Rotational Crop Restrictions" section under the "Information" heading of this label for the appropriate rotationalcrop plant back intervals.

SPRAY ADDITIVESFor corn, Liberty 280 SL Herbicide must be applied with ammonium sulfate (AMS). It is recommended to use only fine feed grade orspray grade AMS at 3 Ibs per acre (17 lbs/100 gallons). When temperatures exceed 85° F, the rate of AMS can be reduced to 1.5 Ibsper acre (8.5 lbs/100 gallons) to reduce potential leaf burn.

Use of additional surfactants or crop oils may increase risk of crop response.

10

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\ltflf)CORN TANK MIX RECOMMENDATIONSCertain herbicide tank mixes may aid in the performance of Liberty 280 SL Herbicide. No additional surfactant is needed with any tankmix partner. Liberty® 280 SL Herbicide may be applied in tank mix combinations with labeled rates of other products provided theseother products are labeled for the timing and method of application for the corn to be treated. The tank mix partner must be used inaccordance with the label limitations and precautions. No label dosage rates may be exceeded. Liberty® 280 SL Herbicide cannot bemixed with any product containing a label prohibition against such mixing.

Corn Herbicide Tank Mix Partners:2,4-DacetochlorAim™*atrazineCallisto™Camix®*Distinct™Guardsman Max®

Hornet® WDGImpact®Laudis™Lexar®*Lumax®*metolachlor*nicosulfuronNorthStar™

pendimethalin**Permit®Python® WDGs-metolachlor*Spirit®Status®Yukon®

*lt is recommended that these products are tank mixed at 1/2 the recommended use rate with Liberty 280 SL Herbicide to reduce risk ofcrop response.**Tank mixing with pendimethalin may result in reduced control of barnyardgrass, fall panicum, field sandbur, yellow foxtail, andvolunteer corn.

APPLICATION DIRECTIONS FOR USE ON COTTONUniform, thorough spray coverage is necessary to achieve consistent weed control. Liberty 280 SL Herbicide may be applied as abroadcast, over-the-top, post-emergence spray or as a directed spray only to LibertyLink cotton. This product may be applied post-emergence to non-LibertyLink cotton varieties or cultivars by using equipment designed to minimize contact of the spray with the cottonfoliage. See the Application Methods on Non- LibertyLink Cotton section for selection of shielding equipment. Severe injury or deathmay result if the Liberty 280 SL Herbicide contacts the foliage or stems of cotton NOT labeled as LibertyLink.

APPLICATION RATE AND TIMING

For best results, apply to emerged, young, actively growing weeds. Warm temperatures, high humidity, and bright sunlight improve theperformance of Liberty 280 SL Herbicide. Weed control may be reduced when applications are made to weeds under stress due todrought or cool temperatures. For optimal yield, early season weed removal is important.

Apply Liberty 280 SL Herbicide to cotton from emergence up to the early bloom stage at 22 to 29 fl oz/A. Should environmentalconditions prevent a timely herbicide application, a single application of up to 43 fl oz/A of Liberty 280 SL Herbicide may be made tocotton. If more than 29 fl oz/A are used in any single application, the seasonal total may not exceed 72 fl oz/A, including all applicationtimings. See Restrictions to the Directions for use on Cotton below for additional information.

Refer to the Weed Control Recommendations for Row Crops section of this label for selection of the proper rate dependent upon weedspecies present and size. In weed populations with mixed species, select the highest rate required to control all the species. VolunteerLibertyLink crop plants (corn, rice, cotton, soybeans, sugar beets) from the previous season will not be controlled by applications ofLiberty 280 SL Herbicide. A repeat application of Liberty 280 SL Herbicide or tank mixes with a residual herbicide will be needed tocontrol weeds that have not emerged at the time of application. See the Tank Mix Recommendations for Use on Cotton to selectsuitable tank mix partners.

Use Pattern

Option 1Option 2

1st Application22-29 fl oz/A30-43 fl oz/A

2nd Application22-29 fl oz/A

22-29 fl oz/A

3rd Application22-29 fl oz/A

None

Season Maximum

87 fl oz/A72 fl oz/A

RESTRICTIONS TO THE DIRECTIONS FOR USE ON COTTON

• DO NOT apply Liberty 280 SL Herbicide to-cotton in Florida, South of Tampa (Florida Route 60), or in Hawaii, except for testplots or breeding nurseries.

