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J o u rn a l o f R a d i a t i o n R e s e a r c h and A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 7
Available online at w
ScienceDirectJournal of Radiation Research and Applied
Sciencesjournal homepage: ht tp: / /www.elsevier .com/locate/ j r ras
New procedure calculation of photon-inducedKb/Ka intensity ratios for elements 16S to 92U
A. Kahoul a,b,*, N. Kup Aylikci c, V. Aylikci d, B. Deghfel e,f, Y. Kasri g,M. Nekkab e,f
a Department of Materials Science, Faculty of Sciences and Technology, Bordj-Bou-Arreridj University, Bordj-Bou-
Arreridj 34030, Algeriab LPMRN Laboratory, Department of Materials Science, Faculty of Sciences and Technology, Bordj-Bou-Arreridj
University, Bordj-Bou-Arreridj 34030, Algeriac Department of Energy Systems Engineering, Faculty of Technology, Mustafa Kemal University, 31040 Hatay,
Turkeyd Department of Metallurgical and Materials Engineering, Faculty of Technology, Mustafa Kemal University, Hatay
31040, Turkeye Physics Department, Faculty of Sciences, M'Sila University, 28000 M'Sila, Algeriaf LESIMS Laboratory, Physics Department, Faculty of Sciences, Ferhat Abbas University of Setif, 19000 Setif, Algeriag Theoretical Physics Laboratory, Physics Department, University of Bejaia, Algeria
Department of Materials Science, Faculty of Sciences and Technology, Bordj-Bou-Arreridj. Tel./fax: þ213 035666599.(A. Kahoul).ptian Society of Radiation Sciences and Applications
sevier
l, A., et al., New procedure calculation of photon-induced Kb/Ka intensity ratios forResearch and Applied Sciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
iety of Radiation Sciences and Applications. Production and hosting by Elsevier B.V. All rights
Buyukkasap, and Erdo�gan (2002) was measured the Kb/Ka X-
ray intensity ratio for elements in the range 22 � Z � 30 using
Si(Li) solid state detector with high resolution by 5.9 keV g-
rays from a filtered 241Am source. Ertugrul (2002) determined
the Kb/Ka X-ray intensity ratios of some elements in the
atomic range 30 � Z � 40 using 59.5 keV g-rays. Pawłowski,
Polasik, Raj, Padhi, and Basa (2002) measured the Kb/Ka X-
ray intensity ratios for elements of 22Ti, 24Cr, 26Fe and 27Co
excited by 59.54 keV g-rays from 7400 MBq (200 mCi) 241Am
point source. Ertugrul, Karabulut, and Budak (2002) measured
the K-shell absorption jump factor and the Kb/Ka X-ray in-
tensity ratios of some elements in the atomic range 40� Z� 60
using Si(Li) detector (FWHM ¼ 160 eV at 5.96 keV). S‚ ahin,
Demir, and Budak (2005) studied Kb/Ka X-ray intensity ratios
for six elements in the range 16 � Z � 23 at 5.96 keV. Chemical
effect on the Kb/Ka X-ray intensity ratios of 25Mn, 28Ni and29Cu complexes of a new Schiff-base with salen N2H2 type
were investigated by Cevik, De�girmencio�glu, Ertu�gral,
Apaydin, and Baltas‚ (2005) using 59.543 keV g-rays from an241Am annular radioactive source. The Kb/Ka X-ray intensity
ratios for 17 elements from 25Mn to 42Moweremeasured by €Oz
(2006) using 59.5 keV g-rays from a 241Am point source. Bennal
and Badiger (2006) determined the Kb/Ka intensity ratios by
adopting 2p geometrical configuration for the elements 73Ta,79Au and 89Pb. Han, S‚ ahin, Demir, and S‚ ahin (2007) measured
the K X-ray fluorescence cross sections, fluorescence yields
and intensity ratios in the atomic region 22� Z� 68 excited by
59.54 keV g-rays from 241Am filtered point source. Demir and
S‚ ahin (2007a, 2007b) measured the Kb/Ka X-ray intensity ra-
tios for 60Nd, 63Eu, 64Gd, 66Dy and 67Ho using the 59.5 keV
photons in an external magnetic field. The experimental
values of Kb/Ka were obtained for the elements 24Cr, 26Fe,27Co, 29Cu, 30Zn, 31Ga, 34Se, 39Y, 42Mo, 48Cd, 49In, 50Sn, 52Te,56Ba, 73Ta, 74W and 83Bi by Cevik et al. (Cevik, Kaya, Ertugral,
Baltas, & Karabidak, 2007) using 59.5 keV photons emitted by
a 50 mCi 241Am radioactive source. Kalayci, Aydinuraz,
ure calculation of photon-induced Kb/Ka intensity ratios forciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
Table 1 e Summary of the experimental Kb/Ka intensity ratios, Unweighted average value (Kb=Ka), Weighted average value(Kb=KaW ), Unweighted standard deviation (USD(Kb/Ka)), Weighted standard deviation (WSD (Kb/Ka)) and Unweighted Standarderrors (USE (Kb/Ka)).
