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Intro to Chap 5 ‘Sources of Electricity’ Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and philosophers had observed lightning. It was through the experimentation and research of Franklin that the relationship between lightning and static electricity was confirmed. What is electricity and where does it come from?
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Intro to Chap 5 ‘Sources of Electricity’ Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Dec 22, 2015

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Page 1: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Intro to Chap 5 ‘Sources of Electricity’

Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and philosophers had observed lightning. It was through the experimentation and research of Franklin that the relationship between lightning and static electricity was confirmed. What is electricity and where does it come from?

Page 2: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Years before the discovery of the electron theory by J. J. Thomson, it was suggested by Franklin that electricity consisted of many tiny particles. or electric charges. He further theorized that electrical charges were created by the distribution of electrical particles in nature.

Page 3: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

We have learned that a potential difference or electromotive force is created when electrons are redistributed. A body might assume a charge; its polarity is determined by the deficiency or excess of electrons. People have turned their scientific interests and research to the development of machines and processes that cause an electrical imbalance and an electrical pressure.

Page 4: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

There are six basic sources of electricity or electromotive force. They are friction, chemical action, light, heal, pressure, and magnetism.

Page 5: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

In this chapter, we will discuss in detail producing electricity from chemical action or batteries. You will also learn how electricity is produced using light, solar batteries, pressure, and heat.

Page 6: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

5.1 CHEMICAL ACTION One of the more familiar sources of an

electrical potential or voltage is the battery. In 1790, the Italian scientist, Luigi Galvani, observed a strange phenomena during the dissection of a frog supported on copper wires. Each time he touched the frog with his steel scalpel, its leg would twitch. Galvani reasoned that the frog's leg contained electricity.

Page 7: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Alessandro Volta, another Italian scientist, invented the electric cell, named in his honor, called the voltaic cell. The unit of electrical pressure, the volt, is also named in his honor. Volta discovered that when two dissimilar elements were placed in a chemical that acted upon them, an electrical potential was built up between them. Thus, electricity can be produced by chemical action.

Page 8: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The student can construct several voltaic cells to demonstrate this action. Cut a one inch square of blotting paper and soak it in a strong salt solution. Place the wet paper between a penny and a nickel as shown in Figure 5-1- If a sensitive meter is connected to the coins, i[ will indicate that a small voltage is present.

Page 9: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

In Figure 5-2 electricity is created using a grapefruit. Make small cuts in the skin of a grapefruit. In one cut, place a penny. In the other cut, place a nickel. Once again, a meter will indicate that a small voltage is present. A better cell can be made by placing a carbon rod (these may be removed from an old dry cell) and a strip of zinc in a glass jar containing an acid and water solution, Figure 5-3. Fallow all safety precautions when performing experiments.

Page 10: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Nickel Figure 5-1. A simple cell is produced using

a nickel, a penny, and a salt solution.

Figure 5-2. A grapefruit can be used to produce enough electricity to operate a small radio.

Page 11: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Lesson in safety: When mixing acid and water, always pour

acid into water. Never pour water into acid. Acid will burn your hands and your clothing. Wash your hands at once with clean water if you spill acid on them. Acid may be neutralized with baking soda. See your instructor for first aid!

Page 12: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Acid and water solution

Figure 5-3. This experimental cell, made with zinc, carbon, and acid, produces enough electricity to power the light.

Page 13: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

When the polarity of the carbon rod is tested, it will be positive. The zinc strip is negative. If a wire is connected between these elements, or electrodes, a current will flow. A voltaic cell can be described as a way of converting chemical energy into electrical energy.

In the zinc-carbon example of a voltaic cell, the sulfuric acid (HiSO,) and water (H=0) solution is also known as an electrolyte. When the electrodes are placed in this acid electrolyte, a chemical action takes place. The sulfuric acid breaks down into positive ions (2H+) and negative ions (50,=-).

Page 14: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The negative ions move toward the zinc electrode, and combine with it by making zinc sulfate (ZnSO,). The positive ions move toward the carbon electrode. This action creates a potential difference between the electrodes. The zinc will be negative. The carbon will be positive. This cell will develop about 1.5 volts.

