Hydrozone-based CobaltSupporting Complexes Information ...(a) CV study of an acetonitrile solution of complex 2 (0.1 mM) referenced against Fc+/Fc. (b) Plots of anodic and cathodic
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Fig. S11.(a)CV study of an acetonitrile solution of complex 1 (0.1 mM) referenced against Fc+/Fc. (b) Plots of anodic and cathodic peak currents at redox process II versus the square root of the scan rates, v1/2.
Table S1. Summary of Electrochemical Data for Cobalt(III) complex 1.Co3+/2+ Co2+/+
Scan rate(mVs-1)Eox (v) Ered (v) ΔE Em (v) Eox (v) Ered (v) ΔE Em (v)
Fig. S12. (a) CV study of an acetonitrile solution of complex 2 (0.1 mM) referenced against Fc+/Fc. (b) Plots of anodic and cathodic peak currents at redox process II versus the square root of the scan rates, v1/2.
Table S2. Summary of Electrochemical Data for Cobalt(III) complex 2.Co3+/2+ Co2+/+
Scan rate(mVs-1)Eox (v) Ered (v) ΔE Em (v) Eox (v) Ered (v) ΔE Em (v)
Fig. S13. (a) CV study of an acetonitrile solution of Complex 3ClO4 (0.1 mM) referenced against Fc+/Fc. (b) Plots of anodic and cathodic peak currents at redox process II versus the square root of the scan rates, v1/2.
Table S3. Summary of Electrochemical Data for Cobalt(III) complex 3ClO4.Co2+/+
Fig. S14. (a) CV study of an acetonitrile solution of complex 4 (0.1 mM) referenced against Fc+/Fc. (b) Plots of anodic and cathodic peak currents at redox process II versus the square root of the scan rates, v1/2.
Table S4. Summary of Electrochemical Data for Cobalt(III) complex 4.Co3+/2+ Co2+/+ Ligand-baseScan
rate(mVs-1) Ered (v) Eox (v) ΔE Em (v) Ered (v) Eox (v) ΔE Em (v) Ered (v) Eox (v) ΔE Em (v)