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HAZMAT Identification
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HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Dec 29, 2015

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Norman Preston
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Page 1: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

HAZMAT Identification

Page 2: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

HAZMAT Identification

Often most difficult part of incident ALWAYS use at least TWO concurring

sources

Page 3: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

HAZMAT References

Emergency Response Guidebook

Container Markings Shipping Papers Material Safety Data Sheets Monitors/Chemical Tests Computer Databases

Telephone Hotlines Poison Centers Chemists Toxicologists Reference Books

Page 4: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Emergency Response Guidebook

U.S., Canada, Mexico Lists >1000 products

with placards, UN numbers, chemical names

Cross references emergency, evacuation procedures

Medical information is limited, very generic

Multiple chemicals share UN numbers

Page 5: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Container Markings

Page 6: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Container Markings

“Candystriper” HCN Tank Car

Page 7: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Shipping Papers

List specific substances

Indicate quantities carried

Operators may not take papers with them

Scene may be too unstable to retrieve

Papers may be incomplete, inaccurate

Page 8: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.
Page 9: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.
Page 10: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Material Safety Data Sheets

Present at fixed facilities

Available for ALL hazards on site

Cover wide range of common, simple products

Typically list: Material name Characteristics Manufacturer Health, fire, reactivity

dangers Safe handling

considerations Emergency

procedures

Page 11: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Monitors and Testing

Radioactivity Combustibility Oxygen availability pH (Corrosiveness) Carbon monoxide Hydrogen sulfide Organic vapors

Page 12: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Computer Databases

CAMEO® ALOHA® MARPLOT® OHMTADS®

Page 13: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Telephone Hotlines

Chemical Transportation Emergency Center (CHEMTREC)

Sponsored by Chemical Manufacturer’s Association (CMA)

Page 14: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

CHEMTREC Services

Emergency response information Access to manufacturer’s representatives Activation of specialized teams to deal

with chlorine, phosphorus, vinyl chloride, HCN, HF, and LPG

Activation of CHEMNET response teams

Page 15: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

CHEMTREC Limitations

Communicators NOT technical personnel Will NOT interpret data or go beyond what

information sheets say Must have product trade or chemical

name to provide assistance Cannot provide information on effects of

mixing of several products

Page 16: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

CHEMTREC Information Needed

What has happened? Where? When? Chemical(s) involved Container type condition Shipper/origin Carrier

Consignee/destination Nature/extent casualties Nature/extent property damage Prevailing weather Nature of incident area Caller name/location Call-back number

Page 17: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Federal, State, Local Resources

Federal US EPA Coast Guard

State TNRCC TDH Railroad Commission Parks & Wildlife Agriculture Department

Local Poison Control Health Department Colleges, Universities

Page 18: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Reference Books

NIOSH Pocket Guide to Chemical Hazards Farm Chemical Handbook Chemical Hazards Response Information System

(CHRIS) NFPA Fire Protection Guide on Hazardous

Materials American Association of Railroads Emergency

Action Guides

Page 19: HAZMAT Identification. Often most difficult part of incident ALWAYS use at least TWO concurring sources.

Reference Books

Condensed Chemical Dictionary Dangerous Properties of Industrial Chemicals (Sax) Chemical Synonyms and Trade Names Merck Index