hydrogen sulfide provisional

iPUBLICATIONS

NBSIR 83-1694

HYDROGEN SULFIDE PROVISIONALTHERMOPHYSICAL PROPERTIES FROM188 TO 700 K AT PRESSURES TO 75 MPa

Robert D. Goodwin

National Bureau of Standards

U.S. Department of CommerceBoulder, Colorado 80303

October 1983

NBSIR 83-1694

HYDROGEN SULFIDE PROVISIONALTHERMOPHYSICAL PROPERTIES FROM188 TO 700 K AT PRESSURES TO 75 MPa

Robert D. Goodwin

Chemical Engineering Science Division

National Engineering Laboratory

National Bureau of Standards

U.S. Department of CommerceBoulder, Colorado 80303

October 1 983

U.S. DEPARTMENT OF COMMERCE, Malcolm Baldrige, Secretary

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director

Contents

Page

1 . Introduction

2 . Physical Properties

2.1 Fixed-Point V-a lues

2.2 Melting Line and Vapor Pressures 2

2.3 The Orthobar ic Densities 2

2.4 The Second Virial Coefficient 3

2.5 The Equation of State 4

2.6 Tiie Ideal Gas Functions

2.7 The Heats of Vaporization

2.8 Saturated Liquid Enthalpies and Entropies

3. Computational Methods 8

3.1 The Homogeneous Domain

3.2 The Saturated Liquid 9

3.3 The Compressed Liquid

3.4 Fugacity Coefficients

4. Tests and Conclusions

5. Tables of Physical and Thermodynamic Properties

5.1 Calculated P-p-T Isocnores and Isotherms

5.2 The Joul e-Thomson, I nvers i on Locus 12

5.3 Properties of the Saturated Liquid

5.4 Properties Along Selected Isobars 12

6 . Ac knowl edgments

7. References 14

Appendix A. Fixed-Point Values for Hydrogen Sulfide

Appendix B. Symbols andUnits

Appendix C. Coexistence Data of Kay and Rambosek [27] 2U

Appendix D. Vapor Densities of Reamer, et al. [38] 21

Appendix E. P-p-T Data of Wright and Maass [49]

Appendix F. Computer Programs S3

Appendix C. Ideal Gas Functions by Haar, et al

List of Fi gures

1. Dens i ty-temperature diagram of hydrogen sulfide

2. P-T locus of P-p-T data of Reamer and of Leins

3. P-T locus of P-p-T data of Rau

4. Specific heats, CV(T) at 20.34 mol/L

List of Tables

1.

Comparisons of vapor pressure data for H^S

2. Comparisons of saturated liquid density data for H2S

3. Comparisons of saturated vapor density data for II^S

4. Coefficients of equation of state for hydrogen sulfide

5. Calculated critical isotherm for hydrogen sulfide

6. Comparisons for P-p-T data for hydrogen sulfide

7. Comparisons of ideal gas functions for hydrogen sulfide .... 00

i i i

Contents (continued)

List of Tables (continued)

Page

8. Interpolated ideal gas functions for hydrogen sulfide 67

9. Comparison with HgS thermofunctions by Starling 68

10. Calculated P(T) isocnores of hydrogen sulfide 69

11. Calculated P(p) isotherms of hydrogen sulfide 88

12. The J oul e-Thomson inversion locus for hydrogen sulfide 112

13. Properties of saturated liquid hydrogen sulfide 113

14. Properties of hydrogen sulfide along isobars 115

HYDROGEN SULFIDE PROVISIONAL THERMOP N YS 1 UAL PROPERTIED FROM

188 TO 700 K AT PRESSURES TO 75 MPa

Robert D. CoocUin

Chemical Engineering Science DivisionNational Engineering LaboratoryNational Bureau of StandardsBoulder, Colorado 80303

T nermophy s i ca 1 properties of hydrogen sulfide are derived fromphysical properties data by using our nonartalytic equation of state,and are tabulated along isobars at integral temperatures. Resultsinclude vapor pressures, orthobaric densities, the second virialcoefficient, the equation of state, the ideal gas state functions,compressibility factors, densities, derivatives of the P(p,T) surface,neats of vaporization, internal energies, enthalpies, entropies,specific heats, fugacity coefficients, speeds of sound, and theJoul e-Thomson inversion. Thermofunct i uns by another author arecompared with present results.

key words: densities; enthalpies; entropies; equation of state;fugacities; heats of vapor i zat i o n ; hydrogen sulfide; isobars;isochores; isotherms; J ou 1 e-Tnomsoii inversion; orthobaricdensities; specific neats; speeds of sound; vapor pressures;virial equation.

1 . I ntroduct i on

Hydrogen sulfide (H^S) is a component of most fossil fuels. For thermody-

namic properties computations, tne present report uses the highly-constrained,

nonanalytic equation of state to obtain a smooth and consistent P(p,T) surface

using the P-p-T data of Reamer, et al . [38], Lewis and Fredericks [Blj, Rau and

Mathia [ 3 6 j , and two preliminary isotherms communicated by Straty [43]. Ideal

gas state functions are from Baehr, et al . [1J.

Earlier compilations have been presented by Nest [48], and by Starling [48].

The work of Clarke and Clew [8] is especially valuable. A bibliography of

references appears in the book by Howarth [26a].

For orientation, figure 1 presents an outline of the densi ty-temperature

phase diagram for H^ S . Present fixed-point values are in Appendix n. Symbols

and units are in Appendix B. Appendices C, D, E and G give some experimental

data not used in the present report. Tiie computer programs are in Appendix •.

2. Piiysical Properties

2.1 Fi xed-P oi nt Values

The values selected for tne present work are listed in Appendix a.

(a) The Triple Point. Our Tt

= 187.66 K is based on the 193o valui or

Giauque and Blue [17] which was 187.61 K based on (0°u = 273.1 0 k). in H3',

Kruis and Clusius [30j reported Tt

= 187.60 k. Our vapor pressure, and

orthobaric densities at the triple point are from eqs (2), (3), and {4 below.

(bj The Boiling Point. The temperature is from vapor pressure eq (l at a

pressure, 1 atm = 0.1 01 325 MPa. Giauque and Blue observed - 212. '7 K on

1

their Y-scale, whereas the value from our formulation is = 212.874 K. Liquid

and vapor densities are from eqs (3) and (4) below.

(e) The Lritical Point. Cardoso purified his H-,

S

sample v/ith great

care l 4]. Cardoso and arni [5] quote tlie critical temperature from earlier

authors as Tc

= 373.55 + 0.1 K, and give their observations as tc

= 100.40

+ 0.1°C (or, they say, 373.4 K). he have adopted Tc

= 373.4 K. In this same

paper [5] the critical pressure was 09.05 + 0.1 atm (90.23 bar), but in a report

on vapor pressures Cardoso L 6 ] gives Pc

= 8&.90 + 0.1 atm, i.e., 90 .00 bar. Our

vapor pressure eq (2) uses data of Reamer, et al . [30] and yields 09.629 bar at

Tc

= 373.40 K. Our critical density, 10.20 mol/L, was selected tediously by

inspecting the rectilinear diameter from orthobaric densities data of Reamer,

et al. [30], and the behavior of fitting functions, eqs (3) and (4).

2.2 Melting Line and Vapor Pressures

(a) The Melting Line. Ilo measurements have Deen found for the sol ia-1 iquiu

P m (T) relation of H^S. In present work this is used only to establish a low-

temperature limit for the isobar tabulations in table 14. Hence, we have usc-d

the reduced Simon equation.

Pr.,

* Pt

+ Po

t(T/Tt

)

n- U (1)

with parameters for propane, n = 1.283, P 0 = 718 MPa.

(b) The Vapor Pressures. Table 1 presents a comparison of selected data

with the fitting function eq (2) below. Authors are identified by their Id's

given at the top of the table. Excluded data appear at the bottom of this table.

Our vapor -pressure equation is

£n[PQ*10] = a/x + b + c*x + d*x

2+ e*x

2+ f*(l - x)*

3

(2)

where x = T /

T

cis the reduced temperature, pressure P

Qis in units of MPa, the

exponent is p = 1.70, and

a = - 8.023 473 844 d = 9.690 908 499

b = 16.731 062 287 e = -3.577 167 041

c = -10:325 650 140 f = 3.174 310 817

The rms relative deviation for 54 selected data is 0.08 percent. The

experimental residual in the last column of table 1 is £n(P/Pt)/£n(P

c/P

t )-

(1 - Tt / T ) / (

1 - T .j. / T c ) . DPS/DT is the slope, in units of MPa/K.

2.3 The Orthobaric Densities

(a) Saturated Liquid Densities. Table 2 presents the comparisons of data

with eq (3) below. Author ID's appear at the top of this table. Our liquid

densities equation is

p^/p c- 1 = a*u p

+ b*u + C‘u2

+ d*u2

(3)

where u = (1 - T/Tc ), exponent 8 = 0.35, and

2

a = 1.9063 9527 c = -0.5709 1447

b = 0.8356 0589 cl = 0 .7234 7653

The mis relative deviation for 45 data is 0.033 percent. In taule 2, DD3/DT is

the slope, in units of (mol/L)/K.

(b) Saturated Vapor Densities. TaDle 3 compares data with eq (4) below.

Among autnor identifications at the top of this table, data at ID = 9 are from

our virial eq (5) below. Data at ID = 10 we derived from heats of vaporization:

see section 2.4 below. Data at ID = 95 are computed via a selected rectilinear

diameter [coefficient b in eq (3)j with liquid data from eq (3). Divergent data

of Reamer, et al. [38J have been omitted (Appendix D). The fitting function is

designed to yield ZQ ( T

) —>1 as p —O. Let AQ = (Z

c - 1) and define the

arguments

n(T) = ^0(T)/P

C ,x ( T )

= T /

T

c ,u ( T ) = ( 1 - x )

.

The reduced vapor densities, pg

= PQ / lZ q

«R * *T j , then are given by

iom = i + A • ii•

ou x”

2*f(x)

f(x) = 1 + [A^

• up + A • u

d+ A

3* u + A

4-u

2. ,

3-,+ A r • u j

•

5XP ,

XP = exp Lb • ( x - l)3/x]

where 8 = 0.35, a = 0.70, b = 2.0, and k * = R. d c ,IIP a /

k

= -0 .7525 7980 a4

= 2.1729 6301

l\z = -0 .8654 811 7 A

5= -5.7660 7853

A3

= 1.9754 3043

Tne first coefficient in eq ( 4 ) is constra i neu (fo r symmetry) in terms of

first coef f i c i ent , a , for the liquid in eq (3) » A1

a • Zc / ( Z c

- 1), by

inspecting eq (4) at T very close to Tc

. The rms relative deviation for

weighted data is 0.12 percent. In table 3, DDS/DT is the slope, in units of

(mol/L)/K. Column F ( <. )gives the experimental residual,

F <‘> 5 n Sxpt - i )/U c- D3-x 2

/» .

2.4 The Second Virial Coefficient

Data at higher temperatures are available in tiie bout L»y D>mond and

Smith 1 3 j . At and below the boiling point we derived values for the second

virial coefficient, B ( T ) , with heats of vaporization at the b.p. of oiauque j u

Blue l 1 7 j and of Frank and Clusius L 1 5 ] at 188.7 K, via tuo C 1 a p e y r u i i e q u a t i

o" .

Using Vc

= 1.0/10.2 L/mol, a plot of all data yiolus

B(T)/VC

= 1.75- 3 . 0 • ( 3 7 3 / T ) , v 5

where B(T) is in units of L/mol. This was used to obtain some sdturat.ee v a .i o’

densities at low temperatures by way of the truncated virial equation of state.

3

Z(P,T) 1 + B ( T )• d + ... (5a)

where d is the density iri mol/L.

2.5 The Equation of State

The present equation of state (EOS) is valuable for use with inaccurate

P-p-T data because it is constrained to the coexistence boundary; it yields a

maximum in Cv(p,T) at the critical point; and it has only three least-squares

coefficients. A general description was given by Goodwin [19]. The present form

of the EOS is the same as was used recently for isobutane [22].

Figures 2 and 3 show the P-T regions covered by P-p-T data of Reamer,

et al. [38], Lewis and Fredericks [31], and by Rao [36]. Two preliminary,

high-temperature isotherms communicated by Straty [43] were used with Reamer's

data for adjusting the EOS. The other data (including Reamer's near the C.P.)

were ignored, but comparisons with the EOS also are presented in table 6 . In

this table, some calculated densities fall in the opposite liquid-vapor phase

from the data, and so these deviations should be ignored.

Equation ( 6 ) is the outline of our EOS. For any density (isochore) the

coexistence temperature, TQ (p), is obtained by iteration from eqs (3) or (4)

for the orthobaric densities; hence the vapor pressure, P [TQ (p)], is a

function of density.

P - PQ(p) = pR *

* [T - T0(p)] + p

2R*T

c.F(p,T) ,

F ( P , T )e B ( p )

• *(p,T) + C(p) • *(p,T) ,

( 6 )

where p is the reduced density.

The temperature-dependent functions in eq ( 6 )are defined as folio w s , where

x e T/Tc

is the reduced temperature and xQ

e Tq(p)/T

cis the reduced

coexistence temperature.

*(P,T) = xe*ex p[ b • ( 1 - T

q(p)/T)] - x^ , ( 6 a)

where e = 3/4, b e (1 - e) + (1 - e)

^ / ^ = 3 / 4 # and

y(p,T) e 1J1 ( p , T ) / <|>

q ( p )- 1 ( 6 b)

where d0 (p) is obtained from 4* ( p , T ) merely by replacing T with T (p), and, for

i|/(p,T) we use the argument,

u>(p,T) = [1 - 0 ( p ) / T ] , (6 c)

where e(p) is a locus of temperatures inside the coexistence envelope,

e ( P )= T

q ( p )• ex p[ -a • f ( p ) ]

f(p) = IP -1

|

3/(P

t- l )

3

( 6 d)

in which p tis the reduced density of liquid at the triple point. Then,

*(p,T) e 1 - (u» - ojn/n

)

/ ( 1 - 1/n) • (6e)

4

Equations (6b, 6e) dictate behavior of the P(p,T) surface about tne critical

point (C.P.). We selected exponent value ri = 1.10 because it cannot oe

established by fitting P-p-T data. Experimental data become inaccurate near tne

C.P., just where they are needed most to establish exponent q for the EOo.

Tne density-dependent coefficients in eq (6) are,

B(p) a B]

+ B2-p

2, ( 6 f

)

c(p) = ci

• ( p - 1) *(P - 2) • exp[ - Y • P J • ( 6g)

We selected y = 1/2 for an i nf 1 ect i on in p^ •C(p) at p =1 , see eq (6 / , to

ODtain symmetry about the C.P.

Parameters arid coefficients of eq (6) for H 2 S thus are

,

a =1 , 8 = 0.35, y = 1/2 > e = 3/4, n = 1 .1

B•]

= 0.3932 5678 673

B2

= 0.1329 0189 038

C1

:000ro0III 113

In fitting eq (6) to P-p-T data by least squares, we constrained tne slope of tne

critical isochore at the C.P. to equal the slope of vapor-pressure eq (2) at tne

C.P., 3P/3T = dPQ/dT = 0.152 378 MPa/k. Table 4 gives behavior of tne coeffi-

cients, and table 5 shows behavior of the calculated critical isotherm. PVT uata

deviations are in table 6.

Specific heats on tiie critical isotherm can oe derived from our EdS at

reduced densities near p = 1 via

ACv

= - T-J

(

3

2P / 3

T

2) -dp/p

2.

Isochore curvatures, 3^P/3T , depend on t(p). y ( p , T ) ,

t(p,T) - ii/(p>l)/ij<0(p) -

1 >

*(p,T) = 1 - (a) - u)n/n ) / ( 1 - l/n)

( aa

/

Differentiating \|»(p,T) twice vs. T via uj(p,T), dropping insensitive terms and

factors, 3 uj/3T, 3^jj/ 3T^, gives

2 234P / 3T

4(P - U-oi ( a

)

Howeve r

,

u) ( P , Tc )

s 1 - e(p)/T V b

0 ( p )= T

0(p) *expL- a* |p -

1|

°j . vt

how, let T0 (p) be obtained from tne usual formulation of orthooaric densities

very near T c ,

Po

= 1 + a - L 1 - To(p)/T

cj1/J

, Id)

5

1T0(P)/T

C- b .

|

p - 1

Also at p near 1,

3- 3exp L- ot •

|p - 1| J = 1 - a*|p - 1|

Thus from (b), (c), (e) and (f),

6( P )

/'1 - c •

| P - 1

u(p,Tc

)». IP - 1

(e)

(f)

( 9 y

(li)

and, via ( a) ,

0 2P/8T

2) % (p - 1) -|p -

1 |

3 * r'“ ^ (i )

along the critical isotherm near p = 1.

To obtain Cv(p,T

c )by integrating (i) vs. p, we have assumed that l/>

0 (p)

in (aa) will have negligible effect. It lias the approximate form near p = 1,

31 / iji ( P )

t l + const.*|p-l|

Ue find two limiting values for exponent n • If (3

• n - 6) = -2, i.e., n = 4/3,

then,

Cv(p,T

c)

-x- - Jon |p - 1| , ( j )

and if n > 4/3, the behavior of Cv

is wrong. Then, if (3*n - 6) —*--3, i.e.,

n —*1 .0+

(r) = 1 excluded), we would ootain for n = 1,

Cv ( p ,T

C) ^

| p -1

|

-1(k)

Hence the exponent is restricted to 1 < n <_ 4/3, and, for our value n = 1.10,

Cv(p,T

c) . |p -

1|" 0 - 7

, (1)

along the critical isotherm, and near p = 1.

In early work we, used a logarithmic form

4> ( p , T ) 1 - u> + to • x, n ( (D )(m)

to obtain nonanalytic beliavior of the EOS. By methods analogous to tiie above,

always along the critical isotherm, we find that (m) gives a logarithmically

infinite rate of change of isochore slopes (3P/3T) vs. p at p = 1 . This is

capable of producing an irregular critical isotherm, P ( p ) y. The present

formulation of ^ ( p , T )with an exponent, n = 1.1, fields a linear dependence of

isochore slopes vs. p along the critical isotherm at p = 1,

( 3P / 3 T

)

T* a - b«(p - 1 ) ,

(n)

c

by disregarding integral powers of p in the EOS.

6

2.6Tne Ideal Gas Functions

Spectroscopic specific heats and ideal gas state tliermof uncti oris have been

tabulated by Bae hr, et al. [1], Stull and Prophet [44], and by Edmister [14]. .<e

used data of Baehr and of Stull before receiving the Edmister report. Table 7

gives deviations from our fitting e-q (7) below. Table headings for Vi0 - V.

J,

etc. are given by H4-Hzz, etc. Upon discovering differences between data of

Baehr, ID = 1, and of Stull, ID = 2, we gave zero weights to the ID = 2 data wneri

fitting eg (7), by using x s T/100,

C°/RP

e x p (- e / x

'

where e = 10.37, R = 8.3145 (J/mol)/K, and

A

Aou

H n

- 0 .1 952 556

11.0377 525

-74.8072 768

6

* 2 - i

(7)

330.650 146

-655.671 639

475.053 933

Table 8 gives interpolated values at integral temperatures. After present work

was completed, Dr. L. Haar kindly noted that he and coworkers computed ideal gas

state functions [ 2 3 a ] , and that ttie entropies differ significantly from tiiose

used here. For convenience in future work, these data are duplicated in

Appendix C.

we have fit the Karmens' [25] version of willioit's G°(T) formula to the

highly precise H2S data of Baehr, et al. [1]; see table 7. By fitting to tne

Cp(T) data, the deviations were strongly systematic, to above 0.5 percent,

with an rms relative deviation of 0.34 percent [as compared with 0.012 percent

via our eq (7)]. By fitting to the (H° - H°) data, the systematic deviations

exceed 0.08 percent, rms = 0.055 percent [as compared with less than 0.01 percent

via our eq (7)].

2.7 The Heats of Vapori zat ion

we have used the Clapeyron equation to compute heats of vaporization,,

in J /mo 1

,

Q = 1 00 »T • ( dP / dT ) • ( v - v ) (6V vap 0 g x,

where dPQ/dT from eq (2) is in units of bar/K, and v = 1 /

d

g, v

v= 1/d^, in

units of L/mol, are from eqs (3) and (4). Results are given in table 13.

2.8 Saturated Liquid Enthalpies and Entropies

These formulations save computer time when calculating compressed

thermofunctions at T < T^

. He computed 24 data along the saturated liquid

boundary from Tt

through Tc

by using the ideal gas functions, tne EOS, ana

heats of vaporization. Each of the following fitting equations is constrained to

the end-point values. lie define the normalized argument,

u(T) = (Tc

- T ) / (T c

- Tt ),

when these enthalpies 1I

Qin J/mol are given eg

7

(H0

- Hc

) / (H t

- Hc

)= u + (u

p - u )• [A

i

+ A ^ • ua

+ sum]

(9)

7i 2sum = Y A

i* u

i = 31

where 3 = 0.35, a = 0 . 70 , Ht

= 0 .797 J/mol

,

Hc

= 17073.874 J/mol , and

A1

= 0.456 446 719 A5

= 3.744 016 417

A2

= 0.017 191 502 A6

= -2.788 695 456

A3

0.207 055 552 A7

= 0.699 929 755

A4

= -1.906 453 736

For the 22 data at Tt

< T < Tc , the rms relative deviation is 0.021 percent

The greatest absolute differences are about 2 J/mol at T = 370 .0 and T = 37

These enthalpies appear in table 13 under heading H.

The entropies, SQ

in (J/nol)/K, have been formulated with a minimum of

constants because the formula is used to obtain specific heats along the liquid

boundary, CQ

( T )= T • dS

Q/ dT . The arguments are x(T) = T /

T

c ,

u(T) e (Tc

- T)/(TC

- Tt ), and we use the constant k = £n(T

t/T

c ),when,

( So

“ Sc^

7 ^ St

“ V = u3 + A-| • [£n( x) /k - u

3] + A^-Lu

2- u

p] , (10)

where 3 = 0.35, St

= 109.28667, Sc

= 167.26532 (J/mol)/K, and

A1

= 0.412 265 764 Ao = 0.212 761 017

For the 22 entropies, obtained as described above at Tt < T < T

c , the rms

relative deviation is 0.072 percent. The greatest absolute deviations are about

0.1 (J/mol)/K.

The saturated liquid specific heats, 0 (T) in (J/mol)/K, obtained from

eq (10), use Sn = b

t - Sc , A3 e 1 - A-j - A ^ » and

sum = 2*A,, *u + A q *3*up "*

, (11)L. O

when,

C0(T) = S

n• L A 1 / k + x* sum* ( du/dx) ] , (12)

where (du/dx) e -

T

c / (

T

c- T

t ) . Results for b ( T ) are given in table 13 under

iieading 5, and for 1 (T) under heading OS.

3. Computational Methods

The numerical values for E and H in this report are based on the assigned

value, E = 0 at the liquid triple-point, obtained by use of the arbitrary value,

E^ = 13400.138 J/mol. Specific heats of Ciauque and Blue [17] could be

integrated to give the solid at T = 0 as reference state.

3.1 The Homogeneous Domain

The homogeneous domain of figure 1 includes all regions which can be

attained along isotherms starting at zero density without crossing the

8

vapoi -liquid dome, and without passing very close to the critical point at

T > T c .

Computations start with ideal gas thermodynamic functions at zero density,anu then continue by integrating numerically along isotherms by using theequation of state in the following relations,

AE = / IP - T*(3P/3T)].dp/p 2, (13)

ACy

= -T-J ( 3

2 P/3T 2) -dp/p 2

, (14)

o r ^LS = R ^n[P / ( P RT ) ] + / LR - (3P/3T)/ Pj «dp/p . (15)

Jo

equation (15) is for use with initial entropies in hypothetical ideal gas states

at P° = 1 atm (0.101325 MPa). For all other initial states,

AS =- J (3P/3T).dp/p 2

. (15a)

In eacli (p,T) state, reached by above integrations, the following are computed,

H = E + P • v, (16;

Cp

= Cv

+ T-( 3P/3T) 2 /[(3P/3T) •p2

J 07 )

= Cp-(3P/3p)/C

v . v 18;

3.2 The Saturated Liquid

Mt temperatures from the triple point to the critical point, thermofunctions

for the saturated vapor are obtained via eqs (13) through (16). Tnen eq (t>) for

the heat of vaporization, Q vap > is used to compute

AH = - Q , AS = AH/T , ( 1 9

>

such that tne free energy of vaporization, AL = AH - T»£,S, is zero. See

section 2.8 for consistency of the formulations. Having obtained II and a for tr.c

saturated liquid, E = H - P • v is computed.

The single-phase specific heat, Lv(p,T), at the saturateo liquid oounuar;.,

is obtained from eq (10) using CQ(T) = T*dS

Q/dT ano the thermodynamic relatio-.

Cv(p,T) = C

q(T) + T-(3P/3T) *(d Pj,/dT)/p

2

where p^ is density of the saturated liquid,

tiiis boundary follow from eqs (17) and (18).

boiling point, the following values have been

Values for Cp ( p , T ) ana K ,7

For liquid II 25 at the normal

obta i ned

,

n

Tb

= 2 1 2.874 K,

Eb

= 1690 .3 J/mol

,

Hb = lb 94 .3 0/mol

,

Sb

= 117.871 ^J/f-

9

3.3 The Compressed Liquid

Starting with abuve values for E, 5, and Cv

on the saturated liquid

boundary, eqs (13), (14), and (15a) are used to integrate along isotherms, and

then H, Cp

, and U are obtained via eqs (16), (17), and (18).

3.4 Fugacity Coefficients

The fugacity coefficients in table 14 were computed along isotherms relative

to properties in hypothetical ideal gas states at a pressure, P° = 1 atm

(0.1 01 325 IlPa) ,

(f/P) = (P°/P) -exp UO/RTj . (21 )

For any (P,T) point, the isothermal free energy change is

^C = (H - E°q

)- H° - T • ( S - S°) , (22)

in which the arbitrary value of E ° was added to tabulated values of H ( P , T

)

such that E(P,T) = 0 for liquid at the triple point.

4. Tests and Conclusions

Vapor pressures of H^b at T > 325 K iiere are based only on data of

Reamer, et al. [38], with no independent data for comparison. Saturated liquid

densities of Reamer, et al. at T > 325 K become smaller than our fitting function

by up to 2 percent. (Similarly, tneir vapor densities (not used uere) are

greater than from our fitting function by several percent.) The liquid densities

of Baxter, et al. L 2 j we concluded to be wrong, and then found that Clarke and

Clew [8] had reached this same conclusion. The critical density of 1125 is not

known accurately. Data for vapor pressures and orthobaric densities measured by

Kay and Rarnbosek [27] were discovered after the present work was completed.

Their critical constants were Tc

= 373.07 + .06 k, Pc

= 8.9432 MPa,

dc

= 10.167 mol/L. In .Appendix C the data are compared with our results from

eqs (2), (3), and (4). Their vapor pressures are slig fitly higher than ours

(based on Reamer, et al.). Their orthobaric densities, however, uiverge from

ours at higher temperatures in the same sense as those of Reamer, et al.: liquid

densities are lower, and- vapor densities are higher. The critical temperatu re in1 x

[27] is lower tnan ours (373.40 K). Small changes in the assigned critical

temperature have an enormous effect on ttie "fit" of orthobaric densities data

near T c . The above experimental ortuobaric densities deviations suggest that

T c should be lower than used here. This simplistic conclusion, however, is not

necessarily correct, in view of gravitational effects in the experiments, because

the compressibility, 9p/9P, becomes infinite approaching the C.P. This problem

iias been addressed by Weinberger, et al. [47a], Ulybiri, et al. [46a], and by

Moldover, et al. [32a], in no case reaching a definitive method to adjust the

experimental observations.

Some vapor and liquid densities of Reamer, et al. [38], not used here, are

given in Appendix D.

The obscure "apparent molecular weights," M , of Wright ano Maass l 4 9 ] we

finally ueduced yield densities p, in mol/L, via

10

P = (M/M0

) • P / (R

• T

)

where MQ = 34.08 is the correct m.w., and we used their gas constant, R' = 0.08206

(L

• atw/mol ) /K . Results are tabulated in Appendix E. It is improbable that tnese

data would significantly affect the EOS developed here.

Compressibility data in table 6 apparently are not of the accuracy and

precision usually needed to establish a valid EOS. Also, no data have been founo

from the t ri p 1 e- po i nt , 188 K, up to 278 K. With the present type of EOS,

however, our greatest problem for H^S has been to derive credible specific

iieats on the liquid boundary (see below).

Our derived heat of vaporization at the normal boiling point ( n b p ) is

18.679 kJ/'mol as compared with 1 8 .673 + 0.02 kJ/mol measured by Ciauque and Blue

(G/B) [17]. Our derived saturated liquid specific heat, C 0 (T), at the nbp is

68.77 (J/mol)/K as compared with 68.3 (d/mol)/K observed by C7B.

A comparison with thermofunctions derived by Starling l42j is presented in

taDl e S along seven isotherms from 25 5 through 478 K at pressures through 20 lir’a.

The nearly constant enthalpy differences arise because we believe tiiat Starling

adjusted his ideal gas state enthalpies by the heat of formation of H^S from

the elements at stanaard conditions. The nearly constant entropy differences may

be due to different ideal gas state values used. Thus we conclude that our

results are consistent with those of Starling.

The single-phase specific neats at the liquid boundary, Lv(p,T;

0 , are

derived here for H?S via eq (20), which is a difference of two terms because

(dp^/dT) is negative. Values for Lv(p,T)

0under heading tV_ in table 14 diminisn

uniformly from tiie triple point temperature up to 350 K, above which they

increase sharply, as needed for consistency witii an infinity in Cy(p,T)

approaching tiie C.P. Our extensive efforts to modify this oehavior have been

f ru i 1 1 ess .

For ethane [20], nitrogen trifluoride L23j, and for ethylene [47], Cv(p,T;

0

at first decreases vs. T, and then increases, in each case with a minimum near

(Tt + T

c)/2. For carbon monoxide [21], however, we encountered tne Same

general behavior as found here for H£3

.

Values for Cp(p,T) in the compressed liquid depend uirectly on tne derived

t ( T ) along the liquid boundary, due to the method of computation. n

consistency check along isobars can be made via Cp

= (3H/3T)p

. For isobar

P = 8.0 MPa in table 14, from T = 340 to 350 K, 611/^T = 91.31 ( J / m 0 1 ; / k , a no i<_

average specific heat is Cp

= 91.73 (J/mol)/K, in good agreement, also in

this interval, L\\ = 913 J/mol, and T *63 = 908 J/mol, wnich agreement is gooo

considering the large (10 K) interval at T not far below i c .

Dr. [. Haar has suggested a closed loop consistency test. On figure 1,

compute along the 330 A isotherm from p = 0 up to tiie liquid coexistence boundary

at p near 20 .34 mol/t. Then compute along this isochore up to 41b k toC .

Tnen compute along the 415 K isotherm oown to p - 0. Finally, at p - c 0 r y u c

c

from 415 K down to the starting point at T = 330 k. Tne only computation not

already done is along the isochore at 20.34 mol/L from 3 30 to 415 n, aid tins

11

involves derived specific heats Cv

( T )along this path, which data are well known

to be difficult to derive with good accuracy.

figure 4 is a plot of tnese isocnoric specific heats, estimated from out-

table 14. As this curve is not easily represented by a polynomial, we nave

summed the trapezoiual areas between adjacent points to compute AE aiiu AS from

330 to 415 K, and then have compared these results with changes obtained from

table 14:

AE , J /mol n S , J / mol /K

Integration of Ly(T) 3141 8.40

Estimated from table 14 3346 8.63

The differences of only about three percent probably are within uncertainty of

tiie numerical integration, and thus confirm the t hermody nam i c consistency of the

present work.

Experimental determinations of specific heats CQ

( T )for the saturated

liquid, and of Cv(p,T) for the compressed liquid are needed to obtain any

higher accuracy, because tne computation of these specific neats from only a

P(p,T) surface is notoriously difficult, involving first arid second derivatives

and differences; and tne need for very accurate saturated vapor densities

(which usually arc not available).

5. Tables of Physical anu Thermodynamic Properties

5.1 Calculated P-p-T Isocnores and Isotherms

Tables 10 and 11 give a selection of isochores and isotherms computed by

equation of state (6). These are essential to examine behavior of the P(p,Tj

surface. They are a useful supplement to tne isobars of table 14 for

interpolating P-p-T values and their derivatives.

Tne tables of isocnores show that the isocnore curvatures are qualitatively

consistent with a maximum in the specific heat ov(p,l) at the critical point.

The isotherm tables snow that 3P/3p is nonnegative and that pressure increases

monoton i cal ly with density along isotherms.

5.2 The Joule-Thorn son Inversion Locus

Table 12 gives the P-p-T locus of the JT inversion, ( 3 T / 3 P) ^

= 0,

obtained from equation of state (6; under the condition, T*(3P/3T) = p*(3P/3p;.

Tnis table lias been computed to temperatures well above tuose of P-^,-1 data, to

show approach to a maximum in P-T coordinates.

6.3 Properties of the Saturated Liquid

Table 13 gives physical and thermodynamic properties of the saturated liquid

computed by methods of section 3. (Properties of tne saturated vapor can be

Obtained from Table 14 from values given at cue coexistence boundary for eacn

i sobar . )

5.4 Properties Along Selected Isobars

Table 14 gives piiysical and thermodynamic properties on isobars, computed by

methods of section 3. These tables include values beyond tne range of the data

used for adjusting the equation of state. Small discontinuities may be detected

12

o . 96 o 1 1 P a uue to a C I i a n g 0 in tilt p a t n Sat Tc

= 373.40 k along isoburs at P > Pc =

of coi.iputation (section 3).

The first line of each table refers to freezing liquid on the P(T; melting

line. Eacn table at P < Pc

contains a blank line for the transition from

saturated liquid to vapor, as seen ug tiie abrupt decrease of density.

6 . Acknowledgments

Many staff members of the Chemical Engineering Science Division of the

national Bureau of Standards (DBS) nave contributed valuaule suggestions,

references, and documents. kubert D. McCarty coritriouted trie essential

1 east- squares program, providing for constraints. James P. Ely inoicated the nev/

numerical integration procedure, and the simple method for obtaining fugacities.

Ileil A. Olien and Jo Mendenhall nave been of invaluable assistance in supplying

references arid in procuring documents. Karen A. Bowie deserves special

appreciation for preparing the manuscript for publication. he express grateful

appreciation for support of this work by tne Gas Research institute and the

technical coordination provided by Dr. Frank Little.

13

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14

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16

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17

Appendix A. Fixed-Point Values for Hydrogen Sulfide

Triple Point Boiling Point Critical Point

Temperature, K 18 7 .66 212.874 373.40

Pressure, PIP a 0.02320 0.101325 8.96291

Density, i.iol /L

Vapor 0 . U1 496 0 . 0 5 o4 3 10.2

Li quid 29 .136 27.845 10.2

18

Appendix B. Symbols and Units

Subscripts £ and t_ refer to critical and liquid triple points

Subscripts £ and £ refer to saturated vapor and liquid

Subscript £ refers to liquid-vapor coexistence

Superscript £ refers to ideal gas states

,y ,e ,n,p

B(T)

B ( P ) , C(p)

CV(P,T)

Cp ( P ,

T

)

C 0(T)

a

E(P,T)

E° H°o

f/P

F(P,T)

C(P,T)

H(p,T)

J

L

mol

P

exponents in various equations

second virial coefficient, L/mol

coefficients in the EOS

isocnoric specific heat, J/mol/K

isobaric specific heat, J/mol/K

saturated liquid specific neat, J/mol/K

density, mol /

L

internal energy, J/mol

13 400.138 J/mol (arbitrary)

fugacity/pressure ratio

defined function for the EOS

Gibbs free energy, J/mol

enthal py , J / mol

enthalpy for ideal gas state at T =

joule, 1 N • m

liter, 10“ 3 m3

34.08 grams of

0

Ho s

N/ m3 )pressure in MPa (1 MPa = 10

1 atm = 0.101325 MPa = 1.01325 bar

( 1 bar = 10 bU/r.i

2) ,

F0(T)

p0 (p)

n(T)

* ( P ,T)

f(p,T)

Q v ap

R

R*

P

S ( p , T

)

T

T0 (P)

9 (p )

u (T

)

v

uj ( p , T )

H ( p , T )

x(T)

x0 (p)

i.(P.P,T)

melting pressure, MPa

vapor pressure, MPa

P0

[T 0 ( p ) ] , vapor pressure as function of density, MPa

p0 (

T ) /P c ’

reduced vapor pressure

function in t h e EOS

function in the EOS

AH vap ,heat of vaporization, J/mol

gas constant, 8.3145 ( J / r.i o 1 ) / K , 0.0083145 (MP a • L / mol ) / K

(0.0083145) dc ,

MPa/K

d/dc ,

reduced density

ent ropy , ( J /mo 1 ) /

K

temperature, K

liquid-vapor coexistence temperature, is

defined locus of temperatures, k

defined in various equations

1/d, mol a 1 volume, L/mol

LI - e ( P j / T J ,for the EOS

speed of sound, m/s

T/T reduced temperature

T (p) /Tc .

reduced coexistence temperature

the "compressibility factor"

19

Appendix C. Coexistence Data of Kay and Rambosek

HYDROGEN SULFIDE COEXISTENCE DATA OF KA Y/R AN80SEK» VS. RDG (CALC)

T PRESSURE. MPA LIODEN# HOL/L GASDEN, NOL/LK DATA CALC PCNT DATA CALC PCNT DATA CALC PCNT

272.039 1.0032 .9991 .41 24.977 24.552 1.73 0.0000 0.0000 0.00277.594 1.1728 1.1735 -.06 24.573 24.207 1.51 0.0000 0.0000 0.00283.150 1.3707 1.3693 .10 24.159 23.853 1.28 0.0000 0.0000 0.00283 .706 1.5865 1.5879 -.09 23.727 23.489 1.01 0.0000 0.0000 0.00294.261 1.8285 1.8308 -.13 23.290 23.113 .77 0.0000 O.OOOC 0.00299.817 2.0974 2.0995 -.10 22.843 22.723 .53 0.0000 0.0000 0.00305.372 2.3945 2.3956 -.04 22.383 22.319 .28 0.0000 0.0000 0.00310.928 2.7207 2.7206 .00 21.927 21.898 .13 1.3631 1.3582 .36316.433 3. 0785 3.0762 .08 21.443 21.457 -.07 1.5605 1.5461 .93322.039 3.4681 3.4640 .12 20.963 20.993 -.14 1.7720 1.7570 .85327.594 3.8928 3.8858 .18 20.441 20. 501 -.29 2.0305 1.9948 1.79333.150 4.3547 4.3434 .26 19.891 19. 977 -.43 2.3078 2.2645 1.91333.706 4.8504 4.3389 .24 19.295 19.413 -.61 2.6321 2.5737 2.27344.261 5.3839 5.3743 .27 18.660 18.797 -.73 3.0082 2.9331 2.56349.817 5.9681 5.9521 .27 17.955 18.112 -.87 3.4594 3.3602 2.95355.372 6.5941 6.5752 .29 17.179 17.331 -.87 4.0328 3.8846 3.82360.928 7.2712 7.2470 .33 16,258 16.396 -.84 4.7473 4.5647 4.00366.433 8.0013 7.9723 .36 15.041 15.170 -.85 5.7484 5.5460 3.653 72 .03 9 8.7901 8.7588 .36 12.526 12.956 -3.32 7.9904 7.5394 5.98373.094 8.9432 8.9166 .30 10.120 11.623- 14.40 10.1666 8.6225 17.91

20

Appendix D. Vapor Densities of Reamer, et a 1 . [38]

(Not used in table 3)

Temperature, K Density, mol/L

282.706 0.6922

298.150 1 .0355

31 1 .539 1 .3941

323.1 50 1 .7739

331 .483 2.1824

338.761 2.6260

345.428 3.1 226

352.039 3.6909

358.094 4.3766

363.539 5.2177

368.706 6.4254

373 .1 50 9.5633

373.539 10.2354

Liquid densities not in table 2

368.706 14.201

37 3.1 50 10 .566

373.539 10.235

21

Appendix E. P-p-T Data of Wright and Maass.

T»K P, MPA MOL /L320.15 , 3 2 3 6 9 P .163928320.15 .363170 .139592320.15 .326573 .123782320.15 .236636 .093070320.15 .235713 .093687320.15 . 1

c 3 C f 3 .053121320.15 .122923 .036630320.25 . C 9 p 099 .037078320.25 .095805 .036212320.25 .050009 .018852320.25 .050503 .019022295.15 .32363? .177019293.15 .375836 .156133293.15 .309331 .127936293.15 .257036 .105757295.15 . 2 3 3 6 P 1 .095909293.15 .1 P9051 .077333293.15 . 1 30733 .057375293.55 • 1 C 0° 5 B .0306392 9 “ . 2 5 .099086 .030308293.55 .099099 .030226295.25 .093699 .030115298.55 .065701 .026599295.^5 .066953 .027138295.65 .035157 .013203298.65 .033717 .013022273.25 .375302 . 1 7

1

0 75273.25 .375169 .171668273.25 .317307 .133291773.15 . 2756 7 7 . 1 2 3 ? c 5

273.15 .221638 .09973*-273.16 .17225? .07717e273.15 .165320 .073093273.15 .096232 .032793273.15 .099285 .033126273.1-6 .099072 .033070273.15 .09P779 .033926273.15 .0°6319 .033055273.15 .096699 .033013273.15 .050929 .022589252.95 .302797 .201953252.9; .338239 .163030252.95 .305175 .150637252.95 . 23??3P .113665252.95 .212516 .103653252 . 95 .160520 .07782?252.95 .099938 .033103252.98 .096079 , 03666 c

237.95 .271311 . 133CP6237.95 .205983 .107372237.95 .16?720 .083813237.95 , 1 3 0 7 8 8 • 0 ? 6 9 ? 3

237.95 .100152 .051378237.95 .063220 .033132

22

onnooonn

Appendix F. Computer Programs

BRnORA* H 2 S Thp r (n , IT>J ijT,TAPF?0*IN o U T *T4 o E20)HYOPDGEN SULFIDE TH ER m 0 FIJ N C T I OS S , APPIL 15, 19«3 START.

C p-psaT * S*GK*(T-TSAT) + S * S * GK * T C P T* F ( S , T ) , W«F»E -

F(S,T) « B(S)*XRF(S,T) + C(S)*XCE(S,T) F ( S ) * x E F ( S » T )

,

XRF * (X - VS), X * T/TC, XS * TS/TC,XCF « ( x**EP ) *EXP ( A* ( 1-TS /T ) )

- X S * * E P, A * (1-EP)*S0RT(1-EP),X E F # H(P,T)/HS(P) - 1.0, W # (1-TH/T), w E # W**E

,

H(P,T) # l.o - (W-ue/E) /(1-1/E >, E * ET.B ( S ) * B1 + B2*S + R3*S7, C(S) # Cl C2*S + C3*$2,E ( S ) # E1*(S-])*(S-EP)*Exp(-GA*S**IX).G A # ( 2 *ER-3 ) M E p -1 ) / I X FOP INFLECTION AT S 1.W HE p E » P * DFN/DTRP, S * DEN/DCPT,

Common IX,pp,GK,GKK, A1.A2.A3, B 1 , P ? , 3 3 , C1.C2.C3, F1.E2.F3Cr)M wn M /1 /A L ,RF,GA»OE»EP,E T . DCRT.TCRT.oCRT, DGAT,DTRP,TTRR,pTRbC n«MOs/3/DPDT,0?PDT2,0PS0T,D° M DT,DPD0,DPDR,0TS0P,DTHDP,CDS0TC0HMnN/4/XBl,xR2» XC1.XC2 , XE1.XE2, D X B D R » DX C n R , DX E DR

C 0 M M ON /6 / TSAT, THFTA, PSATCO'MnN/B/lK.lK, P,T,OEN, E.H.S, CV.CP.CSAT, W,UK

/ 1 1 / D cL S , DELCV

CPMmpn/1?/7CRT»ZCALC«DZDT» 7 S AT , D7SDT, 7 F X, FRT.DFRTDTCommon / i q/ ON G, FG, HC-, SG, CVG.CPG.UG, OPGDT.DPGODCnMHlN/7l / T ° S ( 7 0

)

COMHON/95/ PIS, DIS, 0 0 T I S , D p D I

S

COmmon/sic/ T I , E Z Z » EZ.SZ.CVZ, H7,CPZOImfnSIQn H 7 A (

1 r o ) , SZA(IOO), PR(99)OATA(UK«R<r .o«),(PA=l. 01325), ( G J 8 . 3195)

1

FnîTds 2 F 1 C . 0 )

7 FDPM4TLI5, 3F1G.0)3 FDPHAT{?I1C)5 F r'°“AT ( I V )

9 FORMAT ( 3F1C. 0

)

14 FORKATLl*-1 ! 21X * MVipnQEM SULFIOF ISO RAP AT 0 * * F9.5, 4H “PI/)

19 FORMAT ( l 4 X 1HT 9 X 'P HD E N BXlHZ 5 XS HDP/^T 5x6 HOP/OO

2 «X1M= R x

l

h H R X 1 M S B x 2 HC V 6 X 2 HC 0 PX3HF/P 5 X 1 H W /

3 1 4 X 1 HR 7XSHM n L/L 9 X 5X5HMPA/K 1 X9 H«

p

4 - L / MQL

4 4X5MJ/M0L 4XBHJ/M0L 2X7HJ/MOL/K 1X7MJ/M01/K 1X7HJ/MQL / K

c 11* IXBmim/SEC )

17 f 0 ? M A T ( 6 X F9.R, E 1 2 .‘p

, F 9 . 5 ,c 1 0 . 6 » F 1 0 . 4 ,

1 ?F9.1, FQ.3, 2 F 8 . 2 , Ell. 4, 16)

20 FORM AT ( 1H11*X*TFST IDEAL FNCTNF*/17X 3HT.K 7 X 3 HH Z A 7X3HSZA )

21 FORMAT (

l

rv FI r ,2

,

F 1 0 . I ,c

1 D . 3 )

25 CALL PVTDATAC NOTE , RETURN, IN CQFXIST AT 16+ FOR USE ONLY WITH SSATFIT.

CALL °EEP J CALL ISOTHRMCALL JTLPCUSCALL tarlic

C SAVE HZ A ( 100 ) , S 7 A ( 1 0 0 ) F R 0 M 190 THRU 7C0 K.

85 DO R5 J = 1 9 » 7 0 1 TI * 1 0 + J T CALL IDEAL i HZA(J) * w 7

86 SZ A ( J ) = SZ84 GO TO 9097 ppinT 20 T DC 88 J*19,70 % T 10*J

8 R PRINT 21* T, H 7 A ( J ) , SZA(J)

C

C COMPUTE THFR MOFUNC TIHN S CN ISOBARS. START PN THE M ELTING LINE.

C NOTE, I S 0 0 A P P-PCRT OR. 8 UT ISOTHERM T-TCPT IS EXCLUDED.

C ISO c ARS AT R UNDER °CRT TRAVERSE THE DO M E.

C NPTF USE OF OVAD .DATA. TO CRO^S THE » DO M F » .

C NOTE USE P F CSAT .DATA, fnP SPECIFIC HEATS IN CPMpRESSf '1 L 1

1

1

1 0 •

23

Appendix F. Continued

C NOTE TPS(IX) USED BY C 0 M PR E S S AT T.LE.TCPT.C GET FUGACITIESf F/R, VIA H,S, HZ(T),S7(T). (J.F.ELY).

90 IN - 1 t NI . 56 * READ 9, ( PP( I ) » I»1 »NI )

91 DD 300 I I N , N I t IK « I $ LS - 0

9? P * P P ( T ) J IFU.F0.32) P PC R T

93 PK p/10 i PRINT 1*, PK % PRINT 16100 T FTN0T*F(P) % CALL COMPRLC $ V-l/DEN % IW«W101 Z * P/DPN/GKK/T102 TI - T i CALL IDEAL $ GI3 » H-F77-4Z - TMS-SZ)103 XP - E XP (GI B/GJ /T ) T FOP XP*PA/P * CALL CON10* PRINT 17, T,DFN, 7, DPTIS, DPDIS, E,H,S»CV,CP, FOP, IV105 IT - T/10 J IF(P.LT.pCPT) 110,180

C CASES FOR P LESS HAN PCPT.110 T P S ( I k ) « TS « FINDTSF(O) $ k . L « 0

111 DO 150 J * 1 , 99 5 T * J T * 10*(IT*J)112 IF(T.LT.TS) 113, 11«113 CALL C 0 M P P E S % IV - W J 7 - P/DEN/GKK/T11* m J T / 1 0 * GIP h-E7Z-hza(*) - T*(S-SZA(M))115 XP • EXP(GIP/GJ/T) $ FOP * X P# P A / P S CALL CON116 PRINT 17, T, 0 E N , Z, DPTIS,QP0IS, E , H, S , C V ,

C

0, F0P,IV

117 GO TO 150IIP LS « LS 1 1 IF(LS.EO.l) 120,130

C CASE FOR SATURATED LIQUID AND VAPOR.120 T - TS T CALL COEXIST t Iw « u $ I ,r. . WG121 Z • P/DEN/GRK/T % ZG p/DNG/G k K/T123 GIP » H-EZ7-HZ - T*(S-SZ)12* FOP * EXP(GI3/GJ/T)*pa/p $ CALL CON125 PRINT 17, T , D E N , Z, DPTIS,DPDTS, E»H,S,CV,CP, FPP,IW1?^ PRINT 5 ? DIS«0NG*W" \ DPTI S-DPGDT/10 T DPDIS DPGDD/10127 PRINT 17, T » QNG > 7 G , D p T I S , 0 PD I S , FG, MG, S G, C VG» C PG, F 0 P , I WG1?B T « JT

C CASES for THF HOMOGENEOUS DOMAIN.130 I F ( JT.GT.500) 133,135133 K K + l % T - JT - JT 4 1 0 * K

13* IF ( JT.GT.700) 3C0.135135 CALL GENIUS T Iw » w * Z« p/DEn/Gkk/T136 h J T / 1 0 i GIP * H-E 7 7 -HZ AM) - TMS-SZA(N))137 xp « EXD(GIB/GJ/T) $ CO 0 « X o * o A / P $ CALL CON1*1 PRINT 17, T,DEN, 7, OPTIS,OPDIS, E,H,S,CV,CP, FOP, TV150 CONTINUE

C FOP P.GF.PCPT, CASES Fop T . L T . OR . T . G T . TC R T .

