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Version: 12
Primax Electronics LTD.
Green Product Chemical Substances Specification PAGE: 1 OF 31
Green Product Chemical Substances Specification –v12 Document No.: QW-5Q002 Level of Secret ■Common□confidential
Green Product Chemical Substances Specification
Approver Reviewer Issuer Department
By Honda Lee Jay Yung PDTC
Date 01/02/2013 01/02/2013
Version: 12
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Green Product Chemical Substances Specification PAGE: 2 OF 31
Green Product Chemical Substances Specification –v12 Document No.: QW-5Q002 Level of Secret ■Common□confidential
Version Date Change Content Issuer Approver
1.0 8/29/2003 Original Issue Hongdar Kuo LY Wang
2.0 12/15 / 2003 Title, Scope, Spec and requirement Hongdar Kuo Honda Lee
2.1 12/30 / 2003 Spec update Hongdar Kuo Honda Lee
2.2 1/15 / 2004 Revise testing method, spec and wording
Hongdar Kuo Honda Lee
3.0 9/29/2004 Revise testing method and update spec. Add heat resistance requirements for lead-free component
CORP. LTD., PRIMAX ELECTRONICS (CHONGQING) CORP. LTD. And the aforementioned
company in the present and future, directly or indirectly established in countries around the subsidiaries,
affiliates or owned the factories, offices and other business organizations) (referred here after as
Primax). It clearly clarifies banned substances, restricted substances and managed substances so that
impact to the environment can be minimized and achieve the goal of enterprise sustainable
development.
1.1 Primax Green Product Policy:
Primax commits to actively participating in the protection of global environment, implementing
green designs and green management to fulfill our duties as a global citizen, while providing
excellent products and services.
2 SCOPE
2.1 Products are designed, purchased, manufactured, and sold by Primax. Products and parts are
provided by Primax’s suppliers or outsourced contractors.
2.2 Parts, materials and other items used for Primax’s and OEMs’ products are:
‧Assemblies: including function units, modules, and board assemblies.
‧Accessories: for using products such as remote controls, AC adopters, and batteries, etc.
‧Parts: including electronic/electrical parts, mechanical parts, electro-mechanical parts, printed
circuit boards (PWBs), recording media, packaging materials and packaging components.
‧Auxiliary materials: such as adhesives, solder materials, and tapes.
‧Substances are used in process, such as fluxes and washing solutions.
‧Repair parts.
‧Packaging materials are used for transport/protection by part suppliers.
3 REFERENCE DOCUMENTS
3.1 JIG-101 Ed 2.0: Joint Industry Guide: Material Composition Declaration for Electrotechnical
Products
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3.2 Regulation of the European Parliament and of the Council on the Registration, Evaluation,
Authorization and Restriction of Chemicals, 1907/2006/EC, December 2006. (REACH
Regulation)
3.3 Directive of the European Parliament and of the Council on Packaging and Packaging waste,
94/62/EC, December 1994.(including the order of extending)
3.4 Council Directive 2006/66/EC on Batteries and Accumulators and Waste Batteries and
Accumulators and Repealing Directive 91/157/EEC, September 2006.
3.5 Directive of the European Parliament and of the Council on the Restriction of the Use of
Certain Hazardous Substances in Electrical and Electronic Equipment, 2002/95/EC and
2011/65/EU. (RoHS Directive) (including the order of extending)
3.6 Customer’s Green Product Requirement.
4 TERMINOLOGY AND ABBREVIATIONS
4.1 Environment-related substances: Substances that have significant impact on environment and
human body and therefore are controlled by Primax.
4.2 Management Category: to manage the above-mentioned substances, the following three levels
are used.
4.2.1 Level I Banned Substances: The substance groups of Level I are those subject to currently
enacted legislations that prohibit or restrict their use in products or marketing. For those
substances may possible be used in Primax product, it must be banned immediately.
4.2.2 Level II Restricted Substances: Substances and purposes classified at this level are those
for which periods for phase-out are individually set, or for which Primax’s clients ban the
use of these substances, which makes Primax an advocate prohibiting the use of these
substances.
4.2.3 Level III Managed Substances: No periods or targets for reduction are currently set for the
substances and purposes classified at this level. However, the contents of the substances in
parts and materials ought to be reduced. Or for survey purposes only.
