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Introduction to Hazardous
Evaluation Techniques
• Guidelines for Hazardous Evaluation
Procedures (1992 by AIChE)• !econd Edition "ith #or$ed E%a&'les
• Center for Che&ical Process !afety(CCP!)
• A&erican Institute of Che&icalEnineers (AIChE)
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Hazard Evaluation echni*ues
19+, - 2,,1 19+, - 2,,1 19+. - 2,,1 19/, - 2,,1 19/2 - 19/0 19/0 - 2,,1
Safety Check Lists Relative PHA What if HAZOP
Review Ranking
Walk Historical ICI Mond Preliinary !rainstoring Ha"ards#hro$gh Lists Inde% Ha"ard O&era'ility
Ins&ection Analysis Analysis
(es ) *o +ow ,-I
Ha"ardo$s Mtls Line 'y Line
Ha"ardo$s O&ns +eviation
Analysis
#his &resentation only considers the HAZOP techni.$e/
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HAP
• HAP "as develo'ed by 3a"ley (19/0) ofICI 4ased on early account by Elliott 5 "en
(19+6)
• Hazo' studies are carried out by an
e%'erienced7 &ultidisci'lanary tea&
• 8evie" all 'hysical as'ects of a 'rocess
(lines7 e*ui'&ent7 instru&entation) to
discover 'otential hazards
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Basis for HAP
• he basis for a HAP is a critical
e%a&ination of infor&ation found in a
"ord &odel• It includes a flo"sheet7 a 'lant layout7
e*ui'&ent s'ecification or a P5I7
(Pi'in and Instru&ent ra"in)
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Hazo' Includes
1 Intention2 9eviation
: Causes
0 Conse*uences
(a) hazards
(b) o'eratin difficulties. !afeuards
+ 8eco&&endations ; Actions
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Hazo' Guide #ords
*O or *O# *egation of intention *o ,low of A
MOR- 0$antitative increase ,low of A greater than design flow
L-SS 0$antitative decrease ,low of A less than design flow
AS W-LL AS 0$antitative increase #ransfer of soe co&onent additional to A
PAR# O, 0$antitative decrease ,ail$re to transfer all co&onents of A
R-1-RS- Logical o&&osite of intention ,low of A in direction o&&osite to design direction
O#H-R #HA* Co&lete s$'stit$tion #ransfer of soe aterial other than A
More recent co&$teri"ation techni.$es $se a Standard Set Of 2eneric +eviations
,or S&ecific Section #y&es/ See +ev3ns ta' for e%a&les/
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Co&&on HAP Analysis
Process Para&eters,low #ie ,re.$ency Mi%ing
Press$re Co&osition 1iscosity Addition
#e&erat$re &H 1oltage Se&aration
Level S&eed #o%icity Reaction
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Pre'are for the 8evie"
Attitude
Pre'aration no"lede Info for study
E%'erience ea&s HAP P5Ids7 3ayout
E%'erience
able
eviation Causes Conse*uences !afeuards Action
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Hazop
Flow
Sheet
!elect a 'rocess
section or
o'eratin ste'
E%'lain desin 8e'eat for all
intention 'rocess sections
!elect a 'rocess 8e'eat for all
variable or tas$ 'rocess variables
A''ly uide "ord 8e'eat for all
to 'rocess variable uide "ords
E%a&ine evelo' action
Conse*uences ite&s
associated "ith
deviation
3ist 'ossible Assess acce'tability
causes of of ris$ based on
deviation conse*uences
Identify e%istin
safeuards to
'revent deviation
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Hazop Pitfalls
Poor $nderstanding 'y anageent of the HAZOP &roced$re
An Ethylene 'lant has 1,, P5Is7 +2. e*ui'?t ite&s 456 ite&s
Consider . variables7 Pressure7 e&'erature7 =lo"
Co&'osition and =unction 6 variables
Consider + Guide"ords7 @one7
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ther Pitfalls
• Ine%'erienced HAP tea&
• Inade*uately trained or in-e%'erienced
leader
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Co&&on Hazo'
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Hazo'
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Hazo'
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HAP E%a&'le
)o Co&'ressor Inlet
)ea&s tend to *uic$ly identify alar&s7 shut-do"ns
and controls7 and clai& the& for safe(uards
An alar& not tested &ay not "or$ "hen called u'on
Inlet 3ine to do so
@uisance alar&s are fre*uently by'assed and are
not effective as safe(uards
ften o'erators are not &onitorin( control 'anel
Ealve in &anual Auto&atic control routines are often set in &anual
&ode
=
1
3AH
3IC
1
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!tandard !et of eviations
I @o eviation Colu&n essel 3ine E%chaner Pu&' Co&'ressor
1 Hih =lo" 8
2 Hih 3evel 8 8
: Hih Interface 8
0 Hih Pressure 8 8 8 8
. Hih e&'erature 8 8 8 8
+ Hih Concentration 8 8 8
/ 3o" ; @o =lo" 8 86 3o" 3evel 8 8
9 3o" Interface 8
1, 3o" Pressure 8 8 8 8
11 3o" e&'erature 8 8 8 8
12 3o" Concentration 8 8 8
1: 8everse ;
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y'ical Hazo' #or$sheetCo&'any @ova 8evision 7 ate ,2-Fun-9/
3ocation Corunna " @o Cor -12:-0.+/ Pae 9
3eader RAH Proc es :! 8esearch ' ech
!cribe 2,R Instr?ts 2H Electrical HH ther Prod?n PM
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Chec$ 3ist E%a&'le
1 Chanes In uantity a Hih =lo" 1 Pu&' racin7 delivery vessel 'ressure lost7
suction 'ressurized7 scale disloded7 lea$ in
heat e%chaner
3oss of auto&atic
control
b 3o" =lo" 2 Pu&' failure7 scalin of delivery7 'resence of
forein body7 'oor suction condition7
cavitation7 lea$ in heat e%chaner7 drain
lea$7 valve a&&ed
'erator error
c @o =lo" : Pu&' failure7 delivery vessel
over'ressurized7 as bloc$ae7 'resence of
forein body7 scale7 sedi&ent7 suction vessel
e&'ty
=ailure of oint7 'i'e7
valve7 tra'7 burstin
disc7 relief valve
d 8everse =lo" 0 Pu&' failure7 'u&' reversed7 delivery vessel
over 'ressurized7 'oor isolation7 as loc$in7
surin7 bac$ si'honin
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Chec$ 3ist ContDd
2 Chanes in 'hysical
condition
a Hih or 3o"
'ressure
1 4oilin7 cavitation7 freezin7 che&ical
brea$do"n7 flashin7 condensation7
sedi&entation7 scalin7 foa&in7 as
release7 'ri&in7 e%'lodin7 i&'lodin
Chanes in viscosity7 density E%ternal =ire7
#eather conditions7 Ha&&erb Hih or 3o"
e&'erature
2 sa&e as 1
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Chec$ 3ist ContDd: Chan(es in che&ical
condition
a Hi(h or 3o"
Conentration
1 Chan(es in 'ro'ortion of &i%ture7 in "ater or
solvent content
b Conta&inants 2 In(ress of air7 "ater7 stea&7 fuel7 lubricant7
corrosion 'roducts7 other 'rocess &aterials
fro& hi(h 'ressure syste&7 lea$a(e throu(h
heat e%chan(ers (as entrain&ent7 s'ray7
&ist
0 !tartu' and
!hutdo"n Condition
a )estin( 1 Eacuu&7 'ressure testin( "ith "ith har&less
&aterial
b Co&&issionin( 2 Concentration of reactants7 inter&ediates
c
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End of HAP Presentation
• Presented to E!-:1/y
• 2/ =eb7 2,,1
• 4y 8A Ha"rela$