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NMR Spectroscopy: A Short Course
Example Problem from Textbook:
'e8u?qr PIno^\,(ue ;o senlel eltg 6releuo.llceds
e ur rurulceds eqt ur e8wqc plno^\ tsrll6 'q'seqrsuelul
perroo qlr.r elucs .{cuenber; pepuedxe uu uoerp
^\oqs'1e1dr11nru qcee rod'1e1dr11nru
uoprsod eq1 Surrrroqs '211 ur ,(cuenber; 'saaql € lold 'pesn sr releuorlceds zHI tr-009 V
ur ua.tr8 eru erlceds g141g uolord JreqI 'eu?lnqoJolqc-Zpuu euelnqoJolqc-I eJB If,6HtJ Jo sreuosr elqrssod o.'rr1
'sprrE ourruu JeqloJoJ ueql ,(8reue ur pnbe ,(1:eeu erou ere puoq eprlded eql JosuJtoJ suotl puu .rp eql l?ql ur sprce ounue Suorue pnsnunsr eullord : ord : d '1y\oleq u.{\oqs aru pn dsy ell ord.rrJ: ACIdI epqded (sdnorS HN eelll Surureluoc) prre ourree^u e Jo J.;zN rrrnlceds uI trN eql ur secueuoser HN eqJ .il
'Urqs Iucrureqr 8ur$ercep Jo repro ur 1,(q1eru g pue '1,(qteurL 'LH'LH 'dH 'DH sE ua{ul eq uec sg:rr{s Ierrureqr Jo reproeq1 '(dnor3 I.(qteru e uo suotord eerqt eqt ldecxe) grqsprruer{c luereJJrp ,(lqurnseeru e seq uolord qcBe leqlSurunsse 'eurJnelosr ro; rurulceds ISOJ erp qcte{S .q
'pe^loser tou aru sl,(qleur g o^u eql tuql puepelloseJ tou eJB suoloJd g/ o,16 eq1 luqt Sulunss? 'eurrnelro; urelled ISOJ eql s.troqs (q)91'7y ern8rg 'grqsFcrrueqr Sursuercep Jo JepJo ur ,1,(q1eur g pue '1,(qteute'tu'{u'dH'"H se ue{B} eq uec surqs Ie3rureqc Joropro eqJ '(dnor8 1,(qteu e uo suolord eerql eqt ldecxe)Urr{s pcrueq, tuereJJlp .(yqernsueru u seq uolord qceeturp Sururnsse 'eurcnel ro; rurulceds ISOJ erlt qcleIs .B
'lueruuedxe ISOJ u ur s>1ued ssorc;o surellud crlsrrelcuJer1c e,rr8 ,(eql'uretord e olur pelerod-.rocu1 'uolord o11 euo sug osle esJnoJ Jo prce ourrrru qcuA'1dq1eru g E pue '1(qteu zL u 'suotord'H o^t 'uotord dp1
euo seq eurcnelosr Jo uruqc eprs eqI 's1,(qleur g o,^A1 pue'uolord r11 euo 'suolo.rd dH o^1 seq eurcnel Jo ureqc eprseq1 'xrpuedde eql ur ue,tr3 eJu seJnlcn4s lreql :reqlo qceeJO SJATUOST eJB luq] SprCB OUTTUB eJe euronelosr pue eurcne.I
'sgoN peJnseeu eql Jo srurelur re,l.rsrre rno,( ureldxg eleeqs-6| lelpredque ro '1eeqs-6/ 1e1-prud'xr1eq-lr lI sI leprrded ogt Jo ernlcruts eql sr tBqA\
'uolo;d epruru euruBIB ue ol gON u?seq uolo;d n eurs,(1 qJ€e 'acuulsur Jo; iuolo;d eprure lxeueql ol .(lrsuelul e]€Jepou Jo AON ue seq uolord "H qrrg 'g
'uolord (N11) oprue euruEIE ue o1 gg51 3uor1se suq (Ng) epnue eursdl rlcee'acuelsur ro; iuolord eprurutxeu eq] ot AON esuetur fuel e suq uolord eprue qceg 'l
:pe^Jesqo eJesgg51 Sur.LrolyoJ eql '(eurcnel sr T 'eurusle sr y 'eurs.(1sl )) )vlY\.)IYTV\a)Ylwx :eprtdedo8rlo IopourIIEUs egl 8ur,{pn1s u1 ('uolord e eql uroq ,(u,,ru sanprsereerql uolord eprur? uu ol sreJer 6 1 r lducsqns eql)
r+1'NH _ DH
NH*"HNH_NH
.J
'q
HH
.ZI
uddv'L zt 0't BO
.0L
.99
.09"91.09"9V
E<
LV
s<LL
e'n
n't9E8'Z
'urlceds asetp ol esu e.tr8 ol Surunccoeq ,(eu luqm ureldxe 'srurel lereue8 u1 'e:nluredruel Jo uon-runJ e se u,roqs sr (CCCCVIVfCJCJ)p rauo8rlo ypqe ut (1 uo) dnor8 1.(qteru e18urs e urorg urrulceds UI N eqI
'ureldxg ipeqsrnS-uDsrp eq IIqs sprce oufirr? o.rJ eql u?c 'pe^Ioser ]oueJe eurcnelosr ;o suolord L o,r1 eql pue 'eurcnal Josldqteur g o^\t eqt 'eurcnel Jo suolord gl o,u1 eq1;1 'eurc-nelosr pue eurcnel uee.llteq qsrn8urlsrp o1 nof molpslued ssorc ;o surelled luereJJrp eql .^aor{ eqrrJseq .J
149 | sLualqor6
:s.4AoIIoJ se pezrJerrrurns eru sleaqs-gl prru secrleq-i,ul (NH) uolord epruu eql pue ("11) uoq;ec l: erll uouolord eq1 roJ (y u, secuelsrp uolord-uolord pcrd,(1 'c