4.2.4 The following table lists usage status of substances:
Category Subject Allowed to be contained in
parts
Level I Banned Substances
Banned by regulations No, report to Primax
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Level II Restricted Substances
Substances that Primax advocates restricting the use
No, report to Primax
Level III Managed
Substances
Substances that are to be prohibited or used in the future or for survey purposes only
Yes, report to Primax
4.3 Contained: a situation in which a substance is added to, fills up, mingles with, or adheres to the
parts or devices employed in products, or the materials used for the parts or devices, regardless
if the situation is intentionally created or not.(When a substance is unintentionally contained in,
or added to a product in processing process.)
4.4 Impurity: a situation in which natural impurities are part of a natural material but cannot be
removed in the refining process, or impurities are generated in a synthesis process and cannot
be removed.
4.5 Homogenous Material: a homogenous material is a unit that cannot be mechanically disjointed
into different materials and that has uniform composition throughout and include alloys,
plastics, glass, ceramics, coating…(electronic component is not homogenous material.)
4.6 ppm threshold: Environment-related substances that are banned or restricted cannot be used in
materials and parts and be provided to Primax. The ppm threshold refers to the maximum
concentration of impurities in homogenous materials, but exceptions are not included. ppm is
parts per million, unit of measurement for weight percentage. 1 ppm = 1 mg/kg = 0.0001 % by
weight.
4.7 Highly hazardous material: materials that are controlled under EU RoHS are defined as highly
hazardous materials. Suppliers are required to provide a testing report (from ITS, SGS, TUV…)
4.8 Halogen-Free requirement:Total bromine or total chlorine concentration of each homogenous
material in the part or product must comply with Br < 900 ppm and Cl < 900 ppm and Br + Cl <
1500 ppm
4.9 Phthalates requirement:Total phthalates and each phthalate concentration of each homogenous
material in the part or product must be less than 1000 ppm.
4.10 Regarding the substances or their purposes whose use is banned by regional or country laws
and ordinances or banned by Primax customer, if the substances or their purposes are not
clearly regulated in this specification, Primax and its supplier must meet the individual
requirement.
4.11 GP Portal:http://gp.primax.com.tw/gpms_primax/
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5 Requirement
5.1 Any materials, parts, assemblies, accessories, auxiliary materials and packaging materials
provided to Primax must not contain environment-related substances defined by the Primax
Green Products Chemical Substances Specification (except for substances that are used for
survey). Natural impurities are acceptable but they must be in line with the related regulations.
5.2 When part approved, Primax’s suppliers must send parts/materials to an authorized laboratory
(see Appendix 3) and follow up disassembling rule 6.2.1 to test and complete the “GP Portal”.
(Test report deadline is one year). Test report requirements follow up item 8.
5.3 If parts/materials provided or added to a product in processing process by Primax suppliers
contained environment-related substances listed in Appendix 1, suppliers must report and
complete the “GP Portal” by homogenous materials. In order to comply with EU related
environmental rules (ex. REACH directive…..), Primax’s suppliers must survey all substances
(100% composition) which contained in parts and fill out the “GP Portal”. Reference example:
capacitor (see the following picture) is disassembled at least 7 homogenous materials and fill
out the “GP Portal”.
Terminal Plating
5.4 When fill out the “GP Portal”, supplier must follow up homogenous material principle to
declare coating material which is used on pin of electronic component(such as
Sn-3.0Ag-0.5Cu,matte Sn….) or surface treatment of metal alloy.(such as Ni,Cr3+, Cr6+…)
5.5 Primax will use XRF to carry out incoming inspection for Br and Cr (Cr3+ + Cr6+) contained in
homogenous material of a product. Primax’s suppliers must fill Br, Cr3+ and Cr6+ content
clearly in the “GP Portal”.
5.6 If suppliers don’t follow 5.3 to fill out the “GP Portal”, suppliers must send the samples to test
by Primax approved laboratory. Furthermore, suppliers must provide MSDS/materials content
list of parts and identify what kinds of environment-related substances.
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5.7 Halogen threshold of Appendix 1 is applicable to Halogen-Free part.
5.8 Halogen-Free part must meet requirements of Safety, EMC, Reliability, electrical, mechanical
and related criteria.
5.9 Lithium battery must provide MSDS and test report of UN manual of tests and criteria, part III,
subsection 38.3. Non-lithium battery must provide MSDS.
5.10 If parts/materials provided or added to a product in processing process by Primax suppliers
contained conflict minerals, such as tin, tantalum, gold, tungsten or their derivatives. Suppliers
must upload the “Declaration of DRC Conflict-free” and complete the smelter information in
GP Portal.