180 TPS ( IK ) TCRT % K L 0

1P1 DO 250 J-1,99 1 T - JT - 1 0 ( I T J

)

102 IF (T.LT.TCRT) 19", 210C CASE A for t LESS Than TCRT.

190 CALL COMPRFS I IV V % 7 P/DEN/GKK/T192 « .jt/10 5 GIP - h-E7Z-HZA(N) - T* ( S-S Z A <h

)

)

193 XP * EXP(GIP/GJ/T) % FOP - X P * P A

/

p $ CALL CON194 PRINT 17, T , 0 E N , Z, DPTIS, DPDIS, E.H,S,CV,CP, FOP,IW195 GO TO 250

C CASE F n R T ABOVE TCRT, H0POGFNE0US DO-AIN.210 IF ( JT.GT.50G) 233,220213 K - K4l % T , jT . jt 10*K21* IF (JT.GT.700) 300,220220 CALL GENIUS S IW - W t Z • P/DEN/GKK/T22* M .JT/1C $ GIP = H-FZZ-HZA(M) - TMS-SZA(M))225 XP EX°(GIB / G J / T ) t FQP « XP7PA/P $ CALL CON2’6 PRINT 17, T , DE N , Z, DPTIS, DPDIS, E,H,S,CV,CP, FOP, IV250 CONTINUE300 CONTINUE999 STO°

END

24


c

c

c

c

c

c

SU bo Q'JT II-E COEXISTGIVES T AT COEXISTENCE, GET BOTH VAPOR AND LIQUID FUNCTIONS.FOR VAt>00, GET PNG.FG.HG.SC-* CVG .CPG, WG, DPGDT.DPGDD. -c OR LIQUID. GET Dbn,p,h,S, C V , C b

, C S A T, w . D°DT,DPDD.COEXIST CALLED BY C Q u D O L 0 . P NOT USED, *UST NOT CHANGE.CC|H“Hn/i/4L ,BF,GA»DE,E p »FT. DCRT.TCRT.PCRT, DGAT,DTBO,TTRD,t>TROCO M HON/3/nPOT,D? D DT?,r)PSDT,DPMDT,D c, Dn,OPDO,DTSDP,DTHDP.DDSPTCPHia N /o/ IN, Ik, D

, t , 0 p N , F » H , S . CV.CR.CSAT, W.VKCOHMON/11/ DELS, DELCVCOSMGN/lo/ DN5.EG.HG.SG. CVG, CPG, WG. DPGDT.DPGDDC0HN0N/9Q/ T I , E ? 7 » F7.SZ.CV7. H7,CPZDATA (0*1. 01325), (C-*Q.O«31A5),(W'»3A. 0 80 )

1 FORMAT (1HQ Q x * T EXCEEDS TC R T IN COEXIST. * / )

WK * 10C000/W M

2 IP (T.GT.TCRT) ’.A

3 PPINT1 S STOPA PS * ? S A T F ( T ) « DNG * DB DENGASP(T)5 T I * T * CALLIDFAL * " » 15 T DA * L • 0

5 EG = C ZZ EZ PD PL R ( L , h , T, DA , QP )«. hg = EG + 100*°S/D3

7 SC- « SZ DELS - 1 30*G* AL OG ( G*T*DB / 0 ) t GF * EG

B IF ( T.EO. TCPT ) 9,11

9

PX * D VTF(T.DB,1) i DPC-DT = DPDT i D P GDD * DPDD10 C p G * CVG = w 0 * 0 * GO TO 15

11 C VC- * CVZ + DELCV < PX * PVTF(T.DB,l)1 ? CPG CVG + 100*T/OBQD*(DOOT/OB)**? * WG * S QR T ( WK * C D C-* D PDD/ C V G )

13 PPGPT = DP0T $ OPC-DO * DPDDNOW travprse THE . D0 M c

» UÎNG QVAP .DATA.,15 DEN * DL * DENLIQF(T) % DDLDT * PPSQT t QV OVAPXF(T)1 ,, H HG - QV f S * SG - OV/T S E « H - 1DQ*PS/DL

This PF TURN AT 16+ US F D ONLY WHEN CALLING SSATFIT, HSATPIT.17 IF(T.fo.tcRT) 18,191 P PX * PVTP(T.DL.l) ? CP*CV*C SAT»«=0 T RETURN

19 CSAT » CSATXF(T) t »x « PVTF(T.DL.l)22 C V * CSAT + ico*T*DPQT*DDLDT/QL/DL?B CP = CV 1 00*T/PPDn * ( DPDT/DL ) ++?

30 W * SQR T ( WK*CP*D?no/CV) % RETURNEND

25


SUBROUTINE CG^PRESC SAVES Cn MD UTFR TI“E INTEGRATING COMPRLIO AT T.LT.TCRT.c FOR T = INTEGER MULTIPLES OF 10 K. FIPST ISOBAR USES COMPRLQ.C F np SUCCEEDING ISOPARS, START ON PREVIOUS ISOBAR, EXCEPT -

C AT TEMPS GE TPS(IK-l) ON PREVIOU' ISOBAR, «UST USE COMPRLO.COMMflN/1/ & L , BF»GA, 0 e , E R

, FT , DC R T , TC R T , PC R T , D G A T , D TR P , TT P P , PTR P

CnM M 0N/?/DFDT,D2 5 DT2,DPSDT,DRMDT,DPDD,DPDR,DTSDP,DTH0R,DDSDTCOMNON/8/ IN, IK, o,T,DEN, E , H , S , CV,CP,CSAT, W,WKCOMMON/ll / DELS, DELCVCO M MDN /? 1 / T P S ( 70

)

DIMENSION DK (AO) *fk ( 4 0 ) , S K ( 40 ) » C k ( 40

)

1 EOR M AT { 1H0 9X * T G.E. TCRT IN COMPPES. * / )

2 IF (T.GE.TCRT) 3,43 PRINT 1 t STOP4 J * T/10 t IF(T - 10*J ) 5 » fc

5 CALL COMPRLO < RETJRN6 IE(IK.FO.IN) 7,97 CALL CO m °FLOB DK ( J ) = D E N < EK(J)=E S S K ( J ) * S $ CK(J)=CV $ RETURN

C INTEGRATE F R G M OLD OF N TO NEW DEN ON GIVEN ISOTHERM -

C E X C E D T IF T EXCEEDS OLD TM4X, IJ S F CP m PRLO.

9

IF(T,GE.TPS( IK-1) ) GO TO 7

ID D A *0 K ( J ) $ DK(J) . D f N * DB * FINDF N F(T,P) * N - 13

11 EK(J) - E - E K ( J ) + EDEL F ( 1,N, T, CA,DB ) T H E + 100*P/DR12 S k ( J ) = S * S K ( J ) + DELS i C K { J ) * CV = CK(J) DELCV

C GET NEW OP/DT, DP/no, C°, W.

15 p y . PVTF(T,DP,1) «• CP * C V + 100*T/npPD*(D D DT/DB)**330 W SDRT(WK*CP*PP r'D/CV) t P F TURN

F n n

SUBROUTINE COMPRLOC GIVEN P,T FOP COMPR.ITO. AT T.LT.TC, GET DEN AND FUNCTIONS.C REVISED TO USE HSATF, Sâtf, CSATXF, BUT NOT COEXIST. TTMESAVER.C INTEGRATE ALONG ISOTHERM T FROM SATLIO UP TO POINT (P,T).

CnMMnN/l/AL.BF,GA,DE,E D ,ET, DCRT,TCRT,°CRT, DGAT,DTRP,TTRP,PTRPC0MMr)M/3/0PDT,D?PDT2,DPSDT,DPMDT,op0D,0PDR,DTSDP,DTHDR,DDSDTCOMm^n/b/ in, ik, p,T,DEN, E,H,S. CV.CP,CSAT, W,WKCOMM 3%| /i i / DFLS, DELCV

C? FUNGSCt C A LI S

1 format ( 1^0 9 X *T NOT UN D F R TCRT IN C n MPRLO. + /)

2 IF (T.GE.TCRT) 3,43 PRINT 1 J STOP

C GET PSAT, D F N L I 0 , AND SATLIO FUNCTIONS FOR START.4 PS * PSATF(T) % DL = DFNIIQF(T) $ DDLDT = DDSDT5 HS « m s A TF ( T ) 1 ES HS - 100WPS/DL % SS - SSATF(T)9 PX.PVTFf T, D L , 0 ) t CVS - CSATXF(T) + 1 00* T

D

P D T + D DL D T / P L / DLC 9 CVS * C V t A T F ( T )

C INTEGRATF IIP TO POINT (P,T).10 D° * FINDFNF(T,P) % OX = DR - DL * IF(DX.GT.O) 11,2011 M • li, t E « ES EDELE(1 ,m,T,DL,DB)12 H - E 100*p/DP \ S « SS DELS 1 C V CVS DELCV

11

P x = PVTF(T,DB,1) « CP = CV 1C0*T/DPDD*( DRDT/DB)»*214 W - SQR T< WK*CP*DPDD/C V ) 5 DEN - DB % RETURN20 DEN-DL * E«ES t H-HS % S-SS $ CV=CVS f PX * °VTE(T,DL,1)21 CP * C V ) 03 * T / 0 D OD * (OP0T/DL )

+ * 2 1 W * S OR T ( W K C P* D P D D / C V

)

30 RETURNENO

26

Appendix- F. Continued

SU3R0UTINE CONCONVERT T n El UNITE FOR P, DEN, DP/DT, DP/DO,CnMMnN/3/DPDT»02P0T?, DRSDT,DR*«DT,nROD,DPDP,QTSDR»DTHDR,DDSOTCONDON /9 / IN , IK ,

R, T » D E N , E » H » S » CV,CP,CSaT, W,W*

CnHMHN/Q5/ PIS, DIS, 0 3 T I S 0 p D I S

DATA ( W M * ? 4 . 0 » )

1 PIS * p/ 10 5 nis *

2 DPTIS OPOT/1C T 1P0IS « C°DD/1C9 PET'JRN

END

FUNCTION CSATXF (T)HYDROGEN SULFIDE SATLTO ENTRHpy, J/NPL/K., RDG/NPS, 4/15/83.YS - ( S-SC ) / ( ST-SC ) , X - T/TC, 4 L T - LNtTT/TC), U « ( T C-T ) / ( TC-TT )

,

C n NETR4lNJED 4T T R I P L F 4 N D CRITICAL POINTS.Y R - IJR + 41*(LN(X)/AL T - UE) + 4 2 * ( U 2 - UE ) .

D 4 T 4 ( TTPP-137.68) . ( T C R T « 3 7 3 . 4 n )

r 4 T 4 (ES-C.75),(SE-0.65),(STRP = 1C'?.’«667),(SCRT-187.2653?)0 4 T 4 ( ALT -0.88«01«42)DATA (41-0.412265764), (A2-0. 212761 Cl 7)

1 FORM4T(1ho 9X CSATyp, T.GT.T r RT. * )

2 IP(TCRT-T) 3,4,53 PRINT 1 ? ST-io

4 CSATXF - 0 « RETURN5 SN - ETRP-SC?T 1 UN - TCRT-TTRP T X « T/TCkT6 U = (TCRT-TJ/UN $ DUD X = -TCRT/IJN7 43 « 1-41-42 ? SU M - 2 * A 2 *U 43*ES/U**SE8 CSATXF SN MAI/ALT + X*SU M *PUDX) $ RETURN

FND

FUNCTION DFLTAF(T»D)GET ( T * D p / OT - C* nD /P^) FOR THE J-T INVERSION CURVE.C0YVQN/1 /AL»°E»GA,DP,E d ,ET, DCPT,TC5T,PCRT, ogat,dtrp, ttr p, ptrpCOMM n N /3/DPOT,D2PDT2»ORSDT,DPNOT,DPDD,OPr'P,DTSDR , D THD R , DO SOT

1 IMT-TCPT) 2,4,47 DL - OENLIOF(T) * TF(D-DL) 3,3,43 DELTAR = 1.CE+10G % RETURN4 P - P V TR ( T , D , 1 )

5 OELTAF - 4«S (T*PPTT-D*DPDP) % RETURNEND


FUNCTION DFN3AS c (T)

c u 2 s s &tp vaphr densities. rdg /nbs , april 15 , iq«3.C DESIGNED fop 7 SAT - 1 AT L n w DENSITIES. 5/29/77.r (7-l)/?N * ( P/PC ) * ( 1 /X2 )*F ( X ) , X = T/TC. U - C

1 - X )

,

C F ( x ) 1 + ( A 1 * U F * A p * U A G A3*'J AA*!J2 + . . )*XP,C yp * EX°( (3G/X)*(*-1)**3).

Cnii M ON/l/AL»3E.GA»"iE»EP»ET, DCPT»TCPT,oCRT, DGAT .DTRP.TTRP.PTRPCONÔN/3/DPrT,P2PDT2.DPSD7,DP'<OT,DPDD.D?DP»nTSDP,DTHDR.DnSDTCn“ M ON/l?/7CRT,7CALC.DZDT, ZSAT,DZSDT,zfx, F P T» D F R TDTPI M ENSin^' A V ( 5 )

DATA (NFG- c ).(FG«0. 35). ( AG«0. 70 )»( B G»2.0)»(GKK»0. 083145)D A T a ( s V * -c. 75257 9795. -D . « 5 5 A 8 11 7

1

,

1 1 . Q7^pp<,?f , 2.172963C1A, -5 . 76607 *5 92

)

1 FHO^TllPO 9 X + T EXCEEDS TC IN OFNGASF. * / )

? IP(TCPT-T) ?, A, 5

3 p c

I

m T 1 * STOPA DFNPASF * DCRT « ZPy * 1 % DDSPT * 1.0F+1D0 t P F TUP N

5 7 N ZCPT-l y D C P C P T « P Pfatf(T)6 PI * °/PC * D IT » ^PCPT/pc $ TC 1 T C p T

7 y * T/TC T X 2 = y*y % u « l-y 5 UF = U**EC- $ UE1 - -FG«"JE/'JA U A * u * * A C f t'Al * -AG*'JA/M9 V * X- I « V2«V*V « VP«V*V’ T XP«EXP(RG*V3/X)

ID X P 1 - ( 3 * V 2 / * - V3/X2)*XP*PGu y = a v ( i )

*

u e + Avm+UA j yi = Avm*uFi + a v ( 2 ) *

u

a 1

1Z O n H x.B.'JtS « L * ^ - 2 1 UL = U**L13 Y - Y + A V ( K ) *

! J L * Yl Yl - AV(*)*L*UL/U1 a continue t Z f y * p = 1 + y * y p * f 1 « y * x 0 1 v 1 * x p

15 ZCALC = 7 S A T = 7 = 1 ZN*PJ* c /x?16 PZSDT * OZDT « ( p I * (

F

1 -? * F / > ) / TC + C *PIT) + ZN/X217 D E N G A s F « P/T/7/GKK18 PPSDT - ( P p S D T - p/T - PAP7PT/7) /T/Z/GKK $ RETURN

FNp

FUNCTION PEk'lioF(T)C H 2 S SATLIOOFn, * n l / L , 3/21/83.C D/PC - 1 « A 1 * UE A ? U » *'J « (1 - T/TC).

C nMM 0N/3 / CPrT,P?PPT2,D°SDT,DP M DT,DPDD.DPDR,DTSDP>DTHPP. DDSPTDIMENSION A U (A

)

DATA (NFL-A),(EI*D.35),(DCFT»1C.2C)»(TCPT«373.A0)P A T A ( A W = 1 .906?95 7 7, 0.83560539. -C . 6 70 9 1 A A7 , 0 . 7 2 3 A 76 c 3

)

1 FDP M AT(1HC 9 X *PPNLIDF = 0, T EXCEEDS TCPT. * / )

2 IF (TCP T — T) ? , A ,c

3 PRINT 1 T STOP A W ( 1 )* 'J F T

7 DO 9 K ® 2

»

k ' c L « L « K-l « UL l'* + L

8 Y * Y AW(K)*UL t Y 1 T = Y1T + AW(*)*L*UL/U+U1T9 CONTINUE T DENLIDF - DCRT*( 1 +Y)

10

DDSDT DCPT+Y1T « RETURNEND

28

0.0

o

o

o


FUNCTION EPF LF ( L , M, T, DA , DB )

C GET C MANGE OF E, S, CV WITH DENSITY ALONG ISOTHFRMS.GET E DE L c » PELS, DELCV from DA TP DP ON ISOTHEPM T.POMBFPG NUMERICAL INTEGRATION VIA -

C APNAHAN/LUTHER /HLÊ S, APPLIED NU M F p IOAL METHODS, P. 90,JOHN WILEY AND SON'S, INC., N.Y., 1969.NOTP. NMAV . % NK . FINAL, TOTAL SUBDIVISIONS OF INTERVAL D *

,

CPM*inN/l/AL,BE,CA,PE>E D ,ET, nCPT,TC 0 T,PCPT, DGAT,DTRP,TTRP,PTRPC0 M M0N/3/DPDT,D?PD T ’,0 o SDT,DPNDT,DPnD,DPDR,DTSDP,DTHDR,DDSDTCOMMON/11/ DELS, DELCVC0 u M0N/l?/ZCPT,ZCALC,n7DT, ZSAT,D7SDT. ZFX, RRT,DRRTDTDIMENSION F ( 2 C ) > S ( 2 0 ) , C C 2 0 )

DATA ( L D *= 1 ) , (01 = 0.00 001 ), < GO. 0 831A5)

1

pn?MA T (lM09Y*EDFLR L -*I2,5H, N «I3»5H, T « F8.3,6H, DA -E1C.A,1 6 H , DE * E 1 0 . A , 6H, LD -12//2 1DX 1WN 7X5HEPELR 8 X A HOE L S 7X5HDFLCV )

? F 0 R M A T ( l H 0 9 X 6MEDIF * FI 0 . 3 , 8H, SDIR -FID. 5, 9H, CVDIF -F10.3)

3

FORMAT ( 6 X 15. F 1 2 . 3 , F 1 2 . “5 , F12.3)A format ( I *-• 0 9 x *EOELF NG AT TC R T FOP CV AT DEN NEAP OR GT C.P.*/)

C FOP D A = 0 AND DP.LF.DI, TDEAL GAS, E D E L F - D E L S - DE L C V = 0

.

C FOR DA=0 AND DE.CT.OI, START R PM 8 E P G WITH DA = DI,C TO AVOID INFINITIES IN ORDINATE FUNCTIONS AT DA - 0.

5 N< i 1 t cm - DC PT / 2 < DZ - C.9°*DCRT9 7K = 1.0 - 1/ZCPT « RK - 100*S* T C=T/DCPT

10 I F C L . F 0 . 0 ) 11, 1A

11 IP(D«.LE.DI) 12,1312 EDELF OFLS * DELCV * 0 ? RETURN13 DA = DI

C GET FIRST TRAPFZOIP AREA, c( 1 ) ETC., FROM DA TO DE.

14 DX » DR"- DA « R - PVT P (T,DA,0) l IF(DA.LT.DM) 16,17Ei , PKMZk*ZSAT*7FX + FRT - T+DFRTDT) < GO TP 18

1 7 EA = i C o*(P-T*DPQT)/DA/OA18 IF(L.Eo.r) 19, ?C

19 SA - -pk*DFPTDT $ GO To 21

20 SA « -100*DPDT/DA/DA’1 CA - -10C*T7D2ddT?/DA/DA2? P = PVTF(T,D3,D) t IF(D8.LT.DM) 2 b

, 2 A

53 £3 x R k + (7K * Z

c A T* 7 F X + FRT - T*D FR TOT ) J GO To 25

2A F3 100* ( o-T*D p DT ) /D8/D325 IF(L.EC.C) 26,2726 s a - -pk*dfptdt % GO TO 28

2? SB - -1CC*D ROT /D8 /03

?3 ra, « -] oo*T*D2PO T P /DB/DR

29 E(l)=(EA + FP)*DX/2 $ Fm = (SA+SP)*DX/2 » C(l)-(CA + C8)*rx/2

C INTERVAL HALVING, GET E(N+1), ETC.

3D DO 60 N . I , m % * « N + 1

31 JM * 2 **N - 1 t OXN - DX

/

2 * * N $ E(K) » S ( K > - C(K) • C

33 DO A5 J=1,JM,2 $ NK = NK+1 $ DN - DA J*DXN

34 p X RVTF(T,DN,0) % IF(ON.LT.DM) 35,363c

£ a x RK*

(

ZP*7SAT*Z C X + FRT - T + DFRTDT) % GO TO 37

-36 E8 - 100*( P-T + DPOT ) 7DN/DN37 IF(L.FO.O) 38,3933 53 , _pk*DFPTDT 1 GO TO AO

39 S3 -130*DPDT/DN/QNAD C 3 - -100*T*D2 p PT2/DN/DN4 1 E(P) = F ( K ) f B l SCO S(K) SB % COO * C(K) + CP

A5 CONTINUE 1 E ( < ) = F ( N ) / 2 E ( O * n *N

29


46 S(K) x S ( N ) / ? * S ( K ) Q X N $ C < K ) = C ( N ) / 2 + C ( K ) 0 X N

r

C TEST FOR CON VF p GE NC E

.

50 E n x a 3 S ( E (k )-E (N )

}

5 SD-ARS ( S ( * )-S (N )

)

% CD= APS (C ( K )-C ( N )

)

53 IF (PP.LT.0.2) 54, 6054 IF ( SD.LT.C .002 ) 5 5,6055 IF (T.EO. TCPT. AND. PP.GT.QZ) C-0 TO 5 7

54 IF(CD.LT.0.04) 5T , 6057 F D p L F = F ( K"

) $ DELS = S ( K ) S DELCV * C (K ) $ RETURN60 CONTINUE $ N * M 1 N 3 x N-l t NP X N + l

61 PRINT 1, L, N, T, DA, D8, LD62 PRINT 3, N m , F (

n

y

)

, S ( NM ) , C ( NR ) $ PRINT 3 , N , E (N) , S (N ) ,C (N )

64 PRINT 3, NP,E(NP) »S(NP),C<NP) I PRINT 2, ED, SO, CD33 STOP

END

FUNCTION F INDEN'F ( T» 3)

C 0 N TSOThpRR T, PINT DEN, MOl/L, TC “TNIÎZE ( P -P C ) VIA CONSTATE.rpMMO N /i/4(_,RF,r-,4,nc,FP,ET, DCR T, TCR T, RCR T , DGAT,DTRP,TTRP»PTRPCDM*nNn/CiPDT,D2<> DT2tDPSDT.nPMDT,DPt'G,DPDPfDTSDP»DTHDP#DDSDTDATA (GKK = 0.693145)

41 FDRMATdCiO <3 x *FINOFNF * 0, PAILS TD CONVERGE. * / )

62 FOP“AT(].MO 9* FIN'IEMF . nCPT, DP/DP ZERO OR NEG. * / )

6 3 Cfi»«AT(lwo cx +CINOFNF . 3, OOU n LF-VALUFO AT 0 * PSAT. * / )

0^ = 1.1C+DTRP I IF(P.OT.O) 1,3 s

1 Ic

( T-TCPT) 2.5,8’ PS PSATF(T) 1 IP(P-PS) 3. 32.

A

3 OG * OFMTASF(T) % D = DG / 2 } GO TO 114 DL » OENLIOF(T) t 0 = (DL+DTPP)/2 T» GO TO 11

5 I p(p- 3 C p T) 6.33.7

6D-DCPT/2 T GO TO 117 D = 2»DCPT % GO TO 1

1

3 PC = PVTF(T.DCPT.O) % I F ( P- D C ) 6,33,711 00 30 J*1 , 50 « dp=°-°V t F (T.0,1 ) i I p ( A 3 S ( DP

/

0 ) -1 . OE-7 ) 31,31,1212 I F ( DPOD.GT. C) 13,3413 p>D * OP/DPOP ? I p ( A o $ (DD/0)-l .OF-7) 31,31,1414 0 = 0 + 00 $ IF(O.GT.O.C) 16,1516 0 » P/GKP/T ? GO TO 3014 IF(C.GT.OM) 17,1817 0 • OM 1 GO TO 3013 IF(T-TCPT) 13,24,3013 IF(o.LT.PS) 20,2220 IF(D.GT.OG) 21.3021 P - DG % GO TO 3022 IF(D.LT.DL) 23,3023 0 * OL 1 GO TO 3024 IF(P.LT.PCPT) 25,2725 IF(D.LT.nCPT) 30,26?6 D * DC p T - C.02 $ GO TO 3027 IF(D.GT.DCRT) 30,2323 D « DC p T + C.0230 CONTTNUE i PRINT 41 % STOP31 FINDENF = D $ R p TUR N

3? PRINT 63 T STOP33 PINOENF • DC P T % RETURN34 c

I N n F N F x DCRT I ppINT 42 6 PETUPN35 FINnFNP = DPDT = D2P r'T2 = 0 % DPDD=GKK*T 1 D PD R » D P DD * DTR P

36 RETURNEND

30


FUNCTION FINDTfF(P)C GIVEN o rjK thc mating LINE, fjnD T FOR p p n p AN E

.

C0mmon/1/AL,BF,GA,DE»E d ,ET, DCRT,TCRT,PCRT, DGAT,DTRP,TTPp,pTRPDATA ( E*1 .203 ) . (A-7180.C)

1 X » <P-PTPP)/A + 1 t F I N D T M F . TTPP*X** ( 1 . 0 /E ) * RETURNEND

FUNCTION FINDTS c(0

>

C GIVEN VAonc PRESSURE ITERATE T TO MINIMIZE (P-PC).Common /I /AL>9E»G A ,DE»E 0

» ET» OCPT,TCRT,pCRT, DGAT,DTRP,TTPp,ptrpCOMMON/ 0/DPrT,n2POT?,DPSDT,DPNDT,DPDD,DPDP,DTSOR,DTHDR»DDSDT

1 fp^m AT( 1h3 Qy *FINDTSF * 0, FAILS T0 CONVERGE. * / )

7 FOR m AT(1mo 9x *FINO t S c « 0, a EXCEEDS PCRT. * / )

3 IHP-PCRT) A, 11,1?A T = (TTPP+TCRT ) /?

D n 9 J=l.SO ? D = * P - PSATF(T) 1 ADP * ABS(OP)0 IF ( ADP/P-1. CE-7) 10,5,0a IF ( ADP/QPSOT/T-1 .QF-7 ) 10,7,77 T = T PP/DPSDT % I F ( T-TCRT ) 9,9,03 T > TC R T

9 CONTINUE t PRINT 1 i STOP10 fjnDTSF = T $ RETURN11 F I N G j S F = TORT t R c TURN1? PRINT ? $ STOP

END

SUBROUTINE GFNEO'JS

C given p,T fop the ho m OGENE'TUS domain -

C GET D F N AND FUNCTIONS AT ANY TF MD F®ATURF,CnMM 3 M/3/r;ppj,02PDT?,D D SDT,DRMDT,0PDD, n PDP,DTSDP,DTHDR,DDSDTCOM-ON /« / IN, I®, P,T,DEN, E,H,S, CV,C S ,CSAT, w,WK

CO M M ON /ll/ dels, delcvC0MMON/9G/ TI , E Z

7,

C7 ,SZ,CVZ, H Z , C P 7

DATA (O*1.C1325)«(G«D.O031A‘>)3 TI . T T CALL IDEAL S IF(P.GT.C) A, 10

A D F n = D3 * FINDENP(T,P) i M x 15 T DA = L * 0

5 E * E Z 7 + EZ + EOELF(L» M »T»DA,DR) 1 H * F IC0*P/D9

5 S SZ + DELS - 100*G*ALOG<G*T*DB/0)7 C V * CVZ DFLCV % P X * PVTF(T,DB,1)n CP • CV 1 00*T /DPDO* ( DPDT/D3 ) **2

9 U SORT! VP*CP*D 0 DD/CV) 1 RETURN

10 D E N S * 0 « E E77 EZ « H - E + 100*G + T 1 CV-CVZ t CP-C*

17 W * SO p T(WK*CP*G*T/CV) * RETURN

END

31


SUBROUTINE GFNIUSC VALID INLY FOR THE HQMQGE NE OUS DO M A IN.C S A V E F C 0 Mp UT E e TIm E wmfnj TABULATING FUNCTIONS ALONG ISOBARS.C S A V F S OEN,E,S,CV ALONG ISOBARS FOB USE IN INTEGRATING TO NEXTC HIGHER ISOBAR. VALID ONLY FDR «ON ETON IC A L L Y INCREASING ISOBARC PRESSURES, AND AT TEMPS. T * TNTEGFP MULTIPLES OF 10 K.

COM', ON/?/DPDT,D2PDT2,DPSPT,DPMDT,DPDD,QPDP,DTSDP , DTHDP , DDSDTCO m mon/P/ IN, IK, R.T.DEN, E > H , S , CV.C°,CSAT, W,WKCOMMON/11/ DEIS, DEICVDIMENSION 0K( 100) , EK( 100), SK ( 100 ) ,CK( ICO)

1 F np w 4 T ( 1 (-0 9X * G E N T U S T NOT INTEGRAL. * / )

2 J T/10 ? IF ( T - 10* J ) 3,43 CALL GENEOUS % RETURN4 IF (IK. CO. IN) 5,95 CALL OENEDUS5 DK(J) - DEN % E K ( J ) - E ? S *< f J ) « $ % CK(J)«CV T RETURN

C TNTEGBATF FROM OLD OF N IJP TD new DEN on GIVFN ISOTHERM.9 DA * DK(J) % DK(J) => DEN = 03 = FINDENF(T,P) 1 N * 14

11 EK(J> * E * EK(J) + EDELF(1,N,T,DA,DB) i “ = E + 1D0+R/DB13 FK(J) = S - S k

( J ) + DELS t C K ( J ) - CV - CK C J ) DE L C V

C NOW GET NEW DP/DT. 0° / DU, C p, W.

15 PX = PVTF(T,DB,1) % CP = CV 4 1C0*T /D D DD* (

D

3 DT / D B ) * * 2

3D W SOPT( WK*CP*DPDD/C V) % RETURNEND

C

C

C

FUNCTION h s A T c ( T

)

HYDROGEN S U L P I D F SATLIO FNTHAL°Y, J/ m H|.., RDG/N3S, 4/15/B3.DEFINE YH # f H-HC ) / (HT-HC ) , X * ( TC-T ) / ( TC-TT ) , WHEN -

YH « X (XE-X)*(AI + A ? * X H P A 3 * X A4*X? *•.,),DIMENSION A H ( 7

)

1

1

2

3

4

5

6

7

9

9

DATA ( NCH.7) , ( F H=D . 35 ) , ( H£rO. 70)DATA ( TTPP»l 87 .4,5 ) , ( TCRT = 373. 4C )

DATA (HTPP = G.7ST), (HCPT=1707B,R*<i)D A T A ( A u * 0.456446719, 0.D171915C2, 0.207055352 ,

-1.904453730, 3.744014417, - ? . 7 R B 59 c 4 5 4 , 0.499929755)FORMAT (1H0 9 X 3 HT »F 10 • 5 » + IN HSAT C (T) .*/)IF(T.GT.TCRT) 3,4PRINT 1, T % STOPX (TCRT-T)/(TCRT-TTRP) % IF(X.LE.O) 5,6HSATF * HC R T t RETURNV = X*«ch - X S XH = X * * HFF < « X V * ( A H ( 1 ) + A H ( 2 ' * X H ) $ p,D R K * 3 , N F H

FX - PX + V*AH(K)*X**(K-P)HSATF = HC R T - (HCPT-HTR P )*F* * RETURNEND

32


StmTJTIMF idealC H?s VIA 3 A E H R ET Al> 1968.

C°Z/9 * 4.0 + ( A 1 + x 4 A 7 4 A 3 / X 4 A 4 / X 7 4 . . )*FXP(-E/X), XXT/100.Com«on/ 9Q/ T I , E 7 ? * EZ,SZ»CV7* HZ,CP7DI‘*ENSI r'^ A (6)DATA <NK - 6) ,(E - 10.37)DATA (Fx8,3]45),(SI*76.146)»(HT»4.0168)D A T A ( A = -0.19525562. 11.0377525, -74.8072768,

1

330.650148,

-655.671639, 475.053933)1 XI TI/10C 5 xo . EXP(-E/XI )

3

C p * 4.0 $ DO 3 <«1,MK3 CP * CP + A ( K ) *XP*XI + ( 2-K )

C numerical INTFRP ATI ON FDR mz/R, S7/R -

5H.S-D J N » A8S(TI-3C0) /4 4 1 % DX . { X I -3 ) /

N

6 DO 10 J*1»N f X « 3.0 4 ( J -0 . 5 ) * D X $ XP * E X P ( -E / X )

7 CPX >4.0 J DO » x=l, NK3 CPX » C°x 4 A (K )*X 3 * X** ( 2-K )

9 H H 4 C Py*n> * S S 4 CPX*DX/vID CONT

I

VUE « (HI*3 4 H ) / X I $ S = SI 4 S $ PT - P*TIC CONVERT TC JOULES, MILES, KELVINS.

11 MZ * RT*h i P7 « u 7 - RT 1 S 7 * ?*S17 C D 7 P * C ® 1 CVZ C D Z - P ? RETURN

E N n

SUBROUTINE ISOTHRmc PRINT H 2 S CRITICAL IS3T~IER«.C USE D

»M P A , AND DEN REDUCED RY DC»T, NOT DTPP.

COM M ON/1 / A L »PE,GA,DE,EP*ET , DCPT,TCRT,PCRT, DGAT ,DTP°,TTRP,pTR®CON‘'0N/3/DPDT,D3PDT3,DPSDT,DPMDT,DP0D,DPDR,nTSDP,DTHDR,DDSDTCnÎM /4 /X°l . X32 , XC 1 > XC 2 » XE1.XE2, D X3DR , DXC D® , D * EDRCOM“ON/6/ TSAT, THETA, PSAT

1 FORMAT ( 1H1 1 4 X HYDROGEN SUL P IDF CRITICAL ISOTHERM //

1 1 5 x 4H TC * F 8 . 3 , * K * AH, DC « E 6 . 2 , * mql/L, ®C = * F 9 . 6 , M P A > /

2 1 5 X + A T Tmc C.R., DPS/DT -*F0.6, *, DP/DT F9.6»* “PA/K.4 //

3 6*4H r'/ r'r 8X5HTS/TC 7X6HDTS/DD 8X5HPS/®C 7X6 HD d S/DD4 9X4HP/PC «X 5 HDp/oo qx5HDP/DT fX7HD?°/DT2 /

5 Z9X7mr-l/mdl 17VQHMPA-L /HPL 17X9H“PA-L /MOL 8X5hmpa/K 6X7hmp A /K/K)p p OP ma T( 3 v F 6 . 3 , 7F13.9, F13.5)3 PC P VT C

( TCPT,DCRT,0) t PCS « RCPT/104 U p B S DT « DPSDT/10 t D° X DT « D p r T / 1 0

5 PRINT 1, TCRT,DCRT. PCS, DPSSDT,DPxDT t DR D S - DCRT/DTRP4 DO 12 J * 1 , 4 1 % DR* 0 . 8 9 c 4 0 . 00 5 J 1 DN D R * DC R T

7 PR P VTF ( TCRT , DN, 1 )/ OCR T * D p S D R DPSDT+DTSDR

8 TSN * TSAT/TCPT * ®SN * PSAT/PCRTq DPOD = D p DR*DPD <:

/ 1 0 t OTSDD = DTSCR *DR DS J D ® S DD - D® S OR DR D S / 1

0

10 D p D T « 0 ®9 T /I 0 T D2PDT2 * D2®DT2/10I F ( j.EQ.21 ) D2 ®DT ? * 0

IP PRINT 2, DR, TSN,DTSDD, PSN,D®SDD, PR, DPDD, 0°DT,D2PDT230 RETURN

END

33


RU9P0UTINE JTLOCUSC the J DUL E-THniS r

'Ki INVERSION LOCUS FOR HYDROGEN SULFIDE.C P F p I V R THR J-T INVERSION CURVE. USE ROUTINE P F L T 4 F ( T , D I ) .

CTM*r)M/l/AL,RE»GA»DF,E D »ET, DC p T.TC p T,PCRT, PGAT,DTRP,TTRP,PTRPDIMENSION DM''0),DN(60>»TT(ft0),PP(60>TATA (A=l.?275),(P=O.Ae5),(w“=3A.09)

1

FTP" AT ( 1 mi ifcx* jmjL F-THH- SIN INVEPSI n N LOCUS FOR HYDROGEN SULFIDE*/1 1 7 X *(0I IS INITIAL DENSITY RPR ITERATION) * II

2 1 7 X 3 U T , K E X 2 n C I 5Y5HNOL/L 5X5hP,H°a3 7 x 3 MT,v bx’hoi SX5HOOL/L 6X5HP,M D A )

? pprmAT( 10X 110. 2 F 1 o , 3 . F 1 0 . 3 » 110. 2F10.3, F10.3)3 FO p NAT( inn fcX*J0UL c -THOYS0N INVERSION LOCUS FOR H Y DR OG F n SULFIDE*? // 17 x ahT.R 5X5HHPL/L 5X50®, “RA 7 X 3 H T , K 5x5HRpL/L 5X5HP,NPA )

A FORMATdC'X 110, 2 F 1 0 . 3 , TIG, 2 E 1 0 . 3 )

c save initial, trial density, dr ( i j - di.5 n P 5 6 9 T A 2 7 0 % PRINT 1

6 00 2 *5 1=1, NP 9 DX = D.6A 9 T r TA + 10*17 X * T/TCPT 9 DR ( I ) =01= DCRT*EXP( A-B*X )

ID IF (T-TC p T) 11 ,1 2,1211 DL = PEMTOP(T) 9 IF(DI.LT.OL) 23,121’ SS = n

E L T A R( T »

nI ) $ DO 20 I T = 1 , 16

1A Dr^l-DX 9 SL =DEL TA= ( T , 0 ) 9 0=DI+DX 9 S P « 0 E L T AF ( T , 0

)

1 5 IP

(

SS-SL

)

19,16,1616 IF ( S p-SL

)

10,17,1717 SS = SL 9 DI =oi - 0 x 9 GO TO 2019 IF ( SS-SD ) 20,20,1619 SS = S° 9 01 - 01 + D»2D Dx » OX 12 9 TT ( I ) = T 9 DN ( I )

= 01 9 Po (I) = PVTF(T,DI ,0)’1 GO TO 25} 1 TT( I) x T 9 DR ( I ) = om ( y ) « PP( I ) = 0

25 CONTINUE 9 N « NP/225 00 35 J=1,N 9 R * J N

27 IT r TT ( J ) 9 ITT = TT(K)29 DR J = 0 R ( J ) 9 DNJ = 0 n

(

j )

27 PR ^ » DR(R) 9 DNK = D N ( R )

3D PPJ P P( J ) /ID 9 °0R * P p ( R ) / 1 C

35 PRINT 2, IT, OKJ.DNJ, PPJ, ITT,CRK,PNR, ppr',0 point 3 9 DO A 5 J»1,N .9 R « J N

A1 IT « T T ( J ) 9 ITT * T T ( K ) 9 DNJ - DN(J) 9 PPJ • P D( J ) / 1

C

A 2 DNR « DN(R) 9 PPR = 0 P ( R ) / 1 c-

A5 PRINT A, IT, DNJ, PPJ, IT?, DNR, PPR50 PFTIJPN

END

34


SUBROUTINE KAYC COMPARE H2S SATN. DATA Of K A Y/R AMBOSEK, 1953.

DATA (VN*3A,0B),(AL8*A53.592A)»(CUF*28.31665)1 FORMAT ( Af 1 0 . 0

)

2 FOPHATdHl 13X *HYDRCGEN SULFIDE COEXISTENCE*1 * DATA OF KAY/PAMBOSEK, VS. ROG (CALC) //2 1 A X 1HT 7X13HPRESSURE, MPA 9X13HL IQDEN, NOL/L 9X1 3HG AS DEn, NOL/L/3 1 A X 1HK 3(AXAHDATA AXAHCALC 2XANPCNT ) )

3 FORMAT (5X F 10. 3# 2F8.A,Ffc.2, 2F8.3»F6.2, 2F8.A,F6.2)5 PK « 1.01325/1A.696 $ DK - ALB/CUF/WN

10 PRINT 2 $ DO 30 J«l,9911 READ 1# TF, PS I # D L 8, DG B \ IF(TF) 12,9912 T • (TF A59.67)/i.e S PX - PK*PSI $ DLX - DK*DLB13 PC - PSATF(T) $ PPCT * 1 00* ( P X- PC ) / PC

1A DLC » DENLIOF(T) $ DLPCT » 100* ( DLX-DLC ) /DLC16 IF(DGB.EO.O) 17*1817 DGX DGC • DGPCT - C J GO TO 2018 DGX - DK*DGB $ DGC - DENGASF(T) $ DGPCT « 1 00* ( D GX-DGC ) / DGC20 PX - PX/10 S PC * PC/1030 PRINT 3* T, PX. PC, PPCT, DLX , DLC , DL PCT, DGX , DGC, DGPCT99 RETURN S END

35


SUBROUTINE P C E«

C E * & M T N F PFHAVIPP O'1 Tme EOS COEFFICIENTS.C B(S) # B1 + P?*S + B 3 * S 2 » C(S) « Cl C 2 * S + C3 + S2*C F(S) » E1*(S-1)*(S-ER)*EXP(-GA*S**IX).C WH E P F » D » PFN/DT3P, S n DEN/DCPT.

COmmpn T X, FP , GK ,G<* , 41,42,43, Bl, 82,83 , C1,C2,C3, E1,F2,E3CDMM0N/1/AL»3E,GA,DE»EP,ET, DC P T , TC PT , PC P T , D G A T , D T P P , T T P P , P TP 3

CO M ÔN/3/DPDT,r>2PDT2»D p SDT»DP^DT,DPPO»DPDP,DTSDR»DTHDP»DD$QTCOMMOn/6/ TSAT, TMFTA, P S 4 T

4 FnPMATdHl 14X * E ON S T ATE CnE p FS., HYnpoGEN SULFIDE * //

1 15X6HTTPP E 1 3 • 8 » R4, TPLP -E13.6, «H, TCPT -E13.6, * K,* /

? 1SY6MPTPP = E 1 3 . 6 ,bei, 0 p L P * E 1 3 • 6 , R4, PC p T -E13.6, * MPA,* /

3 lBX4-wnr,AT * FI 3 ,6 » pm. DGRP -E13.*, 84, DCPT -F13.6,* MOL/1,* /

4 15X6HDTPP -E13.6, 8H, DLPP -F13.6, 84, DCPT -E13.6,* M 0 L / L » * /

5 15XQMDPS/DTP * El 2 . 5 , * mpa/k, OVAPP, KJ/«DL -* F8.4//4 IPX 4 m I X =12, 6M, fr -F6.3 /

5 1 5 X 4 M A L F 1 0 . 7 , 64, RE -F10.7, OH, GA -F10.7/6 15X 4 4 D E -FID. 7, *>H, E= -Fin. 7, few, ET -F10.7 //

7 1 5 X 4 m 3

1

-F14.il, 84, R 2 -Fl4.il, 64, R3 -Fl4.il/8 1 8 X 4MC1 -F14.il, 84, C 2 -F14.il, 64, C3 -F14.1]/ )

5 FORmaT( 15Y 44D/DC 5 *5 H'' r'L /L 6X44TSAT 5X5HTHFTA 6X44P$AT

1 QX1HR 9 Y ] 4 C )

6 FORMAT (9Y F10.2, FID. 4, 2F10.P, FIG. 4, 2 F 1

0

. 5

)

7 TR = F INnTSF ( 1 . 01325 ) I D GP - D F N G A S F

(

TB ) % DLB -DENLIQF(TB)p OP - T n *n°SDT*(l/DGP - 1/DLR)/1C.07 PTP - PTRP/10 7 P3L«0.ini325 } por.pcpT/10 8 D°SDT -DPSDT /ID

10 PRINT 4. TTFP,TR,T:PT,PTP,PeL,PCP,PG4T,DGR,DCRT,1 OTPP,DLP, DCPT, DPSDT, OR, IX, FP, A L , 3 F , G 4 , DE ,

E

3, E T

,

2 C1.C2.C3, F1,E3,EB11 PRINT 8 * N = 10*DTP°/nC»T 1

1’ DO 20 J = 1 , N i S = 0.1*

J

13 on * S *DC p T % S 2 - S * P * SN-S-1 $ SX - S * * I X

14SP-1 * I F ( E p . G T . 0) SP-S-ER15 8 » 31 + p 2 * S B 3 * S 2 1 C - Cl C2*S C3*S21 7 E = E1*SN*SP*F*P(-GA*SX)17 TS4T-TS-TSATF(0N) <, Th-T4FT4F(DN) t p S S A T F ( T S ) / 1

0

20 PPTNT 6, S , P N , TS,T4,0S, C»E 7 PETUPNEND

FUNCTION p M E L T F ( T

)

C RROPANF MFLTING LINE. PAP, VIA PEFVES, SCOTT, AND BABP(JP),r j. CHFM . 0 4 Y S , 40 ( 12), 366? (1964).

COMMON /I

/

AL , PE ,G A , DE .

E

P, E T, OC

P

T

,

TC PT , P

C

R T , DG A T

,

DTR P , TTR

P

, P TP p

C0MMON/3/DPCT,D2PDT2»DPSnT,PPMDT,DPDD,DPDR,DTSDR,DTHDP,DDS0TDATA (A = 71 PC.O) , ( F « 1 .263

)

1 X - T/TTPP * XF X**E 7 OMELTF - PTPP 4 A*(XE-1)? D p M D T » A*F*XE/X/TTRP I RETURN

END

36


SUBROUTINE PVTDATA^2$ EOS CONSTANTS, RDG/NPS » APRIL 15, 19 03 .

I^>tP,GK»GKt<» A 1 , A 2 , A 3 » 8 1 , B 2 , 3 3 » C1»C2»C3» E 1 » E 2 # E 3CnM«rjv/l/AL»3E»GA»OE»EP»FT» DCRT>TCRT, 0 CRT> DGAT»DTR p >TTRP>PTRPC'l^^DN /P/IN, IK, P»T»DFN» E»M,S, CV.CP.CSAT, W,WKCOmmom/ip

/

7rPT,ZCALC»07DT, 7 S AT , DZ S C T » Z F X , FR T» OF RTDTCORMON/RQ/ TI,E77, F7,SZ,CV7, H Z » C P 7

ID W* = 34. CPC $ TTRP = 107.86 S TC R T = 373.4012 DC R T = 10.20 7 0 T RP * D F N L I Q F ( TTRP)13 PTRP * °SATF(TTP°) 1 P C p T » PSATF(TCRT)17 GKK * O.C833 % G R GKK*DCRT2D 7C R T = PCPT/DCRT/P^R /TCRT $ DGAT * 0 F MG A SF ( T TR P )

* al=1.D % PE * 0.75 $ GA 1.0/IX22 DE E° « 0 * ER - 2.0 « ET « 1.10’3 A1*A?=A3*C ? Fl*82*33*0 $ C1*C2*C3*0 % F1 = E2*E3«028 Cl = 0,3P a 2 c F7o^73 % C3 = 0 . 1327018703 9 1 FI * -0.3107087111327 VK * 100000 /** $ E Z 7 * 13400.13830 RETURN

FNO

FUNCTION PVTP(T,D. u>

C HVPR-'GEN SULFIDE EONSTATE, PVTF . P,PAR.NOTE. RETURNS D*/DT, D2P/DT2. M = l RETURNS A l S DP/OD.e-RSAT = S*GK*( T-T5AT) S * S* OK *T C R T*F ( S , T ) , WHERE -

C P( S > T ) # P(S)*7PF(S»T) C(S)*XCF(S*T) E ( S)*XF F ( S,T)

,

C P(S) * PI + p?*S + 3 3 * S 2 » C(S) * Cl C 2 * S C3*S2>C E ( S ) * c l*( S-l )* (S-FR )4FyP(-PA*s+*iy)

.

C pc, ? # ofn/dtro, S # den/dcrt.CQRRON Iv,ER,GK,GKK, a 1 , a 2 » A 3 » *1,82, *3, C1,C2»C3, E1,E2»E3Cn*MnN/l/AL,P F,GA,OE»EP*ET* DCRT,TCRT,PCRT> DGAT,DTRP,TTPP,pTRpCDMMDN/3/DPDT.D2PDT7,DPSDT>DP^DT,DPDD,DPDP»DTSDR,DTHDR,DDSDTcommon /A /XP1 , XP2 , XC 1 > XC 2 » x c 1 » x E 2 * D xp DR , D xC DR , D X EDRCOM*0N/E>/ TSAT, THETA, PSATCOmmon/ 17/7CRT,ZCALC,OZ^T, 7SAT»07S r'T*ZFX» FRT,PFPTDT

1 S = D / DC R T % c 2 = S*S % SN = S - 1 $ SN1 - 1

3 = s - E p ? S? 1 = 1 t S X S * * I X

5 G< « DCRT+GKK « TC - TC»T 1 DSDR » DT p P/DCRT6 RG « S *0K $ GKT - GK * T r

7 TS4T=TS = t SATE(D) T PS A T= PS= °S ATF ( TS ) $ THETA«THETAP( D)

3 xC * x C P( T , D ) ? y E * x E

p( T , D ) i C * (Cl + C3*S2)*S2

10 XP * EXP(-GA*SX) T S E * E 1 * S 2

11 S* « SE + SN*SR % F - S M * X P

12 F * C*XC + F * x F $ PI - C * XC 1 + F * XF 1 % F2 C*xC2 E*XE2

13 PVTF . PS + RGMT-TS) + GKT*F t FPT-P/S2 t 0 F R T DT • F 1 / S 2 / TC

13 DPDT = RG GK + F1 % D2 D DT 2 • GK+F2/TC S I F ( M ) 15,3015 X R 1 * -IX*CA*SX/S i SF1 = 2 * F 1 + S

17 3“l . SF*SN*SR1 + SE*SN1*SR SF1*SN*SRIP ED ( S M * X P 1 + S M

. 1 )*XP*DSDP

IQ CD ( 2 *C 1 A*C3*S2 )*S*DSDP20 FI = C*D XCDP CD* XC + F *D X F DR + FO*X E

2-3 DODR * (DPSDT-RG)*OTSDR ( T-T S ) +GK *D SDR + GK T* F 1

27 DPOD DPDR/DTPP30 RETURN

END

37

Appendix F Continued

F UNC T I ON PSATF(T)C H2S VAPOB PRESSURE, RAP, 3/21/83.C L N ( P ) - P!/y + P2 + P 3 + X + P8*x? + P 5* X 3 + P6M 1- X ) **E P P .

Cn^ M nM/3/DPnT,n?P0T2»D D SnT,noMnT,0PnD,DPDP,DTSDP,DTHDP»DDS0Tni-FNSIHN P J ( 6

)

DATA ( EPP*1 .70) , (TCPT- 373 . AO)D A T A ( P J « -8 .023473 844 , 18.731082287, -10 .325650140,

1 9.890908499, - 3 .