Z Kb/Ka(exp) References Kb=Ka Kb=KaW USD(Kb/Ka) WSD (Kb/Ka) USE (Kb/Ka)
Z ¼ 16, S 0.0525 ± 0.0021 (S‚ ahin et al., 2005) 0.0558 0.0539 0.0047 0.0033 0.0033
0.0591 ± 0.0040 (Ertu�gral et al., 2007)
Z ¼ 17, Cl 0.0678 ± 0.0027 (S‚ ahin et al., 2005) 0.0688 0.0683 0.0014 0.0010 0.0010
0.0698 ± 0.0050 (Ertu�gral et al., 2007)
Z ¼ 19, K 0.0951 ± 0.0038 (S‚ ahin et al., 2005) 0.1039 0.0983 0.0124 0.0088 0.0088
0.1126 ± 0.0080 (Ertu�gral et al., 2007)
Z ¼ 20, Ca 0.1050 ± 0.0042 (S‚ ahin et al., 2005) 0.1139 0.1109 0.0126 0.0089 0.0089
0.1228 ± 0.0060 (Ertu�gral et al., 2007)
Z ¼ 21, Sc 0.1268 ± 0.0050 (Ertu�gral et al., 2007) 0.1268 0.1268 e undefined e
Z ¼ 22, Ti 0.1282 ± 0.0014 (Bhuinya and Padhi, 1992) 0.1252 0.1269 0.0089 0.0029 0.0027
0.1289 ± 0.0014 (Bhuinya and Padhi, 1993)
0.1359 ± 0.0017 (B�e et al., 1998)
0.1265 ± 0.0006 (Raj et al., 1999)
0.1210 ± 0.0100 (Ertu�grul, S€ogut, et al., 2001)
0.1265 ± 0.0006 (Raj et al., 2002)
0.1364 ± 0.0134 (Sogut et al., 2002)
0.1265 ± 0.0006 (Pawłowski et al., 2002)
0.1089 ± 0.0043 (S‚ ahin et al., 2005)
0.1100 ± 0.0090 (Han et al., 2007)
0.1282 ± 0.0080 (Ertu�gral et al., 2007)
Z ¼ 23, V 0.1479 ± 0.0003 (Chang et al., 1994) 0.1284 0.1396 0.0100 0.0158 0.0032
0.1363 ± 0.0017 (B�e et al., 1998)
0.1312 ± 0.0008 (Raj et al., 1999)
0.1312 ± 0.0008 (Raj et al., 2002)
0.1316 ± 0.0111 (Sogut et al., 2002)
0.1244 ± 0.0050 (S‚ ahin et al., 2005)
0.1130 ± 0.0090 (Han et al., 2007)
0.1294 ± 0.0060 (Ertu�gral et al., 2007)
0.1166 ± 0.0009 (Yalcin, 2007)
0.1227 ± 0.0007 (Yalcin, 2007)
Z ¼ 24, Cr 0.1338 ± 0.0009 (Bhuinya and Padhi, 1993) 0.1294 0.1307 0.0082 0.0055 0.0024
0.1124 ± 0.0013 (Kucuk€onder et al. 1993)
0.1394 ± 0.0017 (B�e et al., 1998)
0.1314 ± 0.0008 (Raj et al., 1999)
0.1314 ± 0.0008 (Raj et al., 2000)
0.1280 ± 0.0100 (Ertu�grul, S€ogut, et al., 2001)
0.1314 ± 0.0008 (Raj et al., 2002)
0.1341 ± 0.0130 (Sogut et al., 2002)
0.1314 ± 0.0008 (Pawłowski et al., 2002)
0.1130 ± 0.0090 (Han et al., 2007)
0.1320 ± 0.0050 (Cevik et al., 2007)
0.1342 ± 0.0050 (Ertu�gral et al., 2007)
Z ¼ 25, Mn 0.1383 ± 0.0017 (B�e et al., 1998) 0.1283 0.1284 0.0105 0.0075 0.0032
0.1344 ± 0.0009 (Raj et al., 2000)
0.1310 ± 0.0130 (Ertu�grul et al., 2001b)
0.1344 ± 0.0009 (Raj et al., 2002)
0.1235 ± 0.0104 (Sogut et al., 2002)
0.1270 ± 0.0060 (Cevik et al., 2005)
0.1320 ± 0.0110 (€Oz,2006)
0.1060 ± 0.0080 (Han et al., 2007)
0.1440 ± 0.0040 (Ertu�gral et al., 2007)
0.1188 ± 0.0011 (Yalcin, 2007)
0.1214 ± 0.0008 (Yalcin, 2007)
Z ¼ 26, Fe 0.1290 ± 0.0005 (Padhi and Dhal, 1995) 0.1311 0.1302 0.0047 0.0020 0.0015
0.1372 ± 0.0017 (B�e et al., 1998)
0.1330 ± 0.0110 (Ertu�grul, S€ogut, et al., 2001)
0.1307 ± 0.0007 (Raj et al., 2002)
0.1287 ± 0.0110 (Sogut et al., 2002)
0.1307 ± 0.0007 (Pawłowski et al., 2002)
0.1340 ± 0.0120 (€Oz,2006)
0.1200 ± 0.0100 (Han et al., 2007)
0.1350 ± 0.0070 (Cevik et al., 2007)
(continued on next page)
J o u rn a l o f R a d i a t i o n R e s e a r c h and A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 7 3
