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Large-scale WW Treatment
Schemes
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• Characteristics of wastewater ( domestic)CONSTI TUENT(mg/l)
STRON G Di l uted Tr eated WWf or dischargeto water bodies
Solids : TotalDissolved, Total
FixedVolatile
Suspended, TotalFixedVolatile
120085052532535075
275
72050030020022055
165
100
Settleable solids 20 10
Biochemical oxygendemand(BOD 5 , 20°C) 400 220
30
Total Organiccompound (TOC)
290 160
Chemical oxygendemand (COD) 1000 500
250
Nitrogen (Total as N)
OrganicFree ammonia Nitrites Nitrates
85
355000
40
152500
50 (NH4)
10( NO3)
Phosphorus (Total as P)OrganicInorganic
155
10
835
5
Chlorides 100 50
Alkalinity (as CaCO 3 ) 200 100
Grease 150 100
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Wastewater Treatment System • Wastewater treatment system in general comprises of three parts:(i) primary treatment
– The objective of primary treatment is to remove suspended, easily settleableand floating material
(ii) secondary treatment, and –
Secondary treatment systems are mostly biological processes to removecolloidal and dissolved carbonaceous organic matter.(iii) tertiary treatment.
– Tertiary treatment systems are aimed at nitrogen and phosphorus removalprovided for polishing the secondary treated effluent to meet the dischargerequirements
(iv) Quaternary treatment : To bring back waste water to the similar orbetter quality as the freshwater by removing dissolved solids so that it can bereused in industries or recycled back into the water supply
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Wastewater Treatment:ReactionsThe aerobic conversion of the organic matter occurs in three steps:1. Oxidation
COHNS + O2 + BACTERIA CO2 + NH3 + END PRODUCTS+ ENERGY(Organic matter)
2. Synthesis of new cellsCOHNS + O2+ BACTERIA + ENERGY C5H7NO2
Organic matter (new cells )3. Endogenous respiration
C5H7NO2 + 5O2 5 CO2+ NH3+ 2H2O + ENERGY(Bacterial cells)
• Tertiary Treatment for nitrogen removal ( Biological)
NH4 + + Nitrifying bacteria NO 3 - + Denitrifying bacteria Nitrogen gas
• Tertiary Treatment for phosporus removal with Alum or Ferric or Lime( Chemical)
Al3+ + PO4 -3 -- AlPO4; Fe3+ + PO4-3 Fe PO4;
Ca(OH)2 + PO4 Ca5OH(PO4)3
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Different Biological Systems
Suspended growthActivated Sludge processSBR, Extended Aeration, contact stabilisation
Attached GrowthTricking Filters, Bio towers
Hybrid systemsRotating Biological Contactors ( RBC)Moving Bed Bio reactors( MBBR)
Membrane Bio reactors (MBR)
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Sewage Treatment Process Selection
Considerations Consideration Goal Treated Sewage qualitystandards
The technology must consistently meet the standards asrequired.
Power requirement The process choice should consider minimizing power
requirements
Land required Minimize land requirement
Capital Cost of Plant Process should allow optimum utilization of capital
Operation & Maintenancecosts
Process design should be conducive to attaining lowerrunning cost
Maintenance requirement Simplicity and reliability Operator attention Easy to understand procedures
Reliability Deliver the desired quality on a consistent basis
Resource Recovery Ability to minimize operational costs.
Load Fluctuations: Plant can able to withstand organic and hydraulic load
fluctuations
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Flow diagram ASP based WWTP
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Bar screen - coarse
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Oil and Grease removal – SkimmingTank
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An empty sedimentation tank.
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secondary Sedimentation tank at a ruraltreatment plant.
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Suspended Growth Processes
Activated Sludge Process
Designed based on loading
(the amount of organicmatter added relative tothe microorganismsavailable)
Commonly called the food-
to-microorganisms ratio,F/M
F measured as BOD. Mmeasured as volatile
suspended solidsConcentration MLSS
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Conventional Activated Sludge Process
• Activated Sludge Process is a suspended growth aerobic process.• About 40% of organic load is removed in primary clarifier• Detention period in aeration tank is maintained between 4-6hours.• A major portion of the sludge is re-circulated and excess sludge is
sent to a digester
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Merits and Demerits – Good process flexibility – Reliable operation – Proven track record in all plant sizes – Less land requirement – Low odour emission – Energy production – Ability to withstand nominal changes in water characteristics
Demerits – High energy consumption –
Skilled operators are needed – Uninterrupted power supply is required – Requires elaborate sludge digestion, drying and disposal arrangement – No nutrient removal
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Extended Aeration ASP SystemExternal substrate is completely removed.