5

T 7 1 6 ?0 8 1 , 3.178310817)1 FOP84T(luo QX *T A ROVE TCPT IN P S A T F ( T ) . * / )

8 X « T/TCPT $ V « 1.0 - X % IF (V) 7,0,97 0 P T N T 1 f STOPR 7 = 71 = 0 % GO TD 109 Z V* * E 0 P f 71= -E°P*Z/V

10

D L - PJ f 6)*7 % P L 1 * P J ( 6 ) + 7

1

U 00 1 3 8x1.8 s L * <-2 t XL - X **L1? p L = PL * P J ( K ) * X L « P L 1 * 0 L 1 + PJ ( 8 ) *1 *XL / X

13 CONTINUE 1 0 S A T F x FXP(DL)15 DPSOT « PL1*PSATF/TCPT % SETUPN

END

FUNCTION 0 V A D x F ( T

)

C 0 V A p , J/MOL, VIA CLAPEXPON. ^ F N G A S F ( T ) CALLS dsaTF(T).Cn88OK/-a/0POi,o?DpT5,OPSDT,DP M OT, r| PD r',D pr>R,rTSDF,OTHDP, rtDSDT

1 VL = 1 ,'J/OFNLIQF(T )« V G = 1 . * /D F NGA S F ( T )

2 0 V A p x f x 100*T*D°SDT* ( VG-VL

)

9 P F T IJ P N

E NO

FUNCTION S S A T f ( T

)

C H YD9 OGEV SULFIOE SAT1I0 FNTPODy, j/*OL/><., PDG/NPS, 4/15/03.C YS - (S-SC) /( ST-SC ) , X . T/TC, ALT - LNtTT/TC )* U « ( TC-T ) / ( TC-TT )

,

C CONSTPMNFO AT T p T p L E ANO CPITICAL POINTS.C YS = UE A1 ml M X ) /alt - UE ) + A 2 + ( U 2 - UE).

DATA ( TTPD=1R 7 .66) ,

(

T CPT*373.40)DATA (ES-0.35),(FE-0.85),(STPP*109.?P667),(SCPT-167.26532)DATA (ALT = -0.6 a P01 R *» 2 )

DATA ( A 1 *0 . 412268784), ( A?»0. 212761017)1 FOP0AT(1HO 9 X 3HT -F10.5, * IN SSATF(T). * / )

2 IF(TCBT-T) ?,4,53 P P I N T 1, T * STOP4 S S A TF « SC P T $ P E TUP N

5 SN . S TP 0 - S C P T l UN - TCPT - TTP p % U » < TC R T— T ) / UN7 y > T/T^T % U E «

IJ * * E S

0 YS - UE + AlMALCGm/ALT - UE) A2MUH' - UE )

9 SSATF - SC p T + S N * Y S 5 PETUPNEND

38


SUBROUTINE STAPLNGC COMPARE STAPLING H’S CEPAPTUPFS WITH RDG.C HIS T,F. ° >

D S I > V , C UP T /LB, h,BTU/LP» S»BTU/LB/R.C T. KELVIN « (T,PANKINE )/1.8.C 1 L" > 453.6924 GRAM, 1 CUPT - 28.31685 L, 1 BTU - 1055. JOULE.C ONF PT'J * ( 453.5°24)*(4,184) / (1,8) - 1054.350 JOULES.C TO CONV. LB TO Mn L »

M l'LT. BY ( 5 2 . 592 4 ) /WMC TO C^NV. CUPT/LB T n L/MOl, «ULT. BY ( 2 8 . 3 1 6 B 5 ) * WM / ( 4 5 3 , 5 9 ? 4 ) .

C TO CONV. BTU TO JOULF, MILT. BY 1055.0.C n C n NV. BTU/L a TO J/MOL, MULT. BY ( 1 0 5 5 . 0 ) * W * / ( 4 53 . 5 92 4 )

.

C TO CONV. BTU/LB/R TO J/M-U/K, MULT. BY 1 . 8 * ( 1 0 5 5 . 0 ) * W M / ( 4 5 3 . 5 92 4 ) .

Common /i/al,«e,ga,de»ep,et, dcpt,tcrt,pcrt, dgat,dtrp,ttrp,ptrpCOMMON/?/ IN, IK, p,T,OEN, E » H > S > CV,CP»CSAT, W,WKCnMMnN/cq/ T I , E 7 Z , EZ»S7»CVZ» HZ,CPZDATA ( R-R .3145 ), ( 9-1054.350 )

DATA (w M *34.0 fi ), (ALB = 453. 5924), (CUF-26. 31685)

1

Fnt«iT(l5, 4F10.0)7 POPMAT ( 1HH3X*HYDP0GEN SIJLFIDE PROPERTIES, S T A P L IN G ( D A T A ) VS.*1 * PCG(CALC)* //

2 1 4 K 1 H T 0 X 1 H P 8X14HDENSITY, MOL/L 1 0 X 1 5 HF N T H A L P Y, J/MOL3 1 2 X lBMENTR^PY, J/moL/k /

4 l 4 X ] H K 4X3HMD 1 5X4HDAT A 5X4HCALC 2 X 4H PC NT

5 ?( s X4HDATA 5X4HCALC 5X4HDIFF) )

* P0PM 4 T( e x F10.3, 8F9.4, F6.2, 3F9.1, 3F9.3)5 PK « 1.01325/14.696 IV K • ALB/WM/CUF

c b HK > 0*W M /ALB 1 SK 1.8+HK6 SK « 4 .1 a 4*WM S HK - SK /l . 8

1C PRINT ? ? DO 50 J-1,9911 PFAD 1, TTF, p S I * VB, H3, SB $ I F ( I TF . E 0 . 900 ) RETURN12 T « ( I T F 4 5 9.67 ) / 1 . 8 t P - PK*PSI $ DX - VK/VB

13 HX • H K * H B $ SX - SK*SP » RT - R*Tr FOP EACH ( T » P ) POINT, GET MY D F N , (H-EZZ), S.

C AT T,LT. T CPT* EITHER GAS, OP LIOUID.20 I F ( T. LT.TCPT ) 21,3021 PS « p S A T F ( T ) % IF(P.GT.PS) 23,3023 CALL C O w P R L 0 % 1XItX EZ Z $ GO TO 40

30 CALL G E N F n i1

S

! H « H - E 7 Z

40 D 0 1 F - DX - DEN T DPCT - 100*D0IF/DEN41 H D I F - m* - H t SDIF - SX - S % pis - P/ 10

5 C PRINT 3, T, PI', DX, DEN, DPCT, HX > H, HDIF, SX, S, SDIF

99 RETURN 1 END

39


SUBROUTINE SURFACEC PRINT H2S ISOCHORES, ISOTHERMS.

COMMON/1 / AL, BE»GA,DL , EP.ET, DCRT,TCRT,PCRT, DGAT,OTRP,TTRP,RTRPCOM MON/3/DPDT,D2PDT2»DPSDT,DPMDT, DPDD, DPDR,DTSDR,DTHDR,DDSDTDATA (R - 0.0931*5)

1 FORMAT ( I 5, 2 F 1 0 • 0 )

2 FORMAT(I5, FIO.O, 110)5 FORMAT(IX)6 FORMATdHl 10* *HYDPOGEN SULFIDE ISOCHORE AT* F7.3, * MOL/l* //

1 1 9 X 1 H T 9X1HP 9X1H2 6X5HDP/DD 7X5HDD/DT 5X5HDP/DT 5X7HD2P/DT2 /

2 19X1HK 7X3HMPA 1 2 X 9 H M P A-L / M OL 5X7HM0L/L/K 5X5HMPA/K 5 X7HMP A /K /K )

7 FORMAT ( 1 OX F10.3, F10.A, F10.5, Fll.A, E12.A, F10.5, F12.7)

0

FORMATdHl 1 6 X *HYDRCGEN SULFIDE ISOTHERM AT*F9.3, * K * //

1 17X3HDEN 9X1HP 9 X 1H Z 6X5HDP/DD 7X5HDD/DT 5X5HDP/DT 5X7HD2P/DT2 /

2 15X5HMDL/L 7X3HMPA 12X9HMPA-L /MOL 5X7HM0L/L/K 5X5HMPA/K3 5 X 7HMPA/K/K )

C PRINTOUT THE ISOCHORES.20 DO 60 1-1,99 $ READ 2, IDD, DN, IT * IF(IDD) 21,9921 IFd.EQ.20) ON - DTPP30 PRINT 6, DN $ TS - TSATF(DN) $ PS - P VTF ( TS, DN, 1

)

31 Z - PS/DN/R/TS S DDDT - -DPDT/DPDDPS-PS/10 i DPDD-DPDD/10 S DPDT-DPDT/10 S D2 PDT2 -D2PDT 2 / 10

32 PRINT 7, TS,PS,Z, DPDD, DDDT, DPDT, D2PDT250 DO 59 J-l 92, 720.IT $ TT - J S IF(TT.LE.TS) 59,5252 PP PVTF(TT,DN,1) S IF ( P P . GT . 850 ) 60,5555 Z - PP/DN/R/TT \ DDDT « -DPDT/DPDD

PP-PP/10 $ DPDD-DPDD/10 $ DPDT-DPDT/10 S D 2 PD T2 -D2 PD T2 /I

D

58 PRINT 7, TT,PP,Z, DP CD , DDDT , D POT , D2PDT259 CONTINUE60 CONTINUE

C PRINTOUT THE ISOTHERMS.

99

DO 130 1-1,99 % READ 1, IDD, TT, D* i I F ( IDD) 100,999100 IFfI.E0.13) TT - TCRT101 PRINT 8, TT $ PM - PMELTF ( TT

)

102 IF(TT-TCRT) 103,103,10*103 DG - DENGASF(TT) $ DL DENLIOF(TT)10* L - 0 $ ns - DX105 DO 120 N-1,900 $ DN « N*OS $ I F ( TT .L T . TC RT ) 106.117106 IF(DN.GE.DG.AND.DN.LE.DL) 107,117107 L L*1 % IF(L.EO.l) 108,120108 PG « PVTF(TT,DG,1) $ Z • PG/DG/R/TT $ DDDT - -DPDT/DPDD

PG-PG/10 $ DPDD-DPDD/10 $ DPDT-DPDT/10 % D2 P D T2 -D2 PD T2 /I

0

109 PRINT 7, DG.PG.Z. DPDD, DDOT , DPDT , D2PDT2110 PRINT 5

111 PL - PVTF ( TT,DL»1 ) $ Z - PL/DL/R/TT % DDDT - -DPDT/DPDDPL-PL/10 % DPDD-DPDD/10 $ DPDT-DPDT/10 $ D 2 PD T2 -D 2 RD T2 / 10

112 PRINT 7, DL»PL,Z, DP DO , DDDT , D P DT , D2PDT2116 GO TO 120117 PP - PVTF ( TT.DN.l ) $ I F ( P P . GT . P M . OP . P P . GT . 850 ) 130, 118118 Z - PP/DN/P/TT $ DDDT - -DPDT/DPDD

PP-PP/10 i DPDD-DPDD/10 t DPDT-DPDT/10 S D2 P DT2 -D2 PD T 2 / 10119 PRINT 7 , DN , P P , Z , DPDD, DDDT, DPDT, D2PDT2120 CONTINUE130 CONTINUE999 RETURN $ END

41)


SUBS P'JT INF TARLTOC TABULATF UYPROGFN SULFIDE SATO, LICUID FUNCTIONS.

C0 MM 0N/l/4L» a E»F.A, r'F, F P , E T » DCRT,TCPT,oCRT, DGAT,DTR 0 »TTPP, p TRP

CnNHON/B/C D PT,C?PDT?,OPSDT,DP M OT,DP[)0»DPDK,DTSDF,DTHDR»DDSDTCn us10N/6/ TSAT, THFTA, DSATCDÔN / a / IN, IK, p , T, PEN , £ , H , S , CV, CD, CSAT, W,WKCrtMMON/12 / Z C R T , ZCALC ,OZDT , Z S A T, D Z SO T, 7 F X , F ft T , D FP TDTCQ"N0N/1Q/ DNG,EG,HG,SG, CVG,C D G,WG, DP&DT,0PGD0C OR M on / 99 / T I , E Z 7 , FX.SZ,CVZ, HZ,CP7DIMENSION DSa(6'‘'),TSA(6D)» d SA(60)»DLT(60),DPT(6O),DPD(6C)DATA (C«O.De3145),(UR«36.08)

A FOPM AT( lHH3y*PPOPEPTIES OF SATURATE^ LIOUIO HYDROGEN SULFIDE*//1 1 A X l H T 11 y I H D 3X5HDEN, L 7X5HDFN»G 3X5HZ.LIQ 3 X *5 H Z , G A S

2 *X*>HOPS/DT 3 X 6 HOD |_ / Q T 3X5HDP/DT 6X5H0P/D0 /

3 1AX UK 9 * 3 H N p A 3 Y 5 H M OL / L 7X5HMDL/L 16XA 6X5HNPA/K 2X7HMOL/L/K 3X5HNPA/K 2X9H* p A-L/MOL )

5 FOPM AT( 5XF1(,,3, F12.5, FR.2, F12.5, 2F3.5, F 1 1 . A , F 9 . 5 , F P . A , F H . A )

U pn? s.4 t ( 1 *-'l 1 3 y*d?D°EP T I E S OF SATURATED LIQUID HYDROGEN SULFIDE*//1 14X l w T AXFHO,VAP R X 1 HF R X 1 FH 3 X 1 H S

2 0X7HCV A x 2 S A X 2 R C P 6XRHF/P 6X1HK /

3 1 A x 1«< AX C HJ/MHL AX 5 MJ/MHL 4X5HJ/N0L 2X7MJ/-0L/KA 1X7HJ/ M PL / R 1X7MJXYHL/K lY7>3j/MrL/K m 5H*/SEC )

12 FORMAT ( 5 X F 1 C « 3 » 3F9.1, F9.3» 3FB.2, F9.5, 17)f COP PAGE QNF of TARLIO.C INSERT BOILING POINT AT J = 7.

100 no s AO I PRINT p, « DO 15 0 J * 1 , N o « T=1P0+5*JID? IF(J.EO.l) T - TTRo t I F ( J

.

c 0 . 7 ) 106,10*10* T * FJNDTSF (1 .01323)IDA I F ( J , f T , -7 ) T = T - 5.0125 IF(J.EO.NR) 126*13°1 ? 5 T « TCRT * ns A ( J ) »0G*DL “OCR T J OLTfJ) DOLDT • 0

1 o 7 VG = VL = 1 . 0 / o C R T t ZG = ZCRT $ GO T° 1A1139 D S A ( J ) = Dl = OCNLIDF(T) % DLT(J) = D C L 0 T = ODSOT140 0 0 * OFNGASF(T) i 7 G 7CAT <1 VG * 1/DG $ VL • 1/DL

1 A 1 T S A ( J ) * T $ PX « D VTF(T,DL,1) « 0PT(J)*O°DT $ DPD(J)-DDDD1AP PSA(J) = PS » PSAT % x x PS/DL/G/T143 DC=PS/10 ? DPS0T*0°S0T/lO < OROT-OPOT/ID t D=0D=DDDD/10

150 print 5, T , P S * DLfOG, 7,ZG, DP SDT ,DDL0T , DP0T,0PDD

C PAGE 2* TARLIO. AVOID COEXIST, TTMFSaVER.C GET FUG AC TTY GOFF., (F/P), VIA w7, S7* MG, SC-.

160 PRINT 11 T DC 180 J * 1 ,

N

3 S TxTSA(J) f DL*DSA(J) 1 DSxOSA(J)

161 DDLDT*DLT( J ) f DYOVAPXF(T) T S-SÂTF (T) ? H«HSATF(T)

157 F * h - 100*0$/°! i I F ( J , E 0 , N p ) 16 3, 1 6 A

163 CV = C S A T = CP = IW * 0 t G,n TC l^C

154 dx x 3VTF(T,0L,1) ? CSAT x CSATXF(T)

165 CV • CSAT + 10 0* T* D° DT* DDL DT / D L / 0L

166 C® * GV 100+T/0P0D* ( DPDT/OL ) **? $ I W = S OR T ( WK * C P* D D / C V

)

lÔ TI * T S CALL IDEAL * GI9 = H - EZZ - HZ - T*(S-S?)

171 GJ - 100*G * FOP » l.C1325/PS*EXP(GIP/GJ/T)

130 p p I N T 12, T , 0 X , E,h,S, CV,CSAT,C p , FD°» IW

999 RETURNEND

41


FUNCTION THPTAF (OEM

)

TMETA - TSAT*EX P (U(S' ) .

LET 0 * ( S-l ) / (ST-1 ) . WHERE ST - DTRP/OCRT, THEN -

IF S < 1. U = AL*0**3» TF S > 1, U * -AL*0**3>CO“"ON/l/AL,RF,r, a,DF,e d ,ET, OCR T» TC R T» D C R T, 0 G A T , D TR P , T TR p , P TR R

C1M M ON/3/DPDT,n.3 p DT2,UDSUT,DPMDT,DPDO,DPDR, DTSDR, DTHDR.DDSDTCOMMON /6/ TSAT, tmpTA, PS AT

1 S * DEN/OCRT 4 osne * OTRP/DCRT 4 C * DSDR-12 0 - (S-l )

/

r $ 02 » 0*C 4 U - A L *0* 02

3 L'l « AL*3*02*DSDR /C 4 IF(O) 5 » 9 , A

A U « -U 4 U1 « -Ml5 X P = f X P ( U ) 4 THETAP * T S A T * X P

6 nTHQP * (TSAT+U1 0T4nR)*YP I RETIREq THE T AF » TCPT 4 OTHOP - 0 4 PETIJRN

F N n

FUNCTION TSATF(OEN)ITFPATE T TO minimise (OFN-DCALC) VIA OENCASF (T) « DENLIOF(T).IF TTFRATION f 4 j l E » PRINTOUT ONCE ON L y AND STOP AT K * 2.

C n«MnN/i/4L,PE»GA,0E»EP#ET, DCRT.TCRT.pCRT, DGAT,DTRP,TTRP,PTRRComm ON /3/UPDT,D’RUT?,D d S0T,DPMDT,DpDU,DddR, DTSDR, DTHDR,DDSDTDATA (0*2.0), (fn*6.’«R0561)

NOTE, FN » EXP (0) - l.C.1 FORMAT ( ] H 1 1 A X *TSATF(DFN) FAILS AT DEN * * F L 5 . 7 / /

1 15X EMOCALC 13 X? HDD 1 0 X 5 HDD S 0 T 13X2 HU T 12X3HT,W )

2 fiopmat ( 5 X f El c .7)

3 * » 0 4 D * DENAS* 0 / DC P T 4 YN = TCRT/TTPP-1 4 IF(O-DCRT) 5,30,65 ?T»DGA T/nCRT 4 F * A L n G ( S) / ALOG( 5 T ) * ( ( 1 — S ) / ( 1 — S T ) )**

2

4 SO TO 7

6 ST-DTPP/DCPT 4 U * ( (S - 1 ) ( S T- 1 ) ) * * 3 4 F • ( E X P ( 0 * U ) -1 ) / F

N

7 T * TCPT/ ( vnmF+i

)

B

q

10li

17

131 A

15

16IB

70717530

no 20 J = I , 5 C 4 IF(D-DCRT) 0,30,10DC * DENGASF(T) 4 GO TO 11DC * OENL IOF ( T

)

DO = 0 - DC 4 IF(APS(DD/D) .LT.l.CF-7) 25,1’

DT = DD/DDSOT 4 I F ( A R S < D T / T ) . L T . 1 . 0 E -7 ) 26,13T - T + DT 4 IF ( T ) 1 A , 1 A , 1 5

T « TTRP « GO TO IBIF ( T.LT.TCRT) IB, 16T « TCPT - 0 . 0 0 0 n

2

IF(K.EO.l) PRINT 2, DC. D n , DDSOT, DT, T

CONTINUE 4 K = K+l 4 IF(K.NE.l) STOP4 CO TO A

DTSDR - DTPP/DDSDT 4 RETURNPRINT 1 , DENTSATF T 4

T S AT F

FNDTCRT DTSDR 4 RETURN


FUNCTION XCF(T.O)C X C F « ( X**BF ) *E XP

{

A*( 1-TS /T ) )- XS**RF. WHEPE -

C X # T/TC. XS * T S / T C > A # (1-BE) SOOT(l-PE).xcp = u*fxp(a*V) - us. u n x**b> us n xs**b, v # ( 1 -ts/t).CnMM-iM/i/AL, t'E»GA,OF»F t> »ET. DCRT.TCRT.pCPT, QGAT.DTPP.TTPP.PTRPC0*H0s,/3/dPDT,Q2PQT2.0PFDT,DPMDT,DPQD,QPDR,DTSDP,QTHDP»1DSDTCDMmon/^/xPI, XR 2, XC1.XC2. XE1.XE?. 0 X B DP , D X C 0 P , 0 X E DPCOMMnn/6/ TSAT, TH F T A » °SAT

1 B x BE X PN - 1-3 X A • BN SO=T ( BN

)

2 TC » T C R T « T S = TSAT X X * T / TC $ X S * TS/TC 1 XS1«DTSDP/TC3 U = X7*B l U1 = 3*U/X $ U2 S -RNWiJl /X

9 US * x S **B $ US1 « B*US+XX1/XX5 V X 1-TS/T X VIP . -OTCOR/T X V1X - TS /T/X X V2 x -2* V 1 X / *

6 P X F X P ( A * V )x 3 1 x A*P X P 2 - A * P 1

7 PI R = PI *V1

R

$ pi x = pi+vi x $ P 2 X = p 1 * v? X •f P2*V1 X* V1X3 xc F * U* D - US X 0 XC PR x U * p 1

P

- MSI * xci x U*P1X U1*P9 XC 2 x IJ+D2X + 2*'J1*P 1 X + U2* p X RETUPN

E NH

FUNCTION XFF(T,n)C ULTRA REVISION, "APCH 29, 1 9 B 1 ,

C X E p * H(P,T)/HMP) - 1.0. W # (1-TH/T), WE « W**E»

C H(P.T) # 1.0 - ( W-WF/F ) / { 1-1/ E ) > E * ET.COMMON /i/al, 3 f,ga,oe»e d .ft, dcrt.tcpt.pcpt, ogat.dtpp.ttrp.ptrpCOW“ON/3/C)PDT»D2 D DT2>'' :> P r)T»OPÔT»DP ri D.OPnP»r)TSDP»DTMPP.OOSOTCQmôn/ 9/ XF1.XR2. XC1.XC2. XE1.XE2* OXBDP.OXCDP.OXE OR

Cn^^HN/6/ TEAT. THETA, dSST

1 E = FT x F K = E / (E - 1 ) i TC « TCPT

2 TS = TSAT « TH * THETA t X « T/TC

3 W - 1.0 - TH/T X I F ( W ) 3 C » 3 0 > E

S W1P * -OTHQ P / T X W1X * TH/T/X X W 2 X * -2*Wlx/X*, WE = W * * F $ WET x F*Wt/w T W E 1 R = WEI * Wl R

7 uE 1 v * WF1 * Wl x x w E 2 X x WE 1 * W2 x ( E-i ) * WF 1 * wl X* Wl * / W

3

u « i - fw*(w-je/E) t HIP -E K * ( Wl R-W E 1 P / E

)

9

wi x « -EK*( W1X-WE1 X/F ) % u 2 X * -FR*( W2X-WE2X/E

)

10 wS = 1.0 - TH/TS X IF(WS) 11.11.12

11 HS * 1 I HS1 =0 % GO TO 16

1? vSl • (Th+DTSDP/TS - DTHDP)/TS13 WS c = wS**F 1 WSE1 = F*WSE*WS1/WS14 MB * 1 - EK + ( WS-WS C /F ) X MSI * - E K * ( W S 1 - W S E 1 / E )

16 U 1.0/hS x U1 • -U*HS1/HS20 ycc , H*U - 1.0 1 OXEDR - H + U 1 N1R*U

21 X F 1 X U*H1X X XE? = U*H2X $ PFTJPN

30 X E F x X F 1 * XF2 * OXEDR 0 X RETURN

END

43

Appendix U Ideal Gas Functions by Haar, et al

Table 3. Ideal gas thermodynamic functions for H 2S

°K c;

R(H°-Eo )

RT~(F°-Ei

)

RT

—s°

~R

50 4.00286 2 3. 95091 866 13. 59988 72115 17. 55080 72981

60 4. 00288 13 3. 95957 619 14.32103 61086 18. 28061 61705

70 4. 00301 20 3. 96576 467 14.93189 52988 18. 89766 53454

80 4.00321 24 3. 97043 366 15. 46177 46787 19. 43220 47153

90 4.00345 28 3. 97409 295 15.92964 41887 19. 90373 42182

100 4. 00373 31 3. 97704 244 16. 34851 37917 20. 32555 38161

no 4.00404 39 3.97948 206 16. 72768 34635 20. 70716 34841

120 4.00443 51 3. 981.54 178 17. 07403 31876 21.05557 32055130 4. 00494 72 3.98332 157 17.39279 29526 21.37612 29682

140 4.00566 103 3. 98489 141 17. 68805 27498 21.67294 27640

150 4.00669 148 3. 98630 132 17. 96303 25731 21. 94934 25863

160 4.00817 204 3. 98762 127 18.22034 24179 22. 20797 24305

170 4.01021 272 3.98889 125 18. 46213 22803 22. 45102 22929180 4.01293 353 3.99014 129 18. 69016 21577 22. 68031 21706

190 4.01646 443 3. 99143 136 18. 90593 20477 22. 89737 20612

200 4. 02089 540 3. 99279 146 19. 11070 19484 23. 10349 19631

210 4. 02629 640 3. 99425 160 19.30554 18585 23.29980 18745

220 4. 03269 743 3. 99585 176 19. 49139 17766 23. 48725 17942

230 4.04012 844 3. 99761 194 19. 66905 17018 23. 66667 17212

240 4.04856 944 3. 99955 215 19. 83923 16331 23. 83879 16546

250 4. 05800 1040 4.00170 236 20. 00254 15700 24. 00425 15936260 4. 06840 1130 4. 00406 259 20. 15954 15116 24. 16361 15375

270 4. 07970 1215 4.00605 283 20.31070 14576 24.31736 14858

280 4. 09185 1293 4. 00948 306 20. 4.5646 14075 24. 46594 14382290 4. 10478 1366 4. 01254 330 20. 59721 13609 24. 60976 13938

300 4. 11844 1432 4.01584 354 20. 73330 13174 24. 74914 13528310 4. 13276 1491 4. 01938 377 20. 86.504 12767 24. 88442 13144320 4. 14767 1546 4. 02315 401 20. 99271 12386 25. 01586 12787330 4. 16313 1595 4. 02716 423 21. 11657 12028 25. 14373 12452340 4. 17908 1640 4.03139 445 21.23685 11692 25. 26825 12137

350 4, 19548 1680 4. 03584 467 21. 35377 11376 25. 38962 11843360 4. 21228 1717 4. 04051 487 21. 46753 11077 25. 50805 11564370 4. 22945 1752 4. 04538 508 21.57830 10795 25. 62369 11303380 4. 24697 1782 4. 05046 526 21.68625 10529 25. 73672 11054390 4. 26479 1811 4. 05572 646 21. 79154 10275 25. 84726 10821

400 4.28290 9429 4.06118 2982 21. 89429 48002 25. 95547 50984450 4. 37719 9955 4. 09100 3355 22. 37431 43273 26. 46531 46629500 4. 47674 10382 4. 12455 3671 22. 80704 39481 26. 93160 43152650 4.58056 10705 4, 16126 3939 23. 20185 36375 27.36312 40313600 4.68761 10909 4. 20065 4164 23. 56560 33786 27. 76625 37951

650 4. 79670 10981 4.24229 4352 23. 90346 31597 28. 14576 35949700 4. 90651 10923 4.28581 4503 24. 21943 29722 28. 50525 34225750 5. 01574 10751 4. 33084 4618 24. 51665 28098 28. 84750 32715800 5. 12325 10481 4. 37702 4699 24. 79763 26676 29. 17465 31376850 5.22806 10139 4. 42401 4751 25. 06439 25421 29. 48841 30171

900 5. 32945 9744 4. 47152 4773 25. 31860 24304 29. 79012 29078950 5. 42689 9314 4.51925 4773 25. 56164 23303 30. 08090 280751000 5. 52003 8866 4. 56698 4751 25. 79467 22397 30. 36165 271491050 5. 60869 8410 4. 61449 4712 26.01864 21576 30. 63314 262871100 5. 69279 7960 4.66161 4658 26. 23440 20824 30. 89601 25483

1150 5. 77239 7518 4. 70819 4593 26. 44264 20136 31. 15084 24728

1200 5. 84757 13774 4. 75412 8951 26. 64400 38408 31.39812 473601300 5. 9853

1

12224 4. 84363 8600 27. 02808 36213 31.87172 448121400 6. 10755 10843 4. 92963 8222 27. 39021 34293 32. 31984 425151500 6.21598 9632 5.01185 7832 27. 73314 32598 32. 74499 404311600 6. 31230 8576 5.09017 7446 28. 05912 31084 33. 14930 38530

1700 6. 39806 7661 5. 16463 7069 28. 36996 29723 33. 53460 367921800 6 47467 6869 5. 23.532 6707 28. 66719 28487 33. 90252 3519419(H) 6. 54331. 6182 5. 30239 6362 28. 95206 27361 34. 25446 3372320(H) 6.60518 5588 5. 36601 6036 29. 22567 26328 34. 59169 323642100 6. 66106 5070 5. 42637 5730 29. 48895 25377 34.91533 31106

2200 6.71176 4621 5. 48367 5441 29. 74272 24497 35. 22639 299392300 6. 75797 4227 5. 53808 5172 29. 98769 23680 35. 52578 2885224(H) 6. 80024 3882 5. 58980 4921 30. 22449 22919 35.81430 278402500 6. 83906 3.580 5. 63901 4685 30. 45368 22209 36. 09270 268942000 6. 87486 3312 5. 68586 4466 30. 67577 21543 36. 36164 26008

2700 6. 90798 3070 5. 73052 4261 30. 89120 20918 36. 62172 251792800 6. 93874 2866 5. 77313 4069 31. 10038 20330 36. 87351 244(H)29(H) 6. 96740 2678 5 81382 3891 31

. 30368 19776 37. 11751 236663000 6.99418 4872 5. 85273 7289 31.50144 38009 37. 35417 45298

3200 7.04290 4331 5. 92562 6702 31.881.53 36128 37.80715 42830|

3400 7.08621 3887 5. 99264 6185 32. 24281 34430 38. 23545 40616 i

3600 7. 12508 3520 6. 05449 5729 32. 58711 32890 38. 64161 38619|

38(H) 7. 16028 3213 6. 11178 5324 32. 91601 31487 39. 02780 368104000 7. 19241 2954 6. 16502 4964 33. 23088 30201 39. 39590 35165

4200 7. 22195 2731 6. 21466 4641 33. 53289 29018 39. 74755 336604400 7. 24926 2538 6. 26107 4352 33. 82307 27929 40. 08415 322814600 7. 27464 2370 6. 30459 4092 34. 10236 26920 40. 40696 310114800 7. 20834 2222 6. 34551 3856 34. 37156 25982 40. 71707 298395000 7. 320.56 6.38407 34.63138 41.01546

Table 4. Ideal gas thermodynamic functions for HDS

°K ClR

(H°-Ei )

RT-(F°-Eh )

RT ~R

50 4.00238 14 3.96864 563 14.84410 72410 18.81274 7297460 4. 00252 22 3. 97427 405 15. 56820 61295 19. 54248

|

6170070 4. 00274 26 3. 97832 307 16. 18115 53145 20. 15948 5345180 4.00300 29 3.98139 242 16.71260 46908 20. 69399

;

4715090 4.00329 35 3.98381 196 17. 18168 41984 21. 16549 42181

100 4.00364 46 3. 98577 165 17.60152 37997 21. 58730 38161110 4. 00410 66 3. 98742 141 17.98149 34701 21.96891 34843120 4. 00476 101 3. 98883 126 18. 32850 31933 22.31734 32059130 4. 00577 154 3.99009 118 18. 64783 29574 22. 63793 29691140 4.00731 224 3. 99127 114 18. 94357 27541 22. 93484 27655

150 4. 00955 314 3. 99241 116 19.21898 25770 23.21139 25886160 4.01269 419 3. 99357 124 19. 47668 24214 23. 47025 24339170 4.01688 537 3. 99481 137 19. 71882 22838 23. 71364 22975180 4. 02225 664 3.99618 154 19. 94720 21610 23. 94339 21764190 4.02889 797 3. 99772 175 20. 16330 20510 24. 16103 20685

200 4. 03686 930 3.99947 200 20. 36840 19519 24. 36788 19718210 4. 04616 1063 4.00147 227 20. 56359 18620 24. 56506 18847220 4. 05679 1190 4.00374 256 20. 74979 17802 24. 75353 18059230 4. 06869 1313 4.00630 287 20. 92781 17057 24. 93412 17343240 4.08182 1428 4.00917 319 21. 09838 16373 25. 10755 16692

250 4. 09610 1535 4. 01236 351 21. 26211 15743 25. 27447 16095260 4. 11145 1634 4. 01587 384 21.41954 15163 25. 43542 15547270 4. 12779 1726 4.01971 417 21.57117 14627 25. 59089 15043280 4. 14505 1808 4. 02388 448 21. 7K44 14128 25. 74132 14576290 4. 16313 1884 4.02836 481 21.8.5872 13664 25. 88708 14146

300 4. 18197 1953 4.03317 511 21.99536 13233 26. 02854 13744310 4. 20150 '2015 4.03828 541 22. 12769 12830 26. 16598 13371320 4. 22165 2072 4. 04369 571 22. 25599 12452 26. 29969 13022330 4. 24237 2123 4. 04940 599 22. 38051 12097 26. 42991 12696340 4. 26360 2170 4. 05539 625 22. 50148 11765 26. 55687 12391

3.50 4. 28530 2212 4.06164 652 22.61913 11451 26. 68078 12103360 4. 30742 2250 4.06816 677 22. 73364 11155 26.80181 11832370 4.32992 2286 4. 07493 701 22. 84519 10877 26.92013 11578380 4. 35278 2316 4.08194 724 22. 95396 10612 27.03591 11336390 4. 37594 2345 4. 08918 747 23.06008 10362 27. 14927 11108

400 4. : 9939 12066 4.09665 4029 23. 16370 48480 27. 26035 52510450 4. 52005 12430 4. 13694 4451 23. 64850 43814 27. 78545 48264500 4. 64435 12565 4. 18145 4779 24. 08664 40075 28. 26809 44855550 4. 77(HH) 12499 4. 22924 5028 24. 48739 37014 28. 71664 42041600 4.89499 12267 4. 27952 5208 24. 85753 34459 29. 13705 39668

650 5.01766 11902 4.33160 5328 25. 20212 32295 29. 52373 37623700 5. 13668 11438 4. 38488 5396 25. 52507 30436 29. 90996 35832750 5. 25106 10904 4. 43884 5420 25. 82943 28821 3(1. 26828 34241800 5 36010 1033(1 4. 49304 5407 26. 11764 27401 30. 61069 32808850 5. 46340 9736 4. 54711 5364 26. 39165 26143 30. 93877 31506

900 5. 56076 9142 4. 60075 5296 26. 65308 25017 31. 25383 30314950 5. 65218 8557 4. 65371 ^09 26. 90325 24004 31. 55697 292121000 5. 73775 7993 4. 70580 5106 27. 14329 23083 31.84909 2819010.50 5.81768 7455 4. 75686 4993 27. 37412 22245 32. 13099 2723811(H) 5. 89223 6945 4.80679 4873 27. 59657 21475 32. 40337 26347

1150 5. 96168 6467 4. 85552 4745 27.81132 20765 32. 66684 25511

1200 6. 02635 11624 4.90297 9099 28. 01897 3960S 32. 92195 487061300 6. 14259 10082 4, 99396 8573 28. 41.50.5 37326 33. 40901 459(H)

1400 6. 24341 8761 5. 07969 8057 2S. 78831 35324 33. 86801 4338115(H) 6. 33102 7636 5. 16026 7561 29. 14155 33548 34. 30182 411081600 6. 40738 6680 5. 23587 7092 29. 47703 31957 34. 71290 39050

17(H) 6. 47418 5864 5. 30679 6652 29. 79660 30523 35. 10340 371751800 6. .53282 5168 5. 37331 6242 30. 10183 29221 35. 47515 354621900 6. 58450 4572 5. 43573 5860 30. 39404 28033 35. 82977 338932000 6. 63022 4059 5, 49433 5508 30. 67437 2694

1

36. 16870 3244921(H) 6. 67081 3617 5. 54941 5181 30. 94378 25937 36. 49319 31118

2200 6. 70698 3233 5. 60122 4879 31. 20315 25007 36. 80437 298802300 6. 73931 2898 5. 65001 4600 31.45322 24144 37. 10323 287452400 6. 76829 2605 5. 69(H) 1 4342 31. 694(H) 23341 37. 39(H;s 2768325(H) 6. 79434 2346 5. 73943 4103 3 1 . 92807 22592 37. 66751 2609526(H) 6.81780 2119 5. 78046 3882 32. 15399 21889 37. 93446 25771

2700 6. 83899 1916 5.81928 3677 32. 37288 21230 38. 19217 249072H(H) 6. 85815 1735 5. 85605 3486 32. .58.518 20611 38. 44124 2409729(H) 6. 87550 1573 5. 89091 3308 32. 79129 20028 38. 68221 233303000 6:89123 2720 5. 92399 6133 32. 991^7 38431 38. 91557 44564

3200 6. 91843 2236 5. 98532 5557 33. 37.588 36456 39. 36121 4201234(H) 6. 94079 1830 6. 04089 .5052 33. 74044 34674 39. 78133 3972636(H) 6. 95909 1483 6.09141 4607 34.08718 33060 40. 17859 3766738(H) 6. 97392 1180 6. 13748 4213 34. 41778 31589 40. 05526 358034000 6. 98572 913 6. 17961 3862 34. 73367 30246 40, 91329 34107

42(H) 6. 99485 673 6. 21823 3546 35. 03613 29010 41. 25436 3255644(H) 7. (H)l 58 454 6. 25369 3262 35. 32623 27872 4 1 . 57992 3113446(H) 1 7. 00612 250 6. 28631 3005 35. 60495 26818 41.89126 2982448(H) 7. 00862 60 6. 31636 2771 35.87313 25842 42 18950 286135(HHI 7. 00922 6. 34407 36. 13155 42. 47563

44

Hydrogen

Sulfide

45

200

300

400

500

ooCO

oom

oo

ooCO

*

edW ‘d

46

Figure

2.

P-T

lucus

of

P-p-T

data

of

Reamer

and

of

Lewis.

Hydrogen

Sulfide

oo00

edlfl ‘d

47

lyure

oCM"S’

oo"3-

oCDCO

oCO

CD CM 00^ CO CO

»/ioiu/r ‘(i)Ao

OCO

48

Figure

4.

Specific

neats,

Cv(Tjat

2U.S4

r.iol/L.

Table 1 Comparisons of vapor pressure data for H 2S

hydrogen sulfide vapor pressure# MPA# epp 1.700

(l)REAMER# (2)GIAU0UE# (8)I.C.T.# (15)WEST# (2DCARD0S0(32KLEMENC, ( 70 ) C L ARKE

TTRO - 187.660# TBLP - 212.874# TC R T • 373.400PTRo . ,02320# PC PT 8.96291# DPS/DTC « . 15238

A -8.023473844, 3 - 16.'731062287# c — io .:325650140D • 9.690908499# E - -3.!577167041, f - 3.:174310817

ID WT T# K T/TC P# MPA CALCO PC N T DPS /DT P ESID2 1.00 187.660 .50257 .02318 .02320 -.07 .00156 -.000122 1.00 188.400 .50455 .02438 .02438 .01 .00163 .000462 1.00 19 C . 556 .51033 .02810 .02810 -.01 .00163 .00163

70 1.00 193.150 .51727 .03318 .03319 -.03 .00210 .002932 1.00 193.890 . 51926 .03478 .03477 .02 .00218 .003362 1 . 00 197.030 .52766 .04219 .04217 .04 .00255 .00479

70 1.00 198.150 .53066 .04509 .04510 -.01 .00269 .005152 1.00 199.959 .53551 .05022 .05018 .09 .00293 .00601

70 1.00 203.150 . 54405 .06025 . 06 C 26 -.01 .00339 .006942 . 20 203.450 .54486 .06140 .06128 .20 .00344 .007382 .20 206.625 .55336 .07319 .07301 .23 .00396 .00635

70 1.00 203.150 .55745 .07925 .07925 -.00 .00423 ,00e342 .20 210.226 .56300 .08866 .08842 .27 .00461 .00929

70 1.00 212.875 .57010 .10133 .10133 -.00 .00514 .0093670 1.00 212.074 .57036 .10103 .10184 -.01 .00516 .0093870 1.00 213.150 .57084 .10274 .10275 -.01 .00520 .009412 .20 213. 216 .57101 .10339 .10309 .26 .005?1 .00991

70 1.00 218.150 .58423 .13144 .13145 -.01 .00631 .0101970 1.00 223.150 .59762 .16608 . 16610 -.01 .00758 .0107270 1.00 228.150 .61101 .20747 .20751 -.02 .00901 .0110270 1.00 233.150 .62440 .25645 .25650 -.02 .01062 .0111470 1.00 238.150 .63779 .313*9 .31395 -.02 .01240 .oiiio70 1.00 243.150 .65118 .38070 .3e07B -.02 .01436 .0109270 1.00 243.150 .66457 .45761 .45790 -.02 .01652 .0106270 1.00 253.150 .67796 .54617 .54629 -.02 .01897 . 01C2270 1.00 258.150 .69135 .64680 .64692 -.02 .02142 .0097470 l .00 263.150 .70474 .76067 .76079 -.02 .02417 .0092070 1.00 268.150 .71813 .88862 .8 e 892 -.01 .02712 •00 P 61

21 1.00 273.150 .73152 1.03352 1.03235 .11 .03029 . 0081770 1.00 273.150 .73152 1.03230 1.03235 -.01 .03029 .0079770 1.00 279.150 .74491 1.19219 1.19213 .01 .03366 .0073270 1.00 283.150 .75030 1.36941 1.36930 .01 .03725 .0066470 1.00 288.150 .77169 1.56527 1.56496 .02 .04105 .00596

1 . 20 293.150 .78508 1.77471 1.78018 -.31 .04507 .00471

70 1.00 293.150 .78508 1.78069 1.78018 .03 .04507 .0052770 1.00 298.150 .79847 2.01667 2.01607 .03 .04932 .00459

70 1.00 303.150 .81186 2.27495 2.27374 .05 .05379 .00395

70 1.00 308.150 .82525 2.55592 2.55435 .06 .05849 .00330

1 1.00 310.928 .83269 2.71653 2.72059 -.15 .06120 .002.60

1 1.00 311.539 .83433 2.75790 2.75817 -.01 .06181 .00275

1 1.00 313.150 .83864 2.85443 2.85905 -.16 .06343 .00230

70 1.00 313.150 .83864 2.86111 2.85905 .07 .06343 .00269

70 1.00 318.150 .85204 3.19174 3 .18904 .08 .06861 .00212

70 1.00 323.150 .86543 3.54881 3.54556 .09 .07404 .00157

49

Table 1 Continued

HYDROGEN SULFIDE VAPOR PRESSURE* MPA, EPP • 1.700

ID WT T , K T/TC P , MPA C ALCD PC NT DPS /DT RESID1 1.00 333.150 .89221 6.33562 6.36361 -.18 .08571 .000161 . 20 338.761 .90723 6.82633 6. 866 C 0 -.36 .09278 -.000611 1,00 366.261 .92196 5.37033 5.37626 -.07 .10011 -.000671 . 20 36 5 .

A

2 8 .92509 5.51581 5.69203 .63 .10173 .000311 1.00 352.030 .96279 6.20528 6.19573 .15 .11129 -.000621 1.00 353.150 .96577 6.32180 6.32030 .02 .11297 -.000671 1.00 358.096 .95901 6.89676 6.89796 -.05 .12080 -.000851 1.00 360.928 .96660 7.26915 7.26701 .03 .12557 -.000711 1 . 00 3^3.539 .97359 7.58623 7.58087 .06 .13020 -.

0

CC 631 1.00 368.706 .98763 8.27371 8.27896 -.06 .16026 -.00057

32 0.00 188.200 .50602 .02616 . 02606 .62 .00161 .0010332 0.00 193.200 .51761 .03393 .03329 1.91 .00210 .0061832 0. 00 198 . 200 .53080 .06666 .06523 3.16 .00269 .0106132 0.00 203.200 .56619 .06229 . C 6 0 6 3 3.08 .00360 .0120632 0.00 208.200 .5575° .08158 .07967 2.66 .00626 .0127732 0.00 210.200 . 56296 .09069 . 088’0 2.67 .00661 .0129232 0.00 213.200 .57097 .10510 .10301 2.03 .00521 .012801 0.00 277.596 .76362 1.16521 1.17352 -.71 .03327 .00620

15 0.00 277.596 .76362 1.15832 1.17352 -1.30 .03327 .005201 0.00 282.706 . 75711 1.37895 1. 35286 1.93 .03692 .00990

21 0.00 287.950 .77116 1.51177 1.55676 -2.89 .06089 .001031 0.00 298.150 .79867 2.06863 2.01607 2.60 .06932 .00 e 86

2 1 0.00 301.000 .80611 2.11161 2.16020 -2 .25 .05186 .0003321 0.00 309.800 .82967 2.60709 2.65218 -1.70 .06009 .0001115 0.00 310.928 .83269 2.73722 2.72059 .61 .06120 .0038721 0.00 319. 35 C .85525 3.22315 3.27216 -1.50 .06989 -.00069

1 0.00 323.150 .86563 3.66738 3.56556 -2.77 .07606 -.0033021 0.00 329.350 .88203 3.97599 6.02663 -1.25 .08115 -.001321 0. 00 331.683 .88776 6 , 1 3685 6.20222 -1.56 .0 P 369 -.00206

21 0.00 333.250 .89267 6.32962 6.35199 -.51 .0 e 586 -.0006221 0.00 337 . 800 .90666 6.71366 6.75563 -.88 .09156 -.001611 5 0.00 366.261 .92196 5.69512 5.37626 2.25 .10011 .0033921 0. 00 351.600 .96108 6.05216 6.12692 -1.19 .11033 -.0026721 0.00 358.750 .96077 6.96360 6.97756 -.68 .12189 -.0015921 0. 00 360.900 .96652 7.19610 7.26350 -.65 .12552 -.001 8615 0.00 360.928 .96660 7.62565 7.26701 2.66 .12557 .0033321 0.00 363.650 .97335 7.52561 7.56928 -.58 .13003 -.0016921 0.00 363.650 .97399 7.56087 7.59533 -.65 .13060 -.001672 1 0. CO 369.700 .99009 8.60592 8.61962 -.16 .16261 -.0006621 0.00 370.000 .99089 8.50117 8. 66226 .66 .16307 . 00060

NP - 56, RMS PC T - .081

50

Table 2 Compari sons of saturated liquid density data for H 2 S.

HYDCOGEN SULFIDE SATLIQUID DENSITIES# EL .350

(l)REAMER, (8)1. C.T,# (32)KLENENC# (34)BA*TER# (70JCLARKETTPo 187.660# TBL P * 212.074, TC R T « 373.400DTRP « 2 9.136, D L B 0 - 27.845, DC R T - 10.20

1.90639527 .83560589 -.57091447 .72347653

10 WT T»K T/TC KG/M3 MOL /L C ALCD PCNT DDS/DT3 2 1.00 190.050 .50897 988.8 29.014 29.015 -.00 -.050732 1.00 192.050 .51433 995.4 28.914 28.913 .00 -.050832 1.00 194.050 .51968 981.5 28. 8C0 28.812 -.04 -.050932 1.00 196.050 .52504 978.4 20.709 20.710 -.00 -.051032 1.00 198.050 .53040 974 .

8

28.603 28.608 -.02 -.051032 1.00 200.050 . 53575 971.4 28.504 28. 506 -.01 -.051132 1.00 202 . C50 .54111 96 8.0 28.404 20.403 .00 -.051232 1.00 204.050 .54646 964 .4 28.296 23.301 -.01 -.051332 1.00 206.050 .55182 960.9 28.195 23.198 -.01 -.051532 1.00 206.050 .55718 957.4 28.093 28.095 -.01 -.051632 1.00 210.050 .56253 953.9 27.990 27.991 -.00 -.051732 1.00 212.050 .56769 950.4 27.857 27.888 -.00 -.05191 1.00 282.706 .75711 813.8 23.880 23 . 8e2 -.01 -.06451 1.00 298.150 . 79847 778.8 22.851 22.842 .04 -.07061 1 . 00 311 . 539 .83433 745.1 21.862 21 .850 .05 -.07791 1.00 323.150 .86543 711.6 20.879 20. 897 -.oe -.00681 0. 00 331.483 .88774 684.3 20.078 20.138 -.30 -.09561 0.00 338.761 .90723 657.8 19.302 19. 4C7 -.54 -.10591 0. 00 345.428 .92509 631.0 18.514 10.660 -.70 -.11911 0.00 352.039 .94279 600.9 17.632 17.814 -1.02 -.13P31 0. 00 358.094 .95901 568.7 16.688 16.897 -1.24 -.16701 0.00 363.539 .97359 532.6 15.628 15.872 -1.54 -.21551 0.00 368.706 .98743 484.0 14.201 14.510 -2.13 -.3359

70 1.00 193.150 .51727 983 .5 28.860 28.857 .01 -.050070 1 . 00 198.150 .53066 974 .8 28.604 28.603 .00 -.051070 1.00 203.150 . 54405 966.3 28.353 23. 347 .02 - • 0 s 1

3

70 1.00 208.150 .55745 957.3 23.090 28.090 .00 -.051670 1.00 212.875 .57010 949.0 27.847 27.845 .01 -.051970 1.00 212.974 .57036 949.0 27.047 27.840 .03 -.051970 1 . 00 213.150 .57084 948.5 27.832 27.831 .00 -.051970 1.00 218.150 .58423 939.9 27.579 27.570 .03 -.052470 1.00 223.150 .59762 930.9 27.315 27.307 .03 -.052e70 1.00 228.150 .61101 921.8 27.049 27.042 .03 -.053370 1.00 233.150 . 62440 912.7 26.781 26. 774 .03 -.0539

70 1 . 00 238.150 .63779 903.3 26.504 26.502 .01 -.054670 1.00 243.150 .65118 893.6 26.226 26.228 -.01 - .0 5

K 3

70 1.00 248.150 .66457 884.3 25.947 25.949 -.01 -.0561

70 1.00 253.150 .67796 874.5 25.661 25.667 -.02 -.0570

70 1.00 258.150 .69135 864.5 25.368 25.379 -.04 -.0580

70 1.00 263.150 .70474 854.6 25.075 25.087 -.05 -.0591

70 1.00 268.150 .71813 044.4 24.777 24.708 -.05 -.0603

70 1.00 273.150 .73152 034.1 24.474 24.484 -.04 -.0616

70 1.00 278.150 .74491 823.6 24.166 24.172 -.03 -.0630

70 1.00 283.150 .75830 812.8 23.849 23.853 -.02 -.0646

70 1.00 288.150 .77169 801.9 23.529 23.526 .01 -.0664

70 1.00 293.150 .78508 790.5 23.196 23.189 .03 -.0634

70 1.00 298.150 .79847 778.8 22.852 22.842 .05 -.0706

70 1.00 303.150 .81196 766.7 22.497 22.483 .06 -.0730

70 1.00 308.150 .82525 754.0 22.124 22.111 .06 -.0758

70 1 . 00 313.150 .83864 740.7 21.734 21.724 .05 -.0790

70 1.00 318.150 .85204 726.5 2 1 . 3 1 7 21.320 -.01 -.0026

70 1.00 323.150 .86543 711.5 20.«77 20.697 -.09 -.0060

HP » 45# RHSPCT • .033

51

Table 3. Comparisons of saturated vapor density data for H2 S.

