O O O O O O O OH O-Ac OH O OH O COOH OH OMe OH OH O O O-Ac OH O OH O-Ac 1 2 3 4 5 1 2 4 5 3 3 Influence of Hemicellulose Extraction on Suitability for Oriented Strand Board (OSB) Production Rory H. Jara a Juan Paredes b Adriaan van Heiningen a Stephen Shaler b a Department of Chemical and Biological Engineering b Advanced Engineered Wood Composites Center
Extraction of wood components from OSB strands using hot water. A composition of the liquid phase (extract) is given for different extraction conditions. Mechanical properties of OSB panels made with the extracted wood are compared with standard panels.
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Influence of Hemicellulose Extraction on Suitability for Oriented Strand Board
(OSB) Production
Rory H. Jaraa
Juan Paredesb
Adriaan van Heiningena
Stephen Shalerb
a Department of Chemicaland Biological Engineering
b Advanced Engineered Wood Composites Center
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Department of Chemical and Biological Engineering2
Outline
BackgroundObjectivesExperimental proceduresResults and discussionsConclusions
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OSB ProcessWood componentsChemical composition and wood strength
Background
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OSB ProcessBackground
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Log Hauling and SortingLadding
Debarking
Logs
StrandingScreening
Drying
Blending
Forming linePressing
Finishing lineShipping
HemicelluloseExtraction Process
Modified OSB Process
Sugar-basedpolymers
Sugar-basedchemicals
FurfuralXylitol
Ethanol
Background
PERFORMANCE ?
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Softwood (% o. d. wood)Cellulosea 33.0 – 42.0Lignina 27.0 – 32.0Hemicellulosesa 26.0 – 33.0Ashb 0.1 – 0.5
a Sjostron, E., 1993b Rowell, R., 2005
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CelluloseGlucomannan
Lignin 1
XylanLignin 2
(Lawoko et al. Biomacromolecules 6(6) 3467-3473, 2005)
Wood ComponentsBackground
(Sweet et al. Holzforschung 53 (1999) 311-317)
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Chemical composition and wood strength
Background
Molecular level depends on individual components of the cell wall
Cellulose greatest polymeric chain and higher DP
Lignin is a nature’s adhesive. Hydrophobic polymer.
Cellulose and lignin are the main structural wood components. Hydrogen bonds are important for providing rigidity.
Hemicelluloses are a series of carbohydrate molecules with lowerDP than cellulose. They exhibit hydrogen bonding.
Early degradation of hemicelluloses affect the wood strength (Curling at al., Forest Products Journal, Vol. 52, No 78, 2002)
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Issues to be consideredMechanical properties of OSB must be maintained after hemicellulose extractionThe extraction process must minimize degradation of both cellulose and lignin
Background
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Objective
• Determine how specific variables in the OSB strand extraction process (namely, pH, temperature, time and strand thickness) affect hemicellulose yields and characteristics of cellulose and lignin in the wood
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Procedure
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Wood material preparationRed Maple tree (hardwood)Stranding process at AEWC CenterWood material air-dried
Experimental Procedures
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Lab ExtractionExperimental Procedures
Modified ASE-100Wood strands
Water
Filtrate(Hemicellulose Extract)
Solid Residue(Extracted strands)
Temperature: 140 – 170ºC
Time: 15 – 90 min
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Water Extraction
Solid Phase
Weight Loss(Oven Dried)
DMC Extraction
Liquid Phase(Solid Determ.) Hydrolysis (1º, 2nd)
HPAEC Analysis
Klason Lignin Cellulose
Liquid Phase
Centrifuge
2nd Hydrolysis
Undissolved Material
HPAEC Analysis
Klason Lignin
Cellulose Hemicelluloses
Solid Content(Freeze Drying)
Ash Content
Hemicelluloses
Ash Content
WOOD
Acid Sol. Lignin
Chemical analysis procedure
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