Auto oxidation (internal substrate is used)
Net growth = 0
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Advantages of Extended aeration ASP (IITM plant)
• Sludge production minimal
• Stabilized sludge No digesters are required
• Nutrient requirement minimalDisadvantages of Extended Aeration ASP
• High power requirement
• Large volume of aeration tank
• Suitable for small communities
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Aerated lagoon used to treat wastewaterfrom a hogfarm
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Fine bubble membrane diffusers in anaeration tank
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Sequencing Batch Reactor
• It is a fill-and-draw batch ASP incorporating all the featuresof extended aeration plant.
• Reactor operation takes place in certain sequence in cyclicorder and in each cycle
–
Filling tank – Aeration – Sedimentation/clarification – Decantation – Sludge withdrawal
• A number of large and small scale plants exist with severalyears of continuous operation in India and elsewhere.
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System Schematics
C-Tech Basin
DECANTER SELECTOR
INLET
OUTLET
SLUDGE PUMPDIFFUSER BIOMASS
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SBR Cycle of operation
Inletstart
Inletend
Outletstart
Outletend
B
BB
B B
Aerobic
Aerobic Anoxic
Anoxic
Anoxic
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System Schematics …
3 Hrs
Basin - 1 Settling Decanting
Basin - 2 Settling Decanting
Fill + Aeration
Fill + Aeration
1.5 HrsTime - 0 hrs
Operating sequence of a 2 Basin system
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Ammonia converted to Nitrates in the Aeration basin.
Denitrification of recycled effluent occurs in the selector basin
Denitrification occurs concurrently in the aeration tank duringthe settling / decant phase
Nitrogen gas is stripped off during aeration cycle.
Nitrate diffusion rate is 5 times more than Oxygen. So Nitratereaches the center of the flocs faster than Oxygen, therebypromoting denitrification.
Concurrent Nitrification / Denitrification in SBR
Biofloc
De-nitrification occursin the central portionof the floc
Nitrification happensin the periphery ofthe floc
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Biological Phosphorous Removal in SBR Anaerobic conditions for short time followed by aerobic phase willincrease the uptake of Phosphorous by biomass
During settlement and decant the biomass oxidation reductionpotential depletes from a positive value of around +50 to +100 mVto a negative value of around –150 to – 200 mV. This aids P removal
d
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Over 50% Energy Reduction
Conventional
K W H / K g C O D
Continuous measurement of DO and Temperature in the basin
Predictive calculations of Biological metabolic activity by the PLC
Automatic and dynamic control of aeration time and intensity by the PLCbased on the existing metabolic activity - Oxygen Uptake Rate (OUR).
Recovering the oxygen used for nitrification back in the process bydenitrificationBlower can be switched off during low flow as there is no problem of shortcircuiting like in continuous system like ASP..
Dynamics of OUR and COD-loads
0
200
400
600
800
1.000
1.200
2 5. 6 26. 6 26. 6 26 .6 2 6. 6 27. 6 27. 6 27. 6 27. 6 28. 6 28. 6
[ k g C O D / 2 h r s ]
0
5
10
15
20
25
O U R [ m g / l . h ]
COD
ffc-OUR
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Merits and Demerits of SBR – Excellent effluent quality – Smaller footprint because of absence of primary and secondary
clarifiers, and digester – Proven technology –
Biological nutrient (N and P) removal – High degree of coliform removal – Less chlorine dosing required – Can withstand hydraulic and organic shock loads
Demerits – Comparatively higher energy consumption – To achieve high efficiency, complete automation is required – Highly skilled operators are needed – No energy production – Uninterrupted power supply is required
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Attached growth processTrickling filter
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Attached Growth Systems - Trickling Filters
T.F Reactor in which randomly packed solidsforms provide surface for microbial growth.
- system for wastewater distribution
Specific surface area and porosity
Specific surface area: The amount of surface areaof the media that is available for bio film growth
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A typical complete trickling filter system
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Trickling Filters
With time, the “slime” layerbecomes thicker and thicker untiloxygen and organic matter can notpenetrate to the organisms on theinside.
The organisms on the inside thendie and become detached from themedia, causing a portion of the“slime” layer to “slough off”.
This means the effluent from atrickling filter will have lots of solids(organisms) in it which must be
removed by sedimentation
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Trickling filter- A schematic cross-section of the contact face of the bed of media in a
trickling filter
Trickling Filters Single St ge nd T ost ge
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Trickling Filters -Single Stage and Twostage
Single Stage Trickling Filter
Two Stage Trickling Filter
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Hybrid systemsRotating Biological contactor
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RBCs
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Moving Bed Bio film Reactor
• MBBR is an aerobic attached biological growth process• It does not require primary clarifier and sludge
recirculation.• Raw sewage, after screening and de-gritting, is fed to
the biological reactor.• Floating plastic media is provided which remains in
suspension. Biological mass is generated on the surfaceof the media.
•
Excess biological mass leaves the surface of media andis settled in clarifier.• Usually a detention time of 5 to 12 hours are provided
in the reactors.