Page 15: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

If a load, such as a light, is connected to the cell, a current flows and the light glows, as seen in Figure 5-3. As the cell is used, the chemical action continues until the zinc electrode is consumed. The chemical equation for this action is:

Page 16: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Zn + H=50, + H=0 - ZnSO,+ H,O + H= f

Zinc plus sulfuric acid plus water chemically reacts to form zinc sulfate and water and free hydrogen gas. This cell cannot be recharged because the zinc has been consumed.

Page 17: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Primary Cells The zinc-carbon cell just described is what

is known as a primary cell. A primary cep is a cell in which the chemical action cannot be reversed. A primary cell cannot be recharged.

Page 18: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Defects in the primary cell

One might think that the chemical action of the zinccarbon primary cell would continue to produce a voltage as long as the active ingredients of the cell were present. In studying the equation for the discharge of the cell, you will observe the formation of free hydrogen gas. Since the carbon electrode does not enter into chemical action.

Page 19: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

the hydrogen forms gas bubbles. These collect around the carbon electrode. As the cell continues to discharge, an insulating blanket of bubbles forms around the carbon. This reduces the output and terminal voltage of the cell. The cell is said to be polarized. The action is called polarization.

Page 20: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

To overcome this defect in the simple voltaic cell, a depolarizing agent can be added. Compounds that are rich in oxygen, such as manganese dioxide (MnO,), are used for this purpose. The oxygen in the depolarizer combines with the hydrogen bubbles and forms water. This chemical action appears as:

Page 21: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

2Mn0z + Hz - MnzO,+ Hi0

The free hydrogen has been removed, so the cell will continue to produce a voltage.

Page 22: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

One might assume that when current is not being used from the cell, the chemical action would also stop. However, this is not true. During the smelting of zinc ore, not all impurities are removed. Small particles of carbon, iron, and other elements remain. These impurities act as the positive electrode for many small cells within the one large cell.

Page 23: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

This chemical action adds nothing to the electrical energy produced at the cell terminals. This action is called local action. It can be reduced by using pure zinc for the negative electrode, or by a process called amalgamation. With amalgamation a small quantity of mercury is added [o the zinc during manufacturing. As mercury is a heavy liquid, any impurities in the zinc will float on the surface of the mercury, causing them [o leave the zinc surface. This process increases the life of a primary cell.

Page 24: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Types of Primary Cells There are many different primary cells.

What follows are details on some of most common primary cells you might encounter.

Page 25: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Zinc-carbon cell Although the primary cell has been

described as a liquid cell, the liquid type is not in common use. Rather, the primary cell is often a dry cell. In x dry cell, the electrolyte is in a paste form as opposed to a liquid form. A dry cell averts the danger of spilling liquid acids.

Page 26: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Flashlight batteries (cells) are examples of dry cells. The dry cell consists of a zinc container that acts as the negative electrode. A carbon rod in the center is the posi tive electrode. Surrounding the rod is a paste made of ground carbon, manganese dioxide, and sal ammoniac (ammonium chloride), mixed with water. The depolarizer is the MnO,.

Page 27: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The ground carbon increases the effectiveness of the cell by reducing its internal resistance. During discharge of the cell, water is formed.

Page 28: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

You may recall having difficulty removing dead cells from a flashlight. This is because the water produced caused the cells to expand. Although this problem has been solved by improved manufacturing techniques, it is still not advisable to leave cells in your flashlight for long periods of time. You should keep fresh cells in your flashlight, so it will be ready for emergency use.

Page 29: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Lesson In safety: Improper battery use can cause leakage

and explosion. Therefore, obey the following precautions.

1. Install the batteries with the positive (+) and negative (-) polarities in the proper direction. 2. Do not use new and old batteries together.

Page 30: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

3. Never attempt to short circuit, disassemble, or heat batteries. Do not throw batteries into a fire.

4. Batteries contain dangerous materials that should be recycled or disposed of properly. Contact your local recycling facility or fire department for more information.

