MANOIR PETROCHEM ® Heat-resistant alloys for hydrocarbon processing
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MANOIR INDUSTRIES
www.manoir-industries.com MANOIR PETROCHEM®
Heat-resistant alloys for hydrocarbon processing
MA
NO
IR PETROC
HEM
®
Manoir Pitres12, rue des Ardennes - BP 8401 - Pitres
77108 Val de Reuil Cedex
Tel. +33 2324 87200 - Fax +33 2324 95726
Manoir YantaiN° 1, Zhichu South Road, Zhifu district
Yantai, China 264 000
Tel. +86 6851 895, 6851 881 - Fax +86 6851 895
Manoir UKHi-Tech Fabrication Ltd
Bretby Business Park - Ashby Road
Burton on Trent - Staffordshire DE15 OYZ
Tel. +44 1283 817902 - Fax +44 1283 81790
Manoir Petro India LimitedUniversal Business Park
602, B - Wing - Chandivali farm Road - Andheri (E)
Mumbai - 400 072 India
Tel. +91 9920 167307
Manoir ChennaiKartik Steels Ltd
”Minimic Centre“ 2nd Floor - Chennai 600087
Tel. +91 4424 762451, 4442 144494 - Fax +91 4424 762452
MMG 4 - NOVEMBRE 10 ................. 1
Owned by Sun Capital Partners, anAmerican investment fund, the Manoir
Industries Group, a specialist in steel
transfor mation through casting and
forging, has been structured into Business
Units.
While the Aerospace & Specialties
Business Units consist of 4 forges and 3
foundries, the petrochemical BU, known as
Manoir Petrochem Nuclear has grown in
strength through significant internal and
external development:
• The plant of Pitres, France, well known
historically for having given its name to
the Group, is still positioned as the
leading plant and focuses on the
production of sophisticated alloys and
technologies. The current boom observed
in the nuclear market has also reinforced
the position of this plant for being one of
the most knowledgeable companies in
respect of QA systems for the casting
industry. This facility is dedicated to the
manufacture of high integrity products
and recently developed a new generation
of alloys (as detailed in this document)
which has gained market acceptance
since their introduction in 2005.
• Manoir Yantai, in China, is now a well
established manufacturer for the
petrochemical industry and has supplied
reformer tubes and ethylene coils direct
to engineering companies and end users.
The production has been transferred as
planned to a brand new facility and
operates with production tools similar to
the ones established in France.
• Moreover, Manoir Industries has since
2010, acquired the balance of the Manoir
Yantai shares to become the sole owner
of the company.
• One recent acquisition of Manoir
Industries and adding to Manoir
Petrochem Portofolio is Hi-tech
Fabrication, a fabrication shop located
near to Birmingham, UK. HTF is an
extremely capable shop when it comes to
complex welding in various alloys and
processes. This unit significantly enhances
our product offer through the production
of cold inlet & outlet systems, transfer
lines, and other fabricated components,
including convection banks. This addition
to the Group reinforces our objective to
become a major supplier of a wide
package of spares for furnaces in the
petrochemical industry.
• To further develop our presence in the
Indian subcontinent, and following the
opening of our sales office in Mumbai in
2009, we have acquired a casting facility
located south of Chennai, called Kartik
Steels Limited (KSL). Adjacent to this
foundry which has been producing for
the last 30 years and which casts products
for the petrochemical industry, Manoir
will build a fabrication shop aiming at
welding various tubes, coils and other
components from the other plants of the
division for the Indian Market.
This brochure will provide you withan update on the mechanical properties of
our current alloy portfolio, as well as the
latest alloy releases available.
Visit us on www.manoir-industries.comfor the latest updated news.
Thank you.
