A. Nitzan, Tel Aviv University ELECTRON TRANSFER AND TRANSMISSION IN MOLECULES AND MOLECULAR JUNCTIONS AEC, Grenoble, Spet 2005 Lecture 1 Lecture 1
Jan 14, 2016
A. Nitzan, Tel Aviv University
ELECTRON TRANSFER AND TRANSMISSION IN MOLECULES AND MOLECULAR JUNCTIONS
AEC, Grenoble, Spet 2005
Lecture 1Lecture 1
IntroductionIntroduction
Introduction to electron Introduction to electron transport in molecular systemstransport in molecular systems
I. Benjamin, A. Burin, G. Cuniberty, B. Davis, S. Datta, D. Evans, M. Galperin, A. Ghosh, H. Grabert, P. Hänggi, G. Ingold, J. Jortner, S. Kohler, R. Kosloff, J. Lehmann, M. Majda, A. Mosyak, V. Mujica, R. Naaman, F. v Oppen, U. Peskin, M. Ratner, D. Segal, T. Seideman, H. Tal-Ezer, A. Troisi
Thanks
Reviews: Annu. Rev. Phys. Chem. 52, 681– 750 (2001) [http://atto.tau.ac.il/~nitzan/nitzanabs.html/#213]
Science, 300, 1384-1389 (2003); MRS Bulletin, 29, 391-395 (2004); Bulletin of the
Israel Chemical Society, Issue 14, p. 3-13 (Dec 2003) (Hebrew)
Molecular conductionMolecular conduction
m o lecule
Molecular Rectifiers
Arieh Aviram and Mark A. RatnerIBM Thomas J. Watson Research Center, Yorktown Heights, New
York 10598, USADepartment of Chemistry, New York New York University, New
York 10003, USA
Received 10 June 1974Abstract
The construction of a very simple electronic device, a rectifier, based on the use of a single organic molecule is discussed. The molecular rectifier consists of a donor pi system and an acceptor pi system, separated by a sigma-bonded (methylene) tunnelling bridge. The response of such a molecule to an applied field is calculated, and rectifier properties indeed appear.
Xe on Ni(110)
Feynman
Chad Mirkin (DPN)
Moore’s “Law”
Moore’s 2nd law
Molecules get wired
Cornell group
IEEE TRANSACTIONS ON ELECTRON DEVICES VOL.43OCTOBER 1996 1637
Need for Critical AssessmentRolf Landauer,Life Fellow,IEEE
AbstractAdventurous technological proposals are subject to inadequate critical assessment. It is the proponents who organize meetings and special issues. Optical logic, mesoscopic switching devices and quantum parallelism are used to illustrate this problem.
This editorial,disguised as a scientific paper, is obviously a plan for more honesty. We do not, in the long run, build effective public support for science and technology by promising more than we can deliver.
Feynman
• For a successful Technology, reality must take precedence over public relations, for nature cannot be fooled
First Transport Measurements through Single Molecules
Single-wall carbon nanotube on Pt
Dekker et al. Nature 386(97)
Nanopore
Reed et al. APL 71 (97)
Break junction: dithiols between gold
Molecule lying on a surface Molecule between
two electrodes
Dorogi et al. PRB 52 (95) @ Purdue
Au(111)
Pt/Ir Tip
SAM1 nm
~1-2 nm
Self-assembled monolayers
Adsorbed molecule addressed by STM tip
C60 on gold
Joachim et al. PRL 74 (95)
STMtip
Au
Reed et al. Science 278 (97) @ Yale
Nanotube on Au
Lieber et al. Nature 391 (98)
Park et. al. Nature 417,722-725 (2002)
Datta et al
Weber et al, Chem. Phys. 2002
Electron transfer in DNA
loge of GCGC(AT)mGCGC conductance vs length (total number of base pairs). The solid line is a linear fit that reflects the exponential dependence of the conductance on length. The decay constant, , is determined from the slope of the linear fit. (b) Conductance of (GC)n vs 1/length (in total base pairs).