Please cite this article in press as: Kahoul, A., et al., New procedure calculation of photon-induced Kb/Ka intensity ratios forelements 16S to 92U, Journal of Radiation Research and Applied Sciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
Z Kb/Ka(exp) References Kb=Ka Kb=KaW USD(Kb/Ka) WSD (Kb/Ka) USE (Kb/Ka)
0.1324 ± 0.0050 (Ertu�gral et al., 2007)
Z ¼ 27, Co 0.1285 ± 0.0006 (Padhi and Dhal, 1995) 0.1328 0.1322 0.0053 0.0028 0.0012
0.1379 ± 0.0017 (B�e et al., 1998)
0.1335 ± 0.0008 (Raj et al., 1999)
0.1335 ± 0.0008 (Raj et al., 2000)
0.1330 ± 0.0100 (Ertu�grul, S€ogut, et al., 2001)
0.1335 ± 0.0008 (Raj et al., 2002)
0.1387 ± 0.0140 (Sogut et al., 2002)
0.1335 ± 0.0008 (Pawłowski et al., 2002)
0.1370 ± 0.0110 (€Oz,2006)
0.1370 ± 0.0080 (Cevik et al., 2007)
0.1390 ± 0.0070 (Ertu�gral et al., 2007)
0.1390 ± 0.0030 (Porikli and kurucu, 2008)
0.1310 ± 0.0050 (Porikli and kurucu, 2008)
0.1240 ± 0.0050 (Porikli and kurucu, 2008)
0.1313 ± 0.0087 (Kup Aylikci et al., 2009)
0.1342 ± 0.0063 (Han and Demir, 2010)
0.1230 ± 0.0062 (Kup Aylikci et al., 2010)
0.1230 ± 0.0062 (Kup Aylikci et al., 2011)
Z ¼ 28, Ni 0.1356 ± 0.0006 (Bhuinya and Padhi, 1992) 0.1367 0.1358 0.0059 0.0018 0.0014
0.1368 ± 0.0006 (Bhuinya and Padhi, 1993)
0.1371 ± 0.0006 (Bhuinya and Padhi, 1993)
0.1336 ± 0.0005 (Padhi and Dhal, 1995)
0.1363 ± 0.0006 (Raj et al., 1998)
0.1377 ± 0.0017 (B�e et al., 1998)
0.1350 ± 0.0120 (Ertu�grul, S€ogut, et al., 2001)
0.1346 ± 0.0012 (Raj et al., 2002)
0.1466 ± 0.0124 (Sogut et al., 2002)
0.1410 ± 0.0120 (Cevik et al., 2005)
0.1380 ± 0.0110 (€Oz,2006)
0.1190 ± 0.0090 (Han et al., 2007)
0.1378 ± 0.0010 (Kalayci et al., 2007)
0.1330 ± 0.0030 (Ertu�gral et al., 2007)
0.1450 ± 0.0040 (Porikli and kurucu, 2008)
0.1410 ± 0.0050 (Porikli and kurucu, 2008)
0.1350 ± 0.0050 (Porikli and kurucu, 2008)
Z ¼ 29, Cu 0.1382 ± 0.0016 (Casnati et al., 1985) 0.1339 0.1345 0.0054 0.0030 0.0014
0.1211 ± 0.0019 (Kucuk€onder et al. 1993)
0.1335 ± 0.0006 (Padhi and Dhal, 1995)
0.1360 ± 0.0006 (Raj et al., 1998)
0.1358 ± 0.0017 (B�e et al., 1998)
0.1340 ± 0.0130 (Ertu�grul, S€ogut, et al., 2001)
0.1343 ± 0.0012 (Raj et al., 2002)
0.1374 ± 0.0113 (Sogut et al., 2002)
0.1370 ± 0.0110 (Cevik et al., 2005)
0.1390 ± 0.0130 (€Oz,2006)
0.1220 ± 0.0100 (Han et al., 2007)
0.1360 ± 0.0050 (Cevik et al., 2007)
0.1359 ± 0.0030 (Ertu�gral et al., 2007)
0.1314 ± 0.0087 (Kup Aylikci et al., 2009)
0.1370 ± 0.0052 (Han and Demir, 2010)
Z ¼ 30, Zn 0.1360 ± 0.0100 (Ertu�grul, S€ogut, et al., 2001) 0.1318 0.1245 0.0114 0.0087 0.0034
0.1254 ± 0.0102 (Sogut et al., 2002)
0.1580 ± 0.0050 (Ertugrul, 2002)
0.1410 ± 0.0100 (€Oz,2006)
0.1260 ± 0.0100 (Han et al., 2007)
0.1360 ± 0.0050 (Cevik et al., 2007)
0.1379 ± 0.0050 (Ertu�gral et al., 2007)
0.1225 ± 0.0007 (Yalcin, 2007)
0.1267 ± 0.0011 (Yalcin, 2007)
0.1200 ± 0.0061 (Kup Aylikci et al., 2010)
0.1200 ± 0.0061 (Kup Aylikci et al., 2011)