• DO NOT apply Liberty 280 SL Herbicide within 70 days prior to cotton harvest.• Up to three applications of Liberty 280 SL Herbicide may be made to cotton per season at a maximum application rate of 29 fl

oz/A. DO NOT apply more than 87 fl oz (including all application timings) to cotton per season under this application scenario.Sequential applications should be at least 10-14 days apart.

• If environmental conditions prevent timely applications resulting in large weeds or heavy infestations, a single application ofLiberty 280 SL Herbicide at up to 43 fl oz/A may be made to cotton. OO NOT apply more than 43 fl oz of Liberty 280 SLHerbicide in a single application under this use scenario. If a single application greater than 29 fl oz is made, a subsequentapplication not to exceed 29 fl oz may be made to cotton. The seasonal total use rate under this scenario may not exceed 72 floz of Liberty 280 SL Herbicide. Sequential applications should be at least 10-14 days apart.

• DO NOT apply this product through any type of irrigation system.• Refer to the "Rotational Crop Restrictions" section under the "Information" heading of this label for the appropriate

rotational crop plant back intervals. 11

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APPLICATION METHODS TO LIBERTYLINK COTTONRefer to the Weed Control Recommendations for Row Crops to select the proper application rate based upon the weeds present andtheir size. Uniform and thorough spray coverage is required to achieve consistent weed control. For ground application, apply Liberty280 SL Herbicide to LibertyLink cotton as an over-the-top foliar spray or as a spray directed to the lower one-third of the cotton stand.

APPLICATION METHODS TO NON-LIBERTYLINK COTTON

Application of Liberty 280 SL Herbicide to cotton varieties not labeled as LibertyLink requires the use of hooded spray equipmentdesigned to minimize exposure of the spray to the cotton stand. A hooded sprayer directs the spray onto weeds, while shielding thecotton stand from contact. Use nozzles that provide uniform coverage within the treated area. Keep hoods on these sprayers adjustedto protect desirable vegetation. Extreme care must be exercised to avoid exposure of the desirable vegetation to the spray.

With a hooded sprayer, the spray pattern is completely enclosed on the top and all 4 sides by a hood, thereby shielding the crop fromthe spray solution. This equipment must be set up and operated in a manner that avoids bouncing or raising the hoods off the ground inany way. The spray hoods must be operated on the ground or skimming across the ground. Tractor speed must be adjusted to avoidbouncing of the spray hoods. Avoid operation on rough or sloping ground where the spray hoods might be raised off the ground. If thehoods are raised, spray particles may escape and come into contact with the cotton, causing damage or destruction of the crop.

Herbicide rates and spray volume recommendations are presented as broadcast equivalents and must be reduced in proportion to thearea actually treated. Use the following formulas to calculate the correct rate and volume per planted (field) acre:

Band width in inches

Row width in inchesX Broadcast RATE per acre Amount of banded product

needed per acre

Band width in inches

Row width in inchesX Broadcast spray VOLUME

per acre= Banded spray volume

needed per acre

POST-HARVEST

Liberty 280 SL Herbicide may be applied as a post-harvest burndown treatment to fields (after cotton harvest). Up to 43 fl oz/A ofLiberty 280 SL Herbicide may be applied in a single application to control larger weeds growing in the crop at the time of harvest. Ifmore than 29 fl oz/A is used in a single application, the seasonal total may not exceed 72 fl oz/A, including all application timings. Referto the Rotational Crop Restrictions section of this label for appropriate rotational crop information.

COTTON TANK MIX RECOMMENDATIONS

Certain tank mixes may aid in the performance of Liberty 280 SL Herbicide. No additional surfactant is needed with any tank mixpartner. Liberty® 280 SL Herbicide may be applied in tank mix combinations with labeled rates of other products provided these otherproducts are labeled for the timing and method of application for the cotton to be treated. The tank mix partner must be used inaccordance with the label limitations and precautions. No label dosage rates may be exceeded. Liberty® 280 SL Herbicide cannot bemixed with any product containing a label prohibition against such mixing.

