Montana Tech Library Digital Commons @ Montana Tech Graduate eses & Non-eses Student Scholarship Summer 2017 Hexavalent Chromium Exposure to Military Aircraſt Painters Doug Rosaaen Montana Tech Follow this and additional works at: hp://digitalcommons.mtech.edu/grad_rsch Part of the Occupational Health and Industrial Hygiene Commons is Non-esis Project is brought to you for free and open access by the Student Scholarship at Digital Commons @ Montana Tech. It has been accepted for inclusion in Graduate eses & Non-eses by an authorized administrator of Digital Commons @ Montana Tech. For more information, please contact [email protected]. Recommended Citation Rosaaen, Doug, "Hexavalent Chromium Exposure to Military Aircraſt Painters" (2017). Graduate eses & Non-eses. 135. hp://digitalcommons.mtech.edu/grad_rsch/135
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Hexavalent Chromium Exposure to Military Aircraft Painters
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Hexavalent Chromium Exposure to MilitaryAircraft PaintersDoug RosaaenMontana Tech
Follow this and additional works at: http://digitalcommons.mtech.edu/grad_rsch
Part of the Occupational Health and Industrial Hygiene Commons
This Non-Thesis Project is brought to you for free and open access by the Student Scholarship at Digital Commons @ Montana Tech. It has beenaccepted for inclusion in Graduate Theses & Non-Theses by an authorized administrator of Digital Commons @ Montana Tech. For more information,please contact [email protected].
Recommended CitationRosaaen, Doug, "Hexavalent Chromium Exposure to Military Aircraft Painters" (2017). Graduate Theses & Non-Theses. 135.http://digitalcommons.mtech.edu/grad_rsch/135
Park, R., Bena, J., Stayner, L., Smith, R., Gibb, H., & Lees, S. (2004). Hexavalent Chromium
and Lung Cancer in the Chromate Industry: A Quantitative Risk Assessment. Risk
Analysis, 24(5), 1099-1108.
Public Health Service. (2012, 9 1). Toxilogical Profile for Chromium. Atlanta: Agency for Toxic
Substances and Disease Registry.
Steenland, K., & Palu, S. (1999). Cohort mortality study of 57000 painters and other union
member: a 15 year update. Occupational and Environmental Medicine, 6(5), 315-321.
U.S. Environmental Protection Agency. (1998). Toxicological Review of Hexavalent Chromium.
Washington D.C.: U.S. Environmental Protection Agency.
Vincent, R., Gillet, M., Goutet, P., Guichard, C., Hedouin-Langlet, C., Frocaut, A., . . . Rousset,
D. (2015). Occupational Exposure to Chrome VI Compounds in French Companies:
Results of a National Campaign to Measure Exposure (2010-2013). The Annals of
Occupational Hygiene, 59(1), 41-51.
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Appendix A: IHSTAT and ANOVA analysis
Excel ANOVA Analysis
42
IHSTAT Analyses
43
44
45
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Appendix B: Safety Data Sheets and Tukey Analysis
MIL-PRF-85582 Type I Class 1 Primer MSDS
*** Emergency Overview ***: Flammable liquid and vapors. Harmful by inhalation, in contact with skin, and if swallowed. Contact with eyes or skin causes irritation. Effects Of Overexposure - Eye Contact: Exposure to liquid, aerosol, or vapors may cause irritation, tearing, redness, and swelling accompanied by a stinging sensation. Contact with eyes may cause blurred vision and irritation. Effects Of Overexposure - Skin Contact: Direct skin contact may cause irritation. Symptoms may include swelling, burning, redness, itching, and rash. Prolonged or repeated skin contact may cause dermatitis, drying, and defatting due to the solvent properties. May cause allergic skin reaction. May cause severe skin irritation. It is possible for one of the components to pass through the skin, and the component may add to the toxic effects of either ingestion or inhalation. Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes) & acute nervous system depression characterized by the following progressive steps: headache, nausea, weakness, dizziness, staggering gait, confusion, fatigue, drowsiness, unconsciousness, or coma. Exposure may cause a sore throat, runny nose, difficult breathing, shortness of breath, or coughing. Inhalation of decomposition products in high concentration may cause shortness of breath (lung edema). Inhalation may cause headaches, difficult breathing, and loss of consciousness. A component maybe harmful if inhaled. Effects Of Overexposure - Ingestion: Ingestion may cause irritation to mucous membranes. May result in possible corrosive action in the mouth, stomach tissue, and digestive tract. Vomiting may cause aspiration of the solvent, resulting in chemical pneumonitis. Ingestion may cause nausea, vomiting, abdominal pain, and diarrhea. Ingestion may cause nervous system effects, which may include headache, dizziness, numbness, staggering gait, or confusion. Effects Of Overexposure - Chronic Hazards: Prolonged contact will cause drying and cracking of the skin, due to defatting action. Skin sensitization, asthma, or other allergic responses may develop. Kidney and liver damage may occur from prolonged or repeated overexposures. Repeated and prolonged exposure may cause delayed effects involving the blood, gastrointestinal, nervous, and reproductive systems. Exposure to a component may cause kidney damage, coma, difficult breathing, liver damage, blood abnormalities (breakage of red blood cells), blood in the urine, or death. Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Material Safety Data Sheet
For Coatings, Resins and Related Materials NOTE: CHEMTREC, CANUTEC and National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals
24 Hour Emergency: 1-800-123-4567 CHEMTREC: 1-800-424-9300National Response in Canada CANUTEC: 613-996-6666 Outside U.S. and Canada Chemtrec: 202-483-7616
Section 1 - Chemical Product / Company Information
Product Name: MIL-PRF-85582D-TYPE I-CLASS C1 BASE Revision Date: 06/21/2011
Identification Number: 44GN007 Print Date:
Product Use/Class: EPOXY PRIMER BASE COMPONENT/MIL-PRF-85582, TYPE I, CLASS C1 (BARIUM CHROMATE)
NSN:
Manufacturer: Deft, Inc. (CAGE CODE 33461) 17451 Von Karman Ave Irvine, Ca. 92614
Information Phone: Emergency Phone:
(949) 474-0400(800) 424-9300
Section 2 - Hazards Identification
Section 3 - Composition / Information On Ingredients
ALL INGREDIENTS ARE ON THE TSCA INVENTORY LIST, UNLESS OTHERWISE NOTED IN SECTION
8.
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Hold eyelids open to rinse out the entire eye. Consult a physician. If symptoms develop from airborne exposure, move to fresh air. First Aid - Skin Contact: Remove contaminated clothing and shoes. In case of contact, immediately flush skin with plenty of water and wash affected areas thoroughly with soap and water for at least 15 minutes. If symptoms develop (such as irritation), consult a physician or get medical attention. Wash contaminated clothing thoroughly before reuse or discard. First Aid - Inhalation: Move to fresh air in case of accidental inhalation of vapors. Give oxygen or artificial respiration if needed. Asthmatic type symptoms may develop and maybe immediate or delayed by several hours. In the case of inhalation of aerosol/mist, consult a physician, if necessary. First Aid - Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Consult a physician.
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Spray, Dry Sand, Dry Powder Unusual Fire And Explosion Hazards: Keep containers tightly closed. Isolate from heat, sparks, electrical equipment and open flame. Closed containers may burst if exposed to extreme heat or fire. Application to hot surfaces requires special precautions. Toxic gases may form when product burns. Vapors are heavier than air and may travel/spread along the floors/ground. Vapors may flow along surfaces or they can be moved by ventilation, to a distant source of ignition. Do not use a cutting or welding torch near or on a drum of product, because vapors may ignite explosively, even if the drum is empty and contains only product residue. Peroxides of unknown stability and that are explosive may form. Special Firefighting Procedures: In the event of fire, wear self-contained breathing apparatus. Firefighters should wear full protective clothing. In the event of fire, cool tanks with water spray.
Steps To Be Taken If Material Is Released Or Spilled: Evacuate all non-essential personnel. Remove all sources of ignition. Ventilate area. Contain and remove spilled material with inert absorbent and non-sparking tools. Dispose of as hazardous waste. Dike to prevent entering any sewer or waterway. Soak up with vermiculite or inert absorbent material and dispose of as hazardous waste. Only trained personnel wearing protective equipment should handle spill cleanup. Avoid personal contact.
Handling: Prevent prolonged breathing of vapors or spray mist. Avoid contact with eyes and skin. Do not take internally. Do not handle until the manufacturers safety precautions have been read and understood. Handle in accordance with good industrial hygiene and safety practice. Keep away from heat and sources of ignition. Use safety precautions with empty containers. Empty containers may contain hazardous materials (product residues) in the form of solids, liquids, or vapors. Always use grounding leads when transferring from one container to another. Storage: Store in buildings designed to comply with OSHA 1910.106. Avoid storing near high temperatures, fire, open flames, and spark sources. Keep containers upright to prevent leakage and tightly closed in a dry, cool, and well-ventilated place. Protect material from direct sunlight.