6 Specifications
6.1 Environment-related substances that are controlled by Primax, for detailed specifications, see
Appendix 1.
6.2 Highly hazardous banned substances:
According to EU RoHS, six chemical substances: lead, cadmium, mercury, hexavalent
Chromium, PBB, and PBDE are considered as highly hazardous banned substances by Primax.
Suppliers must report to Primax if they used the environment-related substances in their
parts/materials and provide testing report if they used highly hazardous banned substances as
well.
6.2.1 The same type of parts may contain several kinds of materials. Therefore, when parts are
testing, they must be disassembled and testing separately. Disassembling rule is suggested
as follows:
a. Outer or exposed parts of a product should be disassembled as separate materials.
E.g.: If ink is used on an outer part, the ink and the outer part should be testing separately.
b. Small-scale parts smaller than 4 cubic millimeter (mm3) need not to be disassembled. The
part is more than 4 mm3 must follow up next 3 steps:
1.The parts with pin need to be disassembled pin and body. (such as: DIP, QFP…)
2.The parts without pin need to be disassembled electrode and body. (such as:
Resistance…)
3.BGA series need to be disassembled solder ball and body.
c. A part with different materials should be disassembled as separate materials.
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E.g.: Connectors should be disassembled as housing (plastic) and contact (metal) and be
testing separately.
d. A part with different colors materials (such as ink, plastic and cables) should be testing
separately.
E.g.: If a part has three colors for the same kind of wire: red, blue, and white. Wires of
different colors should be testing separately.
e. Parts made from different formulas or made by different vendors should be testing
separately.
E.g.: Different ABS materials should be testing separately.
f. Notice that materials added in manufacturing process, such as lubricants, must be testing.
6.2.2 Lead:
6.2.2.1 Applicable to all items apart from the exceptions listed in 6.2.2.4
6.2.2.2 Specifications: ・Plastic, rubber, paint, ink, printing, resin and packaging materials: lead concentration < 90 ppm ・Metal: lead concentration < 1000 ppm (*for lead concentration of steel, aluminum, copper, refer to 6.2.2.4 Exceptions) ・Glass materials, ceramic parts: lead concentration < 1000 ppm, but exceptions defined in RoHS are acceptable ・Electronic parts: lead concentration< 1000 ppm ・Solder: lead concentration < 1000 ppm ・Others: lead concentration < 1000 ppm ・Cable: cable wrappings, cable jacket, etc.: lead concentration < 90ppm; the metal part of a cable: lead concentration < 1000 ppm.
6.2.2.3 Testing Method: IEC 62321
6.2.2.4 Exceptions: · Alloys: a. steel: lead concentration < 3500 ppm b. aluminum alloy: lead concentration < 4000 ppm c. copper alloy: lead concentration < 40000 ppm · Lead contained in a high-melting point solder (lead based alloys containing 85% by weight or more lead) · Lead contained in solder used for a server or a storage device. · Electrical and electronic components containing lead in a glass or ceramic other than dielectric ceramic in capacitors. (e.g. piezoelectric devices, or in a glass or ceramic matrix compound) The above glass materials include adhesives, resistor elements, glass frit, conductive pastes(silver or cooper ones), and sealing materials. · Lead in glass of cathode-ray tubes.
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· Lead in glass of fluorescent tubes not exceeding 0.2 % by weight. · Optical glass, filter glass.
· Solder to complete a viable electrical connection between semiconductor die and carrier within integrated circuit Flip Chip packages.