HYDROGEN SULFIDE SATVAPQR DENSITIES# AG .70# BG 2.00

(l)REANER# (9IVIA 3 ( T ) » (10)VIA QVAP# (70JCLARKE# ( <5 5 ) V I A P.D.TTR° 187.660# T9 L 3 - 212.87*# TCRT « 373. *00DGAT .01*96. DG8P .058*3# DC R T - 10.20# ZCRT .28303

-.75257979* -.865*8120* 1.975*80377 2.172963661 -5 . 7660796*

3

ID VT T , K T/TC K G / M 3 HOL /L C ALCO PC N T DDS/DT F ( Z )

70 .*2 193. 150 .51727 .710 . 0208 * .02083 .02 .00122 . 332 *

70 .*6 198.150 .53066 . 9*3 .02767 .02766 .03 .00152 . 833370 .50 203.150 . 5**05 1.233 .03617 .03615 . 0 * .00188 .836 8

70 . 5 * 208.150 . 557*5 1.587 . 0*658 . 0*657 .02 .00229 . 82*170 .57 212.875 .57010 1.992 . 058*5 . 058*3 . 02 . 0027 * . 820270 .57 212 . 97 * .57036 2.001 .05872 .05871 .02 .00275 . 822 *

70 .57 213.150 . 5708 * 2.017 .05917 .05919 -.03 .00277 . 800 *

70 .61 218.150 . 58*23 2 . 53 * . 07*35 . 07*33 .02 .00330 . 320 1

70 .65 223.150 .59762 3 . 1*7 . 0923 * .09231 .03 .00390 .818670 .68 228.150 .61101 3 . 86e . 113*9 . 113*8 .01 . 00*58 .813570 .71 233.150 . 62**0 *.711 . 1382 * .13819 .03 .00532 , ei3770 . 7 * 238.150 .63779 5.689 .16695 .16685 . 06 .00615 . 81*070 .77 2 * 3.150 .65118 6.817 . 2000 * .19986 .09 .00707 .813770 .80 2 * 8.150 . 66*57 8.105 .23761 . 23765'’ .07 .00807 . 805 1

70 .82 253.150 .67796 9.570 .2 80 82 . 2P070 . 0 * .00917 .797070 . 8 * 258.150 .69135 11.233 .32960 . 329*8 . 0 * .01037 .79037 C .96 263.150 . 70 * 7 * 13.108 . 38*62 . 38*53 .02 .01167 .783070 .88 268.150 .71813 15.221 .**663 .** 6*1 .05 .01310 .778270 .90 273.150 .73152 17.585 .51600 .51570 .06 . 01 * 6 * .771570 .91 278.150 . 7**91 20.226 . 593*7 .59307 .07 .01633 . 76*770 .93 283.150 .75830 23.168 .67981 .67921 .09 .01816 . 753270 . 9 * 288.150 .77169 26. *39 .77580 . 77*89 .12 .02015 .751770 .95 293 .150 .78508 30.053 .881 83 .88097 .10 .02232 . 7*3570 .96 298.150 . 798*7 3*. 080 1.00000 . 998*0 .16 . 02*69 . 738 2

70 .97 303.150 .81186 38. *95 1.12956 1.12829 .11 .02731 . 729 8

70 .97 30E.150 .82525 * 3 . 36 * 1 . 272*3 1.27192 . 0 * .03020 .721670 .98 313.150 . 83 86 * * 8.707 1 .*2918 1 .*3081 -.11 . 033*2 .712570 0.00 319.150 . 8520 * 5*. 537 1.60026 1.60682 -.*1 .03706 .701970 0.00 323.150 . 865*3 60.668 1.78603 1 . 80229 -.90 . 0*123 .6 8969 .39 190. COC . 5088 * .589 . 01 728 .01727 .02 .00105 . 8 37 *

9 .*7 200.000 .53562 1 . 0*3 .03060 .03060 .01 .00165 . 822 5

9 .55 210.000 . 562*0 1.737 .05096 .05096 -.01 . 002*6 .. 30909 .62 220. CCO .58918

'

2 . 7*7 .08059 . oeo6 * -.05 .00352 .79709 .69 230.000 .61596 *.160 .12205 .12219 -.11 . 00 * 8 * .786 8

9 .75 2 * 0.000 . 6 * 27 * 6 * 07 * .17822 .17853 -.18 . 006*8 .77369 .81 250.000 .66952 8.602 .25239 . 2529 * -.22 . 008*6 . 77269 .85 2 * 0.000 .69630 11.873 . 3*839 . 3*909 -.20 . 0108 * . 76919 .89 270. CCO .72309 16 . 0*6 .*7083 .*7115 -.07 .01365 . 7 0 8 *

10 .38 lee. 750 . 505*9 . 5*5 .01599 .01600 -.08 .00099 .706310 .57 212.870 .57009 1.992 . 058 ** . 058*2 .03 . 0027 * . 325 1

95 .99 325.000 .87038 63.902 1.87506 1 .88012 -. 27 . 0*293 .701395 .99 330.000 .88377 71.650 2 . 102*0 2 . 1072e -.23 . 0*808 .700995 1 .00 335.000 .89716 80 . 38 * 2.35869 2.36267 -.17 . 05*27 . 702 *

95 1.00 3 * 0.000 .91055 90.322 2.65029 2 . 652 ** -.08 .06193 . 706395 1.00 3 * 5.000 . 9239 * 101.770 2.98621 2.98556 .02 .07176 .712895 1.00 350.000 .93733 115.187 3.37991 3.37571 .12 . 0 0 5 0 2 . 722 5

95 1.00 355.000 .95072 131 . 31 * 3.85312 3 . 8 * 5*5 .20 . 10*17 . 736 3

95 1 .00 360.000 . 96*11 151 .*90 *. **512 *.*3605 .20 . 13*79 . 756195 1.00 365.000 .97750 178.638 5 . 2*172 5.23790 .07 . 193*7 .785 8

95 1.00 370.000 .99089 222.319 6 . 523*3 6 . 5*170 -.28 . 370*7 . 339 9

N P - *8, RMSPCT • .123

52

Tao 1 e 4 Coefficients of equation of state for hydrogen sulfide

eonstate coeffs.* hydrogen sulfide

T TR p

PTR P

OGAT «

DTP R •

DPS /DTB

• 1 87660F D3 » TRIP «

.231991E-01. p 9 L P =

. 149574E-01 , DG9P «

.291360F+0P* DL 9 p -

* .51360E-02 mpa/K,

•212874E*03* TCRT «

.1C1325E+00, PORT =

.5«4329E-01> DC R T

.278450E+O2* DC R T -

OVAPP, RJ/MOL * 18.

.3734C0E+C3

.696291E+01 M 0 A ,

• 1 0200C E 02 8 0 L / L >

.1C2C00E*02 M 0L /L »

I* • 2* FR « 2.030Al • 1 . COOOOGC * BE o 7500000# GA • .5000000DE O.OOCOOOO* FP * O.OOOCOOG* ET - 1.1000000

81 « .39825876573, BP * 0 . 0000 CO 00000 » 93 * .13290189038Cl « -. 31070871113* C 2 * 0.30000000000* C3 * 0. OOOOCOOOOOO

D/DC M PL /

L

TSAT THETA PSAT 8 C.10 1.0200 299.017 266.817 2.0592 .39959 -.52866.20 2 .0400 328.577 303.309 3.9641 .40357 -.43956.30 3 . 0600 346.021 327.959 5.5526 .41022 -.35347.40 4.0800 357.141 345.285 6.7636 .41952 -.27535.50 5.1300 364.264 357.217 7.6757 .43148 -.20565.60 6.1200 368 . 7?3 365.054 8.2914 . 4<t ‘-10 -.14533.70 7.1400 371.369 369. 80 c 8.6602 . 46339 -.09455.60 8.160C 372.762 372.297 8 .8666 .48331 -.05415.90 9.1900 373.313 373.254 8.9496 .50591 -.02280

1.00 1C. 20CC 373.400 373.400 8.9629 .53116 0.000001.10 11.2200 373.319 373.260 8.9505 .55907 .015271.20 12.24CO 372.816 372.350 8.9746 .58964 .024201.30 13.2600 371.577 370 . C13 6.6909 .62286 .02 9031.40 14.2600 369.360 365.683 8.3711 .65874 . 027991 .50 15.3000 365.994 358.903 7.9048 .69729 .0252?1.80 16.3200 361.328 349.333 7.2974 .73849 .020731.70 1^.3400 355.310 336 . 764 6.5679 .78234 .015391.80 1 8.3600 347.892 321.129 5.7459 .82886 .009841.90 19.3900 339.016 302.508 4.8677 .87803 .004602.00 20.4000 328.699 241.139 3.9739 . 9 2 9 P6 0.000002.10 21.4200 316.933 257.409 3.1063 .98435 -.003772.20 22. 4400 303.734 231 . 848 2.3053 1.04150 -.006632.30 23.4600 289.139 205.107 1 .605 9 1.10131 -.008602 .40 24.4800 273.212 177.928 1.0342 1.16377 -.009772.50 25.5000 256.058 151.096 .6033 1.22889 -.010242.60 26.5200 237.828 125.363 .3100 1.29667 -.010162.70 27.5400 218.722 101.488 .1351 1.36711 -.009662.30 28. 56C0 199.984 79.976 . 0474 1 . 44021 -.009992.90 29.5800 178.882 61.235 .0124 1.51596 -.00793

53

Table

5.

Calculated

critical

isotherm

for

hydroyen

sulfide

cj an ro o CO CD CJ o 03 rH o CO an c- r- o DO 4 O' O o 4 X 4 X o DJ 4 X O' X o r-H rH 4 X p^ rH 4 X— 4 O 4 rH CD c- ao -H 03 sO o ro 03 03 4 r-H an ro DO DO o 03 x> CO CO X o co r-H 4 O' o 4 rH o rH X p* rH Xo an an X p- p- ao O' rH C0 4 o 4 O o ro >o O' DO 03 o rH X X p^ cn o rH X o p«- 4 X rH o O' CD N X X X"V. o O o o o O o rH rH rH rH co co CO cn an CO an o o o 4 CO p'- X 4 X co DO rH r-H f-H rH rH o o o o o oCl •< o o o o o o o o o o o O o O O O o rH DO rH o xT ro rH o o o o o o o o o o o o o o o o oCO CL

O z: 1 1 1 i # ( 1 1 1 I i 1 i i i 1 1 1 rH1

o rH

o 4 H ao 03 CO O' r-H 03 4 4 O' OD O' OD CD 4 rH rH X X r- o X o X c- 4 o X o X X X O' X p~ o oo 4 o 03 >r O CO o co O' r- OD O CO fn- an P- 4 xO o c- X CO xO co X 4 X OD rH rH X r- rH X O' o O' ao o 4V, •< x p- CO o co >J* an o an an 03 O O 4 o CJ xO CO O' rH an CO CO X o rH rH xO o O' 4 X o o o O' o X o oCL Cl 4 ro o CO co c- a> an 03 CJ co xO co O' ro an an xO co 4 o X o o O' 4 4 OD X X X X X CJ rH o p^ X p-

o ZT m CJ rH O' fn- rH CD 4 O an O' cn an fn- OD an o CO CO xO o xO 4 xO o X X X O' 4 r-H o rH 4 CD X XCD X >5- rH o an CJ O CD an co O 4 rH CD an DJ X CO O' an CO o D- X X co o O' X c- p- r^- p- p- p- OD or- GD CT o o rH co CO 4 4 an 03 ac O' O' o r-H rH co co ro 4 X X xO p^ cc O' O' o rH CJ X 4 X X OD oCO CO CO 4 xT >T 4 4 4 4 4 4 4 4 4 an an an un an an X X X X X O' X X X X X X X X X X X XH rH H rH r-H rH rH rH rH rH rH rH rH rH rH rH rH f-H rH rH rH rH r-H rH rH f-H f-H f-H rH rH s=-H rH f-H rH rH rH rH rH rH f-H

o ~J CO o o an a co CJ 03 03 an CO c- 4 OD an CJ o an 4 xO o O' X X X X X X O' X CO o X X X X CJ X rH DJ Xo O x o p- 4 co O' CJ CO CJ rH OD CO 03 xO rH rH f-H rH 4 o an X rH co xO 4 rH o X X X OD rH o rH X rH X f-H

^s. X O o p- X an 03 xC c- O' CJ rH CC an CO K- xO r-H C- o xO 03 c- rH CO rH o c- CJ r- X CJ ao O' r^- ac O' X o oo m an CO CD an nT an c- CD o O' Cl rH CO CO CJ an rH X CO o rH o o r- 03 rH xO X o 4 O' X X rH an rH CD Xo an 4 X O co rH rH o an cn O 4 O an 03 O' O xT 4 O o o X p^ CJ cn X c—

H

p^ OD c- o X o r- or »-H O' pi f-H 4i O CP co ao o 0"1 ac. !fn on co CJ an CJ rH CO c- 4 rH O a o o o rH 4 X 4 X 4 O' X CJ o 4 X o X X X rH CD*3 CD H x O' O an CO O CD O' 4 CO CJ rH o o O o o o o o o o o f-H CJ X 4 X O' CJ X O' X O' X CJ o CDCL 4 4 co CJ CO co rH rH rH O o O C; o O o o o o o o o o o o o o o o o o o f-H rH rH DO co X 4 X XZ~ o o o o o O O o O o o o O O O o o o o o o

fl

o o o o o o o o o o o o o o G o o o o o

g X H an O' an CO ao O' o CO an u—

1

co rH CO o CO c- o o o 4 o o CJ o X ac o p^ f-H X o o Co 4 X o 4 CoCL 0D o ao o an CO an ao o 03 un o ao an 4 ro CD o o o rH c- CP. X rH 4 4 O' 4 4 P- 4 o X 4 X O' 4>*. O o ro an fn ac Cs» o co co CO 4 CD ac 4 r- O' O' o o G o o rv X CJ cv cc rH 4 O' X 4 rH co o o p 4 ccCL 4 cc O CD ro 03 03 an CO c- rH 4 03 r- CD O' O' O' O' e o o o o G o C—

3

CJ X X o X O' D- p^ o 4 DJ X O' ox CD H CJ >J- an >c> c- ac CD O' O O' O' O' O' o o o o o o o c o o o c o o o rH rH CJ X 4 X CD o DJ XCD CD O' o- O' O' O' O' O O' o O' a O' O' O' o o o o o o o G o o o c G c o o G o o o G o rH rH rHo O O' O' O' O' o O' o O' O' O' O' O' O' O' O' o o o o o o o o o o o o o o o o o G o o o o c o

• o O O' o O' o* o O' O' O' O' o o o O' O' O' o o o o o o o o o o o o o o o o o o o o o c o ca O O' o O' o O' O' o O' O' o O' O' O' O' o o o o o o o G o o o o c o o o G o o o o o o o G

Q. 4 rH rH rH f-H f-H rH rH rH rH rH f-H f-H f-H f-H rH f-H rH rH rH rH f-H

Z* Q-

z:

Q —

J

o 0L o cc O' o cr rH 4 C- c- XT c- an rH co an CD CO aN o a X X X CJ o 4 4 X X X 0—

.

X o rH p f— CJO a O a o On CO ao rH ro o o 03 co un <V c- 03 fO Co O' o an co o ro X 4 X o X o 4 r- rH X 4 o p- X p- f-H ac acO r- T O' r-H an P- rH co o O' O' Cx 0D o Cr CD o S*H X rr D- o Co co CO c- X O' X o o 4 c- c X X X co f-H X X XCO x on 'v. x p- rH co o CD c xp C- o o cr. xT 4 03 cr o o xO O o X xO xO O' rH X X 4 an 4 CJ X o cc X rH rH X O' CDx co o _J x P- an CP f\.’ co 4 CJ O' xO 03 CO C- cn 4 m xO xC DJ o X rH X xT o X X CJ CD rH X X DJ X (V rH O' p- cc x.O' xc g 1 CD O 4 03 m 03 IT a CO o 03 O' o ao O' O 4 o X o CO r- o O' rH rH f"- G X' X CJ r- rH G X o rH X X• H <X H on ro rH co an o 03 4 cn 4 OD CO o ao X c- 4 o o o 4 o r^- r- X o a. o ac r- o X CD 4 f-H f—

H

f-H XCD • Q. ao 4 H ac an co O' c- 4 CJ O au xT an CO co f-H rH O o o o o f—

«

r-H cv X X X CD O' r-H X X ac o X X O' cv XB B

ro ro CO co (V CJ rH H rH rH r-H C O O O O o o o o o o o o o o G o o o o rH rH rH rH CJ DJ PI c X X

O — 1 1 1 1 ! t i 1 1 1 1 1 1 1 1 t t 1 1 t

a oG x h r-l o rH r—4 O' 03 rH an CJ 4 4 rH CD co 4 CO xO o o CJ o o X o 4 o cv O' XI 4 X 4 f-H rH ac p^ X. CD

•> a CL 4 p- 03 o o <r o O an r- CJ an 4 CD C- CO O cn an o xC o X c- X rH o a- X f-H xr XT O' X X o D\J X p—

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—

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•» a H CO o P- CO an r- r- 03 ro O' an O co a> I'' ao o o O' o o o o X c- X X o XT o 4 X- o o CD X oo o f—

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G an an O' O Cj On >r XT 03 c- ao CD o O' O' o o o c o O' o o o o O' O' CL ar X r X X 4 r (V rH O' a XS' CP OC c

c

O a o O o O' O' O' O' O' O' O' o- o o o O' c O' o o a o o O' o o O' o O' o O' O' o o a X am a O' o a O' o O' O' o O' O' o O' O' O' O' o o o o G o o o O o o O' o o O' o O' o O' O' o o o o O'O co o o O o o- o a o o O' O' o O' o O' O' o o o O' o o o o O' o o O' o o O' o O' O' O' o o o O' o O'

10

. rH•

rH

B o _J x 4 O' 03 an un xl- CO o on c- rH c- <\) O' c- o xO o o rH cc X X rH o X XT o CJ o XT r-H p^- rH DJ X 4 X XB o O 4 Cu o o r- ac O' CJ 03 03 rH CD cr rH ar cr an o r-H o an r- X c- o xC cv <\ X f-J O' 4 Do X (P o Cj X cv

»- v. X on >c cc p- Co X* CJ o 03 o or O' O' ro co Co G CP. CJ c X 4 r- o X c DO f-H r- c- o r— cv 4 O' 4 4 X o XO G on "n. r^- o C H o IT o r-> xT 0" CO cr C- o ar co CO X 4 xO o c CJ O' f-H r-H o X cv» c X f-H X DJ X f-H »—• X G oo V* _J CO r-H un co •4- 03 IT c- c- O (M rH <v 03 X DO X o xj X O' 4 r- X X f-H «—

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4 X rH r-H rH X cv ac X Cl Xon O i CO p an 4 r- a^ O ro o: o r- O' 0. rH un o O C xT X o X O' o o 4 X CJ O' r—

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X X o X p- 4 X o X X o•> a -r CC co (V CJ ro an c- o LO o O' 4 O xC O an o C\J G X X o X X f-H X o XT' O' X p- o X X X >C

* O f-H CL 03 an an 03 ac rH 03 rH cc an 4 4 an X DO xi3 CP O o o cn xT rH X X DO X 4 o 4 o X 4 cv f-H rH pan CJ o ao 0. xT co rH O' ac >c un 4 CO cv rH rH o O O o o o o f-H rH CJ X 4 X X c- O' o CJ X X p- O' f-H X

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CO co CO rH rH rH rH rH 1 1 1 8 1 1 1 1 1 1 • • rH1 1

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X on on a p rc ao 03 rv a-' an ac 03 ro ac CJ an c- O O' O' o O' O' O' D- X CJ o cn O' G O' X Cl X 4 cv p- o rH— »— an cr CJ an fn O' rH CO 4 an o: ac ao O O' O' o a O' o O' O' O' O' O' a CD cr r* X x. 4 X cv o ao X cr r—

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p D- a ao a a O' O' O' O' O' O' O' O' O a o o O' O' o o O' O' O' o o O' o a o o o O' o O' cc ar a a p-g 1— a o O O' O' O' O' O' O' O' r> o O O' O' O' o o O' o o o O' O' O' O' O' O' o O' o o o O' O' o O' o o a o*— •a O' O' O' O' o O' O' O' O' O' O cr o O' O' o o o O' o o o O' O' O' o O' O' o O' o o o O' O' O' o O' o O' O'

o o o o o O' O' O' O' O' O' O' O' O' O' o o o O' o orH

o cr O' O' O' o O' o O' o o o o O' o o o o o o

g o an o an o a- o un o an o an o XT' o a> o an o an o an o X o X o X o X o XT o X e X o Xi G IT co o o rH rH Co co CO co 4 4 ID O' xT o. r-. X X' O' O' o o f-H rH cv cv X X 4 4 O' X X X p- p- a or O' o oo a o O' O' o O' O O' O' a O' a O' O' O' o O' a O' o o o o o o o o o o o o o o c e o o G G —f-H r-H rH rH f-H f-H rH f-H f-H rH r-H r-H f-H rH f-H rH rH rH rH r-H rH

54

6. Comparisons for P-p-T data for hydrogen sulfide.

MVORDGEN sulfide pvt DAT 4 vs. eonstate<1)REAMER» ( 2

)

l EW I S # ( 3

)

R AU» (4)STRATY

ID p N WT T,K HOL/L c alcd D , PC T P » H P A c alcd P > PC T1 1 1.000 277.594 .0444 .0443 .17 .1013 .1015 -.171 2 1.000 277.594 .0607 .0605 .22 .1379 .1382 -.221 3 1.000 277.594 .0917 .0914 .30 .2068 .2074 -.291 4 1.000 277.594 .1232 .1228 .36 .2758 . 2768 -.351

c 1.000 277.594 .1552 .1546 .39 .3447 .3460 -.331 6 1.000 277.594 .1878 .1869 .45 .4137 .4155 -.431 7 0.000 277.594 .2547 . 2532 .58 .5516 .5546 -.541 e 0.000 277.594 . 3243 .3217 . 79 .6895 .6945 -.721 9 0.000 277.594 .4150 .4109 .99 .8618 . 8695 -. p «

1 10 0.000 277.594 .5101 .5046 1.10 1.0342 1.0442 -.951 1

1

1 .000 277.594 24.2300 24.2194 .04 1.3790 1.5600 -11.611 12 1.000 277.594 24.2704 24.2596 .04 2.0684 2.2564 - 8.331 13 1.000 277.594 24.3109 24.2991 .05 2.7579 2.9651 -6.991 1 * 1.000 277.594 24.3590 24.3382 .09 3.4474 3.8188 -9.731 15 l.ooo 277.594 24.4072 24.3767 .13 4.1369 4.6904 -11.801 15 1.000 277.594 24.4856 24.4522 .14 5.5158 6.1368 - 10.1

2

1 17 1.000 277.594 24 . 5644 24.5258 .16 6.8948 7.6321 -9.661 1 P l.OCC 277.594 24 .6514 24.6153 . 1 5 8.6184 9.3275 -7.601 19 1 .000 277.594 24.7428 24.7022 .16 10.3421 11.1632 -7.361 20 1 .000 277.594 24.8271 24.7867 .16 12.0658 12.9077 -6.521 21 1.000 277.594 24.9121 24.8689 .17 13.7895 14.7130 -6.2 3

1 2 ? l.OCC 277.594 24.9937 24 , 949 C .18 15.5132 16.4949 - 5.951 23 1.000 277.594 25.0719 25.0271 .18 17.2369 18.2466 - 5.531 24 1.000 277.594 25.1546 25. 1033 . 20 18 . 9606 20.1456 - 5.381 25 1.000 277.594 25.2339 25.1777 .22 20.6843 22.0121 -6.031 26 1.000 277.594 25.3899 25.3216 .27 24.1317 25.8215 - 6.541 27 1.000 277.594 25.5356 25.4594 .30 27.5790 29.5460 -6.661 28 1.000 277. 594 25.6583 25.5916 .26 31.0264 32.8103 - 5.441 2 <? 1.000 277.594 25.7822 25.7191 .25 34 .473 8 36.2274 1 4“ CD 4

*

1 30 1.000 277.594 26.0845 25.9606 .48 41.3685 45.0927 - 8.261 31 1.000 277.594 26.3245 26.1866 .53 48.2633 52.6873 -8.401 32 1.000 277.594 26.5338 26.3993 .51 55.1581 59.7268 - 7.651 33 1.000 277.594 26.7019 26.6005 .38 62.0528 65.6711 - 5.51

1 34 1.000 277.594 26.8091 26.7915 .07 68.9476 69.6035 -.94

1 35 1.000 310.928 .0395 .0395 .06 .1013 .1014 -.09

1 36 1.000 310.928 .0539 .0538 .04 .1379 .1380 -.04

1 37 1.000 310. 92e .0812 .0812 .03 .2068 .2069 -.03

1 3 P 1.000 310 . 9 ?« .1088 .1088 .05 .275 8 .2759 -.05

1 39 1.000 310.928 .1367 .1367 .01 . 3447 .3448 -.01

1 40 1.000 310.928 .1650 .1649 .07 .4137 . 414C -.07

1 41 1.000 310.928 .2222 .2222 .01 .5516 .5516 -.01

1 42 1.000 310.928 , 2«05 .2 807 -.06 .6895 .6891 .06

1 43 1.000 310.928 .3552 . 3558 -.17 . 8618 . 8605 .15

1 44 1.000 310.928 .4329 . 4330 -.02 1.0342 1.0340 .02

1 45 1.000 310 . 92P .5937 . 5947 -.17 1 . 3790 1.3768 .15

1 46 l.OCO 310.928 .9523 .9539 -.16 2.0684 2.0657 .13

1 47 1 .000 310.928 21.9071 21.9016 .02 2.7579 2.8107 -1.83

1 48 1.000 310.928 21.9702 21.9720 -.01 3.4474 3.4295 .52

1 49 1.000 310.928 22.0336 22.0404 -.03 4.1369 4.0682 1 .69

1 50 1.000 310.928 22.1555 22.1717 -.07 5.5158 5.3419 3.26

1 51 1.000 310.928 22.2757 22.2966 -.09 6.8948 6.6591 3.84

1 52 1.000 310.928 22.4191 22.4447 -.11 8 .6184 8.3140 3.66

1 53 1.000 310.928 22.5644 22.5849 -.09 10.3421 10.0847 2.65

1 54 1.000 310.928 22.6987 22.7181 -.09 12.0658 11.8089 2.18

1 55 1.000 310.928 22.8248 22.8453 -.09 13.7805 13.5072 2.09

1 56 1.000 310.928 22.9491 22 . 9668 -.08 15.5132 1 5 .

2

5 6 q 1 . 65

1 57 1.000 310.928 23.0647 23.0835 -.08 17.2369 16.9563 1.66

55

Table 6 Conti nued

HYDROGEN SULFIDE PVT DATA VS . FONSTATE( l ) REAMER , ( 2UEWIS , ( 3 ) R A U » ( 4JSTRATY

ID PN WT T,K MOL/L CALCC D » PC

T

P , 1PA C ALCD P * »CT1 58 l.OOC 310.928 23.1816 23.1956 -.06 18.9606 18.7415 1.171 59 1.000 310.929 23.2894 23.3036 -.06 20.6843 20.4549 1 .121 60 1.000 310.928 23. 5082 23.5085 -.00 24.1317 24.1256 .021 61 1.000 310.928 23.7100 23.7006 .04 27.5790 27.7535 -.631 62 1.000 310.928 23.8975 23.8815 .07 31 .0264 31.3396 - 1.001 63 1.000 310.928 24.0771 24.0528 .10 34.4738 34.9779 -1.441 64 1.000 310.928 24.3924 24.3705 .09 41.3685 41.8675 -1.191 65 1.000 310.928 24.6704 24.6608 .04 48.2633 48.4995 -.491 66 1.000 310.928 24.9315 24.9287 .01 5*. 1581 55.2308 -.131 67 1.000 310.928 25.1467 25.1779 -.12 62.0528 61.1637 1 .451 68 1.000 310.928 25.3457 25.4112 -.26 68.9476 66.9676 2.961 69 1.000 344.261 .0356 .0356 .01 .1013 .1013 -.011 70 1.000 344.261 .0485 .0485 -.00 .1379 .1379 .001 71 1 .000 344.261 .0730 .0730 -.04 .2068 .2068 .041 72 1.000 344.261 .0977 .0978 -.02 . 2758 . 2757 .021 73 1.000 344.261 .1226 .1227 -.08 .3447 . 344 5 .081 74 l.OOC 344.261 .1476 .1477 -.07 .4137 .4134 .071 75 1.000 344.261 .1982 .1985 -.13 .5516 .5509 .131 76 1.000 344. 261 .2495 . 2501 -.22 .6895 . 6880 .211 77 1.000 344.261 .3147 .3156 -.29 .8618 . 8595 .201 78 1.000 344.261 .3814 .3 82 5 -.28 1.0342 1.0315 .261 79 1.000 344.261 .5184 .5201 -.33 1 .3790 1.3747 .311 80 1.000 344.261 .8107 .8132 -.31 2.0684 2.0627 .281 81 1.000 344.261 1.1328 1 .1346 -.15 2.7579 2.7544 .131 8 ? 1.000 344.261 1.4971 1.4936 .23 3.4474 3.4536 -.131 83 1.000 344.261 1.9230 1.9072 .83 4.1369 4.1610 -.581 84 1.000 344.261 18.7044 18.8354 -.70 5.5158 5.0461 9.311 85 1 .000 344.261 19.0153 19.1740 -.83 6.8948 6.2178 10.891 86 1.000 344.261 19.3787 19.5296 -.77 8.6184 7.8508 9.781 97 1.000 344.261 19.6811 19.8343 -.77 10.3421 9.4459 9.491 88 1.000 344. 261 19.9306 20.1029 -.61 12.0658 11.2565 7.191 89 1.000 344.261 20.2535 20.3441 -.45 13.7895 13.1218 5.091 90 1.000 344.261 20 .4552 20.5638 -.53 15.5132 14.6423 5.951 91 1.000 344.261 20.6530 20.7661 -.54 17.2369 16.2566 6.031 92 1.000 344.261 20.8357 20.9539 -.56 18.9606 17.8612 6.161 93 1.000 344.261 21.0051 21.1295 -.59 20.6843 19.4513 6.341 94 1.000 344.261 21.3153 21.4505 -.63 24.1317 22.6322 6.631 95 1.000 344.261 21.5999 21.7391 -.64 27.5790 25.8739 6.591 96 1.000 344.261 21.8921 22.0020 -.50 31.0264 29.5490 5.001 97 1.000 344.261 22.1311 22.2441 -.51 34.4738 32.8304 5.011 99 1.000 344.261 22.5612 22.6788 -.52 41.3685 39.4111 4.971 99 1.000 344.261 22.9327 23.0623 -.56 48.2633 45 . 8442 5.281 100 1.000 344.261 23.2996 23.4067 -.46 55.1581 52.9399 4.191 101 1.000 344.261 23.6261 23.7201 -.40 62.0528 59.91 89 3.561 102 1.000 344.261 23.9690 24.0084 -.16 68.9476 67.9722 1.441 103 1.000 377.594 .0324 .0324 -.02 .1013 .1013 .021 104 1.000 377.594 .0441 . 0442 -.04 .1379 .1378 .041 105 1.000 377.594 .0664 .0664 -.06 .2068 .2067 .061 106 1.000 377.594 .0887 . 0888 -.09 .2758 . 2756 .091 107 1.000 377.594 .1112 .1113 -.10 .3447 .3444 .101 10 8 1.000 377.594 .1338 .1340 -.14 .4137 .4131 .131 109 1.000 377.594 .1794 .1797 -.18 .5516 . 5506 .181 110 l.OCO 377.594 .2253 .2259 -.28 .6895 .6876 .271 111 1.000 377.594 .2 835 . 2844 -.33 .8618 .8591 .321 112 1.000 377. 594 .3430 .3438 -. 22 1 .0342 1.0320 .211 113 1.000 377.594 .4630 .4649 -.42 1.3790 1.3734 .401 114 0.000 377.594 . 746 ] .7176 3.97 2.0684 2.1438 -3.511 115 1.000 377.594 .9833 .9854 -.21 2.7579 2 . 7*28 .19

56

Table 6 Continued

HYDROGEN SULFIDE PVT DATA VS. EQNSTATE(l)REAMER, (2UEWIS# (3)RAU> ( < ) S T R A T Y

10 PN WT T»K MOL/L C ALCD 0, PC T P, MPA C A L C 9 p»°CT1 116 1.000 377.594 1.2713 1.2707 .05 3.4474 3. 4 A 8 8 -.041 117 1.000 377.594 1 .582 9 1.5772 .36 4.1369 4.1491 -.291 118 1.000 377.594 2.3015 2.2781 1.03 5.5158 5.5571 -.741 119 1.000 377.594 3.2361 3.1773 1 . 85 6.8948 6.9704 -1 .091 120 1.000 377.594 5.2008 5.1026 1.92 8.6184 8.6718 -.611 121 1.000 377.59*, 13 .9899 13.9092 .56 10.3421 10.3861 -.421 122 1.000 377.594 15.6796 15.6889 -.06 12.0658 12.0518 .1?1 123 1.000 377.594 16.5463 16 . 5687 -.14 13.7895 13.7356 .391 124 1.000 377.594 17.1522 17.1845 -.19 15.5132 15.4104 .671 12 5 1.000 377.594 17.6434 17.6675 -.14 17.2369 17.1424 .551 126 l.OOC 377.594 18.0185 18.0689 -.28 18 . 9606 18.7284 1.241 127 1 .000 377. 59*. 18.3551 18.4148 -.32 20.6843 20.3699 1.541 129 1.000 377.594 18.9165 18.9938 -.41 24.1317 23.6275 2.131 129 1.000 377.594 19.3811 19.4718 -.47 27.5790 26.8792 2.601 130 1.000 377.594 19.7881 19.8817 -.47 31.0264 30.1961 2.751 131 1 .000 377.594 20.1617 20.2422 -.40 34.4738 33.6679 2.391 132 1.000 377.594 20.7493 20.8580 -.52 41.3685 40.0529 3.281 133 1.000 377.594 21.2531 21.3753 -.57 48.2633 46.5363 3.711 134 1.000 377.594 21.7199 21.8239 -.48 55.1581 53.4794 3.14

1 135 1 .000 377.594 22.1402 22.2214 -.37 62 .05 2 8 60.5816 2 .43

1 136 1.000 377.594 22.5676 22.579? -.05 68.9476 68.7109 .34

1 137 1 .000 410.928 .0297 .0297 -.04 .1013 .1013 .04

1 13 « 1.000 410.928 .0405 .0405 -.04 .1379 .1378 .04

1 139 1.000 410.928 .0609 .0609 -.08 . 2068 .2067 .08

1 140 1.000 410.928 .0814 .0814 -.08 . 275 8 . 2756 .08

1 141 1 .000 410.928 .1019 .1020 -.11 . 3447 . 3444 .10

1 142 l.OOC 410.928 .1225 .1227 -.18 .4137 .4130 .17

1 143 1.000 410.928 . 1640 .1643 -.21 .5516 . 5504 .21

1 144 1.000 410.928 . 2059 .2063 -.20 .6895 . 68 82 .19

1 145 1.000 410.928 .25 84 .2593 -.36 .8618 . 8588 .35

1 146 1.000 410.928 .3116 .3128 -.38 1.0342 1.0304 .37

1 147 1.000 410.928 .4193 .4216 -.54 1.3790 1.3719 .52

1 149 0.000 410.929 .6955 .6457 7.71 2.0684 2.2180 -6.74

1 149 1.000 410.928 .8763 . 8791 -.32 2.7579 2.7499 .29

1 1 5 C l.OCC 410.928 1.1202 1.1223 -.19 3.4474 3.4416 .17

1 151 1.000 410.928 1.3773 1.3765 .06 4.1369 4.1391 -.05

1 152 1.000 410.928 1 .9369 1.9249 .63 5.5158 5.5445 -.52

1 153 1.000 410.928 2.5753 2.5439 1.23 6.8948 6.9597 -.93

1 154 l.OCC 410.028 3.5361 3.4704 1.89 8.6184 8.7260 -1.23

1 155 1.000 410.928 4.7533 4.6886 1.38 10.3421 10.4191 -.74

1 156 1.000 410.929 6.4202 6.4575 -.58 12.0658 12.0360 .25

1 157 1.000 410.928 8.6821 8.9455 -2.94 13.7895 13.6149 1 .28

1 15 8 1.000 410.928 11,0472 11 .2058 -1.42 15.5132 15.3723 .92

1 159 1.000 410.928 12.7739 12.8059 -.25 17 .2369 17.1954 .24

1 160 1.000 410.928 13.8929 13.9282 -.25 18 . 960 * 18.8969 . 34

1 161 1.000 410.928 14 .7093 14.7606 -.35 20.6843 20.5643 .59

1 162 l.OOC 410.928 15.9229 15.9526 -.19 24.1317 24.0283 .43

1 163 1.000 410.928 16 .7820 16.8063 -.14 27.5790 27.4674 .41

1 164 1.000 410.928 17.4493 17.4743 -.14 31.0264 30.8840 . 46

1 16 5 1.000 410.928 17.9983 18.0255 -.15 34.4738 34.2895 .54

1 166 l.OOC 410.928 18.8741 18.9086 -.18 41.3685 41 .0640 .74

1 167 1.000 410.928 19.5419 19.6078 -.34 48.2633 47.5518 1.50

1 16 8 1.000 410.929 20.1363 20.1903 -.27 55.1541 54.4709 1.26

1 16 9 1 .000 410.928 20.682 3 20.6917 -.05 62.0528 61.9157 • 22

1 17 0 1.000 410.928 21.1884 21.1331 .26 68.9476 69.8704 -1 .32

1 171 1.000 444.261 .0275 .0275 -.03 .1013 .1013 • 0 3

1 172 1.000 444.261 .0374 .0375 -.03 .1379 .1378 . 0 3

1 173 1.000 444.261 .0562 .0563 -.07 .7068 • 2067 .07

57

T a b 1 e 6 Conti nued

HYDROGEN SULFIDE PVT DATA VS. EONSTATE(l)REAMER, ( 2 ) L E WI S» (3)RAU, <*)STRATY

ID P h WT T,K HOI /L CALCD D, PC T P, HP A CALCD P»PCT1 17* 1.000 ***.261 .0751 .0752 -.11 .2758 .2755 .111 175 1.000 ***.261 .09*0 .09*1 -.15 .3**7 .3**2 .1*

1 176 1.000 ***.261 .1130 .1132 -.18 .*137 .*129 .181 177 1.000 ***.261 .1511 .151* -.21 .5516 .5505 .201 1 7 P 1.000 ***.261 .1893 .1899 -.32 .6695 .6873 .311 179 1.000 *** .261 .2 377 . 2385 -.33 .6618 . 6590 .33

1 180 1.000 ***.261 .2866 . 28 7* -.28 1.03*2 1.031* .271 191 1.000 *** .261 . 3 85 1 . 3863 -.33 1.3790 1.37*6 .321 182 1 .000 ***.261 . 5859 .5 e 8 e -.*9 2.068* 2.0588 .*71 183 1.000 ***.261 .793 8 . 7972 -.*3 2 .7579 2.7*66 • ^ D

1 18* 1.000 ***. 261 1.0087 1.0117 -.30 3 .**7* 3. *379 .281 165 1.000 ***.261 1.2312 1.2326 -.13 *.1369 *.1320 .121 186 1.000 ***.261 1.7005 1.6971 .20 5.5158 5.5256 -.181 197 1.000 *** .261 2.209* 2.1967 .58 6.69*8 6.9266 -.*91 138 1.000 ***.261 2 . 912* 2.8863 .91 8.618* 8 . 6798 -.711 189 1 . 000 *** .261 3.7080 3.67*2 .92 10.3*21 10. *105 -.661 190 1.000 ***.261 *.6296 *.5970 .71 12.0656 12.1216 -.*61 191 1.000 *** .261 5.6823 5.69*1 -.21 13.7895 13.772* .121 192 1 .000 *** .261 6.8*8* 6.9761 -1 .82 15.5132 15 .

3

e 1* 1.051 193 1.000 ***.261 8.1271 8.3537 -2.71 17.2369 16.9530 1.671 1 9* 1 .coo ***.261 9.3730 9.6591 -2.96 18.9606 18.56*5 2.131 195 1 .000 ***.261 10.5*5* 10.7938 -2.30 20.68*3 20.2832 1.981 196 1 .000 ***. 261 12. *75* 12.5852 -.87 2*. 1317 23.8853 1.031 197 1.000 ***.261 13 .832 9 13.8939 -.** 27.5790 27.3939 .661 1 9 p 1.000 ***.261 1* . 831

9

1* . 8686 -.38 31 .026* 30.6058 . 72

1 199 1 .000 *** .261 15.6*30 15.6802 -.2* 3*. *736 3*. 2956 .521 200 1 . ooc ***.261 16.8793 16.8915 -.07 *1.3685 *1.2873 . 201 201 1.000 ***.261 17. POO ? 17.8060 -.03 *8.2633 *8.21*6 .101 20? 1 .coo ***.261 1 8 , 5 1 P 5 1 8. 8992 -.13 55 . 1 5 e 1 5* .91*0 .**1 203 1.000 ***.261 19.1379 19.1601 -.1? 62.0528 61 .786* .*3

1 ’0* 1.000 ***. 261 19.727? 19.6936 . 17 68 .9*76 69. *132 -.67

ND > 20*, DNRMSPCT - .593, DNTPNDPCT « -. 119 , PHEANPCT 2.023

58

Table 6 Continued

HYr>enGEN SULFIDE PVT DATA VS. EONSTATE(l)PEAYEP, ( 2) LEWIS# ( 3 ) R A U > ( A ) STR AT

Y

ID P N WT T,K MOL /L CALCD D, PC T P, MP A CALCD P> p CTA 2 0 5 1 .000 A93 .000 . 0 5 A 0 . 0 5 A 1 -.06 .220 8 . 2207 .06A 206 1.000 A93.000 .0869 . 0870 -.11 . 3 5 A 1 . 3538 .11A 207 1.000 A93 .000 .1395 .1398 -.18 .5670 . 666C .17A 708 1.000 A93 .000 .1529 .1532 -•;9 .6207 .6195 .19A 209 1.000 A93.000 . 1 80 A .1008 -.22 .7310 . 7? 9 A .22A 210 1.000 A 9 3 . 000 . 2 2 A 2 . 2 2 A 8 -.26 . 90 6 A . 90AC .26A 211 1.000 A 9 3 . 000 , 2 A 5 6 . 2 A6 3 -.28 . 991 A . 9e87 .27A 212 1.000 A 93 . 000 .2 898 .2907 -.30 1.1665 1.1630 .30A 213 1.000 A93.000 .3603 .3615 -.33 1 .AA38 1 . A392 .32A 2 1 A 1.000 A93.000 . 3 9A6 . 3959 -.33 1.5781 1.5729 .33A 21 S 1.000 A 9 3 . 000 .A656 . A6 7 1 -.33 1.8536 1.0A76 .32A 216 1.000 A93 .000 .5788 . 5006 -.30 2 .2 881 2.2815 .29A 217 1.000 A93. 000 . 63A0 .6358 -.28 2. A978 2 . A 9 1 2 .27A 21 8 1.000 A93.000 , 7 A 8 1 . 7 A96 -.20 2.9263 2.9207 .19A 319 1.000 A93.000 .9301 . 9305 -.OA 3.5975 3.5960 .OAA 220 1.000 A93 .000 1.0137 1.0182 .05 3.9106 3.9203 -.OAA 221 1 .000 A93.000 1.2019 1. 199C .25 A. 5718 A. 50 2<> -.23A 22 2 1.000 A 93 .000 1 . A9A6 1. A860 .58 5 . 5 8 A 9 5.6151 - . 5 A

A 723 l.COC A93.000 1.6370 1 . 62 Ae .75 6 .06AA 6.1060 -.68A 2 2 A 1.000 A 9 3 . 000 1.9319 1.9116 1.06 7.0325 7.100C -.95A 72 5 1 .000 A93.000 2.2052 2.1766 1.32 7.9001 7.9925 -1.16A 226 1.000 A 9 3 . 000 2 . A027 2.3679 1 .A7 6.5102 8.6199 -1.27A 227 1.000 A93.0C0 2.6315 2.5697 1.62 9.2001 9.3202 -1.37A 228 1.000 A93.0C0 2 . 93 A 2 2.8838 1.75 10.0868 10.2353 -1 . A 5

A 22 9 1.000 A 9 3 . 000 3 . 1 0 A 6 3.0501 1.79 10.5737 10.7313 -1.A7A 230 1.000 A93 .000 3 . 5 A36 3 . A 8 1

1

1.80 11.7895 11 . 9 6 0 A -1 .A3

A 731 1.000 A93.0C0 3 . 8605 3 . 795 A 1.72 12.6356 12 . 8 0 6 A -1 .3A

A 232 1.000 A93 .000 A . 2 26 A A. 1622 1 . 5 A 13.5026 1 3 . 7 A A 2 -1.13A 233 1.000 A 9 3 . 000 A .7136 A . 6 5 7 A 1.21 1A.7987 1 A . 93 26 -.90A 2 3 A 1.000 A 9 3 . 000 A . 9907 A.939A 1 .CA 1 5 . A 62 0 15.5817 -.76A 735 1 .000 A93.0C0 5.6965 5.678C .33 17.1228 17.1632 -. ’A

A 236 1.000 A 93.000 6.2070 6 . 2 1 8 A -.18 18.2826 10.2586 .13

A 237 1.000 A93.000 6.7980 6 . 8 A 8 9 - . 7 A 19.6023 19. A96A . 5 A

A 23 8 1.000 A 9 3 . 000 7.5870 7.6852 -1.2 6 21 .3A13 21.1359 .97

A 739 1.000 A 9 3 . 000 8.0197 8.1526 -1.63 22.3301 22 .0A67 1.29A 2 A 0 1.000 A 93 . 000 9.3067 9.3191 -.13 2 A . 9 A 1 7 2 A . 9 1 2 3 .12

A 2A1 1.000 A93.000 9.9750 10.1256 -1 .A9 26.9A2

A

26. 553A 1 . A6

A 2 A 2 1.000 A93 .000 10.9190 11.0395 -1.09 29. A80A 29.1269 1.21A ?A3 1.000 A93.00C 12.19A0 12.2393 -.37 33.3875 33.2256 . A9

A 2 A A 1,000 A 93 . 000 12.6500 12.9165 -2.00 35.9698 3A.9A68 2.93

A 2 A 5 1.000 523.150 . 0 A 8 A . 0 A 8 5 -.07 .2102 .2100 .07

A 2 A 6 1.000 523.150 .0511 .0511 -.07 .2216 . 2 2 1 A .07

A 2 A 7 1.000 523.150 .0561 .0562 -.08 . 2 A3 A .2A32 .03

A 2 A 8 1.000 523.150 .0565 .0565 -.0 8 . 2 A A 9 , 2 A A 7 .00

A 2 A 9 1.000 523.150 .0778 .0779 -.12 .3372 . 3360 .12

A 250 1.000 523.150 . 0 82 1 . 0822 -.13 , 3 5 5 A . 3550 .13

A 251 1.000 523.150 .0902 .0903 -.1A .3905 . 3899 .1A

A 252 1.000 523.150 .0907 .0909 -.1A . 392 0 .3923 .1A

A 253 1.000 523.150 .1251 .1253 -.19 . 5 AO 5 . 5395 .19

A 25 A 1.000 523.150 .1318 .1321 -.20 .5695 , 5 6 8 A .20

A 255 1.000 523.150 . 1 AA 9 . 1 A5 3 -.22 .6258 .62 AA .22

A 256 1.000 523.150 , 1 A5 7 . 1 A 6

1

-.22 .6292 .6270 .22

A 257 1.000 523.150 .2009 . 2015 -.29 . 86 A 8 . 8 6 2 A .29

A 258 1.000 523.150 .2118 . 2 1 2 A -.30 .9112 .9005 .30

A 259 1.000 523.150 .232 8 . 2336 -.32 1 .0007 . 9975 .32

A 260 1 .000 523.150 . 2 3 A

1

. 2 3 A 9 -.33 1.0062 1 .0030 .32

A 261 1.000 523.150 . 3227 . 32AC -.39 1.3806 1.3753 .39

59

Tabl e 6 Continued

hydrogen sulfide pvt data vs. eqnstate(l)REAMER, ( 2 ) L E W I S > (3)RAU, ( A ) STR ATY

ID PN WT T»K MOL/l CALCD D, PC T P » M P A CALCD P» PCT

A 262 1.000 523. 15C . 3 A02 . 3A16 -.AO 1 .A5A0 1 . AA63 .AOA 263 1.000 523.150 • 37A0 .3756 - . A 2 1.5957 1.5892 .Al

A 2 6 A 1.000 523.150 .3761 .3777 - . A 2 1 .60AA 1.5979 .Al

A 265 1.000 523.1 50 . A 5 1 3 . A 5 3 2 -.A3 1.9176 1.9095 . A2

A 266 1.000 523.150 .5032 , 505

A

-.A3 2 . 1 3 2 A 2 . 1 2 3 A .A 2

A 267 1.000 523.150 .5183 .5206 -.A3 2 . 1 9A 9 2.1056 . A 2

A 2 6 8 1.000 523.150 . 5 A 6A , 5 A 8 8 -.A3 2.3106 2.3010 .A 2

A 269 1.000 523.150 . “>626 . 5650 -. A2 2.3768 2.3670 .Al

A 270 1.000 523.150 .6008 . 6033 -. A1 2.5331 2.5229 .AOA 271 1.000 523.150 . 60A2 .6067 -.Al 2.5A70 2.536P .AOA 272 1.000 523.150 ,72A 8 . 72 7 A -.36 3.0362 3.0257 .35A 273 1.000 523.150 . 8082 .8107 -. 31 3.3709 3.3610 .29A 2 7 A 1.000 523.150 . 8326 . 8350 -.29 3.A603 3 . A 5 8 7 .20A 275 1.000 523.150 . 8778 . 8800 -.25 3 . 6 A 79 3.6390 . 2 A

A 276 1.000 523.150 . 9036 .9057 -.23 3 .7503 3 . 7 A 1 9 .22A 277 1.000 523.150 .9650 . 9667 -. 10 3.9920 3.9851 .17A 278 1.000 523.150 .9705 .9722 -.18 A. 0136 A. 0060 .17A 279 1.000 523.150 1 .16AA 1 .16A3 .01 A. 7673 A .7678 -.01A 2 8 n 1.000 523.150 1.2985 1 .2966 .15 5.2796 5.2870 -.1AA 281 1.000 523.150 1 .3380 1.3355 . 19 5.A292 5 . A 3 90 -.13A 282 1.000 523.150 1 . A109 1. A072 .27 5.7036 5.7179 -.25A ?83 1.000 523.150 1 .A517 1.AA73 .31 5.8563 5 . 873A -.29A 2 8 A 1.000 523.150 1.5510 1 . 5 A A 6 .Al 6.2251 6 . 2 A 92 -.39A 285 1.000 523.1 50 1 .5595 1.5529 . A 2 6.2565 6.2813 -.39A 286 1.000 523.150 1.7533 1 . 7 A 2 5 .62 6 . 96 5 A 7 . 00 5