Xu et al (Tao), NanoLet (2004)
=0.43Å-1
Electron transmission Electron transmission processes in molecular processes in molecular
systemssystems Electron transferElectron transfer Electron transmissionElectron transmission ConductionConduction Parameters that affect molecular Parameters that affect molecular
conductionconduction Eleastic and inelastic transmissionEleastic and inelastic transmission Coherent and incoherent conductionCoherent and incoherent conduction Heating and heat conductionHeating and heat conduction
Coming March 2006
(4) Recent research(a) Inelastic issues in molecular
conduction(b) Tunneling trough redox molecular species(c) Molecular heating and molecular heat conduction(d) What can be done with photons?
Grenoble Sept 2005
(1) Relaxation and reactions in condensed molecular systems•Kinetic models•Transition state theory•Kramers theory and its extensions•Low, high and intermediate friction regimes•Diffusion controlled reactions
(2) Electron transfer processes•Simple models•Marcus theory•The reorganization energy•Adiabatic and non-adiabatic limits•Solvent controlled reactions•Bridge assisted electron transfer•Coherent and incoherent transfer•Electrode processes
(3) Molecular conduction•Simple models for molecular conductions•Factors affecting electron transfer at interfaces•The Landauer formula•Molecular conduction by the Landauer formula•Relationship to electron-transfer rates.•Structure-function effects in molecular conduction•How does the potential drop on a molecule and why this is important•Probing molecules in STM junctions•Electron transfer by hopping
Chapter 13-15Chapter 16Chapter 17
PART APART A
Relaxation and reactions Relaxation and reactions in molecular systemsin molecular systems
Molecular processes in Molecular processes in condensed phases and condensed phases and
interfacesinterfaces•Diffusion
•Relaxation
•Solvation
•Nuclear rerrangement
•Charge transfer (electron and xxxxxxxxxxxxxxxxproton)
•Solvent: an active spectator – energy, friction, solvation
Molecular timescales
Diffusion D~10-5cm2/s
Electronic 10-16-10-15s
Vibraional 10-14s
Vibrational xxxxrelaxation 1-10-12s
Chemical reactions xxxxxxxxx1012-10-12s
Rotational 10-12s
Collision times 10-12s
Molecular vibrational Molecular vibrational relaxationrelaxation
D
/~ DcVRk e
Relaxation in the X2Σ+ (ground electronic state) and A2Π (excite electronic state) vibrational manifolds of the CN radical in Ne host matrix at T=4K, following excitation into the third vibrational level of the Π state. (From V.E. Bondybey and A. Nitzan, Phys. Rev. Lett. 38, 889 (1977))
ˆ ˆ~ ( ) (0)ifi tf i T
k dte F t F
Golden RuleFourier transform of bath correlation function
Molecular vibrational Molecular vibrational relaxationrelaxation
The relaxation of different vibrational levels of the ground electronic state of 16O2 in a solid Ar matrix. Analysis of
these results indicates that the relaxation of the < 9 levels is dominated by radiative decay and possible transfer to impurities. The relaxation of the upper levels probably takes place by the multiphonon mechanism. (From A. Salloum, H. Dubust, Chem. Phys.189, 179 (1994)).
Dielectric solvationDielectric solvation
q = + e q = + eq = 0
a b c
C153 / Formamide (295 K)
Wavelength / nm
450 500 550 600
Rel
ativ
e E
mis
sion
Int
ensi
ty
ON O
CF3
Emission spectra of Coumarin 153 in formamide at different times. The times shown here are (in order of increasing peak-wavelength) 0, 0.05, 0.1, 0.2, 0.5, 1, 2, 5, and 50 ps (Horng et al, J.Phys.Chem. 99, 17311 (1995))
2 11 1 2eV (for a charge)
2 s
q
a
Born solvation energy
Continuum dielectric theory of Continuum dielectric theory of solvationsolvation
D 4
(r, ) ( ) (r, )t
D t dt t t E t
D E
( ) ( ) 4 ( )
( ) ( ) ( )
1
4
D E P
P E
D(r, ) r ' (r r ', )E(r ', )εt
t d dt t t t
1 2
( )1
s ee
Di
How does solvent respond to a sudden change in the molecular charge distribution?