Page 31: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Alkaline cell The alkaline battery uses manganese

dioxide for the positive activating substance. Zinc powder is used as the negative activating substance. A caustic alkali is used for the electrolyte. Recent progress in electronic product design has demanded more compact supply sources.

Page 32: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The number of products needing a large current and a long battery life have increased. This required the development of more advanced batteries. Cylindrical alkaline batteries are now widely used to supply power for electronic products. They can be used with common manganese dioxide batteries, Figures 5-4 and 5-5.

Page 33: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Mercury cell A relatively new type of dry cell is shown

in Figure 5-6. It is called a mercury cell. It creates a voltage of 1.34 volts from the chemical action between zinc (-) and mercuric oxide (+). It is costly to make. However, the mercury cell is better in that it creates about live times more current than the conventional dry cell.

Page 34: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

It also maintains its terminal voltage under load for longer periods of operation. The mercury cell has found wide use in powering field instruments and portable communications systems.

Page 35: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Figure 5-4. AA size alkaline cells.

Figure 5-6. Mercury cell. It creates voltage by chemical action between zinc and mercuric oxide.

Page 36: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Safety adsorbent sleeve Electrolyte absorbent material

Figure 5-5. Cutaway of AA size alkaline cell.

Page 37: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Lithium cell Lithium has the highest negative potential

of all metals. It is, therefore, the best substance for an anode. Many battery makeups are possible by mixing lithium with various cathode substances. Energy densities of these batteries can be computed by respective reaction equations.

Page 38: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Figure 5-7 shows the energy densities of lithium batteries compared with those of conventional batteries. Lithium is the most suitable anode for production of high voltage and lightweight batteries. Refer to Figure 5-8.

Features of lithium batteries, such as voltage and discharge capacity, are determined by the type of cathode substance used. Fluorocarbon is an intercalation (inserted between or among existing elements) compound. It is produced through reaction of carbon powder and fluorine gas. It is expressed in (CF)n.

Page 39: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Silver oxide cell Silver oxide cells have several advantages

over other types of cells. These advantages include:

Very stable discharge voltage.

Page 40: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Excellent high discharge characteristics. High energy density per unit volume. Wide range of operating temperatures. Compact, thin size.

Page 41: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Compact silver oxide batteries have the highest electrical volume and leakage resistance of any battery of that size. They are commonly used in watches. Two types of silver oxide batteries are made for use in watches. One type uses caustic potash for electrolyte. The other uses caustic soda.

Page 42: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The caustic potash battery has the symbol W on the bottom of the battery. It is for high drain use, where more power is needed. It is used in wristwatches with liquid crystal displays and multifunction analog watches.

Page 43: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The caustic soda battery has the symbol SW on the bottom of the battery. It is for low drain use. It is used mostly in single function analog watches. Figure 5-9 shows a cutaway of a silver oxide cell.

Page 44: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Figure 5-7. Theoretical energy densities of lithium batteries compared with conventional batteries. (Panasonic Battery Sales Division)

Page 45: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Figure 5-8. Cross-sectional view of a cylindrical shaped lithium battery. (Panasonic Battery Sales Division)

Electrolyte to absorbent Barrier

Figure 5-9. Cutaway view of a silver oxide cell.

(Panasonic Battery Sales Division)

Page 46: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Secondary Cells A secondary cell can be recharged or

restored. The chemical reaction that occurs on discharge may be reversed by forcing a current through the battery in the opposite direction.

Page 47: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

This charging current must be supplied from another source, which can be a generator or a power supply. Figure 5-10 shows one type of battery charger used for recharging automobile and motorcycle batteries. An alternating current, which will be studied in a later chapter, must be rectified to a direct current for charging the battery.

Page 48: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Figure 510. This type charger is called a trickle charger. It slowly brings a battery back to full charge.

Page 49: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Lead acid cell

A common type of lead acid cell is the car storage battery. A storage battery does not store electricity. Rather, it stores chemical energy, which in turn produces electrical energy.

