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HELIOS-IR Mid-IR Transient Absorption Spectrometer Femtosecond Transient Absorption of Mn 2 (CO) 10
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HELIOS-IR. Femtosecond Transient absorption of Mn2(CO)10 in Mid-IR.

Aug 08, 2015

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Page 1: HELIOS-IR. Femtosecond Transient absorption of Mn2(CO)10 in Mid-IR.

HELIOS-IRMid-IR Transient Absorption Spectrometer

Femtosecond Transient Absorption of Mn2(CO)10

Page 2: HELIOS-IR. Femtosecond Transient absorption of Mn2(CO)10 in Mid-IR.

Experiment Details• Date: May 08, 2014

• Sample: Mn2(CO)10

• Solvent: Cyclohexane

• Laser / OPA: Libra (Coherent) @ 1 kHz / TOPAS

• Pump energy: 2 uJ

• Pump wavelength: 400 nm

• Sample thickness: 0.15 mm

• Averaging time per scan: 1.0 s

• Number of scans: 3

• Measurement time: 00:21:05

© Ultrafast Systems

Page 3: HELIOS-IR. Femtosecond Transient absorption of Mn2(CO)10 in Mid-IR.

Mn2(CO)10 Dynamic Surface with Kinetic and Spectral Slices in Surface Xplorer Software

© Ultrafast Systems

Page 4: HELIOS-IR. Femtosecond Transient absorption of Mn2(CO)10 in Mid-IR.

Dynamic Surface of Mn2(CO)10

Linear Timescale

© Ultrafast Systems

Page 5: HELIOS-IR. Femtosecond Transient absorption of Mn2(CO)10 in Mid-IR.

Dynamic Surface of Mn2(CO)10

Logarithmic Timescale

© Ultrafast Systems

Page 6: HELIOS-IR. Femtosecond Transient absorption of Mn2(CO)10 in Mid-IR.

Transient Kinetics & Spectra of Mn2(CO)10 in Cyclohexance

© Ultrafast Systems