A

-.57A 287 1.000 523.150 1 .871 A 1.8578 .73 7.3910 7 . A A 0 8 -.67A 288 1.000 523.150 2 . 0870 2.0681 .92 0.1556 8.2239 -.83A 289 1.000 523.150 2.1502 2.1296 .97 8.3765 8. A502 -.87A 290 1.000 523.150 2 .2682 2. 2AA6 1 .05 8.7859 8.8696 - . 9AA 291 1.000 523.150 2.333A 2.3001 1.10 9.0102 9.0991 -.98A 292 1.000 523.150 2 . A 92 9 2 . A 63 6 1.19 9.5537 9.6550 -1.0 5

A 293 1.000 523.150 2.5066 2. A770 1.19 9.6000 9.7023 -1.05A 2 9 A 1.000 523.150 2.8172 2.7807 1.31 10.6358 10.7583 -1 .1AA 295 1.000 523.150 3.0073 2.9673 1.35 11.2568 11.308A -1.16A 296 1.000 523.150 3.3526 3 . 308 A 1.33 12.3620 12.5023 -1 .12A 297 1.000 523.150 3.A613 3. A092 1. 53 1 2 . 68 1

A

12. 8A52 -1.27A 298 1.000 523.150 3.6509 3.5991 1 .AA 1 3 . 27 A 2 1 3 . A 3 3 0 -1.19A 299 1.000 523.150 3.7562 3.7013 1. A8 13.5687 13.7563 -1.22A 300 1.000 523.150 A . 0 1 1 A 3.9579 1.35 1A.36AA 1 A . 52 37 -1.10A 301 1.000 523.150 A. 0352 3.9815 1.35 1 A . A 3 A 9 1A. 59A6 -1.09A 302 1 .000 523.150 A . 5 3 A 9 A. A886 1.03 15.9116 16.0A31 -.82A 303 1.000 523.150 A.8A12 A . 8 0 3 0 .78 16.7977 16 . 901 A -.61A 30 A 1.000 523.150 5.3983 5 . 3 8 A 1 .26 18.3771 18.A150 -.21A 305 1.000 523.150 5.5617 5.5560 .09 18.8365 18.8A95 -.07A 306 1.000 523.150 6.0358 6.0572 -.35 20 .1A71 20.0916 .28A 307 l.OCO 523.150 6.AA51 6 , A 95 9 -.78 21.2003 21 . 1 A 95 .62A 308 1 .000 523.150 6 . A 8 39 6.5379 -.83 2 1 . 3 8 0 A 21 .2A92 .65A 309 1.000 523.150 7.2872 7.3960 -1.A7 23 . 600 A 23. 3100 1.21A 310 1.000 523.150 7.7796 7. 9 10

A

-1.65 2 A , 95 1

1

2A.60A7 1 .AlA 311 1.000 523.150 0 . 6 7 A 0 8, 8A75 -1.96 27.5259 27 . 03 AA 1.82A 312 1.000 523.150 8.9381 9.1165 -1 .96 28.30AA 27.7857 1.87A 313 1.000 523.150 9.6980 9. 87A 3 -1.79 30.6255 30.0670 1.86A 31 A 1.000 523.150 10.3581 10.5228 -1.57 32.7913 32.2237 1 .76A 315 1.000 523.150 10.A16A 1 0 . 5 6 A 5 -1.57 33.0072 3 2 . A 3 00 1.78A 316 1.000 523.150 1 1 . 7 1 A 8 11.0213 -.90 37.760 8 37.3160 1 .19

NP - 112 , DN RMS PC T • . 90 2 » DNTRNDPCT . 0 A 1 , pmeanpct .631

60

Table 6 Cont i nued

HYDROGEN SULFIDE PVT DATA VS. EONSTATE(l)REAMER, ( 2 ) l E WI S, (3>RAU, ( A ) STR A TY

ID PN WT t,k *01 / L CALCD D, PC T P » M P A CAICD Pf’CT1 317 .001 360.928 17.7983 17.92A1 -.70 10.5835 10.1B6A 3.901 31 e .001 360 .928 16.8615 1 7 , 003 A -.83 6 . 2 ie 6 7 , 9 5 A 9 3.311 31 9 .001 360.928 A . AA96 A . 2 90 A 3.71 7 . 1 1 5 A 7.1952 -1.111 320 .001 360.928 A.00A6 3 • 8 A 77 A. 08 6.8396 6 . 9 A 68 -1 .5A1 321 .001 366. A63 17.7983 17, 815 A -.10 12.7691 12.7102 . A 61 322 .001 366 .A83 16.8615 16.8887 -.16 10.20A2 1 0 . 1 A 6 5 .571 323 .001 366. A83 16.0185 16.0339 -.10 8.7701 8.7508 .221 3 2 A .001 366. A83 5.7209 5.A8AO A. 32 7.9565 8.0116 -.691 325 .001 366. A83 5.0058 A. BA7A 3.27 7.7359 7.8016 - . 8 A

1 326 .001 366. A83 A. AA96 A. 3133 3.16 7 , A 5 3 2 7 . 5 3 A 9 -1.0 8

1 327 .001 366. A83 A . 00 A 6 3.8770 3.29 7.1A30 7 . 2 A 1

8

-1.361 328 .001 372.039 16.8615 16.87A3 -.08 12.3761 12.3AA9 .251 32 9 .001 372.039 16.0185 16.0210 -.02 10.6869 10.6829 .OA1 330 .001 372.039 1A.5622 1 A , A 65 3 .67 9.1700 9.2229 -.571 331 .001 372.039 1 3 . 3 A 8 7 13.6959 -2.53 8 . 8 80 A e . 8088 .81l 332 .001 372.039 8.0092 7. A922 6.90 8.7563 8 . 78 A6 -.321 333 .001 372.039 6.67AA 6.5501 1.90 8.6598 8.67ee -.221 33 A .001 372.039 5.7209 5.6898 .55 8 « A 5 99 8.A696 -.111 33 5 .001 372.039 5.0058 A.9AA5 1. 2 A 8.1565 8.1871 -.371 336 .001 372.039 A.AA96 A. 3509 2.27 7.7980 7.8659 -.861 337 .001 372.039 A . 00 A 6 3.9070 2.50 7.AA63 7.5305 1.121 33 * .001 377. 59A 16.0185 16.0227 -.03 12.6312 12.6233 .061 339 .001 377. 59A 1 A, 5622 1A . 5052 .39 10.7282 10.7735 -. A21 3 A 0 .001 377. 59A 1 3 . 3 A 8 7 13.306A .32 10.0801 10.0952 -.151 3 A 1 .001 377. 59A 1 1 • A A 1 8 11.5511 -.95 9.7216 9.7096 .121 3 A 2 .001 377. 59A 10.0115 9.3513 1.63 9.5768 9.5883 -.121 3A3 .001 377. 59A 8.0092 7 . 8 A A 8 2. 10 9.A113 9 , A 3 0 1 -.201 3 A A .001 377. 59A 6.67AA 6.6732 .02 9.211 A 9.2117 -.001 3 A 5 .001 377. 59A 5.7209 5 . 6 A 16 1 . A

1

8 . 8 60

A

6.9131 -.371 3 A 6 .001 377. 59A 5.0058 A. 9023 2.11 8.5012 8.5632 -.721 3 A 7 .001 377. 59A A . A A96 A . 3 A A 7 2. A1 8.1062 8.1902 -1.001 3 A 8 .001 377. 59A A . OOA 6 3.908C 2 . A 7 7.7221 7 . 81 AC -1.191 3 A 9 .001 383.150 1 A . 5622 1A .535 5 .18 12.3071 12 .33A9 -.221 350 .001 383.150 13 . 3 A 8 7 13.3370 .09 11.3901 11.3966 -.061 351 .001 383.1 50 11 . AA1

8

11.6761 -2.01 10.7627 10. 70AA .55

1 352 .001 383.150 10.0115 10.0685 -.57 1 0 , A 2 A 9 1 0 . A 1 A 8 .10

1 353 .001 383.150 8.0092 e.lA20 -1.63 10.0939 10.0682 .26

1 3 5 A .001 383.150 6.67AA 6.6657 -.17 9. 735

A

9.7317 .OA

1 355 .001 383.150 5.7209 5. 6A27 1.39 9.3079 9 , 3 A 7 2 - . A 2

1 356 .001 383.150 5.0058 A. 9202 1 . 7 A 8.8736 8.9323 -.66

1 357 .001 383.150 A , AA96 A .3690 1.85 8 . A 3 9 2 8.5091 -.82

1 358 .001 383.150 A.00A6 3.9323 1.8A 8.0186 8.0933 -.92

1 359 .001 388.706 1 3 . 3 A 8 7 13. 5A39 — 1 . A A 12.8587 12.7070 1.19

1 360 .001 388.706 11 . A A 1

8

11.7979 -3.02 11 .BA52 11.70A3 1 .20

1 361 .001 388.706 10.0115 10.2187 -2.03 11.3005 11 .2A0A , 5 A

1 362 .001 3 68.706 0.0092 8.0178 -.11 10.7007 10.6982 .02

1 363 .001 388.706 6 . 6 7 A A 6.5A9A 1.91 10.1905 10 . 2 A 3 2 -.52

1 36 A .001 388.706 5.7209 5.5755 2.61 9.6871 9 . 77 A 2 -.89

1 365 .001 388.706 5.0058 A, 8803 2,57 9.1976 9.2958 -1.06

1 366 .001 388.706 A , AA96 A.A22A .61 8.7977 8 . 82 3 A -.29

1 367 .001 388.706 A . 00 A 6 3.9198 2.16 8.2737 8 . 3690 -1. 1A

1 368 .001- 39A.261 11.AA18 11.7618 -2.72 12 .879A 12.7077 1.35

1 369 .001 39A.261 10.0115 10.3012 -2.81 12.1830 12.0653 .93

1 370 .001 39A.261 8.0092 6.1153 -1.31 11.3626 11 .3226 .35

1 371 .001 3 9 A . 2 61 6.67AA 6.6211 .80 10.7213 10. 7A83 -.25

1 372 .001 39A.261 5.7209 5.5928 2.29 10.1077 1 0 . 1 9 5 A -.86

1 373 .001 39A.261 5.0056 A. 9081 1.99 9.5699 9.65 AA -.87

1 37 A .001 39A.261 A.AA96 A. 3717 1.78 9.0528 9.1336 - . 89

1 375 .001 39A.261 A.00A6 3.93A1 1.79 8 . 5 56 A 8 . 6 A 1 3 -.99

HP 59, DNRMSPCT • 2 .136, DNTPNDPCT - .898, P ME AN PC T • • 70A

61

Table 6 Cont i nued

HYDROGEN SULEIDE PVT DATA VS. EONSTATE(l)REAHER# { 2 REWIS, ( 3 )RAU, (A)STRATY

ID PN WT T,K NOl/l CALCD D.PCT P, MPA CALCD P# °C T

2 376 .001 373.000 1*.0000 13.7151 2.08 9.1193 9.2150 - 1 . 0 *

2 377 .001 373.000 15.0000 15 . 2*66 -1.62 10.0312 9.8055 2.302 376 .001 373.000 16.0000 16.0967 -.60 11 . 1*58 10.9888 1 , * 3

2 37 9 .001 373.000 17.0000 17 . 1*15 -.83 13. *762 13 . 08*2 3.002 300 .001 373.000 18.0000 16.1003 -.55 16.9213 16 .

*

89 * 2.622 381 .001 373.000 19.0000 19 . 1*08 -. 7 * 22.5955 21 .6877 *.192 362 .001 373.000 20.0000 20.0917 -.*6 30.0935 29.2578 2 .66

2 383 .001 373.000 21.0000 21.0352 -.17 * 0 . 327 * 39.8677 1.102 38 * .001 373.000 22.0000 21.9770 .10 5*. 0062 5*. 3900 -.712 385 .001 373.000 23.0000 22 . 9*21 .25 72 ,** 7 * 73.7155 -1.722 386 .001 393.000 8.0000 6.2872 27 . 2 * 10 .*365 11.1780 -6.6 3

2 3 B 7 .001 393.000 9.0000 6.9023 30 . 39 10 . 7*05 11.5220 -6.782 388 .001 393.000 10.0000 8.1951 22.02 11 . 2*71 11.8738 -5.282 389 .001 393.000 11.0000 9.6698 13.76 11.7537 12.2763 -*.262 390 .001 393.000 12.0000 10 . 963 * 9. *5 12.2603 12.7702 -3.992 391 .001 393.000 13.0000 12 . 6 * 6 * 2.80 13.1723 13 .

*

32 * -1 . 9 *

2 392 .001 393.000 1*.0000 13 . 818 * 1.31 1 * . 1 85 5 1 * . 3 8 8 * -1 .*12 393 .001 393.000 15.0000 1*. 8102 1.28 15.5027 15.8222 -2.022 39 * .001 393.000 16.0000 16.0192 -.12 18.0359 17.9851 .282 395 .001 393.000 17.0000 16.9672 .19 21.0756 21.2018 -.602 396 .001 393.000 18.0000 16.0111 -.06 25.9392 25.8773 . 2 *

2 397 .001 393.000 19.0000 19 . 0 * 1 * -.22 32.8293 32 . 50*6 1.002 398 .001 393.000 20.0000 20.0161 -.08 * 1 . 8*72 * 1.6751 .*12 399 .001 393.000 21.0000 20 . 99*0 .03 5*. 0062 5*. 0926 -.162 *00 .001 393.000 22.0000 21 . 920 * .36 69.1037 70.5880 -2.102 *01 .001 393.000 23.0000 22.9192 .35 90.1792 92 .1332 - 2.122 *02 .001 * 13.000 8.0000 7 . 68*1 *.11 13.1723 13 . 39*1 -1.662 *03 .001 * 13.000 9.0000 8. *103 7 . 01 13.6789 1* . 0909 -2.922 * 0 * .001 * 13.000 10.0000 9 . 68*2 3.26 1* .

5

90 8 1 *. 83*8 -1 . 6 *

2 *05 .001 * 13.000 11.0000 10.6835 2.96 15 .

*

01 * 15 . 68*8 -1.812 *06 .001 * 13.000 12.0000 11 . 6*37 3.06 16.3133 16.6979 -2.302 *07 .001 * 13.000 13.0000 12.6823 2.50 17.5292 17.9682 - 2 .**2 *08 .001 * 13.000 1* .0000 13.9036 .69 19 .

*

5 ** 19.6378 -.932 *09 .001 * 13.000 15.0000 15.0312 -.21 21.9875 21 . 90 ** .382 *10 .001 * 13.000 16.0000 16 . 05*1 -. 3 * 25.2299 25.0302 .802 *11 .001 * 13.000 17.0000 17.0070 -. 0 * 29 . 38*3 29 . 3*90 .122 *12 .001 * 13.000 18.0000 18.0273 -.15 35. *638 35 . 27*9 . 5 *

2 *13 .001 * 13.000 19.0000 19.0708 -.37 * 3.9751 * 3.3112 1.532 * 1 * .001 * 13.000 20.0000 20.0119 -.06 5 * .2089 5*. 0621 .272 *15 .001 * 13.000 21.0000 20 . 971 * . 1 * 67 . 786 * 68 . 2*65 -.672 *16 .001 * 13.000 22.0000 21.9129 .*0 8 * .9103 86.71 31 -2.082 *17 .001 * 13.000 23.0000 22.8610 .61 106.7966 110. *532 - 3.312 *18 .001 * 33.000 8.0000 8 . 026 * -.33 15 . 60*1 15 . 576 * .182 *1 9 .001 * 33.000 9.0000 8.9806 .22 16.6173 16 . 638 * -.132 *20 .001 * 33.000 10.0000 10.1176 -1.16 17 . 93*5 17.7897 .812 *21 .001 * 33.000 11.0000 11.0336 -.30 19 . 150 * 19.1027 .252 *22 .001 * 33.000 12.0000 12.0721 -.60 20.7716 20 . 6*86 .602 *23 .001 * 33.000 13.0000 13 . 21*9 - 1.63 23.0000 22 . 536 * 2.062 * 2 * .001 * 33.000 1*.0000 1 * . 2 1

9

8 -1.55 25.5339 2*. 9227 2. *52 *25 .001 * 33.000 15.0000 15.0136 -.09 28.0670 28.0190 .172 *26 .001 * 33.000 16.0000 15.9828 .11 32.0187 32.0989 -.252 *27 .001 * 33.000 17.0000 17 . 0*59 -.27 37 . 79*2 37 . 507 * .762 *28 .001 * 33.000 18.0000 18.0265 -.15 ** .8870 **.6689 .*92 *29 .001 * 33.000 19.0000 19 . 038 * -.20 5 * .5129 5*. 0979 .772 *30 .001 * 33.000 20. 0000 20.0113 -.06 66.5705 66. *116 . 2 *

2 *31 .001 * 33.000 21.0000 20 . 9 e *9 .07 82.0733 82 . 3**1 -.332 *32 .001 * 33.000 22.0000 21.8875 .51 100 . 210 * 102.7608 -2. *8

62

Table 6 Continued

HYDROGEN SULFIDE PVT DATA VS . EONSTATE( l ) PEAME ?, ( 2 ) LEWIS » ( 3 ) RAU # (*)STRATY

ID PN WT T,K MOl/L C ALCD D,PCT P » M P A CALCD P » PCT2 *33 .001 * 33.000 23.0000 22.7968 .89 122.9072 128.6723 - * . * 37 * 3 * .001 * 53.000 8.0000 8.2136 -2.60 10.0359 17.7356 1.69? *35 .001 * 53.000 9.0000 9. *535 -*.80 19.8597 19.1707 3 .592 *36 .001 * 53.000 10.0000 10.2589 -2.52 21.1769 20.7386 2.112 *37 .001 * 53.000 11.0000 11 . 2*37 -2.17 23.0008 22.5239 2.122 *33 .001 *53 .000 12.0000 12.1368 -1.13 2*. 9260 2 * .6108 1.282 *39 .001 * 53.000 13.0000 13.1555 -1.18 27 . 560 * 27.1215 1.622 ** 0 .001 * 53.000 1 * .0000 1 * . 0 7 7 8 -.55 30. *988 30.2263 .902 **1 .001 * 53.000 15.0000 15.0899 -.60 3 * . 551

8

3 *. 1*96 1.132 ** 2 .001 * 53.000 16.0000 16.0592 -.37 39.5168 39 . 177 * .872 ** 3 .001 * 53.000 17.0000 17.0725 -.*2 * 6 . 20*2 *5.6657 1.182 *** .001 * 53.000 18.0000 18.0378 -.21 5*. *115 5*. 0503 .672 ** 5 .001 * 53.000 19.0000 19.0322 -.17 65.2533 6*. 8577 .612 **fc .001 * 53.000 20.0000 20.0072 -. 0 * 78 .8309 78 . 718 * . 1 *

2 ** 7 .001 * 53.000 21.0000 20.9112 .*2 9*. 6375 96.3810 -1.81? ** 8 .001 * 53.000 22.0000 21.7980 .93 113.7880 118.7282 -* .162 ** 9 .001 * 53.000 23.0000 22 . 7**7 1.12 139.0179 1 * 6 . 788 * -5.292 *50 .001 * 73.000 8.0000 8.2761 - 3 . 3 * 20.3663 19.8773 2 .*62 *51 .001 * 73.000 9.0000 9.2092 - 2.27 22.0889 21.6905 1 . 8 *

2 *52 .001 * 73.000 10.0000 1 C . 2955 -2.87 2*. 3180 23.6812 2.692 *53 .001 * 73.000 11.0000 11.3231 - 2 . e 5 26 . 7*98 25 . 9*51 3.102 *5 * .001 * 73.000 12 .0000 12 . 2 * 1 * - 1.97 29.2829 28.5780 2 .*72 *55 .001 * 73.000 13.0000 13.2017 -1.53 32 .

*

2*0 31 . 71*9 2 . 2 *

2 *56 .001 * 73.000 1* .0000 1*. 0537 -.38 35.7677 35.5388 . 6 *

2 *57 . 0 C 1 * 73.000 15.0000 1* . 9806 .00 * 0.2260 * 0.2865 -.152 *5 9 .001 * 73.000 16.0000 16.0822 -.51 * 6 .8122 * 6.2563 1 .20

2 *5 9 .001 * 73.000 17.0000 17.0695 -. *1 5*. *115 53.8158 1.11? *60 .001 * 73.000 18.0000 18.0203 -.11 63.6321 63. *127 .35

2 *61 .001 * 73.000 19.0000 I 8.9705 .16 75 .1 83 2 75.5856 -.53

2 *62 .001 * 73.000 20.0000 19 . 9*75 .26 90 .0779 90.9783 -.99

2 *63 .001 * 73.000 21.0000 20 . 91 ** . *1 108.5191 110 . 35*6 - 1 . 66

2 * 6 * .001 * 73.000 22.0000 21.7870 .98 128.9867 13*. 6131 -*.10

2 *65 .001 * 73.000 23.0000 22.6830 l .*0 1 5 * .5206 16 *. 9 CC 5 - 6 . 2 *

2 *66 .001 * 93.000 8.0000 8. *165 -* .95 22 .8995 22 . 00*8 * .07

2 *67 .001 * 93.000 9.0000 9. **02 -*.66 25.2299 2*. 1998 *.26

2 *68 .001 * 93.000 10.0000 10. *339 -*.16 27.7631 26.6175 *.30

2 *6 9 .001 * 93.000 11 .0000 11. *717 -*.11 30.8028 29.3639 *.90

2 *70 .001 * 93 .000 12.0000 12.3923 -3.17 33 . 9*39 32 . 5*61 * .29

2 *71 .001 * 93.000 13.0000 13.2321 - 1.75 37.2876 36.3110 2.69

2 *72 .001 * 93.000 1* .0000 1 *

.

19 ** -1.37 * 1 . 0*72 * 0.8535 2. *3

2 *73 .001 * 93.000 15.0000 15 . 1*27 -. 9 * *7.3188 **> .*229 1.93

2 * 7 * .001 * 93.000 16.0000 16.0871 -. 5 * 5*. 0062 53.3293 1 .27

2 *75 .001 * 93.000 17.0000 17.0166 -.10 62.1122 61.9523 . 2 o

2 *76 .001 * 93.000 19.0000 17.9663 .19 72 . 3*61 72.7513 -.56

2 *77 .001 * 93.000 19.0000 19 . 003 * -.02 86 .3289 86.2777 .06

2 *78 .001 * 93.000 20.0000 19.9979 .01 103 . 1*89 103.1086 -. 0 *

2 *79 .001 * 93.000 21 .0000 20 . 893 * .51 121.7927 12*. 2626 -1 . 9 P

2 *80 .001 * 93.000 22.0000 21.7030 1.37 1 * 2.0577 150 .

*

1*6 -5.56

2 *81 .001 * 93.000 23.0000 22 . 6*99 1.55 170.6313 182 . 700 * -6.61

so * 106 » D NR M S PC T - 5 • 0 95 » DNTRNDPC T » . 716 * P M E A N PC T - 1 . 9*6

63

Table 6 Conti nued

hvdptgen sulfide pvt data vs . eqnstate( l ) REAMER * ( 2 ) L E W I S » ( 3 ) R A

U

» (

4

) STR ATY

ID PN WT T » K MGL/L C ALCD D » °C T P>MPA C ALCD P » PC T

3 48 2 .001 380.400 14 . 0540 15.3680 -3.34 12 . 50 C 0 11 . 8546 5.443 483 .001 390.400 14.8436 14.9783 -.90 15.0000 14.7863 1.433 404 .001 398.600 14.8409 14.9897 -.94 17.5000 17.2266 1.593 485 .001 408.600 14.8361 14.7609 .51 20.0000 20.1722 -.853 486 .001 416.900 14 . ei 96 14.7819 .26 22.5000 22.6001 -.443 467 .001 426.600 14 . 8098 14 .

6

5 7 e 1.04 25.0000 25.4579 -1.803 480 .001 435.600 14.8069 14.6211 1 .27 27.5000 28.1283 -2.233 48 9 .001 443.900 14.7942 14.6463 1.01 30.0000 30.5533 - 1.813 490 .001 451.600 14.7793 14.7099 .47 32.5000 32.7840 -.873 491 .001 460.400 14.7667 14.6097 .52 35.0000 35.3424 -.973 492 .001 477.900 14.7578 14.6632 .64 40.0000 40.4890 -1.213 493 .001 400.100 14.7458 14.5754 1.17 42 . 5000 43.4443 - 2.173 494 .001 495.900 14.7295 14.6163 .76 45.0000 45.6543 -1.433 495 .001 506.900 14.7332 14.5065 1.56 47.5000 48.9228 - 2.913 496 .001 514.900 14.7169 14.5397 1.22 50.0000 51.1729 -2.293 497 .001 532.100 14.7096 14.5493 1.10 55 . 0000 56.1755 - 2.093 498 .001 552.900 14.6683 14.4288 1.66 60.0000 61.9335 - 3.123 499 .001 522.900 14,6994 14.5698 .89 52 . *000 53.4023 - 1.693 500 .001 54 1.900 14.6060 14.5084 1.22 57.5000 58.8661 -2.3 2

3 501 .001 389.900 9.9206 12.6319 - 21.46 12.5000 11 . 3898 9.753 50 ? .001 409.600 9.9118 10.8737 - 0.05 15.0000 14.2691 5.123 503 .001 4 2 . 600 9.9020 10.3129 - 3.98 17.5000 17.0305 2.763 504 .001 444.400 9.8922 10.3505 -4.43 20.0000 19.3136 3.553 505 .001 461.900 9.8824 10.2303 - 3.48 22 .5000 21.8314 3.063 506 .001 480.100 9.0736 10.1203 -2 .44 25 .OOCO 24.4393 2.293 507 .001 490.100 9.8619 10.0501 - 1.07 27.5000 26.9981 l .«63 508 .001 515.900 9 .

8

5 C 3 10.0093 -1.59 30.0000 29.5133 1 .653 *09 .001 533.900 9.0542 9.9710 - 1.17 32.5000 32.0953 1.263 510 .001 552.500 9.8416 9.9199 -.79 35.9000 34.6967 .873 511 .001 570.100 9.0280 9.9134 -.86 37,5000 37 . 136 C .903 512 .001 588.500 9.0135 9.0048 -.72 40.0000 39.6674 .843 513 .001 606.900 9.8020 9.8620 -.61 42 . 5000 42.1957 .72

3 514 .001 624.900 9 . 805 e 9.8539 -.49 45.0000 44.7366 .593 515 .001 643.900 9.7991 9.8242 -.25 47.5000 47.3525 .313 516 .001 663.900 9.7847 9.7773 .08 50.0000 50.0469 -.093 517 .001 701.900 9.7723 9.7416 .31 55.0000 55.2191 -.403 510 .001 740.400 9.7542 9.7078 .48 60.0000 60.3694 -.613 519 .001 402.100 7.2051 8.6120 - 16.34 12.5000 11 . 767 ? 6.233 520 .001 428.400 7.2062 7.9204 - 9.02 15.0000 14.3028 4.873 52 1 .001 454.400 7.2077 7.7284 - 6.74 17.5000 16.7604 4.413 522 .001 480 .100 7.2098 7.6621 -5.90 20.0000 19.1586 4.393 523 .001 507.400 7 .

1

870 7.5639 - 4.98 22.5000 21.6230 4.063 524 .001 535.400 7.1839 7.4825 - 3 .99 25.0000 24.1626 3.473 525 .001 562.400 7.1927 7.4593 - 3.57 27.5000 26.6290 3.273 526 .001 589.400 7.1798 7.4459 -3.57 30.0000 29.0080 3.423 527 .001 617.100 7.1762 7.4231 - 3.33 32.5000 31.4631 3.303 52 8 .001 645.400 7.1746 7.3958 -2.99 35.0000 33.9652 3.053 529 .001 672.900 7.1726 7.3900 - 2.94 37.5000 36.3012 3.003 530 .001 702.100 7.1705 7.3596 -2.57 40.0000 38.9345 2.743 53 1 .001 730.900 7.1690 7 . 341 * - 2.35 42.5000 41.4436 2.553 532 .001 759.900 7.1674 7.3250 -2.15 45.0000 43.9594 2.373 533 .001 390.900 4.8900 5.0177 - 15.95 10.0000 9.3436 7.033 534 .001 435.600 4.8924 5.1979 -5.8 8 12.5000 12.0526 3.713 535 .001 478.900 4 .8852 5.1039 - 4.28 15.0000 14.5392 3.173 536 .001 523.400 4.8852 5.0538 -3.34 17.5000 17.0369 2.723 537 .001 568.100 4 . 882 8 5.0332 - 2.99 20.0000 19.4920 2.613 53 e .001 613.600 4.8733 5.0164 -2.85 22.5000 21.9263 2.62

64

Ta bl e 6 Continued

HYDRDGF* SULFIDE PVT DATA VS. EONSTATE(DREADER# <2»LEWIS* (3JRAU, <4>STRATY

ID P N WT T»K M 0L / L c alcd D, PC T P,MPA C ALCD P, =>CT

3 5 3 <5 .0C1 663.600 4.8709 4.9568 -1.73 25.0000 24.5966 1.643 5 0 .001 711.600 4 . 8662 4.9369 -1 .43 27.50C0 27.1717 1.393 541 .001 759.100 4.8614 4.9287 -1.37 30.0000 29.5968 1.363 542 .001 361.900 3.9293 4.341C -9.48 7.2000 6.9475 3.633 543 .001 365.900 3.0120 3.3915 -11.19 7.5000 6.9631 7 .713 544 .001 465.100 3.0184 3. 1779 -5.02 10.0000 9.5966 4.203 545 .001 544.600 3.0120 3.1351 -3.92 12.5000 12.0667 3.593 546 .001 628.700 3.0075 3.0944 -2.81 15.0000 14.6065 2.693 547 .001 715.300 3.0021 3.0625 -1.97 17.5000 17.1660 1.953 54 3 .001 342.300 3.0711 19.2100 -84.28 6.0000 5.3725 11.68

NP » 67, DNRMSPCT -11. 816, DNTPNDPCT - -4.044, PME ANPCT » 2.781

N P » 316, DNRMSPCT « . 723, DNTRNDPCT « -.061, PMEANPCT 1.520

65

Table 7. Comparisons of ideal d as functions for hydroyen sulfide.

HYDROGEN SULFIDE IDEAL GAS, J OUL E S , HOL E S , K E L VI N

S

(l)BAEHR, ( 2 ) J AN A F

.

ID T , K HZ-HZZ C ALCD PONT sz CALCD PONT C PZ CALCD PCNT1 50.0 16 AA .6 16 A 5.0 -.03 157 . 5 A 3 157.560 -.01 33.27 33.26 .021 100.0 3308 . A 3308.2 .01 180.616 180.609 .00 33.29 33.28 .021 150.0 4973.2 4973.3 -.00 1

9

A . 1 10 194.110 .00 33.31 33.32 -.021 190.0 5973.3 5973 .

A

-.00 200 '. 188 200.188 .00 33.37 33.36 .011 200.0 66 A 1 ,1 66 A 1 . 3 -.00 703.705 203.706 -.00 33.43 33.43 .021 220.0 7310.7 7310.

7

-.00 206.898 206.896 .00 33.53 33.53 .011 24 C .0 79 P 2.9 7992.6 .00 209.825 209.819 .00 33.67 33.67 .001 2 5 0.0 9657.9 8657.6 .00 212 .527 212.520 .00 3 3. 84 33 . 84 -.011 2 6 C . 0 9226.

5

9336.3 .00 21^.038 215.035 .00 34.03 34.04 -.0 2

1 300 . 0 10019.3 10019.3 0 . 00 217.391 217.391 0 .00 3 A . 26 34 .26 -.021 320.0 10706.9 1 C 707.0 -.00 219.611 219.610 .00 34.51 34.51 -.011 3 A 0 .

0

11399.6 11399.8 -.00 221 . 71 A 221.710 .00 34.77 34.77 -.011 360.0 12097.7 12098.0 -.00 223.710 223.705 .00 35 . 05 35.05 .001 380.0 12801.7 12801.9 -.00 225 . 61 A 225.608 .00 35.34 35.34 .011 A 0 0 .

0

13511.7 13511.7 -.00 227 . A 35 227.428 .00 35.65 35.64 .011 A 2 0 .

0

1 A 227.8 1 A 227.7 .00 229.181 229.175 .00 35.96 35.95 .021 A A 0 .

0

1 A 950.0 1 A 9 A 9.9 .00 230.860 230.855 .00 36.28 36.27 .021 A 60.0 15678.9 15678.6 .00 232 . A 73 232 . 47 A -.00 36.60 36.60 .011 A 8 0 .

0

16 A 1 A .0 16 A 13.9 .00 23 A . 0 A 5 234.039 .00 36.94 36.93 .011 500.0 17156.1 17155.9 .00 235.558 235.553 .00 37.27 37.27 .001 520.0 17905.1 1 790 A . 8 .00 237,030 237.022 .00 37 . 62 37.62 -.001 5 A 0.

0

18660.6 18660.6 .00 238 .452 238.448 .00 37.96 37.97 -.001 560.0 19 A 23.5 19 A 23.4 .00 239.840 239.835 .00 38.32 38.32 -.011 580.0 20193 .

A

20193 .

A

-.00 2 A 1 .187 2 A 1 . 1 86 .00 38.67 38.68 -.011 600.0 20970.5 20970.5 -.00 242.509 2 42 . 503 .00 39 . 03 39.04 -.011 620.0 2 1

7

5 A ,6 2 175 A . 9 -.00 2 A 3.789 243.789 .00 39.39 39.40 -.011 6 A 0 .

0

225 A 6.3 2 2 5 A 6 .

5

-.00 245 . 0 A 5 2 A 5 . 0 A 6 -.00 39.76 39.76 -.011 660.0 233 A 5.2 2 3 3 A 5 . A -.00 2 A 6.275 2 A 6.275 .00 40.12 40.13 -.011 680.0 2 A 151.0 2 A 151 .

5

-.00 2 A 7 . A 81 2 A 7 . A 78 .00 40 . 49 40.49 -.011 700.0 2 A 96 A.A 2 A 95 5 « 0 -.00 2 A 8 .662 248.657 .00 40.85 40.85 -.011 720.0 2 578 A .

8

25785.6 -.oc 249.817 249.813 .00 41.21 41.22 -.001 7 A 0 .

0

26613.0 26613.6 -.00 250 .948 250.947 .00 41.58 41 .58 -.001 760.0 27 AA 7.9 27 AA 8.

7

-.00 252.062 252.061 .00 41.94 41.93 .001 780.0 28290.2 28290.

9

-.00 253.160 253.155 .00 42.29 42.29 .011 800.0 291 A 0.0 291 A 0.3 -.00 254.232 254.230 .00 42.65 42.64 .011 820.0 29996.7 29996.7 .00 255 .288 255.287 .00 43.00 42.99 .011 8 A 0 .

0

30859.6 30860.0 -.00 256.328 256.327 .00 A 3 . 35 43.34 .011 860.0 31730.2 31730.2 -.00 257.359 257.351 .00 43.69 43.68 .011 980.0 32607.1 32607.2 -.00 258.365 258.359 .00 44.03 44.02 .011 000.0 3 3 A 91 .

1

33 A 91.0 .00 259 . 35 A 259.352 .00 44.36 44 .35 .011 020.0 3 A 381 . 5 3 A 381 •

3

.00 260.335 260.331 .00 44.69 44.68 .011 060.0 361 82 .0 36181.5 .00 262 . 2 A 8 262.246 .00 45.32 45.32 .001 1000.0 380 C7.2 38006.8 .00 264.110 264.109 .00 45.94 45.94 -.001 1050.0 A 0323.2 A 0322.5 .00 266.372 266.368 .00 46.68 46.68 -.011 1100.0 A 267 A .

1

A 2 67 A . A -.00 268.558 268.556 .00 47 . 38 47.39 -.021 1150.0 A 5059 .A A 5060.5 -.00 270.679 270.677 .00 48.04 46.05 -.021 1200.0 A 7 A 77 .

5

A 7 A 78.

8

-.00 272 . 7 A 1 272.736 .00 48.67 48.68 -.021 1300.0 52 A 03.5 52 A 0 A .3 -.00 276.682 276.678 .00 49.82 49.81 .03•> 200.0 66 A 6.

9

66 A 1 .3 .09 191.932 203 . 7 C 6 - 6.13 33.38 33.43 -.14Z 300.0 10019.3 10019.3 0.00 205.859 217.391 - 5.60 34.21 34 .26 -.16z AOO.O 13508.7 13511.7 -.02 215.886 227 . 42 « - 5.35 35.58 35 . 6 t -.17z 500.0 1 7

1

A A .5 17155.9 -.07 223 .993 235.553 - 5.16 37.19 37.27 -.21z 600.0 20952.0 20970.5 -.09 230.927 242.503 - 5.01 38.94 39.04 -.26z 700.0 2 A 925.3 2 A 965.0 -.12 237.063 248.657 -4.89 40.74 O • CD VJ1 -.28

66

Tabl e 8 Interpolated ideal gas functions for hydrogen sulfide.

HYDROGEN SULFIDE IDEAL GAS, J OUL E S , H 0 L E S , K E L V IN

S

T,K EZ-EZZ HZ-HZZ SZ CVZ CPZ180.0 4476.8 5973.4 200.188 25.05 33.36190.0 4727.4 6307.2 201.992 25.08 33.39200.0 4976.4 6641.3 203.706 25.11 33.43210.0 5229.7 6975.8 205.338 25.16 33.47220.0 5481.6 7310.7 206.896 25.21 33.53230.0 5734.0 7646.3 208.388 25.28 33.592 A 0 .

0

5987.2 7992.6 209.819 25.35 33.67250.0 6241.1 8319.7 211.195 25.43 33.75260.0 6495.8 8657.6 212.520 25.52 33.84270.0 6751.6 8996.5 213.799 25.62 33.93290.0 7008.3 9336.3 215.035 25.72 34.04290.0 7266.0 9677.3 216.231 25.83 34. 15300.0 7525.0 10019.3 217.391 25.95 34.26310.0 7785.0 10362.5 218.516 26.07 34.38320.0 8046.4 10707.0 219.610 26.20 34.51330.0 8309.0 11052.8 220.674 26.32 34.64340.0 8572.9 11399.8 221 .710 26.46 34.773 50.0 8838.1 11748.2 222.720 26.60 34.91360.0 9104.8 12098.0 223.705 26.74 35.05370.0 9372.9 12449.2 224.668 26.88 35.19390.0 9642.4 12801.9 225.608 27.03 35.34390.0 9913.4 13156.1 226.528 27.18 35.49400.0 10185.9 13511.7 227.428 27.33 35.64410.0 10460.0 13868.9 228.310 27.48 35.80420.0 10735.6 14227.7 229.175 27.64 35.95430.0 11012.7 14598.0 230.023 27.60 36.11440.0 11291.5 14949.9 230.855 27.96 36.27450.0 11571.9 15313.4 231.672 28.12 36. 43460.0 11853.9 15678.6 232.474 28.28 36.60470.0 12137.6 16045.4 233.263 28.45 36.764 fiO.O 12422.9 16413.9 234.039 28.62 36.93490.0 12709.9 16794.0 234.802 28.79 37.10500.0 1

2

Q 98 .6 17155.9 235.553 2 8.96 37.27510.0 13299,1 17529.5 236.293 29.13 37.44520.0 13581.2 17904.8 237 .022 29.30 37.62530.0 13875.1 19281.8 237.740 29. <,8 37.79540.0 14170.7 18660.6 238.448 29.65 37.97540.0 14468.1 19041.1 239,14'- 29. P3 38.14560.0 14767.3 19423.4 239.835 30.01 38.32570.0 15068.3 19807.5 240.515 30.18 38.50590.0 15371.0 20193.4 241.186 30.36 38.68590.0 15675.5 20591.1 241.849 30.54 3 8.86

600 .0 15981.8 20970.5 242.503 30.72 39.04610.0 16290.0 21361.8 243.150 30.90 39.22620.0 16599.9 21754.9 243.789 31 .08 39.40630.0 16911.7 22149.8 244.421 31.27 39.58

640.0 17225.2 22546.5 245.046 31.45 39.76

650.0 17540.6 22945.0 245.664 31.63 39.94

660.0 17857.8 23345.4 246.275 31.81 40.13

670.0 18176.8 23747.6 246.880 31.99 40.31

680.0 18497.7 24151.5 247.478 32.18 40.49

690.0 18820.3 24557.3 248.071 32.36 40.67

700.0 19144.8 24965.0 248.657 32.54 40.85

710.0 19471.1 25374.4 249.238 32.72 41.03

720.0 19799.2 25785.6 249.813 3 2.90 41.22

730.0 20129.1 26198.7 250.383 33.08 *1.40

740.0 20460.8 26613.6 250.947 33.26 41.58

750.0 20794.3 27030.2 251.507 33.44 41.76

67

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CM ro ro ro ro ro O' CM «H O' O' O' O’ O' CM rH 0 00 O CM -h 0 m in OD CP CM rH 0 O' GO HD ao CM fH fH O O' HD PJ rH rH -H rH O P-O P- p- p- P- r*- F*- r^- r- n- 6*- h: H5 HD HD P~ p*» pw HD p*- HD H) Pr P'- p*- HD HD HD HD P^ P^ P^ HD HD HD P- P- r- f- P- H>S.

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ro ro m rn ro ro O CP rp rp rp O rpro ro CO ro ro ro ro a O' O' O' O' O' O' O' O' O’ O' O' O' O’ in in n m in in in CD ao <r> OD ao ao ao O O O O 0 O O in in in m in m min in n n n in n 0 O 0 0 O O O HD HD HD HD HD HD HD N p- p- p- Pt O' O' O' O' O' O O' <M PJ CM PJ PJ CM pj p- p- p^ p- Pr p- p-m m m in n n in H >—

4

rH -H -4 r-4 r-H HD HD nO HD HD HD >0 P- P- P- p^ p^ O' O' O' O O' CP O' CM nj CM PJ PJ PJ CM p» p- p- p^ P-CM CM CM CM rvi <M CM ro ro ro ro CO CO CO ro co CO CO CO ro ro co CO ro co CO CO <0 ro ro ro CO CO ro ro O' O' O' o- O’ O’ O' 0 0- O' O’ O' O’ O’

68

Table 10. Calculated P(T) isochores of hydrogen sulfide.

HYDROGEN SULFIDE ISOCHORE AT .500 MOL/L

T P Z DP/DDK HP A MP4-L/M0L

27?. 065 .9999 ,88*03 1.73722 80.000 1.0373 .89110 1.8237288.000 1 . 0 7 A 5 . 8 97 A 8 1.9036296.000 1.1115 .90323 1.991730*. 000 1.1*81 . 908A5 2.0733312.000 1 . 1 8 A 5 .91321 2 .1536320.000 1.2207 .91758 2.2330328.000 1.2567 .92160 2.3115336.000 1.2925 .92532 2.389?3 A A . 000 1 .32 82 .92877 2 . A663352.000 1.3638 .93198 2.5*23360.000 1.3993 .93*98 2.6186368.000 l.A3*7 .93778 2 . 69 AA376.000 1 . A700 .9A0A1 2.76953 8 A . 000 1 . 5052 .9*288 2 . 8 A A3392.000 1 . 5A0* .9*521 2.9186AOO.OOO 1 . 575

A

. 9A7A0 2.9930A 08 . 000 1.6105 . 9A9A8 3.0669A 1 6 . 000 1 . 6A5A . 951 AA 3.1*06A2A. 000 1 .680A .95330 3.21*1'*32.000 1.7152 .95507 3.287*A AO. 000 1.7501 .95676 3.3605A A8 .000 1 . 73A9 .95836 3. *33*A56.000 1.8197 . 95988 3.5062A6A .000 1 . 8 5 A A .9613* 3 . 5 7°

5

A 72 . 000 1 .8891 . 96273 3 .6513A 80.000 1.9238 .96*06 3.7236A 38 . 000 1 .956A .9653* 3.7959A 96.000 1.9930 . 96656 3.86*050*. 000 2 .0276 .96773 3 .9*00512.000 2.0622 . 96886 A. 0120520. COO 2.0968 .9699* A. 083852P.OOO 2.1313 .97098 A. 1556536.000 2.1659 .97198 A .22735*A .000 2. 2C0A .9729* A. 298?552.000 2 .23AP .97387 A. 3705560.000 2.2693 .97*77 A . A A 1

9

568.000 2.3038 .97563 A .5133576.000 2.3382 .976*7 A. 58A75 8 A . 000 2.3727 .97727 A. 6560592.000 2. A071 .97805 A. 7272600.000 2 . AA15 .97881 A .798*608.000 2. A759 .9795* A. 8696

616.000 2.5103 .9802* A.9A076 2 A . 000 2. 5AA6 .98093 5.0117632.000 2.5790 .98159 5.08276 AO . 000 2 . 61 3 A .98223 5.15376*8.000 2.6*77 .98285 5.22A6656.000 2.6820 .983*6 5.295566A.000 2 .716* .98*05 5.366A672.000 2.7507 .98*62 5. A372

680. 000 2.7850 .98517 5.5080688.000 2.8193 .98571 5.5788696.000 2.8536 .9862* 5 .6*95

70* .000 2.8879 .98675 5.7202712.000 2.9222 .9872* 5.7909720.000 2.9565 .98772 5.8615

OO/DT DP/DT 0 2 p / 0 T2MOL /L /< MPA/K MP4 /K/K

-•2730E-02 .00*7* -.000008*-.256SE-02 .00*68 -.0000066- . 2A29E-C 2 .00*6* -.000005*- . 2 30 8 E -0 2 .00*60 -.00000*5-.2201E-02 .00*56 -.0000038-.2 106E-02 ,00 A 5

A

-.0000032-. 2020E-02 . 00*51 -.0000029-.19A3E-02 , 00 A A 9 -.000002*-.1P72E-02 , 00 A A 7 -.0000021-.1 807E-02 •00AA6 -.0000019-.17A7E-02 . 00 AAA -.0000017-.1691E-02 .00**3 -.0000015- .1 639E-02 • 00AA2 -.0000013-•1591E-02 . 00 A A 1 -.0000012-.15A6E-02 . OOAAO -.0000011-.150AE-02 .00*39 -.0000010-.1A6AE-02 .00*38 -.0000009-.1A27E-02 .00*38 -.0000009-.1 391E-02 .00*37 -.0000008-.1357E-02 .00*36 -.0000007-.1 326E-02 .00*36 -.0000006-.1295E-02 .00*35 -.0000006— . 1 266E-02 .00*35 -.0000005-.1 239E-02 .00*3* -.0000005-.1213E-P2 .00*3* -.0000005-.1188E-02 .00*3* -.000000*-.116AE-02 .00*33 -.000000*-.11A1E-02 .00*33 -.000000*-.1119E-02 .00*33 -.000000*-.1097E-02 .00*32 -.0000003-.1077E-0? . 00*32 -.0000003-.1058E-02 .00*32 -.0000003-.1039E-02 .00*32 -.0000003-.1021E-02 .00*31 -.0000003- . 1 00 3 E -0 2 .00*31 -.0000003-.9862E-03 .00*31 -.0000002- • 9699E-03 .00*31 -.0000002-.95*2 E -0 3 .00*31 -.0000002-.9390E-03 . 00*30 -.0000002-.92A2E-03 .00*30 -.0000002-•9100E-03 .00*30 -.0000002- . 8962 E-0 3 .00*30 -.0000002-.3828E-03 .00*30 -.0000002-. 8698E-03 .00*30 -.0000002-.8572E-03 .00*30 -.0000002-. 8A50E-03 .00*30 -.0000001-. 8332E-03 . 00*29 -.0000001-.8216E-03 .00*29 -.0000001— .810AE-03 .00*29 -.0000001- , 7995 E -0 3 .00*29 -.0000001-. 7890E-03 .00*29 -.0000001-.7786E-03 .00*29 -.0000001-. 7686E-03 .00*29 -.0000001-.7588E-03 .00*29 -.0000001-.7A93E-03 . 00*29 -.0000001-.7A00E-03 .00*29 -.0000001-.7309E-03 .00*28 -.0000001

69

2 983043123203283363443 82

3603683763 84

3924004084164244324404484 564644724 804 884965045125205285365445525605685765845 92

6006086 16624632640649656664672680688696704712720

Tabl e 10. Conti nued

.

HYDPHGFN SULFIDE ISOCHORE at 1.000 MOl/L

T p 7 DP/DD DO/ DT DP/DT D2P/DT2K HP A MPA-L/MOL MOl /L /K HP A/K HPA/K/K

215 2.0193 .81438 1.5764 - .6 5 95 E -02 .01040 -.0000279000 2.0790 .82251 1.6515 -.6206E-02 .01025 -.0000235000 2.1603 .83275 1 .7517 -.5755E-02 .01008 -.0000190000 2.2403 .84203 1.9485 -.5379E-02 . 00994 -.0000158000 2.3194 .85048 1.9427 -.5058F-02 .00983 -.0000133000 2. 3976 . 95823 2.0347 - . 4 78 1 E -0 2 .00973 -.0000114000 2.4751 .86536 2.1249 -•4538E-02 .00964 -.0000099000 2.5519 . 87194 2.2136 -.4323E-02 .00957 -.0000086oco 2. 6282 . 87805 2.3009 -•4131E-02 .00950 -.0000076000 2.7040 .88374 2.3872 -. 3957E-02 . 00945 -.0000067000 2.7794 .88904 2.4724 -.3 801E-02 .00940 -.0000060oco 2.8544 .89401 2.5567 -.3654E-02 .00935 -.0000054000 2.9290 . 89867 2.6402 -.3526E-02 .00931 -.0000048000 3.0033 .90304 2.7231 -.3406E-02 .00927 -.0000044000 3.0774 .90717 2.8053 - . 3 2 94 E -0 2 .00924 -.0000039000 3.1512 .91106 2.9869 -.3190E-02 .00921 -.0000036000 3.2248 .91474 2.9681 -.3094E-02 .00918 -.0000033000 3. 29*1 .9ie23 3.0497 - . 3 004 E -0 2 •

. 00916 -.0000030000 3.3713 .92153 3.1290 -.2919E-02 .00914 -.0000028000 3.4443 .92467 3 . 2 0 0 8 -.2840E-02 .00911 -.0000025000 3.5171 .92766 3.2883 -.2766F-02 .00909 -.0000023000 3.5898 .93050 3.3675 -.2695E-02 . 00908 -.0000022000 3.6624 .93322 3.4463 -.2629E-02 .00906 -.0000020000 3.7348 .93581 3.5249 -•2566E-02 .00904 -.0000019000 3.8071 .93828 3.6033 -.2506E-02 .00903 -.0000017000 3.8792 .94065 3.6813 -.2449E-02 .00902 -.0000016000 3.9513 . 94292 3.7592 -.2395E-02 .00900 -.0000015000 4.0233 .94510 3.8348 -.2343E-02 . 00899 -.0000014000 4.0952 .94718 3.9143 -.2294E-02 .00898 -.0000013000 4.1670 .94919 3.9916 -. 2247E-02 .00897 -.0000013000 4.2387 .95111 4.0687 -.2202E-02 .00896 -.0000012000 4.3103 .95297 4.1456 -.2159E-02 , 00 F 9 5 -.0000011000 4.3819 . 95475 4 .2224 -.2118E-02 .00894 -.0000011000 4.4534 .95647 4.2990 - . 207 8 E -0 2 . 00893 -.0000010000 4.5249 .95812 4.3755 - .2040E-02 .00893 -.0000010000 4.5962 .95972 4.4519 - . 200 3 E-0 2 .0089? -.0000009000 4.6676 .96126 4 .5281 -.1968E-02 .00891 -.0000009000 4.7388 .96275 4.6043 -.1934E-02 . 00890 -.0000004000 4.8100 . 96419 4.6803 - . 1 90 1 E -0 2 .00890 -.0000008000 4.8812 .96558 4.7562 -•1870F-02 .00 ee9 -.0000007000 4.9523 .96692 4.8320 -.1839E-02 .00889 -.0000007000 5.0234 . 96822 4.9079 -.1810E-C2 .00888 -.0000007000 5.0944 .96949 4.9834 -.1781E-02 .00888 -.0000006000 5.1654 .97071 5.0589 -.1753E-C2 .00887 -.0000006000 5.2364 .97189 5.1344 -.1727E-02 .00 887 -.0000006000 5 . 3073 . 97304 5.2098 -.1701E-02 . 00886 -.0000006000 5.3781 .97415 5.2851 -•1676E-02 .00886 -.0000005,000 5.4490 .97523 5 . 3604 -.1651 F-C2 .00885 -.0000005000 5.5198 . 97623 5.43^5 -.1628E-02 .00885 -.0000005000 5.5905 . 97730 5.5106 -.1 605E-02 .00884 -.0000005000 5.6613 .97830 5.5857 -•1583E-02 .00884 -.0000005,000 5.7320 .97926 5.6607 -.1 561E-02 .00884 -.0000005000 5.8027 .98020 5 .7356 -.1540E-02 .00 e83 -.0000004000 5 .8733 .99111 5.3104 -.1 520E-02 .00883 -.0000004

70

Table 10. Conti nued

.