Z ¼ 31, Ga 0.1430 ± 0.0110 (€Oz,2006) 0.1430 0.1430 0.0000 0.0000 0.0000
0.1430 ± 0.0060 (Cevik et al., 2007)
J o u r n a l o f R a d i a t i o n R e s e a r c h a nd A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 74
Please cite this article in press as: Kahoul, A., et al., New procedure calculation of photon-induced Kb/Ka intensity ratios forelements 16S to 92U, Journal of Radiation Research and Applied Sciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
Z ¼ 44, Ru 0.2126 ± 0.0005 (Padhi and Dhal, 1995) 0.1964 0.2066 0.0177 0.0162 0.0088
0.1980 ± 0.0160 (Ertu�grul, S€ogut, et al., 2001)
0.1714 ± 0.0013 (Yalcin, 2007)
0.2034 ± 0.0010 (Yalcin, 2007)
Z ¼ 45, Rh 0.2033 ± 0.0020 (Marques et al., 1980) 0.2077 0.2075 0.0044 0.0011 0.0025
0.2078 ± 0.0005 (Padhi and Dhal, 1995)
0.2120 ± 0.0170 (Ertu�grul, S€ogut, et al., 2001)
Z ¼ 46, Pd 0.2061 ± 0.0016 (Marques et al., 1980) 0.2059 0.2118 0.0059 0.0062 0.0030
0.2124 ± 0.0005 (Padhi and Dhal, 1995)
0.2070 ± 0.0140 (Ertu�grul, S€ogut, et al., 2001)
(continued on next page)
J o u rn a l o f R a d i a t i o n R e s e a r c h and A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 7 5
Please cite this article in press as: Kahoul, A., et al., New procedure calculation of photon-induced Kb/Ka intensity ratios forelements 16S to 92U, Journal of Radiation Research and Applied Sciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
Z ¼ 55, Cs 0.2340 ± 0.0180 (Ertu�grul, S€ogut, et al., 2001) 0.2220 0.2171 0.0128 0.0108 0.0057
0.2165 ± 0.0007 (Yalcin, 2007)
0.2287 ± 0.0012 (Yalcin, 2007)
0.2021 ± 0.0010 (Yalcin, 2007)
0.2287 ± 0.0012 (Yalcin, 2007)
Z ¼ 56, Ba 0.2350 ± 0.0170 (Ertu�grul, S€ogut, et al., 2001) 0.2323 0.2294 0.0102 0.0110 0.0036
0.2270 ± 0.0180 (Han et al., 2007)
0.2380 ± 0.0100 (Cevik et al., 2007)
0.2472 ± 0.0050 (Ertu�gral et al., 2007)
0.2118 ± 0.0013 (Yalcin, 2007)
0.2355 ± 0.0008 (Yalcin, 2007)
0.2307 ± 0.0058 (Timmaraju and Premachand, 2009)
0.2331 ± 0.0058 (Timmaraju and Premachand, 2009)
Z ¼ 57, La 0.2414 ± 0.0036 (Marques et al., 1980) 0.2452 0.2432 0.0061 0.0043 0.0030
0.2420 ± 0.0020 (Ertugrul, S‚ ims‚ek, et al., 2001)
0.2430 ± 0.0210 (Ertu�grul, S€ogut, et al., 2001)
0.2542 ± 0.0050 (Ertu�gral et al., 2007)
Z ¼ 58, Ce 0.2450 ± 0.0020 (Ertugrul, S‚ ims‚ek, et al., 2001) 0.2444 0.2452 0.0021 0.0010 0.0009
0.2440 ± 0.0180 (Ertu�grul, S€ogut, et al., 2001)
0.2410 ± 0.0130 (Ertugrul et al.,, 2002)
J o u r n a l o f R a d i a t i o n R e s e a r c h a nd A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 76
Please cite this article in press as: Kahoul, A., et al., New procedure calculation of photon-induced Kb/Ka intensity ratios forelements 16S to 92U, Journal of Radiation Research and Applied Sciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
Z Kb/Ka(exp) References Kb=Ka Kb=KaW USD(Kb/Ka) WSD (Kb/Ka) USE (Kb/Ka)
0.2460 ± 0.0050 (Ertu�gral et al., 2007)
0.2460 ± 0.0050 (Ertu�gral , 2007)
Z ¼ 59, Pr 0.2550 ± 0.0020 (Ertugrul, S‚ ims‚ek, et al., 2001) 0.2443 0.2508 0.0084 0.0098 0.0042
