ISSN: 0973-4945; CODEN ECJHAO E-Journal of Chemistry http://www.e-journals.net 2010, 7(3), 1090-1094 Influence of Benzotriazole on Corrosion Inhibition of Mild Steel in Citric Acid Medium P. MATHESWARAN * and A.K. RAMASAMY * Department of Chemistry, Vidyaa Vikas College of Engineering and Technology, Tiruchengode, Namakkal Dt. -637 214, India. Department of Chemistry, Periyar University, Salem Dt., India. [email protected]Received 6 November 2009; Accepted 2 January 2010 Abstract: Benzotriazole an organic compounds has been studied as corrosion inhibition for mild steel in 1 N citric acid by weight loss method. The result showed that the corrosion inhibition efficiency of the compound was found to be varying with the temperature and acid concentration. Also it was found that the corrosion inhibition behaviour of benzotriazole is better when the concentration of inhibitor is increased. The kinetic treatment of the results shows first order kinetics. Keywords: Mild steel, Corrosion Inhibitors, Weight loss method and Benzotriazole. Introduction Iron and its alloys are extremely used in many engineering application in various environments especially in inorganic and organic acid environments because of their excellent combination of properties 1-2 . Various types of inhibitors have been used as corrosion inhibitors for mild steel corrosion in acidic medium 3 . High electron density of the sulphur and nitrogen atoms in the heterocyclic organic compounds helps the organic molecules to get chemisorbed on to the metal surface 4 . Most of the earlier studies have been related to the general performance and the inhibition of mild steel corrosion in organic acid 5-6 . So in this investigation the corrosion behoviour of mild steel in 1 N citric acid medium in the absence and presence of benzotriazole at various temperature by weight loss method. Experimental According to ASTM method 7 as reported already cold rolled mild steel strips were cut into pieces of 5 cm × 1 cm having the following composition (in percentage) of Fe = 99.686, Ni = 0.013, Mo = 0.015, Cr = 0.043, S = 0.014, P = 0.009, Si = 0.007, Mn = 0.196 and C = 0.017.
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ISSN: 0973-4945; CODEN ECJHAO
E-Journal of Chemistry
http://www.e-journals.net 2010, 7(3), 1090-1094
Influence of Benzotriazole on Corrosion Inhibition of
Mild Steel in Citric Acid Medium
P. MATHESWARAN* and A.K. RAMASAMY
*Department of Chemistry, Vidyaa Vikas College of Engineering and Technology,
Tiruchengode, Namakkal Dt. -637 214, India.
Department of Chemistry, Periyar University, Salem Dt., India.