HYPCOGEN SULFIDE IS0CH09E AT 2.000 MOL /

L

T 0 Z DP/DD DD/DT OP /DT 02 P /0T2K MPA mpa-l/mol MQL /L /K MP A/K MP A /K /<

327.709 3.8949 .71472 1.2175 -.1946E-C1 .02369 -.0000930326.000 3.9017 .71535 1.2223 -.1 936E-01 .02366 -.0000920336.000 4 .0884 .73172 1 .3487 -.1707E-01 . 02302 -.0000709344.000 4.2704 .74653 1.4683 -.1533E-01 .02251 -.0000569352.000 4.4488 .76004 1.5829 -.1396E-01 .02210 -.0000471360.000 4 .6242 .77244 1.6936 -.1284E-01 .02175 -.000039°366.000 4. 7970 .78389 1.8011 -.1191E-01 .02146 -.0000341376.000 4 . 9676 .79450 1 .9061 -.1112E-C1 .02120 -.00002963*4.000 5.1364 .80437 2.0068 -.1045E-01 .02098 -.0000259392.000 5.3034 .81359 2.1098 -.9854E-02 .02079 -.0000229400.000 5.4690 .82221 2.2090 -.9333E-02 . 02062 -.0000203406.000 5.6333 . 83031 2.3069 -. 8870E-02 .02046 -.0000192416.000 5.7965 .83792 2.4036 -.8456E-02 .02032 -.0000163424.000 5.9586 .84510 2.4991 -. 8083E-02 .02020 -.0000149432.000 6.1197 .85188 2.5936 -. 7745E-02 .02009 -.0000134440.000 6.2800 .85830 2.6873 -.7437E-C2 .01999 -.0000122448.000 6.4395 . 86439 2 .7801 -.7155E-02 .01989 -.0000111456.000 6.5983 .87016 2.6723 -.6P96E-02 .019ei -.0000102464 . 000 6.7564 . 87566 2.9637 -.6657E-02 .01973 -.0000094472.000 6.9140 .88089 3.0546 -.6435E-02 .01966 -.00000974 60.000 7.0710 .88567 3.1449 -.6229E-02 .01959 -.0000080468.000 7.2274 .89063 3 .2347 -.6037E-02 .01 953 -.00000744 96.000 7.38 34 .99518 3. 32*0 -. 5858E-02 .01987 -.0000069504.000 7.5390 ,89953 3.4128 -•5669E-C2 .01942 -.0000064512.000 7.6941 .90369 3.5013 - • 5 53 1 E-P 2 .01937 -.0000060520.000 7 . 64 88 .90769 3 .5896 -.5383E-02 .01932 -.0000056528.000 8.0032 .91152 3.6771 -. 5242E-02 . 01928 -.0000053536.000 6.1573 .91520 3.7645 -.5110E-02 .01924 -.00000495 4 A .000 8. 3110 .91973 3.8516 -.4964E-02 .01920 -.0000047552.000 8.4645 .92213 3 .93*4 - . 4 86 5 E -0 2 .01 916 -.0000044560.000 8.6176 . 92541 4.C250 -.4752E-02 .01913 -.0000041568 . 000 8.7705 .92856 4.1113 -.4645E-02 .01910 -.0000039576.000 8.9232 .93160 4.1973 - . 4 54 2 E -0 2 .01907 -.00000375 *4.000 9.0756 .93453 4.2831 -.4445E-02 .01904 -.0000035592 .000 9. 2277 .93736 4.3687 -.4351E-02 .01901 -.0000033600.000 9.3797 .94010 4 .4541 -.4262E-02 .01809 -.0000032608.000 9.5315 .94274 4.5393 - . 4177 E ~0 2 .0189o -.0000030616. COO 9.6831 .94529 4.6243 -.4095E-02 .01893 -.0000029624.000 9.8344 .94776 4.7091 -.4016E-62 .01891 -. 0000027632.000 9 , 9657 .95015 4.7938 -.3941E-02 .01889 -.0000026640.000 10.1367 .95247 4.8783 -.3866E-C2 .01867 -.0000025648.000 10.2876 .95471 4.9626 -.3799E-02 .01885 -.0000024656.000 10.4383 .95689 5.0469 -. 3732E-02 .01883 -.0000023

664.000 10 .5869 .95900 5.1309 -.3667E-02 .01881 -.0000022672.000 10.7394 .96104 5.2148 - . 3 605 E-0 2 .01880 -.0000021

680.000 10.8897 .96303 5.2966 -.3544E-02 .01878 -.0000020

688. OOC 11.0398 .96496 5.3823 -. 3486E-C2 .01876 -.0000020

696.000 11.1899 . 96683 5 .4668 -•3430E-02 .01875 -.00000197 06 .000 11.3396 .96865 5.5493 -.3376E-02 .01873 -.0000019

712.000 11 .4897 .97042 5.6326 -.3324E-02 .01*72 -.0000017

720.000 11.6394 .97214 5.7158 -.3273E-02 . 01871 -.0000017

71

Tab 1 e 10. Cont i nued

.

HYDROGEN SULFIDE ISOCHORE AT 4.000 HQL/L

T P Z DP/DD DD/DT DP /DT D2P/DT2K MPA MPA-L/MOL MOL /L/K mpa/k MPA/K/K

356.435 6.6998 .56518 . 5666 -.9708E-01 .05500 -.0003395360.000 6.8939 .57579 .634? -.05O2E-O1 .05392 -.0002724368.000 7.3176 .59789 .7753 -.6721E-01 .05211 -.0001894376.000 7.7289 .61807 .9077 -.5595 E-0

1

.05079 -.0001447384.000 8.1310 .63667 1.0347 -.4808E-01 .04975 -.0001163392.000 8.5255 .65394 1.1579 -.4224E-01 .04891 -.0000964400.000 8.9138 .67005 1.2782 -. 3771 E-01 .04020 -. 0000818408.000 9.2969 .68515 1.3963 -.3408E-01 .04759 -.0000705416.000 9.6755 .69933 1.5124 -.3112E-01 .04706 -.0000615424.000 10.0501 .71270 1 .6271 - . 2 86 4 E-0

1

.04660 -.0000542432.000 10.4213 .72534 1.7404 -.2654E-01 .04619 -.0000482440.000 10.7893 .73730 1.8525 -•2474E-01 .04503 -.0000432*48.000 11.1546 .74865 1.9637 - . 2 31 7 E-0

1

.04550 -.0000399456.000 11.5174 .75944 2 .0739 - . 2 1 80 E-0

1

.04520 -.0000352464.000 11.8780 .76971 2 .1834 -.2058E-01 .04494 -.0000321472.000 12.2365 .77950 2.2922 -•1950E-01 ,04469 -.0000293480.000 12.5931 .79885 2 .4003 -.1 852E-01 . 04447 -.0000269488.000 12.9480 .79778 2.5079 -.1765E-01 .04426 -.0000248496.000 13.3013 .00633 2.6149 -. 1685E-01 .04407 -.0000229504.000 13.6531 .81452 2.7214 - . 1 61 3 E -0

1

.0*389 -.0000212512.000 14.0036 .82238 2.8275 -.1 547E-01 .04373 -.0000199520.000 14.3528 . 82992 2.9331 - . 1 4 86 E —0

1

.04359 -.0000184528.000 14.7008 .03716 3.0383 — . 1 42 9E -0

1

.04343 -.0000172536.000 1 5.0*77 .84413 3.1432 - . 1 37 8 E-0

1

.04330 -.0000161544.000 15.3936 .05083 3.2478 -•1329E-01 .04317 -.0000151552.000 15 .7385 . 95729 3.3520 - . 1 2 95 E -0

1

.04306 -.0000142560.000 16.0825 . 86352 3.4559 - . 1 24 3 E -0

1

.04295 -.0000134568.000 16.4257 .0695? 3.5595 - . 1 204 E-0

1

.04284 -.0000127576.000 16.7680 . 87531 3.6628 -.1167E-01 .04274 -.0000120584.000 17.1096 .88091 3.7659 -•1133E-01 .04265 -.0000114592.000 17.4504 .88632 3.8688 -.1100E-01 .04256 -.0000108600.000 17.7906 .89154 3.9714 -•1070E-01 .04248 -.0000103608. COO 18.1301 .89660 4.0737 - , 1 04 1 E -0

1

.04240 -.0000098616.000 18.4690 .90150 4.1759 -.101 3E-01 .04232 -.0000093624.000 18.9072 .90624 4.2778 -.9876E-02 .04225 -.0000089632.000 19.1449 .91084 4.3796 -.9631E-02 .04218 -.00000956*0.000 19.4821 .91529 4.4812 -.9397E-02 .04211 -.0000082648.000 19.8187 . 91961 4.5826 -.9176E-02 .04205 -.0000078656.000 20.1549 .92300 4.6838 -. 8964E-02 . 04199 -.0000075664.000 20.4905 .92787 4.7848 - • 876 3 E-02 .04193 -.0000072672.000 20.8257 .93183 4.8857 -.9570E-02 .04187 -.0000069680.000 21.1605 . 93566 4.9964 -. 8386E-02 .04182 -.0000067688.000 21 . 4948 .93940 5.0869 -.8210E-02 .04176 -.0000064696.000 21.8287 .94302 5.1873 -. 8041E-02 .04171 -.0000062704.000 22.1622 .94655 5.2876 -•7880E-02 .04167 -.0000060712.000 22 .4954 . 94998 5.3877 -.7725E-02 .04162 -.0000059720.000 22.8281 .95333 5.4877 -.7576E-02 . 04157 -.0000056

11

Table 10. Continued.

HYDROGEN SULFIDE ISOCHORE AT 6.000 HOL/L

T p Z DP/DDK MPA MP A-L/MOL

368.306 8.2230 .**75* .1830376.000 8.8839 .*7362 .31963 8* . 000 9.5*65 .*983* .*503392.000 10.1937 .52126 .5776<*00. COO 1 0 • 829* .5*271 .7033<*08.000 11 .*568 .56288 .82 82<*16.000 12.0766 .58192 .9525<*2<* .000 12.690* .59996 1.0765*32.000 13.2999 .61708 1.2003<*<*0.000 13.9028 .63338 1 .3238*<*8.000 1* . 5026 .6*890 1 . * * 71*56.000 15.0988 .66373 1 .570**6* .000 15.6918 .67790 1.6935*72.000 16.2818 .691*7 1 .816**80.000 18.9691 .70**7 1.9393*83.000 17. *539 .7169* 2.0621*96.000 18.036* .72892 2.18*750*. 000 19.6169 .7*0** 2.3073512.000 19.195* .75152 2. *297520.000 19.7720 .76218 2.5521523.000 20.3*70 .772*6 2.67**536.000 20.9203 .78238 2 .79655** .000 21. *922 .7919* 2.9185552.000 22.0626 .80118 3.0*05560.000 22.6317 .81011 3.1623568.000 23.1995 .8187* 3.28*0576.000 23.7661 .82708 3. *05658*. 000 2* .3316 .83516 3.5271592.000 2*. 8960 .8*299 3.6*85600.000 25 .*593 .85056 3 .7698609.000 26.0216 .85791 3.8910616.000 26.5829 . 8650* *.012162* .000 27.1*3* .87195 *.1330632.000 27 .7029 . 87866 * .25386*0.000 28.2616 .88517 *.37*66*8.000 28.819* .89150 *.*952656.000 29.3765 .89765 *.615766* .000 29.9327 .90363 *.7360672.000 30. *883 .909** *.8563680.000 31.0*31 .91510 * .976*

688.000 31.597? .92060 5.0965696.000 32.1507 .92596 5.216*70*. 000 32.703* .93119 5.3362712.000 33.2556 .93626 5. *559720.000 33.9071 .9*121 5.5755

DD/DT OP /DT D2P/DT2MOL /L /K HP A/K HP A/</K

-.*828E+C0 .08835 -.0009176-.2631E+C0 . 0 e *08 -.0003691-.1815E+00 .0817* -.0002353-•13P7E+00 .08013 -.0001735-.1122E+00 .07890 -.0001370-.9*0 7 E -0

1

.07791 -.0001127-.8092E-01 . 0770e -.0000952-.7095E-01 .07630 -.0000320- . 631 2 E -0

1

.07576 -.0000716-.5682E-01 .07522 -.000063*-.5165E-01 .07*7* -.0000566-.*732E-01 .07*32 -.0000509- . *36 5 E -0

1

.07393 -.0000*61- • * 05 1 E-0

1

.07358 -.0000*21-.3777E-01 . 07325 -.0000336-.3538E-01 .07296 -.0000355-.3327E-01 .07268 -.0000329-.3139E-01 .072*3 -.0000305- . 297 1 E -0

1

.07219 -.0000285-.2 820E-01 .07197 -.0000266-•268*E-01 .07177 -.0000250-.2559E-01 .07157 -.0000235-.2**6E-01 . 07139 -.0000222- , 2 3* 2 E -0

1

.07122 -.0000210- . 2 2*7 E -0

1

.07106 -.0000199-.2159E-01 .07090 -.0000199- . 207 8 E -0

1

.07075 -.0000130-.2002E-01 .07061 -.0000171-.1932E-01 .070*8 -.000016*-.1866E-01 .07035 -.0000157-.1805E-01 .07023 -.0000150-«17*7E-C1 .07011 -.00001**- . 1 69* E -0

1

.07000 -.0000139-.16A3E-01 .06989 -.000013*-.1595E-01 . 06978 -.0000129-.1550E-01 .06968 -.0000125-.1508E-01 .06950 -.0000120- • 1 *6 7E-0

1

.069*9 -.0000116-. 1*29E-01 .069*0 -.0000113- . 1 3 93 E -0

1

.06931 -.0000109-.1358E-01 .06922 -.0000106-.1325E-01 .0691* -.0000103- . 1 29* E -0

1

. 069C6 -.0000100- . 1 26* E -0

1

.06898 -.0000098-•1236E-01 .06890 -.0000095

73

Tabl e 10. Cont i ruled

HYDROGEN SULFIDE ISOCHORE AT 8.000 MQL/L

T P Z DP/no DD/DT OP/DT D2P/DT2K MPA MPA-L/MOL MOL /L /K MPA/K M? A /< /K

372.609 8 . 8*36 .35682 .0297 -.*061E+01 .12061 -.3031997376.000 9.2*39 .36961 .08*6 -.1378E+01 .11656 -.00060503 8* .000 10.1631 .39789 .2116 -. 5373E+00 .11367 -.0002332392.000 11.0659 .*2**0 .3*21 - • 3 27 8 E *0 0 .11215 -.00015*2*00.000 11.9586 .**9*6 . *756 -.2336E+00 .11109 -.0001151*08.000 12.8*39 .*7327 .6113 -.180*E+00 .11027 -.0000920*16.000 13.7233 .*9595 .7*88 - . 1 *6* E *0 0 .10959 -.0000767*2*. 000 1* .5977 .51760 .8878 -•1228E+00 .10903 -.0003658*32.000 15. *679 .53830 1.0280 -.1056E+00 .10853 -.0000576**0.000 16.33** .55612 1.1692 - • 92*5 E-0 1 .10810 -.0000512**8.000 17.1976 .57712 1.311* -.821*E-01 .10771 -.0000*61*56.000 18.0579 .59536 1 .*5*3 -• 7382E-01 .10736 -.0000*19*6* .000 18.9155 .61288 1.5979 -.6699E-01 .1070* -.0000385*72.000 19.7706 .62973 1.7*20 -•6128E-01 .1067* -.0000356*eo.ooo 20.623* .6*59* 1.8866 - . 56* 3 E ~0

1

.106*7 -.0030331*88.000 21 .*7*2 .66156 2 .0316 -• 5 22 8E -0

1

.10621 -.0000310*96.000 22.3229 .67662 2.1770 -.*868E-01 .10597 -.000029150*. 000 23.1698 .6911* 2.3227 -.*553E-01 .10575 -.0000275512.000 2*. 01*9 .70515 2. *687 -,*275E-01 .10553 -.0000261520.000 2* .8583 .71869 2.61*8 - . *02 6 E-0

1

.10533 -.00002*9528.000 25.7001 .73177 2.7612 -.3807E-01 . 10513 -.0000238536.000 26.5*05 .7***2 2.9078 - • 3 60 9E-0

1

.10*95 -.00002285** .000 27.3793 .75665 3.05** -.3*30E-01 .10*77 -.0000219552.000 28.2168 .76850 3 .2012 -.3267E-01 .10*60 -.0000210560.000 2 9.0529 .77997 3.3*81 -.3119E-01 . 10**3 -.0000203568.000 29.8877 .79108 3. *950 - . 2 98 * E -0

1

.10*27 -.0000196576.000 30.7213 . 80185 3.6*19 -. 285 9 E—0

1

.10*12 -.00001905 8* . 000 31.5536 .81229 3 .7889 -.27**E-01 .10397 -.000018*592.000 32.38*8 . 822*2 3.9359 -.2638E-01 .10382 -.0000179600.000 3 3 • 2 1 * p .83225 * .0829 -.2539E-01 .10368 -.000017*608.000 3* .0*37 .8*180 *.2299 -.2**8E-01 .1035* -.0000170616.000 3*. 8715 .85107 * .3768 - . 2 36 3 E -0

1

.103*1 -.000016662* .000 35 . 6982 . 86007 *.5238 -.2283E-01 .10328 -.0000162632.000 36.5239 . 86883 * .6706 -.2208E-01 .10315 -.00001586*C • 000 37,3*86 .8773* *.817* - . 2 1 3 9 E —0 1 .10303 -.00001556*8.000 38.172* .88562 * .96*2 -.2073E-01 .10290 -.0000151656.000 3e . 99 51 . 89368 5.1109 -

. 201 1 E-0

1

.10278 -.00001*866*. 000 39.8169 .90152 5.2575 - . 1 95 3 E -0

1

.10267 -.00001*6672.000 *0.6377 .90915 5. *0*0 -.1 898E-01 .10255 -.00001*3680.000 *1 .*577 .91658 5.5505 - . 1 8*6 E -0

1

.102** -.30031*0688.000 *2. 2767 .92382 5.6968 - • 1 796E-0

1

.10233 -.0000139696.000 *3.09*9 .93087 5.8*31 — • 1 7* 9E — 0 1 .10222 -.000013570* .000 *3.9122 .93775 5.9892 -.17C5E-01 .10211 -.0000133712.000 **.7287 . 9***5 6.1353 - . 1 66 3 E-0

1

.10200 -.0300131720.000 *5 . 5**3 .95099 6.2812 -.1622E-01 .10190 -.0000129

74

Table 10. Continued

HYDROGEN SULFIDE .ISOCHORE AT 9.000 MOL/L

T P Z DP /DD DO/DT DP /DT D2P/DT2K MPA MPA-L/MOL MOL/L/K MP A/K M? A /< /<

373.261 8.9417 .32013 .005? -.2574E+C2 .13586 -.0093263376.000 9.3069 .33078 .0477 -•2772E+01 .13220 -.00046763 84 . 000 10.3550 .36036 .1806 -.7210E+00 .13023 -.0001510392.000 11.3929 .38839 .3212 -.4025E+00 .12928 -.0000955400.000 12.4242 .41508 .4663 -.2758E+00 .12862 -.0000714408.000 13.4511 .44057 .6148 -.2084E+00 .12811 -.0000577416.000 14.4742 .46497 . 7657 -.1667E+00 .12769 -.0000489424.000 15.4942 .48834 .9188 -.1386E 00 .12732 -.0000427432.000 16.5115 .51077 1.0735 -•1183E 00 .12700 -.0000382440.000 17.5263 .53230 1.2296 -.1030E+00 .12671 -.0000347448.000 18.5389 .55300 1 .3869 -.9117E-01 .12644 -.0000320456.000 19.5494 .57291 1 . 5453 -. 8166E-01 .12619 -.0000299464.000 20.5590 .59208 1.7045 -.7390E-01 .12596 -.0000201472.000 21.5648 .61056 1 .9644 -.6744E-01 .12574 -.00002664 80.000 22.5699 .62836 2.0250 -.6199E-01 .12554 -.0000253488.000 23.5734 .64554 2.1862 -.5733E-01 .12534 -.00002434 96.000 24.5753 .66212 2.3478 -•5330E-01 .12515 -.0000234504.000 25.5758 .67814 2.5099 -.4979E-01 .12496 -.0000226512.000 26. 5748 .69362 2.6723 -.4670E-01 .12479 -.0000219520.000 27.5724 . 70858 2.0350 -.4396F-01 .12461 -.0000213528.000 2P . 5686 .72306 2.9979 -.4151E-01 .12444 -.00002085 36.000 29.5635 .73708 3.1611 - . 3 93 2 E -0 1 .12428 -.0000203544 . 000 30. 5571 .75064 3.3245 -.3734E-01 .12412 -.0000193552.000 31 .5494 . 76379 3 .4880 -•3554E-01 .12396 -.0000194560.000 32.5405 .77653 3.6516 -.3391E-01 .12381 -.0000191568.000 33.5304 .78889 3.8153 -.3241E-01 .12366 -.0000187576.000 34. 5190 .90086 3.9791 -. 3104E-01 .12351 -.0000184584.000 35.5065 .81249 4 .1429 -.2979E-C1 .12336 -.0000181592.000 36.4928 . 92377 4.3068 - , 2 86 1 E -0 1 .12322 -.0000179600.000 37.4780 .83473 4 .4707 - . 2 75 3 E-0

1

.12308 -.0000176609.000 38.4621 .84539 4.6345 -.2653E-01 .12294 -.0000173616.000 39.4451 .85572 4.7983 -.2559E-01 .12280 -.0000171

624. OOC 40.4269 . 86578 4 .9621 - . 247 2 E -0

1

.12267 -.0000169632.000 41.4077 .87556 5.1259 -•2390E-01 .12253 -.0000167

640.000 42.3874 .88507 5.2896 -.2314E-01 .12240 -.0000165

648.000 43.3661 . 89433 5.4532 -.2242E-01 .12227 -.0000163

656.000 44.3437 .90334 5.6168 -.2175E-01 .12214 -.0000161

664.000 45.3203 .91211 5.7802 -.211 1 E-0

1

.12201 -.0000159

672.000 46.2959 .92065 5.9436 -•2051E-C1 .12108 -.0000157

680.000 47.2705 .92897 6.1069 — , 1 994E-0 1 .12176 -.0000155

ftee.ooo 4e.2440 .93708 6.2700 - . 1 940E-0 1 .12164 -.00001 54

696.000 49.2166 .94498 6 .4331 -.1889E-01 .12151 -.0000152

704.000 50.1802 .95269 6.5960 -. 1 840E-01 .12139 -.0000150

712.000 51.1589 .96020 6.7588 -.1794E-01 .12127 -.0000149

720.000 52.1286 .96753 6.9215 -.1750E-01 .12115 -.0000147

75

Table 10. Cunt i nued

.

HYDROGEN SULFIDE ISOCHORE AT 10.200 MOL/L

T P Z OP/DD OD/DT DP/DT D2P/DT2K 8 P A MPA-L/MOL MOL /L /K MPA/K mpa/</k

373.400 8.9629 .28303 0.0000 -R .15238 0.0000000376.000 9.3591 .29350 .0448 -•3403E+01 .15238 -.0000006384.000 10.5761 .32482 .1988 -.7663E+00 .15236 -.0000024392.000 11 .7969 .35485 .3620 -.4208E+00 .15234 -.0000040400.000 13.0154 .39367 . 5303 -.2872E+00 . 15230 -.0000055408.000 14.2337 .41136 .7023 -.2168E+00 .15225 -.0000069416.000 15.4514 .43796 . 8771 -.1735E+00 .15219 -.0000081424.000 16.6687 .46355 1 .0542 -.1443E400 .15212 -.0000092432.000 17.8854 .48818 1.2331 -.1233E+00 .15204 -.0000102440.000 19.1014 .51189 1.4136 -.1075E+00 .15196 -.0000111448. OCO 20.3167 .53474 1.5953 - . 9 52 0 E -0 1 .15187 -.0000119456.000 21.5312 .55676 1 .7781 -.8535E-01 .15177 -.0000126464.000 22.7450 .57800 1.9619 -.7731E-01 .15167 -.0000133472.000 23.9579 .59851 2.1464 - .7061 E-0 1 .15166 -.00001394 80.000 25.1699 .61831 2.3317 -.6495E-01 .15144 -.0000145488.000 26.3810 .63743 2.5175 -.6011E-01 .15133 -.0000149496.000 27.5911 .65592 2.703° -.5592E-01 .15120 -.0000154504.000 28.8002 . 6 7 3 ° 0 2 .8905 -.5227E-01 . .15108 -.0000153512.000 30.0083 .69109 3.0776 - . 490 5 E -0

1

.15095 -.0000161520.000 31.2154 .70783 3.2650 -.4619E-01 .15082 -.0000154528.000 32. 4216 .72404 3.4526 -.4364E-01 .15069 -.0000167536.000 33.6265 . 73974 3.6405 -.4136E-01 .15055 -.0000169544.000 34.8304 .75496 3 . ° 2 8 5 -.3929E-01 .15042 -.0000172552.000 36.0332 .76971 4.0166 -.3741E-01 .15028 -.0000173560.000 37.2348 .78402 4.2048 -.3571E-01 . 15014 -.0003175568.000 38.4354 . 79790 4.3931 -.3414E-01 .15000 -.0000176576.000 39.6348 .81137 4.5814 -.3271E-01 .14986 -.0000177584.000 40.8331 .82445 4 .7698 -.3139E-01 .14972 -.0003178592.000 42.0303 .83715 4.9581 -.3017E-C1 .14957 -.0000179600.000 43 .2263 .84949 5.1464 -.2904E-01 .14943 -.0000180608.000 44.4212 .86149 5.3347 -.279°E-01 .14929 -.0000180616.000 45.6149 . 87315 5.5229 -•2700E-01 .14914 -.3000180624.000 46.8075 .88449 5.7110 -.2609E-01 .14900 -.0000181632.000 47.9989 .89552 5.8991 -.2523E-01 .14885 -.0300181640.000 49.1691 .90626 6.0870 - . 244 3 E-0

1

.14871 -.0000131648.000 50.3782 .91671 6.2749 -.2368E-01 .14856 -.0000130656.000 51 . 5661 . 92688 6.4626 -.2297E-01 .14842 -.0000180664.000 52.7529 .93679 6.6502 -•2230E-01 .14828 -.0000180672.000 53.9385 . 94644 6.8377 -.2166E-01 .14813 -.00001796 80.000 55.1230 .95585 7.0250 - . 2 107 E-0

1

.14799 -.0300179688.000 56.3064 . 96501 7.2121 -.2C50E-01 .14785 -.0000173696.000 57 .4886 .97395 7.3991 - . 1 996 E — 0

1

.14770 -.0000178704.000 58.6696 .98266 7.5660 - • 1 94 5 E -0

1

.14756 -.0000177712.000 59.8495 .99116 7.7726 -.1 897E-01 .14742 -.0000176720.000 61.0283 .99945 7.9591 -.1850E-01 .14728 -.0000176

76

Table 10. Continued

hydrogen sulfide isochore at 11.000 mol /L

T p Z DP/DD DD/DT DP/DT D 2 p / 0 T2K MPA MP A-L/MOL MOL /L /K MP A/K MP A /< l<

373.359 8.9567 .26280 .0019 -.8850E*02 . 16A90 .0187807376.000 9.398A .27330 .0555 -.3027E*01 .16801 .000332038A.000 10.7A89 .30606 .2313 -. 732?E*00 .16936 . 0 0 C 0 9 9 3

392.000 12.1063 .33767 • A1 5 6 -.A089£ +00 .16996 .0000532A 00 , 0 00 13.A676 .36813 .60A9 -.28166*00 , 1703

A

.0000391A 08 , 000 1A .8315 . 3 97 A 6 .7977 21396*00 .17060 .0000275A 1 6 . 000 16.1971 . A7571 .9931 -.17206+00 .17079 . 000019AA2A. 000 17.56A0 . A 5 2 9 3 1.1907 -.1 A35E *00 .17092 .0000133A32 .000 18.9317 • A7916 1.3900 -.12306*00 .17101 .0000035AAO. 000 20 .2999 . 50AAA 1 .5907 -.1075E*00 .17106 .OOOOOA6A A 8 . 000 21 . 6685 . 5 2 8 8 A 1.7927 -.95A36-01 .17108 .000001AA 56 . 000 23.0372 .55238 1.9957 -.85736-01 .17108 - , 0000 0 1 A

A6A.OOO 2A.A057 .57510 2.1995 - . 7777 E -0

1

.17106 -.0000037A72 .000 2 5 . 77 A

1

.59705 2 .A0A1 -.711AE-01 .17102 -.0000058A 80 . 000 27.1A20 .61826 2.6092 -.6552E-01 . 17097 -.0000075A 8 8 . 000 28.5095 .63877 2.81A9 - .6071 E-0

1

.17090 -.0000091A96.000 2 9 , 876

A

.65859 3.0210 -. 565AE-01 .17082 -•00001DA5 OA .000 31 . 2A27 .67778 3.2275 -.5290E-01 .17073 -.0000116512.000 32.6082 .69635 3 . A 3 A 3 -. A9696-0

1

. 1706A -.0000127520.000 33.9728 . 7 1 A 3 3 3.6A13 -.A683E-01 .17053 -.0000136528.000 35.3367 .73175 3.8A85 -.AA28E-01 .170A2 -.0C001 A5

536.000 36.6995 . 7 A 8 6 3 A .0559 -.A199E-01 .17030 -.00001525AA .000 3 8 . 0 61

A

. 76A99 A. 2633 - . 3992E -0 1 .17018 -.0000159552.000 39.A223 .78086 A.A709 -.3 803E-01 .17005 -.0000165560.000 AO. 7822 .79626 A. 6785 -.36326-01 .16991 -.0000170568.000 A2.1A09 .81120 A .8860 -•3A75E-01 .16977 -.0000175576.000 A3. A936 . 82570 5.0936 -.3330E-01 .16963 -.00001795 8 A . 000 AA . 855 1 . 83979 5.3011 -.3197E-01 . 169A9 -.0000182592.000 A6.210A .953A7 5.5086 -.307AE-01 , 1 693 a -.0000135600.000 A7 . 56A 5 . 86677 5 .7160 -.2960E-01 .16919 -.0000188608.000 A8 . 9175 . 87969 5.9233 -.285AE-01 . 1690A -.0000191616.000 50.2692 .89226 6.1305 -.2755E-01 .16889 -.000019362A.OOO 51.6197 . 90A A 9 6.3376 -. 2662E-01 .16873 -.000019A

632.000 52 .9689 .91638 6.5AA5 -.25766-01 .16858 -.0000196

6 AO . 000 5A. 31 69 .92795 6.7513 -.2A95E-01 . 168A2 -.0000197

6 A 8 .000 55.6636 .93922 6.9579 -.2A18E-01 .16826 -.0000198

656.000 57.0091 .95019 7 . 16 A3 -.23A6F-01 .16810 -.0000199

6 6 a . 000 58.3533 . 96088 7.3706 -.22796-01 • 16799 -.0000200

672.000 59.6962 .97129 7.5767 -.221AE-01 .16778 -.0000200

680.000 61.0378 • 981 A3 7.7626 -.215AE-01 .16762 -.0000201

6ee.ooo 62.3781 .99132 7.9883 - . 2096 E-0

1

.167A6 -.0000201

696.000 63 .7172 1.00096 8.1938 -.20A2E-01 .16730 -.0000201

7 OA . 000 65.05A9 1.01037 8.3991 -.19906-01 . 1671 A -.0000201

712.000 66.391A 1 . 0195 A 8 . 60A2 - . 1 9A 1 E-0

1

.16698 -.0000201

720.000 67.7266 1 .028A9 8.8090 -.1B9AE-P1 .16682 -.0000200

77

Table 10. Co nt i n ued

hydrogen sulfide isochore at 12.000 mol/l

T P Z DP/DD DD/DT DP/DT D2P /DT?K P & MPA-l/MOL 00 L / L /

K

MPA /K 0P A/</K372.990 0.9000 .23917 .0237 -.791 5E+01 .10745 .0045988376.000 9 . A729 .25251 .1028 -•1861E+01 .19143 .00059253 PA .000 11.0167 .28754 .3156 -.6150E+00 . 19AC7 .0002057392.000 12 .57A8 .32151 .5339 -.3659E+00 .19535 .0001257A 00 . 000 1 A , 1 A 1

1

.35433 .7559 -.2595E+00 .19619 .0000830A 08 . 000 15.7132 .38600 .9807 -.2007E+00 .19679 .0000852A 16 .000 17.2094 .41655 1.2076 -.1633E+00 .19725 .0000495A2A. 000 18.8689 . AA603 1 .4361 -.1376E+00 .19760 .0000378A 3 2 . 000 20. A507 . A7AA7 1.6661 -.lieBE+OO .19786 . 0000288AAO. 000 22 .03AA .50192 1.8972 -•1044E+00 .19806 .0000215AA9. 000 23.6195 .52842 2.1292 -.9309E-01 .19821 .0000155A 56 . 000 25.2056 .55401 2.3619 - . 83 96 E-0 1 .19831 .0000104A 6 A . 000 26. 792A . 57873 2. 5954 -. 76AAE-01 .19838 .0000062A 72 . 000 28.3796 .60262 2.8293 - . 701 3 E -0

1

.19841 .0000025A 80.000 29.9669 .62572 3.0636 - .6477 E-0

1

.19042 -.0000007A 08 . 000 31 .55A2 .64807 3.2983 -•6015E-01 .19840 -.0000035A 96 . 000 33.1A13 .66968 3.5333 - . 561 AE -0

1

. 19836 -.000005950A.000 3A .7279 .69061 3.7685 -•5262E-01 .19831 -.0000081512.000 3 6 . 3 1 A

1

.71067 A. 0038 -.4951E-01 .19023 -.0000100520.000 37 . 8997 .73049 A. 2392 -•4674E-01 .19815 -.0000116520.000 39. A8A5 .74951 4.4747 -. AA26E-01 . 198C5 -.0000131536.000 A 1 . 06 8 A .76794 4.7102 -.4202E-01 .19794 -.00001455AA .000 A 2 . 6 5 1 A .78581 A. 9457 -. A000E-01 .197e2 -.0000156552.000 AA .2335 .80315 5.1812 -•3816E-01 .19769 -.0000167560.000 A 5 . 8 1 A A .81997 5.4165 -.3647 E-0 1 .19755 -.0000176560.000 A 7 . 3 9A 3 .83630 5.6518 -.3493E-01 .19741 -.00001855 7* . 000 A8.9729 .85215 5.8869 -•3351E-01 .19726 -.00001 925 8

A

. 0 00 50.5503 . 86755 6.1219 -•3220E-01 .19710 -.0000199592.000 52.1265 .88251 6.3568 -.3098E-C1 .19694 -.0000205600.000 53.7013 .09705 6.591A -.2985E-01 .19677 -.0000210600.000 55.27A8 .91119 6.0259 -•2880E-01 .19660 -.0000215616.000 56 . 8A70 . 92 4<?3 7.0602 -•2702E-O1 .19643 -.00002196 2 A . 000 58. 4177 .93330 7.2942 - . 2 691 E -0 1 . 19625 -.0000222632.000 59.9870 .95131 7.5281 -

.

2 60 5 E-0

1

.19607 -.00002266 AO . 000 61 . 55A9 .96397 7.7616 -

. 252 A E-0

1

.19509 -.00002286A8.000 63.1213 .97630 7.9950 -•2443E-01 .19571 -.0000231656.000 6A. 6062 .98830 8.2281 - . 2376E-0

1

.19552 -.00002336 6 A

,

000 66 .2496 1.00000 8.4609 -.2309E-01 .1953- -.0000235672.000 67.8115 1.01139 8.6935 -•2245E-01 .19515 -.0000236600.000 69.3720 1 .02249 8.9257 -.218AE-01 .19496 -.0000237680.000 70.9300 1.03331 9.1578 -. 2127E-01 .19477 -.0000233696.000 72 . A 682 1.0A386 9.3895 -.2072E-01 .19450 -.000023970A .000 7 A , 0 A A

1

1 .05414 9.6209 - . 202 0 E -0

1

.19438 -.0000240712.000 7 5 . 5 9 8 A 1.06418 9.8521 -.1971 E-0

1

.19419 -.0000240720.000 77.1511 1.07397 10.0830 -.1924E-01 .19400 -.0000241

78

Table 10. Continued

HYDROGEN SULFIDE ISOCHORE AT 14.000 MOL /L

T P Z DP/DD DD/DT DP /DT D2P/DT2K 6<PA HPA-L/MOL MOL/L/K MPA/K HR A /< /<

370.077 8.4733 .19670 .2630 -.9595E+00 .25237 .0011726376.000 9.9822 .22807 .5003 -.5127E+00 .25651 .0004588384.000 12.0462 .26950 .8114 -.3195E+00 . 25923 . 000259?392.000 14.1273 .30961 1 .1204 -•2329E+00 .26095 .0001777400.000 16.2200 .34836 1.4289 -.1835E+00 .26217 .0001311408.000 18.3212 .38577 1 .7373 -.1514E+00 .26308 .0001002416.000 20.4288 .42188 2.0457 -.1289E+00 .26379 .0000777424.000 22.5414 .45672 2.354? -.1123E+00 .26434 .0000605432.000 24.658C .49035 2.6626 - . 9 94 4 E -0

1

.26477 .0000469440.000 26.7775 .52282 2 .9709 -.8923E-01 .26510 .0000357448.000 28 . 8993 .55417 3.2792 -. 8092E-0

1

. 26535 .0000265456. OOC 31 .0228 .58446 3.5873 -•7402E-01 .26553 .0000186464.000 33.1476 .61372 3.8953 -.6820E-01 .26565 .0000119472.000 35.2731 .64200 4.2030 -.6322E-01 .26572 .00000614 80.000 37. 3989 .66935 4.5106 -. 5892E-01 .26575 .0000011488.000 39.5249 .69580 4.8178 -.5516E-01 .26574 -.0000033496.000 41 .6507 .72140 5.1247 -•5185E-01 .26570 -.000007?504.000 43.7760 .74618 5 .4313 -.4 891E-01 .26562 -.0000106512.000 45.9006 .77017 5.7376 -.4628E-01 .26553 -.0000136520. COO 48.0243 .79340 6.0434 -.4392E-01 .26541 -.0000162526.000 50.1471 .81592 6.3489 -.4178E-01 .26527 -.0000186536. OOC 52 ,26e6 .93774 6 .6540 -.3984E-01 .26511 -.0000207544.000 54.3888 .85891 6.9587 -.3B07E-01 . 26494 -.0000226552.000 56.5075 .87943 7.2630 - • 364 5 E-0

1

.26475 -.0000243560. COO 58.6247 .89935 7.5668 -.3496E-01 .26455 -.0000258568.000 60.7403 .91868 7.8702 -.3359E-01 . 26434 -.0000272576.000 62.9541 .93745 8.1731 -.3232E-01 .26411 -.00002345 84.000 64.9661 .95567 8.4755 -•3113E-01 .26386 -. 0000294592.000 67.0762 . 97 3 3 e 8.7775 -.3004E-C1 .26364 -.0000304600.000 69.1844 .99059 9.0789 - • 2 90 1 E-0

1

.26340 -.0000312608.000 71 . 2906 1.00731 9.3799 -. 2805E-01 . 26314 -.0000320616.000 73 .3947 1.02358 9.6805 - . 2 716 E-0

1

.26289 -.0000327624.000 75.4967 1 .03939 9.9805 -.2631 E-01 .26262 -.0000332632.000 77.5966 1.05478 10.2800 -.2552E-01 .26235 -.0000338640.000 79.6944 1.06975 10.5790 -.2477E-0

1

.26208 -.000034?648.000 81.7899 1.08433 10.8776 -.2407E-01 .26181 -.0000346656.000 83.8833 1.09852 11.1756 -. 2340E-01 .26153 -.0000350

79

Ta bl e 1 (J. Conti nued


T P Z DP/DO DD/DT DP/DT D2P/DT2K MPA mpa-l/mol MI3L /L /K HOA /K MPA /K/K

362.932 7.5022 .15538 1.0347 -.3329E+C0 . 34440 . 0004766364.000 7.8702 .16253 1.0937 -•3154E+00 . 34488 .0004371366.000 9.2529 .18901 1.3116 - . 2641 E *00 .34641 .0003334372.000 10.6410 .21502 1.5264 -„2277E*00 .34760 .0002680376.000 12.0334 .24057 1.7391 -.2004E+00 . 34858 .0002222380.000 13.4294 .26565 1 .9502 -•1792E 00 .34939 .00018783 64.000 14.8284 .29C27 2.1601 -.1621E+00 .35009 .0001607366.000 16.2300 .31443 2 .3691 - • 1 460E + 00 .35069 .0001387392.000 17. 6338 .33815 2.5772 - • 1 363E *00 . 35120 .0001203396.000 19.0395 .36141 2.7847 -•1263E+00 .35165 .0031047400.000 20.4469 .38425 2.9915 -•1177F*00 .35204 .000091

2

404.000 21.8558 . 40666 3 .1978 -.1102E+00 .35238 .0000793408.000 23.2659 .42865 3.4036 -.1036E+00 . 35268 .0000688412.000 24.6772 .45024 3.6089 -.9780E-01 .35294 .0000595416.000 26.0894 .47143 3.8138 -.9260E-01 .35316 .0000511420.000 27.5024 .49223 4.0183 -. 8793E-01 .35335 .0030435424.000 28.9161 .51265 4.2225 -.8372E-01 .35351 .0000366428.000 30.3304 .53269 4.4262 -.7990E-01 .35364 .0000303432.000 31.7452 .55238 4.6296 -.7641F-01 .35375 .0000245436.000 33.1604 .57171 4.6327 - .7 32 2 E-0

1

.35384 .0030192440.000 34.5758 .59070 5.0355 - . 702 8 E -0

1

.35390 . 0000143444.000 35.9916 .60934 5.2379 -.6757E-01 .35395 .0000097448.000 37.4074 .62766 5.4401 -.6507E-01 . 35396 .0030055452.000 38.8234 .64565 5.6419 -.62 74 E-0

1

.35399 .0300016456.000 40.2394 .66333 5.8435 - . 605 3 E -0

1

. 35399 -.0000021460.000 41.6553 .68070 6.0448 -.5856E-C1 .35398 -.0000055464.000 43.0712 .69777 6.2458 - . 5667 E -0 1 .35395 -.0000086468.000 44 .4869 .71455 6 .4465 -.5490E-01 .35391 -.0000116472.000 45.9024 .73103 6.6470 -•5324E-01 .35386 -.0000144476.000 47.3177 .74724 6.8472 - . 5 16 7E -0

1

.35379 -.03001704 80.000 48.7328 .76317 7.0471 -.501 9E-01 .35372 -.00001 94484.000 50.1475 .77884 7.2468 -•4880E-01 .35364 -.0000217488.000 51. 5619 .79424 7.4462 -•4748E-01 .35355 -.0000239492.000 52.9759 . 80939 7.6454 -•4623E-01 .35345 -.0000259496.000 54. 3e94 .82428 7.8443 - . 4 504 E -0

1

.35334 -.0000278500.000 55 . 8026 .83893 8 .0429 -.4392E-01 .35323 -.0000296504.000 57.2152 .85335 8.2413 -.4285E-01 .35310 -.3000313508.000 58.6274 . 86752 8.4395 - .4 1 82 E-0 1 . 3 5 2 9 ^ -.0000329512.000 60.0390 .88147 8.6374 -.4085E-01 .35284 -.00003445 16.000 61.4501 . 89519 8.8351 — . 3 99 2 E -0 1 .35270 -.0000358520.000 62.8606 . 90870 9.0325 -. 3903E-0 1 . 35255 -.0000372524 .000 64.2705 .92199 9.2297 — • 3 81 8 E-0 1 .35240 -.0000384528.000 65.6798 .93507 9.4266 -.3737E-01 .35225 -.0000396532.000 67 .0885 .94794 9.6234 -.365 9E-C

1

.35209 -.0000407536.000 68.4965 . 96061 9.8198 -.3584E-01 .35192 -.0000418540.000 69.9039 .97309 10.0161 -.3512E-01 .35175 -.0000428544.000 71.3105 .98537 10.2121 -•3443E-01 .35158 -.0003437548.000 72 .7165 . 99746 10.4079 -•3376E-G1 .35140 -.0000446552.000 74.1218 1.00937 10.6034 -.3312E-01 . 35122 -.0000454556.000 75.5263 1.02110 10.7987 -•3251E-01 .35104 -.0000462560.000 76.9301 1 .03265 10.9938 -.3191E-01 .35065 -.0000469564 . 000 78.3331 1.04402 11 .1886 -.3134E-01 .35066 -.0303476568.000 79.7354 1.05523 11.3333 - . 3 07 9E -0 1 . 35047 -.0000483572.000 81.1369 1.06627 11.5777 - . 3 02 5 E -0

1

.35028 -.0300489576.000 82.5376 1.07714 11.7718 -.2974E-01 .35008 -.0000495580.000 83.9375 1.08786 11 .966 8 -.2924E-C1 .34986 -.0000500

80

Table 10. Continued

hydrogen sulfide isochore at 10.000 hol/l

T P Z DP/DD DD/DT DP/DT D2P/0T?K MC& MPA-L /MOL MOL/L/K HP A /K M 0 A / K / K

350.667 6.0444 .11517 2.6721 -.1744E+00 .46610 .0001915352.000 6.6660 .12654 2.7658 - • 1 6 86 E >00 .46635 .0001803356.000 8.532e .16015 3.0453 ~ • 1 534 E 00 .46701 .0001514360.000 10.4019 .19306 3 .3227 -.1407E+00 .46757 .0001280364.000 12.2732 .22529 3.5985 - . 1 301 E +00 .46804 .0001034368.000 14.1462 .25685 3.8727 -.1210E+00 .46844 .0000916372.000 16.0206 .29776 4.1456 -.1131E+00 .46878 .0000770376.000 17.8963 .31803 4 .4174 - • 1062 E>00 .46906 .0000641380.000 19.7730 . 34768 4.6881 -. 1001E+00 .46929 . 0000527384.000 21 .6506 .37673 4.9578 - • 9470 E-0

1

.46948 .0000424380.000 23.5288 .40519 5.2266 -.8985E-01 .46963 .0000331392.000 25.4076 .43308 5 .4946 -• 8549E-01 .46975 .0000246396.000 27.2867 .46041 5.7617 -.8154E-01 .46983 .0000169400.000 29.166? .48720 6.0282 -.7795E-01 .46988 .0000098404.000 31 .0457 .51347 6.2939 - . 746 6 E-0

1

.46991 .0000033408.000 32.0254 .53922 6.5589 -.7164E-01 .46991 -.0000028412.000 34 . 8050 . 56446 6.8233 -.6887E-01 .46989 -.00000844 16.000 36.6845 .58922 7.0870 - . 6630E-0

1

.46964 -.0000136420.000 36.5637 .61351 7.3501 - ,6391 E-0 1 .46978 -.0000184424.000 40.4427 .63733 7.6127 -.6170E-01 .46970 -.0000229428.000 42. 3213 .66070 7.8747 -. 5963E-01 .46960 -.0000271432.000 44 .1994 .63363 8.1361 -

• 5770E-0

1

.46948 -.0000310436.000 46.0771 .70614 0 . 3970 -.5589E-01 .46935 -.0000347440.000 47 ,9542 .72822 8 .6574 -.5420F-01 .46920 -.0000302444.000 49.8307 .74990 8.9172 - . 5260E-C 1 . 46904 -.0000414448.000 51 .7065 .77118 9.1766 -.5109E-01 .46887 -.0000444452.000 53,9016 .79208 9.4355 -

• 4967 F-0

1

.46869 -.0000473456.000 55.4560 .81260 9 .6938 -.4833E-01 .46849 -.0000499460.000 57.3296 .83275 9.9518 -. 4706E-01 .46829 -.0000525464.000 59.2023 .85253 10.2092 -.4585 E-0

1

.46807 -.0000548468.000 61.0741 .97197 10.4662 - . 4 47 0 E-0

1

.46785 -.0000570472.000 62.9451 .89107 10.7227 - . 4 36 1 E-0

1

.46762 -.0000591476.000 64.9151 .90983 10.9788 -.4257E-01 .46738 -.0000611490.000 66.6841 .92827 11.2345 -.4150E-O1 .46713 -.0000629404.000 68.5521 .94638 11.4097 -.4063E-01 .46607 -.0000647488.000 70.4191 .96419 11.7446 - , 3 97 3 E-0

1

.46661 -.0000663492.000 72.2850 .98169 11.9990 -.3887E-01 • 4 6 6 3 -.0000679496.000 74.1498 .99009 12.2529 -.3804E-01 .46607 -.0000693500. OOC 76.0135 1.01581 12.5065 -.3724E-01 .46579 -.0000707

504.000 77.8761 1.03244 12.7597 -.364 8E-0

1

.46550 -.0000719

508.000 79.7375 1.04879 13.0124 - . 3 57 5 E -0

1

.46521 -.0000731

512.000 81.5978 1.06488 13.2640 -.3505E-01 .46492 -.0000743

516.000 83.4569 1.08070 13.5167 -.3437E-01 .46462 -.0000753

81


HYDROGEN SULFIDE ISOCHORE AT 20.000 MOL /L

T P Z DP/DO DD/DT DP/DT D2P/DT2K MPA NPA-L/MOL MOL /L /K MPA /K IP A /K /K

332. 918 4.3235 .07810 5.5111 -• 1 129E *00 .62217 .0000262336.000 6.2413 .11170 5.7819 -.1076E*00 .62223 .000018034C.000 9.7303 .15441 6.1321 -.101 5E*00 .62229 .0000082344.000 11.2195 .19613 6.4809 -.9602E-01 .62230 -.0000010348.000 13.7097 .23699 6.8284 -.9H3E-01 . 62228 -.0000095352.000 16.1977 .27672 7.1747 -.8672E-01 .62222 -.0000176356.000 18.6*64 .31565 7.5199 -.*273E-01 .62214 -.0000251360.000 21.174* .35371 7.8641 -.7 910 E-0

1

.62202 -.00003213 64.000 23.6626 .39093 8.2072 - . 7 577 E -0

1

.62188 -.0000397369.000 26.1498 .42732 8.5492 -•7272E-01 .62171 -.000044937? .000 28.6363 .4629? 8.8904 -.6991E-C1 .62152 -.0000507376.000 31.1220 .49775 9,2306 - . 6 73 1 E -0

1

.62131 -.0000552380.000 33.6067 .53183 9.5698 - . 6490E -0 1 .62107 -.00006143*4.000 36.0905 .56519 9 .90*3 -.6266E-01 .62082 -.00006623*8.000 3*. 5733 .59784 10.2458 - . 605 7 E -0 1 .62054 -.00007083 92.000 41.0549 .62981 10.5826 - . 5 86 1 E -0 1 .62025 -.0000751396.000 43.5353 .66112 10.9195 -. 5678E-01 .61994 -.0000792400.000 46.0144 ,69178 11.2536 -.5506E-01 .61962 -.0000331404.000 4e.492? .721*1 11.58*0 - • 5344 F-0

1

.61928 -.000036740* .000 50.9686 .75124 11 .9216 -.5192F-01 .61893 -.0000901412.000 53.4436 .78007 12.2544 -.5048E-01 .61856 -.0000933416.000 55.9171 . 80832 12.5866 - . 4 91 1 E -0 1 .61818 -.0000963420.000 58.3890 .83602 12.9190 -.4782E-01 .61779 -.000099?424 . 000 60.8594 .86317 13 .24*7 -.4660E-01 .61739 -.0001019428.000 63.3281 .89979 13.5787 -.4544E-01 .61697 -.0001044432.000 65.7951 .91589 13.9080 - ,443 3E-0

1

.61655 -.0001059436.000 68.2605 . 94149 14.2367 -.4328F-01 .61612 -.0001090440.000 70.7241 .96660 14.5647 -.4227E-01 .61568 -.0001112444.000 73.1659 . 99124 14 . 8920 -. 4131E-01 .61523 -.0001131449.000 75.6459 1.01541 15.2187 -•4040E-01 .61477 -.0001150452.000 78.1041 1.03913 15.5448 -.3952E-01 .61431 -.0001167456.000 80.5604 1.06241 15.8702 -.3 86 9 E-0

1

.51384 -.0001184460.000 83.014* 1.08525 16.1950 -.3787E-01 .61336 -.0001199

82

Table 10. Conti nued

.