6.2.3 Cadmium:
6.2.3.1 Applicable to all items apart from the exceptions listed in 6.2.3.4
a. LevelⅡRestricted Substances. Threshold < 1000 ppm (Except for ceramics and glass) b. Ceramics and glass: Level Ⅲ Managed Substances. For survey purpose (Example: electronic component)
a. Level Ⅱ Restricted Substances. Threshold < 50 ppm (Except for semiconductors and metal alloys) b. Level Ⅱ Restricted Substances. Restricted in metal alloys. Threshold < 1000 ppm c. Semiconductors: Level Ⅲ Managed Substances. For survey purpose
Beryllium 7440-41-7
Beryllium oxide 1304-56-9
Beryllium-Aluminum alloy 12770-50-2
Beryllium copper —
Beryllium hydroxide 13327-32-7
Beryllium phosphate 13598-15-7
Beryllium and Beryllium Compounds
Beryllium sulfate tetrahydrate 7787-56-6
a. Level Ⅱ Restricted Substances. Threshold < 1000 ppm (Except for electronic components) b. Electronic components: Level Ⅲ
Managed Substances. For survey purpose
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Category Substance CAS# Threshold
Beryl ore 1302-52-9
Beryllium Carbonate 66104-24-3
Beryllium Nitrate 13597-99-4
Beryllium Chloride 7787-47-5
Beryllium Fluoride 7787-49-7
Beryllium Sulfate 13510-49-1
Beryllium Copper —
Other Beryllium compounds —
Bismuth 7440-69-9
Bismuth trioxide 1304-76-3
Bismuth nitrate 10361-44-1
Bismuth and Bismuth Compounds
Other bismuth compounds —
Level Ⅲ Managed Substances. For survey purpose
Cadmium 7440-43-9
Cadmium oxide 1306-19-0
Cadmium sulfide 1306-23-6
Cadmium chloride 10108-64-2
Cadmium sulfate 10124-36-4
Cadmium Carbonate 513-78-0
Cadmium fluoroborate 14486-19-2
Cadmium nitrate 10325-94-7
Cadmium nitrate tetrahydrate 10022-68-1
Cadmium stearate 2223-93-0
Cadmium chromate 14312-00-6
Cadmium and Cadmium Compounds
Other cadmium compounds —
a. Level I Banned Substances. Banned in plastic, rubber, dyes, pigments, paints, polymer colorants , stabilizers, solder, resistor element(glass frit)and packaging materials. Threshold < 5 ppm; Metal coating is not intentionally added. b. Other application. Threshold < 50 ppm
Chromium (Ⅲ) oxide 1308-38-9
Neochromium 64093-79-4 Chromium and its Compounds(excluding hexavalent chromium) Other chromium compounds —
Level Ⅲ Managed Substances. For survey purpose
Sodium dichromate 10588-01-9
Chromium(VI) oxide 1333-82-0
Calcium chromate 13765-19-0
Lead(II) chromate 7758-97-6
Potassium dichromate 7778-50-9
Potassium chromate 7789-00-6
Chromium (Cr6+) 18540-29-9
Chromic acetate 1066-30-4
Chromium (VI) and its Compounds2 18540-29-9
Lithium chromate 14307-35-8
Sodium chromate 7775-11-3
Hexavalent Chromium Compounds
Potassium chlorochromate 16037-50-6
a. Level I Banned Substances. Plastic, rubber and packaging materials. Threshold < 100 ppm; Metal coating, printing, ink and paint are not intentionally added. b. Other application. Threshold < 1000 ppm
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a. Level I Banned Substances. Banned in plastic, rubber, dyes, pigments, paints, polymer colorants , stabilizers, and packaging materials. Threshold < 90 ppm b. Other application, e.g. electronic parts. Threshold < 1000 ppm c. Solder: Threshold < 1000 ppm d. Steel: Threshold < 3500 ppm e. aluminum alloy: Threshold < 4000 ppm f. copper alloy: Threshold < 40000 ppm
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Category Substance CAS# Threshold
Lead (IV) chloride 13463-30-4
Lead (II) iodide 10101-63-0
Lead (II) cyanide 592-05-2
Lead fluoroborate 13814-96-5
Lead fluosilicate 25808-74-6
Lead nitrate 10099-74-8
Lead perchlorate 13637-76-8
Lead thiocyanate 592-87-0
Lead (II) acetate,trihydrate 6080-56-4
Lead (II) acetate 301-04-2
Lead (IV) acetate 546-67-8
Lead oleate 1120-46-3
Lead stearate 7428-48-0
Lead (II) metaborate 10214-39-8
Lead metasilicate 11120-22-2
Lead metasilicate 10099-76-0
Lead antimonite 13510-89-9
Lead arsenate (1:1) 7784-40-9
Lead (II) arsenite 10031-13-7
Lead chromate; chrome yellow 1344-37-2
Lead molybdate 10190-55-3
Calcium plumbate 12013-69-3
Tetramethyl lead 75-74-1
Tetraethyl lead 78-00-2
Lead Naphthenate 61790-14-5
Lead Methanesulfonate 17570-76-2
Lead Styphnate 15245-44-0
Other lead compounds —
Mercury 7439-97-6