0.2470 ± 0.0190 (Ertu�grul, S€ogut, et al., 2001)
0.2376 ± 0.0050 (Ertu�gral et al., 2007)
0.2376 ± 0.0050 (Ertu�gral , 2007)
0.2350 ± 0.0200 (Durak and €Ozdemir, 1998)
Z ¼ 60, Nd 0.2470 ± 0.0020 (Ertugrul, S‚ ims‚ek, et al., 2001) 0.2449 0.2450 0.0048 0.0031 0.0014
0.2480 ± 0.0180 (Ertu�grul, S€ogut, et al., 2001)
0.2470 ± 0.0140 (Ertugrul et al.,, 2002)
0.2420 ± 0.0060 (Demir and S‚ ahin, 2007a)
0.2490 ± 0.0150 (Demir and S‚ ahin, 2007a)
0.2490 ± 0.0150 (Demir and S‚ ahin, 2007a)
0.2418 ± 0.0060 (Demir and S‚ ahin, 2007b)
0.2495 ± 0.0150 (Demir and S‚ ahin, 2007b)
0.2495 ± 0.0150 (Demir and S‚ ahin, 2007b)
0.2402 ± 0.0050 (Ertu�gral et al., 2007)
0.2402 ± 0.0050 (Ertu�gral , 2007)
0.2400 ± 0.0220 (Durak and €Ozdemir, 1998)
Z ¼ 62, Sm 0.2520 ± 0.0020 (Ertugrul, S‚ ims‚ek, et al., 2001) 0.2454 0.2510 0.0054 0.0062 0.0022
0.2510 ± 0.0190 (Ertu�grul, S€ogut, et al., 2001)
0.2390 ± 0.0190 (Han et al., 2007)
0.2451 ± 0.0080 (Ertu�gral et al., 2007)
0.2451 ± 0.0080 (Ertu�gral , 2007)
0.2420 ± 0.0180 (Durak and €Ozdemir, 1998)
Z ¼ 63, Eu 0.2540 ± 0.0030 (Ertugrul, S‚ ims‚ek, et al., 2001) 0.2453 0.2463 0.0073 0.0072 0.0022
0.2540 ± 0.0200 (Ertu�grul, S€ogut, et al., 2001)
0.2390 ± 0.0150 (Demir and S‚ ahin, 2007a)
0.2400 ± 0.0030 (Demir and S‚ ahin, 2007a)
0.2400 ± 0.0030 (Demir and S‚ ahin, 2007a)
0.2388 ± 0.0150 (Demir and S‚ ahin, 2007b)
0.2402 ± 0.0030 (Demir and S‚ ahin, 2007b)
0.2403 ± 0.0030 (Demir and S‚ ahin, 2007b)
0.2549 ± 0.0030 (Ertu�gral et al., 2007)
0.2549 ± 0.0030 (Ertu�gral , 2007)
0.2440 ± 0.0210 (Durak and €Ozdemir, 1998)
Z ¼ 64, Gd 0.2570 ± 0.0030 (Ertugrul, S‚ ims‚ek, et al., 2001) 0.2510 0.2534 0.0065 0.0065 0.0019
0.2550 ± 0.0200 (Ertu�grul, S€ogut, et al., 2001)
0.2440 ± 0.0200 (Han et al., 2007)
0.2470 ± 0.0050 (Demir and S‚ ahin, 2007a)
0.2480 ± 0.0060 (Demir and S‚ ahin, 2007a)
0.2480 ± 0.0060 (Demir and S‚ ahin, 2007a)
0.2473 ± 0.0050 (Demir and S‚ ahin, 2007b)
0.2487 ± 0.0060 (Demir and S‚ ahin, 2007b)
0.2481 ± 0.0060 (Demir and S‚ ahin, 2007b)
0.2622 ± 0.0050 (Ertu�gral et al., 2007)
0.2622 ± 0.0050 (Ertu�gral , 2007)
Z ¼ 65, Tb 0.2590 ± 0.0030 (Ertugrul, S‚ ims‚ek, et al., 2001) 0.2562 0.2578 0.0041 0.0032 0.0024
0.2580 ± 0.0200 (Ertu�grul, S€ogut, et al., 2001)
0.2515 ± 0.0070 (Ertu�gral et al., 2007)
Z ¼ 66, Dy 0.2470 ± 0.0210 (Durak and €Ozdemir, 1998) 0.2661 0.2741 0.0143 0.0111 0.0043
0.2630 ± 0.0030 (Ertugrul, S‚ ims‚ek, et al., 2001)
0.2590 ± 0.0210 (Ertu�grul, S€ogut, et al., 2001)
0.2460 ± 0.0200 (Han et al., 2007)
0.2770 ± 0.0300 (Demir and S‚ ahin, 2007a)
0.2780 ± 0.0030 (Demir and S‚ ahin, 2007a)
0.2780 ± 0.0030 (Demir and S‚ ahin, 2007a)
0.2774 ± 0.0300 (Demir and S‚ ahin, 2007b)
0.2779 ± 0.0030 (Demir and S‚ ahin, 2007b)
0.2780 ± 0.0030 (Demir and S‚ ahin, 2007b)
0.2461 ± 0.0090 (Ertu�gral et al., 2007)
Z ¼ 67, Ho 0.2500 ± 0.0190 (Durak and €Ozdemir, 1998) 0.2584 0.2606 0.0050 0.0026 0.0015
0.2600 ± 0.0020 (Ertugrul, S‚ ims‚ek, et al., 2001)