Section 4 - First Aid Measures
Section 5 - Fire Fighting Measures
Flash Point (°F): 116 TCC LOWER EXPLOSIVE LIMIT (%): 1.0
UPPER EXPLOSIVE LIMIT (%): 10.
Section 6 – Accidental Release Measures
Section 7 - Handling and Storage
Section 8 - Exposure Controls / Personal Protection
NotesBARIUM CHROMATE CAS# 10294-40-3 - Contains 20.5 weight % Hexavalent Chromium. IARC Group 1 carcinogenic to humans. NTP group 1 known carcinogen. ACGIH category A2 (2002) suspected human carcinogen. Inhalation of 30 mg/m3 of Hexavalent Chromium is immediately dangerous to life or health. Ingestion of high concentration may cause intense thirst, shock, dizziness, oliguria, severe circulatory collapse, vomiting, anuria, or abdominal pain. Death may occur due to uremia. Ingestion in one uptake of approximately 1-16 g
Page 2 of 5MSDS Number: 44GN007 MIL-PRF-85582D-TYPE I-CLASS C1 BASE
Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient concentrations below permissible OSHA exposure limits. Remove all ignition sources (heat, sparks, flame, and hot surfaces). Respiratory Protection: A respirator that is recommended or approved for use in an organic vapor environment (air purifying or fresh air supplied) is necessary. Observe OSHA regulations for respirator use. Ventilation should be provided to keep exposure levels below the OSHA permissible limits. Skin Protection: Solvent-resistant gloves. Eye Protection: Wear safety eyewear (safety glasses, safety glasses with side-shields, chemical goggles, or face shields) to prevent eye contact. Other protective equipment: Long sleeve and long leg clothing is recommended. Remove and wash contaminated clothing before reuse or discard. Wear boots that are chemical-resistant. Hygienic Practices: Wash hands before breaks, eating, smoking, using washroom, and at the end of the workday.
(See section 16 for abbreviation legend)
Conditions To Avoid: Avoid high temperatures. Epoxy resins under uncontrolled conditions. Do not breathe vapors or spray mist. Incompatibility: Material is incompatible (reacts) with oxidizing agents (strong oxidizers), strong acids (including exothermic reactions with strong acids), strong alkalis, strong reducing agents, epoxy resins, isocyanate functional materials, heat, aluminum, and salts of strong bases. Material is incompatible with oxidizing agents. Material is incompatible with acids and bases. Reacts with amines and mercaptans. Hazardous Decomposition: Thermal decomposition can lead to the generation and release of gases and vapors including carbon monoxide, carbon dioxide, and oxides of nitrogen. Chromium oxides when burned. Thermal decomposition may generate irritating gases and vapors. Ketones, organic acids, and aldehydes may form. Hazardous Polymerization: Polymerization may occur. Stability: Stable under recommended storage conditions.
Ecological Information: No Information.
Disposal Information: Dispose of waste in accordance with federal, state, and local environmental regulations. Empty containers will contain product residue and flammable vapors. Handle as hazardous material. Do not incinerate closed containers. EPA Hazardous Waste Number/Code: D001, D007. Hazardous Waste Characteristics: Ignitability.
can be lethal to humans.2-BUTYOXYETHANOL CAS# 111-76-2 - This component has been shown to cause harm to the fetus in laboratory animals. It only caused harm at levels of overexposure that would also harm the pregnant animal. It has been shown to cause cancer in laboratory animals. The relevance to humans is unknown. It also has been shown to cause reversible kidney effects, reversible liver effects, and blood abnormalitiesin laboratory animals. Congestion in the spleen, liver, kidneys, and lungs resulted from acute lethal exposure in animal studies.TITANIUM DIOXIDE CAS# 13463-67-7 - ACGIH/TLV & OSHA/PEL exposure limits are for the total dust. IARC Group 2B possibly carcinogenic to humans. Titanium Dioxide is considered by NIOSH to be a potential occupational carcinogen under Hazard Communication Standard, 29 CFR 1910.1200. This was based on NIOSH's interpretation of the study by Lee, Trochimowicz, and Reinhardt [1985], "Pulmonary Response of Rats Exposed to Titanium Dioxide (TiO2) by Inhalation for Two Years." "The authors of this study concluded that based on the excessive dust loading and overwhelmed clearance mechanism in the lungs of rats exposed chronically at 250 mg/m3 (6 hrs/day, 5 days/week for 2 years), the biological relevance of lung tumors to man appears to be negligible."
