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Silicon Containing Hybrid Copolymers, First Edition. Edited by Chaobin He and Zibiao Li. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA. Published 2020 byWiley-VCH Verlag GmbH & Co. KGaA.
aadditive manufacturing (AM) 239,
240, 247, 260aerosol jet printing (AJP) 249–251amidation 87anchor zwitterionic polysiloxanes 109anionic polymerization 3, 7, 44, 50, 86,
91anionic ROP (AROP) 51, 81antibiofouling (AF) 1, 109anti‐corrosive 128, 137, 140anti‐fouling 1, 11, 15, 16, 109, 111,
119, 128, 137, 140, 148, 151, 163atom transfer radical polymerization
(ATRP) 7, 41, 45–46, 80, 103, 126, 148, 190
azobisisobutyronitrile (AIBN) 79
bbenzoyl peroxide (BPO) 32, 79bifunctional POSS
developing strategy 74–76special cases 73–74
9,10‐bis(phenylethynyl)‐anthracene (BPEA) 87
ccationic polymers 160, 161, 252chain transfer agents (CTAs) 80, 133click chemistry 2, 7, 42–43, 91, 173, 183coaxial 3D‐printing 245common linear polyorganosiloxane
copolymers 98
controlled radical polymerization (CRP) 45
atom transfer radical polymerization 45–46
methods 50reversible addition fragmentation
chain transfer polymerization 47–50
conventional organic chemistry 27, 68
conventional radical polymerization 43–44, 152
Co‐PDMS@PET fabrics 133, 140cyclic siloxane monomers 26, 99cyclic siloxanes 23, 25–27, 99cyclolinear polycarbosilanes 8
ddeposition of silicone influences 160digital light processing (DLP) 251,
252diglycidyl ether of bisphenol A
(DGEBA) 86, 220, 2541,1‐diphenyletylene (DPE) 87direct ink writing (DIW) 242
coaxial 3D‐printing 245embedded 3D printing 245–246rheology‐controlled shape
retention 242–244docetaxel (DTX) 11, 108double‐decker silsesquioxane
(DDSQ) 14, 76, 78doxorubicin (DOX) 11, 109, 153
Index
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Index266
drug delivery micelles 108dye‐sensitized solar cells (DSSCs) 169
eelectrochromic device 182, 185, 187electrochromic polyamic acid 189electrochromic polymers 182embedded 3D printing 245–246epoxy resins 86, 202, 220–222, 224,
226, 227, 231, 233ethylene glycol dimethacrylate
(EGDMA) 111extrusion‐based printing
direct ink writing 242–246fused deposition
modelling 240–242types 240
ffabrication methods 119, 120field‐effect transistor (FET) 112flexible electronic systems 112free radical polymerization 2, 79, 121,
123, 252fused deposition modelling
(FDM) 240–242
gglycoproteins 155, 156
hhair care 159–160halogenated flame retardants 201highest occupied molecular orbitals
(HOMOs) 169hybrid copolymer, structures 97hydrosilation 178hydrosilylation 42, 66, 91, 178
polymerization 87
iimidazolium iodides 169, 188inkjet 3D‐printing (IJP) 247–249
jjetting‐based printing
aerosol jet printing 249–251inkjet 3D printing 247–249
llowest unoccupied molecular orbitals
(LUMOs) 169
mmacromers
block and graft copolymers 35–43crosslinking of functionalized
polysiloxanes 30–35modifying degree of
polymerization 30step‐growth polymerization 35–41
metallocene‐catalyzed polymerization 87
methacrylisobutyl POSS (MA‐POSS) 100, 104
methyl methacrylate (MMA) 44, 45, 79, 80, 104, 121
mono‐functional POSScorner capping of T7R7(OH)3 71–72substituents modification 73
nnitroxide‐mediated polymerization
(NMRP) 81
oocta‐functional POSS
hydrolysis and condensation from RSiX3 monomer 65–66
substituents modification 66–70octameric silsesquioxane 190octasilsesquioxanes (T8) 6, 63octavinylsilsesquioxane (OVS) 181,
193oil‐water separation
PDMS based superhydrophobic materials 129–135
POSS based superhydrophobic materials 135–136
organosilicon polymers 1–2application 10–17biomaterials application 10–12optical and electronic materials
application 13–15surface modification 15–18synthetic strategies 2
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organosilsesquioxanes 63oxidized polydimethylsiloxane
(ox‐PDMS) 112
