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Highland Science Department Ionic Nomenclature
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Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Dec 18, 2015

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Page 1: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Ionic Nomenclature

Page 2: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Ionic Nomenclature

the more metallic element always comes first

Page 3: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Ionic Nomenclature

Multivalent Ions: metals with more than one common valence

-the possible valences are indicated on your periodic table

Page 4: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Ionic Nomenclature

Multivalent Ions: metals with more than one common valence

-the possible valences are indicated on your periodic table

Polyatomic Ions: groups of atoms that behave as a single ion

Page 5: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Ionic Nomenclature

Polyatomic Ions:acetate CH3COO1-

ammonium NH41+

hydroxide OH1-

cyanide CN1-

permanganate MnO41-

thiocyanate SCN1-

hydrogen carbonateHCO31- (bicarbonate)

Page 6: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Polyatomic Ions from oxy-acids

One extra oxygen(per-ate)

Basic Ion(-ate)

One fewer oxygen(-ite)

Two fewer oxygen (hypo-ite)

ClO31-

chlorate

NO31-

nitrate

CO32-

carbonate

SO42-

sulfate

PO43-

phosphate

Page 7: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Polyatomic Ions from oxy-acids

One extra oxygen(per-ate)

Basic Ion(-ate)

One fewer oxygen(-ite)

Two fewer oxygen(hypo-ite)

ClO41-

perchlorateClO3

1-

chlorate

NO41-

pernitrateNO3

1-

nitrate

CO42-

percarbonateCO3

2-

carbonate

SO52-

persulfateSO4

2-

sulfate

PO53-

perphosphatePO4

3-

phosphate

Page 8: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Polyatomic Ions from oxy-acids

One extra oxygen(per-ate)

Basic Ion(-ate)

One fewer oxygen (ite)

Two fewer oxygen (hypo-ite)

ClO41-

perchlorateClO3

1-

chlorateClO2

1-

chlorite

NO41-

pernitrateNO3

1-

nitrateNO2

1-

nitrite

CO42-

percarbonateCO3

2-

carbonateCO2

2-

carbonite

SO52-

persulfateSO4

2-

sulfateSO3

2-

sulfite

PO53-

perphosphatePO4

3-

phosphatePO3

3-

phosphite

Page 9: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Polyatomic Ions from oxy-acids

One extra oxygen(per-ate)

Basic Ion(-ate)

One fewer oxygen (ite)

Two fewer oxygen (hypo-ite)

ClO41-

perchlorateClO3

1-

chlorateClO2

1-

chloriteClO1-

hypochlorite

NO41-

pernitrateNO3

1-

nitrateNO2

1-

nitriteNO1-

hyponitrite

CO42-

percarbonateCO3

2-

carbonateCO2

2-

carboniteCO2-

hypocarbonite

SO52-

persulfateSO4

2-

sulfateSO3

2-

sulfiteSO2

2-

hyposulfite

PO53-

perphosphatePO4

3-

phosphatePO3

3-

phosphitePO2

3-

hypophosphite

Page 10: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Polyatomic Ions from oxy-acids

NICK the CAMEL had a CLAM for SUPPER in PHOENIX

1. First letter(s) indicates name e.g. NICK = nitrate

Page 11: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Polyatomic Ions from oxy-acids

NICK the CAMEL had a CLAM for SUPPER in PHOENIX

1. First letter(s) indicates name e.g. NICK = nitrate

2. # of consonants indicates # of oxygene.g. NICK has 3 = NO3

Page 12: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Polyatomic Ions from oxy-acids

NICK the CAMEL had a CLAM for SUPPER in PHOENIX

1. First letter(s) indicates name e.g. NICK = nitrate

2. # of consonants indicates # of oxygene.g. NICK has 3 = NO3

3. # of vowels indicates valencee.g. NICK has 1 = NO3

1-

Page 13: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Polyatomic Ions from oxy-acids