Page 50: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The active ingredients in a fully charged battery are lead peroxide (P60j, which acts as the positive plate, and pure spongy lead (Pb) for the negative plate. The liquid electrolyte is sulfuric acid (H,50,) and water (H,O). The positive plates are a reddish-brown color. Negative plates are gray.

Page 51: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The chemical reaction is rather involved. However, study the information given in Figure 5-ll. Notice that during discharge, both the spongy lead and the lead peroxide (also called lead dioxide) plates are being changed to lead sulfate and the electrolyte is being changed to water.

Page 52: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

When the cell is recharged, the reverse action occurs. The lead sulfate changes back to spongy lead and lead peroxide; the electrolyte to sulfuric acid.

Figure 5-71. How a lead acid cell works. (ESB Brands, Inc.)

Page 53: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The electrolyte of a fully charged battery is a solution of sulfuric acid and water. The weight of pure sulfuric acid is 1.835 times heavier than water. This is called its specific gravity.

Page 54: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Lesson in safety: During the charging process of a storage

battery, highly explosive hydrogen gas may be present. Do not smoke or light matches near charging batteries. Charge only in a well ventilated room.

Page 55: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Batteries should be first connected to the charger, before the power is applied. Otherwise, the sparks made during connection might ignite the hydrogen gas and cause an explosion.

Page 56: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Specific gravity is the weight of a liquid as it compares to water. The specific gravity of water is 1.000. The acid and water mixture in a fully charged battery has a specific gravity of approximately 1.300 or less.

Page 57: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

As the electrolyte changes to water when the cell discharges, the specific gravity becomes approximately 1.100 to 1.150. Therefore, the specific gravity of the electrolyte can be used to determine the state of charge of a cell.

Page 58: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The instrument used to measure the specific gravity is a hydrometer. The principle of the hydrometer is based on Archimedes principle in physics. This principle states that n floating hour v will displace an amount of liquid equal to its own weight.

Page 59: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

If the cell is in a fully charged state, the electrolyte liquid is heavier, so the float in the hydrometer will not sink as far. The distance that the float does sink, is calibrated in specific gravity on the scale. This can be read as the state of charge of the cell.

Page 60: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Caution: Expensive storage batteries may be

destroyed by excessive vibration and rough handling. Chemicals may break off from the plates and cause internal short circuits and dead cells. Handle a battery gently and be sure it is securely clamped and bolted in your car.

Page 61: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

In the 12-volt automotive battery, six of lead acid cells are placed in a molded hard rubber case. Each cell has its own compartment. At the bottom of each com partment a space, or sediment chamber, is provided.

Page 62: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

This is where particles of chemicals broken from the plates due to chemical action or vibration can collect. Otherwise, these particles would short out the plates and make a dead cell. The individual cells are connected in series by lead alloy connectors.

Page 63: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Caution: Automotive batteries contain ]urge

amounts of lead. Consequently, they should never be disposed of in landfills. Stores that sell automotive batteries are required by law to accept old batteries for recycling.

Page 64: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Nickel-cadmium cell The nickel-cadmium cell is a rechargeable

dry cell. Basically, these are nickel-cadmium alkaline batteries with paste rather than liquid for the electrolyte. The abil ity to be recharged is just one of their advantages. Other advantages include long life, high efficiency, compactness, and lightweight.

Page 65: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The nickel-cadmium cell produces a high discharge current due to its low internal resistance. Other uses include the powering of small radios, burglar alarm systems, camera flushes, and aircraft instruments.

Page 66: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Figure 512. Construction of a nickel-cadmium cell.

(Panasonic Battery Sales Division)

Page 67: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

One type of nickel-cadmium cell uses positive and negative plates, a separator, alkaline electrolyte, a metal case, and a sealing plate with self-resealing safety vent. It is shown in Figure 5l2. The positive plate of this battery is a porous, powdered nickel base plate. It is tilled with nickel hydroxide.