HEAT-RESISTANT ALLOYS FOR HYDROCARBON PROCESSING
2 .................. MMG 4 - NOVEMBRE 10
MMG 4 - NOVEMBRE 10 ................. 3
HEAT-RESISTANT ALLOYS FOR HYDROCARBON PROCESSING
4 .................. MMG 4 - NOVEMBRE 10
MMG 4 - NOVEMBRE 10 ................. 5
HEAT-RESISTANT ALLOYS FOR HYDROCARBON PROCESSING
6 .................. MMG 4 - NOVEMBRE 10
MANAURITE
50/50N
bXTM
40XO
40X
XO
XM
XMR
36X
20XT
M lo
wC
900B
900
Temperature Lim
it
°F16
52**
2192
2192
2102
2102
2015
*20
15*
1922
1850
1976
1976
1835
2102
°C90
0**
1200
1200
1150
1150
1110
*10
50*
1050
1010
1080
1080
1000
1150
Tubes
Rad
iant
Elbows
section
Rad
iant co
ilhan
gers
Conve
ction
Tubes shee
tssection
& brackets
Tran
sfer line
line
Rad
iant
Tubes
section
Conve
ction
Tubes shee
tssection
& brackets
Tran
sfer
Man
ifolds
line
Rad
iant
Tubes
Section
Static
castings
Conve
ction
Tubes shee
tssection
& brackets
Tran
sfer line
STEA
MCRACKING
REF
ORMING
Hyd
rogen
,am
monia,
methan
ol)
DRI
Main high
temperature applications
High carbon alloys
Low
carbon alloys
* for specific applications, a limit of 1135°C (2080°F) can be guaranted
** in severe fuel ash environments
MMG 4 - NOVEMBRE 10 ................. 7
Man
oir
Industries
Additions
Applications
Main Features
designation
EN 10295
CMn
SiNi
Cr
Co
Austenitic Alloys
18 - 9
1.4825
HF0.25/0.400.70/1.251.00/1.75
9.5/11.5
18/21
Ti, Nb
Man
aurit
e 20
1.4848
HK0.30/0.551.00/2.001.00/2.50
18/24
23/28
Man
aurite 24
/24 Nb
1.4855
0.25/0.500.50/1.500.50/2.00
23/25
23/25
Nb
Man
aurite 36
X1.4852
HP0.35/0.601.00/1.501.00/2.00
33/38
23/28
Nb
Man
aurite 35
-25W
0.35/0.600.70/1.251.00/2.00
33/38
21/28
W
Man
aurite XM
1.4852
0.35/0.600.50/1.501.00/2.00
33/38
23/28
Man
aurite XM
R0.35/0.500.50/1.001.00/1.20
33/38
23/28
Man
aurite 40
X0.35/0.600.50/1.501.00/2.00
38/42
28/32
Man
aurite XT
M1.4889
0.40/0.600.50/2.001.00/2.00
43/48
34/37
Austenitic Alloys with aluminium
Man
aurite XO
0.35/0.600.50/1.501.00/2.00
33/38
23/28
Man
aurite 40
XO0.35/0.600.50/1.501.00/2.00
38/42
28/32
Nb, Ti,
and
others
Ti,
and
others
Al, Ta, Ti,
and
others
Al, Ta, Ti,
and
others
Nb, Ti,
and
others
Nb, Ti,
and
others
Tube sheets for
petrochemical furnaces
Reforming and ethylene cracking
tubes
Cast fittings and tube sheets
Reformer tubes
and furnace parts
Ammonia & methanol furnaces
Reforming and cracking coils
Ammonia & methanol furnaces
Reforming and cracking coils
Ammonia & methanol furnaces
Reforming and cracking coils
Ammonia & methanol furnaces
Reforming tubes
DRI radiation. Cracking coils
High carburizing and metal dusting
atmospheres
DRI radiation. Cracking coils
High carburizing and metal dusting
atmospheres
DRI radiation. Cracking coils
High carburizing and metal dusting
atmospheres
DRI radiation. Reforming & Cracking
coils High carburizing and metal
dusting atmospheres
Oxydation resistance
up to 800°C (1472°F)
Resistance to creep
up to 980°C (1800°F)
Improved stress rupture, over H
K 40. Better ductility
at operating temperature without impaired
weldability resistance to oxydation, carburisation
and thermal fatigue
High creep resistance and creep ductility
Good carburization and oxidation resistance
Good weldability after ageing
High carburization and oxidation resistance
up to 1080°C (1976°F). Good creep
strenght and goodcreep strain rate
Superior creep resistance and creep ductility
Improved carburization and oxidation resistance
up to 1100°C (2012°F)
Superior creep resistance to XM with same
properties for creep ductility, carburization
and oxidation resistance.
Superior carburization and oxidation
resistance to XM with same creep
resistance and creep ductility
Superior carburization and oxidation
resistance to 40X with same creep
resistance and creep ductility
Superior carburization and oxidation resistance with
very high creep strengh and creep ductility. Operating
t° up to 1150°C for carburization resistance.