Electric displacement
Electric field
Dielectric function
Dielectric susceptibility
polarizationDebye dielectric relaxation model
Electronic response
Total (static) response
Debye relaxation time
Continuum dielectric theory of Continuum dielectric theory of solvationsolvation
0 0( )
0
tE t
E t
1; 0s
D D
dDD E t
dt
1( ) ( 4) ;e s
D
dE
dDD D E
t
/ /( ) (1 )D Dt ts eD t e e E
0 0( )
0
tD t
D t
1; 0s
e D s
dE E D t
dt
/1 1 1( ) Lt
s e s
E t D De
eL D
s
WATER:
D=10 ps L=125 fs
““real” solvationreal” solvationThe experimental solvation function for water using sodium salt of coumarin-343 as a probe. The line marked ‘expt’ is the experimental solvation function S(t) obtained from the shift in the fluorescence spectrum. The other lines are obtained from simulations [the line marked ‘Δq’ –simulation in water. The line marked S0 –in a neutral atomic solute with Lennard Jones parameters of the oxygen atom]. (From R. Jimenez et al, Nature 369, 471 (1994)).
“Newton”
dielectric
Electron solvationElectron solvationThe first observation of hydration dynamics of electron. Absorption profiles of the electron during its hydration are shown at 0, 0.08, 0.2, 0.4, 0.7, 1 and 2 ps. The absorption changes its character in a way that suggests that two species are involved, the one that absorbs in the infrared is generated immediately and converted in time to the fully solvated electron. (From: A. Migus, Y. Gauduel, J.L. Martin and A. Antonetti, Phys. Rev Letters 58, 1559 (1987)
Quantum solvation
(1) Increase in the kinetic energy (localization) – seems NOT to affect dynamics
(2) Non-adiabatic solvation (several electronic states involved)
C153 / Formamide (295 K)
Wavelength / nm
450 500 550 600
Rel
ativ
e E
mis
sion
Int
ensi
ty
ON O
CF3
Electron tunneling Electron tunneling through waterthrough water
E F
W o rkfu n ct io n( in wa te r)
W A T E R
12
3
Polaronic state (solvated electron)
Transient resonance through “structural defects”
Electron tunneling Electron tunneling through waterthrough water
Time (ms)
STM current in pure waterSTM current in pure waterS.Boussaad et. al. JCP (2003)S.Boussaad et. al. JCP (2003)
Chemical reactions in Chemical reactions in condensed phasescondensed phases
Bimolecular
Unimolecular
diffusion
4k DR
Diffusion controlled
rates
Bk TD
mR
2
1
k1 2 k2 1
k2
excitation
reaction
21 2
12 2
k Mkk
k M k
k
M
Thermal interactions
Unimolecular reactions (Lindemann)
Activated rate processesActivated rate processes
E B
r e ac t i o nc o o r di nate
KRAMERS THEORY:
Low friction limit
High friction limit
Transition State theory
0 /
2B B
TSTE k Tk e
0 /
2B BB B
TSTE k Tk e k
/0
B BE k TB
B
k J ek T
(action)
4k DR
Diffusion controlled
rates
Bk TD
m
Effect of solvent frictionEffect of solvent friction
A compilation of gas and liquid phase data showing the turnover of the photoisomerization rate of trans stilbene as a function of the “friction” expressed as the inverse self diffusion coefficient of the solvent (From G.R. Fleming and P.G. Wolynes, Physics Today, 1990). The solid line is a theoretical fit based on J. Schroeder and J. Troe, Ann. Rev. Phys. Chem. 38, 163 (1987)).
TST
The physics of transition The physics of transition state ratesstate rates
0
2BEe
0
( ,TST B f BP xk d P x
v v v v)
212
212
0 1
2
m
m
d e
md e
v
v
vv
v
20exp
( )2exp ( )
B
B
B EB E
E mP x e
dx V x
Assume:
(1) Equilibrium in the well
(2) Every trajectory on the barrier that goes out makes it
E B
0
B
r e ac t i o nc o o r di nate
The (classical) transition The (classical) transition state rate is an upper state rate is an upper
boundbound
E B
r e ac t i o nc o o r di nate
•Assumed equilibrium in the well – in reality population will be depleted near the barrier
•Assumed transmission coefficient unity above barrier top – in reality it may be less
R *
a b
diabatic
R *
1
1
2
Adiabatic
*
0
( , ) ( )b ak dR R P R R P R
Quantum considerations
1 in the classical case