LibertyLink Cotton: For cotton tolerant to Liberty 280 SL Herbicide, Dual Magnum® or Staple® Herbicide may be tank-mixed withLiberty 280 SL Herbicide and applied over-the-top post-emergence to enhance weed control and/or provide residual control.

All Cotton Types: The following herbicides may be mixed with Liberty 280 SL for hooded-spray application to enhance weed controland/or provide residual weed control:

Aim™

Caparol® 4L

Cotoran® 4L

Cotoran® DF

Direx® 4L

Direx® 80DF

Dual Magnum®

Glyphosate

Karmex® DF

Pendimax™ 3.3

Prowl® 3.3EC

Select Max™

Staple®

12

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)

APPLICATION DIRECTIONS FOR USE ON SOYBEANS |Apply Liberty 280 SL Herbicide only to soybean designated as LibertyLink. Uniform, thorough spray coverage is necessary to achieveconsistent weed control.

APPLICATION RATE AND TIMING

For best results, apply to emerged, young, actively growing weeds. Warm temperatures, high humidity, and bright sunlight improve theperformance of Liberty 280 SL Herbicide. Weed control may be reduced when applications are made to weeds under stress due todrought or cool temperatures. Adding ammonium sulfate with Liberty 280 SL Herbicide may improve weed control if weeds are understress.. For optimal yield, early season weed removal is important.

Applications of Liberty 280 SL Herbicide on soybeans may be made from emergence up to but not including the bloom growth stage.

Apply Liberty 280 SL Herbicide to LibertyLink soybeans from emergence up to but not including the bloom growth stage at 22 to 29 floz/A. See weed chart to determine rate. Should environmental conditions prevent a timely herbicide application, a single application ofup to 36 fl oz/A of Liberty 280 SL Herbicide may be made to soybeans followed by one additional application at a maximum of 29 fl oz/Awith a seasonal maximum of 65 fl oz/A. Liberty 280 SL Herbicide may be applied alone, or in a tank mix application with a residualherbicide to control weeds that have not yet emerged at the time of application.

Although timely post applications of Liberty herbicide can provide complete weed control, residual herbicides at burndown, planting, ortank mixed with Liberty herbicide help ensure optimal weed management, particularly if environmental conditions delay timely postapplications. Residual herbicides can also reduce early season weed competition and are a key element of good weed resistancemanagement practices.

Use Pattern Rate Ranges

1st Application

22-36 fl oz/A

2nd Application

22-29 fl oz/A

Season Maximum

65 fl oz/A

RESTRICTIONS TO THE DIRECTIONS FOR USE ON SOYBEANS

• DO NOT apply Liberty 280 SL Herbicide within 70 days of harvesting soybean seed.

• DO NOT apply more than 65 fl oz/A of Liberty 280 SL Herbicide on soybeans per growing season.

• DO NOT apply more than 36 fl oz/A of Liberty 280 SL Herbicide in a single application.

• DO NOT graze the treated crop or cut for hay.

• DO NOT use nitrogen solutions as spray carriers. A silicone-based antifoam agent may be added if needed.

• DO NOT apply Liberty 280 SL Herbicide if soybeans show injury from prior herbicide applications or environmental stress(drought, excessive rainfall, etc.).

• DO NOT apply this product through any type of irrigation system.

• Refer to the "Rotational Crop Restrictions" section under the "Information" heading of this label for the appropriate rotationalcrop plant back intervals.

13

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,

SOYBEAN TANK MIX RECOMMENDATIONS

Certain herbicide tank mixes may complement Liberty 280 SL Herbicide. No additional surfactant is needed with any tank mix partner.Liberty® 280 SL Herbicide may be applied in tank mix combinations with labeled rates of other products provided these other productsare labeled for the timing and method of application for the soybean to be treated. The tank mix partner must be used in accordancewith the label limitations and precautions. No label dosage rates may be exceeded. Liberty® 280 SL Herbicide cannot be mixed withany product containing a label prohibition against such mixing.