Superior carburization and oxidation resistance. High creep
strengh and creep ductility. Op
erating t° up to 1160°C
(2120°F) for cracking furnaces. Also reforming applian
ce
resistance to contam
ination by heavy gas oil (S, Na, V)
Nominal Composition %
ASTM
A297/
A351
Similar grade
HEAT-RESISTANT ALLOYS FOR HYDROCARBON PROCESSING
8 .................. MMG 4 - NOVEMBRE 10
Man
oir
Industries
Additions
Applications
Main Features
designation
EN 10295
CMn
SiNi
Cr
Co
Austenitic Alloys
Man
aurit
e 50
W2.4879
0.35/0.551.00/1.501.00/2.00
45/52
25/32
W
Man
aurit
e 50
/50N
b2.4680
0.05/0.100.30/0.500.70/1.00
48/52
48/52
Nb
Man
aurite 75
2.4815
HX0.15/0.300.70/1.251.00/2.00
65/76
14/19
Man
aurite 90
01.4859
0.06/0.151.00/1.500.75/1.50
29/37
16/22
Nb
Man
aurite 90
0 B
0.10/0.181.00/1.501.00/1.50
33/37
24/27
Nb
Austenitic alloys with cobalt
Man
aurite 35
K1.4869
0.40/0.600.50/1.251.20/2.00
33/37
24/28
W
Man
aurite 50
W K
0.40/0.550.50/1.501.00/1.75
47/49
27/29
W
Austenitic alloys with tungsten
Man
aure 2
0.15/0.400.50/1.50
< 1.50
48/52
32/54
W: 12/14%
Elbows in petrochemical furnaces.
Tube sheets and supports.
Christmas tree supports.
Tube sheets and tube supports.
Special petrochem
ical com
ponents
For parts located outside furnaces e.g.
reformer furmace manifolds,
transferlines, pyrolysis furnace crossovers
Used at higher tem
peratures e.g.
for parts inside furnaces
Reformer tubes for petrochem
ical
appliances at high temperature
Ammonia furnaces tube sheets.
Equivalent to supertherm.
Similar to Manaurite 50 W but used
at higher tem
peratures. Radiant
tubes. Tube supports
Tube sheets ans supports - furnace
parts Thermow
ells.
Operating at elevated temperatures in cracking
process. Very good resistance to oxidation up to
1200°C (2192°F). Excellent creep resistance.
Resistance to oxidation and fuel ash corrosion.
Good aged ductility
Good creep strength. High thermal shock resistance.
Good ductility after ageing. Operating temperature
up to 1000°C (1832°F)
Similar properties to MAN
. 900 with higher
oxidation and carburization resistance : operating
temperature exceeding 1000°C (1832°F°
Withstands high temperatures up to 1245°C
(2300°F). Good resistance to hot corrosion.
Improved creep resistance with respect to
Manaurite 50 W. O
perating temperature up to
1200°C (2192°F). Good resistance to carburization.
Creep and oxidation resistance up to 1300°C (2372°F)
Nominal Composition %
ASTM
Similar grade
14/16
2,5/3,5
MMG 4 - NOVEMBRE 10 ................. 9
18-9 10
MANAURITE 20 12
MANAURITE 900 14
MANAURITE 900 B 22
MANAURITE 36 X 24
MANAURITE XM 26
MANAURITE 35-25 W 36
MANAURITE XTM 38
MANAURITE 50 W 44
MANAURITE 50/50 Nb 45
MANAURITE 75 46
MANAURE 2 48
MANAURITE 35 K 49
MANAURITE 50 WK 50
MANAURITE 24/24 Nb 51
MANAURITE 40X 59
Latest releaseMANAURITE XO 63
MANAURITE 40XO 75
MANAURITE XMR 78
Comparative COMPARATIVE INFORMATION 85
data
PhysicalandMechanicalproperties
10 ................ MMG 4 - MARS 09
18-9
10 ................ MMG 4 - NOVEMBRE 10
18-9SHORT TIME TENSILE PROPERTIES
18-9
MMG 4 - NOVEMBRE 10 ................. 11
SHORT TIME TENSILE PROPERTIES18-9
MANAURITE 20
12 ................ MMG 4 - NOVEMBRE 10
(typical values)
MANAURITE 20CREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 13
MANAURITE 900
14 ................ MMG 4 - NOVEMBRE 10