0.2600 ± 0.0210 (Ertu�grul, S€ogut, et al., 2001)
(continued on next page)
J o u rn a l o f R a d i a t i o n R e s e a r c h and A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 7 7
Please cite this article in press as: Kahoul, A., et al., New procedure calculation of photon-induced Kb/Ka intensity ratios forelements 16S to 92U, Journal of Radiation Research and Applied Sciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
Z ¼ 73, Ta 0.2648 ± 0.0316 0.2646 ± 0.0019 0.2614 ± 0.0309 0.2634 ± 0.0095
Z ¼ 74, W 0.2656 ± 0.0200 0.2651 ± 0.0275 0.2625 ± 0.0219 0.2643 ± 0.0202
Z ¼ 75, Re 0.2663 ± 0.0079 0.2657 ± 0.0186 0.2635 ± 0.0102 0.2654 ± 0.0115
Z ¼ 76, Os 0.2670 ± 0.0148 0.2664 ± 0.0242 0.2646 ± 0.0173 0.2665 ± 0.0171
Z ¼ 77, Ir 0.2677 ± 0.0174 0.2672 ± 0.0252 0.2657 ± 0.0193 0.2677 ± 0.0177
J o u r n a l o f R a d i a t i o n R e s e a r c h a nd A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 714
Please cite this article in press as: Kahoul, A., et al., New procedure calculation of photon-induced Kb/Ka intensity ratios forelements 16S to 92U, Journal of Radiation Research and Applied Sciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
J o u r n a l o f R a d i a t i o n R e s e a r c h a nd A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 716
between the theoretical and experimental values for the
whole range of used atomic numbers. In this article, the new
intensity ratio values have been given in the field of atomic
inner-shell ionization processes in addition to the available
experimental and theoretical intensity ratios.
r e f e r e n c e s
Bennal, A. S., & Badiger, N. M. (2006). Measurement of K-Lradiative vacancy transfer probabilities for Ta, Au and Pb in 2pgeometrical configuration. Nuclear Instruments and Methods B,247, 161e165.
Bennal, A. S., & Badiger, N. M. (2007). Measurement of K shellabsorption and fluorescence parameters for the elements Mo,Ag, Cd, In and Sn using a weak gamma source. Journal ofPhysics B, 40, 2189e2199.
Bennal, A. S., Niranjan, K. M., & Badiger, N. M. (2010).Determination of K to L shell total vacancy transferprobabilities using a weak gamma source: an alternativemethod. Journal of Quantitative Spectroscopy Radiative Transfer,111, 1363e1371.
B�e, M. M., L�epy, M. C., Plagnard, J., & Duchemin, B. (1998).Measurement of relative X-ray intensity ratios for elements inthe 22 � Z � 29 region. Applied Radiation and Isotopes, 49,1367e1372.
Bhuinya, C. R., & Padhi, H. C. (1992). Alloying effect on the Kb/Kaintensity ratios of Ti, Cr and Ni. Journal of Physics B, 25,5283e5287.
Bhuinya, C. R., & Padhi, H. C. (1993). Alloying effect on the Kb-to-Ka intensity ratios in TixNi1-x and CrxNi1-x alloys studied by g-ray fluorescence and fast proton ionization. Physics Review A,47, 4885e4890.
Casnati, E., Tartari, A., Baraldi, C., & Napoli, G. (1985).Measurement of the Kb/Ka yields ratios of Cu, Mo and Cdstimulated by 59.54 keV photons. Journal of Physics B, 18,2843e2849.