pPEOXA‐b‐PDMS‐b‐PEOXA 105perylene diimide (PDIs)
derivatives 192PHEMPOSS‐b‐PMAA 105photo‐curable 3D printing 251
digital light processing 252photopolymerization
process 252–260stereolithography (SLA)
printing 252photo‐curable polymers 254photodynamic therapy (PDT) 99,
109–111photoinitiators 10, 253, 254photopolymerization process
photo‐curable polymers 254–260photoinitiator 253–254
physical reinforcement 211poly(propylene glycol) (PPG) 103polyamic acid 40, 189polycarbonate (PC) 41, 202, 206, 213,
240polycarbosilanes 7–10, 18polydimethylsiloxane (PDMS) 97–98,
109, 111, 120incorporated hybrid copolymer
materials 120–122self‐assembly 99–107
polyepoxides 86, 202, 220–233polyester 38, 41, 51, 78, 79, 83, 202,
216–220polyhedral oligomeric silsesquioxanes
(POSS) 97, 120, 168biomedical applications 107–109building block for electrochromic
material 181–189coating 111–112electroluminescent and
electrochromic materials 189incorporated hybrid copolymer
materials 122–128mono‐functional
corner capping of T7R7(OH)3 71–72
substituents modification 73octa‐functional
hydrolysis and condensation from RSiX3 monomer 65–66
substituents modification 66–70optical sensors 112–113organic electroluminescent
materials 171organic optoelectronic
materials 167–171photodynamic therapy 109–111self‐assembly 99–107structure 64synthetic protocols 76
preparation from monomers 78–87
preparation from polymers 87–91
synthetic strategiesbifunctional 73–76classes 64mono‐functional 71–73octa‐functional 65–70
polymeric materials 64, 171, 239, 240
polypropylene (PP) 17, 85, 147, 202–206
polysilanes 1, 7, 8, 10, 18polysilazanes 1, 2, 7, 9, 10, 18polysiloxanes 3, 7, 23
backbones 42click reaction 43with di‐functional terminals 25with functional side groups 27–29graft copolymers 41–42hydrosilylation 42–43macroinitiators 43–54macromers 30–43with mono‐functional
terminals 25side chains 41–42
polysilsesquioxanes 1, 3, 5–7, 10, 181polystyrene (PS) 45, 80, 100, 106, 120,
138, 202, 211–216polysulfone (PSf ) 41, 137
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pyrene functionalized silsesquioxane cages (PySQ) 193, 194
pyridyldisulfanyl‐functionalized POSS (POSS‐PDS) 108
qquantum confinement effects 172quantum dots (QD) 98, 154, 172
Rradical polymerization
POSS functions as initiators 80–81POSS functions as
monomers 79–80reversible addition fragmentation chain
transfer (RAFT) polymerization 7, 41, 47–50, 80, 100, 123, 151
ring opening metathesis polymerization (ROMP) 41, 81, 87
ring opening polymerization (ROP) 50POSS functions as initiators 81–83POSS functions as monomers 81
sS‐heterocyclic PDI (SPDI) 192silicon based materials 18, 120, 239silicone copolymers
antibacterial effect 148–150antifouling effect 148based bio‐coating 150–152biomedical and healthcare
applications 145–156construction of artificial
cells 154–156drug delivery and
bioimaging 153–154personal care applications 157–162protein adsorption and cell
interaction 146self‐assembly 152–156surfactants 158–159tissue engineering 150
silicone oil emulsions 157–159, 161silsesquioxanes (SQ) 1, 5, 65, 74, 76,
78, 81, 122, 125, 168skin care applications 161–162small molecular semiconductors 167star shaped copolymers (SPP) 80, 87,
137step‐growth polymerization 35–41,
83–86stereolithography (SLA) printing 252,
256, 258superhydrophobicity 16, 111, 119–123,
125, 128, 135–137, 140, 244superhydrophobic materials and
surfaces 119application 128–140hybrid silicon copolymer
materials 120–128lotus effect 119
super‐hydrophobic POSSs 97
ttetraphenylporphyrin tetrasulfonic acid
hydrate (TPPS) 110thermoplastic urethane (TPU) 2413D printing 239
application 260–261extrusion‐based printing 240–246jetting‐based additive
techniques 247–251photo‐curable 3D printing 251–260
tissue engineering 12, 150, 163T7R7(OH)3 derivatives 71
uurethane reaction 91
vvat photopolymerization 251–260
zzwitterionic polymers 109