MANAURITE 900
MMG 4 - NOVEMBRE 10 ................. 15
MANAURITE 900
16 ................ MMG 4 - NOVEMBRE 10
MANAURITE 900
MMG 4 - NOVEMBRE 10 ................. 17
MANAURITE 900
18 ................ MMG 4 - NOVEMBRE 10
MANAURITE 900CREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 19
MANAURITE 900
20 ................ MMG 4 - NOVEMBRE 10
MANAURITE 900
MMG 4 - NOVEMBRE 10 ................. 21
MANAURITE 900 B
22 ................ MMG 4 - NOVEMBRE 10
MANAURITE 900 BCREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 23
MANAURITE 36X
24 ................ MMG 4 - NOVEMBRE 10
MANAURITE 36XCREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 25
MANAURITE XM
26 ................ MMG 4 - NOVEMBRE 10
(typical values)
MANAURITE XM
MMG 4 - NOVEMBRE 10 ................. 27
MANAURITE XM
28 ................ MMG 4 - NOVEMBRE 10
MANAURITE XMCREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 29
MANAURITE XM
30 ................ MMG 4 - NOVEMBRE 10
MANAURITE XM
100
Mp
a 10 1 10-6
10-5
10-3
10-2
10-1
Cre
ep r
ate
(%h
r-1 )
10-4
Ksi
1000
°C -
183
2°F
1050
°C -
192
2°F
1100
°C -
201
2°F
1150
°C -
210
2°F
950°
C -
174
2°F
Stress Mpa
CREE
P RATE
S
MMG 4 - NOVEMBRE 10 ................. 31
MANAURITE XM
32 ................ MMG 4 - NOVEMBRE 10
MANAURITE XM
PACK CEM
ENT CARBURIZATION TES
T(850
°C - 115
0°C)
MMG 4 - NOVEMBRE 10 ................. 33
MANAURITE 36 XS
34 ................ MMG 4 - NOVEMBRE 10
MANAURITE 36 XSMANAURITE 36XS
CREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)CREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 35
MANAURITE 35-25 W
36 ................ MMG 4 - NOVEMBRE 10
CREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 37
MANAURITE 35-25 W
MANAURITE XTM
38 ................ MMG 4 - NOVEMBRE 10
MANAURITE XTM
MMG 4 - NOVEMBRE 10 ................. 39
MANAURITE XTM
40 ................ MMG 4 - NOVEMBRE 10
MANAURITE XTMCREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 41
MANAURITE XTM
42 ................ MMG 4 - NOVEMBRE 10
MANAURITE XTMCARBURIZATION RESISTANCE DATA
MMG 4 - NOVEMBRE 10 ................. 43
MANAURITE 50 W
44 ................ MMG 4 - NOVEMBRE 10
(typical values)
MANAURITE 50/50 Nb
MMG 4 - NOVEMBRE 10 ................. 45
(typical values)
(typical values)
MANAURITE 75
46 ................ MMG 4 - NOVEMBRE 10
MANAURITE 75
MMG 4 - NOVEMBRE 10 ................. 47
MANAURE 2
48 ................ MMG 4 - NOVEMBRE 10
(typical values)
(typical values)
MANAURITE 35 K
MMG 4 - NOVEMBRE 10 ................. 49
(typical values)
(typical values)
MANAURITE 50 W K
50 ................ MMG 4 - NOVEMBRE 10
(typical values)
(typical values)
MANAURITE 24/24 Nb
MMG 4 - NOVEMBRE 10 ................. 51
(typical values)
(typical values)
MANAURITE 40X
52 ................ MMG 4 - NOVEMBRE 10
MANAURITE 40X
MMG 4 - NOVEMBRE 10 ................. 53
MANAURITE 40X
54 ................ MMG 4 - NOVEMBRE 10
MANAURITE 40XCREE
P RUPT
URE DATA
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 55
MANAURITE 40X
56 ................ MMG 4 - NOVEMBRE 10
MANAURITE 40XCREE
P RATE
S
MMG 4 - NOVEMBRE 10 ................. 57
MANAURITE 40X
58 ................ MMG 4 - NOVEMBRE 10
MANAURITE 40XSIMULATED CARBURIZATION TEST IN SOLID CEMENT
(850°C - 1150°C)
MMG 4 - NOVEMBRE 10 ................. 59
MMG 4 - NOVEMBRE 10 ................. 61
LATESTRELEASE