Cevik, U., Kaya, S., Ertugral, B., Baltas, H., & Karabidak, S. M.(2007). K-shell X-ray fluorescence cross-section and intensityratios for som pure metals at 59.5 and 123.6 keV. NuclearInstruments and Methods B, 262, 165e170.
Cevik, U., De�girmencio�glu, _I., Ertu�gral, B., Apaydin, G., & Baltas‚ , H.(2005). Chemical effects on the Kb/Ka X-ray intensity ratios ofMn, Ni and Cu complexes. European Physical Journal D, 36,29e32.
Chang, C. N., Chen, C. T., Yen, C. C., Wu, Y. H., Su, C. W., &Chiou, S. K. (1994). The vanadium Kb/Ka intensity ratios ofsome vanadium compounds. Journal of Physics B, 27,5251e5256.
Demir, D., & S‚ ahin, Y. (2007a). Measurements of K-shell X-rayproduction cross sections and K to L and M-shell radiativevacancy transfer probabilities for Nd, Eu, Gd, Dy and Ho atexcitation with 59.5 keV photons in an external magnetic field.X-Ray Spectrometry, 36, 178e184.
Demir, D., & S‚ ahin, Y. (2007b). Measurement of the K shell X-rayproduction cross-sections and fluorescence yields for Nd, Eu,Gd, Dy and Ho using radioisotope X-ray fluorescence in theexternal magnetic field. European Physical Journal D, 42,211e216.
Dhal, B. B., & Padhi, H. C. (1994). Relative K X-ray intensities insome selected elements between Mn and Sb followingionization by 59.54-keV g rays. Physical Review A, 50,1096e1100.
Durak, R., & €Ozdemir, Y. (1998). K- to L- and M-shell radiativevacancy transfer probability measurements in some elementsfrom Nd to Pb. Journal of Physics B, 31, 6575e6581.
Please cite this article in press as: Kahoul, A., et al., New procedelements 16S to 92U, Journal of Radiation Research and Applied S
Ertugrul, M., S‚ ims‚ek, €O., Dogan, O., €Oz, A., S€ogut, €O., & Turgut, U.(2001). Measurement of the Ka and Kb X-rays polarizationdegree and polarization effect on the Kb/Ka intensity ratio.Nuclear Instruments and Methods B, 179, 465e468.
Ertugrul, M., S€ogut, €O., S‚ ims‚ek, €O., & Buyukkasap, E. (2001).Measurement of Ka/Kb intensity ratios for elements in therange 22 � Z � 69 at 59.5 keV. Journal of Physics B, 34, 909e914.
Ertugrul, M. (2002). Measurement of K shell radiative transitionprobabilities and K, L2 and L3 shell/subshell fluorescenceyields of some elements in the atomic number range30 � Z � 40. Analytica Chimica Acta, 454, 327e334.
Ertugrul, M., Karabulut, A., & Budak, G. (2002). Measurement ofthe K shell absorption jump factor of some elements. Radiationand Physics and Chemistry, 64, 1e3.
Ertu�gral, B., Apaydin, G., Cevik, U., Ertu�gral, M., & Kobya, A._I.(2007). Kb/Ka X-ray intensity ratios for elements in the range16 � Z � 92 excited by 5.9, 59.5 and 123.6 keV photons.Radiation and Physics and Chemistry, 76, 15e22.
Ertu�gral, B. (2007). Experimental measurements of K X-rayproduction cross-sections and yields for the elements with58 � Z � 64 at 123.6 keV photon energy. European PhysicalJournal D, 44, 313e317.
Han, I., S‚ ahin, M., Demir, L., & S‚ ahin, Y. (2007). Measurement of KX-ray fluorescence cross- sections, fluorescence yields andintensity ratios for some elements in the atomic range22 � Z � 68. Applied Radiation and Isotopes, 65, 669e675.
Han, I., & Demir, L. (2010). Charge transfer and delocalizationstudies from Kb-to-Ka X-ray intensity ratios in CoxCu1-x alloys.Annals of Nuclear Energy, 37, 822e826.
Kalayci, Y., Aydinuraz, A., Tugluoglu, B., & Mutlu, R. H. (2007).Valence electronic structure of Ni in Ni-Si alloys from relativeK X-ray intensity studies. Nuclear Instruments and Methods B,255, 438e440.
Kup Aylikci, N., Tiras‚o�glu, E., Apaydin, G., Cengiz, E., Aylikci, V., &Bakkalo�glu, €O. F. (2009). Influence of alloying effect on X-rayfluorescence parameters of Co and Cu in CoCuAg alloy films.Chemical Physics Letters, 475, 135e140.
Kup Aylikci, N., Aylikci, V., Cengiz, E., & Apaydin, G. (2010).Alloying effect on K shell X-ray fluorescence parameters andradiative Auger ratios of Co and Zn in ZnxCo1-x alloys. ChemicalPhysics Letters, 484, 368e373.