Soybean Herbicide Tank Mix Partners:Assure® 11 Fusilade® DX Raptor™Classic® Fusion® Reflex®clethodim Harmony® GT Resource®Cobra® Phoenix™ Select Max®Dual Maqnum Poast® Plus Synchrony® XPFirstrate® Prefix Ultra Blazer®Flexstar® Pursuit®

APPLICATION DIRECTIONS FOR CANOLA, CORN, COTTON, AND SOYBEANSEED PROPAGATION

Liberty 280 SL Herbicide may be applied to select out susceptible "segregates", i.e., canola, corn, cotton, and soybean plants that arenot tolerant to glufosinate-ammonium during seed propagation.

• Canola: Liberty 280 SL Herbicide may also be used in canola seed propagation as a foliar spray to selectively eliminate canolaplants that do not carry a gene that imparts tolerance to glufosinate-ammonium and as such, can be applied to removesusceptible segregates during canola seed propagation. Breeding material not possessing the glufosinate-ammonium tolerancegene will be severely injured or killed if treated with this herbicide. See Application Use Directions for Use on Canola for userates and application timing.

• Corn: Inbred lines, plants not possessing glufosinate-ammonium tolerance, will be severely injured or killed if treated with thisherbicide. A hooded sprayer may be used to protect plants from coming into contact with the herbicide application. For theselection of tolerant corn "segregates", Liberty 280 SL Herbicide may be applied at 22 fl oz/A plus AMS at 3 Ib/A (17 lb/100gallons) when corn is in the V-3 to V-4 stage of growth, i.e., 3 to 4 developed collars. A second treatment of 22 fl oz/A plus AMSat 3 Ibs/A may be applied when the corn is in the V-6 to V-7 stage of growth or up to 24" tall. Sequential applications should beat least 10-14 days apart. When temperatures exceed 85° F, the rate of AMS can be reduced to 1.5 Ibs/A (8.5 lbs/100 gallons)to reduce potential leaf burn.

• Cotton: Liberty 280 SL Herbicide may also be used in cotton seed propagation as a foliar spray to selectively eliminate cottonplants that do not carry a gene that imparts tolerance to glufosinate-ammonium and as such, can be applied to removesusceptible segregates during cotton seed propagation. Breeding material not possessing the glufosinate-ammonium tolerancegene will be severely injured or killed if treated with this herbicide. See Application Use Directions for Use on Cotton for userates and application timing.

• Soybeans: For the selection of tolerant soybean "segregates", Liberty 280 SL Herbicide may be applied at up to 22 to 36 fl oz/Awhen soybean is in the third trifoliate stage. A second treatment of 22 to 29 fl oz/A may be applied up to but not including thebloom growth stage of soybean. Sequential applications should be at least 10-14 days apart.

14

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APPLICATION DIRECTIONS FOR USE ON LISTED TREE, VINE, AND BERRYCROPS

Apply Liberty 280 SL Herbicide to the tree, vine, and berry crops listed below. Uniform, thorough spray coverage is necessary toachieve consistent weed control.

REGISTERED CROPSTree Nuts: almonds, filberts, hickory nuts, macadamia nuts (bush nuts), pecans, pistachios, and walnutsTree Fruits: applesVineyards: all grape varieties (table, wine, and raisins)Bushberries: blueberry, currant, elderberry, gooseberry, and huckleberryOther Berries: lingonberry, juneberry, and salal

APPLICATION RATE AND TIMING

For best results, apply to emerged, young, actively growing weeds. Warm temperatures, high humidity, and bright sunlight improve theperformance of LIBERTY 280 SL Herbicide. Weed control may be reduced when applications are made.to weeds under stress due todrought or cool temperatures. Weeds under stress or in dense populations will require application at the highest specified label userate. Stressed conditions also include prior treatments of other contact or systemic herbicides. Do not retreat these weeds withLIBERTY 280 SL Herbicide until sufficient regrowth has occurred.

Apply LIBERTY 280 SL HERBICIDE as a directed spray to control undesirable vegetation in tree, vine and berries listed on this label.Apply as a broadcast, banded, or spot treatment application depending on the situation to control weeds listed under the heading"Weeds Controlled in Tree, Vine and Berry crops". Avoid direct spray or drift to desirable vegetation. Regrowth may occur due to theweed stage of growth at application, low use rate, or environmental conditions. Repeat applications of LIBERTY 280 SL HERBICIDEmay be necessary to control plants generating from underground parts or seed.