MANAURITE XO
PHYSICAL PROPERTIES
Specific gravity: 0.29 lb/inch3 (8.02 kg/dm3) Coefficient of expansion
Melting point: 1350°C (2460°F) in/in °F (10-6) mm/mm/°C (10-6)
From 70° F to 1560°F: 10,21 20°C to 850°C: 18.5
From 70° F to 1740°F: 10,4 20°C to 950°C: 18.9
Thermal conductivity From 70° F to 1920°F: 10,6 20°C to 1050°C: 19.3
At 1050°C (1922°F): 30 W/m.°C From 70° F to 2100°F: 10,9 20°C to 1150°C: 19.7
(17 Btu/h.ft.°F)
At 20°C (68°F): 10.5 W/m.°C
(6 Btu/h.ft.°F)
Specific heat Young modulus
62 ................ MMG 4 - NOVEMBRE 10
Temperature Cal/g. °C or J/kg. °C
°C °F BTU/lb. °F
20 68 0,112 469
100 212 0,117 489,9
200 392 0,124 519,3
300 572 0,130 544,4
400 752 0,137 573,7
500 932 0,143 598,8
600 1112 0,150 628,2
700 1292 0,157 657,5
800 1472 0,163 682,6
900 1652 0,170 711,9
1000 1832 0,177 741,2
1100 2012 0,183 766,4
1200 2192 0,190 795,7
Temperature
°C °F MPa ksi
20 68 161,900 23,470
100 212 155,000 22,475
200 392 147,150 21,337
300 572 138,000 20,010
400 752 133,400 19,343
500 932 126,000 18,270
600 1112 117,700 17,066
700 1292 111,000 16,095
800 1472 106,000 15,360
900 1652 101,000 14,650
1000 1832 97,100 14,080
1100 2012 93,200 13,510
MANAURITE XOMECHANICAL PROPERTIES
1 • At room temperature(minimum values)
Ultimate tensile strength: 450 MPa 65 000 psi
Yield strength: 250 MPa 35 500 psi
Elongation (on 4d): 8% for centrifugally pipes
2 • Short time tensile test at various temperatures on as cast material
Temperature U.T.S. Y.S. E
°C °F MPa ksi MPa ksi %
750 1382 333 48,4 157 22,8 16
800 1472 265 38,2 147 21,3 20
850 1562 196 28,4 137 19,9 22
900 1652 147 21,3 118 17,1 30
950 1742 118 17,1 88 12,8 32
1000 1832 93 13,5 78 11,4 40
1050 1922 72 10,7 67 10,0 40
1100 2012 57 8,8 52 8,0 40
MMG 4 - NOVEMBRE 10 ................. 63
CREEP PROPERTIES
Long time creep rupture data
Manaurite XO 100 000 hrs creep rupture strength
Temperature Average Minimum values ° C values (MPa) (MPa)
850 44.5 38.2
875 36.6 31.8
900 30.3 26.6
925 24.8 21.7
950 20.1 17.6
975 16.3 14.2
1000 13.2 11.7
1025 10.4 9.1
1050 8.2 7.1
1075 6.4 5.4
1100 4.8 4.1
64 ................ MMG 4 - NOVEMBRE 10
3031
3233
3435
3637
3839
40
100 10 1
Mp
a
100
000
hr
900
1000
1100
°C °F20
0018
00
LMP
= T
/100
0(22
.96
+ lo
g(t
)) T
: °K
t: h
r
1600
Ave
rag
e St
ress
Min
imu
m S
tres
s
MANAURITE XOCREE
P RUPT
URE ST
REN
GTH
(95
% CONFIDEN
CE LE
VEL
)
MMG 4 - NOVEMBRE 10 ................. 65
66 ................ MMG 4 - MARS 09
2.0
1.8
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.0
00.
51
1.5
22.
53
3.5
4
Dep
th f
rom
ID (
mm
)
∆ Carbon (%)
MANAURITE XO
66 ................ MMG 4 - NOVEMBRE 10
CARBURIZATION TES
T 85
0 - 11
50° C
MMG 4 - MARS 09...........................67
MANAURITE XO
MMG 4 - NOVEMBRE 10 ................. 67
0.005
0.004
0.003
0.002
0.001
0 1
Number of cyclesCycle : heat up = 300° C per hr / soaking time = 10 hr / cooling down = 300° C per hr
2 3 4 7 6 7 8 9 10
∆m p
er s
urf
ace
un
it (
g/c
m2 )
Temperatures
1000° C
1100° C
CYCLING OXIDATION IN AIR:TOTAL WEIGHT INCREASE PER SURFACE UNIT
OXYDATION RESISTANCE
1 • Oxydation processAfter ethanol cleaning, samples are weighed (3 times)
Cycle: Heat up : 300° C.h-1
Soaking time : 10 hours
Cooling : 300° C.h-1
After cycle, sample (with scale eventually) is weighed.
See curves obtained for weight increase hereafter.