Mercury(II) chloride 7487-94-7
Mercury(II) oxide 21908-53-2
Mercuric chloride 33631-63-9
Mercuric sulfide 1344-48-5
Mercury alloys; amalgam —
Mercury (I) oxide 15829-53-5
Mercury (I) chloride 10112-91-1
Mercury (II) nitrate 10045-94-0
Mercury (I) sulfate 7783-35-9
Mercury and Mercury Compounds
Mercury (II) fulminate 628-86-4
a. Level I Banned Substances. Threshold < 5 ppm b. Mercury in cold cathode fluorescent lamps and external electrode fluorescent lamps (CCFL and EEFL) for special purposes (per lamp): b-1 Short length (≦500 mm): mercury concentration < 3.5 mg b-2 Medium length ( >500 mm and ≦1500 mm): mercury concentration < 5 mg b-3 Long length ( >1500 mm): mercury concentration < 13 mg
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Category Substance CAS# Threshold
Mercury (II) acetate 1600-27-7
Methylmercury salts 22967-92-6
Ethymercury salts —
Propylmercury salts —
Phenylmercury salts —
Methoxyethylmercury salts —
Dialkylmercury —
Diphenylmercury 587-85-9
Mercuriphenyl Nitrate 55-68-5
Other mercury compounds —
c. Mercury in other low pressure discharge lamps (per lamp) < 15 mg
Nickel(II) oxide 1313-99-1
Nickel(II) Carbonate 3333-67-3
Nickel(II) Sulfate 7786-81-4
Nickel 7440-02-0
Nickel carbonyl 13463-39-3
Nickelhydroxide 11113-74-9
Nickel(II)hydroxide 12054-48-7
Nickeldioxide 12035-36-8
Nickelsubsulphide 12035-72-2
Nickelsulphide 11113-75-0
Nickelsulphide 12137-12-1
Nickel acetate 373-02-4
Nickelocene 1271-28-9
Nickel and Nickel Compounds
Other Nickel compounds —
a. Level Ⅱ Restricted Substances. It is not intentionally added in the surfaces of products that are intended to come into direct and prolonged contact with the skin. b. Other application: Level Ⅲ Managed Substances. For survey purpose
Selenium 7782-49-2
Selenous Acid 7783-00-8
Hydrogen selenide 7783-07-5
Sodium selenide 1313-85-5
Selenium dioxide 7446-08-4
Sodium selenate 10112-94-4
Dimethyl selenide 593-79-3
Selenium oxide 12640-89-0
Selenium and Selenium Compounds
Other selenium compounds —
Level Ⅲ Managed Substances. For survey purpose
Magnesium Magnesium 7439-95-4 Level Ⅲ Managed Substances. For survey purpose
Copolymer of alkyl acrylate, methyl methacrylate and tributyltin methacrylate(alkyl; C=8)
67772-01-4
Tributyltin sulfamate 6517-25-5
Bis(tributyltin) maleate 14275-57-1 24291-38-3
Tributyltin chloride 1461-22-9 7342-38-3
Mixture of tributyl tin cyclopentanecarboxylate and its alaogs (Tributyl tin naphthenate)
85409-17-2
Mixture of tributyltin 1,2,3,4,4a,4b,5,6,10,10a-decahydro-7- isopropyl-1,4a-dimethyl-1-phenanthlenecarboxylate and its analogs (Tributyltin rosin salt)
26239-64-5
Tributyl tin & compounds 688-73-3
Tributyl tin bromide 1461-23-0
Tributyl Tins & Triphenyl Tins
Triphenyl tin bromide —
Level I Banned Substances. Not intentionally added
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Level I Banned Substances. Not intentionally added
Vinyl Chloride Polymer (PVC)
Poly vinyl chloride(PVC) 9002-86-2
a. Level Ⅱ Restricted Substance. Not intentionally added (except for cable and connectors) b. Level Ⅲ Managed Substances. Cable and connectors for survey purpose
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(14) [ Aliphatic/alicyclic brominated compounds ]
—
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(15) [ Aliphatic/alicyclic brominated compounds in combination with antimony compounds ]
—
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(16) [ Aromatic brominated compounds (excluding brominated diphenyl ether and biphenyls) ]
—
Brominated Flame Retardants
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(17) [ Aromatic brominated compounds (excluding brominated diphenyl ether and biphenyls) in combination with antimony compounds ]
—
a. Level Ⅱ Restricted Substance. Threshold < 900 ppm (except for cable/connectors, electronic component, fans, power supplier,
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Category Substance CAS# Threshold
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(22) [ Aliphatic/alicyclic chlorinated and brominated compounds ]
—
Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(42) [ Brominated organic phosphorus compounds ]