ITT Chng Ch 10 Chemical Bonding II

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Kbifokcn Hld`odg OO1

Flnikuncr Gilfitry cd`

Byhro`ozctold le Ctlfok Lrhotcns

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3=3

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Ucnidki sbinn iniktrld pcor ripunsold!"#$%&' fl`in1

%ri`okt tbi gilfitry le tbi flnikuni erlf tbi iniktrlstctokri(unsolds hit)iid tbi iniktrld !hld`odg cd` dldhld`odg' (cors

CH* * =

Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

3=3

nodicr nodicr

H H

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Kn KnHi

* ctlfs hld`i` tl kidtrcn ctlf

= nldi (cors ld kidtrcn ctlf

3=3

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CH* * = nodicr nodicr

Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

CH, , =trogldcn

(ncdcr

trogldcn

(ncdcr

3=3

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3=3

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CH* * = nodicr nodicr

Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

CH, , =trogldcn

(ncdcr

trogldcn

(ncdcr

3=3

CH- - = titrcbi`rcn titrcbi`rcn

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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CH* * = nodicr nodicr

Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

CH, , =trogldcn

(ncdcr

trogldcn

(ncdcr

3=3

CH- - = titrcbi`rcn titrcbi`rcn

CH. . =trogldcn

ho(yrcfo`cn

trogldcn

ho(yrcfo`cn

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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CH* * = nodicr nodicr

Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

CH, , =trogldcn

(ncdcr

trogldcn

(ncdcr

3=3

CH- - = titrcbi`rcn titrcbi`rcn

CH. . =trogldcn

ho(yrcfo`cn

trogldcn

ho(yrcfo`cn

CH/ / = lktcbi`rcnlktcbi`rcn

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

12/65 3=3

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

13/65 3=3

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hld`odg(cor s hld`odg

(cor ri(unsold

nldi(cor s nldi (cor

ri(unsold

nldi(cor s hld`odg

(cor ri(unsold8 8

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Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

CH, , =trogldcn

(ncdcr

trogldcn

(ncdcr

CH*$ * 3

trogldcn

(ncdcr hidt

3=3

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

CH,$ , 3

CH- - = titrcbi`rcn titrcbi`rcn

titrcbi`rcntrogldcn

(yrcfo`cn

3=3

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

CH- - = titrcbi`rcn titrcbi`rcn

3=3

CH,$ , 3 titrcbi`rcn

trogldcn

(yrcfo`cn

CH*$* * * titrcbi`rcn hidt

B

L

B

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

18/65

Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

3=3

CH. . =trogldcn

ho(yrcfo`cn

trogldcn

ho(yrcfo`cn

CH-$ - 3

trogldcn

ho(yrcfo`cn

`ostlrti`

titrcbi`rld

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Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

3=3

CH. . =trogldcn

ho(yrcfo`cn

trogldcn

ho(yrcfo`cn

CH-$ - 3

trogldcn

ho(yrcfo`cn

`ostlrti`

titrcbi`rld

CH,$* , *trogldcn

ho(yrcfo`cn;sbc(i`

Kn0

0

0

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

3=3

CH. . =trogldcn

ho(yrcfo`cn

trogldcn

ho(yrcfo`cn

CH-$ - 3

trogldcn

ho(yrcfo`cn

`ostlrti`

titrcbi`rld

CH,$* , *trogldcn

ho(yrcfo`cn;sbc(i`

CH*$, * ,

trogldcn

ho(yrcfo`cn nodicrO

O

O

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Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

3=3

CH/ / = lktcbi`rcnlktcbi`rcn

CH.$ . 3 lktcbi`rcns9ucri

(yrcfo`cn

Hr

0 0

00

0

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

22/65

Kncss

+ le ctlfs

hld`i` tl

kidtrcn ctlf

+ nldi

(cors ld

kidtrcn ctlf

Crrcdgifidt le

iniktrld (cors

Flnikuncr

Gilfitry

"#$%&

3=3

CH/ / = lktcbi`rcnlktcbi`rcn

CH.$ . 3 lktcbi`rcns9ucri

(yrcfo`cnCH-$* - * lktcbi`rcn

s9ucri

(ncdcr

5i

0 0

00

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3=3

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%ri`oktodg Flnikuncr Gilfitry