68 ................ MMG 4 - MARS 09
MANAURITE 40XO
PHYSICAL PROPERTIES
Specific gravity:
at 20°C (68°F) : 0.292 Ib/inch3 (8.05 kg/dm3) Coefficient of expansion
Melting point: 1340°C (2440° F) 106.(°K)-1
68°F to 1112°F - 20°C to 600°C: 16.1
68°F to 1292°F - 20°C to 700°C: 16.6
Thermal conductivity 68°F to 1472°F - 20°C to 800°C : 16.9
At 23°C (73°F) : 9.95 W/m.°C 68°F to 1652°F - 20°C to 900°C : 17.2
(5.8 Btu/h.ft.°F) 68°F to 1832°F - 20°Cto 1000°C : 17.6
At 100°C (212°F) : 11.2 W/m.°C 68°F to 2012°F - 20°Cto 1100°C : 17.9
(6.5 Btu/h.ft.°F) 68°F to 2192°F - 20°Cto 1200°C : 18.4
At 750°C (1382°F) : 20.3 W/m.°C
(11.7 Btu/h.ft.°F)
At 1050°C (1922°F) : 30 W/m.°C
(17 Btu/h.ft.°F)
Specific heat Young modulus
Temperature Cal/g. °C or J/kg. °C
°C °F BTU/lb. °F
20 68 0.112 469
100 212 0.117 490
750 1382 0.145 606
Temperature
°C °F MPa ksi
20 68 166,200 24.087
100 212 159,000 23.040
200 392 150,500 21.800
300 572 141,000 20.430
400 752 136,000 19.710
500 932 128,000 18.550
600 1112 119,800 17.360
700 1292 113,000 16.380
800 1472 107,000 15.510
900 1652 101,500 14.710
1000 1832 97,500 14.130
1100 2012 93,500 13.550
68 ................ MMG 4 - NOVEMBRE 10
MANAURITE 40XO
Temperature U.T.S. Y.S. E
°C °F MPa ksi MPa ksi %
700 1292 380 55 176 26 15
800 1472 275 40 155 22 25
900 1652 160 23 127 18 35
1000 1832 100 14 82 12 40
1100 2012 57 8.5 52 7.6 40
MECHANICAL PROPERTIES
1 • At room temperature(Minimum values) (Typical values)
Ultimate tensile strength : 450 MPa 65 000 psi 540 MPa
Yield strength 250 MPa 35 500 psi 280 MPa
Elongation (on 4d) 8% for centrifugally cast pipes 12%
5% for static castings
2 • Short time tensile tests at various temperatures on as cast material
CREEP PROPERTIESLong time test creep dataManaurite 40XO 100,000 hrs creep rupture strength
MMG 4 - NOVEMBRE 10 ................. 69
Temperature Average Minimum values ° C values (MPa) (MPa)
800 47.5 40.7
825 41.3 35.8
850 35.5 30.9
875 30.6 26.6
900 25.8 22.3
925 321.4 18.5
950 17.6 15.3
975 14.3 12.6
1000 11.5 10.1
1025 9.2 8
1050 7.3 6.3
1075 5.8 4.9
1100 4.4 3.8
(typical values)
100
Mp
a 10
2627
2829
3031
3233
3435
36
1
AV
G s
tres
s 40
XO
MIN
str
ess
40X
O
1400
1600
1800
2000
°F°C11
0010
0090
080
010
0 00
0 h
r
LMP
= T
/100
0(20
.3 +
log
(t)
) T
: °K
t
: hr
MANAURITE 40XO
70 ................ MMG 4 - NOVEMBRE 10
CREE
P RUPT
URE ST
REN
GTH
(95
% CONFIDEN
CE LE
VEL
)
100
820
870
920
970
Tem
per
atu
re (
°C)
Co
mp
arai
son
in 1
00 0
00 h
r ru
ptu
re t
ime:
40X
O v
s X
M a
nd
XTM 10
2010
7011
20
1
MPa
XM
min
40X
O m
in
XTM
min
MANAURITE 40XOCOMPA
RATIVE CREE
P DATA
MMG 4 - NOVEMBRE 10 ................. 71
72 ................ MMG 4 - NOVEMBRE 10
MANAURITE 40XO2.
0
1.8
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.0
00.
51
1.5
22.
53
3.5
4
Dep
th f
rom
ID (
mm
)
∆ Carbon (%)
CARBURIZATION TES
T 85
0-11
50°C
MMG 4 - NOVEMBRE 10 ................. 73
MANAURITE 40XO
OXYDATION RESISTANCE
1 • Oxydation processAfter ethanol cleaning, samples are weighed (3 times)
Cycle: Heat up : 300° C.h-1
Soaking time : 10 hours
Cooling : 300° C.h-1
After cycle, sample (with scale eventually) is weighed.
See curves obtained for weight increase hereafter.