CERCLA – SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Toxic Substances Control Act: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:
U.S. State Regulations: As follows – New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product.
Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%.
California Proposition 65: Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other reproductive hazards.
International Regulations: As follows – CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: B2, D1A, D2A, D2B
NFPA Health Rating: 2 NFPA Specific Hazard Rating: ND NFPA Stability Rating: 1 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 390 VOLATILE ORGANIC COMPOUNDS, LB/GAL: 3.25 VOLATILE ORGANIC COMPOUNDS MIXED, GR/LTR: <= 340 VOLATILE ORGANIC COMPOUNDS MIXED, LB/GAL: <= 2.83 VOLATILE ORGANIC COMPOUNDS, LB/LB-SOLID: <= 0.34 VOLATILE ORGANIC COMPOUNDS OF MATERIAL (SCAQMD RULE 443.1), GR/LTR: 390 VOLATILE ORGANIC COMPOUNDS OF MATERIAL (SCAQMD RULE 443.1), LB/GAL: 3.25 VOLATILE HAPs PER WEIGHT SOLIDS, LB./LB. 0.00733 REASON FOR REVISION: ADDED NSN TO FORMAT REGULATORY CODE: 44GN007 LAYOUT CODE: A2004R Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations.
Page 5 of 5MSDS Number: 44GN007 MIL-PRF-85582D-TYPE I-CLASS C1 BASE
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 42%
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
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Section 2. Hazards identification
Signal word : Danger
Hazard statements : Highly flammable liquid and vapor.Harmful if swallowed or if inhaled.Causes serious eye damage.Causes skin irritation.May cause an allergic skin reaction.May cause cancer.Suspected of damaging the unborn child.Causes damage to organs through prolonged or repeated exposure.
Hazard pictograms :
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN (or hair):Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse.If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing. Immediately call a POISON CENTER or physician.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
Supplemental label
elements
: Sanding and grinding dusts may be harmful if inhaled. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Trimethoxysilanes are capable of forming methanol if hydrolyzed or ingested. If swallowed, methanol may be harmful or fatal or cause blindness. Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches,drowsiness and nausea and may lead to unconsciousness or death. This product either contains formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory sensitizer. NTP, IARC and OSHA have classified chromium (+6) compounds as carcinogenic. Avoid contact with skin and clothing. Wash thoroughly after handling.Emits toxic fumes when heated.
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Section 2. Hazards identificationHazards not otherwise
classified
: Prolonged or repeated contact may dry skin and cause irritation.
Section 3. Composition/information on ingredients
strontium chromate ≥20 - ≥50 7789-06-2
Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Product name 513X419 BASE COMPONENT:
SUB codes represent substances without registered CAS Numbers.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
:Eye contact
Potential acute health effects
If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Causes serious eye damage.
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Section 4. First aid measures
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Inhalation :
:Ingestion
Skin contact :
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:stomach painsreduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:pain or irritationrednessdrynesscrackingblistering may occurreduced fetal weightincrease in fetal deathsskeletal malformations
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Harmful if inhaled.
Harmful if swallowed.
Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Section 5. Fire-fighting measures
Use dry chemical, CO≥, water spray (fog) or foam.
Extinguishing media
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:carbon oxideshalogenated compoundsmetal oxide/oxidesFormaldehyde.
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
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Section 6. Accidental release measuresStop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Do not store above the following temperature: 35°C (95°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Special precautions : Ingestion of product or cured coating may be harmful. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.Vapors are heavier than air and may spread along floors. If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts.
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TWA: 20 ppm 8 hours.OSHA PEL (United States, 6/2016).
TWA: 435 mg/m³ 8 hours. TWA: 100 ppm 8 hours.
Appropriate engineering
controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Recommended monitoring
procedures
: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards.Reference to national guidance documents for methods for the determination of hazardous substances will also be required.
Key to abbreviations
A Acceptable Maximum Peak=
ACGIH = American Conference of Governmental Industrial Hygienists.
C = Ceiling Limit
Potential skin absorptionS
SR = Respiratory sensitization
= Skin sensitizationSS
TD = Total dust
Consult local authorities for acceptable exposure limits.
= Threshold Limit ValueTLV
TWA = Time Weighted Average
Fume=F
IPEL = Internal Permissible Exposure Limit
= Occupational Safety and Health Administration.OSHA
R = Respirable
OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z
STEL =
=
Short term Exposure limit values
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :
Chemical splash goggles and face shield.