NICK the CAMEL had a CLAM for SUPPER in PHOENIX

1. First letter(s) indicates name e.g. NICK = nitrate

2. # of consonants indicates # of oxygene.g. NICK has 3 = NO3

3. # of vowels indicates valencee.g. NICK has 1 = NO3

1-

-add an oxygen to any to get "per-ate"-subtract an oxygen to get "ite"-subtract two oxygens to get "hypo-ite"

Page 14: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Formula Writing: criss cross method kris kross

1. Write the valences (oxidation numbers) beside each ion as superscripts

e.g. magnesium oxideMg2+ O2-

Page 15: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Formula Writing: criss cross method

1. Write the valences (oxidation numbers) beside each ion as superscripts

e.g. magnesium oxideMg2+ O2-

2. Cross the valences (without charge) to the pairing atom and write as subscripts

Mg2 O2

Page 16: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Formula Writing: criss cross method

1. Write the valences beside each ion as subscripts

e.g. magnesium oxideMg2+ O2-

2. Cross the valences (without charge) to the pairing atom and write as subscripts

Mg2 O2

3. Reduce the subscripts to their lowest formsMg1 O1

Page 17: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Formula Writing: criss cross method

1. Write the valences beside each ion as subscripts

e.g. magnesium oxideMg2+ O2-

2. Cross the valences (without charge) to the pairing atom and write as subscripts

Mg2 O2

3. Reduce the subscripts to their lowest formsMg1 O1

4. Do not write ones; they are understoodMg O

Page 18: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Formula Writing: criss cross method

1. Write the valences beside each ion as subscripts

e.g. magnesium oxideMg2+ O2-

2. Cross the valences (without charge) to the pairing atom and write as subscripts

Mg2 O2

3. Reduce the subscripts to their lowest formsMg1 O1

4. Do not write ones; they are understoodMg O

* For polyatomic ions, place the ion in brackets before writing the subscript

Page 19: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Formula Writing: criss cross method

Try these:

1. sodium fluoride2. lithium oxide3. beryllium sulfide4. calcium chloride5. ammonium iodide6. magnesium carbonate

Page 20: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Formula Writing: criss cross method

Try these:

1. sodium fluoride NaF2. lithium oxide Li2O3. beryllium sulfide BeS4. calcium chloride CaCl25. ammonium iodide NH4I6. magnesium carbonate MgCO3

Page 21: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Naming: -metal is named first-non-metal is named second with its ending changed to "ide" for binary (2 element) molecules

Page 22: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Naming: -metal is named first-non-metal is named second with its ending changed to "ide" for binary (2 element) molecules-reverse criss cross sorts out the valence of a multi-valent ion

e.g. FeO vs. Fe2O3

Fe1+ O1- Fe3+ O2-

-oxygen can only be O2- so...Fe2+ O2- Fe3+ O2-

double them both

Page 23: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Naming: -metal is named first-non-metal is named second with its ending changed to "ide" for binary (2 element) molecules-reverse criss cross sorts out the valence of a multi-valent ion

e.g. FeO vs. Fe2O3

Fe1+ O1- Fe3+ O2-

-oxygen can only be O2- so...Fe2+ O2- Fe3+ O2-

double them both-the multi-valent ion valence is written in Roman numerals in brackets after the name

iron (II) oxide iron (III) oxide

Page 24: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Naming: Roman numeral FYI

I = 1II = 2III = 3IV = 4V = 5VI = 6VII = 7VIII = 8

*the pattern: I's placed after add to the value, I's placed before subtract

Page 25: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Naming:

the same pattern holds true for bigger numbersX = 10L = 50C = 100M = 1000

2013 MMXIII

1997 MCMXCVII

Page 26: Highland Science Department Ionic Nomenclature. Highland Science Department Ionic Nomenclature the more metallic element always comes first.

Highland Science Department

Naming:

the same pattern holds true for bigger numbersX = 10L = 50C = 100M = 1000

2013 MMXIII

1997 MCMXCVII

Imagine doing scientific notation......or just thank the Middle East for Arabic

numerals