2 • These curves show a tendancy to have a constant rate of weight gain after a
certain number of cycles ; this rate can be calculated and the results are
obtained in 10-6g.cm-2.h-1.These results can be converted in corrosion depth in mm/year
Corrosion depth in cycling oxidation in air
1000 °C 1050 °C 1100 °CXM 1.05
XTM 0.42 0.52 0.83
40XO 0.22 0.45 0.75
74 ................ MMG 4 - NOVEMBRE 1074 ................ MMG 4 - MARS 09
MANAURITE 40XO
0.00
20
0.00
15
0.00
10
0.00
05
0.00
25
XTM
40X
O
∆m per surface unit (g/cm2)
01
23
45
6
Nu
mb
er o
f cy
cles
78
910
CYCLING O
XIDATION IN A
IR AT 10
00°C
TOTA
L WEIGHT INCREA
SE PER
SURFA
CE UNIT
Cycling oxidation in air at 1100° C, see compartive cycling oxidation in air curves p91
MANAURITE 40XO
0.00
35
0.00
30
0.00
25
0.00
15
0.00
10
0.00
05
0.00
20
0.00
40
XTM
40X
O
∆m per surface unit (g/cm2)
01
23
45
6
Nu
mb
er o
f cy
cles
78
910
Cycling oxidation in air at 1100° C, see comparative cycling oxidation in air curves p 91
CYCLING O
XIDATION IN A
IR AT 10
50°C
TOTA
L WEIGHT INCREA
SE PER
SURFA
CE UNIT
MMG 4 - NOVEMBRE 10 ................. 75
76 ................ MMG 4 - MARS 0976 ................ MMG 4 - NOVEMBRE 1076 ................ MMG 4 - MARS 09
MANAURITE 40XO
Weldability of as cast 40XO material is comparable to 40X material and same WPS can be used for both
materials. Aged tubes can also be welded as shown hereunder.
78 ................ MMG 4 - MARS 0978 ................ MMG 4 - NOVEMBRE 1078 ................ MMG 4 - MARS 0978 ................ MMG 4 - MARS 09
MANAURITE XMR
PHYSICAL PROPERTIES
Specific gravity: 0,295 lb/inch3 (8,15 kg/dm3) Coefficient of expansion
Melting point : 1350°C (2460°F) in/in °F (10-6) mm/mm/°C (10-6)
From 70° F to 1560°F : 10,21 20°C to 850°C : 18,5
From 70° F to 1740°F : 10,4 20°C to 950°C : 18,9
Thermal conductivity From 70° F to 1920°F : 10,6 20°C to 1050°C : 19,3
At 1050°C (1922°F) : 30 W/m.°C From 70° F to 2100°F : 10,9 20°C to 1150°C : 19,7
(17 Btu/h.ft.°F)
At 20°C (68°F) : 10,5 W/m.°C
(6 Btu/h.ft.°F)
Specific heat Young modulus
Temperature Cal/g. °C or J/kg. °C
°C °F BTU/lb. °F
20 68 0,112 469
100 212 0,117 489,9
200 392 0,124 519,3
300 572 0,130 544,4
400 752 0,137 573,7
500 932 0,143 598,8
600 1112 0,150 628,2
700 1292 0,157 657,5
800 1472 0,163 682,6
900 1652 0,170 711,9
1000 1832 0,177 741,2
1100 2012 0,183 766,4
1200 2192 0,190 795,7
Temperature
°C °F MPa ksi
20 68 161,900 23,470
100 212 155,000 22,475
200 392 147,150 21,337
300 572 138,000 20,010
400 752 133,400 19,343
500 932 126,000 18,270
600 1112 117,700 17,066
700 1292 111,000 16,095
800 1472 106,000 15,360
900 1652 101,000 14,650
1000 1832 97,100 14,080
1100 2012 93,200 13,510
Temperature U.T.S. Y.S E
°C °F MPa ksi MPa ksi %
750 1350 333 48.4 157 22.8 16
800 1470 265 38.2 147 21.3 20
850 1560 196 28.4 137 19.9 22
900 1650 147 21.3 118 17.1 30
950 1740 118 17.1 88 12.8 32
1000 1830 93 13.5 78 11.4 38
1050 1920 74 10.7 69 10.0 47
1100 2010 61 8.8 55 8.0 39
MMG 4 - NOVEMBRE 10 ................. 79
Temperature U.T.S. Y.S E
°C °F MPa ksi MPa ksi %
750 1350 333 48.4 157 22.8 16
800 1470 265 38.2 147 21.3 20
850 1560 196 28.4 137 19.9 22
900 1650 147 21.3 118 17.1 30
950 1740 118 17.1 88 12.8 32
1000 1830 93 13.5 78 11.4 38
1050 1920 74 10.7 69 10.0 47
1100 2010 61 8.8 55 8.0 39
MANAURITE XMR
MECHANICAL PROPERTIES
1 • At room temperature(minimum values)
Ultimate tensile strength : 450 MPa 65 000 psi
Yield strength 250 MPa 35 500 psi
Elongation (on 4d) 8% for centrifugally cast pipes
6% for static castings
2 • Short time tensile test at various temperatures on as cast material
(typical values)
80 ................ MMG 4 - NOVEMBRE 10
MANAURITE XMR
MANAURITE XMR 100000 hours Creep Rupture Stress in Mpa
Temperature Temperature Stress Min XMR Stress Avg XMR ° C ° F (95% conf.)