Page 68: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The negative plate is a punched plate of thin steel, coated with cadmium active material. The separator is made of a polyamide fiber. For high temperature uses, it is made of a nonwoven polypropylene fiber. The positive plate, separator, and negative plate are pressed together, wound into a coil. and inserted in the metal case.

Page 69: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The electrolyte is an alkaline aqueous solution. It is totally absorbed into the plate and separator. The metal case is constructed of nickel-plated steel. It is welded on the inside to the negative plate. It becomes the negative pole.

Page 70: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The sealing plate uses a special liquid sealing agent to form a perfect seal. The positive plate is welded on the inside to the sealing plate. It becomes the positive pole. The self-resealing safety vent permits the discharge of gas in the event of an abnormal increase of internal pressure. This prevents against rupture or other damage.

Page 71: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The vent is made of a special alkaline and oxidation resistant rubber. This ensures that operating pressure and safety features will be retained over a long period of time.

Page 72: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The electromechanical processes of a nickel cadmium alkaline cell are outlined below.

Page 73: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

In this process, charging and discharging are reversed in a very efficient manner. The electrical energy used during discharge is regained during recharge. Dur ing the final charging stage, an oxygen gas is created with the reaction occurring at the positive.

Page 74: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

vnxiGve 40H=+Ozf+2H:0+4e ...(I) t f 1 f Hydroxide Oxygen Water Electrons

I'll

This oxygen passes through the separator to the negative. After this, an absorption reaction lakes place at the negative and absorption occurs.

Page 75: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Negative 0:+2H=0+4e ~40H ...(2) f t t f Oxygen Water Electrons Hydroxide ions

Page 76: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

***** Ends before Batteries in Series and Parallel

Page 77: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Missing review 5.1

Page 78: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

5.2 OTHER SOURCES OF ELECTRICAL ENERGY Batteries are a very common source of

electrical energy, however, there are many other sources of electrical power. Devices that convert energy in the forms of light, heat, and mechanical pressure are found everywhere. If you have used a solar powered calculator or a crystal microphone, you have seen these conversions in action.

Page 79: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Electrical Energy from Light Thanks to the United States' space

program, we can convert the sun's light directly into electricity. The invention of the photovoltaic cell, also called solar cell and photocell, made this conversion possible.

Page 80: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The first photovoltaic cell was made from selenium, but today crystalline silicon is used. Photovoltaic cells made from crystalline silicon have a much higher efficiency than the original selenium cells.

Page 81: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Figure 5-76. Comparison of primary and secondary batteries and their uses.

Page 82: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

A photovoltaic cell Figure 5-17, is constructed of two thin layers of crystalline silicon each injected with impurities to form a negative and a positive semiconductor material. When secured together and then exposed to light, an electrical potential is developed. The layers are connected to thin wires that allow the photovoltaic cell to be connected to an electrical circuit.

Page 83: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

See Figure 518. While a typical photovoltaic cell produces approximately I watt and 0.5 volts, the cells can be connected into arrays. Arrays consist of many cells connected in series and parallel to increase the voltage and current capabilities to a level sufficient to power lights and equipment.

Page 84: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

One application of power supplied by photovoltaic cells is power for a residential home. As a demonstration of this type of power, the Boston Edison Power Company built a model home powered by solar cells. The home is powered by two arrays of solar cells mounted on the roof. Each array contains 12 modules with 432 individual cells.

Page 85: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

The solar cells provide approximately 45 percent of the family's electricity. Today, solar cells are commonly used to partially power homes and heat swimming pools. The cells can also supply the complete power needs for items such as calculators, watches, and satellites. In addition, solar cells supply power for remote locations where there are no accessible power lines. See Figure 5-19. Figure 5-20 shows a common solar array for providing power.

Page 86: Intro to Chap 5 ‘Sources of Electricity’  Every student knows the story of Benjamin Franklin and his kite. For centuries before Franklin, scientists and.

Figure 5-18. Two semiconductor materials are sandwiched together to form a photovoltaic cell. Electrical energy is produced when light shines on the cell.