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Aerobic reactor Anoxic reactor
Moving bed biofilm reactor (MBBR)Presence of plastic media of various shapes on which bacteria grows into thick biofilmswhich are always kept suspended thus facilitating attached and suspended conditions
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The Moving Bed Biofilm Reactor(MBBR)
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The principal moving bedprocesses
The basic MBBR TM processes
The BAS TM processes
The IFAS(HYBAS TM)processes
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MAJOR COMPONENTSa) Media
b) Aeration Systemc) Sieve Assemblies
d) Tanke) Blowers
f) Mixers
The components of the MBBRtreatment system
The carriers most commonly
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The carriers most commonlyused today
K1
• 500 m 2 /m 3 bulk
• 9,1 mm diameter
• 7,2 mm length
• 335 m 2 /m 3 67 %
• 500 m 2 /m 3 bulk
• 25 mm diameter
• 12,0 mm length
• 335 m 2 /m 3 67 %
K3
Biofilm chip™ -P
• 900 m 2 /m 3 bulk
• 45 mm diameter
• 3 mm thick
• 500 m 2 /m 3 55 % fill
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Comparison between systems
Parameter MBBR IFAS (HYBAS) Activatedsludge
Biomass Attached Attached andsuspeded
Suspended
Recycle No Yes Yes
MLSS-conc Low (100 –
300)
High (2000 –
4000)
High (3000 –
5000)Biomassseparation
Any Settling Settling
Design rate r = Q*C/A – kg/m 2*d
Both F/M – kgBOD/kgMLSS*dƟc – kg SS/kgSS d -1 =
H b id S
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Hybrid Systems-Membrane Bioreactors (MBR)
• Employ biological reactor and membranefiltration as a unified system for the secondarytreatment of wastewater
• Membranes perform the separation of thefinal effluent from the biomass throughfiltration
• Filtration takes place by the application of apressure gradient
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Process Basics
SS
Deni Nitri
SS
SCTdischarge
conventional technologymembrane technology
NDN
effluentUF notSec. Clarif.
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Schematic of conventional activated sludge process(top) and membrane bioreactor (bottom)
Hybrid systems Membrane bioreactor
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Hybrid systems - Membrane bioreactor
Simple schematic describing the MBR process
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Schematic of a submerged MBR
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Merits and Demerits of MBR system – Low hydraulic retention time and hence low foot print (area)
requirement – Less sludge production – High quality effluent in terms of low turbidity, TSS, BOD and bacteria – Nutrient Removal is possible –
Stabilized sludge – Ability to absorb shock loadsDemerits
– High construction cost – Very high operation cost – Periodic replacement of membranes is required – High membrane cost – High automation – Fouling of membrane
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Anaerobic digestion
Can be done for raw wastewater orsludge from aerobic systems
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Stages of anaerobic digestion
Upflow Anaerobic Sludge Blanket
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Upflow Anaerobic Sludge BlanketProcess
Promote Anaerobic treatment technologies forenergy generation
Less energy intensive
Can generate alternate energy
So far not very successful due to the lack ofinformation about the process
• Demonstration plants• Operational guidelines• Training in design, maintenance and operation
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UASB Reactors• UASB is an anaerobic process
in which influent wastewateris fed from the bottom of thereactor and travels in an up-flow mode through thesludge blanket
• Critical components of UASBdesign are the influentdistribution system, the gas-solids separator and effluentwithdrawal design.
•
Compared to other anaerobicprocesses, UASB allows theuse of high hydraulic loading.
Biogas
HydraulicSeal
Effluent
Settling
PhaseSeparator
element
Screenedand de-grittedsewage
Biogas
Anaerobic Sludge Blanket
Anaerobic digestion and regenerative thermal oxidiser
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Anaerobic digestion and regenerative thermal oxidiser component of Lübeck mechanical biological treatment plant
in Germany , 2007
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Application-Gas street lamp
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Tertiary Treatment
Aimed at removing nutrients and make effluent recyclable
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Advanced Water Treatment FacilityFlow Diagram
UltravioletDisinfection
(UV)Treated
Sewage
Microfiltration(MF)
Reverse Osmosis(RO)
PurifiedWater
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Microfiltration is the First Step• Technology brought to
the U.S. after WW II• Used in computer,
food andpharmaceuticalmanufacturing
• Used to sterilizemedicines that can’tbe heated
• Best pre-treatmentbefore reverse osmosis
Water + contaminantsunder pressure
Porous hollowfiber
MF membranePurified
Water
S
S
S
S
SS
S
SS
SS
S
S
Backwashto OCSD
SS
RO Membrane Is Like a Microscopic
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Strainer That Allows Water Moleculesto Pass Through
Protozoa
Bacteria
VirusOrganics
Inorganics
WaterMolecules
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