Gloves butyl rubber:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate,certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Not available.Odor
pH
Yellow.Color
Flash point Closed cup: 16.11°C (61°F)
Not available.
Not available.Odor threshold
:
:
:
:
:
:
:
Appearance
Boiling point : >37.78°C (>100°F)
Yes.:Material supports
combustion.
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Target organs : Contains material which causes damage to the following organs: blood, liver, spleen,brain, skin, bone marrow.Contains material which may cause damage to the following organs: kidneys, lungs, the nervous system, the reproductive system, heart, peripheral nervous system,cardiovascular system, upper respiratory tract, immune system, bones, central nervous system (CNS), eye, lens or cornea.
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Section 11. Toxicological information
Conclusion/Summary :
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Inhalation : Harmful if inhaled.
Harmful if swallowed.:Ingestion
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Causes serious eye damage.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:stomach painsreduced fetal weightincrease in fetal deathsskeletal malformations
Adverse symptoms may include the following:pain or irritationrednessdrynesscrackingblistering may occurreduced fetal weightincrease in fetal deathsskeletal malformations
:
:
:
Eye contact : Adverse symptoms may include the following:painwateringredness
There are no data available on the mixture itself. Trimethoxysilanes are capable of forming methanol if hydrolyzed or ingested. If swallowed, methanol may be harmful or fatal or cause blindness. This product either contains formaldehyde or is capable of releasing formaldehyde above 0.5 ppm under certain conditions. Formaldehyde is a known cancer hazard, a skin sensitizer and a respiratory sensitizer. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache,dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Solvents may cause some of the above effects by absorption through the skin. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. If splashed in the eyes, the liquid may cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
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May cause cancer. Risk of cancer depends on duration and level of exposure.
Causes damage to organs through prolonged or repeated exposure. Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
Suspected of damaging the unborn child.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
There are no data available on the mixture itself.
Section 12. Ecological information
Bioaccumulative potential
Product/ingredient name Aquatic half-life Photolysis Biodegradability
toluene - - Readilyethylbenzene - - Readily
Toxicity
titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
ethylbenzene Acute LC50 150 to 200 mg/l Fresh water Fish - Lepomis macrochirus -Young of the year
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
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The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures
14. Transport information
PAINT
3
II
PAINT
3
II
PAINT
UN1263
3
II
UN1263 UN1263
DOT IMDG IATA
UN number
UN proper shipping
name
Transport hazard class
(es)
Packing group
Environmental hazards No. Yes. Yes. The environmentally hazardous substance mark is not required.
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14. Transport informationMarine pollutant
substances
Not applicable.(strontium chromate,
Formaldehyde, oligomeric
reaction products with 1-chloro-
2,3-epoxypropane and phenol)
RQ substances
37.829
(strontium chromate, xylene)
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Special precautions for user Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
Additional information
Package sizes shipped in quantities less than the product reportable quantity are not subject to the
The marine pollutant mark is not required when transported in sizes of ≥5 L or ≥5 kg.
DOT
IMDG
:
:
IATA : The environmentally hazardous substance mark may appear if required by other transportation regulations.
Product RQ (lbs)
Section 15. Regulatory information
SARA 302/304
SARA 304 RQ : Not applicable.
Composition/information on ingredients
SARA 311/312
Classification : Fire hazardImmediate (acute) health hazard
Delayed (chronic) health hazard
strontium chromate No. No. No. Yes. Yes. -
Formaldehyde, oligomeric reaction
products with 1-chloro-2,
3-epoxypropane and phenol
No. No. No. Yes. No. -
crystalline silica, respirable powder
(<10 microns)
No. No. No. No. Yes. -
heptan-2-one Yes. No. No. Yes. No. -
4-methylpentan-2-one Yes. No. No. Yes. Yes. -
Name Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
All components are listed or exempted.United States inventory (TSCA 8b) :
United States
United States - TSCA 12(b) - Chemical export notification:strontium chromate Annual notification
No products were found.
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Section 15. Regulatory information
SARA 313
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
Hazardous Material Information System (U.S.A.)
3
03
National Fire Protection Association (U.S.A.)
Health InstabilityFlammability
Health Flammability Physical hazards
Disclaimer
Date of previous issue 12/19/2016:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are
to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
Organization that prepared
the MSDS
: EHS
:: :
: : :3 *
3
0( * ) - Chronic effects
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Section 16. Other informationThe information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.