Avoid contact of Liberty 280 SL Herbicide solution, spray, drift or mist with green bark, stems, or foliage, as injury may occur to treesand vines. Only trunks with callused, mature brown bark should be sprayed unless protected from spray contact bynonpourous wraps, grow tubes or waxed containers. Contact of Liberty 280 SL Herbicide with parts of trees or vines otherthan mature brown bark can result in serious damage.

Application Methods for Broadcast Applications

Apply Liberty 280 SL Herbicide at the rates listed below for broadcast applications based on weed size and stage of growth.

Weed Size and Stage

Weeds < 3" in heightWeeds < 6" in height

pre-tiller grassesWeeds > 6" in height

and/or grasses that have tillered

Liberty 280 SLHerbicide Rate

48 fl oz/A

56 fl oz/A

56-82 fl oz/A

Application Methods for Banded Spray Applications

Banded applications may be used using the following formula to calculate the amount of herbicide needed for orchard or vineyard stripsprays:

Band width in inches x Rate per acre = Amount of herbicide

Row width in inches broadcast needed for treatment

Application Methods for Spot or Directed-Spray Applications

For spot or directed spray application, mix LIBERTY 280 SL HERBICIDE at 1.7 fl oz of product per gallon of water. Apply to undesirablevegetation foliage until wet but prior to runoff. Ensure uniform and complete coverage. Thoroughly clean the sprayer following use. DONOT make spot or directed spray applications to tree or vine trunk as injury may occur.

15

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Weeds Controlled in Tree, Vine and Berry crops

Broadleaf WeedsAlkali sidaAmmannia, purpleArrowhead, CaliforniaBuckwheat, wildBuffaloburBurclover, CaliforniaCarpetweedChickweed, commonChinese thornappleCocklebur, commonCudweedCutleaf eveningprimroseDodderEcliptaFiddleneckFilareeFilaree, redstem

Fleabane, annualGoosefootCromwell, fieldGroundcherry, cutleafGroundsel, commonHenbitJimsonweedKnotweedKochiaLambsquarters, commonLettuce, miner'sLettuce, pricklyLondon rocketMallow, commonMalva (little mallow)MarestailMayweed

Morningglory, entireleafMorningglory, ivyleafMorningglory, pittedMullein, turkeyMustard, wildNettleNightshade, blackNightshade, eastern blackNightshade, hairyPennycressPigweed, redrootPineapple-weedPuncturevinePurslane, commonRadish, wildRagweed, commonRagweed, giant

RedmaidsShepherd's-PurseSmartweed, PennsylvaniaSowthistle, annualSpurge, prostrateStarthistle, yellowSunflower, commonSunflower, prairieSunflower, volunteerSwinecressThistle, RussianTurnip, wildVelvetleafVervainVetchVirginia copperleafWillowherb, panicle

Grass WeedsBarnyardgrassBluegrass, annualBrome, ripgutBromegrass, downyCanarygrassChess, softCrabgrass, large

Crabgrass, smoothCupgrass, woollyFoxtail, giantFoxtail, greenFoxtail, yellowGoosegrassJohnsongrass, seedling

JunglericeOat, wildPanicum, fallPanicum, TexasRush, toad"RyegrassSandbur, field

ShattercaneSprangletopStinkgrassWheat, volunteerWindgrassWitchgrass

Biennial and Perennial WeedsAster, white heathBindweed, fieldBindweed, hedgeBluegrass, KentuckyBromegrass, smoothBulrushBurdockCanada thistleClover, AlsikeClover, redClover, white** indicates suppression

DallisgrassDandelionDock, curlydogbank (hemp)FescueGoldenrod, grayGuineagrassHorsetailLovegrassMugwortMullein, common

Mustard, tansyNutsedge, purpleNutsedge, yellowOnion, wildOrchardgrassParagrassPlantainPoison ivy/oakQuackgrassRocket, yellowRose, wild

Rubus spp.Spurge, leafyThistle, bullThistle, muskTorpedograssVaseygrassWoodsorrelYarrow, common

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RESTRICTIONS TO THE DIRECTIONS FOR USE ON TREE, VINE, AND BERRY CROPS

1. DO NOT apply more than 164 f! oz of LIBERTY 280 SL HERBICIDE per acre (3 Ibs ai/A) to berry bushes in a 12-monthperiod.