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Figure 5-17. Schematic symbol for a photovoltaic cell.

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Photoelectric control The same principle of generating

electricity from light is used to produce a device called a photoresistive cell. Photoresisfive cells are light sensitive resistors.

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Instead of providing a direct supply of electricity, this device is used to vary the amount of current that can pass through it, much like a variable resistor would do. The photoresistive cell increases circuit resistance when there is no light. It decreases resistance when there is light. The symbol for a photoresis[ive cell is shown in Figure 5-21.

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Figure 5-19. Solar powered radio transmitter used for highway construction.

Figure 5-20. Solar array.

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Electrical Energy from Heat A device used to indicate and cannot the

heat of electric ovens and furnaces is shown in Figure 5-22. This device is called a thermocouple. When two dissimilar metals in contact with each other are heated, a potential difference develops between the metals, Figure 5-23.

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Photoresistive cell Figure 5-21. Schematic symbol for a

photoresistive cell.

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Figure 5-22. Small thermocouple.

Thermocouple symbol

Figure 523. The basic principle of the thermocouple can be demonstrated by heating two dissimilar wires that have been twisted together.

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Commercial types of thermocouples employ various kinds of dissimilar metals and alloys such as nickelplatinum, chromel-alumeh and iron-constantan. These unfamiliar names apply [o alloys specially developed for thermocouples.

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The combination indicating device, including a meter and a thermocouple, is called a pyrometer. For an instrument that must be sensitive to temperature change, a large number of thermocouples can be joined in series. Such a group is known as a thermopile.

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In the demonstration of Figure 5-23, an iron wire and a copper wire are twisted tightly together. Their ends are connected to a sensitive meter, such as a galvanometer. A galvanometer is a device that is capable of measuring very small currents. When the flame of a lit match heats the twisted joint, a reading on the meter can be observed.

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This indicates that an electromotive force is present. The output voltage of a thermocouple can be strengthened and used to work large motors, valves, controls, and recording devices.

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Electrical Energy from Mechanical Pressure Many crystalline substances such as

quartz, tourmaline, and Rochelle salts have a peculiar characteristic. When a voltage is applied to the surfaces of the crystal, the crystal becomes distorted. The opposite is also true.

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If a mechanical pressure or force is applied to the crystal surface, a voltage is developed. The crystal microphone, Figure 5-?A, is a familiar example of this process. Sound waves striking a diaphragm, which is mechanically linked to the crystal surfaces, cause distortion in the crystal. This develops a voltage across its surfaces. Thus, sound waves are converted to the electrical energy.

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Creating electricity by the mechanical distortion of a crystal is known as the piezoelectric effecA Crystals can be cut for particular operating characteristics. In a later chapter, the use of crystals as frequency controls for radio transmitters will be discussed.

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Figure 5-24. A crystal microphone converts sound waves to electrical energy.

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Fuel Cells A fuel cell is constructed much like a

battery cell. Two metallic electrodes are designed to allow hydrogen and oxygen gases to combine with the electrolyte of potassium hydroxide KOH. See Figure 5-25.

Figure 5-25. Fuel cell construction.

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The two metallic electrodes are not part of the chemical reaction, but rather a means to allow the gases [o combine with the electrolyte. Once the gases combine with the electrolyte, ionization occurs. The electrode attached to the oxygen line develops a positive potential, while the electrode connected to the hydrogen line develops a negative potential.

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The chemical reaction in the fuel cell takes place when the gases combine with the potassium hydroxide. The ionization will continue as long as the two gases are supplied to the electrolyte. Typically, the cell develops only 1.23 volts. However, when used in the space program, these cells have been designed to develop over 2 kW of energy.

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The theoretical efficiency of the fuel cell is 100%. There is no heat loss due to chemical reactions. The only by-product of the fuel cell is water, resulting in virtually no pollution.

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Magnetohydrodynamic Power Generation

Electricity is generated when an ionized gas is passed through a magnetic field. This method of producing electricity is called magnetohydrodynamic (MHD). Figure 5-26 is an illustration of the MHD converter.