850 1562 40,60 46,92860 1580 38,31 44,25870 1598 36,09 41,66880 1616 33,94 39,15890 1634 31,86 36,74900 1652 29,85 34,40910 1670 27,92 32,15920 1688 26,05 29,99930 1706 24,26 27,91940 1724 22,54 25,91950 1742 20,89 24,00960 1760 19,31 22,17970 1778 17,80 20,43980 1796 16,36 18,78990 1814 15,00 17,201000 1832 13,71 15,721010 1850 12,48 14,311020 1868 11,33 13,001030 1886 10,25 11,761040 1904 9,25 10,621050 1922 8,31 9,55
MANAURITE XMR 200000 hours Creep Rupture Stress in Mpa
Temperature Temperature Stress Min XMR Stress Avg XMR ° C ° F (95% conf.)
850 1562 37,84 43,70860 1580 35,61 41,10870 1598 33,45 38,59880 1616 31,37 36,16890 1634 29,36 33,83900 1652 27,42 31,57910 1670 25,55 29,41920 1688 23,76 27,33930 1706 22,04 25,34940 1724 20,40 23,43950 1742 18,82 21,61960 1760 17,32 19,88970 1778 15,89 18,23980 1796 14,54 16,68990 1814 13,26 15,201000 1832 12,05 13,821010 1850 10,91 12,521020 1868 9,85 11,301030 1886 8,86 10,181040 1904 7,94 9,141050 1922 7,10 8,19
MMG 4 - NOVEMBRE 10 ................. 81
MANAURITE XMRCREE
P RUPT
URE DATA
(95%
CONFIDEN
CE LE
VEL
)
82 ................ MMG 4 - NOVEMBRE 10
MANAURITE XMR
COMPA
RATIVE XMR vs XM
1000
00 hours creep
Rupture D
ata
MMG 4 - NOVEMBRE 10 ................. 83
MANAURITE XMRCREE
P RATE
SMANAURITE XMR VS MANAURITE XM
MMG 4 - NOVEMBRE 10 ................. 85
COMPARATIVEDATA
MMG 4 - NOVEMBRE 10 .................87
COMPA
RATIVE SIMULA
TED CARBURIZATION TES
T IN SOLID CEM
ENT
(850
° C - 115
0° C)
COMPARATIVE DATA
88 ................ MMG 4 - NOVEMBRE 10
COMPA
RATIVE CREE
P RUPT
URE 10
0 00
0 hr betwee
n 800
° C and 120
0° C
(Minim
um Values)
COMPARATIVE DATA
MMG 4 - NOVEMBRE 10 .................89
COMPA
RATIVE CREE
P RUPT
URE 10
0 00
0 hr betwee
n 950
° C and 110
0° C
(Minim
um Values)
COMPARATIVE DATA
90 ................ MMG 4 - NOVEMVRE 10
COMPA
RATIVE CREE
P RATE
S AT 10
50° C
COMPARATIVE DATA
MMG 4 - NOVEMBRE 10 .................91
0.00
7
0.00
6
0.00
5
0.00
4
0.00
3
0.00
2
0.00
1
0.00
0
p g
01
2
Nu
mb
er o
f cy
cles
34
56
78
910
XTM
40X
O
XO
XM
cra
ckin
g
COMPA
RATIVE CYCLING O
XYDATION IN A
IR AT 11
00° C
COMPARATIVE DATA
Manoir Pitres12, rue des Ardennes - BP 8401 - Pitres
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Manoir YantaiN° 1, Zhichu South Road, Zhifu district
Yantai, China 264 000
Tel. +86 6851 895, 6851 881 - Fax +86 6851 895
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Bretby Business Park - Ashby Road
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Tel. +44 1283 817902 - Fax +44 1283 81790
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602, B - Wing - Chandivali farm Road - Andheri (E)
Mumbai - 400 072 India
Tel. +91 9920 167307
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”Minimic Centre“ 2nd Floor - Chennai 600087
Tel. +91 4424 762451, 4442 144494 - Fax +91 4424 762452
MANOIR INDUSTRIES
www.manoir-industries.com MANOIR PETROCHEM®
Heat-resistant alloys for hydrocarbon processing
MA
NO
IR PETROC
HEM
®
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