2. DO NOT apply more than 246 fl oz of this product per acre to tree nuts, vines, and tree fruits in any calendar year.

3. DO NOT graze, harvest, and/or feed treated orchard cover crops to livestock.

4. DO NOT apply this product through any type of irrigation system.

5. DO NOT apply this product aerially to tree, berry, or vine crops.

6. DO NOT apply this product within 14 days of nut, apple, berry or grape harvest.

7. DO NOT make spot spray applications to apple suckers, as tree injury may occur.

TANKMIX PARTNER RECOMMENDATIONSLiberty 280 SL Herbicide does not provide residual weed control or control of unexposed plant parts. Certain herbicide tank mixes mayaid in the performance of Liberty 280 SL Herbicide or be added to provide residual herbicide activity. No additional surfactant is neededwith any tank mix partner. Liberty® 280 SL Herbicide may be applied in tank mix combinations with labeled rates of other productsprovided these other products are labeled for the timing and method of application for the crop to be treated. The tank mix partner mustbe used in accordance with the label limitations and precautions. No label dosage rates may be exceeded. Liberty® 280 SL Herbicidecannot be mixed with any product containing-a label prohibition against such mixing.

Chateau Princep® 4L Sinbar® SOW

Devrinol® 50WP Simazine 4L Solicam® DF

Goal®1.6E Simazine SOW Surflan®A.S.

Karmex® DF Simazine 90

Vflj>PL!CATIJiK DIRECTIONS FOR RQTATQ yil̂ JE DESIgCATjON [APPLICATION RATE AND TIMING

Apply LIBERTY 280 SL HERBICIDE at the beginning of natural senescence of potato vines. Apply 21 fl oz/A. Do not split thisapplication or apply more than one application per harvest. Potato varieties with heavy or dense vines may require an application ofanother desiccation product to complete vine desiccation.

Thorough coverage of the potato vines to be desiccated is essential. Use a sufficient volume of water (20 to 100 gpa) to obtain athorough coverage of the potato vines. Vary the gallons of water per acre and the spray pressure as indicated by the density of thepotato vines to assure thorough spray coverage. Increase the spray volume to at least 30 gallons of water per acre when the potatovine canopy is dense or under cool and dry conditions. Apply LIBERTY 280 SL HERBICIDE with the spray boom as low as possible toachieve thorough coverage of the potato vines for best control and to minimize drift potential.

RESTRICTIONS TO THE DIRECTIONS FOR USE IN POTATO VINE DESICCATION

1. DO NOT apply more than 21 fl oz/A to potato vines per season.

2. DO NOT harvest potatoes until 9 days or more after application of LIBERTY 280 SL HERBICIDE.

3. DO NOT apply to potatoes grown for seed.

4. Canola, com, cotton, rice, soybean, and sugar beets may be planted at any time after the application of LIBERTY 280 SLHERBICIDE as a potato vine desiccant.

5. DO NOT plant treated areas to wheat, barley, buckwheat, millet, oats, rye, sorghum, and triticale until 30 or more days after anapplication of LIBERTY 280 SL HERBICIDE as a potato vine desiccant.

6. DO NOT plant treated areas to crops other than those listed in this use precautions section until 120 or more days after anapplication of LIBERTY 280 SL HERBICIDE as a potato vine desiccant.

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Page 19: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

FALLOW'FIELDS

Liberty 280 SL Herbicide may be used as a substitute for tillage in fallow fields to control or suppress weeds listed in the Weed ControlRecommendations for Row Crops section of this label.

Apply Liberty 280 SL Herbicide at 22 or 29 fl oz/A to fallow fields to control specific weeds. Liberty 280 SL Herbicide must be appliedwith ammonium sulfate. Tank mixes with 2,4-0, glyphosate or atrazine are recommended with Liberty 280 SL Herbicide to enhancetotal weed control. When using Liberty 280 SL Herbicide in tank mix combinations, follow the precautions and directions of use of themost restrictive label. See the Application and Mixing Procedures section of this label for additional information on, how to apply thisproduct. See the "Information" section of this label for rotational crop restrictions.

