Ibridizzazione (o ibridazione) ψ i = a i ψ(s) + b i ψ(p x ) + c i ψ(p y ) + d i ψ(p z ) ψ 1 = a 1 ψ(s) + b 1 ψ(p x ) + c 1 ψ(p y ) + d 1 ψ(p z ) ψ 2 = a 2 ψ(s) + b 2 ψ(p x ) + c 2 ψ(p y ) + d 2 ψ(p z ) ψ 3 = a 3 ψ(s) + b 3 ψ(p x ) + c 3 ψ(p y ) + d 3 ψ(p z ) ψ 4 = a 4 ψ(s) + b 4 ψ(p x ) + c 4 ψ(p y ) + d 4 ψ(p z ) ψ(s) = f(r) ψ(p x ) = f(r) 3 1/2 senϑ cosϕ ψ(p y ) = f(r) 3 1/2 senϑ senϕ ψ(p z ) = f(r) 3 1/2 cosϑ 1 dV ψ 2 i = ∫ i = 1, 2, 3, 4 1 2 2 2 2 = + + + i i i i d c b a
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Lezione 03 ibridizzazione - sbai.uniroma1.itmauro.pasquali/page2/page9/page11/files/03.pdf · Idrocarburi ALCHENI C n H 2n La molecola dellʼetilene C 2 H 4: (a)orbitali dei due atomi
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