HYDROGEN SULFIDE ISOCHORE AT 22.000 MOL/l

T P Z DR/DDK MPA MPA-L/MOL

309.602 2.6403 .04662 9.9105310.000 2.9667 .05232 9.9542312.000 4.6066 .09072 10.1739314.000 6.2461 .10875 10.39323 16.000 7. 9952 .13642 10.6123313.000 9.5240 .16373 10.8311320.000 11.1623 .19070 11.0496322.000 12.9002 .21732 11.2679324.000 14.4376 .24361 11.4859326.000 16.0746 .26957 11.7036329.000 17.7112 .29520 11.9210330.000 19.3473 .32051 12.1381332.000 20.9828 .34552 12.3550334.000 22.6179 .37021 12.5716336.000 24. 2525 .39460 12.7879339.000 25.8866 .41870 13.0040340.000 27.5202 .44250 13.2198342.000 29.1532 .46602 13.4354344.000 30.7857 .48925 13.6506346.000 32.4176 .51221 13.8656345.000 34.0490 .53489 14.08043 90.000 35.6798 .55731 14 .29493 52.000 37. 3100 .57946 14.5091354. OCO 3e . 9396 .60135 14.7231356. OOC 40.5696 .62299 14.9368359.000 42.1971 .64438 15 .1503360.000 43.8249 .66552 15.3635362.000 4.5.4520 .68641 15.5764364.000 47.0786 .70707 15.7891366.000 48.7045 .72749 16.0016368.000 50.3297 .74768 16.213e370.000 51.9543 .76765 16.4258372.000 53.5783 .78738 16.6375374.000 55.2015 .80690 16.8490376.000 56.8241 .82620 17,0602378.000 58.4460 .84529 17.27123eo.ooo 6 C . 067 3 .86416 17.48193 82.000 61 ,6e78 .88283 17.6924394.000 63.3076 .90129 17.9027386.000 64 . 9268 .91955 18.1127388.000 66.5452 .93762 18.3225390.000 68.1629 .95549 18.5321392.000 69.7798 .97316 18.7414394.000 71.3961 .99065 18.95053 96.000 73.0116 1 .00795 19.1594399.000 74.6263 1.02506 19.3681400.000 76.2404 1 .04200 19.5765402.000 77.8536 1.05875 19.7846404.000 79.4661 1.07533 19.9926406.000 81 .0779 1.09174 20.2003408.000 82.6889 1.10797 20.4078410.000 84.2992 1.12404 20.6151

DD/DT DP /DT D2P/DT2MOL/L/K MP A/K MP A/</<

-.9275E-01 .82008 -.0000913-.8238E-01 .82004 -.0000919-. 8058E-01 .81986 -.0000943-.78P7E-01 .81966 -.0000977- .772 2 E-0

1

.81947 -.0001006-.7564E-01 .81926 -.0001033-.7412E-01 .81905 -.0001064-.7267E-01 .81884 -.0001092-.7127F-01 ,81662 -.0001121-.6993E-01 .81839 -.0001149— .6863 E-0 1 .81816 -.0001176-•6738E-01 .81792 -.0001204- . 6 61 8 E -0

1

.81767 -.0001231- . 6 50 2 E -0

1

.81743 -.0001257-. 6390E-01 .81717 -.0001234-•6282E-01 .81691 -.0001309-• 6 1 77 E-0

1

. 81 665 -.0001335-•6076E-0 1 .8163e -.0001359-.5979E-01 .81610 -.0001334-•5884E-01 .81582 -.0001408-.5792E-01 .81554 -.0001431-.5703E-01 .81525 -.0001454-. 5617E-0

1

.81496 -.0001476-•5533E-01 .81466 -.0001493-•5452E-01 .81436 -.0001519-.5373E-01 .81405 -.0001540- . 5297E-0

1

.81374 -.0001560-.5222E-01 .31343 -.0001530-, 5150E-01 .81311 -.0001600-•5079E-01 .81279 -.0001613-. 5011E-01 .81246 -.0001637-.494 4 E — 0

1

.81214 -.0001655- . 4 87 9E-0

1

.81180 - • 0001

6

T 2- • 4 81 6 E -0 1 .81147 -.0001639-.4755E-01 .81113 -.0001705- . 4694 E-0

1

.81078 -.0001722— .4636E-01 .81044 -.0001737- . 4 57 9E-0

1

.81009 -.0001752-. 4523E-01 . 80974 -.0001767-.4469E-01 .80938 -.0001781- . 441 5 E-0

1

.80903 -.0001795-•4364E-01 .80867 -.0001 a 09- . 4 31 3 E -0

1

.80830 -.0001922-.4263E-01 .80794 -.0001334-.421 5E-01 .80757 -.0001 346— . 4 16 8 E -0

1

.80720 -.0001859-.4121E-01 . 80683 -.0001870-.4076E-01 .60645 -.0001331-.4032E-01 .80607 -.0001392-.3999E-01 .80569 -.0001902- . 3 94 6E -0 1 .80531 -.0001912- . 3 90 5 E -0

1

.80493 -.0001922

83

Tabl e 10 . Cont i nued .

hydrogen sulfide isochore at 24.000 hol/l

T P 7 DP/DD DD/DT DP/DT D2P/DT2K MPA MPA-L/MOL MOL /L/K MP A/K MP A/K /K

280.867 1.2862 .02295 16.212* - .6607 E -0

1

1 .07113 -.0001067282.000 2 .4995 .04442 16.3691 -.6542E-01 1.07092 -.00010392 84.000 4.6410 .08189 16.6456 -.6431E-01 1.07054 -.0001927266.000 6.7817 .11883 16.9217 -.6324E-01 1.07015 -.00019662 88.000 8.9216 .15524 17.1975 -.6220E-01 1.06975 -.0002004200.000 11.0607 .19113 17.4730 -.6120E-01 1.06935 -.0002041202.000 13.1990 .22652 17.7401 - .602 3 E -0

1

1.06894 -.0002079204.000 15.3364 .26141 18.C230 -.5929E-01 1.06852 -.0002116206.000 17.4730 .29582 18 .2975 -.5637E-01 1.06809 -.0002152208.000 19.6080 .32975 18.5717 - • 5749E-01 1 . 06765 -.0002188300.000 21.7436 .36321 18.8456 - . 566 3 E -0 1 1.06721 -.0002224302.000 23.8776 .39622 19.1192 -.55P0E-01 1.06677 -.0002259304.000 26.0107 .42878 19.3924 -•5499E-01 1.06631 -.0002293306.000 28.1428 .46089 19.6653 -. 5420E-01 1.06585 -.0002326308.000 30.2741 .49258 19.9378 -.5344E-01 1.06538 -.00023593 10.000 32.4044 .52383 20.2100 -.5269E-01 1.06490 -.0002392312.000 34.5337 .55468 20.4819 -.5197E-01 1.06442 -.0002423314.000 36.6620 .58511 20.7535 -.512 7 E-01 1.06394 -.0002454316.000 38.7894 .61515 21 .0247 -.5058E-C1 1.06344 -.0002484310.000 40.9158 .64479 21.2955 -.4991E-01 1.06294 -.0002514320.000 43.0412 .67404 21.5661 - • 492 6 E-0

1

1.06244 -.0002543322.000 45.1655 .70292 21.8363 -.4863E-01 1.06192 -.0002571324.000 47.2889 .73142 22.1061 -.4e01E-01 1.06141 -.0002590326.000 49.4112 .75956 22.3757 -.4741 F-01 1.06089 -.0002624328.000 51.5324 .73733 22 .6448 -.4683E-01 1 .06036 -.0002650330.000 53.6526 .81476 22.9137 - . 462 5 E -0 1 1.05983 -.0002675332.000 55.7717 . 84184 23.1822 - .4 56 9E-0

1

1.05929 -.0002700334.000 57.8897 .06858 23.4504 - . 4 51 5 E -0

1

1.05875 -.0002724336.000 60.0067 .89498 23 .71*2 -.4462E-C1 1.05820 -.0002747338.000 62.1225 . 92105 23.9857 -.4409E-01 1.05765 -.0002769340.000 64.2373 .94681 24.2529 -.4359E-01 1.05709 -.0002791342.000 66.3509 .97224 24.5198 -.4309E-01 1.05653 -.0002812344.000 68.4634 . 99736 24 .7863 -.4260E-01 1.05597 -.0002832346.000 70.5740 1.02218 25.0524 -.4213E-01 1.05540 -.0002852348.000 72.6850 1.04669 25.3183 -.4166 E-0

1

1.05483 -.00028713 50.000 74.7941 1.07091 25.5030 -.4121E-C1 1 .05425 -.0002889352.000 76.9020 1.09483 25 .84~90 - • 4076 E —0

1

1 .05367 -.0002907354.000 79.0087 1.11847 26. 113e -•4033E-01 1.05309 -.0002924356.000 81.1143 1.14183 26.3783 - . 3 990 E -0

1

1.05250 -.000294135e.OOO 83.2187 1.16491 26.6425 - .3 94 8 E -0

1

1.05191 -•003295 7

84



T P Z DP/DDK MPA MPA-L / MOL

2* 7.245 .**31 .00829 2*. 58*92*8 . 000 1 .*939 .02787 2*. 7180250. COO *.2765 .07913 25.070*252.000 7.0580 .12956 25 .*22325* .000 9.3382 .17917 25.7737256.000 12.6173 .22799 26.12*7258.000 15.3951 .27603 26. *751260.000 18.1717 .32331 26.8250262.000 20.9*70 .3698* 27.17**26*. 000 23 .7209 .*156* 27.5233266.000 26. *935 .*6073 27.8717268 . 000 29.26*6 .50513 28.2195270.000 32.03*6 .5*88* 28 . 5668272.000 3*. 8030 .591 89 28.913627*. 000 37.5699 .63*28 29.2599276.000 *0.335* .67603 29.6056278.000 *3.0993 .71716 29.9508280.000 *5.3617 . 75768 30.29552e2 .000 *8.6226 .79759 30.639728* .000 51 .3 820 .83692 30.9833286.000 5*. 1397 .87567 31.326*238.000 56.3958 .91386 31.6689290.000 59.6503 .951*9 32.0109292.000 62 .*032 .98859 32.352*29*. 000 65.15*3 1.02515 32.693*296.000 67.9039 1.06119 33.033829® .000 70.6517 1.09672 33.3737300.000 73.3976 1.13175 33.7130302.000 76.1*2? 1.16630 3*. 051930*. 000 78.88*8 1.20036 3*. 3902306.000 81.6257 1.23395 3*. 7279306.000 8* .36*8 1.26707 35.0652

DD/DT DP/DT D2 P/DT?MQL/L/K MPA /K M» A/K/K

-. 5661E-01 1.39178 -.00027*1-.5630E-01 1.39158 -.0002772-• 5 5* 8 E-0

1

1.39101 -.000285*- . 5 *6 9E -0

1

1.390*3 -.0002935-.5392E-01 1.3898* -.0003013-.5318E-01 1.38923 -.0003090- . 52* 5 E -0

1

1.38860 -.0003165-,517*E-01 1.38796 -.0003238-.5105E-01 1.38731 -.0003309*-.50388-01 1.3866* -.0003378-

.

* 97 3 E -0 1 1.38596 -.0003**5-.*909E-01 1.38526 -.0003511-.*8*7E-01 1.38*55 -.000357*-•*786E“01 1.38383 -.0003636-.*727E-01 1.38310 -.0003698- .* 66 9E-0

1

1.38235 -.000375*- . *61 3E-01 1 .38160 -.0003810-.*558E-C1 1.38083 -.0003365-.*50*E-01 1. 380C5 -.0003917-,**52E-01 1.37926 -.0003968- . **00E-0

1

1.378*7 -.000*018-.*350E-01 1.37766 -.000*065- . * 301 E-0

1

1.3768* -.000*111-,*253E-01 1.37601 -.000*158-. *206E-C1 1.37518 -.000*199-.*160E-01 1.37*33 -.000*2*0-.*115F-01 1.373*8 -.000*230- ,*071 E-01 1.37262 -.000*313-. *023E-01 1.37175 -.000*355-.3986E-01 1 . 37088 -.000*390-.39*5E-01 1 . 37CC0 -.000**2*-.3 90*E-01 1.36911 -.000**57

85


HYDPOGFN SULFIDE ISOCHORE AT 28.000 M L /

L

T P Z DP/DD OD/DT DP /DT D2P/DT2K MPA M&A-L/MCL MOL /L /K MP A/K MPA/K/K

209.883 .0869 .00178 34.8306 -.5184E-01 1.80569 -.0003661210.000 .2974 .00608 34.8572 -.5180E-01 1.80565 -.0003673211.000 2.1029 .04281 35.0854 -•5145E-01 1.60528 -.0003770212.000 3.9080 .07918 35.3134 -.5111E-01 1.80490 -.0003865213.000 5.7127 .11520 35.5410 - . 5077 E -0

1

1.80450 -.0003959214.000 7.5170 .15068 35.7685 - • 5044E-01 1.80410 -.0004051215.000 9.3209 .13622 35.9957 — • 501 1 E -0

1

1.80369 -.0004141216.000 11.1243 .22122 36.2227 -.4978E-01 1.80328 -.0004230217.000 12.9274 .25589 36.4494 — .4 94 6 E -0

1

1.80285 -.0004317218.000 14.7300 .29024 36.6759 - • 491 4 E “0

1

1.80241 -.00044032 19.000 16.5322 .32426 36.9021 -.4883E-01 1.80197 -.0004487220.000 18.3340 .35796 37.1281 -.4852E-01 1.80151 -.0004570221.000 20.1353 .39135 37.3538 -.4822E-01 1.80105 -.0004651222.000 21.9361 .42444 37.5793 ~ .4791 F-0

1

1.80058 -.0004730223.000 23.7364 .45721 37.8046 -.4762E-01 1.80011 -.0004 308224.000 25.5363 .48968 38.0296 -.4732E-01 1.79962 -.0004985225.000 27.3357 .52186 38.2543 -.4703E-01 1.79913 -.0004960226.000 29.1345 .65374 38.4788 - • 4 674 E-0

1

1.70863 -.0005034227.000 30.9329 .58533 38 .7031 -.4646E-01 1.79812 -.0005106228.000 32.7308 .61663 38.9271 — . 4 61 8E -0

1

1.79761 -.0005177229.000 34 . 52 e

1

.64765 39.1509 -.4590E-C1 1.797C9 -.0005246280. OCO 36.3250 .67840 39.3744 -.4563E-01 1.79656 -.0005315231 .000 38.1213 .70886 39.5977 -.4536E-01 1.79603 -.0005381232. OOC 39.9170 .73905 39.8207 -. 4509E-01 1.79548 -.0005447233.000 41 .7122 .76898 40.0435 -•4482E-01 1.79494 -.0005511234.000 43 . 5069 .79863 40.2660 -.445 6 E-0

1

1 .79438 -.0005574235.000 45.3010 .82803 40.4833 -.4430E-01 1.79382 -.0005636236.000 47.0945 .85716 40.7104 - . 440 5E-0

1

1.79326 -.0005696237.000 48.8875 .88604 40.9322 -.4380E-01 1.79268 -.0005755238.000 50.6799 .91467 41.1537 -.4355 E-0

1

1.79210 -.0005813239.000 52.4717 .94305 41.3750 -.4330E-01 1 .79152 -.0005970240.000 54.2629 .97118 41.5961 — . 4 306E-0

1

1.79093 -.0005925241.000 56.0536 .99906 41.8169 “,4281 E-0

1

1.79034 -.0005979242.000 57.6436 1.02671 42.0375 — .4257E-01 1.76973 -.0006033243.000 59.6330 1.05411 42 .2578 -.4234E-01 1.78913 -.0006085244.000 61 .4219 1 .08128 42.4779 -.4210E-01 1.78852 -.0006136245.000 63.2101 1.10822 42.6977 -•4187E-01 1.78790 -.00061 86246.000 64.9977 1.13493 42.9173 - • 4164 E-0

1

1.78728 -.0006234247.000 66.7846 1.16141 43.1367 -.4142 E-0

1

1.78665 -.0006282248.000 68.5710 1.18767 43.3558 -.4119E-01 1.78602 -.0006329249.000 70.3567 1.21370 43.5747 -.4097E-01 1.78539 -.0006374250.000 72.1417 1.2395’ 43.7933 -.4075E-01 1.76475 -.0006419251.000 73.9262 1.26512 44.0117 -.4054E-01 1.78411 -.0006463252.000 75.7099 1.29050 44.2299 -.4032E-01 1.78346 -.0006505253.000 77.4931 1.31567 44.4478 - . 4 01 1 E-0

1

1.78280 -.0006547254.000 79.2756 1.34064 44.6655 -.3990E-01 1.78215 -.0006588255.000 81.0574 1.36539 44 .8829 — .3969E-01 1 .76149 -.0006527256.000 82.8385 1.38995 45.1002 -. 3949E-01 1.78082 -.0006666257.000 84.6190 1.41430 45.3171 - . 3 92 8 E -0

1

1.78015 -.0006704

86


HYDROGEN SULFIDE ISOCHOPE AT 29.136 HOL/L

T P Z DP/DDK HP A MPA-L/MOL

1 87.660 .0232 .00051 41.3041192. OCO 9.1102 .19597 42.4564193.000 11.2027 .23961 42.7209194,000 13.2947 .28289 42.9850195.000 15.3861 .32571 43 .2488196.000 17.4771 .36808 43.5122197.000 19.5675 .41002 43.775219« .000 21.6573 .4515? 44.0379199.000 23.7466 .49259 44.3001200.000 25.8352 .53323 44.5620201.000 27.9233 .57346 44.8235202.000 30.0107 .61328 45.0946203.000 32.0975 .65269 45 .3454204.000 34.1837 .69171 45.6058205.000 36.2693 .73033 45.8658206.000 38.3541 .76856 46.1255207.000 40.4384 .80641 46.38472C8.000 42.5219 . 84389 46.6437209.000 44 .6047 .88099 46.9022210.000 46.6869 .91772 47.16042 11.000 48.7683 .95409 47.4182212.000 50.9490 .99010 47.6756213.000 52.9290 1.02577 47.9327714.000 55.0082 1 .06109 48.1895215.000 57.0867 1 .09605 48.44582 1 * . 000 59.1644 1.13068 48.7019217.000 61 .2414 1.16498 48.9575218.000 63.3176 1 .19e95 49.2127219.000 65.3930 1.23260 49 .4677

220.000 67.4676 1.2659? 49.7222221.000 69.5414 1.29893 49.9764222.000 71.6144 1.33163 50.2303223.000 73.6866 1.36401 50 .4e38

224.000 75.7580 1.39609 50.7370225.000 77.9286 1.42788 50.9899226. OOC 79.9983 1.45936 51.2422227.000 81 .9672 1.49056 51 .4943

228.000 84.0352 1 . 52146 51.7461

DD/DT DP/DT 02P/DT2MOl/L/K H P A / K HP A /< K

-.5072E-01 2.09475 -.0004265-.4929E-01 2.09275 -.0004931-.4897E-01 2.09225 -.0005076-.4866E-01 2.09174 -.0005218-.4835 E -0

1

2 .09121 -.0005357-.4805E-C1 2.09066 -.0005493-.4775E-01 2.09011 -.0005626-.4745E-01 2.08954 -.0005757-.4715E-01 2.08896 -.0005834- . 468 6E -0

1

2.09836 -.0006008-.4658E-01 2.08776 -.0006130-.4629E-01 2.08714 -.0006249- .460 1 E-C

1

2.08651 -.0006366-.4574E-01 2.09586 -.0006479-.4546E-01 2.08521 -.0006591-.4519E-01 2 . 0 fl 4 5 5 -.0006699-.4493E-01 2.08387 -.0006905-.4466E-01 2.09318 -.0006909- • 4 440 E—0

1

2 . 08 ?49 -.0007011-.4414E-01 2.08178 -.0007110-.4389E-01 2.08107 -.0007206- . 4 364 E -0

1

2.08034 -.0007301-.4339E-01 2.07961 -.0007393-.4314 E—0

1

2 . 0 7 8 P 6 -.0007483- .4 2 90 E -0 1 2.07811 -.0007571-.4265E-01 2.07735 -.0007657-.4242E-01 2.07658 -.0007741-.4218E-01 2.07580 -.000792?-.4195E-01 2.07501 -.0007902-.4172 E -0

1

2.07422 -.0007930-.4149E-01 2.07342 -.0009056-. 4126E-01 2.07261 -.0009129-.4104E-01 2.07179 -.0008202-.4082E-01 2.07097 -.0008272- . 406 0 E -0

1

2.07014 -.0008340- . 403 8E-01 2.06930 -.0009407-.4017E-01 2.06846 -.0008472-. 3996E-01 2.06761 -.0003536

87

Table 11. Calculated P(p) isotherms of hydrogen sulfide

HYDROGEN SULFIDE ISOTHERM AT 200.000 K

DEN P Z DP/DD DO/DT DP/DT D2P/DT2MOL /L MPA MPA-L/MOL MOL/L/K MPA/K MO A /< /K

.031 .0503 .98861 1 .6233 -.1585E-03 .00026 -.0000001

28.508 .0503 .00106 37.6755 -.5121E-01 1.92988 -.000392128.600 3.5581 . 07881 38.6839 - . 5 05 1 E-0

1

1.95206 -.000819828.700 7,8758 .15668 39.7128 - . 897 8 E -0 I 1.97689 -.000850828.800 11.5012 .28015 80.7978 -.89C7E-01 2.00200 -.000882728.900 15.6358 .32535 81.3989 -.8839E-01 2.02738 -.000516329.000 19.8815 .81227 83.0163 -.8773E-C1 2.05303 -.000551329.100 28.2397 .50092 88.1501 -.8709E-01 2.07897 -.000537529.200 28.7120 .59131 85.3008 -.8687E-01 2.10518 -.000825029.300 33.3003 .68386 86.8673 -.8587E-01 2.13166 -.000663329.800 38.0061 .77739 87.6509 -.8530E-01 2.15882 -.000708029.500 82.8310 . 87311 88.8513 -.8878E-01 2.18586 -.000785829.600 87 .7769 .97068 50 .0687 -.8819E-01 2.21277 -.000733129.700 52.8853 1.07000 51.3031 -.8367E-01 2.28036 -.000332029.800 5B.03ei 1.17120 52.5586 -.8316E-01 2.26823 -.0008773

88

Table 11. Continued


DEN P Z DP/DO DD/DT DP/OT D 2 p / D T 2

MOL/L MPA MPA-l/MDL MOL /L /K HP A /K M P A / K / K

.051 .0879 .98202 1.6806 -. 2568E-03 .00093 -.0030001

27. 999 .0873 .00179 39.7979 -.5185E-01 1.80927 -.000365028.000 .2979 .00608 39.8572 -.5180E-01 1.80565 -.000357328.100 3.8331 .07812 35.8582 -.5100E-01 1.82061 -.000391729.200 7.9696 .15170 36.9797 -.5022E-01 1.95182 -.000917328.300 11.208'i .22663 37.9069 - . 9997 E-0

1

1.87530 -.00G949128.900 15.0515 .30353 38.9597 -• 9 97 5 E-0

1

1 .99909 -.000971928.500 19.0000 .38182 90.0105 -. 9805E-01 1 .92303 -.000500928.800 23.0557 .96170 91 .0961 -.9738E-01 1.99729 -.000530928.700 27.2202 .59319 92.1938 -.9673E-01 1.97181 -.000562028.800 31.9950 .62632 93.3056 -.9610E-01 1.99659 -.000599328.900 35.8819 .71109 99.9337 -. 9550E-01 2 .02169 -.000627729.000 90.3823 .79751 95.5700 -.9991E-C1 2.09695 -.000662229.100 99 . 9980 .88561 96 .7380 -.9939E-01 2.07252 -.000697929.200 99.7306 .97591 97.9161 - . 9 37 9 E -0

1

2.09836 -.000739529.300 59.5618 1.06690 99.1100 -.9326 E-0

1

2.12996 -.000772529.900 59.5532 1.16012 50.3206 -.9279E-01 2.15Ce2 -.000811529.500 69.6965 1.25507 51 .5901 -.9229 F -0

1

2.17795 -.000851529.800 69.9633 1.35177 52.7925 - .9175E-0 1 2.20935 -.000892729.700 75.2055 1.95023 59.0539 -.9129F-01 2.23150 -.000935029.800 80.6797 1.55098 55.3329 - . 9 09 2 E-0

1

2.25893 -.0009789

89

Tab! e 11. Conti nued

.


DEN P Z DP/DD DD/DT DP/DT D2P/DT2MOL /L MPA MPA-L /MOL MOL/L/K MPA /K mo A /K K.081 .1435 .97312 1.7269 -.3992 E-03 . 00069 -.0000003

27.473 .1435 .00286 31.9745 -.5273E-01 1.68589 -.000340627.500 1.0109 .02010 32 .2284 -.5249E-01 1.69165 -.000345927.600 4.2610 .08480 33.1778 -. 5164E-01 1.71314 -.000366327.700 7.6469 .15092 34.1424 -.5081E-01 1.73486 -.000387527.800 11.1100 .21848 35.1222 -. 5C02E-01 1.75683 -. 000409 7

27.900 14.6718 .28749 36.1174 -.4926E-01 1.77905 -.000432928.000 18.3340 .35796 37.1281 -.4852E-01 1.80151 -.000457028.100 22.0980 .42992 38.1543 -.4781E-01 1.82422 -.000482028.200 25.9654 .50337 39.1962 - • 471 3 E-0

1

1.84718 -.000508028.300 29.9370 .57833 40.2537 -.4647E-01 1.87039 -.000535028.400 34.0167 .65481 41.3271 -.4583E-01 1 .89385 -.000562928.500 38.2037 .73283 42.4164 -.4521E-01 1.91755 -.000591728.600 42.5005 .81240 43.5217 -.4461E-01 1.94151 -.000621528.700 46 .9086 .89354 44.6431 -.4403E-01 1.96572 -.000552428.800 51.4297 .97625 45.7807 -.4347E-01 1.99018 -.000684228.900 56.0653 1.06056 46.9345 -•4293F-01 2.01490 -.000716929.000 60.8171 1 . 14649 48.1047 -.4240E-01 2 .03987 -.000750629.100 65 . 6866 1.23403 49.2913 -.M90E-01 2.06509 -.000705329.200 70.6759 1.32321 50.4945 -.4140E-01 2.09056 -.000820929.300 75.7862 1.414C5 51 . 71*3 -.4092E-C1 2.11629 -.000857529.400 81.0193 1.50655 52.9509 -.4046E-01 2.14227 -.0008950

90



DEN P Z DP/DD DD/DT DP /DT D2 P/DT2MOL /L MPA MP A-L/MOL MOL /L /K MP A/K MP A /K /<.100 .1939 .97155 1.8784 -.4547E-03 .00085 -.0000003.179 .3375 .94745 1.7798 -.8819F-03 .00157 -.0000014

26.401 . 3375 .00641 26.5036 -.5533E-01 1 . 46643 -.000291726.500 2.9956 .05665 27.3261 -.5434E-01 1.48485 -.000305326.600 5.7704 .10871 28.1733 -.5337E-01 1.50372 -.000319726.700 8.6307 .16199 29.0349 -.5245E-01 1.52281 -.000334026.800 11 .5779 .21649 29.9110 -. 5156E-01 1.54210 -.000350526.900 14.6134 .27224 30.8019 -.5070E-01 1.56162 -.000366927.000 17.7383 .32924 31. 7075 - .4 987 E — 0

1

1.58135 -.000333927.100 20.9554 .38751 32 .6280 - • 4 90 8 E-0

1

1.60130 -.000401627.200 26.2649 .44706 33.5634 -.4831E-C1 1.62147 -.000420027.300 27.6686 .50790 34.5139 - .4757E-C 1 1.64186 -.000439127.400 31.1682 .57005 35.4795 -.4686E-01 1.66248 -.000450927.500 34 .7650 .63352 36.4604 -.4617E-01 1.68332 -.000479427. fcOO 38.4607 .69833 37.4566 -.4550E-01 1.70439 -.000500627.700 42.2568 .76449 30.4681 -.4486E-01 1.72568 -.000522527.600 46.1549 . 83200 39.4952 -.4424E-01 1.74720 -.000545127.900 50.1563 . 90090 40.5378 -.4364E-01 1.76895 -.000560428.000 54.2629 .97118 41.59fel -.4306E-01 1.79093 -.000592528.100 58.4761 1.04286 42.6701 -.4249E-01 1.01314 -.00061732 . 2 00 62,7975 1.11595 43.7599 — .4195E-0

1

1.03558 -.000642823.300 67 ,22efc 1.19048 44.8655 -.4142E-01 1.85825 -.000669128 . 400 71 .7712 1 .26644 45.9872 -.4091E-01 1.88116 -.000696128.500 76.4266 1.34386 47.1249 - , 404 1 E-0

1

1.90430 -.000723026.600 81.1967 1.42274 48.2787 -.3993E-01 1.92767 -.0007523

91

Tab! e 11. Cont i nued

.


DEN P Z DP/DD DD/DT DP/OT D2P/DT2MOL /L MPA MP A-L /MOL MOL/L/K MP A /K MPA/K/K.100 .2109 .97559 2.0536 -.4135E-03 . 00085 -.0000002.200 .4106 .94975 1.9409 -.8998E-03 .00175 -.0000010.300 . 5991 .92374 1.8280 -.1480F-02 .00271 -.0000030.349 .6875 .91095 1.7725 - .1 807E-02 .00320 -.0000045

25.272 .6875 .01258 21 .2991 - • 5 94 2 F-0

1

1.26562 -.000242425.300 1.2967 .02371 21.5015 - . 590 8 E-0

1

1.27022 -.00024522 5 . A 00 3 .4827 .06343 22.2211 -.578 9 E — 0

1

1.28648 -.000255125.500 5.7414 .10415 22.9541 - . 5676E-0 1 1.30293 -.000265525.600 8.0740 .14589 23.7007 - . 556 9E-0

1

1.31956 -.000276325.700 10.4820 .18867 24.4609 - • 546 3 E-0

1

1.33638 -.000237525.800 12.9667 .23249 25 .2350 - • 5 36 3 E-0

1

1.35338 -.000299125.900 15.5294 .27736 26.0230 - • 5267E-0

1

1.37058 -.000311226.000 18.1717 .32331 26.8250 -.517 4 E-0

1

1 . 38796 -.000323826.100 20.8949 .37033 27.6412 - . 508 5 E-0

1

1.40554 -.000336826.200 23.7004 .41845 28.4716 -.4999E-01 1.42332 -.000350226.300 26.5897 .46768 29.3164 - . 49 1 6E -0

1

1.44129 -.000364226.400 29.5642 .51803 30.1756 -.4837E-01 1.45946 -.000378626.500 32.6253 .56951 31.0495 -.4760E-01 1.47782 -.000393626.600 35.7746 .62213 31.9380 -.4685E-01 1.49639 -.000409026.700 39.0134 .6759? 32.8412 -.4614E-01 1.51516 -.000425026. POO 42.3433 .73087 33.7593 -•4544E-01 1.53414 -.000441426.900 45.765R .78701 34.6924 -.4477E-01 1.55331 -.000458427.000 49.2823 .84434 35.6405 -.4413 E -0

1

1.57270 -.000475927.100 52.8944 .90288 36.6037 -•4350E-01 1.59229 -.000494027.200 56.6035 .96264 37.5821 - . 42 90 E -0

1

1.61209 -.000512627.300 60.4113 1.02364 38.5759 -.42316-01 1.63210 -.000531727.400 64.3192 1.08588 39.5850 -•4174E-01 1.65232 -.000551427.500 68.3288 1.14937 40.6095 -.4119E-01 1.67275 -.000571627.600 72.4416 1.21414 41.6496 - . 4 06 6 E -0 1 1.69340 -.000592427.700 76.6593 1.28019 42.7053 -.4014E-01 1.71426 -.000613827. POO 80 . 9832 1 .34754 43 .7766 -.396 4 E-0

1

1 .73 533 -.0006357

92

Table 11. Continued.HYDROGEN SULFIDE ISOTHERM AT 280.000 K

DEN P Z DP/DD DD/DT DR /DT 02 R/DT2POL /L MPA MPA-L/MOL MOL /L /K MP A/K MPA / K / K.100 . 2 2 7 <5 .97872 2.2270 -.3799E-03 .00085 -.0000001.200 .**5* .9565* 2.1238 -.81*5E-03 .00173 -.0000007.300 .6527 .93*52 2 .0226 -.1315E-02 .00266 -.0000018.*00 . 8*<5<5 .91272 1.9228 -.1 89*E-02 . 0036* -.0000037.500 1.0373 .89110 1.8237 - . 2 56 8E -0 2 .00*68 -.0000066.600 1.21*7 .86960 1.72*8 -.3359E-02 .00579 -.0000110.62* 1.2556 . 86**9 1.7011 -.3568E-02 .00607 -.0000123

2*. 055 1.2556 .022*2 16. *159 -.6573E-01 1.07897 -.00018922*. 100 1 . <5<55 <5 .03557 16.680* -.6506E-01 1.08521 -.00019262* .200 3.6938 .06556 17 .2805 - • 6 36 1 E-C

1

1.09929 -.00020032*. 300 5. *52* .09638 17.8928 -.6223E-01 1.11352 -.00020832*. *00 7.2728 .12803 18.5173 -.6091E-01 1.12790 -.00021652*. 500 9.1562 .16053 19.15*3 -,596*E-01 1. 1*2*5 -.00022*92* .600 11.10*1 .19389 19.80*0 - . 5 8* 3 E-0

1

1.15715 -.00023362*. 700 13.1175 .22812 20. *663 -• 5727E-0 1 1.17202 -.0002*252*. 800 15.1977 .26323 21.1*15 -.5615E-01 1.18705 -.00025172*. <500 17.3*62 .29923 21.829e -. 5507E-01 1.20225 -.000261225.000 19.56*1 .3361* 22.5312 -.5*0*E-C1 1.21761 -.000271025 . 100 21.8529 .37397 23.2*58 - . 5 30 5 E-0

1

1.23315 -.000281125.200 2* .2138 .*1273 23.9739 -.5209E-01 1.2*885 -.000291525.300 26.6*81 .*52*3 2*. 7155 -.5117E-01 1.26*73 -.000302125. *00 29.1573 .*9308 25 .*707 -.502 8 E-0

1

1 .2807e -.000313225.500 31.7*27 .53*70 26.2397 -.*9*3E-01 1.29701 -.00032*525.600 3* .*057 .57729 27.C226 - . * 860 E -0

1

1.313*1 -.000336225.700 37.1*77 .62088 27.6196 - . *78 1 E-0

1

1 .37999 -.0003*3225.800 39.9701 .665*6 28.6306 -,*70*E-01 1.3*676 -.000360625. <500 *2.97*3 .71105 29. *559 -.*630E-01 1 . 36370 -.000373*26.000 *5.8617 .75768 30.2955 -.*558E-01 1.38083 -.000386526.100 *8.9339 .80533 31.1*96 -.**8 8 E-0

1

1.3991* -.000*00026.200 52.0922 .95*0* 32 .0182 - • **2 1 E-0

1

1 .*1 56* -.000*13926.300 55.3330 . 90380 32.9015 -.*356E-01 1 .*3333 -.000*20126. *00 58.6729 .95*6* 33.7995 - . *2 9* E-0

1

1 .*5121 -.000**2826.500 62.099* 1.00656 3*. 712* -.*2?3E-01 1 .*6927 -.000*57926.600 65.6159 1.05958 35.6*02 - .* 1 7* E-0

1

1 .*8753 -.000*73326.700 69.2270 1.11370 36.5831 -.*117 E-0

1

1.50598 -. 000**92

26.800 72 .9330 1.16895 37.5*10 - . * 06 1 E-0

1

1.52*63 -.000505526. <500 76.7357 1.22532 39.51*2 - . *00 8 E-0

1

1. 5*3*7 -.0005222

27.000 90.636* 1 .2 82 8* 39.5026 - . 3 95 5 E -0 1 1.56250 -.000539*

27.100 8*. 6367 1.3*151 *0.506* -.3905E-01 1.5817* -.0005570

93

Tabl e 11. Cont i nueu .

hydrdgfn sulfide isothep m at 300.000 k

DEN P Z DP /DD DD/DT DP/DT D2P/0T2MOL /L MPA MP A-L /MOL MOL/L/K MP A /« MP A/K/K.?00 .4799 .96189 2.3036 -.7462E-03 .00172 -.0000004.400 . 922 1 .92424 2 .1210 -.1689E-02 .00358 -.0000024.600 1.3287 .88781 1.9454 -.2891E-02 . 00562 -.0000066.800 1.7005 . 85218 1.7727 -.4439E-02 .00787 -.0000140

1.000 2.0378 .81696 1.5999 -.6469E-02 .01035 -.00002641.045 2.1088 .80907 1.5608 -.7011E-02 .01094 -.0000301

22.710 2.1038 .03723 11.9162 - . 7 57 3 E -0 1 .90244 -.000126922.800 3.1962 .05620 12.3389 - • 7401 E -0

1

.91317 -.000133123.000 5.7606 .10041 13.3119 - . 7 04 2 E -0

1

.93748 -.000147023.200 8.5238 .14730 14.3280 -. 6716E-01 .96233 -.000161223.400 11 .4947 .19694 15.3882 -.6419E-01 .98771 -.000175723.600 14.6821 .24941 16.4937 -.6146E-01 1.01364 -.000190723.800 18.0953 .30481 17.6458 - . 5 895 E -0

1

1.04014 -.000206224.000 21. 7436 .36321 18.8456 -.5663E-01 1.06721 -.000222424.200 25.6368 .42471 20.0943 -.5449E-01 1.09488 -.000239224.400 29.7847 .48938 21.3931 -.5250E-01 1.12316 -.000256824.600 34.1974 .55732 22.7430 -.5066E-01 1.15205 -.000275124.800 38.8854 . 62860 24.1452 -.4894E-0 1 1.18157 -.000294425.000 43.8591 .70334 25.6008 -.4733E-01 1.21174 -.000314625.200 49.1293 .78160 27.1106 -.4583E-01 1.24256 -.000335825.400 54.7070 .86348 28.6759 -.4443 E-0 1 1.27405 -.000358125.600 60 . 6034 . 94907 30.2974 -.4311E-01 1.30621 -.000381525. 800 66 . 8298 1 .03847 31.9762 -.4188E-01 1.33907 -.000406026.000 73.3976 1 .13175 33.7130 - . 4 07 1 F -0 1 1.37262 -.00043ie26.200 80.3190 1.22902 35.5088 - . 3 962 E -0 1 1.40689 -.0004589

94

Taule 11. Continued.


DEN p Z DP/DD DD/DT DP /DT 02 0 !~) T?MOL /L MPA MPA-L/MHL MOL /L /K MP A/K MP A K /K.200 .5142 .96623 2.4811 -.6698E-03 .00171 -.0000003.*00 . 9934 .93341 2.3132 -. 1532E-C2 .00354 -.0000016.600 1 .4400 .90206 2.1544 -.256QE-02 .00552 -.0000044.800 1.6585 .87172 2.0004 - . 3 82 2 E -0 2 .00764 -.0000099

1.000 2.2403 .84203 1.8485 -.5379E-02 .00994 -.00001591.200 2 .594 9 .81274 1 .6971 -.7318E-02 .01242 -.00002561.400 2.9192 .78370 1.5456 -.9765E-C2 . 01509 -.00003941.600 3.2131 .75478 1.3935 - . 1290E-C

1

• 01 7 9 p -.00005331.677 3.3178 .74370 1.3349 -.1435E-01 .01915 -.0000633

21.166 3.3178 .05892 7.8623 - . 930 8 E -0 1 .73182 -.000046021.200 3.5884 .06362 7.9809 -.9213E-01 .73525 -.000049721. *00 5.2554 .09230 8.6948 - • 8 690 E -0

1

.75555 -.000063721.600 7.0686 .12300 9.4434 -.8220E-01 .77628 -.000079221.800 9.0352 .15577 10.2280 -.7797E-01 .79744 -.000092422.000 11.1623 .19070 11 .0496 -.7412E-01 .81905 -.000106422.200 13.4576 •227e4 11.9095 - . 706 3 E -0

1

. 84112 -.000120222.400 15.9287 .26727 12.8088 -.6743E-01 .86367 -.000134122.600 18.5838 .30906 13.7488 -.6449E-01 .88669 -.000143022.800 21.4310 .35323 14. 7305 -.6179E-01 .91022 -.000162123.000 24.4789 .40002 15.7552 -• 5930E-01 .93425 -.000176523.200 27.7361 .44934 16.8242 5699E-01 .95880 -.000191223.400 31 . 2116 .50132 17.9396 -. 5485E-01 .98389 -.000206223.600 34.9146 .55604 19.0995 -.5285E-01 1.00950 -.000221723 .800 38.8546 .61359 20.3093 -.5100E-01 1.03569 -.000237724.000 43.0412 .67404 21 .5661 - . 4 92 6 E -0

1

1.06244 -.000254324.200 47.4843 .73748 22.8740 -.4764E-01 1 . 08976 -.000271424.400 52.1942 . 90398 24.2331 -.4612E-01 1.11768 -.000289324.600 57.1811 .87364 25.6446 -.4470E-01 1.14620 -.000307924 . 800 62.4556 .94653 27.1096 -.4336E-01 1.17534 -.000327325.000 68.0286 1 .02274 28.6291 — . 4209E-01 1.20510 -.000347525.200 73.9110 1.10236 30.2041 -.4090E-01 1 .23 550 -.000369625.400 80.1140 1.18546 31.8356 - . 3 97 8 E -0

1

1.26654 -.0003906

95

Table 11 Continued


DEN P Z DP/DO DD/DT DP/DT D2 P/DT2MOL/L MPA MPA-L/MPL MOL /L /K MPA /K MP A /K /K

.400 1.0640 .94091 2.5014 - • 1 40 5 E-02 .00352 -.0000012

.POO 2.0068 .88736 2.2166 -.3382E-02 .00750 -.00000621.200 2.8389 .83686 1.9448 -.6175E-02 .01201 -.00001661.600 3.5630 .78773 1 .6759 -.1019E-01 .01708 -.00003452.000 4.1799 .73930 1.4092 - . 1 61 5E -0 1 . 02275 -.00006322.400 4.6909 .69141 1.1469 -.2533E-C1 .02906 -.00010932.652 4.9599 .66148 .9849 -.3391E-01 .03340 -.0001541

19.274 4.9599 .09103 4.3202 -•1299E+00 .56118 .000078519.600 6.4897 .11713 5.0897 - . 1 15 5 E 00 .58804 .000044320.000 8.7303 . 15441 6.1321 -.1015E+00 .62229 .000008220.400 11.4105 .19786 7.2885 -.9027E-01 .65796 -.000023720.900 14.5774 .24791 8.5669 -.8114E-01 .69516 -.000052921.200 18.2815 .30504 9.9758 -.7357E-01 .73395 -.000090321.600 22.5766 .36973 11.5237 -.6720E-01 .77442 -.000107022.000 27.5202 .44250 13 .2198 -.6177E-01 .81665 -.000133522.400 33.1734 . 52397 15.0733 -.5710E-01 .86072 -.000160222 .800 39.6011 .61441 17.0936 - . 5 304 E-0

1

.90671 -.000187923.200 46.8720 .71468 19.2909 -.494 9 F -0

1

.95471 -.000216523.600 5 5 . 0 5 e6 .82527 21.6740 - .463 6 E-0

1

1.00481 -.000246924.000 64.2373 .94681 24.2529 -•4359E-01 1.05709 -. 000279124.400 74 .4882 1.07990 27.0368 - . 4 1 12 E -0

1

1.11164 -.0003137

96



DEN D Z DP/DDMOL /L MPA mpa-l/mol.*00 1.13*0 .9*718 2.6868. 800 2.1556 .90021 2. *253

1.200 3 .0761 .856*1 2.17821.600 3.8986 .81*05 1.93*62.000 * .62*2 .772** 1.69362. *00 5.25*1 .73139 1 . *5712.800 5.7910 .69097 1.229*3.200 6.2393 .651*0 1.01*33.600 6.60*6 .61292 .8152*.000 6.8939 .57579 .63*?*.*00 7.11*5 .5*020 .*718* .*36 7.1312 .53707 .*581

16.567 7.131? .1*381 1.396316 .800 7. *861 .1*887 1.6*8*17.200 8.2*01 .16005 2.133217.600 9.2022 .17*68 2.689*18.000 10. *019 .19306 3.322718. *00 11.871* .21555 *.039118.800 13.6*51 .2*2*8 *.8**719.200 15.7600 .27*23 5 .7*6119.600 18.2557 .31117 6.750220.000 21.17*8 .35371 7.86*120. *00 2*. 5626 .*0226 9.095520.800 28 .*679 .*5725 10 .*52521.200 32.9*26 .5191* 11.9*3621.600 38.0*19 .588*0 13.577522.000 *3.82*9 .6655? 15.363522. *00 50.35*2 .75102 17.310822 .800 57.6962 .8*5*2 19. *29123.200 65.9215 .9*929 21.728023.600 75 . 1 C *0 1.06319 2*. 2173

DD/DT DP/DT D2P/DT2MOL /L /K MP A/K MPA/K/K

-•1301E-02 .003*9 -.0000009-• 30*8E-02 .00739 -.00000*5- • 5 3 85 E-02 .01173 -.0000117- • 853 6E-02 .01652 -.0000231-.128*E-01 .02175 -.0000398-.1881E-01 .027*1 -.0000625-.2723E-01 .033*8 -.0000931-.3936E-01 .03993 -.00013*0-.5733E-01 .0*67* -.0001903-.8502E-01 .05392 -.00027?*- • 1 30 *E + C0 .06153 -.000*068-.1359E+00 .0622* -.000*236

-.2691E+00 .37570 . 00037*9-.236*E+00 .3897* .0003132-.19*3E+00 .*1*59 .00023*?-. 1638E + 00 .**051 .0001752-.l*07E+00 .*6757 .0001280-.122 8E *00 .*9583 .000088*-.108*E*C0 .52536 .0000539-. 9679E-01 .55619 .0000229-.8717E-01 .588*0 -.0000055- • 791 OE-0

1

.62202 -.0000321-.7225E-01 .6571* -.0000575-.6638E-01 .69380 -.0000823-.6129E-01 .73207 -.0001067- • 5 686 E-0

1

.77203 -.000131?- . 5 2 97 E “0

1

.8137* -.0001560- . * 95 2 E “0

1

.85729 -.0001816--.*6*6E-01 .9027* -.0002082“.*373E-01 .95018 -.000236?“,*128E-C1 .99967 -.0002657

97



DEN P Z DP/DD DD/DT DP/DT D2P/DT2MOL/L MPA MPA-L /MOL MOL/L/K MPA /K MP A/K/K.*00 1.1515 . 9*859 2.7328 - . 1 277E-02 .003*9 -.0000008.800 2.1925 .90308 2 .*766 -.2976E-02 .00737 -.00000*2

1.200 3.13*6 .8607* 2.2350 -.5223E-02 .01167 -.00001081.600 3 .9809 .81985 1 .9970 -•8216E-02 .016*1 -.00002122.000 *.7325 .77970 1.7611 -.122*E-01 .02156 -.00003602. *00 5.390* .7*009 1.5297 - • 1 773 E-0

1

.02712 -.00005602.800 5.9573 .70107 1.3066 -.2529E-01 .0330* -.00009193.200 6. *373 .66287 1 .0958 -.3587E-01 .03930 -.00011513.600 6.8361 .62571 .9008 - . 5093E-0

1

. 0*587 -.0001578*.000 7.1603 .58985 .7237 - . 7 2 8*E-0

1

.05272 -.0002139*.*00 7. *176 .55550 . 5658 - • 1 057 E 00 .05982 -.0002908* .800 7.6155 .52279 .*270 -.1573E+00 .06719 -.000*0515.200 7.7616 .*918* . 3065 -.2***E+00 .07*89 -.00060115.238 7.7730 .*8900 .2959 -.2556E+00 .07565 -.0006277

15.5*2 7.7730 .16*80 .793* -.*0**E*00 .32081 .000578515.600 7.8205 .16519 .83*7 -.3880E+00 .32386 .000550316.000 8.2153 .16919 1.1*85 -.3006E+00 . 3*530 .000*05716. *00 8.7*68 .1757* 1.5186 -•2*21E+00 .36769 .000310816.800 9. *38* •1*512 1.9501 — .2006E*00 .39112 .0002*1517.200 10.3158 .19763 2 , **8* -.1698E+0Q .*1563 .000187117.600 11 .*068 .21356 3.0189 - • 1 *62 E 0 0 .**130 .0001*2318.000 12.7*13 .2332* 3.6671 -.1277E+00 .*6815 .000103918. *00 1* .3516 .25701 * .3991 -.1128E+00 .*9623 .000070118 . 800 16.2725 .28521 5.2209 -.100?E+00 .52559 .000039519.200 18.5*12 .31821 6.1391 - . 906 1 E-0

1

.55628 .000011319.600 21.1976 .35637 7.1606 -. 8216E-01 ,58e3* -.000015120.000 2* .26*5 .*0010 8 .2928 -,7*99E-01 .6218* -.0000*0320. *00 27.8*76 .**981 9.5*32 -.68S3E-C1 .65693 -.00006*620.800 31 . 9359 .50593 10.9200 -•6350E-C

1

.69337 -.000083621.200 36.6016 .56890 12. *317 -,580*E-O1 .73152 -.000112*21.600 *1 . 900* .63920 1* .0871 -,5*76E-01 .77136 -.000136*22.000 *7.8916 .71731 15.895* -. 511*E-01 .81295 -.000160922. *00 5* .6383 .80375 17.8660 - .*793E-0

1

.95637 -.000186222.800 62.2073 . 8990* 20.0086 - . * 507 E-0

1

.90169 -.000212623.200 70.669* 1.00372 22.3328 — ,*2*9E-01 . 9*898 -.0002*0323.600 80.0991 1.11837 2*. 8*83 - . *01 8E -0

1

.9983* -.0002696

98

Tabl e 11. Cont i n ued

.