When applied as recommended, Liberty 280 SL Herbicide controls undesirable plant vegetation in non-crop areas around farmsteadbuilding foundations, shelter belts, along fences, and general nonselective farmstead weed control. Refer to the ApplicationDirections for use on listed Tree, Vine, and Berry Crops section of this label for appropriate application broadcast and spot sprayapplication rates and lists of weeds controlled.

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Page 20: Liberty® 280 SL HERBICIDE - United States … CropScience LP P.O. Box 12014, 2 T.W. Alexander Drive Research Triangle Park, NC 27709 nDea rr Dr. See, o: APR I 4 2D1I Subject: Increased

IMPORTANT: READ BEFORE USERead the entire Directions for Use, Conditions, Disclaimer of Warranties and Limitations of Liability before using this product. If termsare not acceptable, return the unopened product container at once.

By using this product, user or buyer accepts the following Conditions, Disclaimer of Warranties and Limitations of Liability.

CONDITIONS: The directions for use of this product are believed to be adequate and must be followed carefully. However, it isimpossible to eliminate all risks associated with the use of this product. Crop injury, ineffectiveness or other unintended consequencesmay result because of such factors as weather conditions, presence of other materials, or the manner of use or application, all of whichare beyond the control of Bayer CropScience. All such risks shall be assumed by the user or buyer.

DISCLAIMER OF WARRANTIES: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE MAKES NOOTHER WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE OROTHERWISE, THAT EXTEND BEYOND THE STATEMENTS MADE ON THIS LABEL. No agent of Bayer CropScience is authorized tomake any warranties beyond those contained herein or to modify the warranties contained herein. TO THE EXTENT CONSISTENTWITH APPLICABLE LAW, BAYER CROPSCIENCE DISCLAIMS ANY LIABILITY WHATSOEVER FOR SPECIAL, INCIDENTAL ORCONSEQUENTIAL DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT.

LIMITATIONS OF LIABILITY: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, THE EXCLUSIVE REMEDY OF THEUSER OR BUYER FOR ANY AND ALL LOSSES, INJURIES OR DAMAGES RESULTING FROM THE USE OR HANDLING OF THISPRODUCT, WHETHER IN CONTRACT, WARRANTY, TORT, NEGLIGENCE, STRICT LIABILITY OR OTHERWISE, SHALL NOTEXCEED THE PURCHASE PRICE PAID, OR AT BAYER CROPSCIENCE'S ELECTION, THE REPLACEMENT OF PRODUCT.

Net Contents: 2.5 Gallons, 270 Gallons & Bulk

Liberty, LibertyLink, Rely, and the LibertyLink design are registered trademarks and Laudis is a trademark of Bayer CropScience.

Impact is registered trademarks of Amvac Chemical Company.

Guardsman Max, Poast, Prowl, Pursuit, and Status are registered trademarks and Distinct and Raptor are trademarks of BASF Corporation.

Firstrate, Surflan, Goal, and Hornet are registered trademarks and Pendimax is a trademark of Dow AgroSciences.

Assure, Classic, Direx, Harmony, Karmex, Staple, Synchony, Sinbar, and Vitron are registered trademarks of E. I. DuPont de Nemours Company.

Aim is a trademark of FMC.

Cotoran is a registered trademark of Makhteshim Agan North America.

Permit and Yukon are registered trademarks of Monsanto.

Camix, Caparol, Dual Magnum, Flexstar, Fusilade, Fusion, Lexar, Lumax, Reflex, Solicam, Princep, and Spirit are registered trademarks and Callistoand NorthStar, are trademarks of Syngenta Group Company.

Cobra, Resource, Chateau, and Select are registered trademarks and Phoenix and Select Max are trademarks of Valent U.S.A. Company.

Ultra Blazer is a registered trademark of United Phosphorus, Inc.

Produced for

Bayer CropScience

Bayer CropScience LPP.O. Box 12014, 2 T.W. Alexander DriveResearch Triangle Park, North Carolina 277091-866-99BAYER (1-866-992-2937)http://www.bayercropscienceus.com

Liberty 280 SL Herbicide (PENDING) 08/05/10

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