Kup Aylikci, N., Aylikci, V., Kahoul, A., Tiras‚o�glu, E.,Karahan, I. H., & Cengiz, E. (2011). Effect of pH treatment on K-shell X-ray intensity ratios and K-shell X-ray-production crosssections in ZnCo alloys. Physical Review A, 84(4),042509e042510.
Kucuk€onder, A., S‚ ahin, Y., Buyukkasap, E., & Kopya, A. (1993).Chemical effects on Kb/Ka X-ray in coordination compoundsof some 3d elements. Journal of Physics B, 26, 101e105.
Marques, M. I., Martins, M. C., & Ferreira, J. G. (1980). Theexperimental relative intensity Kb/Ka in elements with33 � Z � 57. Journal of Physics B, 13, 41e45.
€Oz, E. (2006). Determination of ratios of emission probabilitiesof Auger electrons and K-L- shell radiative vacancy transferprobabilities for 17 elements from Mn to Mo at 59.5 keV.Journal of Quantitative Spectroscopy Radiative Transfer, 97,41e50.
Padhi, H. C., & Dhal, B. B. (1995). Kb/Ka X-ray intensity ratios of Fe,Co, Ni, Cu, Mo, Ru, Rh and Pd in equiatomic aluminides. SolidState Communications, 96, 171e173.
Pawłowski, F., Polasik, M., Raj, S., Padhi, H. C., & Basa, D. K. (2002).valence electronic structures of Ti, Cr, Fe and Co in somealloys from Kb-to-Ka X-ray intensity ratio studies. NuclearInstruments and Methods B, 195, 367e373.
Porikli, S., & Kurucu, Y. (2008). Effects of the external magneticfield and chemical combination on Kb/Ka X-ray intensityratios of some nickel and cobalt compounds. Applied Radiationand Isotopes, 66, 1381e1386.
ure calculation of photon-induced Kb/Ka intensity ratios forciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003
J o u rn a l o f R a d i a t i o n R e s e a r c h and A p p l i e d S c i e n c e s x x x ( 2 0 1 4 ) 1e1 7 17
Raj, S., Padhi, H. C., & Dhal, B. B. (1998). Influence of solid-stateeffects on the Kb-to-Ka X-ray intensity ratios of Ni and Cu invarious silicide compounds. Physical Review B, 58, 9025e9029.
Raj, S., Padhi, H. C., Basa, D. K., Polasik, M., & Pawłowski, F. (1999).Kb-to-KaX-ray intensity ratio studies on the changes of valenceelectronic structures of Ti, V, Cr and Co in their disilicidecompounds. Nuclear Instruments and Methods B, 152, 417e424.
Raj, S., Padhi, H. C., & Polasik, M. (2000). Influence of chemicaleffect on the Kb-to-Ka X-ray intensity ratios of Cr, Mn and Coin CrSe, MnSe, MnS and CoS. Nuclear Instruments and Methods B,160, 443e448.
Raj, S., Padhi, H. C., Palit, P., Basa, D. K., Polasik, M., &Pawłowski, F. (2002). Relative K X-ray intensity studies of thevalence electronic structure of 3d transition metals. PhysicalReview B, 65, 193105e193108.
S‚ ahin, M., Demir, L., & Budak, G. (2005). Measurement of K X-rayfluorescence cross-sections and yields for 5.96 keV photons.Applied Radiation and Isotopes, 63, 141e145.
Please cite this article in press as: Kahoul, A., et al., New procedelements 16S to 92U, Journal of Radiation Research and Applied S
Scofield, J. H. (1974). Relativistic Hartree-Slater values for K and LX-ray emission rates. Atomic Data and Nuclear Data Tables, 14,121e137.
S€o�gut, €O., Seven, O., Baydas‚ , E., Buyukkasap, E., & Kucuk€onder, A.(2001). Chemical effects on Kb/Ka X-ray intensity ratios of Mo,Ag, Cd, Ba, La, Ce, compounds and total mass attenuationcoefficients of Fe and Cu. Spectrochimica Acta Part B, 56,1367e1374.
Sogut, O., Buyukkasap, E., & Erdo�gan, H. (2002). Chemical-effectvariation of Kb/Ka X-ray intensity ratios in 3d elements.Radiation Physics and Chemistry, 64, 343e348.
Timmaraju, P. K. D., & Premachand, K. (2009). Measurement of K-shell X-ray intensity ratios in compounds of Barium. Journal ofPhysics Conference Series, 185, 012033e012035.
Yalcin, P. (2007). Measurement of relative K X-ray intensity ratiofollowing radioactive decay and photoionization. NuclearInstruments and Methods B, 254, 182e186.
ure calculation of photon-induced Kb/Ka intensity ratios forciences (2014), http://dx.doi.org/10.1016/j.jrras.2014.06.003