3 7rc) 2i)os strukturi elr flnikuni

* Kludt dufhir le nldi (cors ld tbi kidtrcn ctlf cd`

dufhir le ctlfs hld`i` tl tbi kidtrcn ctlf

, ?si "#$%& tl (ri okt tbi gilfitry le tbi flnikuni

bct cri tbi flnikuncr gilfitrois le #L*cd` #0-:

#L L

CH*$

hidt

#

0

0

0 0

CH-$

`ostlrti`

titrcbi`rld

3=3

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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7o(lni Flfidts cd` %lncr Flnikunis

3=*

B 0

iniktrld rokb

rigoldiniktrld (llr

rigold

+

> 6 4 r

6 os tbi kbcrgi

r os tbi `ostcdki hit)iid kbcrgis

3 7 > ,,/ 4 3=,=K f

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3=*

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3=*

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3=*

bokb le tbi elnnl)odg flnikunis bci c `o(lni flfidt:

B*L< KL*< #L*< cd` KB-

LB

B`o(lni flfidt

(lncr flnikuni

#L

L

KL L

dl `o(lni flfidt

dld(lncr flnikuni

`o(lni flfidt

(lncr flnikuni

K

B

B

BB

dl `o(lni flfidt

dld(lncr flnikuni

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7lis H0,bci c

`o(lni flfidt:

3=*

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7lis KB*Kn*bci

c `o(lni flfidt:

3=*

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3=*

Kb o O C o Fo L

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Kbifostry Od Cktold1 Fokrl)ci Lids

B ` 2 o b n o b h ` o B ` 0 :

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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Hld` 7osslkoctold $dirgy Hld` 2idgtb

B*

0*

-,/- Mflni

3.=/ Mflni

- (f

3-* (f

"cnidki hld` tbilry @ hld`s cri elrfi` hy sbcrodgle ierlf lirnc((odg ctlfoklrhotcns

Lirnc( Le

* 3s

* *(

Bl) `lis 2i)os tbilry i4(ncod tbi hld`s od B*cd` 0*:

#bcrodg le t)l iniktrlds hit)iid tbi t)l ctlfs

3=,

Kbcdgi od ]ltidtocn Idirgy le Pwl By`rlgid Ctlfs

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3=,

Kbcdgi od ]ltidtocn Idirgy le Pwl By`rlgid Ctlfs

cs c Eudktold le Pbior @ostcdki le [icrctold

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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Kbcdgi od iniktrld

`idsoty cs t)l by`rlgidctlfs c((rlckb ickb

ltbir

3=,

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"cnidki Hld` ;bilry cd` IB,

I @ 3s**s**(,

, B @ 3s3

Oe tbi hld`s elrf erlf lirnc( le , *( lrhotcns ld dotrlgid

)otb tbi 3s lrhotcn ld ickb by`rlgid ctlf< )bct )lun`tbi flnikuncr gilfitry le IB,hi:

Oe usi tbi

, *( lrhotcns

(ri`okt E==

Cktucn BIB

hld` cdgni os

3=,=

3=-

B ! o`o to o o e t t o

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By!ro`o"ctold@ fo4odg le t)l lr flri ctlfok

lrhotcns tl elrf c di) sit le byhro` lrhotcns

3 Fo4 ct nicst * dldi9uocnidt ctlfok lrhotcns !i.g.scd` (' Byhro` lrhotcns bci iry `oeeiridt sbc(i

erlf lrogodcn ctlfok lrhotcns

* Iufhir le byhro` lrhotcns os i9ucn tl dufhir le(uri ctlfok lrhotcns usi` od tbi byhro`ozctold

(rlkiss

, Klcnidt hld`s cri elrfi` hy1

c Lirnc( le byhro` lrhotcns )otb ctlfok lrhotcns

h Lirnc( le byhro` lrhotcns )otb ltbir byhro`

lrhotcns 3=-

Elrfctold le sp; By!ro` #r!otcns

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3=-

Elrfctold le sp By!ro` #r!otcns

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3=-

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3=-

%ri`okt klrrikt

hld` cdgni

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Elrfctold le spBy!ro` #r!otcns

3=-

Elrfctold le sp8 By!ro` #r!otcns

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Elrfctold le sp8By!ro` #r!otcns

3=-

Bl) `l O (ri`okt tbi byhro`ozctold le tbi kidtrcn ctlf:

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+ le 2ldi %cors

+ le Hld`i` Ctlfs Byhro`ozctold $4cf(nis*

,

-

.

/

s(

s(*

s(,

s(,`

s(,

`*

HiKn*

H0,

KB-< IB,< B*L

%Kn.