DEN P Z DP/DD“HL /L mpa MPA-L/MOL.400 1.1689 .94994 2 .7787.800 2.2293 .90583 2 .5275

1.200 3.1928 .86489 2.29121.600 4.0627 .82539 2.05852.000 4 .3398 .78662 1.82762.400 5.5253 .74836 1 . 600 e

2.800 6.1215 .71067 1.38193.200 6.6325 .67373 1 .17503.600 7.0636 .63780 .98324.000 7.4214 .60310 .80914 . 400 7.7133 . 56984 . 65374.800 7.9469 .53817 .51745.200 8.1298 .50820 .39975.600 8.2690 ,47999 .29956.000 8.3715 .45354 .21536.400 8.4432 .42883 .14546.542 e . 4622 .42049 .1236

14.032 8.4622 .19604 .270214.400 8.5660 .19382 .40^014.800 8 .7844 .19294 .591715.200 9.0650 .19386 .818®15.600 9.4457 .19682 1 .093016.000 9.9464 .20207 1 .419316.400 10.58eP .20908 1.802616. POO 11 .3968 .22051 2 .24 80

17.200 12.3962 .23427 2.76C617.600 13.6149 .25146 3.3458IP. 000 1 5.0e32 .27239 4.009318.400 16.8336 .29739 4 .7571

16 . 300 18.9009 .32680 5.595219.200 21.3227 .36100 6.530419.600 24.1391 .40034 7.569520.000 27.3931 .44522 8.719920.400 31.1309 .49605 9.989420 .eoo 35 .4016 .55325 11.385921.200 40.2577 .61727 12.910221.600 45.7554 .68857 14.595122.000 51.9543 .76765 16 . 4 2

e 8

22.400 58.9178 .85499 18.419722.800 66.7131 .95113 20.586423.200 75.4113 1 .05660 22.9358

DO/DT DP/DT D2P/DT2MOL/L/K MP A /K hd A /K /K

-.1255E-02 .00349 -.0000008- . 2 90 8 E -0 2 .00735 -.0000039- . 507 2 E -0

2

.01162 -.0000100-.7922E-02 .01631 -.0000195-.1170E-01 .02139 -.0000328-.1677E-01 .02685 -.0000505-. 2363E-01 .03266 -.0000728-.3299E-01 .03877 -.0001005-.4591E-01 .04514 -.0001344-.6396E-01 .05175 -.0001760- . 8 954 E -0 1 .05854 -.0002273-• 1265E+00 .06548 -.0002922- . 1 81 5 E +00 .07254 -.0003774-.2662E+00 .07972 -.0004953-.4042E+00 .08702 -.0006795-.6502E+00 .09453 -.0010169-. 7P70E +00 .09726 -.0012232

-.9385E+00 .25342 .0011533-.6619E+C0 .26940 .0007992-.4P56E+00 .28734 .0005919-.3740E+0C .30621 .0004609-.2983E+00 . 32610 . 0003682-.2445E+00 .34704 .0002975-.2047E+00 . 36906 .0002407-.1745E+00 .39220 .0001933-.1509E+00 .41648 .0001524-.1321E+CO .44194 .0001164-.1169E+C0 .46861 .0000840-.1044E+00 .49654 .0000544-.9397E-01 .52576 .0000263-.8519E-01 .55631 .0000009-.7771E-01 .58825 -.0000239-.7129E-01 .62162 -.0000478-.6572E-01 . 65649 -.0000713- . 60 86 E-0

1

.69291 -.0000945-. 5658E-01 .73095 -.0001177-.5280E-01 .77067 -.0001413- , 4944 E-0

1

.81214 -.0001655-.4644E-01 .85543 -.0001905- . 4 37 5 E-0

1

.90061 -.0002166-.4132E-01 .94777 -.0002440

99


HYDROGEN SULFIDE ISOTHEP" AT 373.400 K

DEN P Z DP/DD DD/DT DP/DT D2P/DT2MOL /L MPA MPA-L /MOL MOL/L/K MP A/K MP A/iL/K

. 800 2.2543 .90763 2.5620 -.2 86 4E-02 .00734 -.00000371.800 4.1181 .82901 2. 0999 -.7735E-02 .01624 -.00001842,400 5.6163 .75376 1 .6484 -.1619E-01 .02669 -.000047?3.200 6.7637 .68081 1.2277 -.3131E-01 . 03844 -.00009234.000 7.5964 .61170 .3654 -.5914E-01 .05118 -.00015694.800 8.1680 .54810 .5760 - . 1 1 2 1 F «-00 .06456 -.00024645.600 8.5375 .49106 .3593 -.2178E+00 .07826 -.00037206.400 8 .7599 .44087 . 2063 -.4460E+00 .09201 -.00056227.200 8 . Pei3 .39731 .1048 -.1007E*C1 .10561 -.00087878.000 8.9363 .35988 . 0434 -.2742F+01 .11893 -.00150940. «00 8.9587 .32791 .0118 -.1113E*02 .13187 -.00322279.600 8 . 9628 . 30072 .0010 -.1464E+03 .14422 -.01 3082110.400 8.9629 .27759 .0000 -.3927E+04 .15494 .079856311.200 8.964? .25780 .0054 -.3126E+02 .16951 .005031?12.000 8 . 9780 .24098 .0349 -.5402E+01 .18872 .002217512 . 800 9.0335 .22732 .1147 -.1849E+01 .21216 . 001199?13.600 9.1832 .21749 .2760 -.8686E*00 .23977 .000754614.400 9.5059 .21263 . 5530 -.4911E+00 . 27156 .000511715.200 10.1086 .21421 .9821 -.3132E*00 ' .30759 .000350?16.000 11.1279 .22402 1.6011 -.2173E+-00 .34796 .000250316.800 12.7313 .24409 2.4489 -•1604E+00 .39281 .000148217.600 15.1182 .27668 3 . 566P -.1240E+00 .44231 .000101618.400 18.5221 .32424 4 .9994 -.9935E-C1 .49671 .000044919.200 23. 2141 .38944 6.7955 -.8186E-01 .55630 -.000005720.000 29.5064 .47520 9.0095 -.6898E-01 .62145 -.000052720.800 37.7569 .58469 11.7020 -.5919E-01 .69258 -.000098321.600 48.3749 .72137 14.9397 -.5155E-01 .77018 -.000144522.400 61 .8252 .88901 18.7952 -.4548E-01 .85477 -.000193223.200 78.6323 1.09170 23.3440 -.4056E-01 .94694 -.0002464

100



DEN P Z DP/DDMOL /L MPA MPA-L/M0L.800 2.2660 .00846 2.5782

1.600 4.1440 .83068 2.11022.400 5.6500 .75624 1.67073.200 6.8251 .68406 1.25224.000 7.6781 .61564 .80154.800 8.2710 .55265 .60315.600 8.6623 .40611 .38666.400 8.0064 .44633 .23347.200 0.0403 .40310 .13138.000 0.127] .36501 .06808.800 0.1675 .33412 .03640.600 0.1012 .30707 .0258

—

*

o r* o o 0. 2122 .28400 .027011 .200 0.2370 .26454 .030212.000 0.2818 .24808 .076812.800 0.3742 .23480 .165213.600 0. 5678 .22563 . 335014.400 0.0410 .22141 .620515.200 10.6012 .22360 1.058316.000 11 .6e5C .23423 1 .686116.800 13.3600 .25505 2.543017.600 15.8260 .28840 3.670618.40C 10.3160 .33671 5.113?10.200 24.1042 .40265 6.020120.000 30.5006 .48012 0.145620.800 38.8640 .50028 11.850521.600 40.6070 .73658 15,101622.400 63.1026 .00480 18.071723.200 80.1471 1.10708 23.5370

DD/DT DP/DT 02P/DT2MOL /L/K HP A/K MPA /</K

-.2 843F-02 .00733 -.0000036-.7651E-02 .01621 -.0000180-.1 593'E-Ol .02661 -.0000458-•3058E-01 .03829 -.0000380-.5713E-01 . 05004 -.0001402-.1064E+00 .06418 -.0002296-.2010E+00 .07770 -.0003347-. 3008E4-00 .09110 -.0004800-.7054E+00 . 10442 -.0006324-.1701E+01 .11724 -.0007740-•3559E+01 .12967 -.0007398-.5520E+01 .14224 -.0003341-. 5600E+01 .15598 .0001303-•4386E+01 .17181 .0005090-•2484E+01 .10075 .0003053-.1294E+01 .21365 .0007338-.7190E+00 .24062 .0005341-.4388E+00 . 27231 .0004308-.2912E+00 .30813 . 0003240-.2066E+0C .34835 .0002324-.1546E+00 . 30307 .0001570-.1205E+00 .44247 .0000053- . 971 6 E -0

1

.40678 .0000407-. 8039E-01 .55620 -.0000085-.6794E-01 .62137 -.0000540-.5843E-01 .60242 -.0001000- . 5 00 8 E-0

1

.76005 -.0001450-.4504E-01 .85446 -.0001044-. 4022E-01 . 94654 -.0002475

101

Ta b 1 e 11 Continued


DEN P Z DP/DD DD/DT DP/DT D2P/DT2MOL /L MPA MP A-L/MOL MOL/L/K MP A/K M° A /K /K

.800 2.3026 .91099 2.6286 -.2782E-02 .00731 -.00000341.600 A . 2 2 A 9 .83574 2.1793 -.7400E-02 .01613 -.00001662.400 5.7915 .76376 1.7395 -. 1517E-01 .02639 -.00004173.200 7.0155 .69389 1.3278 -.2852E-01 .03787 -.0000794A. 000 7.9310 .62755 .9718 -.5170E-01 .05024 -.0001291A. 800 8.5892 . 56636 .6857 -• 9208E-01 .06314 -.00018915.600 9.0469 .51132 .4698 -.1623E+00 . 07624 -.00025476 . A 00 9.3573 .46275 .3154 -•2830E+00 .08928 -.00031567.200 9.5650 . A2C47 .2115 - .482 9E 00 .10211 -.0003516« .000 9.7063 .38401 .1476 - . 7 776 E 00 .11479 -.00033568.800 9.8099 .35283 .1163 -.1098E+01 .12765 -.00025219.600 9.8994 .32638 .1115 -.1267E+01 .14126 -.000116710.400 9.9930 .30412 .1243 -•1258E+01 .15630 .000037?11.200 10.1016 .28546 .1506 -•1151E+01 .17336 .000185912.000 10.2423 .27015 . 2083 - . 926 8 E +00 .19308 .000300912.800 10.4495 .25838 .3209 -.6736E+00 .21614 .000355513.600 1C .7779 .25083 .5163 -.4703E+00 .24305 .00034991A.400 11.3074 .24853 . 8293 - . 3 306 E -t-00 .27414 .000306615.200 12.1455 .25290 1 . 2945 -.2391E+00 . 30955 .000243216.000 13.4294 .26565 1.950? - • 1 79? E +C 0 .34939 .000187816.800 15.3272 .28876 2.8360 -.1389E+00 .39379 .000130517.600 18.0394 .32441 3.9935 - • 1 10 9E OO .44290 .000077618.400 21.8012 .37501 5.4678 - . 9 08 9 E -0 1 .49695 . 000028719.200 26.8855 .44320 7.3083 -.7611E-01 .55622 -.000017220.000 33.6067 .53183 9.5698 -.6490E-01 .62107 -.000061420.800 42.3258 .64405 12.3135 -.5619E-01 .69191 -.000105221.600 53.4549 .78327 15.6067 -.4929E-01 .76921 -.000150222. AOO 67.4624 .95322 19.5222 -.4372E-01 .65348 -.000193123.200 84.8767 1.15793 24.1365 -.3916E-01 .94530 -.0002507

102



DEN P Z DP/DDMOL/L MPA MPA-L/MGL.800 2.3756 .91576 2.7288

1.600 4.3e53 .84525 2.29782.400 6.0534 .77784 1.87423.200 7.3906 .71224 1 .47524.000 8.4275 .64974 1.12744.800 9.2121 .59186 .84565.600 9.7983 .53959 .63056.400 10.2368 .49327 .47527.200 10.5720 .45282 . 37068 . 000 10.8413 .41792 .30928.800 11.0769 .38818 ,2e599.600 11.3077 .36325 .296110.400 11.5573 .34271 . 330811.200 11.8419 .32607 .385612.000 12.1844 .31313 .478912.800 12.6246 .30416 .634113.600 13.2226 .29983 .878214.400 14.0617 .30114 1.242415.200 15.2518 .30944 1.761716.000 16.9316 .32635 2 .473316.800 19.2709 .35375 3.416917.600 22.4718 .39375 4.634818,400 26.7718 .44870 6.172619.200 32.4466 .52116 8.080620.000 39.8142 .61391 10.414320.800 49.2395 .73004 13.235621.600 61.1393 .87290 16.612522.400 75.9872 1.04615 20 .6184

DD/DT DP/DT D2P /0T2MOL/L /K MPA /K HP A/K /K

-.2668E-02 .00728 -.0000030-.6951E-02 .01597 -.0000143-.1388E-01 .02601 -.0000352-.2519E-01 .03716 -.0000648-.4355E-01 .04910 -.0001008-.7276E-01 .06153 -.0001390-.1176E 00 .07416 -.0001730-.1827E^00 .08683 -.0001942-. 2686E + 00 . 09954 -.0001943-.3638E+00 .11247 -.0001687-.4406E400 .12596 -.0001198-.4744E^00 .14048 -.0000557-.4732E+00 .15652 .0000138-.4528E+00 .17456 .0000816-.4074E+00 .19506 .0001396-.3448E+C0 .21861 .0001789-•2797E+00 .24563 .0001945-.2226E+00 .27652 .0001874-.1769E+00 .31156 .0001633-.1419E+C0 .35095 .0001291-.1156E+00 . 39488 .0000900-.9569E-01 .44353 .0000493-.8054E-C1 .49713 .0000033-.6880E-01 .55597 -.0000323-. 5957E-01 . 62040 -.0000730- , 521 9E-0

1

.69061 -.0001145-.4621E-01 .76767 -.0001530-.4130E-01 .85147 -.0002047

103

Tab! e 11 Continued.

HYDROGEN SULFIDE ISOTHERM AT *00.000 K

DEN P Z DP/DD DD/DT DP /DT D2P/DT2OL/L MPA MPA-L/MOl MOL/L/K MPA/K MPA/K/K.800 2. **83 .92018 2.8260 -•2565E-02 .00725 -.0000026.600 *.5*** .85*00 2 .*1*3 - . 6 561 E -0 2 .0158* -.0000125.*00 6.3119 .79077 2 .0057 -.1281E-01 .02568 -.0000300.200 7.7591 .72906 1.6183 -.2260E-01 .03657 -.00005*1.000 8.9138 .67005 1.2782 -.3771E-01 .0*820 -.0000818.800 9.8210 .61520 1.0006 -.6026E-01 .06030 -.0001089.600 10. 5320 .565*9 . 7873 -.9229E-01 .07266 -.0001302.*00 11.0965 .52133 .6332 - • 1 3*5 E ••00 .08519 -.0001*0*.200 11.5589 .*8271 .5311 - • 1 8** E 00 .09793 -.0001356.000 11.9586 .**9*6 .*756 -.2336E+00 .11109 -.0001151. 800 12.3313 .*213* .*631 -.2699E+00 .12*99 -.0000813.600 12.7101 .39809 .*898 -.2859E+00 .1*002 -.0000393.*00 13.1231 .379*1 .5*65 -.2866E+00 .15662 .0000058.200 13.5910 .36*87 .6288 -.2786E+00 .17519 .0000*97.000 1 * . 1 * 1

1

.35*33 .7559 -.2595E+00 .19619 .0000890.800 1* . 818* .3*809 .9507 -•2315EÔO .22005 .0001159.600 15.687* .3*683 1.2398 -•199*E+00 .2*722 .0001299.*00 16.8352 .35153 1.6532 -,1682E^00 .27808 .0001289.200 18.37*7 .363*8 2.22*9 - . 1 *07E +00 . 31293 .00011*9.000 20. **69 .38*25 2.9915 - . 1 177E+00 .3520* .0000912. 800 23.2236 .*1565 3.9927 -.9909E-01 .39563 .0000611.600 26.9091 .*5972 5.2709 - , 8*2 2 E -01 .**391 .0000275.*00 31.7*33 .51873 6.9723 -.723*E-01 .*9713 -.0000092.200 38.00*5 .59517 8 .8*78 -.6279E-0 1 .55559 -.0000*51.000 *6.01** .691 76 11.2536 -•5506E-01 .61962 -.0000831.800 56.1*17 .81157 1* .152* -. *8735-01 .68963 -.0001227.600 68.8080 .95783 17.6128 - • *3* 9E -0 1 . 76605 -.00016*7.*00 8* .*916 1.13*15 21.7086 - , 3 91 3 E-0

1

.8*939 -.0002103

104



DEN 0 Z DP/OD DD/DT DP/DT 02 p / DT 2MOL /L MPA MPA-L/MOL MOL /L /K MPA/K M8A/K/K.800 2 .5929 .92312 3.0245 -.2383E-02 .00721 -.0000021

1.600 4.8589 .86962 2.6422 -.5912E-02 .01562 -.00000962.400 6.8201 .81376 2.2612 - • 1 11 3 E-0

1

.02516 -.00002263.200 8.4807 .75892 1.8951 -•1881E-01 .03564 -.00003954.000 9.8633 .70612 1.5699 - . 298 3 E-0

1

.04683 -.00005774 .800 1 1.0079 .65672 1.3019 -.4494E-01 .05851 -.00007405.600 11.9627 .61172 1 .0953 - .6442 E-0

1

.07056 -.0000e526.400 12.7763 .57166 .9482 -.8750E-01 .08296 -.00008907.200 13.4946 .53671 . 8 567 -.1118E+00 .09581 -.00003408.000 14.1611 .50690 .8181 -.1336E+00 .10930 -.00007038.900 14.8173 .48217 .8310 -.1489E+00 .12371 -.00005129.600 15.5037 .46246 . 8925 -.1562E+00 .13938 -.000027510.400 16.2560 .44760 .9935 -.1577E+00 .15664 -.000002311.200 17.1025 .43728 1.1301 - • 1 55 6 E 00 .17587 .000022012.000 18.078P .43142 1.3217 -.1494E+00 .19743 .000043312.800 19.2380 .43039 1.5914 -.1393E*00 .22172 .000059113.600 20.6527 .43486 1.9651 -.1268E+00 .24911 . 000067514.400 22.4176 .44580 2.4719 -.1133E+00 .27997 .000067615.200 24.6520 .46443 3.1444 - . 1 001 E 0 0 .31461 .000059216.000 27.5024 .49223 4.0183 -.8793E-01 .35335 .000043516.800 31.1454 .53088 5.1328 -.7723E-01 .39643 .000021917.600 35.7904 .58233 6.5306 - . 6 80 1 E-0

1

.44412 -.000004119.400 41.6824 .64871 8.2585 -.6014E-0

1

.49670 -.000033419.200 49.1058 .73240 10.3684 -.534 9E-01 .55447 -.000055120.000 58.3890 .93602 12.9180 -.4782 E-0 1 .61779 -.000099220.900 69.9086 .96246 15.9709 -.4302E-C1 .68703 -.000135321.600 84.0953 1.11489 19.5970 -.3892E-01 .76264 -.0001754

105

Tab 1 e 11 Continued


DEN P Z DP/DD DO/DT DP/DT D2P/DT2MOL /L MPA M°A-L /MOL MOL/L /* MPA /K MP A/K /K

. 800 2.8082 .93819 3.3148 -.2158E-02 . 00715 -.00000151.600 5.3236 .88928 2.9747 -.5169E-02 .01538 -.00000692.400 7.5660 .84257 2.6306 -.9351E-02 .02460 -.00001573.200 9.5344 .79634 2.2940 -.1511E-01 .03467 -.00002674.000 11.2456 .75140 1.9913 -.2281E-01 .04542 -.00003794.800 12.7346 .70908 1.7408 -.3259E-01 .05673 -.00004755.600 14 .0469 .67041 1.5502 - .442 1 E-0 1 .06854 -.00005386.400 15.2313 .63607 1.4211 - . 5691 E-0 1 . 08087 -.00005537.200 16.3370 .60644 1.3533 -.6934E-01 .09383 -.00005238 . 000 17.4130 .58175 1.3470 -.798 9F-0

1

.10762 -.00004508.800 18.50P8 .56214 1 .4029 -.8730E-01 .12247 -.00003449.600 19.6737 .54773 1.5191 -.9127E-01 .13865 -.0000219

10.400 20.9531 .53848 1.6869 -.9276E-C1 .15647 -.000008811.200 22.3852 .53419' 1.9029 -.9261E-01 .17622 .000003812.000 24 .0160 .53490 2 .1873 -.9063E-01 .19824 .000014112.800 25.9093 .54100 2.5634 -. 8694E-0

1

. 22285 .000021513.600 28.1467 .55319 3.0568 -.8192E-01 .25041 .000024614.400 30.8391 .57239 3.6959 -.7610E-01 .28124 .000022815.200 34 . 1094 .59977 4.5123 -.6996E-0

1

.31567 .000015716.000 38.1154 . 63670 5.5411 - . 6 38 8 E -0

1

.35399 .000003516.800 43.0420 .68475 6.8208 - . 5 8 1 3 E -0

1

.39650 -.000013317.600 49.1070 .74573 8 .3944 -•5283E-01 .44351 -.000034118.400 56.5641 .82163 10 .3095 -.4804E-01 .49529 -.000058419.200 65 . 7073 .91467 12.6189 -.4376E-01 .55219 -.000035720.000 76.8752 1.02733 15.3818 - . 3 99 5 E-0

1

.61454 -.0001159

106


hydrogen sulfide isotherm at 500.000 K

DEN P Z DP/DD DD/DT DP/DT 02 0 / 0 T 2

* OL /

1

MPA MPA-L/MOL MOL /L /K MPA/K ME> A /K /K.800 3.16*2 .951*2 3.7908 -.1 871E-02 .00709 -.0000010

1.600 6.0851 .91*83 3.5117 -.*301E-02 .01510 -.00000*32. *00 e .779* . 87993 3.2220 - . 7** 5 E -02 .02399 -.00000953.200 11.2*00 .8**91 2.9317 -.11*8E-01 .0336* -.0000158*.000 13 .*773 .810*7 2 .66«2 -.16*8E-01 ,0*39e -.0000221*.800 1 5 . 5221 .77787 2. *531 - . 223 9E -0 1 . 05*9* -.00002735.600 17. *185 .7*820 2.2986 -.289*E-01 .06652 -.00003076. *00 19.2177 .72229 2.2107 -.3563E-01 .07878 -.00003207.200 20 . 97** .70073 2 .1932 -,*187E-01 .0918* -.00003118.000 22 . 7*66 .6839* 2.2*98 - . *70 5E-0 1 .10586 -.00002338.800 2* .59*6 .67228 2.3833 -• 8079E-01 .12105 -.00002*2<5.600 26.580* .66601 2.5935 - . 5307F-0

1

.1376* -.000019310. *00 28.7627 .66526 2.8725 -,5*26E-01 .15587 -.00001**11 .200 31.1938 .66995 3.2179 -. 5*70E-01 .17601 -.000010112.000 33.93*7 .68023 3.6509 -.5*33E-01 .1983* -.000007012.800 37.06*9 .6965* * .195* -.5319E-01 .2231* -.000005913.600 *0.6838 .71958 * .8770 -.51*18-01 .25073 -.00000721*.*00 **.9123 .75023 5.72*2 -. *916E-01 .281*0 -.000011*15.200 *9.89*9 .78960 6.7679 -,*661E-01 .315*7 -.000018916.000 55.8026 .83893 8.0*29 -.*392E-01 .35323 -.000029616.800 62.835* .89968 9.5877 -.*120E-01 .39*98 -.0000*3717.600 71.2263 .973*7 1 1 . A*5* -.38538-01 . **10* -.000060918. *00 81 .2*** 1.06211 13.66** -•3599E-01 .*9173 -.0000812

107

Table 11 Continued


DEN P Z DP/DD DD/DT DP/DT D2°/DT2MOL/L MPA MPA-L/MOL MOL /L /K MP A/K MPA/K/K.400 1 .7892 .97816 4.3876 - . 7 80 2 E -0 3 .00342 -.0000001.600 3.5178 .96156 4.2599 -.1655E-02 .00705 -.0000007

1.200 5.1991 .94743 4.1475 - . 262 5 E -02 .01089 -.00000161.600 6.93 57 .93425 4.0346 -.3701E-02 .01493 -.00000292.000 8.4261 .92130 3.9168 - . 4 89 5 E -0 2 .01917 -.00000442.400 9.9685 .90828 3.7944 -.6220E-02 .02360 -.00000632.800 11.4614 .99512 3.6704 -.7687E-02 .02821 -.00000833.200 12.9051 .88188 3.5485 - • 930 1 E -0 2 .03300 -.00001043.600 14.3010 .86869 3.4326 -.1106E-01 .03796 -.00001254.000 15.6524 . 85570 3.3259 -•1295E-01 .04309 -.00001454.400 16.9634 .84307 3.2314 -.1497 E -0

1

.04837 -.00001634.eoo 18.2394 .83094 3 .1510 - . 1 70 8 E -0

1

.05383 -.00001795.200 19.4864 .81946 3.0866 - . 1 92 6 E -0

1

.05946 -.00001935.600 20.7109 .80875 3.0392 -.2147E-01 .06526 -.00002046. COO 21.9201 .79990 3.01C0 - • 2 367 E-0

1

.07126 -.00002136.400 23.1215 .79002 2.9998 -.2582E-01 .07746 -.00002186.800 24. 3226 .78217 3.0094 -.2787E-01 .08388 -.00002207.200 25.5318 .77544 3.0396 - . 2 97 8E-0

1

.09053 -.00002207.600 26.7572 .76989 3.0911 -.3153E-01 .09745 -.00002178. COO 28.0075 .76557 3 .1645 -•3307E-01 .10464 -.00002128.400 29.2918 .76255 3.2604 -.343 9E -0

1

.11214 -.00002068.800 30.6189 .76087 3.3791 - .3 550E-0

1

.11996 -.00001999.200 31.9981 .76057 3.5207 - . 3 63 9 E -0

1

.12814 -.00001919.600 33.4385 .76169 3 .*847 -.3710E-01 .13670 -.0000184

10.000 34 . 9487 .76424 3.8697 - • 3764E-01 .14567 -.000017610.400 36.5368 .76824 4.0740 -•3806E-01 .15508 -.000017010.800 38.2106 .77368 4.2983 -•3838E-01 .16495 -.000016511.200 39.9796 .78057 4.5458 - . 3 85 7E-0

1

.17533 -.000016211.600 41.8507 .79894 4.8195 - . 3 864 E -0 1 .18624 -.000016212.000 43.8381 .79886 5.1223 -.3 860E-01 .19772 -.000016412.400 45.9529 .81039 5.4574 - . 3 844 E-0

1

.20980 -.000017012.800 48.2087 .82360 5 .8280 - • 3 81 8 E-0

1

.22251 -.000013113.200 50.6205 .83860 6.2375 -•3782E-01 .23589 -.000019513.600 53.2044 . 85548 6.6892 -.3737E-01 .24997 -.000021414.000 55.9780 . 87436 7.1870 -•3684F-01 .26480 -.000023914.400 58.9606 .99537 7.7344 -.3625E-01 .28040 -.000026914.800 62.1727 .91863 8.3357 -.3561E-01 . 29681 -.000030515.200 65.6369 .94429 8 .9950 -.3492E-01 .31408 -.000034715.600 69.3771 .97251 9.7167 - , 341 9E-0

1

.33223 -.000039616.000 73.4192 1 .00344 10.5057 -•3344E-01 .35131 -.000045016.400 77.7912 1.03726 11.3667 -.3267E-C1 . 37136 -.000051116.800 82.5229 1.07415 12.3052 -.3189E-01 . 39240 -.0000579

108



DEN P 7 DP/DDMOL/l MPA mpa-l/mol.400 1.9602 .98233 4 .8272.800 3.0696 . 96959 4.7246

1.200 5.7418 .95913 4.63701.600 7.5790 .94952 4.54042.000 9.3797 .94010 4 .45412.400 11 .1416 .93057 4.35452.800 12.8630 .92086 4.25243.20C 14.5437 .91104 4.15203.600 16.1853 .90122 4 .05714 . 000 17.7906 .89154 3.97144.400 19.3640 .88218 3.89794.800 20.9109 .87326 3.83935.200 22.4377 . 86494 3.79735.600 23.9512 .85734 3.77386.000 25.4593 .85056 3.76986.400 26.9699 .84472 3.78676.800 28.4916 .83989 3.82557.200 30.0333 .03615 3.88727.600 31.6045 .83358 3.97270.000 33.2148 .83225 4.08290.400 34.8742 .83222 4.21858 .300 36.5931 .83354 4.38010.200 36.3ei8 .83628 4.56779.600 40.2507 . 84C46 4.7010

10.000 42.2099 .84611 5.010910.400 44.2688 .85325 5.279510.800 46.4366 . 86189 5.563911.200 48.7235 .87203 5.875311.600 51.1409 .80374 6.216712.000 53.7013 .89705 6.591412.400 56.4189 .91204 7.002512.800 59.3087 .92880 7.453412.200 62.3873 .94740 7.947313.600 65.6728 .96796 8.487914.000 60.1844 .99059 9.078914.400 72.9431 1.01539 9.724214.800 76.9715 1.04251 10.427015.200 81.2937 1.07200 11.1939

DD/DT DP/DT D2°/DT2MOL /L /K MP A/K MPA /K/K

— . 707 8 E — 0 3 .00342 -.0003001-.1487E-02 .00702 -.0000005-.2334E-02 .01082 -.0030011-.3256E-02 .01481 -.0000020-.4262E-02 .01098 -.0003032-.5359E-02 .02334 -.0000045-.6553E-02 .02787 -.0000059-.7844E-02 .03257 -.0000073-.9220E-O2 .03744 -.0300308- . 1 070 E -0 1 . 04248 -.0030103-.1223E-01 .04769 -.0000116-.1382E-01 .05307 -.0030129- . 1 54 4 E -0

1

.05864 -.0000140-.1706E-01 .06439 -.0000149“ • 1 866 E -0

1

.07035 -.0000157“ . 202 1 E-0

1

.07652 -.0000163-.2168E-01 .08292 -.3300160-. 2304E-01 .08957 -.0000171-.2429E-01 .09648 -.0000173-.2539E-01 .10368 -.0000174-.2636E-01 .11119 -.0300175-.2717E-01 .11903 -.0000175-.2785E-01 .12722 -.0000176-.2840E-01 .13580 -.0000177-.2885E-01 .14470 -.0000179-.2921E-01 .15419 -.0003131-.2949E-01 .16407 -.0000185-.2969E-01 .17444 -.3000191- . 2 90 1 E-0

1

.16533 -.0000199-.2985E-01 .19677 -.0003210-.2902E-C1 .20880 -.0300223- . 2 97 1 E -C

1

.22144 -.0000240-.2 954 E — 0

1

.23473 -.0000260- • 2930E-0 1 . 24871 - . 03032 6<«

- . 2 90 1 E -0

1

.26340 -.0000312- . 2 06 8 E-0 1 .27884 -.0000345-.2 03OE-O1 .29507 -.3000302-•2788E-01 . 31213 -.0300424

109

Table 11. Continued

HYDROGEN SULFIDE ISOTHERM AT 650. OOO K

DEN p Z DP/DD DD/DT DP/DT D2P/DT2MOL /L MPA MP A-L/MOL MOL/L/K MPA/K MP A/K/K.AGO 2.1309 , 9857A 5 . 26 5

A

-.6A80E-03 .003A1 -.0000001.000 A .2202 .97610 5.1859 - . 1 3 50 E-02 .00700 -.DOOOOOA

1.200 6.2816 .96858 5.1215 - . 2103E-02 .01077 -.00000091.600 8.3172 .96185 5.0557 -.2912E-02 . 01 A72 -.00000152.000 10.3253 .95526 A. 9837 -.3782E-02 .01685 -.000002A2 . A 00 12 .303A . 9A 8 5 6 A. 9059 -.A718E-02 . 02 31 A -.00000332.800 1 A . 2 A9 6 . 9A1 66 A. 8253 -• 5722E-02 .02761 -. OOOOOAA3.200 16.1638 . 93 A6A A ,7A60 “.6795 E-02 .03225 -.00000553.600 18.0A72 .92759 A. 6722 -.7931E-02 .03706 -.0000066A .000 19.9028 .92067 A. 6079 - • 912 2 E-02 . 0A203 -.0000077A. AOO 21.7352 . 91 AOS A. 5562 -.1036E-01 • 0A718 -.0000038A. 800 23.5A99 .90782 A.52C1 -.1 162E-01 .05251 -.00000935.200 25.3536 .90217 A. 5017 -.1289E-01 .05803 -.00001075.600 27.1538 .89721 A. 5029 -.1A15E-01 .0637A -.00001166.000 28.9507 .89306 A. 5253 -.1539E-01 . 06966 -.00001236. AOO 30.7771 .88981 A. 5703 -.1658E-01 .07579 -.00001306.000 32.6182 .88757 A. 6392 -.1771E-01 .08217 -.00001367.200 3 A , A 9 1 B . 886A1 A .7332 -.1876E-01 .08879 -.00001A17.600 36. A062 . 886A1 A. 853A - . 1 972 E -0

1

.09569 -.00001 A68.000 38.3781 .88766 5.0009 -.2057E-01 .10287 -.00001510. AOO AO. A127 .89020 5.1765 -.2132E-01 .11037 -.00001550.800 A2.5232 . B9A12 5.3810 - • 2 1 96 E-0

1

.11819 -.00001609.200 A A , 721

3

, 899A5 5.61A5 -.2251E-01 .12637 -.00001659.600 A 7 .0187 .90625 5.8769 -.2296E-01 . 13A93 -.000017010.000 A9.A265 . 91A 56 6.1669 -.2333E-01 . 1 A 3 8 9 -.000017710. AOO 51 . 9557 , 92 A 3 8 6 , A 831 -.2 36AE-01 .15328 -.000018A10.800 5A. 6166 .93573 6.8265 -.2390E-01 .16312 -.000019311.200 57 o A2 1

0

. 9A86A 7.2006 -.2A09E-01 . 1 7 3 A 5 -.000020A11.600 60.3816 .96316 7 , 6 0 8 A -.2 A22E-01 .18A28 -.000021712.000 63.5126 .97933 8.0533 -.2 A30E-01 .19566 -.000023112. AOO 66.8296 • 9972

A

8.5385 -.2A31E-01 . 20761 -.0000 2 A912.800 70. 3A92 1.01695 9.067A -.2A28E-01 .22016 -.000026913.200 7A.0898 1 .03857 9 , 6 A 35 -.2A20E-C1 . 2 3 33 A -.000029113.600 70.0706 1.06219 10.2705 -.2A07E-01 • 2 A 7 1 9 -.00003181A .000 02.3135 1.08791 10.9521 - • 2390E-0 1 . 2617A -. 00003A7

110

Table i 1 . Continued.

hydrogen sulfide is-otherh AT 700.000 K

DEN P Z DP/DD DD/DT DP /DT D2P/OT2MOL /

L

MPA MP A-L/MOL MOL/ L/K MP A/K MP A/K/K. A 00 2.301* .98856 5.702* - • 5 97 7 E-0 3 .003*1 -.0000001.800 * . 569Q .981*8 5 .6**9 -.1238E-02 .00699 -.0000003

1.200 6.819? .97638 5.602* -.1916E-02 .01073 -.00000071.600 9.0515 .97200 5.5582 -.2636E-02 .01*65 -.00000122.000 11 .26*9 .96775 5.5076 - . 3*0 3 E-0

2

.0187* -.000001

»

2. *00 13 .*567 .96337 5 .*509 - . *2 1 9 E -0 2 .02300 -.00000262.800 15.6252 .95881 5.3913 -. 5086E-02 .027*2 -.000003*3.200 17.7699 .95*12 5.3330 -.6002E-02 .03201 -.00000*33.600 1<=. 992* .9*9*0 5.2803 - . 6 96 2 E -0 2 .03676 -.0000052*.000 21 . 9955 . 9**80 5 .2375 -.7960E-02 .0*169 -.0000061* . *00 2*. 08*1 . 9 AO * 7 5.2090 -.998AE-02 . 0*679 -.0000070*.800 26.16*1 .93655 5.19*8 - . 1 002 E -0

1

.05207 -.00000795.200 28.2*25 .93318 5.2005 -.1107 E-0

1

.05755 -.00000875.600 30.3272 .930*9 5.2270 -•1209E-01 .06322 -.000009*6.000 32. *271 .92859 5.2763 -.1310E-01 . 06910 -.00001026. *00 3*. 5515 . 92758 5.3*99 -,1*06E-01 .07520 -.00001096.800 36.7105 .92757 5. *89* -.1A96E-01 .0815* -.00001157.200 36.91*7 .9286* 5.5761 -•1581E-C1 .0881* -.00001227.600 *1 .1752 . 93087 5.7313 -.1658E-01 . 09501 -.00001238.000 *3.5037 .93*33 5.9162 - . 1 72 7 E-0

1

.10216 -.000013*8. *00 *5.9122 .93911 6.1318 -.1788E-01 .10963 -.00001*18.800 *8 .*133 .9*525 6.3790 - . 1 8* 1 E-0

1

.117*2 -.00001**0.200 51.0197 .95283 6.6581 -.1886E-01 .12557 -.00001559.600 53 .7**1 .96189 6.9690 - . 1 92 * E -0 1 .13*09 -.000016310.000 56.5990 .972*7 7.3107 - . 1 95 6 E -0

1

.1*301 -.000017310. *00 59.5965 .98*59 7 .6816 - . 1 98 3 E-0

1

.15236 -.000013310.800 62.7*3* .99826 8.0832 -. 2006E-0 1 .16215 -.000019511.200 66.0676 1.01353 8.5187 -•202*E-01 .172*1 -.000020911.600 69.568* 1.030*3 8.9916 -•2037E-01 .18318 -.000022312.000 73.2663 1.0*903 9.5052 -.20A6E-01 .19**8 -.00002*012. *00 77.178* 1.069*0 10.0629 -. 2050E-0 1 . 2063* -.000025912.800 81.3230 1.09161 10.6691 - , 205 1 E-0 1 .21878 -.0000280

111

Table 12. The J ou 1 e-Thoi.ison inversion locus for h^droyen sulfide

T»K MOL/t P , M P 4

2 80 24 .055 1.2562 90 23.402 1.642300 22.712 2.125310 22.498 8.326320 22 .264 14.227330 22 .040 19.836340 21.816 35.164350 21.592 30.218360 21.368 35.009370 21.144 39.5443 80 20.920 43.8373 90 20.696 47.882400 20.472 51.703410 20.247 55.302420 20.02? 53.683430 19.799 61.870440 19.575 64.856450 19.351 67.654460 19.128 70.27?470 16.90“’ 7 2 .719480 16.663 75.002490 1 6.462 77.129500 1 8.241 79.109510 16.021 80.948520 17.803 82.665530 17.5e5 94.235540 17.369 85.698550 17.155 87.C48

T,k MOL /L P,8PA560 16.942 88.292570 16 .731 89.438580 16.521 90.499590 16.314 91.4546CC 16.109 92.335610 15.904 93.140620 15.703 93.87?630 15.504 94.535640 15.307 95.135650 15.112 95.675660 14.911 96.15967C 14.729 96.590680 14.541 96.97269C 14.356 97.3087 C 0 14.173 97.600710 13 .99? 97.851720 13.814 98.065730 13.638 99.242740 13.465 98.3867 5 C 13.294 98.491760 13.125 98.58277C 12.959 98.638780 12.795 98.66879C 12 .633 98.675800 12.474 9e .6598 1 C 12.318 98.622820 12.163 98.5679 3 C 12.011 98.493

112

Table

13.

Properties

of

saturated

liquid

hydroyen

sulfide

o c o o ox. 4 4

O. >. JJ UJ LUO —» o ^H 4

I X 4 **< rH o CT

<\J 00 CM CM CM CM CM CM CM CM CM X X X X X X X X X X X rH rH rH rH rH rH O O0 0 O O O O O O O O O 0 0 O 0 0 0 0 O 0 O 0 O O O O 0 O O O O 0 O O O4 4 4- 4- 4 4- 4- 4- 4- 4- 4- 4- 4- 4- 4 4- 4- 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ Ui UJ LU UJ UJ LU UJ LU UJ LU UJ UJ UJx 0 CD CD p X rH n O X yO P- 0 in rH 0 X in rH 0 X >T O *“H X O X X O in O X 4 4 Xx x O x 0 m CM X in X X in X 0 X >0 4 X rH O CP X X X O X X in X X in CP X 04 •4- x x rH 0 O p yO in X X rH 0 X p^ yQ in 4 X rH 0 X X X O 0 rH X 4 p- O X O* p-x m m CO m X CM CM CM CM CM X X X rH rH rH rH rH rH rH rH O X p*- yC >0 in 4 X X X P^ X

O x >0 CO O 0 in X >r P^ O X yO X X in O O P^ X 4 4 P- X X in 0 X X X X 4 P- X 404

>0 4 0 4 n 0 X O yQ >r *r in r- O 4- cr 4 cr in X cr D) 4 »H cr p- 4 r—

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P'- X in in 0 X X4 0 >0 4 CD CM p rH vO rH >0 rH yO rH n- X h- X X 4 O m rH P- X X 4 0 4 rH p- X p- X in incc CD p p >0 4 in in M- >s- X X X X rH rH 0 O cr cr O X X P- r*- NO 4 4 in in 4 4 X X X rpj rH H rH rH rH rH rH rH rH rH rH rH rH rH rH rH r-0

0 x x O rH O 4 in CP X in P-- cr X O O X rH yC n X X r*- 0 >n X CP in 4 X 0 p^ 4 4 O4 p O O in O in H X in X X <r O •O X rH rH 4 O cr X rH in X rH O 0 4 4 OJ X O OrH H CV CV' X X 4 in >0 X cr 0 X X m cr rH 4 >0 O 4 X X O X X rH 0 0 4 0 O

in in m in in n m in in IT in in in n yC yO >n yD «n >0 P^ r~- X X X 0 O 0 ro 4 X m O OO1

O1

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rH

1

rH

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1

rH

1

rH

1

rH

1

X1

41

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x X CM CVJ CM CM CM X rH H rH rH rH rH rH rH » 1 rH rH rH fH rH H rH O O O O O 0 OO 0 O 0 O O O 0 C 0 0 O O O O O O O O 0 O O O O O O 0 O O O O O O O O O

1 1 1 1 1 1 1 1 1 1 0 1 0 0 1 1 0 0 0 0 0 0 0 « 1 0 1 1 1 4 4 4 4 4 4 4UJ UJ UJ UJ UJ UJ UJ UJ UJ UJ LU UJ UJ LU LU UJ UJ LU UJ UJ UJ LU LU UJ LU LU U_ LU LU UJ LU UJ LU LU LU LUp 0 a 0 O cr 4 in O -r P^ cr rH 4- P^ rH yC X rH X in O cr X CP X X O O rH X a O cr rH 4X 4 x 0 yT X CD CM rH rH X p^ >J- X X in O' vO in vO cr in X X X r-* cr O 4 rH X in 4 X X X4 m rH in p 0 n rH X n n- cr X X X rH 4 CD X >c 0 in 0 X 0 -D rH X 4 O 0 rH X X 4 inX 4 in in 4 CD O rH rH rH rH rH X X X X X X 4 4 X in yO >0 p*- X X CP rH rH rH f-H rH rH rH

O X CM cc CM rH 4 O in CM CM >G m X X >0 X in X r- cr yD 0 0 X in X X X X X O cr Xm O p CL rH p 4 X -J- n in O 0 X X cr 4 4 X P- 0 r- a X p~ X m 4 4 X O 4 0 O 4 O*n X 0 P X p fH 4 r^- O 0 rH 0 0 X 45 4 X X cr X P- rH X in in 4 rH 4 P- If p CP 0 XX x p p P * >C in x. X X rH c X r*- yC in X X 0 CP <J 4 X c CC 4 X O P^ X X X XO 0 cr O O 0 O O 0 O 0 cr cr cr X X X X X X X P- X P- p- p*- yC 4 * 4 in in 4 4 X

O 0 4 P 4 in 4 rH rH vT X in in X 0 0 X X rH m O X >c X O X X in a- r—i O 4 Xm p 0 CM CD in X X M' rH P^ in >C cr IT 4 X pH CP X cr 0 X O r- X 4 O in 4 X X X O 0^H 1 x CM PM X 4 m >0 r- IT O X 4- sC cr CV IT CP X rH p- X X n X rH rH rH X p- X 4 4 XO 0 0 O O O O 0 O 0 O rH rH rH rH rH X X X X X 4 4 in m >C p- cr cr O rH CV 4 4 CP XO 0 0 O O O O Cj O 0 O O O O O O c O 0 0 O O 0 O O O 0 O 0 fH H rH r-H X

rH rH rH rH rH rH O O O 0 O O O O O O 0 O 0 0 rH rH rH rH rH rH rH rH rH J ; r-H r-H rH XO O O O O O O O c 0 O O O O O O 0 O 0 0 O O O O O O O O O O O O O O O 01 » 1 1 1 1

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>0 4 x 4 4 X O CV X >r m cr O m in X yD X 4 a cr X X r- w-4 X P- 4 *C P- 4 rH cr P O4 4) x CD ro IT- rH X in CM cr 0 0 vO rH X a1 4 X O 4 a cc X c p- X X in in in 4 p- x cp O 4 4 4 p CM X X X X X cr >£) X X X X X X 4 X X cr r- X 0 4 in X P- 4 X X 4 rv

0 O CD 4 C 0 CM 4 n rH m 0 4* O P> 4 X rH rH X 0 rH X 4 >0 X rH X 4 CP X X 4 cv in Ox m m 4 X 0 rH X rH CM X X X 4 4“ in P- X cr rH rH rH »H r—i rH X X X X X X 4 in 4 f-H

x 4 IT 4 X 0 X 4 *H m in rH X P- yO cr m X X cv O X a P- >c 4 CP 4 4 X X p- p- X CV OU"» 0 4 PO p 0 4 p c CM r- X nr if X O H 4 >0 X yD X p- cr X f—

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170

NBS-1 14A IREV. 2-80

U.s. DEPT. OF COMM.

4. TITLE AND SUBTITLE

HYDROGEN SULFIDE PROVISIONAL THERMOPHYSICAL PROPERTIES FROM IE

TO 75 MPa18 TO 700 K AT PRESSURES

5. AUTHOR(S)

Robert D. Goodwin

6. PERFORMING ORGANIZATION (If joint or other than N BS, see instructions)

NATIONAL BUREAU OF STANDARDSDEPARTMENT OF COMMERCEWASHINGTON, D.C. 20234

7. Contract/Grant No.

8. Type of Report & Pe r iod Covered

BIBLIOGRAPHIC DATASHEET (See instructions)

1. PUBLICATION ORREPORT NO.

NBSIR 83-1694

2. Performing Organ. Report No, 3. Publication Date

October 1983

9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City. State. ZIP

)

Gas Research Institute8600 West Bryn Mawr AvenueChicago, Illinois 60631

10. SUPPLEMENTARY NOTES

Document describes a computer program; SF-185, FIPS Software Summary, is attached.

11. ABSTRACT (A 200-word or less factual summary of most significant information. I f document includes a significan:

bibliography or literature survey, mention it here)

Thermophysical properties of hydrogen sulfide are derived from physical propertiesdata by using our nonanalytic equation of state, and are tabulated along isobars at

integral temperatures. Results include vapor pressures, orthobaric densities, the

second virial coefficient, the equation of state, the ideal gas state functions,compressibility factors, densities, derivatives of the P(p,T) surface, heats of

vaporization, internal energies, enthalpies, entropies, specific heats, fugacity

coefficients, speeds of sound, and the Joule-Thomson inversion. Thermofunctions by

another author are compared with present results.

12. KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate v,-.

densities; enthalpies; entropies; equation of state; fugacities; heats

tion; hydrogen sulfide; isobars; isochores; isotherms; Joule-Thomson i

obari c densities; specific heats; speeds of sound; vapor pressures; vi

words by semicolons

of vaporiza-nversion; orth-

rial equation.

13. AVAILABILITY

rXl Unlimited

[

—

j

For Official Distribution. Do Not Release to NTIS

|

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Order From Superintendent of Documents, U.S. Government Printing Office. Washington. D.c.

20402.

|~X| Order From National Technical Information Service (NTIS), Springfield, VA. 22 16 1

14. NO. OFPRINTED PAGES

175

15. Price

$16.00

' “ “ u$COmm»OC 6045*° *

:

U.S. GOVERNMENT PRINTING OFFICE:1983- 776-532 / 37