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Figure 5-26. MHD converter. An ionized gas vapor passes through a magnetic field. The two plates (anode and cathode) called the ions and pass them to the outside to provide electric power.

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A gas, like argon or helium, is heated by solar energy and reaches a temperature in excess of 2000°E At this temperature the gas ionizes. The ionized gas is forced through tubing and passed through a magnetic field. The magnetic field is produced by winding conductors into a coil around a pipe and then energizing the coil with a small amount of direct current.

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As the gas passes through the magnetic field, the ions are collected on two conductive plates. The negative plate is referred to as the cathode, and the positive plate is referred [o as the anode. The terms anode and cathode are used throughout the study of electronics and are directly associated with the polarity described above.

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This type of power is in limited production in Middle Eastern countries. Using the sun to produce this type of energy is relatively cheap, but unfortunately not constantly available.

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Electricity from Magnetism A common source of electrical energy is

the dynamo or generator. Generators prove that magnetism can produce electricity. A generator is a rotating machine that converts mechanical energy into electrical energy. This source of electricity requires detailed study. Chapter 10 is devoted to generators, generator types, and controls.

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Review Questions for Section 5.2

1. The____ produces electricity from light.

2. A light variable resistor is called a(n)_____.

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3. When two different metals are joined together and heated, they produce electricity. This is an example of a(n)______device.

4. A(n)____will produce electricity when pressure is applied to its surface.

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5. A(n)____converts sunlight directly into electricity.

6. An ionized gas passes through a magnetic field and produces electricity. This form of electrical production is made by a(n) device.

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7. Explain how a fuel cell works.

8. What is the polarity of an anode?

9. What is the polarity of a cathode?

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Summary 1. Electricity can be produced by chemical

action. 2. Cells are the basic unit for producing

electricity by chemical action. Batteries are two or more cells connected together.

3. Primary cells cannot be recharged, while secondary cells can be recharged.

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4. Some popular primary cells include the zinc-carbon cell, the alkaline cell, the mercury cell, the lithium cell, and the silver oxide cell.

5. Nickel-cadmium cells and lead-acid cells are secondary cells.

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6. Connecting cells in series (- to +) increases their voltage rating, while connecting them in parallel (- to - and + to +) increases their current rating.

7. Battery capacity is a current producing rating measured in ampere-hours (Ah).

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8. A photovoltaic cell produces electricity from light.

9. Photoresistive cells are light sensitive resistors.

10. The device used to produce electricity by heat is the thermocouple.

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11. Electricity can also be produced by applying pressure to certain objects such as quartz, tourmaline, and Rochelle salts.

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Test Your Knowledge 1. Name six basic sources of electricity or

electromotive force.

2. What safety precautions should be taken when mixing acid and water?

3. A(n)_______is a way of converting chemical energy into electrical energy.

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4. A cell that cannot be recharged is a: a. one-way cell. b. secondary cell. c. primary cell, d. None of the above

5. What is polarization?

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6. List five advantages silver oxide batteries have over other types of batteries.

7. What is the major advantage of the nickel-cadmium cell?

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8. In a(n)____connection, the positive terminal of one cell is connected to the negative terminal of the second cell.

9. In a(n)____connection, all positive terminals are connected and all negative terminals are connected.

10. What is the composition of the electrolyte in a lead acid storage battery?

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11. Specific gravity: a. can be measured with a hydrometer. b. can be used to determine the stale of

charge. c. is the weight of a liquid as it

compares to water. d. All of the above.

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12. What is the measurement of battery capacity?

13. A(n)____is a device used to indicate and control the heat of electric ovens and furnaces. What is the piezoelectric effect?

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Discussion 1. How does chemical action operate our

nervous system? Research this question. Write a brief report on your findings.

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2. Do research on one of the following topics. Give a report in class.

a. The electrical system of a lightning bug.

b. The electric eel.

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3. How can electricity from light be used [o solve some of our energy problems? What are the restrictions?

4. Why do materials such as quartz have a piezoelectric effect?