#0/

Bl) `l O (ri`okt tbi byhro`ozctold le tbi kidtrcn ctlf:

3 7rc) tbi 2i)os strukturi le tbi flnikuni

* Kludt tbi dufhir le nldi (cors CI7 tbi dufhir le

ctlfs hld`i` tl tbi kidtrcn ctlf

3=-

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3=-

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3=.

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3=.

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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#ogfc hld` !' @ iniktrld `idsoty hit)iid tbi * ctlfs%o hld` !' @ iniktrld `idsoty chli cd` hinl) (ncdi le duknio

le tbi hld`odg ctlfs 3=.

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3=.

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3=.

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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3=.

7iskrohi tbi hld`odg od KB L

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7iskrohi tbi hld`odg od KB*L

KB

L

BK @ , hld`i` ctlfs< = nldi (cors

K @ s(*

3=.

#o ! ' ` %o H ` ! '

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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#ogfc !' cd` %o Hld`s !'

#odgni hld` 3 sogfc hld`

7luhni hld` 3 sogfc hld` cd` 3 (o hld`

;ro(ni hld` 3 sogfc hld` cd` * (o hld`s

Bl) fcdy cd` hld`s cri od tbi ckitok cko`!odigcr' flnikuni KB,KLLB:

K

B

B

KB

L

L Bhld`s > / 3 >

hld`s > 3

3=.

L

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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Flnikuncr lrhotcn tbilry @ hld`s cri elrfi` erlf

odtircktold le ctlfok lrhotcns tl elrf flnikuncr

lrhotcns

LL

Il ud(cori` i

#blun` hi `ocfcgditok

$4(irofidts sbl) L*os (crcfcgditok

3=/

$dirg ni ins le hld`odg cd` cdtohld`odg flnik ncr

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

54/65

$dirgy niins le hld`odg cd` cdtohld`odg flnikuncr

lrhotcns od by`rlgid !B*'

C hld`odg flnikuncr lrhotcnbcs nl)ir idirgy cd` grictir

stchonoty tbcd tbi ctlfok lrhotcns erlf )bokb ot )cs elrfi`

Cd cdtohld`odg flnikuncr lrhotcnbcs bogbir idirgy cd`

nl)ir stchonoty tbcd tbi ctlfok lrhotcns erlf )bokb ot )cs

elrfi` 3=/

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3=/

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3=/

Pwl ]lsso!ni Odtircktolds Hitwiid Pwl I$uo%cnidt p #r!otcns

7/29/2019 ITT Chng Ch 10 Chemical Bonding II

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Pwl ]lsso!ni Odtircktolds Hitwiid Pwl I$uo%cnidtp#r!otcns

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3=/

& n n # !ot n '( K eo to

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3 ;bi dufhir le flnikuncr lrhotcns !FLs' elrfi` os cn)cys

i9ucn tl tbi dufhir le ctlfok lrhotcns klfhodi`

* ;bi flri stchni tbi hld`odg FL< tbi niss stchni tbi

klrris(ld`odg cdtohld`odg FL

, ;bi eonnodg le FLs (rlkii`s erlf nl) tl bogb idirgois- $ckb FL kcd ckklffl`cti u( tl t)l iniktrlds

. ?si Bud`s runi )bid c``odg iniktrlds tl FLs le tbi

scfi idirgy

/ ;bi dufhir le iniktrlds od tbi FLs os i9ucn tl tbi suf le

cnn tbi iniktrlds ld tbi hld`odg ctlfs

3=

&lnikuncr #r!otcn '( Kldeogurctolds

I fhir le I fhir le

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!ld` lr`ir>3

*

Iufhir le

iniktrlds od

hld`odg

FLs

Iufhir le

iniktrlds od

cdtohld`odg

FLs

! '

3=

hld`

lr`ir

3 =

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3=

@inlkcnozi` flnikuncr lrhotcnscri dlt kldeodi` hit)iid

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t)l c`Ackidt hld`odg ctlfs< hut cktucnny i4tid` lir tbrii

lr flri ctlfs

3=J

$n t ` ot h ` h n tb n e tb

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$niktrld `idsoty chli cd` hinl) tbi (ncdi le tbi

hidzidi flnikuni

3=J

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3=J

Kbifostry Od Cktold1 HukMyhcnn Cdyldi:

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Kbifostry Od Cktold1HukMyhcnn Cdyldi: