GRIDS: Rechargeable Zn – MnO 2 Battery Developments Low Cost Storage for the Grid Scale The City University of New York, Energy Institute PI: Sanjoy Banerjee Presenter: Damon Turney EMD MnO 2 Cathode: Long Cycle Life Demonstration, Failure Studies Cathode active material: EMD -MnO 2 Anode active material: Zn metal Zinc (Zn) and manganese dioxide (MnO 2 ) • Inexpensive • Safe • Water compatible • Abundant Zn-MnO 2 Research Cell ~200 Battery Tester Channels Pasted Zinc Anode: Design of Experiment Results, Failure Studies Investment and Time Technology Cost Cost Target for Grid Application Zn – MnO 2 Active Materials Typical Battery Active Materials Electrolytic MnO 2 (EMD, -MnO 2 ) is reversibly converted to MnOOH during its initial stage of discharge. By cycling in a well-controlled range of cell potential and depth-of- discharge, cycle life of greater than 3,000 is achieved. By controlling zinc material migration, shape-change and zinc dendrites are avoided. We would like to thank ARPA-E for financial support under award number DE-AR0000150 1-D Computational Modeling Film Theory Predictions Dissection Analysis Shows Formation of Zinc Surface Layers Before Cycling 20 um | | After Cycling Same Location Pre-cycling and Cycling Metrics: Baseline vs Improved Designs In-Operando X-Ray Observations of Zinc Paste Degradation at Brookhaven National Laboratory, NSLS Control of Zinc Shape Change Baseline Improved Design Cycle Life Demonstrated > 3,000 160 Convent Ave, New York, NY 10031 Email: [email protected] Email:[email protected] • Porosity, Permeability, Tortuosity • Wettability • 4-Point Conductivity • Shape Change, Zinc Migration • Anode Energy Storage Efficiency • Additives: Paste and Electrolyte • Separators Ongoing experiments
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GRIDS: Rechargeable Zn – MnO2 Battery Developments Low Cost Storage for the Grid Scale
The City University of New York, Energy Institute PI: Sanjoy Banerjee Presenter: Damon Turney
EMD MnO2 Cathode: Long Cycle Life Demonstration, Failure Studies
Cathode active material: EMD -MnO2
Anode active material: Zn metal
Zinc (Zn) and manganese dioxide (MnO2) • Inexpensive • Safe • Water compatible • Abundant
Zn-MnO2 Research Cell ~200 Battery Tester Channels
Pasted Zinc Anode: Design of Experiment Results, Failure Studies
Investment and Time
Tech
no
logy
Co
st
Cost Target for Grid Application
Zn – MnO2 Active Materials
Typical Battery Active Materials Electrolytic MnO2 (EMD, -MnO2) is reversibly converted to MnOOH during its initial stage of discharge. By cycling in a well-controlled range of cell potential and depth-of-discharge, cycle life of greater than 3,000 is achieved. By controlling zinc material migration, shape-change and zinc dendrites are avoided.
We would like to thank ARPA-E for financial support under award number DE-AR0000150
1-D Computational Modeling Film Theory Predictions Dissection Analysis Shows Formation of Zinc Surface Layers
Before Cycling 20 um | |
After Cycling Same Location
Pre-cycling and Cycling Metrics: Baseline vs Improved Designs
In-Operando X-Ray Observations of Zinc Paste Degradation at Brookhaven National Laboratory, NSLS
Control of Zinc Shape Change Baseline Improved Design
Cycle Life Demonstrated > 3,000
160 Convent Ave, New York, NY 10031 Email: [email protected] Email:[email protected]
• Porosity, Permeability, Tortuosity •Wettability • 4-Point Conductivity • Shape Change, Zinc Migration • Anode Energy Storage Efficiency • Additives: Paste and Electrolyte • Separators
Ongoing experiments
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